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Validation of the Ozone Monitoring Instrument Total Ozone Column and
Implications for Trend Studies
M. Kroon1, R.D. McPeters2, J.P. Veefkind1, G. Labow2, D. Balis3, I. Petropavlovskikh4, P.K. Bhartia2, R. Shetter4 and P.F. Levelt1
1.Royal Netherlands Meteorological Institute, 2.NASA Goddard Space Flight Center, 3.Aristotle University of Thessaloniki, 4.NOAA/ESRL, 5.National Center for Atmospheric Research
OMI Science Team Meeting
Helsinki, 24 June 2008
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 2
Total Ozone Column ECS2 > COL3
OMI TOMS V8.5 [DU]OMI TOMS V8.0 [DU]
ECS2COL3 September 2005
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 3
Total Ozone Column ECS2 > COL3
ECS2COL3
DOAS v1.0.5 [DU]DOAS v1.0.1 [DU]
September 2005
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 4
Changing Collection OMI-DOAS
OMDOAO3 algorithm v1.0.5 release for OMI Collection 3 data.
Collection 3 Level 1B has better dark current and stray light corrections yielding better fitting residuals and lower chi-squared.
Treatment of high reflective surfaces (snow/ice) changed. Effective cloud fraction set to zero and surface albedo fitted (~OMTO3).
Airmass factor tables updated. AMF tables primary cause for Solar Zenith Angle dependent bias. New air mass factor tables are based on improved radiative transfer calculations.
Look-up table for cloud radiance fraction updated. New radiative transfer calculations include atmospheric sphericity.
New static irradiance file produced by combining Solar irradiance data of collection 3 for year 2005.
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 5
Changing Collection OMI-TOMS
OMTO3 algorithm v8.5 release for OMI Collection 3 data.
Ingesting daily OMCLDRR (Raman) cloud effective pressure and fraction “CloudFractionForO3” and “CloudPressureForO3”.
Treatment of high reflective surfaces (snow/ice) changed. Cloud fraction set to zero at snow ice fraction >50%.
Jump at Solar Zenith Angle 69º corrected by switching off change in climatological ozone profile used.
Collection 3 Level 1B stray light corrections change yields OMTO3 to drop 6-7 DU on global scale. Under discussion!.
OMSO2 algorithm improved yielding higher SO2 PBL values hence more SO2 polluted pixels correctly flagged hence less influence.
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 6
Total Ozone Column ECS2 > COL3Whole Globe OMITotal Ozone ECS2
260
270
280
290
300
310
320
330
340
Sep
-04
Nov-0
4
Jan
-05
Mar-
05
May-0
5
Jul-
05
Sep
-05
Nov-0
5
Jan
-06
Mar-
06
May-0
6
Jul-
06
Sep
-06
Nov-0
6
Jan
-07
Mar-
07
May-0
7
Jul-
07
Sep
-07
Time (months)
Tota
l O
zon
e C
olu
mn
[D
U]
OMI TOMSOMI DOAS
Whole Globe OMITotal Ozone COL3
260
270
280
290
300
310
320
330
Oct-0
4
Jan-
05
Apr-05
Jul-0
5
Oct-0
5
Jan-
06
Apr-06
Jul-0
6
Oct-0
6
Jan-
07
Apr-07
Jul-0
7
Oct-0
7
Jan-
08
Apr-08
Time (months)
Tota
l O
zon
e C
olu
mn
[D
U]
OMI TOMSOMI DOAS
Closer Match!
Close Match
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 7
Total Ozone Column ECS2 > COL3Whole Globe OMI
Total Ozone Regression ECS2
0.85
0.90
0.95
1.00
1.05
Sep
-04
Nov
-04
Jan
-05
Mar
-05
May
-05
Jul-
05
Sep
-05
Nov
-05
Jan
-06
Mar
-06
May
-06
Jul-
06
Sep
-06
Nov
-06
Jan
-07
Mar
-07
May
-07
Jul-
07
Sep
-07Time (months)
Cor
rela
tion
Reg
ress
ion
RegressionCorrelation
Whole Globe OMITotal Ozone Regression COL3
0.85
0.90
0.95
1.00
1.05
Oct-0
4
Jan-
05
Apr-05
Jul-0
5
Oct-0
5
Jan-
06
Apr-06
Jul-0
6
Oct-0
6
Jan-
07
Apr-07
Jul-0
7
Oct-0
7
Jan-
08
Apr-08
Time (months)
Cor
rela
tion
Reg
ress
ion
RegressionCorrelation
0.90 < Regression < 1.030.91 < Correlation < 0.99
0.85 < Regression < 1.000.89 < Correlation < 0.98
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 8
Total Ozone Column ECS2 > COL3Whole Globe OMI
Total Ozone Difference ECS2
-10
-5
0
5
10
15
20
25
Sep
-04
Nov
-04
Jan
-05
Mar
-05
May
-05
Jul-
05
Sep
-05
Nov
-05
Jan
-06
Mar
-06
May
-06
Jul-
06
Sep
-06
Nov
-06
Jan
-07
Mar
-07
May
-07
Jul-
07
Sep
-07
Time (months)
Diff
eren
ce a
nd
Sta
n.
Dev
. [D
U]
OMI TOMS-DOASStandard Deviation
Whole Globe OMITotal Ozone Difference COL3
-10
-5
0
5
10
15
Oct-0
4
Jan-
05
Apr-05
Jul-0
5
Oct-0
5
Jan-
06
Apr-06
Jul-0
6
Oct-0
6
Jan-
07
Apr-07
Jul-0
7
Oct-0
7
Jan-
08
Apr-08
Time (months)
Diff
eren
ce a
nd
Sta
n.
Dev
. [D
U]
OMI TOMS-DOASStandard Deviation
-7 < Difference < 18 < Deviation < 12
-8 < Difference < 310 < Deviation < 19
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 9
Total Ozone Column ECS2 > COL3Northern Hemisphere OMI
Total Ozone Difference ECS2
-15
-10
-5
0
5
10
15
20
25
Sep
-04
Nov
-04
Jan
-05
Mar
-05
May
-05
Jul-
05
Sep
-05
Nov
-05
Jan
-06
Mar
-06
May
-06
Jul-
06
Sep
-06
Nov
-06
Jan
-07
Mar
-07
May
-07
Jul-
07
Sep
-07
Time (months)
Diff
eren
ce a
nd
Sta
n.
Dev
. [D
U]
OMI TOMS-DOASStandard Deviation
Southern Hemisphere OMITotal Ozone Difference ECS2
-10
-5
0
5
10
15
20
Sep
-04
Nov
-04
Jan
-05
Mar
-05
May
-05
Jul-
05
Sep
-05
Nov
-05
Jan
-06
Mar
-06
May
-06
Jul-
06
Sep
-06
Nov
-06
Jan
-07
Mar
-07
May
-07
Jul-
07
Sep
-07
Time (months)
Diff
eren
ce a
nd
Sta
n.
Dev
. [D
U]
OMI TOMS-DOASStandard Deviation
Northern Hemisphere OMITotal Ozone Difference COL3
-10
-5
0
5
10
15
Oct-0
4
Jan-
05
Apr-05
Jul-0
5
Oct-0
5
Jan-
06
Apr-06
Jul-0
6
Oct-0
6
Jan-
07
Apr-07
Jul-0
7
Oct-0
7
Jan-
08
Apr-08
Time (months)
Diff
eren
ce a
nd
Sta
n.
Dev
. [D
U]
OMI TOMS-DOASStandard Deviation
Southern Hemisphere OMITotal Ozone Difference COL3
-10
-5
0
5
10
15
Oct-0
4
Jan-
05
Apr-05
Jul-0
5
Oct-0
5
Jan-
06
Apr-06
Jul-0
6
Oct-0
6
Jan-
07
Apr-07
Jul-0
7
Oct-0
7
Jan-
08
Apr-08
Time (months)
Diff
eren
ce a
nd
Sta
n.
Dev
. [D
U]
OMI TOMS-DOASStandard Deviation
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 10
TO3C Difference ECS2 > COL3
OMI TOMS V8.5 - DOAS v1.0.5 [DU]
October 2005
OMI TOMS V8.0 - DOAS v1.0.1 [DU]
ECS2COL3
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 11
TO3C Single Orbits ECS2
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 12
TO3C Single Orbits COL3
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 13
Influence of Sulphur Dioxide ECS220.2 N
139.0 E 152.4 E
12.4 N
20.2 N
139.0 E 152.4 E
12.4 N
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 14
Influence of Sulphur Dioxide COL320.2 N
139.0 E 152.4 E
12.4 N
20.2 N
139.0 E 152.4 E
12.4 N
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 15
Influence of Clouds ECS2
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 16
Influence of Clouds COL3
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 17
Ground Based vs OMTO3
OMI AO 2925 - Validation of OMI total ozone using ground-based Brewer observations. Dr. Dimitris Balis, Aristotle University of Thessaloniki - Laboratory of Atmospheric Physics, Greece
ECS2COL3
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 18
Ground Based vs OMTO3
OMI AO 2925 - Validation of OMI total ozone using ground-based Brewer observations. Dr. Dimitris Balis, Aristotle University of Thessaloniki - Laboratory of Atmospheric Physics, Greece
ECS2COL3
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 19
Ground Based vs OMDOAO3
OMI AO 2925 - Validation of OMI total ozone using ground-based Brewer observations. Dr. Dimitris Balis, Aristotle University of Thessaloniki - Laboratory of Atmospheric Physics, Greece
ECS2COL3
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 20
Ground Based vs OMDOAO3
OMI AO 2925 - Validation of OMI total ozone using ground-based Brewer observations. Dr. Dimitris Balis, Aristotle University of Thessaloniki - Laboratory of Atmospheric Physics, Greece
ECS2COL3
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 21
Brewer Dobson
<O-G>/G (O-G) <O-G>/G (O-G)
OMI DOAS 0.483 % 2.754 % 0.070 % 1.653 %
OMI DOAS* -0.555 % 0.200 % 0.086 % 1.601 %
OMI TOMS -0.504 % 2.704 % -0.631 % 1.032 %
OMI TOMS* -1.450 % 0.425 % -0.645 % 1.064 %
* No South Pole (lat > 75 S)
Ground Based Validation COL3
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 22
NASA WB-57 no.926NASA DC-8 no.817
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 23
DOAS vs CAFS∆=10 DU=2.9%
TOMS vs CAFS∆= -5.8 DU=-1.8%
Polar-AVE 20050129 OMI Orbit 2890 CAFS
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 24
Aura Validation Experiment OMI CAFS
OMI-DOAS OMI-TOMSOMI-CAFS (O-C)/O STD OMI-CAFS (O-C)/O STD
Polar-AVE 10.12 DU 2.89 % 10.36 DU -5.85 DU -1.75 % 12.54 DU
Houston AVE -6.06 DU 2.09 % 9.09 DU -2.27 DU -0.77 % 9.47 DU
Costa Rica AVE -8.12 DU -3.40 % 5.92 DU -8.61 DU -3.62 % 3.89 DU
ALL AVE -2.02 DU -0.70 % 11.70 DU -5.14 DU -1.79 % 9.59 DU
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 25
Solar Zenith Angle 200505
NH SH WG
NH SH WG
COL3
ECS2
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 26
Required Accuracy
3%
100 DU
Validation of ECS2 has led to many modifications made to the respective algorithms for COL3 reprocessing.
For COL3 agreement is found within 1-2 % with reference data. Continuing the TOMS total ozone record (> November 1978) is thus achievable with OMI total ozone.
Remaining difference between OMI-TOMS and OMI-DOAS total ozone estimates are significant in size compared to dynamic range covered by trends.
Both algorithms are sensitive to calibration changes, but not up to the level that becomes significant for trends.
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 27
Data Availability
OMI DOAS Total Ozone Column : NASA DISC and NASA AVDChttp://disc.gsfc.nasa.gov/Aura/OMI/index.shtmlhttp://avdc.gsfc.nasa.gov/index.php?site=2045907950
OMI TOMS Total Ozone Column : NASA DISC and NASA AVDChttp://disc.gsfc.nasa.gov/Aura/OMI/index.shtmlhttp://avdc.gsfc.nasa.gov/index.php?site=2045907950
OMI Near Real Time Total Ozone Column : KNMI TEMIShttp://www.temis.nl/protocols/O3total.html (NRT)http://www.temis.nl/protocols/O3global.html (Assim)
OMI Very Fast Delivery Total Ozone Column : FMI OMIVFDhttp://omivfd.fmi.fi/cgi-bin/products.pl
OMI Ozone Profiles : NASA AVDC (provisional)http://avdc.gsfc.nasa.gov/index.php?site=1980959093&id=39
Dr. Mark Kroon – KNMI - OSTM13 – Finland Slide 28