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US5207778 - Method of Matrix Acidizing

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United States Patent [19] Jennings, Jr. 111111111111111111111111111111111111111111111111111111111111111111111111111 . USOO5207778A [11] Patent Number: [45] Date of Patent: 5,207,778 May 4, 1993 [54] METHOD OF MATRIX ACIDIZING [75] Inventor: Alfred R. Jennings, Jr., Plano, Tex. [73] Assignee: Mobil Oil Cor oration, Fairfax , Va. [21] Appl. No.: 782,192 [22] Filed: Oct. 24, 1991 [51] Int. Cl.s E21B 43/27 [52] U.S. Cl 166/281; 166/307 [58] Field of Search 166/281, 3 07, 2 71 [56] References Cited U.S. PATENT DOCUMENTS 2, 850,098 9/1958 Moll et aI 166/307 3,076,762 2/1963 Dill 166/307 3,233,672 2/1966 Carpenter 166/307 3,354, 957 11/1 967 Every et aI 166/302 4, 007,789 2/1977 CIampitt 166/307 X 4 ,23 7,9 74 1 2/ 198 0 S ch er ub el 166/307 X 4,787,456 11/1988 Jennings, Jr et aI 166/281 Primary Examiner -Stephen J. Novosad Atto rney , Agen t, orFirm-A. J. McKillop; G. W. Hager; C. A. Malone [57] ABSTRACT This invention is directed to a method to improve ma- trix acidizing of a carbonate containing formation by t ak in g a dv an ta ge o f w or mh ol es w hi ch a re c re at ed d ur - ing acidizing. The wormholes are closed with a solidifi- able gel which protects them from entry of additional a ci d. T he s ol id if ia bl e g el is a ll ow ed sufficient time to form a solid. After a solid gel is formed, additional acid is directed into the formation where it moves past the wormholes containing the solid gel. Thereafter , an addi- tional volume of solidifiabl gel is directed into the formation where it protects any subsequently formed wormholes and diverts the acid further into the forma- tion. An additional volume of acid is directed into the f or ma ti on a nd t he s te ps r ep ea te d u nt il the f or ma ti on h as been acidized to obtain a de si red degree of permeability. 4 Claims, 1 Drawing Sheet 1 0 1 2
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