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v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals....

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v^_ _ INTKMNATIONAL EXPl-OJIATtON. INC, 577 SACKcrrcrcMto *OAB WAMMIMSTEJI. PA 1M74-1MM (21*) M*.?l*7 MONITOR WELL SAMPLING DATA LOCATION:_____Tonolli Corp., Nescruehoning, PA WELL #: Stream Station #1 South Bank DATE SAMPLED: 7/16/84 TOTAL DEPTH: N/A WATER LEVEL (BTC) : N/A Stream height at bridge 5.95' below rail VOLUME OF WATER PER FOOT: TOTAL VOLUME OF WATER: PUMP TYPE: PUMP SETTING: "?VTE OF FLOW: TIME PUMP ON: TIME SAMPLED: WATER LEVEL WHEN SAMPLED: N/A N/A N/A N/A N/A N/A 10:00 AM N/A VOLUME OF WATER REMOVED PRIOR TO SAMPLING: N/A " AMPLE : 4 - COLOR: - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED: Clear - some bits of organic? debris ^ None 26° C 43 micromhos/cm 5.5 Plastic: (2) Field filtered & oreserv^d (2) unpreserved (2) Glass bottles (2) Bacteria TO BE TESTED FOR: Semi-annual & crroundwater contami nat-ion n^r-^mpff DELIVERED TO: DATE/TIME : ASW Laboratories (215) 434-1870 7/17/84 4:00 PM
Transcript
Page 1: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

v^_ _INTKMNATIONAL EXPl-OJIATtON. INC,

577 SACKcrrcrcMto *OABWAMMIMSTEJI. PA 1M74-1MM

(21*) M*.?l*7

MONITOR WELL SAMPLING DATA

LOCATION:_____Tonolli Corp., Nescruehoning, PAWELL #: Stream Station #1 South Bank

DATE SAMPLED: 7/16/84

TOTAL DEPTH: N/AWATER LEVEL (BTC) : N/A Stream height at bridge 5.95' below rail

VOLUME OF WATER PER FOOT:TOTAL VOLUME OF WATER:

PUMP TYPE:PUMP SETTING:"?VTE OF FLOW:

TIME PUMP ON:TIME SAMPLED:WATER LEVEL WHEN SAMPLED:

N/AN/A

N/AN/AN/A

N/A10:00 AMN/A

VOLUME OF WATER REMOVEDPRIOR TO SAMPLING: N/A

" AMPLE : 4- COLOR:- ODOR:- TEMPERATURE:- CONDUCTIVITY:- pH:

SAMPLES COLLECTED:

Clear - some bits of organic? debris ^None26° C43 micromhos/cm5.5

Plastic: (2) Field filtered & oreserv^d(2) unpreserved(2) Glass bottles(2) Bacteria

TO BE TESTED FOR: Semi-annual & crroundwater contami nat-ion n^r-^mpff

DELIVERED TO:DATE/TIME :

ASW Laboratories (215) 434-18707/17/84 4:00 PM

Page 2: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

INTERNATIONAL. EXPLORATION. INC.•77 *ACKKTT»rCMU> ROAD

WAMUMTK*. PA l*»74-l»*«

MONITOR WELL SAMPLING DATA

LOCATION:_____Tonolli Corp., Nesouehonina. PAWELL #: Steam Station #2

DATE SAMPLED: 7/16/84

TOTAL DEPTH: N/AWATER LEVEL (BTC) : =^QR< t

VOLUME OF WATER PER FOOT:TOTAL VOLUME OF WATER:

PUMP TYPE:rrTMP SETTING:1. PE OF FLOW:

TIME PUMP ON:TIME 'SAMPLED:WATER LEVEL WHEN SAMPLED:

3 HTT Cf*3

NT /ANT/A

N/AN/ANT/A -

N/A10:30 A.M.N/A

VOLUME OF WATER REMOVEDPRIOR TO SAMPLING: N/A

AlPLE:^ - COLOR:

- ODOR:- TEMPERATURE:- CONDUCTIVITY:- pH:

SAMPLES COLLECTED:

ClearNone25° C155 micromhos/cm4.1

Plastic : (2) Field filtered & ores^rvpdr (2) Unoreserved

(2) Glass bottles(2) Bacteria

TO BE TESTED FOR: Semi— annual & aroundwa her con t- ami na f-i on nar^mpt-pi

DELIVERED TO:DATE/TIME :

ASW Laboratories (215) 434-18707/17/84 4:00 P.M.

101065

Page 3: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

INTERNATIONAL. £XF(.ORATION, INC.•77 «ACKerr•*<>«£> ROAD

PA I«e74-llO«Ul*> BM-7197

MONITOR WELL SAMPLING DATA

LOCATION: Tonolli Corp.. Nesuehoni n PAWELL #: Monitorincr Well #2

DATE SAMPLED: 7/16/84

TOTAL DEPTH: 42.6 fWATER LEVEL (BTC): Ifi.TS-

VOLUME OF WATER PER FOOT:TOTAL VOLUME OF WATER:

PUMP TYPE:~TJMP SETTING:iTE OF FLOW:

TIME PUMP ON:TIME SAMPLED:WATER LEVEL WHEN SAMPLED:

1.47 gals.38.59 gals.

Submersible37' BTC12 gpm

4:32 P.M.4:44 P.M.17. 31

VOLUME OF WATER REMOVEDPRIOR TO SAMPLING: 144 gals.

AMPLE: •- COLOR: Bright- ODOR:- TEMPERATURE:- CONDUCTIVITY:- pH:

SAMPLES COLLECTED:

brown (rust color) initially, chanaed to liaht 5!None19° C220 rnicromhos/cm3.6

Plastic : (2) Field filtered & nreservpd(2) Unoreserved(2). Glass bottles(2) Bacteria

TO BE TESTED FOR: Semi-annual & qroundwater contamination parameters

DELIVERED TO:DATE/TIME :

ASW Laboratories7/17/84 4:00 P

(215).M.

434-1870

1^101066

Page 4: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

INTERNATIONAL EXPLORATION. Inc.077 ftACKKTTVO*0 ffOAD

WAJM*JM*TK«. *A 1*074-1 >*•

MONITOR WELL SAMPLING DATA

LOCATION;__________Tonolli Corp. , Nesguehoning, PA.________________WELL i; Monitoring Well #3

DATE SAMPLED:________7/16/84__________________________________________

TOTAL DEPTH:_________47. 25 !___________________________________WATER LEVEL (BTC); 15.8'_____________________________________________

VOLUME OF WATER PER FOOT: 1.47 gals._________________;_______________TOTAL VOLUME OF WATER:______46.23 gals.________________________________

PUMP TYPE;_________________Submersible_______________________________PUMP SETTING;_______________^2J________________________________________IATE OF FLOW:_______________1Q crpm_____:__________________:_____________

TIME PUMP ON:_________________2:46 P.M.______________________________________TIME SAMPLED: ___________3:00 P.M.__________________________________WATER LEVEL WHEN SAMPLED: NR f<42' BTC)_______________________________VOLUME OF WATER REMOVED________________________________________________PRIOR TO SAMPLING: _______140 gals._________

f AMPLE:_______________________________________________________________________- COLOR:______________C^ear___________________________________________" ODOR:_______________None_____________________________________________- TEMPERATURE:________igQ c______________________________________

- CONDUCTIVITY:_______4900 micromhos/cm_______________________________- PH;_________________2.7________________________________________

SAMPLES COLLECTED:__________Plastic: (2) Field filtered & preserved_____________________(2) Unpreserved______________________.____

_________________________(2) Glass bottles________________________________________________(2) Bacteria____________________________

TO BE TESTED FOR: Semi-annual & groundwater contamination parameters

DELIVERED TO;_______________R^W L^oratorip^ (215) 434-1870DATE/TIME: 7/17/84 4:00 P^M_ "~~_"

10

Page 5: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

INTERNATIONAL EXPLORATION, INC.•77 SACK KIT**one ROAD

WAMMINBTK*. *U<«) SM-7137

MONITOR WELL SAMPLING DATA

LOCATION;___________Tonolli Corp., Nesquehoning, PAWELL *: Monitoring Well #4

DATE SAMPLED: 7/17/84

TOTAL DEPTH : 21.55'WATER LEVEL (BTC) : 9 . 5 '

VOLUME OP WATER PER FOOT:TOTAL VOLUME OF WATER:

PUMP TYPE:P"MP SETTING:; ?E OF FLOW:

TIME PUMP ON:TIME SAMPLED:WATER LEVEL WHEN SAMPLED:

1.47 crals.17.71 aals.

Submersible19 ! BTC2 gpm for 5-min. then 1 crprn fo'r 45 min.

12:10 P.M.1:00 P.M.NR (<19 BTC)

VOLUME OF WATER REMOVEDPRIOR TO SAMPLING: 55 aals.

MPLE:- COLOR:- ODOR:- TEMPERATURE:- CONDUCTIVITY:- pH:

SAMPLES COLLECTED:

Cloudy .Nonp22° C365 micromhos/cm3. 4

Plastic: (2) Field filtered & preserved(2) Unpreserved(2) Glass bottles(2) 'Bacteria

TO BE TESTED FOR: s^mi-annual & aroundwater contamination parameters

DELIVERED TO:DATE/TIME:

ASW Laboratories (215) 434-18707/17/84 4:00 P.M.

ARiOi068

Page 6: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

INTERNATIONAL EXPLORATION. INC.• 77 »ACK.«TTirO*O KOAB

WAJM**N«TM. PA IO074-IJMM*

MONITOR WELL SAMPLING DATA

L O C A T I O N : T o n o l l i Corp., Nesuehonin. PAWELL is Monitoring W^13 £fi

DATE SAMPLED: 7/17/84

TOTAL DEPTH: 51'WATER LEVEL (BTC) : 23*

VOLUME OF WATER PER FOOT:TOTAL VOLUME OF WATER:

PUMP TYPE:PUMP SETTING:/ TE'OF PLOW:

TIME PUMP ON:TIME SAMPLED:WATER LEVEL WHEN SAMPLED:

1.47 gals.41.16 aals.

Submersible18 r BTC10 qpm

9:35 A.M.9: 48 A.M.NR (<18* BTC}

VOLUME OF WATER REMOVEDPRIOR TO SAMPLING:

•MPLE:- COLOR:

• - ODOR:- TEMPERATURE:- CONDUCTIVITY:

130 gals.

ClearNone220 c840 micromhos/cm

- pH:

SAMPLES COLLECTED: Plastic: (2) Field filtered & preserved(2) Unpreserved(2) Glass bottles(2) Bacteria

TO BE TESTED FOR: Semi-annual & crroundwater contamination paramo t-.e:

DELIVERED TO:DATE/TIME:

ASW Laboratories (23^1 434-18707/17/84 4:00 P.M.

Page 7: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

INTERNATIONAL EXPLORATION. INC,877 *ACKcrrvQao HOAO

WAMUN*TM.Ul*J

MONITOR WELL SAMPLING DATA

LOCATION:____________Tonolli Corp., Nesquehoni ny . PA______________________WELL §; Monitoring W^ll ft?___________________________________

DATE SAMPLED;________7/16/84______________________________________________

TOTAL DEPTH;_________63.0'_______________________________________________WATER LEVEL (BTC): 4?.fi' BTP______________________________________________

VOLUME OF WATER PER FOOT; (63-52) - 65 oals. = 7.15 aals. fS2-42.fi] -1.47 g^lg = i CDTOTAL VOLUME OF WATER;______13.82 + 7.15 = 20.Q7 gals.______________________

PUMP TYPE:_________________Submersible___________________________________PUMP SETTING;_______________62J___________________________________________

l .TE OF FLOW;_______________2 gpm______:_________________I________________

TIME PUMP ON:_______________10:36-10:41 P 2 ypm - in•41-11•35 fl 1 gpm_______TIME SAMPLED:_________________11: 35 A.M.__________________________________________WATER LEVEL WHEN SAMPLED: 57'_____________________________________________VOLUME OF WATER REMOVED_____________________________________________________PRIOR TO SAMPLING:__________66 gals._____________________________________

\MPLE:_______________________________________________- COLOR:______________Orancre-brown_______________" ODOR:_________:______NonQ_______________-______- TEMPERATURE:________23Q C______________________-CONDUCTIVITY:________695 mi crnmhos /cm______

- PH:_________________3.Q___________________

SAMPLES COLLECTED:__________Plastiic: (2^ F-J^ld f-i 1(2)(2) Glass hnt-.t.l s(2) Bacteria.

TO BE TESTED FOR:

DELIVERED TO: ASW Lahnrat-.nri'DATE/TIME; 7/17/84 4 ;fin P.M

Page 8: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

INTERNATIONAL. EXPLORATION. INC.977 SAGKCTTVOIU) HOAD

PA

MONITOR WELL SAMPLING DATA

LOCATION;___________Tonolli Corp. , Nesq'uehoningf PA_____________________WELL |: Monitoring Well #8 ""

DATE SAMPLED;________7/16/84__________________________

TOTAL DEPTH:_________49. 20 '______________________________________________'WATER LEVEL (BTC) ; 33.12'_________________________________________________

VOLUME OF WATER PER FOOT: .65 gals. (49.2 - 47.0) 4- 1.47 -gals. (47.0-33.12)TOTAL VOLUME OF WATER;______21.83 gals._____________________________________

PUMP TYPE;_________________Submersible____________________________________PUMP SETTING:_______________44 '____________________

t TE OF FLOW:______________5 qpm_______________________;_________________

TIME PUMP ON:_________________l';21 P.M.___________________________________________TIME SAMPLED:_________________1: 34-1: 45 P.M._____________________________________WATER LEVEL WHEN SAMPLED: 39.25'______________________________________________VOLUME OF WATER REMOVED______________________________________PRIOR TO SAMPLING:__________65 gals.,_______________________________________

^__________________________________________________________- COLOR:____________Dark black/brown to It. black/brown___________- ODOR;______________Slight sulfur_________________________________- TEMPERATURE; 27° C- CONDUCTIVITY:_______360 micrpmhps/cm_______________________________

______- pH;________________4. 5___________________________________________

SAMPLES COLLECTED:__________Plastic: (2) Field filtered & preserved______, ________________________( 2) Unpreserved______________________________________________________(2) Glass bottles________________________:_____

___________________________(2) Bacteria__________________________________

TO BE TESTED FOR:_________ Semi-annual & groundwat.er contamination parameters

DELIVERED TO:______________ASW Laboratories (215) 434-1870D A T E / T I M E : 7 / 1 7 / 8 4 4•00 P.M.

Page 9: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

INTERNATIONAL EXPLORATION. INC.B77 SACKCTTBTOKD MOAO

WAHMINCTER, PA 16874-1304(216) Odft-7137

MONITOR WELL SAMPLING DATA

LOCATION; _________ Tonolli Corp. , Nesauehonina, PAWELL t; Monitoring Well »9

DATE' SAMPLED: _______ 7/17/84

TOTAL DEPTH: ________ 1Q . 35 'WATER LEVEL (BTC): 9.121

VOLUME OF WATER PER FOOTSTOTAL VOLUME OF WATER:

PUMP TYPE; __________ Bailed _____________________________"•MP SETTING; _______ N/fi

'. .iTE OF FLOW: _______ Bailed @ 12:pp P.M. on 7/16/84 removing 4 gals

TIME PUMP ON:TIME SAMPLED: 7/17/84 .& 10:30 A.M.WATER LEVEL WHEN SAMPLEDVOLUME OF WATER REMOVEDPRIOR TO SAMPLING; _________ 4 aals. on 7/16/84

iMPLE~ COLOR: Arnber to dark brown as aitated- ODOR: _______ None- TEMPERATURE: _______ 2 1Q C- CONDUCTIVITY: <l Q O O O micromhos/cm- PH: ________________ 6.

SAMPLES COLLECTED: _________ Plastic: (2) Field filtered R________________________ ( 2 ) Unpreserved _____________________________ ..

_____________________ i _____ (2) 'Glass bottles __________________________________________________ C2) Bacteria ___________ ~ ____________________ _

TO BE TESTED FOR: __________ Semi — annual & groundwa ter contamination parameters

DELIVERED TO:DATE/TIME :

ASW Laboratories (215)7/17/84 4:00 P.M.

434-1870

Page 10: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

O•zOEH

SRI 01073

Page 11: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

I

Page 12: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

tc 3E-( ro « t, o

(J < oo 4J 0) ,-)X C 4J rH

M in O U4 0H CM £ < <wM \ 01 T3>« i - I H Q J O^ a • >.c< W'tomo-uZ O nj o u< -u ai . a a)n) E o E >J a v —i IB< •-< v tPu ai —t -a cM . M a; a) nj aiE a M 3M E M (u n o1EC nj eo -P eo -HU . « X W -x C •

co •-* co £ n)U X D»X U -wO o CJ o iJ rat, rH U JJ T3

(mdd)

6RIOI075'

Page 13: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:
Page 14: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

(uidd)

01077

Page 15: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

og

<3

(qdd)

MU01078

Page 16: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

E-t<

Xo

(qdd>

&B10IQ79

Page 17: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

(uidd)

ARID

Page 18: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

X "u* 28 19848/29/84 v ' • i. ~, v ... *••• r -. .<i,.. . ^. it^ao^rc-tii j PiA D|0 '7!3j 6/lt 3J6}6 ;3

v ; one year for #11 rooni taring Wi*lls

facility Permit Nixniuer

Municioality ____ Nesquehoning

•nitoiing Wall rto. * itryyi Check onat uo do«--n X gradient—— — *t-o rt^itar Level. N/A_£'t. Measured from: land surface __ to-> of casing ___ _ _

; •; Dv 3ti._, N/A: '« . i« j.evotion or land surface ____ ft* or- to-* of casing ____ fc.

- >dtft.-ii.»^o •<-i'i^'-- cine) ;3Uino__b^J l^»r_^, Wua the well ourged? Yea __ No __

., *.<>$ Wall ','.".c..i. it.n: Lcat J fcttdi:4Q..* 50 . J58_J'1* J-ongitude 75^^53^ Ol j'w

tfu.M'* Coli-.-c.i.--i _.^_._. Time of Sampling ___ 10:00 A.M. ____7/X7/M* ———— " ————————————————Collector A l-j.^.e ,_I f_T E.X _......

.::A; ';£hS .. ri'.- ,"i ..... x ,i:-J :".u ; i'.> -1 /- * 'i'V AS rali^K-iKG WATEU SUPPLY

. ___ t _ ug/L

______ ug/L

; ..2.1 .„...-",; u / . 4 i> ili^VJO). ______ _4 __ . _____ ug/L

,155 ,i, ;. ' 4, ;,-TV» SiWox (. ;ia/ <1 uq/L

rcury '//ryoo^.^ <Q.J... .* -.....••*#« A •- -t., t )._. . 0.* ___ . __ pCl/l

'.-.«-..<•• ..jfl it; (•!•';•'• ./; Wfi ^v - 'j^r/s.-i U'-c:»j ( > ...... 1»4, * P-J milliyr

; n.L-.,i« 'Oi.lo7> . _ <J >„ '.\ i.btdi;./ (00076)._ __ „_,!_ _______ TU

-Jol tfor-i. t^ ;terii ( ) ^> >OP per100 ml

Page 19: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

8/29/84 » ; h ^ - .- ,..;.;, W,J,Ji •* ?*"" = --' • -* /—.-i. -j_i._,i__;.—™

l.Dr Numhar'U -j.AJ'i'ft MOUXTOaiWG

(ri*o *oe submitted carterly for one year)

cxlity NamaifSp^4lXi CoypQgl itlil____ Monitoring Well Number

cilifcy Number______ __.......__._

v'A'i'EH

Ion-id.* £00940) _ __L__ _ .. mg/L Aaditiondl Parameters if raouired«

on (vototl) (01045) jO.jfj ___ ,i"g/r/ Antimony ( ) _____ <Q.Q 1 ___ mg/L

, Coooer ( ) 0»Q2 mg/L

(32730) <100 ug/1. ainc ( ) j,»4 mg/L

d ii (OG929) ___ 1,6 rag/1.. Bicarbonate ( : ) j_________ mg/L

I i«Le (CJOS45) _ 7 my, i OiL/Grease ( j ) ____Q.j_______ mg/L

,»- PAK--\METEUi> tJSi'J3 AS XiJOXCA'/OR£> F GRO*JKD WATEit ^OiJTTAMXKATlON

R:^lic.«ttes (must 1 ** done for upgrddiant wellsoaly)|

— t •i f ic Coiidot. i »j«r : :0005) <rr j -?:<•- :dnos) 4J, _ _L Organic C' ro;-.:. v ; aicj/ t 1*1J Or jdn ic iic, io - -j , I ) iu.: /i,

Chc-.;*k OP.^J .• '_':. - . .r ' ,-r Jo;7 or ^, Atomic Absc-rotion

«ji:d ?>t..'v*r'/is3or o..: t«i> »r..rtory Performing Chemical'

1701 Unxon ii^vite vAllentovTi, vr- l

P. Dough cjcty

ftRlOI082

Page 20: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

.._ ,.Resources pAiDo(7 3/6ADo|7 36 ; iafe 6 • 3!

J...L L !..{,(__{ | j L J

-kOi'-WD l^KPOKVOc r-e yiuL.. v /,*.'-'- tn; ,»•/ 1« rly j,>^ one yaav for ^-11 monitoring wells)

UA .fiMVfm&M Facility Permit Member ______

c-a: County _ Carbon „ _ Municipality ____Nesquehoni ng

'/•in9* well JNo. _JMlW >!§•% Check oner uo__dot-ti^X gradient

:n to Water ksv*el__j^/£_ft. Measured from: land surface__to? of

Oeoth . .&/&-*"'* . Elevation of litnd siurface, ___ ft. or too of casing, ____ ft-

:..vu.-jlintj <f l~.*,-<i' ••.n«s) ouino _ bji lerv . . Waa the well surged? Vas __ Mo __

t.r.t ; -,g We]l L-..c.s: ,!.•<. l> t i tude 4,0 ° _SlL JIZ.81 Longitude jLS.? J=£.\ .il.J'W

.'.-. .; i<v Co ii •-•!/;» ' ......f/lZ/M -. i'* '<* of Sampling i p • n fi . , _____________

io Cr/iiecior.^ n,-:. • .._.IMIEX.«. -

CJMi^V'i.vitlX.tWiJ .•jU.ClV.iilLl'TY AS I>UINKING WATJBB SUPPLY

• ;/OOV) 10 .- • syihOA/chiot (i 30f* ^ 0»1 __ ug/L. . . . . • .-...- — — .-• ——— .. ——

; ('i *1CO> _ .. _ .jtf..l. ______ ug/L

J1

l.f Qa§ ____ millircm,'. ' yr1 TU

4?. 100 ml

Page 21: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

P D p j J 361 3 jj5j[6J1-jE>" ' ""xOUi WAd'M liOiaTOJEUNG

j rjAC'KGROUtil) KETPORTfVo be submitted quarterly for one year)

XT-. ™.. -jQ jii ] | flfljy r -L-M|____ Monitoring Well Numb

iiumber,_____........__,,„._____

t. PARAMETERS BSTA6LX3H1NG GAOWD WAT3R QUALITY

(00940) _ _ _ • _ ^ tng/L AdditLondl Parameters if recuiredi

L) (O10'ii>) __n>M _ mg/L Anbimony ( ) ______9t9$*_____m^/L

(01054) <i,_LT _ mg/i. Cower ( ) _______Q«04_______ mg/L

J2730)

-IB (00929) 1_l mg/L Bicarbonate ( ) j mg/L

at« (0094'j) ray/i* Oil/Gr&ase ( )

11, PAftAMETBRii Y.SKO y\J .NDl.CA'l-OxiS OP GEOCWD WATER CQNTAMXHiATXON

(must be done for upgradient walla

Orgdnic Carbc: ( ) auj/l 14Organic Halcr-^- ^ ) a*g/L

r Meuula Chock G/, ..- J.. r i... -*•.,*-.r ;x,;.ho ___ or ?. Atomic Absorption

address ...r. ;jt;n >r/7 >T>r 01: L«bo;r,itory Performing Chemical Analysiss

A^W Knviron^ -.;• • i f'.\-M,Tu'.t:*'iUL.G(. .nnc.1701 Onicn) roul-'.-v^jL ,J

tGVi'i, ±'*' .Lwi-)J

P, l;out;i: .-i t /

ftHIOI08<f

Page 22: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

f i';i -V ;• •• •• - - . - _ , ..,

8/29/84 ' ' " I '•••••••* -'c*-'t/-* r-rv.;.^i,,«Titdi Resource* £JAJD~lo F7J3| el.£/_r/.° :. ... ,.. i *» xei-.a OJT c;o.->u "tfjsl.e Management i I | r [ L J j

L=J P ..>t., udw/t- it' >40NitiO

(To Jhf« Ea^r,i5it^d oo^rtetiy ^r ons yeor for all monitoring w^lls)

topolli COtyMriti lt Facility Permit Number

Cou;ity _ Carbon _ Municipality ____ Nesguehpningl~B+tii* MMt4B

>itc/?ing WeJi No. ftrii>Mp% I f»<MI Check one* uo __ dot-n at gradient

>th to Water Ljevel J-,6_ >ft. Measured from: land surface __ too of casing x

IiS CriAii^C^iK^^tlifi i;O I i'AB ;.i J.TY AS DUINKISG WATEJR

_>vk ^y .- :. Hethoxychlor

JT. •; 0 i 0V / ; ,_ _ _ __ „*•<.*. •- T'oxtiphene (39400) _ . __

ug/L

oy i<-:.- (0095 i j__ , ....*** ........ wr?- J^ ^ » A 5* TP S il vex ( 3'H740)_ _< __ ug/L

fi 'V<5U_... .. *.. ...-' .^iv^n ( aa« ) l.» * 0-43 ______ pCi/1

cury {71900},, . , <*•*.. .. ^-J ' i- Tjr -fl A'iohrt ( > CQ.a _______ pCi/1

-w^37 t*i . Elevation of Icind surface __ ._ft* or ±01 of casingj _ _ __ fc.

^^J (*.rhtr /.•;.. on A} oomoX^bttiler _ . Wus the well ourged? Yes x No __ .

.o,-.4ig Well /,*c;c,-- 1cm; LdM tu.3e40 ° _51^ _02_"^ Longitude 2J J> ,52.' r51tr"W

un;-»!e Colljct..-! 7/17/M Yxme of Sampling 4:44 P.M. _______________

e Collectors M .:,-

rate {<in as; J'JOt. ,.'..<, ?W uxr/ ?.. Gross Beti* ( ) lrl OT^ __ millirem/• - " - - - . yr-niu.n '015-i?;. _. ^.I .... ._.>'*•• i- Turbiaity {00076} ______ ftj| ______ TU

( ) ___ Q per100 ml

ARIOI08S

Page 23: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

*' *i\ ''• -v. 1*4 (..'•- c-u: !ri!iu'i£:y L'< •: . ' .. '. ;;,C:dO

8/29/84 »• • hv.4C.at- Oi .i\.- * '- .Mofcv*. fU.-Jicl j'iU'iti

T£-..~."'.*r-J'd'"'""" "nAV. '','<'> ''4 S VsA.j'X'5; .JK.Ai

) REPORT;->e BYibuiitt.^d r'^-cttirlv f°^ one

Monitoring Well

L*li% QOALXTY

-». loo (Q094o'i _ . .M- mg/L Additional Pcjrametera if rsouiredi

{0?,04S. _..itj#t_._ mg/L Antxmony ( ; _____ ^ <tl-IM, ___ mg/L

^ j nnj/ 1* JE* i o«i rhon u te ( ) >>Ba oig/L

( ) <1*% __ mg/L

3- . >t/->SKY«S'<3 "oi-O Ai, XNDiC^rOi'vS OF GROfJWD WATKtt COJaTAM'-UAnON

(must be done for upgr<idient walls"

110 _ 14§_• 0»4l gft-OJl <ro.Oj

\ { To «.M? u-f,-''1;

cr fe-dls Ch-7CK O. -.;t i. :' -., • '. • ;.' H/: i :',oa _ __ .__. oLB Z1- Atomxc Absorption _ J

.r/is:-r o,: w.i!vv r..;i:ory Porformir.g Chemical Analysis:

A3W £in.v iron,- . i • •, i CviiiijUltci-it^^ i.nc*170 J. bnioii -'*-jiov<;r'i

' '

Johi*j ?* Bough /t:;,y

ftftIO

Page 24: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

:-"!. s t a' .n vo/i e;. r. l Resourcas'.•*•« is ur Still.:'' (;i*:jt-3 ;*i<*n«geiiiQnt

____„,.- „. .._ __ ~— .. _ -, __ — -.. __ __ •-»

f JAp~[o \1\ 3j ell .[3(61 6J TsiI X-J _ I i I ( 1 i I [ I _ {

Number

< •••{Y<. he swbnii L *"d ocarteily .for one yeor for till monitoring wellg)

ilit> i ar.ie yoaolli COJfp«f«ti«l Facility Permit Number __________

Stir.nt County Carbon Municiotflitv Nesquehoning" - w

itoring Well No, lilMt* fciHPMil Check onei uo__dovn__gradient

th to Water Level 15.'8_ft, Measured fromt land surface__too of casing

ft;, KJ.evation of land surface ____ ft» or too of casing ft*

h^ck c;ne) ourao^ bailer_,_. Was the well surged? Yea Ko __

ing Well toc.;*r*orii Ldi:J tuda ..fP ° _51' J /'N Longitude w° £l ££»"W

mole Collect-yri 7/17/jM Time of Sampling 3:00 P.M. _____________

lvc?r.u- _.. INTE_X_

S CH-. **.•.."•; A !ai£ tKC SUIV. Ji; Ll'TY AS DKXtfKXN'G WATJ3R SUPPLY

(01002). _ ._. >*0_ _^. __ u 'fi. Liudjn* ('39782)

(01 OO/;.. , _ ^._._u^' h >i«fhoxychior ( 39480 J_._jgft _____ ug/L

.txnn (0"iJ27J. M_ _'uy, i, Toxdohenei { j 9 4 QO ) _ _ ^ < ji _______ ug/L

mi tun (OaOr»4i . **...,„.. __ 'J' 'i. i.1* 4-i> (J97JO) ________ J: _______ ug/L

{00951 __ .**..,._._«'•/'''- :>r 4- 5-TF Si i vex CJ97JO) <1 ug/L

ury (;i9GO). , <•„ .__. ,u,;/ ,. wroww A, oh,, ( ).....„

rtto {^»> 14) (Jui". >'.v 3U>00___ _u<-j/ '., Gross Beta { ) ...__ M T 4 ______ millirem/_u<-j/ '.,yr

Tuibidity (00076) _ . _____ I ______ TV

or (01077) _ 2.1k _ _'^ £> Col i form Bucterid ( ) ____ 9 r>er100 ml

in

AR101087

Page 25: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

i r.n or V-.-. . , .

8/29/84 » > I fewreuu oi Soljo rt*st* hoaageaent |pj AJDJoi 7t3i6il]3 6-«=.—,.=*. ; . « - _ ___,„ •___»„.*.„ „, ,.' V. * -• J, ».? „_ L, . 4—— -*- -t— -r.j_ l j.

e *r*:>«r,d X-D' 4tuinbarREPORT **3- °- «

o 'je submitted aK:rtrterly for one year)

cj-li'.y Name g alli C«rpsif«%l<» Monitoring Well Number

ciliuy Number _______ __ __ _._ _____

ESTABLISHING GftOUHI? WA'i'BJft Ql?ALITY

(0094U) _ m mg/L Additional Parameters if reouirecU

on (Total) (OiO'ib) _lft| fc. _, _ mg/L Antimony ( ) _____ p.ljl ___ mg/r.

i:7aiic.-se (010S4) _ __ JJJ incj/b Coooer ( ) ________ff^ffj

•sn;:! ( 2730) ____

d( :* (00929) __

ll'atx (00945) o _t«K I->J-L Qil/Grciase

JrO AS y.NDXOA'/'GUS u^' GROUND WATEft CONTAMX&ATXON

(must be done for upgr^dient

(tn; -:,rc fohr-3)Organic. c.\,jbci .; ; -.IQ/J. t * — . i**,- _?jJ

H^l .:•:;, ? ) r "/l> _J>t.W7 "ec. Sol,.-. , 'G..-:f-n iftQ/r 3, WO

or .-. Afomic Absorption

b .v- .-.•:,.-, ;-r of .^tj^c-x'.icorry Performing Cheniic^l* Analysis:

A3W £nvlronn . ;i .til Coa^ulttvat s .. Xnc.1701 Or.iojj j. -...io^.v^A I ieii t;o v-n tf f A i iJ ,1 0 J

Jobn P. Uoujfr- •, Ly

Page 26: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

. u-.. -ttCirii -e.jt tit •• *r. >-.„;-- nt,;eiii..il Resources j ~] f~| f] f fTtl [~1blAbltm 3I.Q1 3L6f6L3i~* ' •»-«'i™'1*-- •»*.-.! i id. 11 I n b ^ % IB •*.8/29/54 .... „. .i jrtiTe«u ofx.D.

MONi.UOK.ING' „ rtOQj, o^ Tr*«D ItKPOKT Udlb* No' l 0884-249-5

C.fo be stsbnii^t.C'd rrwarterly for one ye&r for ell monitoring wells)

riiity Nflne Tonolli Corporation Facility Permit Number

:ar.iom County _ af n ___ _ Municipality Nesguehoningh-4-Above Area III

ic.orj.nc/ Well Mo, Disposal Site Check onet uo __ do*--n X gradient

• th to Wttter Level 9'_5_ft. Measured fromj land surface too of casing

>oling Deoth_ .J:?...ft . Elevation of land surface __ __ft. or too of casing x ft>

•.- *'• T«fl.-?lin;j (cheo-rv one) puuio_Xfc<»J ler _ » Was the well ourged? Yoa ^ No __

*. coring Well T.ocoM.t.ru- Latitude 40 ,* 5.1_'_. 9,8 "N Longitude 75 ° 52 • 44 HW

o' amole Collected _ /l?Zg4_._ ^TXma of Sampling _____ 1:00 P.M. ___________

jL Collectors U n.c .. INT X ._

CHAAACTHUlZIflG SUXi'ABlLITY AS DKIHKING WATBB SUPPLY

erar (01002)..... w _..?_._ ____ u^.'L dtncldne (,)9782) _______ <0.01 ____ ug/L

<0i007)fc... . . ..24..*..-. ___ . g'i. ^thoxychlor (39480) <QT_ _____ ug/L

vl^ir. (0;027).. , . 3 _ _ __ u-j. ;- rt>x£oheAe (39400) _____ <1 ______ ug/L

oraiwM* (Oi0. 4i t ..83 _„.__. __ -»0 - 2, 4-D (39730) ________ <! _______ ug/L

uric-? i009Si.'__. 172 _ ..u»J.- t- 2, 4, 5>'fP Sllvex (3^74J? <1 ug/I>

•a ^iO^JJ. _ .. 32 . » . . . - . - *• ' . » - : . < 226 ) _. <1 ______ pCi/1

cury (73900J. . <'0-2 .... . .» . =. :.v--ft A :."i : ( )..1 B,." 1>1 pCl/1

r«te C-js KJ i''jb>--; 650_ __ u .,-. u Gross tut.o { j 7,8-0.9 ____ millirem/yr

*niuifl (Oil47> . _ <2 _ u.j. t. ru;bi^)ty (00076) _______ 1. ______ TU

yer ;OI077) <1 u<v^ Co! If arm Bacteria ( ) __ >2QQ __ per. ....,.„

ria (

Page 27: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

ooii.:i'.o;iv,.i :i.:. t.; or }".;n

8/29/84 *» j sux-e^e of So.Ua tf.-.ste Management jpj ATDfOi? iile * l[ 3?6 *6i3 ]-. — ... .. . _ ..... j LJ J J-iLLia JL__.l J Jr.ccs r^n T.D, Hummer

xi./«ArUi\HU "rtiilM MO^ JTUiiREPORT Lab, tto,s

H'o be submitted carter ly for one year)

Name. * 1 ^ **iriP>>4> *____ Monitoring Well

Number __ _

I. PAZ1AMETSRS ESTABIASHllvTG GROiajr WAT2R QUALITY

•^ovid;* (0094rO___ __ *_ ___ mg/L Additional Parameters if reouiredj

ron (VotciL) {01045} m , _ * . __ wg/L Antimony ( ) _____ : OttOl ____ tng/L

si.ganese (01054) _ mg/L Co-v>er ( ) 0«0€ mg/L

nenol (.12730) _ ug/'L 2inc: { ) ______ ••!» mg/L

x'l-um (00929) ^** rag/L Bicarbon ite ( ) *T^ mg/L

(0094S) zug/L Oil/Ore a e ( ) < !•§ mg/L

AS A&X)U ATO3&S OF

(i uat be dona for upgradient

x.ci£:.c Cowdu- t-.,»i:- • i ;:s053I al organic c«rLoM ;tal Organic H.U,,,, i ) g/i.

t-'i t:oi , '. /VC30-1; . g, L

Ma.;als Chj .-K Or.: -. 7 1 ..-•:':. u-j.hod __ ^ or 2* Atomic Al-sorption X

ri';», Address <-r.d Or. -v -v..sor o:.". U*;>or.iLory Performing Cheutic^l

' nui^a ,i Cc'ii3ul trt*it..s, inc.1701 Union v--'>'-j • -rvsrilAllentovTi j r/-. o.i>;. O

John P . Dou j h i r >: y

Page 28: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

J r . ... :r;i-:i't ov ".j.Vi.von.i.tniurf'i Resource,-fU;,; 03: So!j.:i w^ui.-'is .liana tjetuent

D O 7r r•? ocijc ftd i . D. Ntmibor

-,——— ,-————.-——— ,

1|3 6 6 3

(To he submitted cmarterly toe one year for dll monitoring wells)

5. Facility Permit Number__________^ Carbon ,- - j i*^ Nesquehoningidtion; County ^ _," "^ ^,«^^ Municiodlity M _____ _y ~ tHU«t Of •Oli< '

utoxing Well No. ***™ *** ^ Check one« uo__do^-nx, gradient

>th to Water Level 23 ft. Measured froroi land aurface too of casing

loling Deoth __ _1_8 ft . .Elevation of land surface __ ™ t. or "too of casing x ft.

ny (c-he,. Jv oji e) Dumo_2Lb«ii lor _ .. Waa the well ourged? Yea x_ _Mo __

rfell Locoiion.- Latitude A°° 51' °^ "& Longitude 5° 52< 42 "W

Collecte-J y/lJ/94 Vime of Sampling 9;48 A,M. _____________

iple Collectors W^me INTEX

CilARAC'Vii:r<I2.r G SUI 1'ABILT.TY AS DAINKING WATEK SUPPLY

a (0<.OUS) «^'SfM- ^thoxychlor (J9430) ** ______ ug/L"

____ _ u«:j ' L 2, 4 JD (.i9730) ________ f;_ _______ ug/L

cvry <VI900J.

(c»s W) (OO .'-j; _. _ uy/ I, Gross B«ty ( > ** * ___ millirem/yr

('J.1077J * .A»i ^ Col i form bacteria ( ) ____ ^^ per' -- " • ' ' •••" •'"• ' 100 ml

ftftlO

Page 29: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

8/29/84 ' ' W...i'£uC J/" Sc, f. ?.d Vv 'S t:e Aiandgement-e PrwoMd"""' „.,,,_ MI;. UAWft MGS1TORtaG ITI»7 UuflJiVr

iUXTlrtL bACKGROUNI** (To be aubmitted qi.<srterly for ona ye<ir5

'<scility ^droe TOOOlU CoyyOTfttJO* __Monitoring Well NumberJJHlfg **J**M*

vAcilit.y Number _______.___... _. ____

1. PAKAMBTSR3 BSTABI-lSHIJslG GROUBTD WATKR

'blonde (00940) ___ \ _ 4£ _ mg/b Additiondl Parameters if rsouirsdt

ron i?otdL) (01045) _ j ^ mg/Ju Antimony ( ) ' 0>M _____ mg/L

Uh'jtneae (010S4) _ l* mg/L Co^oer ( ) t«t€ mg/L

•henol (32730;

c ua\ (00929) «f.2 lug/L Bicarbonate ( )

'o (O094:>) J4« mg/.u Oil/Greaaa I ) <!•§

. P/-JRAMSTSU3 MSi'J> AS iH^ACA-rOKS OF GROUND WATER

<mu.t be dona for upgr^dient veils

•H <

'cr.ii 1 Organic Carbon »'ct.al Organic J-«ilo9<=r.

Dissolved So'js . :-

*oi- Ch. ck On---: I M:.. •-.,.; _^-.hod ,__ __ . or 2- Atomic Absorption

'afne, address «nd S;,- ;;/lsor or Oo' or jtory Performing Chemical Analysis:

A;5W Environ'»*.r*-i •.«,!. coasultentc, inc.1701 Union E:v.ii*v«:r«iAllentovn, PA iftlC J

P. Douqh-* A ty

ARtO1092'

Page 30: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

8/29/84 v i '---•^'^•^/i; '.'•jn Hitdt 1U«™W ^ (A ID loj?! 3|6l ijsle 16 I 3 i.. L-.. - .. . . .. ; *«».\:ee-:* oy t.o >o Ivuat.';? ^-Aunogement r_ r^ | \ \._\-\. ] \**r r* \.\L-. ;.'.-;--. .j. «a J(.D, Ntanber

KA2ARDOUS WAC'JK MONicrOKlNG'AL^.TXAL BAClO..KO'SbfD HKPORT

be subr.:U-tc:d cucirtcirly for one yaer for all monitoring wells}

Facility Permit Nuir.ber _________

s Coonty _ , Car? „_ Municipality NesguehoningVMrth of §«Ii4

tot ing Well No.yM^ MttOll Check onet uo y dot-n__gradient

ath to Water Level 42»jft. Measured fromt land surface to-> of casing x

aoling Deoth_ _ ?.2*"t.. Klevatiort of land surface ____ ft. or -to^ of casing x ft-

ra /F air.ollng(checA one) oumo^_h<;iiler _ * Was the wall ot.rged? Yes x_ go __

iJitor ing Well Loco r. Lor-* LbtitudfcjO .* jl . A1 "^ Longitude 75 ° 52 _'. 46 HW

is? >amole Collected .,. 7/16/84 Txroe of Sampling ____ 11:35 A.M. ____________

CollacLora Naiaa INTEX

SUITABILITY AS DRIUKXMG WATKR SUPPLY

C39782)

(OJ007),.. ..... §1. __ .. _o«5/L Methoxychlor (39480) <1 ••! _______ ug/L

- (OL02?). ,. . f „. _..._.ug. 1 Toxsohene (:i9400) ____ Cl ________ ug/'L

, ._..•?...._.... _uo - *- V, 413 ( J9730) _______ £_l _________ ug/L

/ __ 1.10 .. . ,'^ - -;, - 5-TP SiKvei; (3»'MO) < ug/L

_ 57

•cury {7

(as N) ;0-:6.>u; JQ£ _uoj. I, Gross Bet^ ( j 7a§ t ^|. _____ millirem/yr

t.y (00076) ______

v -:r ("DIO?1?) <JL ^ ' i- Coil form b,»oteri^ ( ).. - .„

Page 31: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

altjjL oi: Ponirsr . o£ 5j;',v i c;>n.'i3nval Resources

8/29/84 ' • Bureau of Solid bfcste Management l D o S 61_ _ — t... I .— 4-.Pie oared T n

'U WASfWS f *I INITIAL BACKGROUND REPORT

(To be submitted quarterly for one year)

xlity Kama To»»H4 Cyjry jffi f ifif __ Monitoring Well Number

ility Number ________ _, __ ^ ______

PARAMSTSRS ESTABLISHIUG GROWD WATER QUALITY

orida (O0940) __ __ § __ __ mg/L Additionul Parameters if reouiracl?

n (Total) (01045) _ _ 14 ' _ mg/L Antimony ( } ______ 6,011 _____ mg/L

ganeae (010 4) ____ >^| m«j/L Coooer ( ) ______ Q^lfl ___ mg/L

nol (32730) < JQQ ug/L Sine ( ) mg/L

iiL (00929) ___ 1.0 mg/L Bicarbonate ( ) „„ mg/L

Eate (00945} 450 mg/L Oil/Grease ( ) _<_l.o mg/L

„ i>ARAMBIEKS XjSKJJ AS IWDlCkTOftS Oi? GROUJB «ATBR COHTAMXNATXON

Replicates (must be cione for upgradient wallsonly)

_ 1.1 _ _|*l3ific.Conduol..j,icrt i 0090 j) finictoffihoy} ^JHO __ TtOal Organic C«rbcn * j tig/1al Organic H-alor)--*^ f ) cno/Lai Dissolved So.i'".- f703'>4) a=ov 1 MS |>Jg __ MS Ml

i

Metals Check Ono; i, i>fu--iO .:-: _•.•;..•; iioci __ __ or 2* Atouuc Al*sorption m

;, Address e*rd St.^»'>"vjsor of t ,-jbt>r<?tory Performing Chemio^l Analysis:

A3W Envircnm.riiu.^t Consultants* .inc.1701 UniOA r'o'..l -v

John P. Dough '-rrty

IOS1*

Page 32: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

8/29/84. '• j L' -';-ij:•-•i;ft^ />;' *'•* '-''( ''- .o't Ra Oia'caa |p"JAJDJO pjl 6J1it.. P^oored Jt.D.

HAZARDOUS tvA?. it

he giil.ttiirt.'-c' Quarterly for one yg«r for all monitoring wells)

ic.il;ty Wai.ie TQM «ry»r«o Facility Permit Number ____ __________

>cations County Carbon Municioalitv Nesquehoning"•*la*«Tdriar«'-m ——————————————————

>nitoring Well No. Wart< >JjyM»l check onet uo * do*n __ gradient

to Water Level 33-fLft. Measurod from: land surface too of casing x

PARAMB033RS CHARACTOUIZIiaG SUITABILITY AS r&INKItfG WATJSR SUPPLY

eeaic (0100:2 )_..„.. .. *_.M... __ g/ Hadane (39782)

jn (OjOOV; ug. I. Hethox^chlor (39480) « ______ ug/L* • — - • • * - - 'a.rsi-.n-' (0/.027; * __ .._ g ''-

...3 • L i» , 40 (39730) _______ _________ ug/L

uoride (00953 ;_, iM......_.._ w.oq/ 2, 4, 5* ri"P Silvex (39740) ug/L

"....... .. .vi ; ,. i .- ..: < ..ii. i Mi ) _ _ _ . <:i _____ pci/ircury (71i*00).._. .'.. .. ..»-,../- Or :>!?.«? ALol'.a ( )__ ________ pCi/1

i~J

moling Deoth _ ff_ f t . . j=:lavaiion of land surface ____ ft. or- too of casing x ft.

'oe '/f SaffiolingfcueoV one) purnoj jr jiler ,.. Was tha wo 11 ourged? Yes So

iritora/ig Well Location. Latitude. 19° 51 05 »N Longiruda _75°.j_2i. . "W

t Samoie Collected 7/17/S4 >j>ime of sampling _ _ 1 : 34"1 : 45 P ,M. _________

tuple Collectors Same INTEX

trate (as N) (u06_>0; .._ __ ug/L Gzoas Beta ( ) _ _ _ T _____ ___ millirem/yr

» (Oli47) __ L*...._ «>«»/^ Turbl.lity (00076J _____ *•* ________ TU

Ivftr (01077) <T1 ___U9, t. Col if or n Bricteria ( ) § per100 ml

7rin

ftR!OI09«'

Page 33: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

8/29/84 __ »j j hurt*u o; fijr.ti-; rt.-j&fcfr i'-icCiiiCf ent | PK jD|0|7»3 16 1 3 ;6 J6) 3

i: UACXGUOUfiTO RSPORT(Vo oe aubmxtted q^^rterly for one year)

c-ilihy I drae fy ^ fyfy ^ , __ Monitoring Well 'Number >*»••% •< Agej

cilluy Number __ .. ___ .__ _ ._ _____

. PAUAMETSRS BSTAbT-J SHINS GfiOMB WAVKR

.loxide (00940) _ _ , __ 1_ __ mg/L Additiondl Pardnieters if r^ouired*

on (Total) (Oj045) __ .!£___ »g/l» Antimony ( ) _____ . OfOOl _____ mg/L

aj'-jdrKsse (010 Vi) _ j fy| rn^/L Cooler ( ') ' 0«»4 ____ mg/L

ienol (32730) J>0 g/L Sine ( ) Q,1Q mg/L

(00929) Tt'J/k Bicarbonate ( ) § mg/L

(00945J \M m .'L Oxi/Greijae ( ) _____ j^ _____ mg/L

:*. PARAMETERS »Si:D Aii xajniCATORfl Or GUOUJD WATER CONTAMXNATXON

(must be done ror upgradiantonli

X Organic C^rbcr. . ) nKj/1 _Organic njlo-ju- < ) m^A- _ 9*Dissolved Sol (VO.J04; . .o, J 1*0

Medals Ch^vk c-r--: L £*r^:id^-- i^-»hod or /, Atomic Ahaorption

Performing Ch^micsl Analysis

ASW Snvironiiv.-ut.-.'t. Co:isui.tti7xt^j .inc•170i Onion no^levarrtAllentov-n, T7, IBlO.f

John P*

Page 34: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

8/29/84 '• i ' ' ":*l'-'-*-'c lli v ' -••'•<- -t BUssourcaa pi AJDlO ,7|3J 61 1I3J6 ;6 13 ;._°/ty/°l....... ......] . jrrodi; of £-,>' ; W-i*t* i**urtgement I - l i t L II I ! I [ I \•fce ?;er^red J*O. ND^ber^^ ' HAZARDOUS W t,"tfc' MON^'J^ORXNO•• -W1T/AL BACKUftOMJO RKPORT I db* N°" *^^ (To foe fuhirtitt^d cicirterly for one yoar for all monitoring wells)

icillty fcfame ftM-ttUULflMBBMafci.HL- Facility Permit Number _________

^cation: Conn-ry _ Carbon _ Municipality Nesquehoningf-i<mtt •! loU4

Itfell No. J_ tt-tJ«JBUfc.M»lCneck one« uo__dot-Ti y gradient

to W&ter / .& vt^ I 9 . 12 f t Mtvasvred from; ) nd aurface __ too of casing __ ___

_^R^ r'i . £lsvciticfi of land surface ____ ft. or- too of casing ____ ft.

oj ('.-;... '.- . one) r>urn-,^_ boiler J^. Wan fche well ourged? Yes No __

Weli. Lac,.i.ioii* La t i t: ud »:• 4 Q^° 5 1_ ; 02 » Longitude 7f *52.V 43 "W

t' S-jntole Collected T/17/14 __ Time of Sampling 10:30 A.M. ______________

mpla Collectors Uarr.e INTEX ___ _

CHAI^.CVKKI2JIiflG SUITABILITY AS DRXUK1NG WATER SUPPLY

vqr/I Lindatne (39782).__, .. a -M. , • »-'--.

....... .... Q/. .Mathoxychlor

4 O (397JO) _ ^ ______ j ______ ug/L

4 5-TP Silvex ( !tM740) <^ ug/L

• yrVurtaioit O0076) %M TU

lv., c -0:.077} _ _ MI i. Colifor-n B^:'t«?rid i '* 4^____per" 1 0 0 m l

/.-: in f sv3 Ji0}

RBIOI09?

Page 35: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

°' J' . : '» I -I :•• •'. . i- I 1 .' . IA) _ C_- ' i- ?vl Ati il ."Ti-rnoM "i" I I 1 ^-l—(->.'>-!nl^i^J^'-.1 7 3!6 1 3; 6 6:3c-* P'.rt •>.,,•.. , K .<*> fc v.i.v'i?-Jxi->iX 'i :> '.vAti M MC.vH

Xi\fITJ'?-.t. bACKGKOUriD REVORT Lab(To h«i aubniitted quarterly for one year)

Monitoring Well Mutnber t if [D

acility

I. PAlcAI-iSTSRS ESTABLISHING GftOUUS WATSSA

'hlorida (0094U) m mg/L Alditioncjl 'arameters if reouiredj

ron (Total) (01045 ) ' JUif .._ ._ g/1" A vtimony ( ) ______ j,ytt _______ mg/L

ae (01054) ____ JUJf mg/L C-i-^oer ( J _________ (>«§§ ____ mg/L

(32730) _ __ <z U& ugy u Z: nc C ) »»jl mg/L

(00929)

iulfate (00945) ** in9./L °- L/Graaae ( ) 4»f mg/L

ill, PASAMSWSRS XiSiuD AS XNOXCATORi" OF rt ROWD WATt .^ COiJTAJOHATXOH

Keplicites (aiu£t be done for upgradient walls

>K {00* 03) ' * _ .Tf*

:-ot:al Organic Cu-rLor. ' } .v.g/1 310 lib tM 140*— m— IK-.--— — _|-*Mtj|-»— -"_fc—_i_i_i- *~~

r*otal Orgdnic Hilo^-.-r. < } n /L V«V9t * ***_ **** „r-ofcul Dissolved Sol, 1, :70jC4) ir-n. 1 "ii7>» "ilj4t» U+40« il<4»l

?or Me::als Che-.-l' Or-e: .-. , ^'t .-:•-.•., \.-.J •.•.:;;.l-- -d __ _ or 2- Atronac Absorption .

N'e.f.\e, i.ddr as end Gv.^;?i:vi.Kor of li..hoi:jti ry Performing Chemical Analysis*

ASW Enviromv.-jp.t -.1 Coa^u i.t.i»r.s, .ii c*1701 Or.ion SU-.'-i'svaraAlLentovn, PA Afil03

CTohn P. Bough' rcy

A R I D 1098

Page 36: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

2/27/84

Toooili Corp.Carbon i..u, f - . ljt, j_ ; v Nesquehoning

200 yds*-* " • '* oi..-. u \_. -.:•' ^* _ -M.";' j. .-.;.t

.:u iir'^u l.ihd ::= .r, ..''.; -.-.> . o •:

...... 40^51^ 02 -: L r.«jj . ; 75 ^ 52 42

10/4/B4 fl( ' iv- -'-••. .-'^ ^-^ -._.. . .-JLl?.° ..£:M:INTEX

_ 4 • '"'•• •-' :."'••-''.24 . . ; • • • «iv , ' . ! • - . .' •. ••;'. ,<o.2

as . -j. -. • ••-.. ".- > • u .-i'l.. .

150 ..-. ,. • -i ;• •••: •; • • ( : j,170 . 226 <1.0

<0.2 : ... , , <0.9

170 t- 2.2 * 0.5

< 2 - • - ' :l • • • • • • • .. 15

.... i ••;/- ;-"' ••-• - • • • ' -10, ....<b.oi .

fteiOJ099

Page 37: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

1284-43--

40

200 yds.B«low riant

SU73 ^ t_ mq/7., A->.h^racoy ( '-- _ 0.008

, 1.02 '" ' :"- — or ' • ___ 0.02 .

i"JC-??'?J 44 ••;.;.•.,. -i I-;'., •-'-.-or.-*!* - t • 5 mr.-*?.

(00943" HO C'-;. - C3.?. 'G.v. 'Ji.-r '.". ^ )

T'AH'£jT'FlV» %^"V""' *iw •' '-?r ' V" """:7, " LkT? CI;.".'' T'v MAT'"'-' OC'^-'^v' :

^ 'T - ' •'•<.'' J"?: ' *: '' J'"* "'•''• '*

_•c';?'k. Orcr-sn'c r:., ?; ( "' r--,". ' *"c tjl Orcrcjr^r i-T.|*r^ i-. f > P-/(, <6*()ibv •". nin-ol vc-.-; c3^1 -""r ( ?u.'V' r1^, l 160

nt si Con;,1701 On -o-i J.o,:1 7 ro

Page 38: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

j '/'-rpiir-c^epx: or ^ v -; nnipenra t ilesoorcas j j ] 1 ! f f j [ M jul.i_LJ ..LLL.L.L. ... f

Yo bs jsidbr.iit: t*d #»; -*3:l-vi: JLy :'c?r ons ya^r fox* ,yll rronitorlng walls)

ty Name JCoaaalli-£osp* _____ i'*cility Permit Number

County Carbon ______ Municipality ____ Nesguehoning _____ _____ _

Inn i tor ing Well No. 2-B«low Wact* Chack ones uo __ dor-n JC gradiant"Tre&tafant i*«yoon

>eoth to Water Level 20 • 4 _.t t. Measured from: land surface __ too of casing __ X __

-<3uioling Deoth .,.21 ft. Klovation of liand storface ____ ft. or too of casing X ft

'o& .-j£ Sampling (choc*.; on«2) ouno^X^b^iler. _ f. Was the well ourged? Yea X No __

ion i tor ing Well fcocuU-ori; LiititudeJtft^ 1L 02._MN Longitude Jlf 52J. 51_"W

Jfc1 Saniole Coliecto.J _.lfl/l|/64_m> Time of Sapling ^ ____ 5:00 P.M. ___________

cmole Collectors $<±r:.*2 INT^X• j»- tft- J- <w n>.r. . , — . . j^. — .-i..-,..,—-

. PAJUUdETERS CaARAC^-ERrZ-JKG SUia^.BtL.XTY AS L.RIWKXNG WATER SUPPLY

(01002) ___ ,,__. _____ ..'9-/ L-JIr.d.sne {

.__ »1 ____ __u .-'L Mothox/chlor (3iMSO)__i. ______ ug/L

atr.ixam (01027) __ ,_ 21 ______ g/ Tox^phen^ (39400) ____ .< ________ ug/L

__.. _ ? ____ t __ \?o/l- "-2V 4 D (39730)-., ______ 1 ________ ug/L

luoride (00951) ___ _ ______ u^ :>t 4; 5a,y? silvex Ci 740;_< l ____ ug/L

£ (010511 ____ _ 1^ __ __. -; : ;, /.t,-. ( 226 ; 1.2 A 0?4_pci/l

ercury (719QO) _ _.___5.?J1 __ _«1v-/t oro.«d «I^ha ( >_

itr^te (as N) (OOC^O;_200 ____ u /L Gross Be :«a ( j 2,2 A 0>6

o Ionium (01147) __ .._..\?

•i!v-;-r (01077) __ _ _ 1

yro Ionium (01147) __ .._..\?__ __Ua/L Turb.idil. ' (00076}_. 0>8 ^ TU

100 ml(*9330) ___ _

A810HOI

Page 39: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

Or -^-jt-? »:*l fc.H •* r. Vcnnr.y'-'.v r?, )•• "• •""• ' ' " '""'' r " "" " *• ' • ••' - ' -"'• " ' :< .v,..r...Surest? of. .Vr.'ij. 5 i-TdsS-f* Me Sv<.-.T."«nt '. * r

Xi^CT^POTTeTD ?,"?OP.7 **lt^rt.Grly fcr or.e

*i?" xT " """""'l— -r _Fo- s 1 2 84*4 3

Sattefci.«rdOOllijCO»p«._ _._.. __ Monitoring V^ell Ki.\- b-^r H*" ^

.Yr. PAU?J.J3T3SS B3T.Tv5T,ISHlNG GROttIS

Chlorid-3 (00940? T T jS7 S tng/jj Additional PrTr-r- or.? if v«?GUir*c?r

.<rca ( otal) (0.1045) __5,.64 wti. w mg/L Antimony ( ) __ _^_ 0*006 _mg/L

M-.3:ganes (010.54) 2,75 nVi'' -J Conner ( » 0»13 mg/L

V-honol (32730) _ ^ <100 '-T/•-» ^--"^ ; ) 0.12 r.g/T,iSodium (00929) 41.0 r°r.r-' •' T. j.c.j/:brv:v--ir { ) 4 racj/Ii

So?, f*te (00.945) 130 mg- £ Oil/Grafts-* f

on 7J

CDnc?*j.vJ. u:-':o < 0390:5) 'r j cr-CTUDS1. 490 480 495 480al Organic C.ir:.-n < } -v?/:. ™cT. 2~™ __"! . 5 '" " 2 . S ~ "~ 6"._?. Orgw'r: »..Oc7:a i . ) *-;y.L, ~pi, 014 _ 0.019 6 Oil" "_ 0.012

. j.l :Mrsolvo-:. £oij-":; (7030^; nj/L 210 ' 220 " 225 "

Chsch- Onf: i. £ t;-. '*•'!:•':::" •-"a'.j: ^ or 7- "itf-n:. r; M.-^rotion

s ^rr1 Sir^sr/.^cor r>f .: -r-s:<ft-'?:y l*sx "o/.;r:'.:•;g ChiJtm?7X'. /i^MlyRisj

aSW Environment *.! Con^ult^itc, nc.170A Union .roulevercl*A}.l3nto-..-nr TA 13103

Page 40: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

***'\ \

ox *••;.,l3.d #i.'jte JWiisgement UJ~Jl-LJ«XJ-JL.LJ_LJ_tLe Freo<»red

1 j | I .: I j [ iLi L Lit. t l.(

l b, NO.* W84«43-4(To bb avb^in>.'.d o^HrterXy fcr; or.a year for isll monitorfng wells}

tf«ima gOPOlli COJtp* ___ ___ Facility Permit Number

option: county . . °JL ____ ..., M^ici^alicy Nesguehoning

o.-iitorinq WeJ.l Ho.*"Balow Solid choc-k oner uo dor-n x gradientHBfiotG *xagooir~ —— " —u^th to Water i-*vf.'?wJ4z_3 ft. Measuied frorr.: land aurfsice __ to-> of casin

anioling Peoth ,N/A it, ;5isvdtion of l^nd surface. ____ ft* o:-r to-> of casing _X ft,

yr/:- ^T Samoling(ch^ck cne) pti-.roJC^b^S ler__. Waa the wall oKrged? YesX

or.itoriag Well Locttt.Lorjs Lctti t-.i-ue._ 4tf 51' L02 "N Longitude J75.f52jL 4 6 _»' w

^, - Saraole Collec->c-! W/l?/?*.. ^ . Vinsa of Sampling ____ 5iQO nP^M _.

c-r.iole Collectors tfci.vcj ,_^NTE_X__

CI-yiU>.-:-TKNjL5IilHG fCM'S.SJLrTY AS .DUX15KING WATE.R SU

jm

L1, (01027).

crirle (0095'. t __ , _ _ 20__ __ LV,. .-- ."i, 4. l-i-TP S n.1v o; U';/ 0;_Oi ____ ug/L

51J __ __ __ ^_ .?„.......-•:. i'*.1!.:.. (226 ;„.„.... .._,<!.. __„ __ _pCi/

KJ (00f^-0;_20p ____ u.,;>. Gross Bsho, {

{01147} ____ ....J ?___.._ / Vurbi-T.^ry (00076). ______ * ________ TIT

(01077) _ _4__ _ u /'l. Cclifovn Bacteri* ( ) .„. _ .9" — * — - _ 1GO ml

(39330) <0.01 urr/i.

Page 41: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

'- ;;- . . . . - . . .^ « , .f..f ... -t- »-.. --. (. -.j. —-—..• - tof ,:'c},iV *.7««i.*:e > 'i £g,.T :i'; ! i ! I ! • ' f i j ( '

. ..i(To be <;ubiidti>>" cua>rt.erlv lor CT. vej"'; . 1284-43% -j - ^,

'cv roe TOttolli Corp, M'-n luring V^ll >V-X •- •• 3-B«low Solid- *-- - . . ^ . . ——— .„ — ———

Chloride (009 10) ____ 200«0 ^

tron (Total) (0.104:0 283T.S _. , _ t

J-lsnganese (01054) _ _2°3*3 'ri' 'T- -e:.: ' ^ °«1

f' * enol (32730) _ _ C100 vr/'* -.'-'v: ;' ) 10.8

Sodium {00929) 270' t;.g/?j 3ioar!v.v^^f-2 ( i -~

Salf ate (00945) 3900 - rr.g/ 0 Ci3./Gr->a,?a ( ) <1

(004031 _* w* >" 5000" SOOO

i Orgmlc C-.:-b-.:n ; ) r?.r>A] O-^gpn'c "-'-'c - { ) .r.n-/r. "~a;06 * " CT.060 "'0.057Dissolvoc! ?-l :: ("OV'- rv>/^

Tor Ksfiv

170 i Union ro^Qttfcovnf PA

uohn

Page 42: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

. .au;-.5du of SuUd W^dte ^oiiaoement I I j I If L III- l_.-:-L--'—£:•.:;*-*•—'—L-J—'—*—'i.D. Nt.aibar

**o ^e svidiva-Lt-id iv...ajrteEly for ona ye«r for iill monitoring wells)

exility Haae _.?5! A:f-J E!.____ Facility Permit Ncmber

.ocationi County 4-AbOV* Area XIX Municipality NesquehoningDivjpdael 'Slte" • ————— — — —— i

g Well Ko. _ __ .._ ______ check one .u dot-nj gr ad lent

aoth to W^ter t8vel^j.afcl-£t. Mo^iii-TeaCIrM^ Und" surf ac of

JLa.8"' JSievotion of land surface____,ft. or to-> of "casing^ X

yr>-; ^ flamoling{c:hsc\ one) t>w..>._bsilHj-_^...Wao the well ourgod? Yes_X_No__

onttoring Well Loc,.-Lir,n; L^ l:i t:ude ACL* H 'jjfL" Longi toda^ J g j 4 T"

W Sample Coilec;-d ..... IQ/ /gl.. , Tigua...of Sampling ___ j1j)j0 p7M=." ''"'" '''

cr?Dle Collectora .$c;;v'? ._..XNTRX_ __ * ^ """"•" " "• - ----—-—————=—-:

- PAJlAI*fiO?BRS CFARAC'; KRX2I.UG SUXT.-,BXt,JiT5f" AS "n:<INKIN

rse.iic (0.1002)____ 5 Ul?/t ^Xnc^na

3 ug/l,

Iccridc

-cury (7 1 a 00) _ _ _. < Q,2, ___ / Zl T TT ^ ..6 4 1- - • — — - - - — -=* -* *-' - !• —— ————————— - - - — —

i/l±.f J_

7.5 ailliram/eniu^ (0114?)____..._.__UQ/JL Morbidity (00076)_______»0

v-^r (01C77)______ __}____!jy/L CoLi.iorm^Eacherivi _( ) Q

i-ln (39330)

Page 43: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

_ , . _f C",-3***°ifl ' * "1 iTi*

P.-WS v-M7r'^yiriX»?.jU:^ """ ' '-43-5

r^mo Tonplli Corp. _ __ >!or»itr*rl:.ig rVilV - ': '.-' 4-Above Area VI

.tf. ffAaAIWT.es 3 5ST7v T,XSHXN'? G OVn :. V1ATTO Qi^r.jTY

(Vo-;:r I) (OiO-?!".) _ 5j?,,.._ wc,v TJ -V.-vtxr.ony J 5 .,.., 9 -

35 . ; l • "7-' "•'- • ' 0.12

2.5 '-.'• '' " - '"'•"• • ^- ' J 0

110 t"vf/T' Oxl X-r:?.n 3 ( > 1>0

r"or 'tc J

3.8_ 3.8 3.86

. o.qio(70, ta^; pq, I

•3T> Envi.rnr;'"Dn1;-, I CoTXCI t'i,: :"') '"•.r-l-v^VM

RRIOH06

Page 44: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

. t ^ NumberAi/iB MONi'JORJiKJacKGROiaro KBPORT i*&>. HO. t

(To be submitted eraarterly for one year for all monitoring wells)

acility name TOOOlii Corp. Facility Permit Number _____

Dcation. County Carbon __ _ _ Mani.einfe.lity ___^esauehoning_

wltoring Well Ho. i- jU-t Of Solld check oneg uo_.Xdo^_..gradieat:

«H» to Water i.<?>^l.27.1_It. Mc«>-i..r_ii" froiaT T«nfl "^or!7^^:^f~

r. • a^tv^n r: I ncs?ix rc^ _f t . ortcr of

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it- Suwple Coli..!Ct«..-J 1°/*V9*

ifii-rle Collector •-, t'i..p •:

KAHJSI-SKS OH -.>..'.:'-f:;<j.aiiV3 Si/rvr^TLil-y A

c (OJ002}__. ........... _1»...,., .. ._w«.

.T, (Oi007)_.. .__ .** ur. ':, • ug/L

,, L

ug/I,

rcury (71900),.._..... . ..._... .,..,,. .r.i,,, j ..M.lL?' ___ pCi/1

milliretn/(01147) ._.„._ <2 M..-/,. -ul U >. C0 "''

<0.01

AR40H07.

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105,5 ng/;.» A^Ji.troi^dl r; :-r :'•.'-•

lT>C/7j

(009-13) .r ; " :; " 7. • •.S.f :.?*? 1 : ,

on

J.tS. ,- 3.95 .f-i-c'ci.-C- c Co/'dwct iv ' <00^05i f T J - 1 - --1:;?^ _fSOO__ ....JPSfO. ,, 9MOTo*al Organic C\»;-"OCTS ^ ) -r / ? . ,0«t ,..,.,,. 0.4 ,, <0*1T.,:al Organic •VO.r.-v-. . f 5 (c/3, _0.02I H'o.OM. 0,01«

iMssoJ.v-:? Sc-1 ••'•;•; i'-'OJO^ ,7..). 4tO

',. '-T, /.n dress u-r :* ."*._••"?;••/ •' or -••! •;.«.;'••'. > tor:y '"-^r ':crr »?.r q C '.-rv. '. I

170 1 t*r.ini r-.vAlLenLovr... PA

Page 46: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

"" "12/27/84"" "I ^-,--_--• -:'j_iv-!^r^-.jror!i.«nt^l_Rasoru:caa ~ j~J jl j (TTIT] f

•*D» Number

WAS; IB MONX'JORZtfOftSUXMAL BACKGROUND REPORT1 "^ No**

(To be submitted oaarterly for one year for all monitoring wells)

facility Name Tonolli Corp* _____ Facility Permit Number

jocationr County J arbon _____ _ _ Municipality Nesguehoning

Sonitoriiuj Well No. VHorth of Solid check onss Ud _ K.dovn __ gradient*"w«a"t«i*"l>4aj?a»ai . " - .__

to V?ater I»« vca 14.5 ft. Kt;ftsur«d froru land 3 tar f a ce -o ->o f

5 -ambling -D-^th^^O^Ort. Klevdtion ot l.dnd surface ___ ft* o:d to-> of casing L X _ fc

-jlin'3Jc*liec/^ one) D:.V:' XJ: ilar __* W«i« the wall ourgod? Vea X_ 'p __

Well boc^ticvi.- Lciti cudc- 4 0 ° 51 JJ /'K Longitude .L5_* 2. t£~ "W

-•c cs Samole Collected _ .Ift l/**. -.. . iws or Sapling ____ 5:00 P.M. ____________

toiripie Collectors i^^in-

STEPS ."r.?-.;-..',:'':r;iUi3TMG SU2 I'AB i ITY .AS R1NK17,G WftTER SLTPPLY

( 0 100-2 )___._.._81___ _*J<i'I i^ndsne i

_ ___ ^b-t '^l-hcoryc -ilor

ug/tr

(01034) _ _ ^ _____ tg'L 2. 4-D (Ji£.7JO) _______ ^_ _ ,_ ____ ug/L

^tr.-te (a.-s K) ;006,K-;__W^ __ >,>'•"• G^-033 bet* ( j __ 7,5 £ 1»0 ___ rail I ir em/yr

elenium (01l47)4_.__< ?.iO ___ _u^ L Turbidity (0007C-) ______ 1«P _______ TCJ

(01077) _ <1 _ nq/s Colifor-n B^cteri-i ( ) 1 ____ per•-——--•—•"— ~ __'0l u ':, ^---

Page 47: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

Commonwealth of Pennsylvania *Department of Environmental ResourcesBureau of -Solid Waste Management

ce Prepared HAZARDOUS WASTE MONITORING I^T&umberINITIAL BACKGROUND P.3POR'J ***b. No,s

(To be submitted quarterly for one year)

Facility Name T<molli Corp* ________ Monitoring Well Number _7~gorfchef Eolid~W*ate Disposal

Facility Number _________________

I!- PARAMETERS ESTABLISHING GROUND WATER QUALITY

Chloride (00940) ______ **L__ ___ rcg/L Additional Parameters if raouireds

Iron (Total) (01045) Il*»2 _ mg/L Antimony ( ) ________ 0»02& mg/I/

Manganese (01054) _____ 3/72 mg/L Coooer ( ) ________ 0»28 ____ mg/L

uenol (32730) _____ < IOO _____ ug/L Sine ( ) ________ 0.53 mg/L

Sodium (00929) _______ 2*8 mg/L Bicarbonate ( ) 3 mg/L

Sulfate (00945) _______ 37S mg/L Oil/Grease ( ) _____ < 10Q _____ mg/L

"XIo PARAMETERS 0SED AS INDICATORS OF GROUND WATER CONTAMINATION

Replicates (must be dona ror upgradienfc

PH (00403) 53t!S- ***S __ Ji i. j ? *?Specific Conductance (00905} (miaromhos) ^00 __ 8W _ __800 635Total Organic Carbon ( ) mg/1 jCj*«J- 0.6 '" T-T™" 0*3MotaL Organic Halogen ( ) mg/L ffTgTT " 0 >011 ""SVoIS "_ '0 •6SU.otal Dissolved Solids (70304) mg/1 ^ SOCT ^ 40^

only)

For Metals Check One: 1« Standard Method ____ or 2* Atomic Absorption __5__

Name, Address and Supervisor of Laboratory Performing Chemical Analysis;

ASW Environmental Consultants, Inc.1701 Union BoulevardAllentovn, PA 18103

^John P. Doughsrty

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• . » « • *l.l -iJ L.L-i.-j.-'--;

Preo^rsd X.D. t

RKPORT ^ No<»8 U84-4»~«(To be submitted ouarterly for one year for all monitoring wells)

ncility tf»me ynff^mt r^TTpt____. Facility Permit Ncunber ________________

ocationt County _Carbon^_ __ ^ Munf cioality

Well Wn. |u>f ^ f ftr* ''-neck Oiies uo_jj do»-n __ gradientXX VMt« Dt«pO««l

.to en to Wciter ;,<- v- .. 39.J_il.- i-l'.-rt.-i,r,>d xx'O»-i: Uind 3uri^ca _ ,_.fco-> of casing

4J.t.5' ; - K :.ttvtf t .io'i oi "iriaa £;».!r-J::i(.-?e __ ..... "- or- too of casing

Viic.ora.ng Well Lor., ,.c;.. ,,^ « i f.,ut',, 4p y51._ ,Q5_.i;Z^ Lonv|.lf. d« ,75 52 ; 3_9

^- £-*3U;ole Collucvv.-;. 10/31/ft4 _. "i tr : of Sapling __ 5:00 P.M.

Kirolft Collectors :- i'. :• INTEXi-ik.rf*- *ix. •«!. rnft- — _—._.• ~- - .

f'A«Ai;«:Ti£R3 Cj-U.JV :.."; A.U^INC 3;,;f V'AH i L i''!'* AS XkU INKING WATER SU I'b/

W _____

(01007 j^.. .„_ _ 4X, _.._..._ -9. - '^thoxvciuci: (.•r'-MSOli.. JJB..3 ______ ug/L

| ,......_..*' '. 3"ox.-)»hena C^^^00)____^l_ _ ____ ._ g/L

4 ,„._ . ,...-j ... 2.. A D ( )V7.)0 _ _ „„<_£„ _______ ug/L

-?^ *• 5-ti' S .XL vox (SxfMJ? < 1

, . , . . ' , ' , . ' - . -.» ! 226, . ......... .<!.. _____ pCi/1

rcor (7

yrl-.-nium (01Z47) 'J/' Tuib.t.Jit

i V5 r ( 0 J.C7 7 ) « u9; Co 1 i f or ui B :j c tor i * ( ) ___ Q ___ pe r'••—-"- - --••-— •-

ftRiOiUI

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ft*..*"-.. :'. O/. i*'' .' V~r VJ

P<j;;v>f' yiAr^c^crt^Ti r^ TOP orrvo "he 7'«bT- •..*:>*** •;: •/i*:ts?:",y /or or.rs ^ - ---

JJ1.5

1701 b^\C-:I roAllen*-.-r-nr PA

w-jn i'r or ' rxc, ell j-V- » " •?;: fllMt. .Of ATM XX

• • . • • • . . , , . . .0.51'• '•;,- 1 • v^^ '. -' .•*-«:•'. : ;•-.. ; ; .

--. ---•.: •: -: t J.. 'flr?<ir T ( J j 0

3«75_ _ $••$„ , . 3. M. _.JtM.2400 2400 2400 2400

A.OWo.0361400

f t i l O i I 12

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Oft

SB 101113

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ASSESSMENT OF WATER QUALITY

ANALYSIS RESULTS FROM THE

TONOLLI SOLID WASTE DISPOSAL

AREA MONITORING PROGRAM

TONOLLI CORPORATION, NESQUEHONING, PA.

INTERNATIONAL EXPLORATION. INC.577 SACKETTSFORD ROAD

WARMINSTER, PA 18974-1386(215) 598-7137

A R 1 Q I I f k August 10, 1984

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TONOLLI CORPORATION

NESQUEHONING, PAVOLUME II, EXHIBIT III

TABLE OF CONTENTS

PAGE

INTRODUCTION . . . . . . . . . . . . . . . . . . 1

BACKGROUND INFORMATION ............. 2

METHODS OF ANALYSIS . . . . . . . . . . . . . . 3

ANALYSIS OF STUDENT'S T PARAMETERS . . . . . . . 4

pH '". ' . . . . . . . . . . . .". ~Y"V . . ——4 -

SPECIFIC CONDUCTIVITY ......... 6

TOTAL ORGANIC CARBON . . ....... 8

TOTAL ORGANIC HALOGEN ......... 8

TOTAL DISSOLVED SOLIDS . . . . . . . . 11

KEY INDICATOR PARAMETERS ............ 11

LEAD .................. 13

ARSENIC ................ 18

SULFATE ................ 20

CONCLUSIONS .................. 23

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INTRODUCTION

Tonolli Corporation, located in Nesquehoning, Pa., recycles lead

batteries. As a result, a tsolid waste disposal landfill was installed

in 1978 on the site. Surrounding this landfill, 9 monitor wells

have been installed and 2 stream stations established to monitor

any potential escape of wastes from the landfill.

Sufficient sampling has occurred for over a year in order to

establish an initial background analysis of the site. At this

time it is normal procedure to employ the Students1 T method of

statistical analysis on the laboratory results to determine

whether contamination is present in monitor samples downgradient

of the landfill sites. Unfortunately, analysis results ques-

tion the validity of the upgradient wells as being true back-

ground wells intended to be unaffected by the landfill.

In addition, there is significant evidence from Well Number 9

indicating a potential escape of wastes from the landfill.

The primary purpose of this assessment report is to determine:

1. The reliability of the upgradient wells as back-

ground wells unaffected by the landfill contents.

2. Which wells, if any, indicate the presence of

contaminants emanating from the landfill site.

3. If wastewater is leaving the landfill, is the method

of escape through leakage or by the more probable

overflow of the lined landfill.

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•BACKGROUND INFORMATION

Tonolli Corporation's current solid waste disposal facility

has been in operation since 1975 under a D.E.R. permit issued

in 1974. Part A of the Application for a Hazardous Waste

Management Facility was submitted in November of 1980, and

Part B has recently been submitted.

Used in this assessment report are water sample analyses of

Wells 2 through 9 and stream stations 1 and 2. Installation of

Wells 2 and 3 were completed in October of 1976. Wells 4 and 5

were installed in April of 19.78, Well 6 was installed in

February of 1982 and Wells 7, 8 and 9 were installed in December

of 1983. Well 7 was drilled to replace Well 5 which silted up

after the March 24, 1983, sampling date-and was subsequently

'abondoned. Well 8 replaces Well 6, which shall be covered by

the proposed raising of the existing landfill berm. Well 4 will also

be abandoned when the third landfill area is completed over its loca-

tion. Well 9 is a shallow well designed to test the perched

aquifer resting upon the silty clay layer which underlies the

coal refuse layer and overlies consolidated river gravels and

sandstones.

Samples could not be collected at stream site 1 on October 8,

1983, on account of the Nesquehoning stream being dry. Samples

were not collected as a result of inaccessibility from Monitor

Well 4 on October 8, 1983, and January 12, 1984. In addition,

the D.E.R. collected duplicate samples for in house analysis on

- 2 -

I O I I I 7

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June 9, 1983.

METHODS OF ANALYSIS

Comparative statistical analysis of data, especially with a

small sample group, depends greatly upon the initial presumption

that the background, or uncontaminated wells, are unaffected by

the contaminant source. In order to determine this, graphical

plots were made of the myriad of analyses results. These plots,

drawn for each well and both stream stations, allow a visual inter-

pretation of the data that assists in: %

1. Locating erratic data that may not accurately

represent the true water quality and be indica-

tive of laboratory or sampling errors.

2. Determining background water quality by delinea-

ting analysis groupings.

3. Analyzing yearly fluctuations of water quality

that can indicate variations resulting from

unaccountable factors such as precipitation or

stream flow rates.

Graphic analysis of the data is presented in two groupings. The

first group represents parameters required in a Student-T analyses;

pH, conductivity, total organic carbon, total organic halogen and

total dissolved solids. Since these parameters often generalize

water quality, key indicator parameters were selected for investi-

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gation that can indicate more clearly the presence of contami-

nants specific to the wastewater stored in the landfill. The key

indicator parameters chosen for investigation are lead, arsenic

and sulfate. Lead and arsenic are present in exceedingly high

quantities in the landfill waters (107,000 and 5,200 ppb, respec-

tively) , and sulfate is relatively low in concentration in the

landfill waters (200 ppra), but high in concentration in some rnoni*

tor wells (8,500 ppm) to warrant further investigation..

The following discussions interprete the plots of each parameter.

Chemical analysis of the landfill wastewater is plotted as a triangle

on the vertical axis of the graphs and D.E.R. duplicate analysis

performed on June 9, 1983, samples are plotted as dots within

circles. Monthly precipitation values for the area are presented

at the end of this discussion. A compilation of all laboratory

analyses is included in the appendix to this report.

\ANALYSIS OF STUDENT'S PARAMETERS

pH is an indicator of free hydrogen ions in solution. If water

reflects a pH of less than 7, it is acid; and more than 7, it is

alkaline. The background pH range for the monitor well waters

is 3.5 to 4.5. For stream waters it is higher on account of

dilution by purer waters upstream and ranges from 5.5 to 6.5.

The abrupt decrease in the pH of stream sample 2 beginning on

January 12, 1984, is the result of collecting water from the

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7.0

6.0 -

5.0 -

4.0 -

EttChemical Analysis at Tonolli Site

LEGEND FOR ALL PLOTS• - Monitor Well Analysis* - Stream Station Analysis0 - Analysis Performed by D.E.R.*• - Independent Analysis done on

Pit E and 9 Prior to WellInstallation on 12/17/83

/\ - Analysis of Lagoon Water col-lected on 4/30/84

— — Baseline Limits

3.01/25/83 3/24/83 6/9/83 10/8/83 1/12/84 4/12/84

°*U SAMPLING DATES

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landfill/coal refuse side of the stream, not from the opposite

refuse free bank, which was the originally tested bank. This

indicates that the revised sampling location is more accurately

testing waters emanating from the site.

The pH of 5.8 for Well 8 on April 12, 1984, was confirmed in the-

field during collection by INTEX who recorded a pH value of 6.0.

Well Number 9'has a consistently high pH value that may be from

dilution by shallow surface water infiltration although a more

complicated explanation may be appropriate as the shallow sur-

face pit "E" had a pH of 9.0 on December 12, 1983.

Specific Conductivity

Specific conductivity has been measured in micromhos and is a

method of describing the electrical conductivity of water by

indicating the amount of free ions in solution. The larger the

concentration of ions in solution, the greater the conductivity

of the liquid.

The background conductivity for waters in the area is below 1,000

micromhos. Wells 7 and 8 are marginally within background limits

Well 9 maintains an abnormally high conductivity in the 15,000 to

10,000 microhos range. This is substantially higher than up-

gradient waters collectd from pit "E" which had a conductivity

of less than 200 micromhos. The anomalously high conductivity of

Well 5 on January 25, 1983, is questionable, but similar trends

are seen in total disolved solids and sulfate levels; thus,

supporting its validity.

f l R I O i 1 2 1

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SPECIFIC CONDUCTIVITY

CHEMICAL ANALYSIS AT TONOLLI SITE

2000 -

1000 --

—i—————— —I i i » i1/25/83 3/24/83 6/9/83 10/8/83 1/12/84 4/12/84

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The trends in conductivity seen in Wells 3 and 6 do not directly

correlate with precipitation trends. Firm conclusions cannot

be made concerning these wells other than they are suspect of con-

tamination as is Well 9 by a parameter such as sulfate that is

present in acid mine drainage.

Total Organic Carbon (TOC)

Total organic carbon (TOC) is a measure of the concentration

of organically bound carbon that includes any biomass including

coal. The background range of TOC is between 4.1 and 1.0.

Stream location 2 had a very low TOC value on January 12, 1984,

probably as a result of the cold weather limiting organic growth.

Well 9 is abnormally high in TOC ranging from 150 to 260 ppm.

Well 4 had an anomalously high TOC value on June 9, 1983. The

validity of the analysis of Well 4 is questionable especially

since the DER analysis indicates a reasonable value of 4.5 ppm.

Well 7 shows an extreme peak on January ,12, 1984, that may be

the result of the flushing of coal refuse from the well when it

was first operated, although previous flushing had been performed.

Only Well 9 is truely suspect of contamination; however, the

contaminant is probably coal silt or carbonaceous refuse in which

the well is located.

Total Organic Halogen (TOH)

Total organic halogen (TOH) is a measure of the organic halides

such as chlorine, bromide, iodine that are compounds in water

Milan 23

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7.0

6.0

5.0

§14.0

0 -

2.0 -

1.0 ,

TOTAL ORGANIC CARBON

Chemical Analysis at Tonolli Site

Well 9 Not to Scale

1/25/83 3/24/83 6/9/83 10/8/83 1/12/84 4/12/84

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.07

,06 -

.05 -

.04-Cne

.03 -

02 --

01 .

TOTAL ORGANIC HALOGEN

CHEMICAL ANALYSIS AT TONOLLI SITE

For Sample Dates 1/25/83 thru10/8/83 all measurementsregistered <0.05. After10/8/83 an improvedtechnique gave the followingda ta. " - --- - -

1/25/83 3/24/83 6/9/83 10/8/83 1/12/84 4/12/84

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such as trihalomethanes, pesticides and chloroform. Limited

data is available on this parameter as a result of less accurate

instruments involved in the analysis procedure used prior to

January 12, 1984, The available data suggests a general decline

in TOH values from January to April of 1984 in all wells. Well 9

and 3 are highest in TOC while background wells 7 and 4 have the

lowest values.

Total Dissolved Solids (TDS)

Total values for dissolved solids (TDS) indicates the amount of

materials in solution. Background values are generally below

800 ppm. The trends and interrelationships of TDS values for

the various monitoring wells is very similar, as is expected,

with the specific conductivity values; thus, confirming analysis

validity. Wells 9 and 3 and the January 1983 value of Well 5

are high and Well 6 is marginally high in TDS.

KEY INDICATOR PARAMETERS

A chemical analysis of the landfill waters indicates high concen-

trations of metals. Unfortunately, acid mine drainage is often

high in trace and heavy metals. The difficulty lies in differen-

tiating between the influences of acid mine drainage and the

landfill waters. The parameters previously discussed are too

general to develop sound conclusions about the site since numerous

secondary factors exist to influence their values.

A review of the components present within the landfill waters

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5000

4000 -

3000 -

2000 -

TOTAL DISSOLVED SOLIDS

CHEMICAL ANALYSTS AT TONOLLI SITE

1000 -

Well 9 Not toSeal e

1/25/83 3/24/83 6/9/83 10/8/83 1/12/84 4/12/84

SAMPLING DATES-AIMIHI 27

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revealed two parameters that are unique to the environment.

These key parameters are lead and arsenic which are present in

the landfill at 107,000 and 5,200 ppb, respectively. Unfortunately.

lead is also a product of acid mine drainage but in much lower

concentration, and it may enter the site by air from the company

stacks. Arsenic can also be a product of acid mine drainage but

in-lower concentrations.

In addition, sulfate, which is in very high concentrations in

acid mine drainage but low in the landfill waters is studied.

Interest lies in using it to determine the ability of the silty

clay layer to prevent surface waters from entering the deeper

aquifer as well as providing evidence for determining wells that

may be sampling waters from the shallower perched aquifer.

Lead

Background lead levels are generally below 40 parts per billion

(ppb), which is within the acceptable drinking water limit of

50 ppb. One important concern is the peak in lead levels for

all of the monitor wells sampled on June 9, 1983. Review of the

DER duplicate analysis for that same date indicates that the anoma-

lous highs are probably the result of error in analyses. Thus,

the DER data has been incorporated into the graph to more accu-

rately develop our conclusions.

The most obvious trend is the very high levels of lead in Well 9

indicating that escape of landfill waters has occurred. The sub-

stantial decline in Well 9's lead levels from 5,600 to 503 is

ARID 11283 -

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300

a.IH

Oi 200

100 4

LEAD

Chemical Analysis at Tonolli Site

. 5(000

A/\ 107.000

Well 9 Not to Scale

1/25/83 3/24/83 6/9/83 10/8/83 1/12/84 4/12/84SAMPLING DATES,.

- 14DATES.. t . AAAJtl 0-1129

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300 -

a

rH

^ 200 H

100 -

LEAD

Chemical Analysis at Tonolli SiteUsing D.E.R. Data for 6/9/83

x107.000 73°

Well 9 Not to Scale

1/25/83 3/24/83 6/9/83 10/8/83 1/12/84 4/12/84

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believed to be the result of improved sampling techniques. Thus,

a lead level of 503 ppb is believed to be more realistic. The

rapid decrease of lead levels in Wells 7 and 8 from January to

April of 1984 raises suspicion on January's results. Therefore,

more data is necessary to develop firm conclusions on Wells 7 and 8,

Well 4, which also was above background levels in 1983, shows an

improvement in the quality of April's analysis, placing suspicion

on the sampling procedure of Well 4 in the past. Of importance

is the fact that Well 4 was the only well in early 1983 that had

high lead levels.

Well 3 has a trend in lead levels that provides important evidence

to support the escape of landfill waters by overflowing rather than

leakage. The only time Well 3 exceeded background levels was

following extended periods of extremely high rainfall when the

landfills would most likely overflow (Figure 1). During the summer/

fall drought of 1983, lead levels declined substantially. If a

leakage were occurring, then lead levels would increase from the

decline in volume of diluting rainwaters. Thus, this further

supports overflowing as the major cause for landfill water escaping

into the ground. The moderately high lead level in pit "E" indi-

cates the presence of lead in the vicinity of Well 4; perhaps, from

airborne sources.

Arsenic

The background level for arsenic in the samples is below 10 ppb,

well below the accepted limit of 50 ppb for domestic water use.

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200

150 H

_aCL,Q-.

loo H

so A

ARSENIC

CHEMICAL ANALYSIS AT TONOLLI SITE

8405*200

Well 9 Not to Scale

1/25/83 3/24/83 6/9/83 10/8/83 1/12/84 4/12/84

DATES

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Well 9 is exceedingly above background levels but has improved

to 380 ppb, probably as a result of improved sampling techniques.

Well 3, being above background levels, shows a general increase

in arsenic since January 25, 1983. This may be an indication

that waters began escaping from the landfill sometime after

January of 1983. The validity of the DER value for arsenic in

the April 9, 1983, sample is questionable as it Hoes not fit the

trend. The high value for arsenic in stream sample 2 on October 8,

1983, creates an extreme change in water quality and its validity

is questioned. It also contradicts most other analyses of this

station for other parameters such as specific conductivity and

lead. Well 5 and 7, supposedly background wells, have unexplain-

ably high levels of arsenic. Well 6 has arsenic levels that indi-

cate it to be marginally free of contamination.

Sulfate

Sulfate levels in the landfill waters are relatively low (200 ppm)

in relation to values found in some of the monitor wells that

exceed 4/000 ppm. Sulfate is an abundant product of acid mine

drainage that is proliferous in the area as a result of the ex-

posed coal refuse. Sulfate also is not easily diluted. Thus,

sulfate is a good indicator of contamination of the wells by

acid mine drainage from the overlying refuse.

Background levels of sulfate are difficult to determine. One

group of wells (4 & 2) have low levels below the 250 ppm USPHS

water quality limit and landfill water concentrations. Wells 6,

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SULFATE

CHEMICAL ANALYSIS AT TONOLLI SITE

6500

4000

Well 9 Nto Scale

1/25/83 3/24/83 6/9/83 10/8/83 1/12/84 4/12/84

- 21 -

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7 and 8 have moderately low levels of sulfate between 250 and

750 ppm which is above the concentrations in the landfill waters.

Well 9, with a sulfate level of 8,000 ppm, has over twice the

concentration of that found in Well 3. The sulfate level in

Well 3 peaked on October 8, 1983, probably as a result of the

summer drought causing a reduction in rainwater dilution. The

erratically high sulfate level in Well 5 on January 25, 1983,

questions the validity of the sample. In addition/ the analysis

results of pit "E" and 9 collected on December 12, 1983, are

questionable.

The analysis results indicate that Well 9 is sampling acid mine

drainage water as expected and that Well 3 is also sampling these

waters, but they are being diluted by purer waters of the deeper

protected aquifers.. Wells 5, 6, 7 and 8 may be intercepting the

perched waters. It is believed that the construction of the

wells is responsible for the occurrence of shallow waters and not

the inability of the silty-clay layer to retard infiltration as

Wells 4 and 2 have relatively pure water.

JHHOH37

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CONCLUSIONS

Through a graphic review of the analyses results, the following

important conclusions regarding the monitoring site can be made:

1. Well 4 is marginally acceptable as a background well

using the information obtained to date. Conductivity,

pH, TDS/ sulfate and arsenic levels in the-well fall

within background limits. Not enough data exists to

properly evaluate TOH, although indications point

towards it being at acceptable levels. In contrast

to Well 4, being a suitable background well, are the

abnormally high levels of TOC and, more importantly,

lead even when incorporating the DER data for June 9,

1983. The moderatly high lead levels of the well in

1983 may be the result of ineffective cleaning techniques

for well sampling. Therefore, it is recommeded that

further samples be analyzed prior to condeming this well.

2. The usefulness of Wells 5 and 7 as background wells is

also questioned for reasons similar to Well 4. Further

analysis of Well 7 will provide a better understanding

of its behavior.

3. Contamination of waters from the landfill is

strongly believed to have occurred in Monitor Wells 9

and 3. The best indicators of contamination in the

waters are lead and arsenic. Both parameters are at

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exceptionally high levels in Well 9. This indicates

that the shallow well is suitably designed for moni-

toring groundwater contamination thought to exist

primarily on top of the silty-clay layer at the base

of the coal refuse. Well 3 is believed to monitor

both the shallow and confined deeper aquifers, thus,

accounting for its lower contaminant concentrations.

Well 6 and possibly 4, 5 and 7 may be collecting

small amounts of the contaminated shallow perched

aquifer water. Sulfate levels support this belief.

The difficulty at this site lies in the fact that

the majority of the wells are testing primarily the

quality of the deeper confined aquifer. The results

do strongly suggest that the deeper aquifer has re-

mained relatively pure and free of hazardous sub-

stances; primarily as a result of the overlying

confining silty-clay layer and the high water table

ne ar the s tream.

4. The discrepency between DER and Tonolli analyses

for lead on the June 9, 1983, samples had been

believed to be the result of field filtering of

only the DER samples. Tonolli samples have 'always

been lab filtered only. Thus, since Tonollifs

sampling procedure has never changed, the anoma-

lously high lead readings for the June samples

cannot be blamed on the lack of field filtering.

fti Kbk i-3 9

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Two separate samples were collected on April 12/

1984, to test this theory. One set was field, then

lab filtered; while the other was lab filtered only.

The results presented in Appendix III indicate a

minor but improved difference between analyses.

Field filtering is a more accurate means of obtaining

valid water samples and shall be done on all future

samples.

5. The trend of lead levels in Well 3 closely parallels

precipitation events, providing important evidence to

support the belief that the majority of water escaping

the landfill is caused by overflow. Lead concentration

peaked in Well 3 on June 9, 1983, after a tremendously

wet spring. It quickly declined in October of 1983

in response to the summer drought.

January's low rainfall also kept lead levels low.

Lead concentrations rose sharply in April of 1984 as

did rainfall rates. Arsenic levels roughly support

this belief although the slower suspected migration

rate of arsenic as a result of the site conditions

may cause the more muted response.

Thus, available evidence suggests that overflow of the landfill

lagoon may occur during periods of high rainfall. This would

cause the escape of storage liquids into the subsurface coal

refuse. Migration of the liquids through the ground is believed

ARIOIUO- 25 -

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to be restricted by the silty-clay layer found at the base of

the coal refuse. Wells intercepting this perched aquifer are

best suited for evaluating the success of remedial abatement

actions. The key indicator parameter for the site is lead,

which with its relatively rapid migration response under the

acidic condition of the site, is an ideal indicator of ground-

water contamination.

- 26 -ARiQi

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APPENDIX I

COMPILATION OF TONOLLI

LABORATORY ANALYSES

MHOMH2

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CHEMICAL ANALYSIS RESULTS

^cation:

arsenic (ug/1)Jarium (ug/1)-adnium (ug/1)Chromium (ug/1 )'loride (ug/1)jead (ug/1)lercury (ug/1)litrate (ug/1)lelenium (ug/1 )Jilver (ug/1)Sndrin (ug/1)jindane (ug/1)lethoxychlor (ug/1 )?o- -^phene (ug/1)2; -D2,4,5-TP Silvex (ug/1)Radium (pCi/1)Sross Alpha (pCi/1)aross Beta (pCiyi)Turbidityi (TU):oliform (per 100 ml)

•)ride (mg/1):ron (Total (mg/1)langanese (mg/1)3henol (mg/1 jJodium (mg/1)Julfate (mg/1)antimony (mg/1 ):opper (mg/1)5:i • (mg/1)Bicarbonate (mg/1 ))il/Grease (mg/1)

>HSpec. Cond* (micromhos)Total Org. Carbon (mg/1)Potal Org. Halogen (mg/1Total Dis. Solid (mg/1)

3411

-= 50rM.Q

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CHEMICAL ANALYSIS RESULTS

ition:

rsenic (uq/1)arium (ug/1)adnium (ug/1)hromium (ug/1)loride (ug/1)ead (ug/1)ercury (ug/1)itrate (ug/1)elenium (ug/1)ilver (ug/1)ndrin (ug/1)indane (ug/1)ethox^chlor (ug/1)ol phene (ug/1),4-D',4,5-TP Silvex (ug/1).adiuxn (pCi/1)ross Alpha (pCi/1)ross Beta (pCi/1)'urbidity (TU)oT iform (per 100 ml)

hloride (mg/1)ron (Total (mg/1)anganese (mg/1)henol (mg/1)odium (mg/1)ulfate (mg/1)ntimony (mg/1)o- er (mg/1)i. „ (mg/1)icarbonate (mg/1 )il/Grease (mg/1)

Hpec* Cond. (micromhos)otal Org. Carbon (mg/1)otal Org. Halogen (mg/1otal Dis. Solid (mg/1)

<: 3.0^ ISO^>. o&>.ono3.nLu^oo-<-3,O•< ».O•< G.GQX^ 0.01-=- O.CQ-« O- 1-< O.Q3<0.rsn;3•< 1.0< 0>t*•* /.oe\.i£>.n/o.o0..-3--/a.onq

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CHEMICAL ANALYSIS RESULTS

cation: TOMO///' < c£p-,N&£XXihorii*Jq , "^ • //£> A/rfe/g/A/.D o c

Date Sampled;__________//a5/»3 3/e>-f/g3 &A/83 /Q/sA? tli3J%4

\rsenic (ug/1)Barium (ug/1)-adnium (ug/1)Chromium (ug/1)?loride (ug/1)[jead (ug/ljMercury (ug/1)titrate (ug/1)Selenium (ug/1 )Silver (ug/1)Sndrin (ug/1)Jindane (ug/1)flethoxychlor (ug/1)Fc; -^phene (ug/1 )2, --D2,4,5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Sross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)

Hporide (mg/1) -Iron (Total (mg/1)Manganese (mg/1)Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1 )hooper (mg/1)Z> - (mg/1)Bicarbonate (mg/1 )Oil/Grease (mg/1 )

PHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1Total Dis. Solid (mg/1)

•*«33<5IO/c3inn!fC*o.znLOO0<3

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CHEMICAL ANALYSIS RESULTS

location:iDate Sampled;________,j,3S/X3 3/34/83 £/?/83 /O/g/g3 I fa

Arsenic (ug/1)Barium (ug/1)Cadnium (ug/1 )Chromium (ug/1)Ploride (ug/1)Lead (ug/1)Mercury (ug/1)Nitrate (ug/1)Selenium (ug/1)Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1 )T: aphene (ug/1)2, ,-D2,4,5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)

* loride (mg/1)Iron (Total (mg/1)Manganese (mg/1)Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1 )Cooper (mg/1)2 c (mg/1)Bicarbonate (mg/1 )Oil/Grease (mg/1)

PHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1Total Dis. Solid (mg/1)

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Page 84: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

,W?ation:

Date Sampled:__________//IS/93 3/H j$3 6>A

Arsenic (ug/1)Barium (ug/1) /COCadnium (ug/1) OChromium (ug/1)Floride (ug/1) 25 0 CLead (ug/1)Mercury (ug/1) .O.f? -=••0.Nitrate (ug/1) fl 6To o eSelenium (ug/1) nSilver (ug/1) . D u 7. {£7

Endrin (ug/1)Lindane (ug/1) •<•' o.o/ -<• o.oi 005Methoxychlor (ug/1) o.

iphene (ug/1) o.l / . O /.O /.oo.ou

2,4,5-TP Silvex (ug/1) 0x05" < C-OOfT O.OObRadium (pCi/1) /.o /.oGross Alpha (pCi/1) 7.O r 5,-f ••*;?. o /O. OGross Beta (pCi/1) r . i: 0/7 i 5 ±Turbidity (TU) 5". 0Coliform (per 100 ml) JL

oride (mg/1) //OIron (Total (mg/1) A HOManganese(mg/1)Phenol (mg/1) too /cc <too o.c/A6i| < /OC- /OOSodium (mg/1) foOXSulfate (mg/1) 3,3*50Antimony (mg/1) O. 003 OJOR O.3I O..M3-Copper (mg/1) 0- O O.C4

c (mg/1) l.tetBicarbonate (mg/1) 30 /OOil/Grease (mg/1) I.C A3 /.o < /. o /.O

pHSpec. Cond.(micromhos) 5; 5-900 3", /COTotal Org. Carbon(mg/1)Total Qrg. Halogen(mg/1 r.cviTotal Pis. Solid(mg/1) .530 /."?;#?*

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Page 85: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

.rsenic (ug/1)iarium (ug/1)ladnium (ug/1)Jhromium ( ug/1 )'loride (ug/1)*ead (ug/1)iercury (ug/1)litrate (ug/1)Jelenium (ug/1)lilver (ug/1)Indrin (ug/1)jindane (ug/1)lethoxychlor (ug/1 )?c phene (ug/1)»,«4-D2,4,5-TP Silvex (ug/1)Radium (pCi/1)Sross Alpha (pCi/1)^ross Beta (pCi/1)Purbidity (TU)oliform (per 100 ml)

Juxoride (mg/1 )Tron (Total (mg/1)langanese (mg/1 )'henol (mg/1)Jodium (mg/1)Sulfate (mg/1)Antimony (mg/1 )-o^oer (mg/1)3. . (mg/1)Bicarbonate (mg/1))il/Grease (mg/1)

3H

Spec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1Total Dis. Solid (mg/1)

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Page 86: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHBMXCAL ANALYSIS RESULTS

cations

Arsenic (ug/1)Barium (ug/1)Cadnium (ug/1)Chromium (ug/1)Floride (ug/1)Lead (ug/1)Mercury (ug/1)Nitrate (ug/1)Selenium (ug/1 )Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1)T| aphene (ug/1)2,-i-D2,4,5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TO)Coliform (per 100 ml)

(Blor ide (mg/1 )Iron (Total (mg/1)Manganese (mg/1 )Phenol (mg/l)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1)Cooper (mg/1)2 c (mg/1)Bicarbonate (mg/1 )Oil/Grease (mg/1)

PHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1Total Dis. Solid (mg/1)

f '*~in .0ICO/•3Lj>\4. nsite5.0c?7- O/7 cooeP3

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Page 87: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

^.//tAM Ob/CP.^ D

Date Sampled:__________//3S/g3 a/rt/gj

Arsenic (ug/1)Barium (ug/1)Cadnium (ug/1 )Chromium (ug/1)Florida (ug/1)Lead (ug/1)Mercury (uq/1)Nitrate (ug/1)Selenium (ug/1)Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1)T* aphene (ug/1)2,4-D2,4,5-TP Silvex (ug/1)Radium (pCi/1)Gross1 Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)

Culoride (mg/1)Iron (Total (mg/1)Manganese (mg/1 )Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1)Copper (mg/1)2 c (mg/1)Bicarbonate (mg/1)Oil/Grease (mg/1)

PHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1!Total Dis* Solid (mg/1)

r .0-* /oo-7KO*.0

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Page 88: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

Creation; fMC>l ^D. N 'tO&h&Mt H<3 Tc3

Date Sampled;__________//<aS/S3 3J*4J** 6/S/frS. /fl/S/?3 l

Arsenic (ug/1)Barium (ug/1)Cadnium (ug/1)Chromium (ug/1)Floride (ug/1)Lead (ug/1)Mercury (ug/1)Nitrate (ug/1)Selenium (ug/1)Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1)Tc aphene (ug/1)2\ .-D2r4,5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)

j Boride (mg/1 )j?on (Total (mg/1)Manganese (mg/1 )Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1 )Copper (mg/1)Z 2 (rag/1)Bicarbonate (mg/1 )Oil/Grease (mg/1)

PHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org . Halogen (mg/1 ;Total Dis. Solid (mg/1)

-

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Page 89: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

nation: /6A/O/// Cfo*gO.,

Arsenic (ug/1)Barium (ug/1)^adnium (ug/1)Chromium (ug/1)Florida (ug/1)Lead (ug/1)Mercury (ug/1)Nitrate (ug/1)Selenium (ug/1)Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1)T( aphene (ug/1)2,-^-D2,4,5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)

Liiloride (mg/1)Iron (Total (mg/1)Manganese (mg/1)Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1)Conper (mg/1)Z 2 (mg/1)Bicarbonate (mg/1 )Oil/Grease (mg/1 )

PHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1Total Dis. Solid (mg/1)

*

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Page 90: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

: /GMO///

Date Sampled;__________//as/g3____3#W?J? 6> A As /o/s- /£3Y—-/ —————/—^-———7^———"7 /rwArsenic (ug/1)Barium (ug/1)Cadnium (ug/1)Chromium (ug/1)Floride (ug/1)Lead (ug/1)Mercury (ug/1)Nitrate (ug/1)Selenium (ug/1)Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1){ xaphene (ug/1)2,4-D2,4,5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)

"hloride (mg/1 )Iron (Total (mg/1)Manganese (mg/1)Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1)^">pper (mg/1)-nc (mg/1)

Bicarbonate (mg/1)Oil/Grease (mg/1 )

PHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org . Halogen (mg/1 '.Total Dis. Solid (mg/1)

5?4D/OO(03,

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Page 91: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

[

CHEMICAL ANALYSIS RESULTS

nation: /f'Ajr/f/ \ tv//0O77 jJ . M^f/O^Ai'M^->ri .,' [c3

Date Sampled;

Arsenic (ug/1)Barium (ug/1)Cadnium (ug/1)Chromium (ug/1 )Floride (ug/1)Lead (ug/1)Mercury (ug/1)Nitrate (ug/1)Selenium (ug/1)Silver (uq/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1)Tr1 phene (ug/1)2i -D2,4,5-TP Silvex (ug/1)Rad i urn (pC i/ 1 )Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)

w~xoride (mg/1)Iron (Total (mg/1)Manganese (mg/1)Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1)Copper (mq/1)z: ; (mg/1)Bicarbonate (mg/1 )Dil/Grease (mg/1 )

pHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1Total Dis. Solid (mg/1)

0- 06./3C£-'TlrCC'.

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APPENDIX II

COMPILATION BY D.E.-R.

OF ALL LABORATORY ANALYSES

Page 93: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

f r

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Facility

^ TO NO.L ' Monitorin

Name f OAJ Qx^ /

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Date 1 f-=Z3&

Analysesi , . ————— .- —— , —————— . —————————T°C jr - ——— — - - - - - —— - ----- - ——— 3 ......... .,..-... .

pH (00403) f •' j

Specific Conductance (micromhos) j

Total Organic Carbon mg/l . i

Total Organic Halogen mg/L '» 1 >•• IfclV 1 1 !<•••»••••• 1

Total Dissolved Solids mg/1 - i

Chloride mg/L ' f

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iron (Total) mg/L j . : ;1 j ' '• ' "'"" ""L1.

Manganese mg/L ] '

Phenol ug/L } •

Sodium mg/L j

.

Sulfate mg/L '.

Lindane ug/L l ;

Methoxychlor ug/L t|

Toxaphene ug/L 1

2, 4-D . , ug/L J

2, 4, 5-TP Siivex ug/L J1

i 1

Radium \ pCi/1 j ,. ' :•1

Gross Alpha pCi/1 j • .. J*

Gross Beta millirem/ j J

Turbidity TU ' j

Coliform Bacteria per 100 ml

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Page 103: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

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APPENDIX III

FIELD VERSUS NON-FIELD

FILTERED ANALYSIS RESULTS

FOR APRIL 12, 1984, SAMPLES

A f i i O l 170

Page 108: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

^cation:

Date Sampled:re «. t o

Arsenic (ug/1)Barium (ug/1)Cadnium (ug/1 )Chromium (ug/1 )Floride (ug/1)Lead (ug/1)Mercury (ug/1)Nitrate (ug/1)Selenium (ug/1)Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1)T, aphene (ug/1)2\ ,-D2, 4 , 5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)

toride (mg/1)n (Total (mg/1)

Manganese (mtf/1)Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1 )Cooper (mg/1)2 c (mg/1)Bicarbonate (mg/1 )Oil/Grease (mg/1)

PHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1Total" Dis. Solid (mg/1)

' •-——— ; j- •_•„--

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Page 109: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

"•cation:

Date Sampled:

Arseriic (ug/1)Barium (ug/1)Cadnium (ug/1)Chromium (ug/1)Floride (ug/1)Lead (ug/1)Mercury ( ug/ 1 )Nitrate (ug/1)Selenium (ug/1)Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1)^ :aphene (ug/1)2>4-D2, 4, 5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)

i^nloride (mg/1)Iron (Total (mg/1)Manganese (ma/1)Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1)Copper (mg/1)

'• ic (mg/1)Bicarbonate (mg/1 )Oil/Grease (mg/1 )

PHSpec. Cond. (micromhos)Total Org, Carbon (mg/1)Total Org. Halogen (mg/1!Total Dis. Solid (mg/1)

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Page 110: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

cation: £o£pO£3~//CM , hksguehQMJMQ . la . ^xJeJ/ </

Date Sampled;

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pH 'Spec. Cond* {micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1Total Dis. Solid (mg/1)

A2.OGOO9,0/35lo.L*O.3L 3OO^ ?.O< /.o0.005*•^o-oio.oa.

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Page 111: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

->cation:

Date Sampled;

Arsenic (ug/1)Barium (ug/1)Cadnium (ug/1 )Chromium (ug/1)Floride (ug/1)Lead (ug/1)Mercury ( ug/ 1 )Nitrate (ug/1)Selenium (ug/1)Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1)} caphene (ug/1)2, 4-D2, 4, 5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1).Gross Beta (pCiyi)Turbidity (TU)Coliform (per 100 ml)

chloride (mg/1)Iron (Total (mg/1)Manganese (nuj/1)Phenol (mg/1)Sodium (mq/1)Sulfate (mg/1)Antimony (mg/1)r->pper (mq/1)nc (mg/1)

Bicarbonate (mg/1)Oil/Grease (mg/1)

PHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org . Halogen (mg/1 ;Total Dis. Solid (mg/1)

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Page 112: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

Location: *4Date Sampled;

Arsenic (ug/1)Barium (ug/1)Cadnium (ug/1)Chromium ( ug/1 )Floride (ug/1)Lead (ug/1)Mercury (ug/1)Nitrate (ug/1)Selenium (ug/1)Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1)T^xaphene (ug/1 )i <-D2, 4 , 5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)Mk^loride (mg/1)"on (Total (mg/1)Manganese (mg/1)Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1)Copper (mg/1)' ic (mg/1)Bicarbonate (mg/1 )Oil/Grease (mg/1)

PHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org . Halogen (mg/1Total Dis. Solid (mg/1)

10I4L>

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Page 113: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

1

CHEMICAL ANALYSIS RESULTS

Tocation:

Arsenic (ug/1)Barium (ug/1)Cadnium (ug/1)Chromium (ug/1)Floride (ug/1)Lead (ug/1)Mercury (ug/1)Nitrate (ug/1)Selenium (ug/1 )Silver (ug/1)Endrin (ug/1)L i ndane ( ug/ 1 )Methoxychlor (ug/1)i <aphene (ug/1)k,4-D2, 4 , 5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)

^nloride (mg/1)Iron (Total (mg/1)Manganese (mg/1)Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1 )Copper (mg/1)\ ac (mg/1)Bicarbonate (mg/1 )Oil/Grease (mg/1)

PHSpec, Cond. (micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1Total Dis. Solid (mg/1)

/L14-415

o?5TO51

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Page 114: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

Location: i (2

Date Sampled: -4iL-re/ h p{?iferEjeE£ H/ FPetffiKlt

Arsenic (ug/1)Barium (ug/1)Cadnium (ug/1)Chromium (ug/1)Florida (ug/1)Lead (ug/1)Mercury (ug/1)Nitrate (ug/1)Selenium (ug/1)Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1)-1" xaphene (ug/1).,4-D2, 4, 5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)•b•loride (mg/1):on (Total (mg/1)Manganese (mg/1 )Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1)Copper (mg/1)

nc (mg/1 )bicarbonate (mg/1 )Oil/Grease (mg/1)

PHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1Total Dis. Solid (mg/1)

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Page 115: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

Tocation:

Date Sampled:

Arsenic (ug/1)Barium (ug/1)Cadnium (ug/1)Chromium (ug/1)Florida (ug/1)Lead (ug/1)Mercury (ug/1)Nitrate (ug/1)Selenium (ug/1)Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1)r xaphene (ug/1)1,4-D2, 4, 5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TO)Coliform (per 100 ml)

nlor ide (mg/1 )Iron* (Total (mg/1)Manganese (mg/1)Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1)Copper (mg/1); nc (mg/1)Bicarbonate (mg/1)Oil/Grease (mg/1)

PHSpec. Cond, (micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1Total Dis. Solid (mg/1)

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Page 116: v^37' BTC 12 gpm 4:32 P.M. 4:44 P.M. 17. 31 VOLUME OF WATER REMOVED PRIOR TO SAMPLING: 144 gals. AMPLE: • - COLOR: Bright - ODOR: - TEMPERATURE: - CONDUCTIVITY: - pH: SAMPLES COLLECTED:

CHEMICAL ANALYSIS RESULTS

#Qlocation: /OJfJ/i (.bcr>f'£v"TfrOi\i- N (j&?hOi jS l, T<3. UJ*..li ^ /————A———^—£—^^——————————

/ / .Date Sampled:

Arsenic (ug/1)Barium (ug/1)Cadnium (ug/1 )Chromium (ug/1)Floride (ug/1)Lead (ug/1)Mercury (ug/1)Nitrate (ug/1)Selenium (ug/1)Silver (ug/1)Endrin (ug/1)Lindane (ug/1)Methoxychlor (ug/1)T caphene (ug/1)2,-i-D2, 4 , 5-TP Silvex (ug/1)Radium (pCi/1)Gross Alpha (pCi/1)Gross Beta (pCi/1)Turbidity (TU)Coliform (per 100 ml)

t-oride (mg/1)m (Total (mg/1)

Manganese (mg/1)Phenol (mg/1)Sodium (mg/1)Sulfate (mg/1)Antimony (mg/1)Copper (mg/1)l ic (mg/1)Bicarbonate (mg/1 )Oil/Grease (mg/1)

PHSpec. Cond. (micromhos)Total Org. Carbon (mg/1)Total Org. Halogen (mg/1'Total Dis. Solid (mg/1)

3SO153;?a56HOO503-0..7/,50OCQ;oi

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