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Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such

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SANDIA REPORT SAND2000-0958 Unlimited Release Printed April 2000 Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such as Anti-Terriorist Defenses Prepared by Sandia National Laboratows Albuquerque, New Mexico 87185 and Livermore, California 94550 Sandia is a multiprogram laboratory operated by Sandia Corporation. a Lockheed Martin Company, for the United States Departmeni of Energy under Contract DE-AC04-94AL85000. Approved for public release; further dissemination unlimited. Q Sandia National laboratories
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Page 1: Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such

SANDIA REPORT SAND2000-0958 Unlimited Release Printed April 2000

Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such as Anti-Terriorist Defenses

Prepared by Sandia National Laboratows Albuquerque, New Mexico 87185 and Livermore, California 94550

Sandia is a multiprogram laboratory operated by Sandia Corporation. a Lockheed Martin Company, for the United States Departmeni of Energy under Contract DE-AC04-94AL85000.

Approved for public release; further dissemination unlimited.

Q Sandia National laboratories

Page 2: Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such

Issued by Sandia National Laboratories, operated for the United States Department of Energy by Sandia Corporation.

NOTICE: This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government, nor any agency thereof, nor any of their employees, nor any of their contractors, subcontractors, or their employees, make any warranty, express or implied, or as.sume any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represent that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or othervise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government, any agency thereof, or any of their contractors or subcontractors. The views and opinions expressed herein do not necessarily state or reflect those of the United States Government, any agency thereof, or any of their contractors.

Printed in the United States of America. This report has been reproduced directly from the best available copy.

Availabie to DOE and DOE contractors from Office of Scientific and Technical Information P.O. Box 62 Oak IZldge, TN 37831

Prices available from (703) 605.6000 Web site: http://wwu.ntis.gov/ordering.htm

Available to the public from National Technical Information Service U.S. Department of Commerce 5285 Port Royal Rd Springfield, VA 22161

Page 3: Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such

SAND2000-0958Unlimited ReleasePrinted April 2000

Using Rigid Polyurethane Foams (RPF) forExplosive Blast Energy Absorption in

Applications Such as Anti-Terrorist Defenses

Ronald L. WoodfinExplosive Subsystems and Materials Department

Sandia National LaboratoriesP. O. BOX 5800

Albuquerque, NM 87185-1452

Abstract

Reduction of the data from recent experiments has shown that RPFs have a remarkable andsurprising capability to absorb and perhaps to dissipate the energy of a blast wave. The actualenergy absorbing mechanisms seem quite complex. There is, in spite of the lack of fundamentalunderstanding of mechanisms, a potential to use this material as a protective measure in anumber of situations. The possibility of ship hull protection has been considered. Anotherpossibility is the protection of concrete structures from a terrorist attack, such as a satchelcharge placed in contact, or a larger charge placed some distance away. The purpose of thisreport is to document the recent work done to quantify the blast energy absorbing capability ofthe RPF material as well as possible from the existing data, and to suggest appropriate avenuesfor research to gain better definition of the mechanisms involved. In addition, some potentialapplications are suggested. All of the data presented herein are digested from the earlier reports.This report only considers analysis of those data. Details of the experiments and techniques thatproduced the data are in those reports. RPF can forma valuable tool in protecting structuresagainst blast, such as from terrorist attack. Experiments are needed to confirm the predictivecapability of the derived extrapolator. These experiments are needed to make intelligent designdecisions, but, as an interim, a nine-inch thick layer of six-to-eight pound per cubic foot (pcf)RPF can be considered sufficient to greatly reduce damage, especially interior spalling, fromconcrete walls in a variety of attack scenarios. A six-inch thick layer is almost as effective. Thisanalysis has considered only blast wave damage. RPF should not be used for protection againstexplosively driven fragments. This analysis does not consider the effect of the pressure pulse onthe overall structure.

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Intentionally Left Blank

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Contents

Background ......................................................................................................................... 6Introduction ......................................................................................................................... 7Available Data ..................................................................................................................... 7

Analysis of Cavity Formation Data ............................................................................... 11Analysis of Flyer Plate Data .......................................................................................... 14Adjustment for Density and Explosive Used: ............................................................... 19

Extrapolation to Larger Explosive Charges ......................................................................2lInvestigation of Reduction in Ground Crater Size by RPF Layer .....................................28Conclusion ......................................................................................................................... 29

Figures

Figure I. RPFDestroyed in a Variety of Experiments ............................................................ 8Figure 2. Data from Explosive Tests on Foams (replotted from Cooper& Kurowski,

0ctober6, 1975) ................................................................................................................9Figure 3. Data from fully Embedded Explosive Tests on Foams (replotted from Cooper

& Kurowski, October 6, 1975) ........................................................................................ IQFigure 4. Diagram of Flyer Plate Apparatus (See Reference 2 for More Details) ................ 11Figure 5. Cavity Diameters Produced in RPF by Tetryl and TNT Unit Charges (from

Cooper & Kurowski Fomula) ........................................................................................ 12Figure 6. Mass of RPF Destroyed by Tetryl & TNT Unit Charges (from Cooper &

Kurowskifomula) ........................................................................................................... 13Figure 7. Flyer Plate Velocity Attenuation by 5.7pcf (RPF .................................................. 14Figure 8. Incremental Energy Density Absorbed in 5. 7pcf RPF layers ................................ 15Figure 9. Cumulative Energy Density in 5. 7pcf RPF from PETN Plate Charge..,. ..............16Figure 10. Total Energy Absorbed by 5.7pcfRPF ................................................................ 17Figure 11. Total Specific Energy Absorbed by 5.7pcf RPF .................................................. 18Figure 12. Total Absorbed Specific Energy Density of 5.7pcf RPF, ..................................... 19Figure 13. Absorbed Energy Density in 5. 7pcf RPF from PETN Plate Charges .................20Figure 14. Specific Energy Density Absorbed from PETN Plate Chargesin5.7pcfRPF....21Figure 15. Energy Flux Absorbed by 5. 7pcf RPF from PETN Plate Charges ..................... 22Figure 16. Specific Energy Flux Absorbed in 5. 7pcf RPF by PETN Plate Charges ............23Figure 17. Energy Density Flux Absorbed in 5. 7pcf RPF from PETN Plate Charge ..........24Figure 18. Specific Energy DensiV Flux Absorbed in 5.7 pcf RPF from PETN Plate

Charges ........................................................................................................................... 25

Figure 19. Slopes of Linear Trend Linesfrom Figure 18 (a) ................................................26Figure 20. Extrapolator for Energy Absorption Process .......................................................27Figure 21. Ground Cavity Data and Predictions ...................................................................29

Table.Table 1. CoejLicients of Trend Lines in Figure 18(a) .............................................................26Table 2. Data on Ground Crater Diameter Reduction by Intervening RPF Layers ............... 28

5

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Background

During the last few years we have conducted a series of investigations onthe military applications of rigid polyurethane foam (RI?F) materials.’ As a partof those investigations we considered the impact of explosive blast waves,fragments and projectiles on the RPF materials of different density. RPF materialproperties are dependent principally on the material density. Therefore, varyingthis parameter is most important in studying material responses. In theaforementioned study we determined that the RPF resistance to fragment andprojectile penetration was very slight, but that the effect on an incipient blastwave was significant. This was not the first study of these effects. Cooper andKurowski explored the blast absorbing capabilities of RPF of various densitiesduring the middle 1970s. They considered the cavities produced by chargesdetonated in the interior of blocks of RPF. By varying the RPF densities andcharge weights of explosive (Tetryl) they developed an empirical scaling law.

We extended that work in 1995 and 1996,1 repeating some imbeddedexplosions and adding free surface ones as well. The interesting reported resultwas that the cavity diameter produced by detonation of a given weight ofexplosive was the same whether the explosive was embedded in the center of theblock or lying on the top horizontal (free) surface. Our Phase II report 2furthergeneralized the conditions to include detonations at the undersurface of a block.We supported the blocks on earth and floated them on water. It also includes oneunderwater experiment in which the explosive was not in contact with the block.This was done to investigate the possibility of using this material as a protectionfor ship hulls subjected to nearby explosions, such as from influence mines. Wehave done no work, to date, on non-contact explosions in air. We believe that thisreport provides the first published quantitative data on RPF blast energyabsorption, based on a series of flyer plate experiments reported therein.

General Plastics Corporation (GP) recently conducted severaldemonstrations of a commercial product that was empirically designed toattenuate air blast. One of these demonstrations was conducted during the firstweek in May 1999 at Quantico, Virginia. That demonstration was not planned fordata acquisition. However, some information has been extracted from it.

Reduction of the data from these experiments has shown that RPFs have aremarkable and surprising capability to absorb and perhaps to dissipate theenergy of a blast wave. Some fundamental questions arise when carefullyexamining the available data, and when observing explosive events, such asthose at Quantico. The actual energy absorbing mechanisms seem quite complex.The possibilities seem to include compression of the gas in the cells, multiple“micro reflections” from the many cells encountered by the blast wave, chemicalreactions induced in the gas and in the polyurethane, radiant heat transfer, strainenergy in the polyurethane, secondary burning of the affected material, andacceleration of the affected materials. The research required to assess the relative

6

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effectiveness of these, and possibly other mechanisms as well, has not been done.Therefore, at this time the best use of the existing data seems to be in establishingempirical rules for protection of structures.

There seems to be, in spite of the lack of fundamental understanding ofmechanisms, a potential to use this material as a protective measure in a numberof situations. The possibility of ship hull protection has been mentioned. Anotherpossibility is the protection of concrete structures from a terrorist attack, such asa satchel charge placed in contact, or a larger charge placed some distance away.

An explosive device placed in contact with the structure, and one placedat a distance from it will produce somewhat different effects. We have datasufficient to provide a reasonable estimate of the contact event, though it wouldbe wise to verify the extrapolations described herein with a small number ofconfirmatory experiments.

Introduction

The purpose of this report is to document the recent work done toquantify the blast energy absorbing capability of the RI?F material as well aspossible from the existing data, and to suggest appropriate avenues for researchto gain better definition of the mechanisms involved. In addition, some potentialapplications will be suggested. All of the data presented herein are digested fromthe earlier mentioned reports. This report only considers analysis of those data.Details of the experiments and techniques that produced the data are in thosereports.

The basic problem may be posed in two parts: Can RI?F material beapplied in a useful protective role to prevent damage to structures fromexplosive devices? If so, how can it be effectively used and what are itslimitations? The calculations presented in this report maybe most readilyapplied to the case of contact devices, such as satchel charges, placed against thestructure in question. Suggestions for follow-on work to apply to non-contactingcharges are presented in brief.

Available Data

The first step is to use all available data to generate some empirical rulesrelating the blast energy absorbed to the density and thickness of the RPF andthe weight of the charge. Those rules will then permit estimation of the effect ofthe blast wave on the structure behind the RPF layer.

There are four groups of reported applicable data. All are in theaforementioned documents. Three data sets relate the size of the cavity producedin the RPF to the RI?F density and charge mass. The first of these reports work byCooper & Kurowski; the other two, work by Woodfin. These data are presentedin aggregate in Figure 1. In this figure the data have been presented in a form

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normalized by mass. The five data points with filled symbols, forming a separategroup below the rest, are from the third set of data. They were produced by aplate charge in a dimensionally constrained configuration. Clearly, the RPFabsorbs energy more efficiently in this geometry, which corresponds closely to asatchel charge placed against a surface. All the other data were produced byessentially spherical charges.

There is one set of “soft” data that were obtained through a serendipitousopportunity. These were obtained during the previously mentioned ForceProtection Equipment Demonstration event at Quantico, Virginia, May 3-7,1999.

100000

10000

1000

RPFDestroyed

(gin)

100

10

1

I I I 111

1 1 i 1 1 1

r +W

0.1 1 10 100 1000 10000

TNT Equivalent Charge (gin)

Figure 1. RPF Destroyed in a Variety of Experiments

At this event a large number of vendors of protective products, in addition toGP, exhibited them using explosive charges of different sizes and orientations. Inthe process a number of ground craters were produced by the different companydemonstrations. Those produced in the course of the GP demonstration had RPFintervening between the explosive and the ground; the others did not.Measurement of the crater diameters yielded this set of data. These cannot beregarded as hard data, but interpreting the results in the context of the other datahas provided some additional insight. These insights are discussed in a latersection of this report.

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Cooper and Kurowski used Tetryl to produce the data shown inFigure 2. All these data were produced with totally embedded, nominallyspherical charges. They used these data to develop an empirical scaling rule forboth charge weight and density:

~_ *6.3+0 .5p

(1.)

whereD is the cavity diameter in meters,w is the charge mass in grams, and

P is the RI?F density in pounds per cubic foot (pcf).

1

Blast CavityDiameter

(m)

o.1

0.1 1 10 100 1000

Charge Mass (gins) rlw11RW9

Figure 2. Data from Explosive Tests on Foams (replotted from Cooper& Kurowski, October 6, 1975)

The work that resulted in the second data set established that the cavitysize produced was essentially independent of the location of the explosive. Thatis, a charge of a given mass produced a cavity of the same diameter whether itwas imbedded in, on the upper surface of, or under a block of RPF of a particulardensity. The embedded charges produced nearly spherical cavities, while thesurface charges produced hemispherical cavities of corresponding diameter.

Figure 3 illustrates this effect. In this Figure the filled symbols indicateembedded charges; the larger ones represent the data added and the small ones,the original Cooper & Kurowski data set. The “cube root scaling” lines followthose shown in Figure 2, and are calculated using the empirical scaling rule ofequation 1, above. In Figures 3 all surface charges were on the upper surface.

This third set, henceforth called the “plane wave cavity data set”, differsfrom a fourth set, called the “flyer plate data set”, although both were formed by

9

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firing a charge configured to produce a plane wave of specific diameter normalto the direction of propagation. The cavities formed in the two differed in thatthe former shots were fired into a thickness of RPF sufficient to contain thecavity, while the latter were fired into RF’F layers of specified thickness, backedby a steel plate. These layers were not sufficient to contain the cavity, since theobjective was to accelerate the flyer plate.

This flyer plate data set proved to be the most useful for the purposes ofthis study. It was developed by firing plane wave charges’ through a sheet ofR.PF to accelerate a steel flyer plate. The apparatus is shown diagrammatically

100

10

Blast CavityDiameter

(cm)

10.1 1 10 100 1000

Charge Mass (gins) W1212m9

Figure 3. Data fiomfilly Embedded Explosive Tests on Foams(replottedfrom Cooper& Kurowski, October 6, 1975)

{Embedded & Suglace Charge Data Added by Woodfin @EMRTC Nov & Dee, 1996}

in Figure 4. The velocity of the flyer plate was used to calculate the energyabsorbed by the Rl?F sheet. This energy absorbed became the basis for thefollowing calculations. Flyer plate velocity data was gathered only for 5.7 poundsper cubic foot (pcf) RPF; plane wave cavity data was collected for 3.3 pcf and 5.7pcf RI?F.

The first data’ was collected using Tetryl; the rest,’~ using C-4 and PETN.Consequently, the data is normalized to TNT equivalence in the followingsections. This is appropriate since TNT is the standard for comparison and is alsoone of the most common explosives found in terrorist devices, because it isreadily available and cheap. Figure 5 graphs Equation 1 for both Tetryl and TNT,illustrating the minor difference in performance between the two explosives.

10

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Analvsis of CavitV Formation Data

The effect of density is seen to be modest, especially for densities of lessthan 10 pcf. The similarity in the results for the plane wave and spherical chargecavity experiments seen in an examination of Figure 1 suggests that assuming asimilar relationship to hold for the former should be justified.

RF-W rMonatof

—Oethokk

FaunSpcer+17/&odbyll#4”~h

~opf+$f——~

(Detasheet)

— Foamaltwatw,Wkne!uvafie$

b’

b

. .. .b

Figure 4. Diagram of Flyer Plate Apparatus(See Reference 2 for More Details)

11

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16

i-1“\‘\

— DiaMtlass Tetryl (cm/gm)--- Dia/Mass TNT (cm/gm)

14

12

Diameter / Ma;g(cmlgm)

8

6

4

2

I N\ I I I I I i

o 10 20 30 40 50 60 70

RPF Density (pcf)

Figure 5. Cavity Diameters Produced in RPF by Tet~l and TNT Unit Charges(from Cooper & Kurowski Formula)

In fact, by recasting the relationship in terms of volume, V, of RPFdestroyed in a spherical, imbedded shot such as Cooper and Kurowski used, therelation takes the form:

v=47Tw

3(12.6+p)3(2)

wherev is the volume of the hypothetical spherical cavity in the IU?F, in m3,

w is the mass of explosive in grams, andis the RF’F density in pcf.

(The h~brid system of units adopted by Cooper and Kurowski is continued here.This conforms to the normal industry practice of describing RPFs in terms oftheir density in pcf. It is thus implied that the empirical value 6.3 in equation 1 isa density quantity, to be expressed in pcf.)

In equation 2 the volume depends linearly on the charge. Therefore, usingthe assumption that the cavity produced is spherical, it is possible to calculate themass of RI?F destroyed in the cavity volume by a unit mass of explosive. Themass of the RPF is merely the product of the density and volume, so that the“mass destruction ratio” becomes:

WRPF 12.87pV 53.89P—=W.!ip[ Wkp[ = (12.6+Pj

(3)

12

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whereWWF is the mass of the RPF destroyed, in grams

12.87 is the factor required to reconcile the units, in gm-ft3/lb-m3, andw ~xp, is the mass of the explosive used, in grams.

It is easily shown that this equation has a maximum value at an RPFdensity of 6.3 pcf. Even though the experiments from which this function wasestablished used only Tetryl as the explosive, there, this maximum is assumed tobe effectively independent of the explosive used. Figure 6 illustrates the functionfor Tetryl and scaled for TNT. The existence of a maximum is to be expected,even though we do not understand all the energy absorbing mechanisms. Since itis observed that polyurethane in a rigid foam form absorbs energy moreeffectively than in the form of solid polyurethane, it is to be expected that somedensity is the most effective. It has not been proven that the maximum in thedestruction ratio establishes that value. Some other mechanism may dominate,but it presents a starting place for isolating the density for peak efficiency.

If we make the plausible assumption that the shape of the cavity is ofsecondary effect, then this relation should apply to the roughly cylindricalcavities produced in the plane wave cavity shots. These cavities approach oblatespheroids in shape. Figure 1 does give reason to question this assumption, butfor purposes of estimating the thickness of RJ?F needed for absorption of a givencharge energy the error in this assumption tends toward conservative results.

70

60

50

40

Mass Ratio30

20

10

0o 10 20 30 40 50 60 70

RPF Density (pcf)

Figure 6. Mass of RPF Destroyed by Tetryl & TNT Unit Charges(’jrom Cooper& Kurowskiformula)

13

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Analvsis of Flyer Plate Data

The flyer plate experiments used three different size charges of PETN,each arranged so as to develop a plane wave for propelling the plate with itsvelocity vector normal to its surface. Sheets of RI?F of varying thickness wereplaced between the charges and the steel flyer plates so as to absorb energy fromthe explosive prior to accelerating the plate. The plate velocities were thenmeasured. Figure 7 presents this data. The physical form of the experiments hasbeen described in detail.’

Obviously, the explosive energy is absorbed effectively by these RJ?Fsheets. The geometry of this experiment causes the blast energy to be absorbedprincipally in the cylinder of RF’F between the explosive and the flyer plate. Itappears that the presence of the flyer plate maybe the major contributor to thegreater energy absorption effectiveness observed in Figure 1. The effect of theplate (or a supporting structure behind the RI?F) seems to be in delaying themotion of the RI?F by its greater density. This, perhaps, allows some of the otherhypothesized mechanisms to develop more fully.Therefore, using the diameter of the flyer plate and the thickness of the RF’F sheetbeing used as the attenuator, it becomes possible to directly determine thevolume and mass of RI?F destroyed in attenuating the blast wave. From this and

0.6

0.5

0.4[~ --0- .45.2 gm PETN

-\ - n- -95.5 gm PETN

Measured 3 “ \ +160 gm PETN

Plate Velocity \L

(kmlsec) \()

0.2 .’*.● \

● . \●

0.1x .

● .●

\● \

t ) ------ .0 v -w 43

0 2 4 6 8 10 12

RPF Thickness (in)

Figure 7. Flyer Plate Velocity Attenuation by 5. 7pcf (RPF

14

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the reduction in kinetic energy it is possible to calculate the absorption energyw, i.e., the energy absorbed per unit volume of RPF, of the process througheach incremental layer of the attenuator. The equation is

whereEKEavRPF

m

Ui

Uf

~=~= d“:-4)2VRPF

(4)

RPF

is the absorbed energy density, the bar denoting the energy density,is the attenuated kinetic energy of the flyer plate,is the volume of RPF absorbing energy,is the mass of the plate,is the initial velocity of the plate, andis the final velocity of the plate.

Figure 8 displays the absorption energy density as measured in the flyerplate experiments. This quantity is directly related to the “Mass of RI?FDestroyed” in Figure 1. This figure illustrates the development of the energyabsorption as the-blast wave propagates through the RI?F.

120 -

100 1\

80Energy “-0-45.4 gm PETN

Density - m -95.5 gm PETN

(J/cc) 60+160 gm PETN

(M;;m’)40

20

0 2 4 6 8 10 12 14

RPF Thickness (in)

Figure 8. Incremental Energy Density Absorbed in 5.7 pcf RPF layers

The cumulative effect is obtained by the summing the energy densityabsorbed over the total thickness of RI?F used. The mathematical process is

15

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E=$~n=l

where

(5)

n denotes the n’h layer of the FWF attenuator andN is the total number of layers.

Figure 9 illustrates the cumulative effect of several inches of RI?F. The two figures(8 and 9) show that the layers that encounter the blast wave first do the greatestrate of attenuation. The energy remaining for the deeper layers to attenuate issubstantially less, on a volumetric basis. This tempts one to speculate that themechanisms of attenuation accomplish much of their work by internal reflectionsand refractions at cell boundaries to weaken the wave structure. Research isneeded to determine these mechanisms.

EnergyDensity

(Jlcc)or

(MJ/m3)

160

140

120

100

80

60

40

20

00 2 4 6 8 10 12 14

RPF Thickness (in)

Figure 9. Cumulative Energy Density in 5.7 pcf RPFfrom PETN Plate Charge

Two other related quantities are useful to calculate, the total energy

absorbed, E, and the total specific energy absorbed, ~. The first is found by anyof several calculations:

where

(6)

E. is the energy absorbe~ in the nthlayer, (with small error the totalenergy absorbed can be considered to be only the kinetic energy attenuated)

16

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is the kinetic energy attenuated in the nth layerm is the mass of the flyer plate,v. is the volume of RPF destroyed in the nti layer of the attenuator,Ui” is the constructive initial velocity of the plate for layer n,

considering it to have been produced by a charge attenuated by layers 1, . . . .. n-1,

‘f n is the constructive final velocity of the plate for layer n,considering it to have been produced by a charge attenuated by layers 1,.....n .

In each caseu. = Uf (6a)

‘n+] n

This variation in total energy is illustrated in Figure 10, with the RI?F thickness incentimeters to facilitate further analysis.

EnergyAbsorbed

(KJ)

70

60

50

40

30

20

10

0

//.

+3 ------- 0. . . ...! . . . ..-. . . . . .. 0;

0 5 10 15 20 25 30

RPF Thickness (cm)

Figure 10. Total Energy Absorbed by 5.7 pcf RPF

The other useful quantity is the normalization of the energy absorbed onthe basis of the explosive mass, that is, the specific absorption energy is thatwhich is absorbed by a unit mass of explosive, in this case PETN. Thisnormalization will lead to a form of the process description that will permitextrapolation to larger explosive charges. It is characterized by

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Page 18: Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such

(7)n=l n=] ‘Vfipl ~~.E@n =1

whereA (caret) superposed signifies the specific energy. Figure 11 then presentsthe total specific energy absorbed.

500

400

300

SpecificEnergy(J/gin)

200

100

47 --- - “--G- --El

- -~ .45.4 gm PETN-~ -95.5 gm PETNL+ 160 gm PETN

I

o0 5 10 15 20 25 30

RPF Thickness (cm)

Figure 11. Total Speci$ic Energy Absorbed by 5.7 pcf RPF

The two normalizations may be combined to form the absorbed specificenerm densiw by dividing the specific energy absorbed by the volume of RJ?Fdestroyed in each layer:

,.

~=$+=+~~n=+En (8)“=] ~ =*1 n=l fip[ .=1

as shown in Figure 12.No matter which data presentation is used, it becomes readily apparent

that the majority of the available energy is absorbed in the first four inches (tencentimeters) of the RPF, with almost all being absorbed by the first nine inches.In fact, very little is energy remains after six inches are destroyed. This isconsistent with the underwater standoff shots as well, where 1.5 inches of 3.3 pcfRI?F were sufficient to prevent major structural damage in the experimental

18

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panels. An earlier attempt at suppressing underwater shock damage using rigidepoxy foams was unsuccessful.

SpecificEnergyDensity

(J/cc-gin)

1

0.8

0.6

0.4

0.2

0

--- --

T 5 10 15 20 25 30

RPF Thickness (cm)

Figure 12. Total Absorbed Specijic EnergyDensity of 5. 7pcf RPF

Adjustment for Densitv and Exdosive Used:

This absorbed specific energy density forms a most useful measure of theenergy absorbing capability of the RI?F of the density under consideration. It isnecessary to adjust it to the density of interest. While the Cooper-Kurowskiequation suggests a way to do this, it requires a rather weakly substantiatedassumption, to wit, that that the volume of RYP destroyed in the cylindricalgeometry of the flyer plate experiments is represented by the volume term in thespherical geometry of the cavity experiments. The quality of this assumption hasnot been established. One procedure for adjusting for the RPF density would beto consider the ratio of volumes consumed by equal explosive charges in RPFs ofdifferent density. Using equation 2 that ratio takes the form

~ _ (12.6 +pO~

~ - (12.6+P1~(9)

19

Page 20: Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such

where the subscripts simply indicate two different RPF densities. For a givenvalue of the baseline density this ratio varies monotonically. This result defiesintuition, since neither air nor solid polyurethane is expected to be as effective assome intermediate density, based on the cavity experiments. An optimum is tobe expected. If Figure 6 is an accurate guide, then the optimum density for mostapplications will be near 6.3 pcf. By using a mass ratio instead of a volume ratio,a maximum is achieved at that point, following the relation:

y P,(12.6+L%Y(9a)

WO– pO(12.6+P, f

which does exhibit a maximum at p] = 6.3pcf, for any value of p.. That maybemisleading, however. Additional experiments are necessary to understand thisprocess more thoroughly.

The specific energy density form also permits adjustment to the explosiveof interest. It is most useful to use TNT as a baseline. PETN has 1.45 the energy ofTNT; Tetryl, 1,.31 times. The advantage of normalizing by the charge will be seenlater. Figure 13 illustrates the energy density: Figure 14 employs the specificenergy density. In these figures the independent variable has been changed to bethe TNT equivalent charge. Clearly a linear model is a better approximation ofthe process when using the specific energy density.

120

100

80

EnergyDensity

(J/cc) ~.

(M;;m’)40

20

0

+ -5.1 cm RPF. -G -10.2cm RPF

P

-+-15.2 cmRPF- -A- -22.9 cm RPF-w-- 30.5 cm RPF / ‘

/

1/ ,JJ0

/ “/ ‘ 0

A ,0” ,..”””O/ 0 --.-*

/d

/

// m 0..0

.dti ~.”’ “ -.——w // **----

Er .-*” . .A. ‘- .:.:.--”---

8_...--=- ‘---- ---

““-----,#-----

::>..

-----~ .A.-

-------- ..4---- _---F..

I I I

50 100 150 200 250

TNT Equivalent Charge (gin)

Figure 13. Absorbed Energy Density in 5.7 pcf RPF from PETiV Plate Charges

20

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0.5

0.4

SEP;:::; ().3

Density(J/gin-cc)

0.2

0.1

0

-A?-/

F-

// /“”/#

~ /“----u-

.- .-. +~- -~ -_-*------

--0-”..--*-”

0 -------- -A---- ......”

-------A.---- “- -------v

A .---- ._....#------v-----------,-.--—-----+--

1 I I

50 100 150 200 250

TNT Equivalent Charge (gin)

Figure 14. Specific Energy Density Absorbed from PETN Plate Charges in 5.7 pcf RPF

Extrapolation to Larqer Explosive Charqes

Using the absorbed specific energy density it is possible to then calculatean even more useful quantity that relates the energy absorbed to the area of thesurface impinged by the wave. This is particularly true since the proposedapplication to anti-terrorist protection systems will always be directed toward asurface or off-surface charge, likely never an embedded one. Because of itsrelationship to the area, this quantity is appropriately considered as a ~. Forthe flyer plate experiment this area is well defined by the area of the plane wave,which is the same as that of the flyer plate, 86 cm’. The flux is obtained bydividing the absorbed energy by the effective area, or equivalently for the flyerplate experiments, by multiplying the absorption density by the thickness of theabsorbing RPF. The flux is denoted by the “dish”, or “smile” symbol. Theincremental absorbed energy flux is:

KEUin= “ = Fntn

A.(1.0)

where

An is the effective area of the nt~RI?F layer andt. its thickness,

so that

21

Page 22: Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such

The total absorbed energy flux is computed by

(12)n=] n=l

and shown is in Figure 15. The specific energv flux absorbed is the more usefulquantity for extrapolation and application, since it is much better represented bya linear extrapolator, especially as the RPF thickness becomes adequate to absorbmost of the energy:

EnEn=—wExpl

Therefore, using equations 7 and 11, the total absorbed specific energy flux is

i=~E==-+Entnn=l E@ n=]

(13)

(14)

This total absorbed specific energy flux is shown in Figure 16.

2500

2000

1500Enee;y

(KJ-cm)1000

500

0

--o-- 5.1cm RPF-D -10.2cm RPF~15.2 cm RPF

S7●**

-- A- -22.9 cm RPF●*

●**----v-w 30.5 cm RPF ,**

●**●*’‘

.**- ●

●,** ●

●,4* ●*,4●.** ●

,* ,*,0 ●

●**’‘ ●

Jr” ●.=,./”” ● ‘*

//’” . .A’../”” ●.=* ..”=

~/” .-” - - ~d~.

-*- deA- *“.- . ------- 0. . . . .

0 .m----- -. . . ..-. ---. ------50 100 150 200 250

TNT Equivalent Charge (gin)

Figure 15. Energy Flux Absorbed by 5.7 pcf RPF from PETN Plate Charges

22

Page 23: Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such

\ ..~=5.I cm RPF I I 4

8

SpecificE;f~fy 6

(MJ-cm/gm TNT)

4

2

-u- -10.2cm RPF ..7

_ ~ 15.2 cm RPF.**H**

P-- A- -22.9 cm RPF

.e,##

=-==v==-30.5 cm RPF●*#

.@+-”4 @

-*.* v“ A# ---,@ .-. .● F -.

#/-””@...-

-. A“ “ -...-

.“--A- F

.+ -cl4 ,

*-H H

u“-- ‘-4 ❑ “ ‘

-= *...... ----- “00.-- . . . ,. ...-= Q- “

00 50 100 150 200

TNT Equivalent Charge (gin)

Figure 16. Specific Energy Flux Absorbed in 5.7 pcf RPF by PETN Plate Charges

As in the case of the density, above, the advantage of using the specificform is apparent, as it provides a more nearly linear data description. Combiningthe density and flux normalizations produces an interesting result. In Figure 17the RPF thickness is observed to become a less dominant parameter in thisdescription of the process. As noted earlier, the first few inches of the 12F’Fencountered by the blast wave absorbs the energy most rapidly. After the wavetraverses about six inches (ten centimeters) of RF’F the energy absorption ratebecomes more nearly constant. For predictive purposes, especially when morethan six inches of RPF are used, the effect of thickness maybe regarded as asecondary parameter.

250

23

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800

700

1---0-- 5.1 cm RPF-0--l O.lcm RPF

600 *15.2 cm RPF- =A- =22.9 cm RPF

EnergyDensity

‘oorFlux 400

(J/cm2) ~oo

200

100

o 50 100 150 200 250

TNT Equivalent Charge gm)

Figure 17. Energy Density Flux Absorbed in 5.7 pcf RPF from PETN Plate Charge

This effect is maintained when all the normalizations, including thespecific form, are used simultaneously, as in Figure 18. This combinationprovides the most effective predictor form.

In of Figure 18a trend line has been calculated for each set of data plotted.These are shown in Figure 18(a), where the line connecting the data points inFigure 18 has been replaced by the trend line for each set of data points. Theerror bars shown indicate a five percent data scatter, or uncertainty. Examinationof Figure 18(a) shows that the quality of the predictive ability of the trend linesimproves rapidly as the RI?F thickness approaches the 30 cm value. In fact thesmall differences in the trend line equations for the 15.2, 22.9 and 30.5 cmthicknesses are within the scatter of the data. Therefore, it is proposed that asimplified extrapolator may be realistic.

24

Page 25: Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such

3.5

3

2.5

SpecificEnergy 2Densitv

Flux-

(J/cm2- gm) ‘“5

1

0.5

0

0

Z40

/ ‘ ,.0-.*

-.*CT” -.~

.“.-. .cY-

-. ---o“--

--0-- 5.1 cm RPF-D--1O.1 cmRPF+ 15.2 cm RPF-- A- -22.9 cm RPF--v- 30.5 cm RPF

o 50 100 150 200 250

TNT Equivalent Charge (gin)

Figure 18. Specific Energy Density?lux Abso;bed in 5.7 pcf RPF from PETN Plate Charges

3.5

3

2.5

SpecificEnergy 2Density

Flux , ~

(J/cm2- gm)

1

0.5

0

#

. .?.

/ ..””-.---

..- 3---

.-0-- 5.1 cmRPF-D -10.1 cm RPF~ 15.2 cm RPF-- A.. 22.9 cm RPF--v- 30.5 cm RPF

o 50 100 150 200 250

TNT Equivalent Charge gm)

Figure 18(a)

Trend Lines of Specific Energy Density FluxAbsorbed in 5.7 pcf RPF form J?ETN Plate Charges

Figure 18(a) Trend Lines of Speci$c Energy Density Flux Absorbed in 5.7 pcf ~Ffrom PETN Plate Charges

25

Page 26: Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such

The trend lines of Figure 18(a) are seen to converge for the greater thicknesses ofthe RPF. The trend lines all take the form

;=A+QW~W (15)

where

Q is the slope of the trend line in J/ (cm-grn)zA is the ordinate axis intercept (with little apparent significance), and

w is the TNT equivalent charge in grams.As the tre~d lines converge their slopes seem to approach a limit. This limit, from

observation of the effect in Figure 19, is about 0.0083 J/ (cm-grn)2. Table 1 lists thecoefficients of the trend lines in terms of Equation 15. The slopes from Table 1 areshown in Figure 19.

0.0085

+(0.008

0.0075 /

Slope 0“007

J/(cm- gm)2

0.0065

0.006

0.00555 10 15 20 25 30 35

RPF Thickness (cm)

Figure 19. Slopes of Linear Trend Lines from Figure 18 (a)

Table 1. Coeflcients of Trend Lines in Figure 18(a)

RPF Thickness Axis Intercept (A) Slope (Q) Goodness of(cm) U/(cm2-gm)] (J/(cm-gm)2] Fit Ratio

5.1 1.0029 0.0056710 0.9849610.2 1.3855 0.0070758 0.9842615.2 1.4518 0.0076060 0.9990822.9 1.4437 0.0079597 0.9995830.5 1.4188 0.0081314 0.99990

26

Page 27: Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such

With the foregoing established, it is possible to form an extrapolator forthis data. Figure 20 is formed by plotting the data shown on Figures 18 and 18(a),with the addition of a simple extrapolator of the form

;=l.4+8.3W~m (16)where

w’Tm is the TNT equivalent charge expressed in Mogranzs, as

signified by the prime. The parameters are estimated from the trends observed inFigure 19 and Table 1.

50

40

Specific ~0EnergyDensity

Flux

(J/cm2- gm) 20

10

0

a.

o 5.1 cm RPF ●

❑ 10.1 cm RPF.

A 15.2 cm RPF ●

●●

A 22.9 cm RPF ●

v 30.5 cm RPF ●●

----- Extrapolator ,*=●

●●.

●.,●

● Extrapolator:●..

●●

●* E= 1.4 + 8.3WTNT●.,.

.●.

o 1 2 3 4 5

TNT Equivalent Charge (kg)

Figure 20. Extrapolator for Energy Absorption Process

Experience with these materials and explosives indicates that the processshould be well described by this extrapolation. However, such extrapolationsoften hold surprises. Therefore it is obvious that confirming experiments areneeded. Some have been proposed, but are not funded as of this writing.

27

Page 28: Using Rigid Polyurethane Foams (RPF) for Explosive Blast Energy Absorption in Applications Such

Investigation of Reduction in Ground CraterSize bv RPF Laver

Some corroborating information about the ability of the RPF material to be usefulin this manner may be gained from the impromptu experiment conducted at Quantico.Since there were many demonstrations being conducted, it was necessary to use any thatwould apply. Several of the demonstrations were conducted by firing TNT charges on theground near a protective system being demonstrated by some hopeful vendor. The USMCEOD personnel conducting the firings had prepared and distributed a program for thedemonstrations. This program listed the explosive and quantity for each demonstration.Following all the demonstrations the ground craters produced were measured, andcompared with the published size of the corresponding charge in the program. The GPdemonstrators assisted by supporting their demonstration charges on sheets of RPF. (Thissupport had no effect on their demonstration, but formed a convenient way of raising thecharge to the level they needed.) The craters produced by these charges were measured inthe same manner as the non-RPF supported charges. These “data” are tabulated in Table2 and shown on Figure 21. It is an interesting observation that the linear trend linedescribes the cavity data better than the cube root scaling line.

Figure 21 also includes some calculations of craters sizes made with the“CONWEPS” code. Calculations were adjusted to represent the Quantico soil byapplying an 82% reduction in the prediction for dry sand. That caused the computation tomatch the mean of the data for one charge size. The predictive quality of the CONWEPScode is not known precisely, but the relative effect of the surface burst and the air burstone foot above ground are likely dependable. Comparison of the two RPF data pointswith the air-burst calculation indicates that the RPF is substantially more effective thanan air separation in reducing cavity size. While this information does not flt directly intothe foregoing analysis, it is compatible with the results.

Table 2. Data on Ground Crater Diameter Reduction by Intervening RPF layers

Charge RPF Layer RPF Layer Ground CraterWeight Density Thickness Diameter(lb TNT) (pcf) (in) (in)

25 0 0 4825 0 0 3650 0 0 78

50 0 0 76

50 0 0 8850 0 0 72

40 4 12 32

1 40 7 12 21

28

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250

200

150Cavity

Diameter(cm) ,00

50

0

0 Cavity Diameter cm)Lv 30.5 cm 4 pcf RP Intervening

A 30.5 cm 7 pcf RPF Intervening. . . . . Cube Root Scaling Prediction--- Linear Trend Line

❑ CONWEPS Cavity Diameter cm - Surface Burst[]❑ CONWEPS Cavity Diameter cm 30.5 cm HOB

•1

m . . - u.--”..- , ~%...

--- /..- /

...”

//

..”. 0//’... /

. /0.. / v.. 0. / A

. //

//

z 5 20 25

Charg;”Weight &g TNT)

Figure 21. Ground Cavity Data and Predictions

Conclusion

It does appear that RPF can forma valuable tool in protecting structuresagainst blast, such as from terrorist attack. The confirming experiments arenecessary to make intelligent design decisions, but, as an interim, a 9 inch thicklayer of 6 to 8 pcf RPF can be considered sufficient to greatly reduce damage,especially interior span from concrete walls in a variety of attack scenarios. Asshown earlier, a 6 inch layer is almost as good.

This analysis has considered only blast wave damage. RI?F should not beused for protection against explosively driven fragrnentsz. Also, this analysis didnot consider the effect of the pressure pulse on the overall structure. That is aseparate issue. RPF may help some in mitigating that effect, but that is probablynot its best use.

29

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References

1. Woodfin, R. L, Rigid Polyurethane Foam (RPF) Technology for Countermines (Sea) Program, Phase I,Sandia Report, SAND 96-2841, January, 1997

2. Woodfin, R. L., D. L. Faucett, B. G. Hance, A. E. Latham, & C. O. Schmidt, Rigid Polyurethane Foam(RPF) Technology for Countermines (Sea) Program, Phase II, Sandia Report, SAND 98-2278, October1998.

3. Cooper, P. W., & S. R. Kurowski, Scaling Blast Cavity Diameters in Rigid Foam, Sandia Laboratoriesmemo of October 6, 1975

4. Giacofci, T. A, & Costanzo, A. A., An Investigation of Underwater Explosion shock Mitigation

Effectiveness of Rigid Syntactic Foam Materials, LATA Report CTOOI06(01), Los Alamos TechnicalAssociates, Inc., Fairfax, VA, for the Defense Advanced Research Projects Agency, AdvancedSubmarine Technology Program., April 1990.

5. Johnson, D. R. & Fischer, S. H., TNT Equivalence of Energetic Materials, Sandia NationalLaboratories Explosive Components Facility OP-905-0009, Issue B, Appendix A, p 7

6. Hyde, D. W., CONWEPS Computer code, implementing the equations in US Army TM 5-855-1,USAEVES/SS, 1 May, 1989, Reference:WES Instructional Report SL-88-

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Distribution

1

2

4

2

1

4

U.S. Department of EnergyAlbuquerque Operations OfficePost Office Box 5400Albuquerque, NM 87185-5400Attn: Daniel G. Krivitzky

CommanderNaval Surface Warfare CenterIndian Head Division101 Strauss AvenueIndian Head, MD 20640-5035Attn.: C. F. Falkler/630

J. L. Barron

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D. Crute/R32J. RumboughJ. Mott

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Lt. Col. W. Harem

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Office of Naval ResearchOcean Atmosphere and Space ScienceTechnology Department (SMT)1322800 N. Quincy StreetArlington, VA 22217-5660Attn.: R. Jacobson

D. TodoroffK. Ward1335T. Swean

1

1

3

1

2

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2

CommanderMine Warfare Command325 Fifth Street SECorpus Christi, TX 78419-5032Attn.: Code N 02

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CPT A. Alba, Department of Physics

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Commandant, US AmlyTransportation School 1

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10 MS 1452 R. L. Woodfin, 2552MS 1454 M. G. Vigil, 2554MS 1454 D. E. Paul, 2554MS 1454 R. A. Benham, 2553MS 1156 P. W. Cooper, 15322MS 9018 Central Technical Files 8940-2

2 MS 0899 Technical Library, 9616MS 0612 Review& Approval Desk,

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