Vapor-liquid Equilibrium (Vle)- Portal

7/25/2019 Vapor-liquid Equilibrium (Vle)- Portal

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Zenutleo Qcbrgeayoiglj4

Piper/Nlqula Bqulnlmrlug (PNB)

VQQ =69/1 QCB]GEA\OIGLJZ

ZBG 9 (=69:/=691)


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Oiturb e` Bqulnlmrlug Ab`loltleo Gbisurbs e` jegpesltleo

PNB 4 Yuinltitlvb mbcivlerZlgpnb Geabns `er PNB - ]ieunts Ni! - Ab!pelot " #ummnbpelot $injunitleos !ltc

]ieunts Ni! - %bor&s Ni!PNB m& geal`lba ]ieunts ni!PNB `reg '-vinub jerrbnitleos

Jciptbr Eutnlob (Zgltc)


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(%B O)(*]B +, BY*N#]*G

Bqulnlmrlug4 ) stitlj jeoaltleo lo!cljc oe jcio.bs ejjur lo tcbgijresjeplj prepbrtlbs e` i s&stbg !ltctlgb/

(cb (6 96jegpesltleorbijcbs `loin

vinub !cljc !lnnrbgilo `l=ba4bqulnlmrlug


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g

g

g

gx lll

7

P

xJ ll 7

l

llGxG

Gbisurbs e` jegpesltleo

Gbisurbs

e`jegpesltleo

Giss ergenb `rijtleo

Genirjeojbotritleo

Genir giss `eri glxturb ersenutleo


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PNB4 Ztitb e` jeb=lstbojb e` N " P pcisbs) jeoaltleo !cbrb i nlqula pcisb ioa viper pcisb

irb lo bqulnlmrlug !ltc bijc etcbr

)t tcls jeoaltleo4 ritb e` bviperitleo :nlqula viper) 7ritb e` jeoabositleo (viper nlqula)

PNB4 Y*)N()(PB #B%)P+]

Mloiry glxturb4 Gl=turb tcit jeotilos t!e

jeostltubotsb/.4 gl=turb e` nlqula ioa viper it io bqulnlmrlugnbvbn

ti1bs pnijb !cbo nlqula ioa viper irb inne!ba tejeotijt te bijc etcbr lo i jnesba nejitleo


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*oabr surìjb- sit/ Pstitbs :9-(-&20

*ppbr surìjb- sit/ N stitbs:9-(-=20

Nlqula it ,6 rbaujbsprbssurb it jeostiot ( "jegpesltleo ineo. ,;6 tcb`lrst mummnb ippbir it N 3

mummnb pelot4 i pelotwcbo i nlqula èrg tcb`lrt mummnb e` !iper ioamb"lo te b!iperitb

)s prbssurb rbaujbs6 gerb" gerb N viperl


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PNB

]ieunts Niw Cborys Niw Geal`lba]ieunts Niw

H-Pinubs


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ZG9NB G+ABNZ ,+] PNB

Zlgpnb Geabns@er PNB 4@loa ! "! jegpesltleo

]ieunts Niw Cborys Niw


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]ieunts Ni!

P pcisb ls io labin .is )ppnljimnb `er ne! te geabritb

prbssurb

N pcisb ls io labin senutleo

Pinla eon& l` tcb spbjlbs irb jcbgljinn&slglnir :sl


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( )OlVxVy sitlll ,...,=,977

cbrb8

prbssurbQetin4

spbjlbspurbe`prbssurbPiper4`rijtleogenbpcisb4

`rijtleogenbpcisb4

V

lVPy

Nx

sit

l

l

l

2


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M#MN $4 $injunitb 7&l? ioa 96 .lvbo 7=

l? ioa (

%B& $4 $injunitb 7=l? ioa 96 .lvbo 7&l? ioa (

M#MN Q4 $injunitb 7&l? ioa (6 .lvbo 7=l? ioa 9

%B& Q4 $injunitb 7=l? ioa (6 .lvbo 7&l? ioa 9

Ab!pelot " #ummnbpelot$injunitleos !ltc ]ieunts Ni!

'% *PB


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,er mloir& s&stbgs te senvb `ermummnbpelot jinjunitleo :( ls .lvbo08

97l ly

7 lsit

llVxV ( ) 9=9= xVVVV sitsitsit +7

VVxy

sit

99

97

5

F


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7

l

sit

ll VyV 9

]ieunts ni! bquitleo jio mb senvba `er=lte senvb `er ab!pelot jinjunitleo :(

ls .lvbo0 97l lx

sitsit VyVyV

==99//

9+

7

sitV

Vyx

9

9

97

I

M


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Bxigpnb +

#loir& s&stbg ijbteoltrlnb:20Joltregbtciob:50jeoèrgs jnesbn& te ]ieunts ni!/ Piperprbssurb èr tcb purb spbjlbs irb .lvbo m& tcbènne!lo. )otelob bquitleos4

66.=6$6 tcb situritba prbssurb ls .lvbo m&)otelob bquitleo8


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(cb jerrbspeoalo. vinub e` &2ls `euoa `reg Bq/26

sit

lll VxVy 7

=2 &2 9J19i

>/> >/>>>> I2/@

>/5 >/FF2F M>/5F

>/I >/MK5 M@/I

=2 &2 9J19i

>/K >/I@F KK/5

>/@ >/@@@> I/K

2/> 2/>>>> @F/52

( )( )

( )

;1":.6

;=.00

=9.":0.6999 777

V

Vxy

sit


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)t pelot j6 tcb viper jegpesltleo ls &2C>/K6mut tcb jegpesltleo e` nlqula it j ioa tcbprbssurb gust rbia `reg .ripc er jinjunitba/

(cus AB 9 jinjunitleos irb rbqulrba/ #& uslo.Bq/ F8

sitsit

VyVy

V

==99

9

+7

,er &2C>/K ioa tCM>$

hViV ;1.219i6 (2sitCK/@I>$6 (5sitC@/M@>$/ Zbnbjt (mbt!bbo tcbsb t!e tbgpbriturbs ioa jinjunitb 92sit "

95sit `er tcb t!e tbgpbriturbs/

Bvinuitb =2m& Bq/ :)0/ ,er b=igpnb8

sitsit

sit

VVVVx

=9

=9

7 2920.6

"1.10;0.


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Zuggir&8

=2 &2 (JL$

>/>>>> >/>>>> @/M@:t5sit0

>/2I5I >/5I>2 @K

>/F2@I >/II5 @5

>/M2MK >/KM @

>/F@ >/@I@I I2/>>>> 2/>>>> K/@I

:t2sit0


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2/ ,er prbssurb ne!

t ls se ne! tcit lt jio mb issugb is labin.is

5/ ,er spbjlbs prbsbot is i vbr& alnutbsenutleo lo nlqula pcisb

)ssugptleos8

%bor&s Ni!


25/39

( )OlCxVy lll ,...,=,977

cbrb8

prbssurbQetin4

jeostiots#bor$%4`rijtleogenbpcisb4

`rijtleogenbpcisb4

V

CPy

Nx

l

l

l

%bor&s Ni!

K


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Bxigpnb ,

)ssuglo. tcit jirmeoitba !itbr jeotilos eon&$+5:20 ioa %5+:506 abtbrglob tcbjegpesltleos e` tcb P " N pcisbs lo i sbinbajio e` Dseai " tcb 9 b=brtba eo tcb jio it2>>$/ %bor&s jeostiot `er $+5lo !itbr it 2>>$ls imeut > mir ioa =2C>/>2/


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%bor&s ni! `er spbjlbs 2 " ]ieunts ni! `erspbjlbs 5 irb !rlttbo8

999 CxVy 7 sitVxVy === 7

ltc %2C> mir " 95sit C >/>255 mir :`regstbig timnbs it 2>>$0

( ) ( ) ( ) ( )

mirV

V


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(cbo m& ]ieunts ni!6 Bq/ 2 !rlttbo `er spbjlbs 58

( ) ( )669=.6


30/39

(cb 5oaissugptleo e` ]ieunts Ni! ls imioaeoba6ti1lo. lote ijjeuot tcb abvlitleo `reg senutleo

labinlt& lo N pcisb/

(cus6 ijtlvlt& jeb``ljlbot ls lotreaujba lo]ieunts Ni!

( )OlVxVy sit

llll ,...,=,977

PNB #H G+A,BA ])+*N(Z N)

) tl lt ``l l t ` tl ` ( "


31/39

)jtlvlt& jeb``ljlbots irb `uojtleo e` ( "nlqula pcisb jegpesltleo6 =

97l ly

7l

sit

lll VxV

7

l

sit

lll VyV

9

,er mummnb pelot

,er ab! pelot

Zlojb8

97ll

x

@


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)B+(]+9B

) gl=turb tcit cis i

jeostiot jegpesltleoe` nlqula ioa viperpcisb

cbo =2C&26 tcb ab!

pelot ioa mummnb pelotjurvbs irb tio.bot tetcb sigb cerl


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PNB ,]+G '-P)N*B$+]]BN)((+OZ

(cb pirtltleo mbt!bbo nlqula ioa viperpcisbs e` i jcbgljin spbjlbs ls bqulnlmrlugritle6 H

l.

l

ll

xyH

(cls quiotlt& ls jinnba H-vinub/

2>


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sit

lll VxVy 7H-vinub `er ]ieunts Ni!

V

VH

sitl

l 7

H-vinub `er geal`lba ]ieunts Ni! sit

llll VxVy 7

V

VH

sit

lll

7

22

25


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%bojb6

,er mloir& s&stbgs te senvb `ermummnb pelot jinjunitleo8

97l ly

97 ll lxH

,er mloir& s&stbgs te senvb `erab! pelot jinjunitleo8

97l lx

%bojb697l

l

l

H

y

2F

2I

' vinub


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'-vinub`regAb9rlbstbr

jcirt-Ne! (rio.b

' vinub


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'-vinub`regAb9rlbstbr

jcirt-%l.c (rio.b

cbo .lvbo i gl=turb e` jegpesltleo it jbrtilo


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cbo .lvbo i gl=turb e` jegpesltleo it jbrtilo( er 98

Mummnb pelot

- Z&stbg ls ingestviperl


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Qcb Boa

Date post:	13-Apr-2018
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