UW Superior Flammable Liquid Storage Program ndash Barstow Hall Section __ Appendix __ of the UW Superior Chemical Hygiene Plan Prepared by Carol Lindberg CIH Environmental Health and Safety (EH amp S) Department
December 2012 Section 1 Introduction
The NFPA 45 Standard on Fire Protection for Laboratories Using Chemicals and NFPA 30 Flammable
and Combustible Liquids Code are two fire safety regulations adopted as part of building codes and
occupational safety regulations that are implemented in the State of Wisconsin Both NFPA codes have a
direct impact on flammable liquid use and storage in UW Superior laboratories and storage areas
Flammable and combustible liquids are classified using boiling point and flash point data for the
substances Since any amount of flammable and combustible liquids including empty containers are a
significant fire risk for personal injury and property damage strict storage requirements are both essential
and required by law
Section 2 Definitions
NFPA National Fire Protection Association The NFPA produces recommended standards for fire
safety State and Federal agencies adopt the NFPA standards as law through the standard setting process
Flammable liquid A liquid with a flash point below 100deg F (378deg C) [closed cup] and a maximum vapor
pressure of 2068 mm Hg at 100deg F (37deg8 C) Flammable liquids are further categorized as Class IA IB
and IC
Class 1A Liquids having a flash point less than 73degF and boiling point less than 100degF
Class 1B Liquids having a flash point less than 73degF and boiling point equal to or greater than 100degF
Class 1C Liquids having a flash point equal to or greater than 73degF but less than 100degF
Combustible liquid A liquid with a flash point at or above 100degF (378degC) [closed cup] Combustible
liquids are further categorized as Class II IIIA and IIIB
Class II Liquids having a flash point equal to or greater than 100degF but less than 140degF
Class IIIA Liquids having a flash point equal to or greater than 140degF but less than 200degF
Class IIIB Liquids having a flash point equal to or greater than 200degF
Section 3 General Flammable Liquid Storage Conditions - All Spaces
Storage and use of flammable and combustible liquids in laboratories is governed by NFPA 45 Standard
on Fire Protection for Laboratories Using Chemicals as adopted through occupational health and safety
regulations enforced by the State as well as the local fire marshal
1 NFPA 45 specifies that no more than three flammable liquid storage cabinets are permitted in a
single space (lab space enclosed with a door)
For safety purposes UW Superior recommends that no more than two flammable liquid
storage cabinets be kept in an academic lab space
Three flammable liquid cabinets are permitted in labs and prep areas not used as teaching
labs such as prep labs and research labs as long as the space has appropriate ventilation
The number of cabinets in a space is not size dependent an 18 gallon capacity cabinet 30
gallon capacity cabinet 45 or 60 gallon cabinet (even if built-in) would all count as one
cabinet each
2 Quantities of flammable liquids in a space or cabinet should be limited to the amount necessary
for the work in progress
3 No more than a combined total of 10 gallons of flammable and combustible liquids and liquefied
flammable gases can be stored outside of a flammable storage cabinet unless safety cans are used
This volume includes any flammable solvents found in refrigerators etc
4 No more than 25 gallons of flammable and combustible liquids combined can be stored in safety
cans in a laboratory outside of a flammable liquid storage cabinet The safety can must be UL or
FM approved have a spring-closing lid and a spout cover and cannot exceed 5 gallons in size
5 Storage of flammable liquids must not obstruct any exit or safety equipment It is recommended
that flammable liquid storage cabinets not be installed next to room exits
6 Flammable liquids should be stored separately from strong oxidizers (ie bleach nitric acid
hydrogen peroxide nitrates potassium permanganate etc) shielded from direct sunlight and
away from heat sources
7 Flammable liquid storage cabinet doors must be kept closed and latched at all times Locking the
cabinets is the userrsquos discretion
Section 4 Flammable Liquid Storage Room - Barstow 10A (formerly room 10B)
In 2012 the Flammable Liquid Storage room (Barstow 10A) was re-designated for use by all programs
within Barstow An agreement by a committee of primary users designated the Chemical Hygiene
Officer (EH amp S Director) to provide oversight for the room and its use as a neutral party It is important
to note that no individual department purchased any of the storage units located in flammable liquid
storage room and therefore no individual department ownership
The intended use of the Flammable Liquids Storage room is to
1 Store flammable or combustible chemicals that are not in regular use andor
2 Store samples waiting to be processed andor
3 Store samples for long-term storagepreservation
Flammable liquid storage cabinets found in prep rooms and laboratories should be used to meet short-
term storage and routine use to reduce the risks associated with transporting flammable liquids outside of
the laboratory or between the laboratory and flammable liquid storage room
Anyone who enters the flammable liquid storage room must have completed lab safety training be aware
of emergency procedures such as fire safety spill response and the location of emergency equipment
Regular users of the flammable liquid storage room can request a key following the University Key
Policy The supervisory signature for the key request is the Chemical Hygiene Officer The Academic
Department Associate in the Department of Natural Sciences will have a key that can be checked out as
needed for intermittent access
Requirements for use of the Flammable Liquid Storage Room
1 The maximum capacity of the Flammable Liquid Storage room (Barstow 10A) is 450 gallons of
Class I II and III flammable and combustible liquids combined as established through a variance
granted by the Superior Fire Department (see Section 9) Of this total quantity no more than a
total of 60 gallons of Class IA flammable liquids are allowed in the storage room
a The amount of non-flammable solvents (chloroform methylene chloride etc) is not
counted towards the total capacity of the room Non-flammable solvents will be stored in
flammable liquid storage cabinets with the flammable solvents
2 The variance REQUIRES that ALL FLAMMABLE and COMBUSTIBLE LIQUIDS be kept
in cabinets at ALL TIMES ANY VIOLATION of this will INSTANTLY REDUCE THE
ROOM CAPACITY TO 120 GALLONS This includes materials in 5 gallon pails safety cans
coolers bottles aerosol cans or fueled equipment like generators
Note ALL materials being delivered to the flammable liquid storage room must be
stored properly immediately upon delivery
3 Violating the conditions in Section 3 items 1 and 2 above may result in the revocation of the
variance by the Superior Fire Department Should a violation occur
a Violators may lose their storage privileges in Barstow 10A
b The violator may be required to pay the monetary penalties if UW Superior is cited
for improper storage in Barstow 10A by the Superior Fire Department
4 The capacity rating on a flammable liquid storage cabinet is a recommended capacity based on an
average number of shelves and container sizes of typical users Users are permitted to exceed the
stated capacity (ie 30 gallon 45 gallon etc) of the cabinet provided that the cabinet contents
never exceeds 60 gallons (maximum) of Class I and Class II flammable liquids combined
regardless of the cabinet size
5 Dispensing or transferring flammable liquids from one container into another is FORBIDDEN in
the flammable liquid storage room Dispensing must be conducted in a laboratory hood
6 The priorities for use of the flammable liquid storage cabinets in Barstow 10A are
a Storage of flammable chemicals purchased in bulk or used infrequently
b Academic department specimen storage (not research related)
c Active research specimen storage
d Archival research sample storage ndash lowest priority
7 Each cabinet in Barstow 10A is assigned a number to track its use See Table 1 for a description
of each cabinet
8 Flammable liquid storage cabinets will be assigned by the Chemical Hygiene Officer
a Some cabinets will be permanently assigned for priority uses
b Other cabinets will be assigned for temporary use for specific time periods based on
project needs as agreed upon by both the user and Chemical Hygiene Officer Users are
encouraged to discuss their storage needs well in advance of the projectrsquos anticipated start
date and are expected to honor the time frame agreed upon so the cabinetrsquos future use can
be considered in planning needs for fairness to all users
c The EH amp S Department is permanently assigned one flammable liquid cabinet in
Barstow 10B for emergency use in case the hazardous waste facility experiences a critical
breakdown This cabinet will be available to be assigned for temporary storage as
discussed in 8-B
d Principle investigators must consider the limited amount of flammable liquid storage
available in project design and proposals Commitments for long term storage (more than
1 year) and permanent sample archiving are discouraged If long term or archival storage
is proposed arrangements should be discussed with the Chemical Hygiene Officer prior
to making any contractual agreements The flammable storage area in the Hazardous
Waste Building may be available and has a larger capacity but should not be depended
upon for long-term storage needs
e If the contents of cabinets require secured access padlocks will be assigned to user by the
Chemical Hygiene Officer The Chemical Hygiene Officer will hold a copy of the key
for emergency access
9 Users are expected to do the following
a Regularly check the materials in storage for condition and age and properly dispose of
any chemicals or samples that are outdated or poor condition
b Ensure that the flammable liquid storage cabinet contents never exceed a total of 60
gallons of Class I and Class II solvents
c Maintain a department chemical inventory of any laboratory chemicals stored in the
flammable liquid storage cabinets in room 10B
d Ensure that the vent covers on the cabinets are not removed
e Provided a description of the general contents of each cabinet posted on the front of the
cabinet This inventory should be maintained on a regular basis (See attached)
f Record the amount of Class IA flammable liquids in the storage cabinet on the inventory
sheet No more than a total of 60 gallons of Class IA flammable liquids can be stored in
Barstow 10B at a time Volumes do not need to be reported for Class IB IC II IIIA or
IIIB materials
Table 1 Description of Each Flammable Liquid Cabinet in Barstow 10B
Cabinet Brand Cabinet
Size Shelf Dimensions
Cabinets are 65rdquo tall with multiple shelves Mfr
Key
Permanently Assigned or
Temporary Usage
FLC-01 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-02 Justrite 60 gal 30375rdquo x 29rdquo
Drum roller in the bottom of the cabinet CH545
FLC-03 Justrite 60 gal 30375rdquo x 29rdquo
Drum roller in the bottom of the cabinet CH545
FLC-04 Justrite 54 gal 19625rdquo x 29rdquo CH545
FLC-05 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-06 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-07 Justrite 22 gal 19625rdquo x 14rdquo CH545
FLC-08 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-09 Justrite 45 gal 39375rdquo x 14rdquo CH545
Section 5 References
NFPA 45 Standard on Fire Protection for Laboratories Using Chemicals 2004 Edition National Fire
Protection Association
NFPA 30 Flammable and Combustible Liquids Code 2008 Edition National Fire Protection
Association
Section 6 Acknowledgements
This document was prepared and issued based on the recommendations and final review by the following
individuals This document will be included as a section of the next revision of the UW Superior
Chemical Hygiene Plan
Mary Balcer LSRI (Lake Superior Research Institute) and Department of Natural Sciences
Edward Burkett Department of Natural Sciences
James Lane Department of Natural Sciences
Carol Lindberg CIH Environmental Health and Safety
Lorena Rios Mendoza Department of Natural Sciences
Christine Polkinghorne LSRI
Deanna Regan LSRI
Kurt Schmude LSRI and Department of Natural Sciences
Jeffrey Schuldt Department of Natural Sciences
Matt TenEyck LSRI
Section 7 Resource
NFPA Classification of Common Flammable and Combustible Liquids and their Classification -
UW Superior
NFPA Classifications of Common Flammable and Combustible Liquids
UW Superior Environmental Health and Safety 2012
Class Example of Common Solvents and Chemicals
1A
Acetaldehyde
Butane
Diethyl Ether (Ethyl ether)
Ligroine
Methane (natural gas)
N-Pentane
Petroleum Ether
Propane
1B
Acetone
Aerosol cans
Acetonitrile
Benzene
Cyclohexane
Ethanol (Pure)
Ethanol aqueous solutions gt51 ethanol
Methanol aqueous solutions gt51 methanol
Isopropanol aqueous solutions gt
Ethyl acetate Gasoline
Heptane
Hexanes
Methanol
Isopropyl Alcohol
Toluene
Ligroin
1C
Butanol
Chlorobenzene
Ethanol aqueous solutions (20 - 50 ethanol)
Octane
Methanol-aqueous solutions (26-51 methanol)
Turpentine
Xylenes
Isoamyl alcohol
Isobutyl alcohol
2
Glacial Acetic Acid
Chlorocyclohexane
Ethanol-aqueous solutions 10-19 ethanol
Formalin solution 37 (15 methanol)
Diesel fuel
Motor oil
Kerosene
3A
Dimethyl Sulfoxide
Ethanol-aqueous solutions lt5 ethanol
Specimens in 10 formalin (15 methanol)
Methanol-aqueous solutions (05-8 methanol)
Some paints (oil)
Linseed oil
1-Octanol
16-Hexanediamine
3B
Benzyl Alcohol
Eugenol
Ethylene glycol
12-Propanediol
Triethylene Glycol
Mineral oil
Vegetable oil
None
Bromine
Bromoform
Chloroform
Carbon tetrachloride
Methylene Chloride
Perchloroethylene
Flammable and Combustible Liquid Classifications
Class 1A - Flash Point less than 73degF Boiling Point less than 100degF
Class 1B - Flash Point less than 73degF Boiling Point equal to or greater than 100degF
Class 1C - Flash Point equal to or greater than 73degF but less than 100degF
Class 2 - Flash Point equal to or greater than 100degF but less than 140degF
Class 3A - Flash Point equal to or greater than 140degF but less than 200degF
Class 3B - Flash Point equal to or greater than 200degF
Laboratory Storage of Compressed Gases
Common Compressed Gases
GasGas
Mixture
Flammable
Limits
in air
NFPA
Class
NFPA Rating
Scale is 0 ndash 4 (0=ordinary hazard 4= high hazard)
Health
Rating
Flammability
Rating
Instability
(Reactivity)
Rating
Special
Hazard(s)
Acetylene 25 ndash 82 1A 0 4 2 None
Air compressed Non-
flammable
0 0 0 None
Argon Non
flammable
0 0 0 None
Butane 16 ndash 84 1A 1 4 0 None
Helium Non
Flammable
0 0 0
Simple
Asphyxiant
Hydrogen 4 ndash 75 1A 0 4 0 None
Methane 5-15 1A 0 4 0 None
Nitrogen Non-
flammable
0 0 0
Simple
Asphyxiant
Nitrous Oxide Non-
flammable
2 0 0 Oxidizer
Oxygen Non-
flammable
0 0 0 Oxidizer
Propane 210-101 1A 1 4 0 None
P5 5 methane
+95 argon
Non-
flammable
1 0 0 None
Lecture bottles
Gases in lecture bottles must be stored in a continuously operating hood when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
The gas is pyrophoric
Cylinders
The number of gas cylinders larger than a lecture bottle in a laboratory should be limited to no more
than
One cylinder of each gas in use (connected to the equipment and secured) and
One cylinder in reserve (regulator removed capped and secured)
No more than 3 cylinders of flammable or oxidizing gases permitted in labs of 500 square feet
or less
Gases in cylinders larger than a lecture bottle must be stored in a continuously-vented approved gas
cabinet when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
Pyrophoric gases in cylinders larger than a lecture bottle must be stored in an approved
continuously-vented sprinklered gas cabinet
Section 8 Flammable Cabinet Inventory Records
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Permanently assigned to __________________________________________________________
Contents Description Volume amp
Units Date
Inventory of All Class IA Chemicals or Materials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Temporarily assigned to ________________________________ Dept ___________________
Agreed Upon Dates for Use From ____________________ To ___________________
Contents Description Volume amp
Units Date
Inventory of All Class IA ChemicalsMaterials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Section 9 Variance from Superior Fire Department
February 17 2012
Ms Carol Lindberg
University of Wisconsin Superior
1800 Grand Ave
Superior WI 54880
Dear Ms Lindberg
I have reviewed your request for a variance from the maximum allowed quantity of flammable liquids permitted
to be stored in the flammable storage room at Barstow Hall on the Superior campus of the University of
Wisconsin
Fire Chief Jim Rigstad has granted conditional approval to this variance The terms of the variance are as
follows
A maximum of 450 gallons of flammable liquids may be stored in the room at any given time
All flammable liquids stored in the room must be stored in UL listed flammable liquid storage cabinets
Cabinets constructed in compliance with the requirements of NFPA 30-953 shall also be acceptable
Non-compatible materials stored in the room must be separated as required by code
A containment sill must be installed in the doorway to prevent spilled product from escaping the room
The sill must be sealed with masonry or with a rated fire caulk to maintain the rating of the room
Other liquids stored in the room shall not exceed the quantities permitted by code and may only be
stored in the room outside of a flammable liquid storage cabinets provided there is adequate space in the
room after the installation of the flammable liquid storage cabinets required under conditions listed
above
The flammable liquid storage room must be maintained in full compliance with any other requirements
of NFPA 30 or any other applicable codes
If you have any questions regarding this variance please feel free to contact me
Sincerely
Arthur E Gil de Lamadrid
Lead Fire Inspector
Cc J Rigstad Fire Chief
V Johnson Battalion Chief
Superior Fire Department Phone (715) 394-0227
Fax (715) 394-0215
Jim Rigstad Fire Chief
Superior Fire Department
3326 Tower Av
Added by Carol Lindberg for documentation
From Gil de Lamadrid Arthur [mailtoarthurgcisuperiorwius] Sent Thursday February 23 2012 942 AM
To LindbergCarol A Subject RE Flam Cabs
Yes I believe that in your original request you asked for 10 cabinets Unfortunately I tossed my notes after writing the letter But I thought that the quantity was based upon that number of cabinets
From LindbergCarol A [mailtoCLindberuwsuperedu]
Sent Friday February 17 2012 1025 To Gil de Lamadrid Arthur
Subject RE Flam Cabs Art Yes ndash this is very good news One question ndash under the terms listed are we allowed to have more than 3 flammable liquid storage cabinets in the space Thank you Carol A Lindberg CIH Environmental Health and Safety Program University of Wisconsin - Superior
3 No more than a combined total of 10 gallons of flammable and combustible liquids and liquefied
flammable gases can be stored outside of a flammable storage cabinet unless safety cans are used
This volume includes any flammable solvents found in refrigerators etc
4 No more than 25 gallons of flammable and combustible liquids combined can be stored in safety
cans in a laboratory outside of a flammable liquid storage cabinet The safety can must be UL or
FM approved have a spring-closing lid and a spout cover and cannot exceed 5 gallons in size
5 Storage of flammable liquids must not obstruct any exit or safety equipment It is recommended
that flammable liquid storage cabinets not be installed next to room exits
6 Flammable liquids should be stored separately from strong oxidizers (ie bleach nitric acid
hydrogen peroxide nitrates potassium permanganate etc) shielded from direct sunlight and
away from heat sources
7 Flammable liquid storage cabinet doors must be kept closed and latched at all times Locking the
cabinets is the userrsquos discretion
Section 4 Flammable Liquid Storage Room - Barstow 10A (formerly room 10B)
In 2012 the Flammable Liquid Storage room (Barstow 10A) was re-designated for use by all programs
within Barstow An agreement by a committee of primary users designated the Chemical Hygiene
Officer (EH amp S Director) to provide oversight for the room and its use as a neutral party It is important
to note that no individual department purchased any of the storage units located in flammable liquid
storage room and therefore no individual department ownership
The intended use of the Flammable Liquids Storage room is to
1 Store flammable or combustible chemicals that are not in regular use andor
2 Store samples waiting to be processed andor
3 Store samples for long-term storagepreservation
Flammable liquid storage cabinets found in prep rooms and laboratories should be used to meet short-
term storage and routine use to reduce the risks associated with transporting flammable liquids outside of
the laboratory or between the laboratory and flammable liquid storage room
Anyone who enters the flammable liquid storage room must have completed lab safety training be aware
of emergency procedures such as fire safety spill response and the location of emergency equipment
Regular users of the flammable liquid storage room can request a key following the University Key
Policy The supervisory signature for the key request is the Chemical Hygiene Officer The Academic
Department Associate in the Department of Natural Sciences will have a key that can be checked out as
needed for intermittent access
Requirements for use of the Flammable Liquid Storage Room
1 The maximum capacity of the Flammable Liquid Storage room (Barstow 10A) is 450 gallons of
Class I II and III flammable and combustible liquids combined as established through a variance
granted by the Superior Fire Department (see Section 9) Of this total quantity no more than a
total of 60 gallons of Class IA flammable liquids are allowed in the storage room
a The amount of non-flammable solvents (chloroform methylene chloride etc) is not
counted towards the total capacity of the room Non-flammable solvents will be stored in
flammable liquid storage cabinets with the flammable solvents
2 The variance REQUIRES that ALL FLAMMABLE and COMBUSTIBLE LIQUIDS be kept
in cabinets at ALL TIMES ANY VIOLATION of this will INSTANTLY REDUCE THE
ROOM CAPACITY TO 120 GALLONS This includes materials in 5 gallon pails safety cans
coolers bottles aerosol cans or fueled equipment like generators
Note ALL materials being delivered to the flammable liquid storage room must be
stored properly immediately upon delivery
3 Violating the conditions in Section 3 items 1 and 2 above may result in the revocation of the
variance by the Superior Fire Department Should a violation occur
a Violators may lose their storage privileges in Barstow 10A
b The violator may be required to pay the monetary penalties if UW Superior is cited
for improper storage in Barstow 10A by the Superior Fire Department
4 The capacity rating on a flammable liquid storage cabinet is a recommended capacity based on an
average number of shelves and container sizes of typical users Users are permitted to exceed the
stated capacity (ie 30 gallon 45 gallon etc) of the cabinet provided that the cabinet contents
never exceeds 60 gallons (maximum) of Class I and Class II flammable liquids combined
regardless of the cabinet size
5 Dispensing or transferring flammable liquids from one container into another is FORBIDDEN in
the flammable liquid storage room Dispensing must be conducted in a laboratory hood
6 The priorities for use of the flammable liquid storage cabinets in Barstow 10A are
a Storage of flammable chemicals purchased in bulk or used infrequently
b Academic department specimen storage (not research related)
c Active research specimen storage
d Archival research sample storage ndash lowest priority
7 Each cabinet in Barstow 10A is assigned a number to track its use See Table 1 for a description
of each cabinet
8 Flammable liquid storage cabinets will be assigned by the Chemical Hygiene Officer
a Some cabinets will be permanently assigned for priority uses
b Other cabinets will be assigned for temporary use for specific time periods based on
project needs as agreed upon by both the user and Chemical Hygiene Officer Users are
encouraged to discuss their storage needs well in advance of the projectrsquos anticipated start
date and are expected to honor the time frame agreed upon so the cabinetrsquos future use can
be considered in planning needs for fairness to all users
c The EH amp S Department is permanently assigned one flammable liquid cabinet in
Barstow 10B for emergency use in case the hazardous waste facility experiences a critical
breakdown This cabinet will be available to be assigned for temporary storage as
discussed in 8-B
d Principle investigators must consider the limited amount of flammable liquid storage
available in project design and proposals Commitments for long term storage (more than
1 year) and permanent sample archiving are discouraged If long term or archival storage
is proposed arrangements should be discussed with the Chemical Hygiene Officer prior
to making any contractual agreements The flammable storage area in the Hazardous
Waste Building may be available and has a larger capacity but should not be depended
upon for long-term storage needs
e If the contents of cabinets require secured access padlocks will be assigned to user by the
Chemical Hygiene Officer The Chemical Hygiene Officer will hold a copy of the key
for emergency access
9 Users are expected to do the following
a Regularly check the materials in storage for condition and age and properly dispose of
any chemicals or samples that are outdated or poor condition
b Ensure that the flammable liquid storage cabinet contents never exceed a total of 60
gallons of Class I and Class II solvents
c Maintain a department chemical inventory of any laboratory chemicals stored in the
flammable liquid storage cabinets in room 10B
d Ensure that the vent covers on the cabinets are not removed
e Provided a description of the general contents of each cabinet posted on the front of the
cabinet This inventory should be maintained on a regular basis (See attached)
f Record the amount of Class IA flammable liquids in the storage cabinet on the inventory
sheet No more than a total of 60 gallons of Class IA flammable liquids can be stored in
Barstow 10B at a time Volumes do not need to be reported for Class IB IC II IIIA or
IIIB materials
Table 1 Description of Each Flammable Liquid Cabinet in Barstow 10B
Cabinet Brand Cabinet
Size Shelf Dimensions
Cabinets are 65rdquo tall with multiple shelves Mfr
Key
Permanently Assigned or
Temporary Usage
FLC-01 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-02 Justrite 60 gal 30375rdquo x 29rdquo
Drum roller in the bottom of the cabinet CH545
FLC-03 Justrite 60 gal 30375rdquo x 29rdquo
Drum roller in the bottom of the cabinet CH545
FLC-04 Justrite 54 gal 19625rdquo x 29rdquo CH545
FLC-05 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-06 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-07 Justrite 22 gal 19625rdquo x 14rdquo CH545
FLC-08 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-09 Justrite 45 gal 39375rdquo x 14rdquo CH545
Section 5 References
NFPA 45 Standard on Fire Protection for Laboratories Using Chemicals 2004 Edition National Fire
Protection Association
NFPA 30 Flammable and Combustible Liquids Code 2008 Edition National Fire Protection
Association
Section 6 Acknowledgements
This document was prepared and issued based on the recommendations and final review by the following
individuals This document will be included as a section of the next revision of the UW Superior
Chemical Hygiene Plan
Mary Balcer LSRI (Lake Superior Research Institute) and Department of Natural Sciences
Edward Burkett Department of Natural Sciences
James Lane Department of Natural Sciences
Carol Lindberg CIH Environmental Health and Safety
Lorena Rios Mendoza Department of Natural Sciences
Christine Polkinghorne LSRI
Deanna Regan LSRI
Kurt Schmude LSRI and Department of Natural Sciences
Jeffrey Schuldt Department of Natural Sciences
Matt TenEyck LSRI
Section 7 Resource
NFPA Classification of Common Flammable and Combustible Liquids and their Classification -
UW Superior
NFPA Classifications of Common Flammable and Combustible Liquids
UW Superior Environmental Health and Safety 2012
Class Example of Common Solvents and Chemicals
1A
Acetaldehyde
Butane
Diethyl Ether (Ethyl ether)
Ligroine
Methane (natural gas)
N-Pentane
Petroleum Ether
Propane
1B
Acetone
Aerosol cans
Acetonitrile
Benzene
Cyclohexane
Ethanol (Pure)
Ethanol aqueous solutions gt51 ethanol
Methanol aqueous solutions gt51 methanol
Isopropanol aqueous solutions gt
Ethyl acetate Gasoline
Heptane
Hexanes
Methanol
Isopropyl Alcohol
Toluene
Ligroin
1C
Butanol
Chlorobenzene
Ethanol aqueous solutions (20 - 50 ethanol)
Octane
Methanol-aqueous solutions (26-51 methanol)
Turpentine
Xylenes
Isoamyl alcohol
Isobutyl alcohol
2
Glacial Acetic Acid
Chlorocyclohexane
Ethanol-aqueous solutions 10-19 ethanol
Formalin solution 37 (15 methanol)
Diesel fuel
Motor oil
Kerosene
3A
Dimethyl Sulfoxide
Ethanol-aqueous solutions lt5 ethanol
Specimens in 10 formalin (15 methanol)
Methanol-aqueous solutions (05-8 methanol)
Some paints (oil)
Linseed oil
1-Octanol
16-Hexanediamine
3B
Benzyl Alcohol
Eugenol
Ethylene glycol
12-Propanediol
Triethylene Glycol
Mineral oil
Vegetable oil
None
Bromine
Bromoform
Chloroform
Carbon tetrachloride
Methylene Chloride
Perchloroethylene
Flammable and Combustible Liquid Classifications
Class 1A - Flash Point less than 73degF Boiling Point less than 100degF
Class 1B - Flash Point less than 73degF Boiling Point equal to or greater than 100degF
Class 1C - Flash Point equal to or greater than 73degF but less than 100degF
Class 2 - Flash Point equal to or greater than 100degF but less than 140degF
Class 3A - Flash Point equal to or greater than 140degF but less than 200degF
Class 3B - Flash Point equal to or greater than 200degF
Laboratory Storage of Compressed Gases
Common Compressed Gases
GasGas
Mixture
Flammable
Limits
in air
NFPA
Class
NFPA Rating
Scale is 0 ndash 4 (0=ordinary hazard 4= high hazard)
Health
Rating
Flammability
Rating
Instability
(Reactivity)
Rating
Special
Hazard(s)
Acetylene 25 ndash 82 1A 0 4 2 None
Air compressed Non-
flammable
0 0 0 None
Argon Non
flammable
0 0 0 None
Butane 16 ndash 84 1A 1 4 0 None
Helium Non
Flammable
0 0 0
Simple
Asphyxiant
Hydrogen 4 ndash 75 1A 0 4 0 None
Methane 5-15 1A 0 4 0 None
Nitrogen Non-
flammable
0 0 0
Simple
Asphyxiant
Nitrous Oxide Non-
flammable
2 0 0 Oxidizer
Oxygen Non-
flammable
0 0 0 Oxidizer
Propane 210-101 1A 1 4 0 None
P5 5 methane
+95 argon
Non-
flammable
1 0 0 None
Lecture bottles
Gases in lecture bottles must be stored in a continuously operating hood when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
The gas is pyrophoric
Cylinders
The number of gas cylinders larger than a lecture bottle in a laboratory should be limited to no more
than
One cylinder of each gas in use (connected to the equipment and secured) and
One cylinder in reserve (regulator removed capped and secured)
No more than 3 cylinders of flammable or oxidizing gases permitted in labs of 500 square feet
or less
Gases in cylinders larger than a lecture bottle must be stored in a continuously-vented approved gas
cabinet when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
Pyrophoric gases in cylinders larger than a lecture bottle must be stored in an approved
continuously-vented sprinklered gas cabinet
Section 8 Flammable Cabinet Inventory Records
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Permanently assigned to __________________________________________________________
Contents Description Volume amp
Units Date
Inventory of All Class IA Chemicals or Materials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Temporarily assigned to ________________________________ Dept ___________________
Agreed Upon Dates for Use From ____________________ To ___________________
Contents Description Volume amp
Units Date
Inventory of All Class IA ChemicalsMaterials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Section 9 Variance from Superior Fire Department
February 17 2012
Ms Carol Lindberg
University of Wisconsin Superior
1800 Grand Ave
Superior WI 54880
Dear Ms Lindberg
I have reviewed your request for a variance from the maximum allowed quantity of flammable liquids permitted
to be stored in the flammable storage room at Barstow Hall on the Superior campus of the University of
Wisconsin
Fire Chief Jim Rigstad has granted conditional approval to this variance The terms of the variance are as
follows
A maximum of 450 gallons of flammable liquids may be stored in the room at any given time
All flammable liquids stored in the room must be stored in UL listed flammable liquid storage cabinets
Cabinets constructed in compliance with the requirements of NFPA 30-953 shall also be acceptable
Non-compatible materials stored in the room must be separated as required by code
A containment sill must be installed in the doorway to prevent spilled product from escaping the room
The sill must be sealed with masonry or with a rated fire caulk to maintain the rating of the room
Other liquids stored in the room shall not exceed the quantities permitted by code and may only be
stored in the room outside of a flammable liquid storage cabinets provided there is adequate space in the
room after the installation of the flammable liquid storage cabinets required under conditions listed
above
The flammable liquid storage room must be maintained in full compliance with any other requirements
of NFPA 30 or any other applicable codes
If you have any questions regarding this variance please feel free to contact me
Sincerely
Arthur E Gil de Lamadrid
Lead Fire Inspector
Cc J Rigstad Fire Chief
V Johnson Battalion Chief
Superior Fire Department Phone (715) 394-0227
Fax (715) 394-0215
Jim Rigstad Fire Chief
Superior Fire Department
3326 Tower Av
Added by Carol Lindberg for documentation
From Gil de Lamadrid Arthur [mailtoarthurgcisuperiorwius] Sent Thursday February 23 2012 942 AM
To LindbergCarol A Subject RE Flam Cabs
Yes I believe that in your original request you asked for 10 cabinets Unfortunately I tossed my notes after writing the letter But I thought that the quantity was based upon that number of cabinets
From LindbergCarol A [mailtoCLindberuwsuperedu]
Sent Friday February 17 2012 1025 To Gil de Lamadrid Arthur
Subject RE Flam Cabs Art Yes ndash this is very good news One question ndash under the terms listed are we allowed to have more than 3 flammable liquid storage cabinets in the space Thank you Carol A Lindberg CIH Environmental Health and Safety Program University of Wisconsin - Superior
3 Violating the conditions in Section 3 items 1 and 2 above may result in the revocation of the
variance by the Superior Fire Department Should a violation occur
a Violators may lose their storage privileges in Barstow 10A
b The violator may be required to pay the monetary penalties if UW Superior is cited
for improper storage in Barstow 10A by the Superior Fire Department
4 The capacity rating on a flammable liquid storage cabinet is a recommended capacity based on an
average number of shelves and container sizes of typical users Users are permitted to exceed the
stated capacity (ie 30 gallon 45 gallon etc) of the cabinet provided that the cabinet contents
never exceeds 60 gallons (maximum) of Class I and Class II flammable liquids combined
regardless of the cabinet size
5 Dispensing or transferring flammable liquids from one container into another is FORBIDDEN in
the flammable liquid storage room Dispensing must be conducted in a laboratory hood
6 The priorities for use of the flammable liquid storage cabinets in Barstow 10A are
a Storage of flammable chemicals purchased in bulk or used infrequently
b Academic department specimen storage (not research related)
c Active research specimen storage
d Archival research sample storage ndash lowest priority
7 Each cabinet in Barstow 10A is assigned a number to track its use See Table 1 for a description
of each cabinet
8 Flammable liquid storage cabinets will be assigned by the Chemical Hygiene Officer
a Some cabinets will be permanently assigned for priority uses
b Other cabinets will be assigned for temporary use for specific time periods based on
project needs as agreed upon by both the user and Chemical Hygiene Officer Users are
encouraged to discuss their storage needs well in advance of the projectrsquos anticipated start
date and are expected to honor the time frame agreed upon so the cabinetrsquos future use can
be considered in planning needs for fairness to all users
c The EH amp S Department is permanently assigned one flammable liquid cabinet in
Barstow 10B for emergency use in case the hazardous waste facility experiences a critical
breakdown This cabinet will be available to be assigned for temporary storage as
discussed in 8-B
d Principle investigators must consider the limited amount of flammable liquid storage
available in project design and proposals Commitments for long term storage (more than
1 year) and permanent sample archiving are discouraged If long term or archival storage
is proposed arrangements should be discussed with the Chemical Hygiene Officer prior
to making any contractual agreements The flammable storage area in the Hazardous
Waste Building may be available and has a larger capacity but should not be depended
upon for long-term storage needs
e If the contents of cabinets require secured access padlocks will be assigned to user by the
Chemical Hygiene Officer The Chemical Hygiene Officer will hold a copy of the key
for emergency access
9 Users are expected to do the following
a Regularly check the materials in storage for condition and age and properly dispose of
any chemicals or samples that are outdated or poor condition
b Ensure that the flammable liquid storage cabinet contents never exceed a total of 60
gallons of Class I and Class II solvents
c Maintain a department chemical inventory of any laboratory chemicals stored in the
flammable liquid storage cabinets in room 10B
d Ensure that the vent covers on the cabinets are not removed
e Provided a description of the general contents of each cabinet posted on the front of the
cabinet This inventory should be maintained on a regular basis (See attached)
f Record the amount of Class IA flammable liquids in the storage cabinet on the inventory
sheet No more than a total of 60 gallons of Class IA flammable liquids can be stored in
Barstow 10B at a time Volumes do not need to be reported for Class IB IC II IIIA or
IIIB materials
Table 1 Description of Each Flammable Liquid Cabinet in Barstow 10B
Cabinet Brand Cabinet
Size Shelf Dimensions
Cabinets are 65rdquo tall with multiple shelves Mfr
Key
Permanently Assigned or
Temporary Usage
FLC-01 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-02 Justrite 60 gal 30375rdquo x 29rdquo
Drum roller in the bottom of the cabinet CH545
FLC-03 Justrite 60 gal 30375rdquo x 29rdquo
Drum roller in the bottom of the cabinet CH545
FLC-04 Justrite 54 gal 19625rdquo x 29rdquo CH545
FLC-05 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-06 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-07 Justrite 22 gal 19625rdquo x 14rdquo CH545
FLC-08 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-09 Justrite 45 gal 39375rdquo x 14rdquo CH545
Section 5 References
NFPA 45 Standard on Fire Protection for Laboratories Using Chemicals 2004 Edition National Fire
Protection Association
NFPA 30 Flammable and Combustible Liquids Code 2008 Edition National Fire Protection
Association
Section 6 Acknowledgements
This document was prepared and issued based on the recommendations and final review by the following
individuals This document will be included as a section of the next revision of the UW Superior
Chemical Hygiene Plan
Mary Balcer LSRI (Lake Superior Research Institute) and Department of Natural Sciences
Edward Burkett Department of Natural Sciences
James Lane Department of Natural Sciences
Carol Lindberg CIH Environmental Health and Safety
Lorena Rios Mendoza Department of Natural Sciences
Christine Polkinghorne LSRI
Deanna Regan LSRI
Kurt Schmude LSRI and Department of Natural Sciences
Jeffrey Schuldt Department of Natural Sciences
Matt TenEyck LSRI
Section 7 Resource
NFPA Classification of Common Flammable and Combustible Liquids and their Classification -
UW Superior
NFPA Classifications of Common Flammable and Combustible Liquids
UW Superior Environmental Health and Safety 2012
Class Example of Common Solvents and Chemicals
1A
Acetaldehyde
Butane
Diethyl Ether (Ethyl ether)
Ligroine
Methane (natural gas)
N-Pentane
Petroleum Ether
Propane
1B
Acetone
Aerosol cans
Acetonitrile
Benzene
Cyclohexane
Ethanol (Pure)
Ethanol aqueous solutions gt51 ethanol
Methanol aqueous solutions gt51 methanol
Isopropanol aqueous solutions gt
Ethyl acetate Gasoline
Heptane
Hexanes
Methanol
Isopropyl Alcohol
Toluene
Ligroin
1C
Butanol
Chlorobenzene
Ethanol aqueous solutions (20 - 50 ethanol)
Octane
Methanol-aqueous solutions (26-51 methanol)
Turpentine
Xylenes
Isoamyl alcohol
Isobutyl alcohol
2
Glacial Acetic Acid
Chlorocyclohexane
Ethanol-aqueous solutions 10-19 ethanol
Formalin solution 37 (15 methanol)
Diesel fuel
Motor oil
Kerosene
3A
Dimethyl Sulfoxide
Ethanol-aqueous solutions lt5 ethanol
Specimens in 10 formalin (15 methanol)
Methanol-aqueous solutions (05-8 methanol)
Some paints (oil)
Linseed oil
1-Octanol
16-Hexanediamine
3B
Benzyl Alcohol
Eugenol
Ethylene glycol
12-Propanediol
Triethylene Glycol
Mineral oil
Vegetable oil
None
Bromine
Bromoform
Chloroform
Carbon tetrachloride
Methylene Chloride
Perchloroethylene
Flammable and Combustible Liquid Classifications
Class 1A - Flash Point less than 73degF Boiling Point less than 100degF
Class 1B - Flash Point less than 73degF Boiling Point equal to or greater than 100degF
Class 1C - Flash Point equal to or greater than 73degF but less than 100degF
Class 2 - Flash Point equal to or greater than 100degF but less than 140degF
Class 3A - Flash Point equal to or greater than 140degF but less than 200degF
Class 3B - Flash Point equal to or greater than 200degF
Laboratory Storage of Compressed Gases
Common Compressed Gases
GasGas
Mixture
Flammable
Limits
in air
NFPA
Class
NFPA Rating
Scale is 0 ndash 4 (0=ordinary hazard 4= high hazard)
Health
Rating
Flammability
Rating
Instability
(Reactivity)
Rating
Special
Hazard(s)
Acetylene 25 ndash 82 1A 0 4 2 None
Air compressed Non-
flammable
0 0 0 None
Argon Non
flammable
0 0 0 None
Butane 16 ndash 84 1A 1 4 0 None
Helium Non
Flammable
0 0 0
Simple
Asphyxiant
Hydrogen 4 ndash 75 1A 0 4 0 None
Methane 5-15 1A 0 4 0 None
Nitrogen Non-
flammable
0 0 0
Simple
Asphyxiant
Nitrous Oxide Non-
flammable
2 0 0 Oxidizer
Oxygen Non-
flammable
0 0 0 Oxidizer
Propane 210-101 1A 1 4 0 None
P5 5 methane
+95 argon
Non-
flammable
1 0 0 None
Lecture bottles
Gases in lecture bottles must be stored in a continuously operating hood when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
The gas is pyrophoric
Cylinders
The number of gas cylinders larger than a lecture bottle in a laboratory should be limited to no more
than
One cylinder of each gas in use (connected to the equipment and secured) and
One cylinder in reserve (regulator removed capped and secured)
No more than 3 cylinders of flammable or oxidizing gases permitted in labs of 500 square feet
or less
Gases in cylinders larger than a lecture bottle must be stored in a continuously-vented approved gas
cabinet when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
Pyrophoric gases in cylinders larger than a lecture bottle must be stored in an approved
continuously-vented sprinklered gas cabinet
Section 8 Flammable Cabinet Inventory Records
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Permanently assigned to __________________________________________________________
Contents Description Volume amp
Units Date
Inventory of All Class IA Chemicals or Materials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Temporarily assigned to ________________________________ Dept ___________________
Agreed Upon Dates for Use From ____________________ To ___________________
Contents Description Volume amp
Units Date
Inventory of All Class IA ChemicalsMaterials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Section 9 Variance from Superior Fire Department
February 17 2012
Ms Carol Lindberg
University of Wisconsin Superior
1800 Grand Ave
Superior WI 54880
Dear Ms Lindberg
I have reviewed your request for a variance from the maximum allowed quantity of flammable liquids permitted
to be stored in the flammable storage room at Barstow Hall on the Superior campus of the University of
Wisconsin
Fire Chief Jim Rigstad has granted conditional approval to this variance The terms of the variance are as
follows
A maximum of 450 gallons of flammable liquids may be stored in the room at any given time
All flammable liquids stored in the room must be stored in UL listed flammable liquid storage cabinets
Cabinets constructed in compliance with the requirements of NFPA 30-953 shall also be acceptable
Non-compatible materials stored in the room must be separated as required by code
A containment sill must be installed in the doorway to prevent spilled product from escaping the room
The sill must be sealed with masonry or with a rated fire caulk to maintain the rating of the room
Other liquids stored in the room shall not exceed the quantities permitted by code and may only be
stored in the room outside of a flammable liquid storage cabinets provided there is adequate space in the
room after the installation of the flammable liquid storage cabinets required under conditions listed
above
The flammable liquid storage room must be maintained in full compliance with any other requirements
of NFPA 30 or any other applicable codes
If you have any questions regarding this variance please feel free to contact me
Sincerely
Arthur E Gil de Lamadrid
Lead Fire Inspector
Cc J Rigstad Fire Chief
V Johnson Battalion Chief
Superior Fire Department Phone (715) 394-0227
Fax (715) 394-0215
Jim Rigstad Fire Chief
Superior Fire Department
3326 Tower Av
Added by Carol Lindberg for documentation
From Gil de Lamadrid Arthur [mailtoarthurgcisuperiorwius] Sent Thursday February 23 2012 942 AM
To LindbergCarol A Subject RE Flam Cabs
Yes I believe that in your original request you asked for 10 cabinets Unfortunately I tossed my notes after writing the letter But I thought that the quantity was based upon that number of cabinets
From LindbergCarol A [mailtoCLindberuwsuperedu]
Sent Friday February 17 2012 1025 To Gil de Lamadrid Arthur
Subject RE Flam Cabs Art Yes ndash this is very good news One question ndash under the terms listed are we allowed to have more than 3 flammable liquid storage cabinets in the space Thank you Carol A Lindberg CIH Environmental Health and Safety Program University of Wisconsin - Superior
c Maintain a department chemical inventory of any laboratory chemicals stored in the
flammable liquid storage cabinets in room 10B
d Ensure that the vent covers on the cabinets are not removed
e Provided a description of the general contents of each cabinet posted on the front of the
cabinet This inventory should be maintained on a regular basis (See attached)
f Record the amount of Class IA flammable liquids in the storage cabinet on the inventory
sheet No more than a total of 60 gallons of Class IA flammable liquids can be stored in
Barstow 10B at a time Volumes do not need to be reported for Class IB IC II IIIA or
IIIB materials
Table 1 Description of Each Flammable Liquid Cabinet in Barstow 10B
Cabinet Brand Cabinet
Size Shelf Dimensions
Cabinets are 65rdquo tall with multiple shelves Mfr
Key
Permanently Assigned or
Temporary Usage
FLC-01 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-02 Justrite 60 gal 30375rdquo x 29rdquo
Drum roller in the bottom of the cabinet CH545
FLC-03 Justrite 60 gal 30375rdquo x 29rdquo
Drum roller in the bottom of the cabinet CH545
FLC-04 Justrite 54 gal 19625rdquo x 29rdquo CH545
FLC-05 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-06 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-07 Justrite 22 gal 19625rdquo x 14rdquo CH545
FLC-08 Justrite 45 gal 39375rdquo x 14rdquo CH545
FLC-09 Justrite 45 gal 39375rdquo x 14rdquo CH545
Section 5 References
NFPA 45 Standard on Fire Protection for Laboratories Using Chemicals 2004 Edition National Fire
Protection Association
NFPA 30 Flammable and Combustible Liquids Code 2008 Edition National Fire Protection
Association
Section 6 Acknowledgements
This document was prepared and issued based on the recommendations and final review by the following
individuals This document will be included as a section of the next revision of the UW Superior
Chemical Hygiene Plan
Mary Balcer LSRI (Lake Superior Research Institute) and Department of Natural Sciences
Edward Burkett Department of Natural Sciences
James Lane Department of Natural Sciences
Carol Lindberg CIH Environmental Health and Safety
Lorena Rios Mendoza Department of Natural Sciences
Christine Polkinghorne LSRI
Deanna Regan LSRI
Kurt Schmude LSRI and Department of Natural Sciences
Jeffrey Schuldt Department of Natural Sciences
Matt TenEyck LSRI
Section 7 Resource
NFPA Classification of Common Flammable and Combustible Liquids and their Classification -
UW Superior
NFPA Classifications of Common Flammable and Combustible Liquids
UW Superior Environmental Health and Safety 2012
Class Example of Common Solvents and Chemicals
1A
Acetaldehyde
Butane
Diethyl Ether (Ethyl ether)
Ligroine
Methane (natural gas)
N-Pentane
Petroleum Ether
Propane
1B
Acetone
Aerosol cans
Acetonitrile
Benzene
Cyclohexane
Ethanol (Pure)
Ethanol aqueous solutions gt51 ethanol
Methanol aqueous solutions gt51 methanol
Isopropanol aqueous solutions gt
Ethyl acetate Gasoline
Heptane
Hexanes
Methanol
Isopropyl Alcohol
Toluene
Ligroin
1C
Butanol
Chlorobenzene
Ethanol aqueous solutions (20 - 50 ethanol)
Octane
Methanol-aqueous solutions (26-51 methanol)
Turpentine
Xylenes
Isoamyl alcohol
Isobutyl alcohol
2
Glacial Acetic Acid
Chlorocyclohexane
Ethanol-aqueous solutions 10-19 ethanol
Formalin solution 37 (15 methanol)
Diesel fuel
Motor oil
Kerosene
3A
Dimethyl Sulfoxide
Ethanol-aqueous solutions lt5 ethanol
Specimens in 10 formalin (15 methanol)
Methanol-aqueous solutions (05-8 methanol)
Some paints (oil)
Linseed oil
1-Octanol
16-Hexanediamine
3B
Benzyl Alcohol
Eugenol
Ethylene glycol
12-Propanediol
Triethylene Glycol
Mineral oil
Vegetable oil
None
Bromine
Bromoform
Chloroform
Carbon tetrachloride
Methylene Chloride
Perchloroethylene
Flammable and Combustible Liquid Classifications
Class 1A - Flash Point less than 73degF Boiling Point less than 100degF
Class 1B - Flash Point less than 73degF Boiling Point equal to or greater than 100degF
Class 1C - Flash Point equal to or greater than 73degF but less than 100degF
Class 2 - Flash Point equal to or greater than 100degF but less than 140degF
Class 3A - Flash Point equal to or greater than 140degF but less than 200degF
Class 3B - Flash Point equal to or greater than 200degF
Laboratory Storage of Compressed Gases
Common Compressed Gases
GasGas
Mixture
Flammable
Limits
in air
NFPA
Class
NFPA Rating
Scale is 0 ndash 4 (0=ordinary hazard 4= high hazard)
Health
Rating
Flammability
Rating
Instability
(Reactivity)
Rating
Special
Hazard(s)
Acetylene 25 ndash 82 1A 0 4 2 None
Air compressed Non-
flammable
0 0 0 None
Argon Non
flammable
0 0 0 None
Butane 16 ndash 84 1A 1 4 0 None
Helium Non
Flammable
0 0 0
Simple
Asphyxiant
Hydrogen 4 ndash 75 1A 0 4 0 None
Methane 5-15 1A 0 4 0 None
Nitrogen Non-
flammable
0 0 0
Simple
Asphyxiant
Nitrous Oxide Non-
flammable
2 0 0 Oxidizer
Oxygen Non-
flammable
0 0 0 Oxidizer
Propane 210-101 1A 1 4 0 None
P5 5 methane
+95 argon
Non-
flammable
1 0 0 None
Lecture bottles
Gases in lecture bottles must be stored in a continuously operating hood when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
The gas is pyrophoric
Cylinders
The number of gas cylinders larger than a lecture bottle in a laboratory should be limited to no more
than
One cylinder of each gas in use (connected to the equipment and secured) and
One cylinder in reserve (regulator removed capped and secured)
No more than 3 cylinders of flammable or oxidizing gases permitted in labs of 500 square feet
or less
Gases in cylinders larger than a lecture bottle must be stored in a continuously-vented approved gas
cabinet when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
Pyrophoric gases in cylinders larger than a lecture bottle must be stored in an approved
continuously-vented sprinklered gas cabinet
Section 8 Flammable Cabinet Inventory Records
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Permanently assigned to __________________________________________________________
Contents Description Volume amp
Units Date
Inventory of All Class IA Chemicals or Materials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Temporarily assigned to ________________________________ Dept ___________________
Agreed Upon Dates for Use From ____________________ To ___________________
Contents Description Volume amp
Units Date
Inventory of All Class IA ChemicalsMaterials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Section 9 Variance from Superior Fire Department
February 17 2012
Ms Carol Lindberg
University of Wisconsin Superior
1800 Grand Ave
Superior WI 54880
Dear Ms Lindberg
I have reviewed your request for a variance from the maximum allowed quantity of flammable liquids permitted
to be stored in the flammable storage room at Barstow Hall on the Superior campus of the University of
Wisconsin
Fire Chief Jim Rigstad has granted conditional approval to this variance The terms of the variance are as
follows
A maximum of 450 gallons of flammable liquids may be stored in the room at any given time
All flammable liquids stored in the room must be stored in UL listed flammable liquid storage cabinets
Cabinets constructed in compliance with the requirements of NFPA 30-953 shall also be acceptable
Non-compatible materials stored in the room must be separated as required by code
A containment sill must be installed in the doorway to prevent spilled product from escaping the room
The sill must be sealed with masonry or with a rated fire caulk to maintain the rating of the room
Other liquids stored in the room shall not exceed the quantities permitted by code and may only be
stored in the room outside of a flammable liquid storage cabinets provided there is adequate space in the
room after the installation of the flammable liquid storage cabinets required under conditions listed
above
The flammable liquid storage room must be maintained in full compliance with any other requirements
of NFPA 30 or any other applicable codes
If you have any questions regarding this variance please feel free to contact me
Sincerely
Arthur E Gil de Lamadrid
Lead Fire Inspector
Cc J Rigstad Fire Chief
V Johnson Battalion Chief
Superior Fire Department Phone (715) 394-0227
Fax (715) 394-0215
Jim Rigstad Fire Chief
Superior Fire Department
3326 Tower Av
Added by Carol Lindberg for documentation
From Gil de Lamadrid Arthur [mailtoarthurgcisuperiorwius] Sent Thursday February 23 2012 942 AM
To LindbergCarol A Subject RE Flam Cabs
Yes I believe that in your original request you asked for 10 cabinets Unfortunately I tossed my notes after writing the letter But I thought that the quantity was based upon that number of cabinets
From LindbergCarol A [mailtoCLindberuwsuperedu]
Sent Friday February 17 2012 1025 To Gil de Lamadrid Arthur
Subject RE Flam Cabs Art Yes ndash this is very good news One question ndash under the terms listed are we allowed to have more than 3 flammable liquid storage cabinets in the space Thank you Carol A Lindberg CIH Environmental Health and Safety Program University of Wisconsin - Superior
Section 6 Acknowledgements
This document was prepared and issued based on the recommendations and final review by the following
individuals This document will be included as a section of the next revision of the UW Superior
Chemical Hygiene Plan
Mary Balcer LSRI (Lake Superior Research Institute) and Department of Natural Sciences
Edward Burkett Department of Natural Sciences
James Lane Department of Natural Sciences
Carol Lindberg CIH Environmental Health and Safety
Lorena Rios Mendoza Department of Natural Sciences
Christine Polkinghorne LSRI
Deanna Regan LSRI
Kurt Schmude LSRI and Department of Natural Sciences
Jeffrey Schuldt Department of Natural Sciences
Matt TenEyck LSRI
Section 7 Resource
NFPA Classification of Common Flammable and Combustible Liquids and their Classification -
UW Superior
NFPA Classifications of Common Flammable and Combustible Liquids
UW Superior Environmental Health and Safety 2012
Class Example of Common Solvents and Chemicals
1A
Acetaldehyde
Butane
Diethyl Ether (Ethyl ether)
Ligroine
Methane (natural gas)
N-Pentane
Petroleum Ether
Propane
1B
Acetone
Aerosol cans
Acetonitrile
Benzene
Cyclohexane
Ethanol (Pure)
Ethanol aqueous solutions gt51 ethanol
Methanol aqueous solutions gt51 methanol
Isopropanol aqueous solutions gt
Ethyl acetate Gasoline
Heptane
Hexanes
Methanol
Isopropyl Alcohol
Toluene
Ligroin
1C
Butanol
Chlorobenzene
Ethanol aqueous solutions (20 - 50 ethanol)
Octane
Methanol-aqueous solutions (26-51 methanol)
Turpentine
Xylenes
Isoamyl alcohol
Isobutyl alcohol
2
Glacial Acetic Acid
Chlorocyclohexane
Ethanol-aqueous solutions 10-19 ethanol
Formalin solution 37 (15 methanol)
Diesel fuel
Motor oil
Kerosene
3A
Dimethyl Sulfoxide
Ethanol-aqueous solutions lt5 ethanol
Specimens in 10 formalin (15 methanol)
Methanol-aqueous solutions (05-8 methanol)
Some paints (oil)
Linseed oil
1-Octanol
16-Hexanediamine
3B
Benzyl Alcohol
Eugenol
Ethylene glycol
12-Propanediol
Triethylene Glycol
Mineral oil
Vegetable oil
None
Bromine
Bromoform
Chloroform
Carbon tetrachloride
Methylene Chloride
Perchloroethylene
Flammable and Combustible Liquid Classifications
Class 1A - Flash Point less than 73degF Boiling Point less than 100degF
Class 1B - Flash Point less than 73degF Boiling Point equal to or greater than 100degF
Class 1C - Flash Point equal to or greater than 73degF but less than 100degF
Class 2 - Flash Point equal to or greater than 100degF but less than 140degF
Class 3A - Flash Point equal to or greater than 140degF but less than 200degF
Class 3B - Flash Point equal to or greater than 200degF
Laboratory Storage of Compressed Gases
Common Compressed Gases
GasGas
Mixture
Flammable
Limits
in air
NFPA
Class
NFPA Rating
Scale is 0 ndash 4 (0=ordinary hazard 4= high hazard)
Health
Rating
Flammability
Rating
Instability
(Reactivity)
Rating
Special
Hazard(s)
Acetylene 25 ndash 82 1A 0 4 2 None
Air compressed Non-
flammable
0 0 0 None
Argon Non
flammable
0 0 0 None
Butane 16 ndash 84 1A 1 4 0 None
Helium Non
Flammable
0 0 0
Simple
Asphyxiant
Hydrogen 4 ndash 75 1A 0 4 0 None
Methane 5-15 1A 0 4 0 None
Nitrogen Non-
flammable
0 0 0
Simple
Asphyxiant
Nitrous Oxide Non-
flammable
2 0 0 Oxidizer
Oxygen Non-
flammable
0 0 0 Oxidizer
Propane 210-101 1A 1 4 0 None
P5 5 methane
+95 argon
Non-
flammable
1 0 0 None
Lecture bottles
Gases in lecture bottles must be stored in a continuously operating hood when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
The gas is pyrophoric
Cylinders
The number of gas cylinders larger than a lecture bottle in a laboratory should be limited to no more
than
One cylinder of each gas in use (connected to the equipment and secured) and
One cylinder in reserve (regulator removed capped and secured)
No more than 3 cylinders of flammable or oxidizing gases permitted in labs of 500 square feet
or less
Gases in cylinders larger than a lecture bottle must be stored in a continuously-vented approved gas
cabinet when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
Pyrophoric gases in cylinders larger than a lecture bottle must be stored in an approved
continuously-vented sprinklered gas cabinet
Section 8 Flammable Cabinet Inventory Records
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Permanently assigned to __________________________________________________________
Contents Description Volume amp
Units Date
Inventory of All Class IA Chemicals or Materials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Temporarily assigned to ________________________________ Dept ___________________
Agreed Upon Dates for Use From ____________________ To ___________________
Contents Description Volume amp
Units Date
Inventory of All Class IA ChemicalsMaterials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Section 9 Variance from Superior Fire Department
February 17 2012
Ms Carol Lindberg
University of Wisconsin Superior
1800 Grand Ave
Superior WI 54880
Dear Ms Lindberg
I have reviewed your request for a variance from the maximum allowed quantity of flammable liquids permitted
to be stored in the flammable storage room at Barstow Hall on the Superior campus of the University of
Wisconsin
Fire Chief Jim Rigstad has granted conditional approval to this variance The terms of the variance are as
follows
A maximum of 450 gallons of flammable liquids may be stored in the room at any given time
All flammable liquids stored in the room must be stored in UL listed flammable liquid storage cabinets
Cabinets constructed in compliance with the requirements of NFPA 30-953 shall also be acceptable
Non-compatible materials stored in the room must be separated as required by code
A containment sill must be installed in the doorway to prevent spilled product from escaping the room
The sill must be sealed with masonry or with a rated fire caulk to maintain the rating of the room
Other liquids stored in the room shall not exceed the quantities permitted by code and may only be
stored in the room outside of a flammable liquid storage cabinets provided there is adequate space in the
room after the installation of the flammable liquid storage cabinets required under conditions listed
above
The flammable liquid storage room must be maintained in full compliance with any other requirements
of NFPA 30 or any other applicable codes
If you have any questions regarding this variance please feel free to contact me
Sincerely
Arthur E Gil de Lamadrid
Lead Fire Inspector
Cc J Rigstad Fire Chief
V Johnson Battalion Chief
Superior Fire Department Phone (715) 394-0227
Fax (715) 394-0215
Jim Rigstad Fire Chief
Superior Fire Department
3326 Tower Av
Added by Carol Lindberg for documentation
From Gil de Lamadrid Arthur [mailtoarthurgcisuperiorwius] Sent Thursday February 23 2012 942 AM
To LindbergCarol A Subject RE Flam Cabs
Yes I believe that in your original request you asked for 10 cabinets Unfortunately I tossed my notes after writing the letter But I thought that the quantity was based upon that number of cabinets
From LindbergCarol A [mailtoCLindberuwsuperedu]
Sent Friday February 17 2012 1025 To Gil de Lamadrid Arthur
Subject RE Flam Cabs Art Yes ndash this is very good news One question ndash under the terms listed are we allowed to have more than 3 flammable liquid storage cabinets in the space Thank you Carol A Lindberg CIH Environmental Health and Safety Program University of Wisconsin - Superior
NFPA Classifications of Common Flammable and Combustible Liquids
UW Superior Environmental Health and Safety 2012
Class Example of Common Solvents and Chemicals
1A
Acetaldehyde
Butane
Diethyl Ether (Ethyl ether)
Ligroine
Methane (natural gas)
N-Pentane
Petroleum Ether
Propane
1B
Acetone
Aerosol cans
Acetonitrile
Benzene
Cyclohexane
Ethanol (Pure)
Ethanol aqueous solutions gt51 ethanol
Methanol aqueous solutions gt51 methanol
Isopropanol aqueous solutions gt
Ethyl acetate Gasoline
Heptane
Hexanes
Methanol
Isopropyl Alcohol
Toluene
Ligroin
1C
Butanol
Chlorobenzene
Ethanol aqueous solutions (20 - 50 ethanol)
Octane
Methanol-aqueous solutions (26-51 methanol)
Turpentine
Xylenes
Isoamyl alcohol
Isobutyl alcohol
2
Glacial Acetic Acid
Chlorocyclohexane
Ethanol-aqueous solutions 10-19 ethanol
Formalin solution 37 (15 methanol)
Diesel fuel
Motor oil
Kerosene
3A
Dimethyl Sulfoxide
Ethanol-aqueous solutions lt5 ethanol
Specimens in 10 formalin (15 methanol)
Methanol-aqueous solutions (05-8 methanol)
Some paints (oil)
Linseed oil
1-Octanol
16-Hexanediamine
3B
Benzyl Alcohol
Eugenol
Ethylene glycol
12-Propanediol
Triethylene Glycol
Mineral oil
Vegetable oil
None
Bromine
Bromoform
Chloroform
Carbon tetrachloride
Methylene Chloride
Perchloroethylene
Flammable and Combustible Liquid Classifications
Class 1A - Flash Point less than 73degF Boiling Point less than 100degF
Class 1B - Flash Point less than 73degF Boiling Point equal to or greater than 100degF
Class 1C - Flash Point equal to or greater than 73degF but less than 100degF
Class 2 - Flash Point equal to or greater than 100degF but less than 140degF
Class 3A - Flash Point equal to or greater than 140degF but less than 200degF
Class 3B - Flash Point equal to or greater than 200degF
Laboratory Storage of Compressed Gases
Common Compressed Gases
GasGas
Mixture
Flammable
Limits
in air
NFPA
Class
NFPA Rating
Scale is 0 ndash 4 (0=ordinary hazard 4= high hazard)
Health
Rating
Flammability
Rating
Instability
(Reactivity)
Rating
Special
Hazard(s)
Acetylene 25 ndash 82 1A 0 4 2 None
Air compressed Non-
flammable
0 0 0 None
Argon Non
flammable
0 0 0 None
Butane 16 ndash 84 1A 1 4 0 None
Helium Non
Flammable
0 0 0
Simple
Asphyxiant
Hydrogen 4 ndash 75 1A 0 4 0 None
Methane 5-15 1A 0 4 0 None
Nitrogen Non-
flammable
0 0 0
Simple
Asphyxiant
Nitrous Oxide Non-
flammable
2 0 0 Oxidizer
Oxygen Non-
flammable
0 0 0 Oxidizer
Propane 210-101 1A 1 4 0 None
P5 5 methane
+95 argon
Non-
flammable
1 0 0 None
Lecture bottles
Gases in lecture bottles must be stored in a continuously operating hood when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
The gas is pyrophoric
Cylinders
The number of gas cylinders larger than a lecture bottle in a laboratory should be limited to no more
than
One cylinder of each gas in use (connected to the equipment and secured) and
One cylinder in reserve (regulator removed capped and secured)
No more than 3 cylinders of flammable or oxidizing gases permitted in labs of 500 square feet
or less
Gases in cylinders larger than a lecture bottle must be stored in a continuously-vented approved gas
cabinet when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
Pyrophoric gases in cylinders larger than a lecture bottle must be stored in an approved
continuously-vented sprinklered gas cabinet
Section 8 Flammable Cabinet Inventory Records
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Permanently assigned to __________________________________________________________
Contents Description Volume amp
Units Date
Inventory of All Class IA Chemicals or Materials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Temporarily assigned to ________________________________ Dept ___________________
Agreed Upon Dates for Use From ____________________ To ___________________
Contents Description Volume amp
Units Date
Inventory of All Class IA ChemicalsMaterials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Section 9 Variance from Superior Fire Department
February 17 2012
Ms Carol Lindberg
University of Wisconsin Superior
1800 Grand Ave
Superior WI 54880
Dear Ms Lindberg
I have reviewed your request for a variance from the maximum allowed quantity of flammable liquids permitted
to be stored in the flammable storage room at Barstow Hall on the Superior campus of the University of
Wisconsin
Fire Chief Jim Rigstad has granted conditional approval to this variance The terms of the variance are as
follows
A maximum of 450 gallons of flammable liquids may be stored in the room at any given time
All flammable liquids stored in the room must be stored in UL listed flammable liquid storage cabinets
Cabinets constructed in compliance with the requirements of NFPA 30-953 shall also be acceptable
Non-compatible materials stored in the room must be separated as required by code
A containment sill must be installed in the doorway to prevent spilled product from escaping the room
The sill must be sealed with masonry or with a rated fire caulk to maintain the rating of the room
Other liquids stored in the room shall not exceed the quantities permitted by code and may only be
stored in the room outside of a flammable liquid storage cabinets provided there is adequate space in the
room after the installation of the flammable liquid storage cabinets required under conditions listed
above
The flammable liquid storage room must be maintained in full compliance with any other requirements
of NFPA 30 or any other applicable codes
If you have any questions regarding this variance please feel free to contact me
Sincerely
Arthur E Gil de Lamadrid
Lead Fire Inspector
Cc J Rigstad Fire Chief
V Johnson Battalion Chief
Superior Fire Department Phone (715) 394-0227
Fax (715) 394-0215
Jim Rigstad Fire Chief
Superior Fire Department
3326 Tower Av
Added by Carol Lindberg for documentation
From Gil de Lamadrid Arthur [mailtoarthurgcisuperiorwius] Sent Thursday February 23 2012 942 AM
To LindbergCarol A Subject RE Flam Cabs
Yes I believe that in your original request you asked for 10 cabinets Unfortunately I tossed my notes after writing the letter But I thought that the quantity was based upon that number of cabinets
From LindbergCarol A [mailtoCLindberuwsuperedu]
Sent Friday February 17 2012 1025 To Gil de Lamadrid Arthur
Subject RE Flam Cabs Art Yes ndash this is very good news One question ndash under the terms listed are we allowed to have more than 3 flammable liquid storage cabinets in the space Thank you Carol A Lindberg CIH Environmental Health and Safety Program University of Wisconsin - Superior
Laboratory Storage of Compressed Gases
Common Compressed Gases
GasGas
Mixture
Flammable
Limits
in air
NFPA
Class
NFPA Rating
Scale is 0 ndash 4 (0=ordinary hazard 4= high hazard)
Health
Rating
Flammability
Rating
Instability
(Reactivity)
Rating
Special
Hazard(s)
Acetylene 25 ndash 82 1A 0 4 2 None
Air compressed Non-
flammable
0 0 0 None
Argon Non
flammable
0 0 0 None
Butane 16 ndash 84 1A 1 4 0 None
Helium Non
Flammable
0 0 0
Simple
Asphyxiant
Hydrogen 4 ndash 75 1A 0 4 0 None
Methane 5-15 1A 0 4 0 None
Nitrogen Non-
flammable
0 0 0
Simple
Asphyxiant
Nitrous Oxide Non-
flammable
2 0 0 Oxidizer
Oxygen Non-
flammable
0 0 0 Oxidizer
Propane 210-101 1A 1 4 0 None
P5 5 methane
+95 argon
Non-
flammable
1 0 0 None
Lecture bottles
Gases in lecture bottles must be stored in a continuously operating hood when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
The gas is pyrophoric
Cylinders
The number of gas cylinders larger than a lecture bottle in a laboratory should be limited to no more
than
One cylinder of each gas in use (connected to the equipment and secured) and
One cylinder in reserve (regulator removed capped and secured)
No more than 3 cylinders of flammable or oxidizing gases permitted in labs of 500 square feet
or less
Gases in cylinders larger than a lecture bottle must be stored in a continuously-vented approved gas
cabinet when
The gas has a NFPA health hazard rating of 3 or 4
The gas has a NFPA health hazard rating of 2 and the gas does not have physiological warning
properties such as an odor
Pyrophoric gases in cylinders larger than a lecture bottle must be stored in an approved
continuously-vented sprinklered gas cabinet
Section 8 Flammable Cabinet Inventory Records
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Permanently assigned to __________________________________________________________
Contents Description Volume amp
Units Date
Inventory of All Class IA Chemicals or Materials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Temporarily assigned to ________________________________ Dept ___________________
Agreed Upon Dates for Use From ____________________ To ___________________
Contents Description Volume amp
Units Date
Inventory of All Class IA ChemicalsMaterials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Section 9 Variance from Superior Fire Department
February 17 2012
Ms Carol Lindberg
University of Wisconsin Superior
1800 Grand Ave
Superior WI 54880
Dear Ms Lindberg
I have reviewed your request for a variance from the maximum allowed quantity of flammable liquids permitted
to be stored in the flammable storage room at Barstow Hall on the Superior campus of the University of
Wisconsin
Fire Chief Jim Rigstad has granted conditional approval to this variance The terms of the variance are as
follows
A maximum of 450 gallons of flammable liquids may be stored in the room at any given time
All flammable liquids stored in the room must be stored in UL listed flammable liquid storage cabinets
Cabinets constructed in compliance with the requirements of NFPA 30-953 shall also be acceptable
Non-compatible materials stored in the room must be separated as required by code
A containment sill must be installed in the doorway to prevent spilled product from escaping the room
The sill must be sealed with masonry or with a rated fire caulk to maintain the rating of the room
Other liquids stored in the room shall not exceed the quantities permitted by code and may only be
stored in the room outside of a flammable liquid storage cabinets provided there is adequate space in the
room after the installation of the flammable liquid storage cabinets required under conditions listed
above
The flammable liquid storage room must be maintained in full compliance with any other requirements
of NFPA 30 or any other applicable codes
If you have any questions regarding this variance please feel free to contact me
Sincerely
Arthur E Gil de Lamadrid
Lead Fire Inspector
Cc J Rigstad Fire Chief
V Johnson Battalion Chief
Superior Fire Department Phone (715) 394-0227
Fax (715) 394-0215
Jim Rigstad Fire Chief
Superior Fire Department
3326 Tower Av
Added by Carol Lindberg for documentation
From Gil de Lamadrid Arthur [mailtoarthurgcisuperiorwius] Sent Thursday February 23 2012 942 AM
To LindbergCarol A Subject RE Flam Cabs
Yes I believe that in your original request you asked for 10 cabinets Unfortunately I tossed my notes after writing the letter But I thought that the quantity was based upon that number of cabinets
From LindbergCarol A [mailtoCLindberuwsuperedu]
Sent Friday February 17 2012 1025 To Gil de Lamadrid Arthur
Subject RE Flam Cabs Art Yes ndash this is very good news One question ndash under the terms listed are we allowed to have more than 3 flammable liquid storage cabinets in the space Thank you Carol A Lindberg CIH Environmental Health and Safety Program University of Wisconsin - Superior
Section 8 Flammable Cabinet Inventory Records
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Permanently assigned to __________________________________________________________
Contents Description Volume amp
Units Date
Inventory of All Class IA Chemicals or Materials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Temporarily assigned to ________________________________ Dept ___________________
Agreed Upon Dates for Use From ____________________ To ___________________
Contents Description Volume amp
Units Date
Inventory of All Class IA ChemicalsMaterials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Section 9 Variance from Superior Fire Department
February 17 2012
Ms Carol Lindberg
University of Wisconsin Superior
1800 Grand Ave
Superior WI 54880
Dear Ms Lindberg
I have reviewed your request for a variance from the maximum allowed quantity of flammable liquids permitted
to be stored in the flammable storage room at Barstow Hall on the Superior campus of the University of
Wisconsin
Fire Chief Jim Rigstad has granted conditional approval to this variance The terms of the variance are as
follows
A maximum of 450 gallons of flammable liquids may be stored in the room at any given time
All flammable liquids stored in the room must be stored in UL listed flammable liquid storage cabinets
Cabinets constructed in compliance with the requirements of NFPA 30-953 shall also be acceptable
Non-compatible materials stored in the room must be separated as required by code
A containment sill must be installed in the doorway to prevent spilled product from escaping the room
The sill must be sealed with masonry or with a rated fire caulk to maintain the rating of the room
Other liquids stored in the room shall not exceed the quantities permitted by code and may only be
stored in the room outside of a flammable liquid storage cabinets provided there is adequate space in the
room after the installation of the flammable liquid storage cabinets required under conditions listed
above
The flammable liquid storage room must be maintained in full compliance with any other requirements
of NFPA 30 or any other applicable codes
If you have any questions regarding this variance please feel free to contact me
Sincerely
Arthur E Gil de Lamadrid
Lead Fire Inspector
Cc J Rigstad Fire Chief
V Johnson Battalion Chief
Superior Fire Department Phone (715) 394-0227
Fax (715) 394-0215
Jim Rigstad Fire Chief
Superior Fire Department
3326 Tower Av
Added by Carol Lindberg for documentation
From Gil de Lamadrid Arthur [mailtoarthurgcisuperiorwius] Sent Thursday February 23 2012 942 AM
To LindbergCarol A Subject RE Flam Cabs
Yes I believe that in your original request you asked for 10 cabinets Unfortunately I tossed my notes after writing the letter But I thought that the quantity was based upon that number of cabinets
From LindbergCarol A [mailtoCLindberuwsuperedu]
Sent Friday February 17 2012 1025 To Gil de Lamadrid Arthur
Subject RE Flam Cabs Art Yes ndash this is very good news One question ndash under the terms listed are we allowed to have more than 3 flammable liquid storage cabinets in the space Thank you Carol A Lindberg CIH Environmental Health and Safety Program University of Wisconsin - Superior
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Permanently assigned to __________________________________________________________
Contents Description Volume amp
Units Date
Inventory of All Class IA Chemicals or Materials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Temporarily assigned to ________________________________ Dept ___________________
Agreed Upon Dates for Use From ____________________ To ___________________
Contents Description Volume amp
Units Date
Inventory of All Class IA ChemicalsMaterials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Section 9 Variance from Superior Fire Department
February 17 2012
Ms Carol Lindberg
University of Wisconsin Superior
1800 Grand Ave
Superior WI 54880
Dear Ms Lindberg
I have reviewed your request for a variance from the maximum allowed quantity of flammable liquids permitted
to be stored in the flammable storage room at Barstow Hall on the Superior campus of the University of
Wisconsin
Fire Chief Jim Rigstad has granted conditional approval to this variance The terms of the variance are as
follows
A maximum of 450 gallons of flammable liquids may be stored in the room at any given time
All flammable liquids stored in the room must be stored in UL listed flammable liquid storage cabinets
Cabinets constructed in compliance with the requirements of NFPA 30-953 shall also be acceptable
Non-compatible materials stored in the room must be separated as required by code
A containment sill must be installed in the doorway to prevent spilled product from escaping the room
The sill must be sealed with masonry or with a rated fire caulk to maintain the rating of the room
Other liquids stored in the room shall not exceed the quantities permitted by code and may only be
stored in the room outside of a flammable liquid storage cabinets provided there is adequate space in the
room after the installation of the flammable liquid storage cabinets required under conditions listed
above
The flammable liquid storage room must be maintained in full compliance with any other requirements
of NFPA 30 or any other applicable codes
If you have any questions regarding this variance please feel free to contact me
Sincerely
Arthur E Gil de Lamadrid
Lead Fire Inspector
Cc J Rigstad Fire Chief
V Johnson Battalion Chief
Superior Fire Department Phone (715) 394-0227
Fax (715) 394-0215
Jim Rigstad Fire Chief
Superior Fire Department
3326 Tower Av
Added by Carol Lindberg for documentation
From Gil de Lamadrid Arthur [mailtoarthurgcisuperiorwius] Sent Thursday February 23 2012 942 AM
To LindbergCarol A Subject RE Flam Cabs
Yes I believe that in your original request you asked for 10 cabinets Unfortunately I tossed my notes after writing the letter But I thought that the quantity was based upon that number of cabinets
From LindbergCarol A [mailtoCLindberuwsuperedu]
Sent Friday February 17 2012 1025 To Gil de Lamadrid Arthur
Subject RE Flam Cabs Art Yes ndash this is very good news One question ndash under the terms listed are we allowed to have more than 3 flammable liquid storage cabinets in the space Thank you Carol A Lindberg CIH Environmental Health and Safety Program University of Wisconsin - Superior
Flammable Liquid Storage Cabinet FLC - ___________________
Maximum Permitted Storage Capacity 60 gallons of combined Class I and Class II combustible and
flammable liquids
Temporarily assigned to ________________________________ Dept ___________________
Agreed Upon Dates for Use From ____________________ To ___________________
Contents Description Volume amp
Units Date
Inventory of All Class IA ChemicalsMaterials in Cabinet
The Flammable Liquid Storage Room is limited to 60 Gallons total quantity of Class IA liquids
Class IA Chemical Name or description Volume amp
Units Date
Section 9 Variance from Superior Fire Department
February 17 2012
Ms Carol Lindberg
University of Wisconsin Superior
1800 Grand Ave
Superior WI 54880
Dear Ms Lindberg
I have reviewed your request for a variance from the maximum allowed quantity of flammable liquids permitted
to be stored in the flammable storage room at Barstow Hall on the Superior campus of the University of
Wisconsin
Fire Chief Jim Rigstad has granted conditional approval to this variance The terms of the variance are as
follows
A maximum of 450 gallons of flammable liquids may be stored in the room at any given time
All flammable liquids stored in the room must be stored in UL listed flammable liquid storage cabinets
Cabinets constructed in compliance with the requirements of NFPA 30-953 shall also be acceptable
Non-compatible materials stored in the room must be separated as required by code
A containment sill must be installed in the doorway to prevent spilled product from escaping the room
The sill must be sealed with masonry or with a rated fire caulk to maintain the rating of the room
Other liquids stored in the room shall not exceed the quantities permitted by code and may only be
stored in the room outside of a flammable liquid storage cabinets provided there is adequate space in the
room after the installation of the flammable liquid storage cabinets required under conditions listed
above
The flammable liquid storage room must be maintained in full compliance with any other requirements
of NFPA 30 or any other applicable codes
If you have any questions regarding this variance please feel free to contact me
Sincerely
Arthur E Gil de Lamadrid
Lead Fire Inspector
Cc J Rigstad Fire Chief
V Johnson Battalion Chief
Superior Fire Department Phone (715) 394-0227
Fax (715) 394-0215
Jim Rigstad Fire Chief
Superior Fire Department
3326 Tower Av
Added by Carol Lindberg for documentation
From Gil de Lamadrid Arthur [mailtoarthurgcisuperiorwius] Sent Thursday February 23 2012 942 AM
To LindbergCarol A Subject RE Flam Cabs
Yes I believe that in your original request you asked for 10 cabinets Unfortunately I tossed my notes after writing the letter But I thought that the quantity was based upon that number of cabinets
From LindbergCarol A [mailtoCLindberuwsuperedu]
Sent Friday February 17 2012 1025 To Gil de Lamadrid Arthur
Subject RE Flam Cabs Art Yes ndash this is very good news One question ndash under the terms listed are we allowed to have more than 3 flammable liquid storage cabinets in the space Thank you Carol A Lindberg CIH Environmental Health and Safety Program University of Wisconsin - Superior
Section 9 Variance from Superior Fire Department
February 17 2012
Ms Carol Lindberg
University of Wisconsin Superior
1800 Grand Ave
Superior WI 54880
Dear Ms Lindberg
I have reviewed your request for a variance from the maximum allowed quantity of flammable liquids permitted
to be stored in the flammable storage room at Barstow Hall on the Superior campus of the University of
Wisconsin
Fire Chief Jim Rigstad has granted conditional approval to this variance The terms of the variance are as
follows
A maximum of 450 gallons of flammable liquids may be stored in the room at any given time
All flammable liquids stored in the room must be stored in UL listed flammable liquid storage cabinets
Cabinets constructed in compliance with the requirements of NFPA 30-953 shall also be acceptable
Non-compatible materials stored in the room must be separated as required by code
A containment sill must be installed in the doorway to prevent spilled product from escaping the room
The sill must be sealed with masonry or with a rated fire caulk to maintain the rating of the room
Other liquids stored in the room shall not exceed the quantities permitted by code and may only be
stored in the room outside of a flammable liquid storage cabinets provided there is adequate space in the
room after the installation of the flammable liquid storage cabinets required under conditions listed
above
The flammable liquid storage room must be maintained in full compliance with any other requirements
of NFPA 30 or any other applicable codes
If you have any questions regarding this variance please feel free to contact me
Sincerely
Arthur E Gil de Lamadrid
Lead Fire Inspector
Cc J Rigstad Fire Chief
V Johnson Battalion Chief
Superior Fire Department Phone (715) 394-0227
Fax (715) 394-0215
Jim Rigstad Fire Chief
Superior Fire Department
3326 Tower Av
Added by Carol Lindberg for documentation
From Gil de Lamadrid Arthur [mailtoarthurgcisuperiorwius] Sent Thursday February 23 2012 942 AM
To LindbergCarol A Subject RE Flam Cabs
Yes I believe that in your original request you asked for 10 cabinets Unfortunately I tossed my notes after writing the letter But I thought that the quantity was based upon that number of cabinets
From LindbergCarol A [mailtoCLindberuwsuperedu]
Sent Friday February 17 2012 1025 To Gil de Lamadrid Arthur
Subject RE Flam Cabs Art Yes ndash this is very good news One question ndash under the terms listed are we allowed to have more than 3 flammable liquid storage cabinets in the space Thank you Carol A Lindberg CIH Environmental Health and Safety Program University of Wisconsin - Superior
Added by Carol Lindberg for documentation
From Gil de Lamadrid Arthur [mailtoarthurgcisuperiorwius] Sent Thursday February 23 2012 942 AM
To LindbergCarol A Subject RE Flam Cabs
Yes I believe that in your original request you asked for 10 cabinets Unfortunately I tossed my notes after writing the letter But I thought that the quantity was based upon that number of cabinets
From LindbergCarol A [mailtoCLindberuwsuperedu]
Sent Friday February 17 2012 1025 To Gil de Lamadrid Arthur
Subject RE Flam Cabs Art Yes ndash this is very good news One question ndash under the terms listed are we allowed to have more than 3 flammable liquid storage cabinets in the space Thank you Carol A Lindberg CIH Environmental Health and Safety Program University of Wisconsin - Superior