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WOODARD&CURRAN Engineering • Science Operations CORPORATE OFFICES: Maine, Massachusetts, New Hampshire, Connecticut, Florida Operational offices throughout the U.S October 12, 2005 Mr. Terrence Connelly USEPA - New England Division 1 Congress Street, Suite 1100 (HBT) Boston, MA 02114-2023 RE: Residential Tap Water Monitoring Program Hows Corner Superfund Site, Plymouth, Maine September 2005 Water Sampling Results Dear Mr. Connelly: Enclosed please find the laboratory results for the tap water sampling event conducted for the subject project in September 2(H)5, summary tables providing the data for each residence sampled, and the data validation report. The September 2(H)5 sampling event was completed on September 13, 2005 and included the residences scheduled for quarterly sampling, as follows; Quarterly Lots 2 (Skidgel) 7 (Melanson) 8-1 (Foss) ll-l(Godsoe) 11-2 (Ward) ll-3(Deraps) 11^1 (Leathers) 21-16 (Levesque) 31 (G. Hopkins) 31 (Knight) 32-2 (Hames) 36 (Norris) 83-1 (Gray) No sample was collected at Lot 2 (Skidgel) during the September 2005 sampling event because the homeowner could not be contacted by telephone to arrange a sampling appointment or in person to collect a sample. Several unsuccessful attempts were made during the September sampling event to collect a sample at this residence. Quarterly Residential Sampling Results Thirteen residences were scheduled for quarterly sampling and 12 samples were successfully collected. As indicated above, no sample was collected at Lot 2 (Skidgel) during this sampling event. As outlined in Table 1, chloroform and tetrachloroethylene (PCE) were detected in the samples collected from the quarterly residential sampling locations. Chloroform was detected in the water sample collected at Lot 7 (Melanson) at 9.0 fig/L, which is below the chloroform Maximum Contaminant Level (MCL) of 100 pig/L. At Lot 32-2 (Hames), PCE was detected at a concentration of 0.28 J /ig/L; however, this detection is below the PCE MCL of 5.0 (ig/L. No other project-related compounds were detected in water samples collected from the quarterly residential sampling locations. Therefore, there were no cxceedences of the MCLs observed. 41 Hutchins Drive i Portland, Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) • 1-800-426-4262 • www.woodardcurran.com 205 279.06/9_05 summary report.doc
Transcript
Page 1: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

WOODARDampCURRAN Engineering bull Science bull Operations

CORPORATE OFFICES Maine Massachusetts New Hampshire Connecticut Florida

Operational offices throughout the US

October 12 2005

Mr Terrence Connelly USEPA - New England Division 1 Congress Street Suite 1100 (HBT) Boston MA 02114-2023

RE Residential Tap Water Monitoring Program Hows Corner Superfund Site Plymouth Maine September 2005 Water Sampling Results

Dear Mr Connelly

Enclosed please find the laboratory results for the tap water sampling event conducted for the subject project in September 2(H)5 summary tables providing the data for each residence sampled and the data validation report The September 2(H)5 sampling event was completed on September 13 2005 and included the residences scheduled for quarterly sampling as follows

Quarterly Lots 2 (Skidgel) 7 (Melanson) 8-1 (Foss) ll-l(Godsoe) 11-2 (Ward) ll-3(Deraps) 11^1 (Leathers)

21-16 (Levesque) 31 (G Hopkins) 31 (Knight) 32-2 (Hames) 36 (Norris) 83-1 (Gray)

No sample was collected at Lot 2 (Skidgel) during the September 2005 sampling event because the homeowner could not be contacted by telephone to arrange a sampling appointment or in person to collect a sample Several unsuccessful attempts were made during the September sampling event to collect a sample at this residence

Quarterly Residential Sampling Results

Thirteen residences were scheduled for quarterly sampling and 12 samples were successfully collected As indicated above no sample was collected at Lot 2 (Skidgel) during this sampling event As outlined in Table 1 chloroform and tetrachloroethylene (PCE) were detected in the samples collected from the quarterly residential sampling locations Chloroform was detected in the water sample collected at Lot 7 (Melanson) at 90 figL which is below the chloroform Maximum Contaminant Level (MCL) of 100 pigL At Lot 32-2 (Hames) PCE was detected at a concentration of 028 J igL however this detection is below the PCE MCL of 50 (igL No other project-related compounds were detected in water samples collected from the quarterly residential sampling locations Therefore there were no cxceedences of the MCLs observed

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) bull 1-800-426-4262 bull wwwwoodardcurrancom 205 279069_05 summary reportdoc

WOODARD ampCURRAN Engineering bull Science bull Operations

Data Validation

The validation report indicates that chloroform was detected in one of the method blanks associated with the selected September 2005 samples indicating potential low level false positive concentrations of this compound in associated samples As a result concentrations of chloroform in associated samples below a calculated action level were qualified as non-detect Non-compliant continuing calibration results were reported for 111-trichloroethane and 11-dichloroethene resulting in qualification of positive and non-detect concentrations of these compounds in associated samples as estimated In addition non-compliant methylene chloride results were reported in one laboratory control sample therefore positive and non-detect methylene chloride results in associated samples were qualified as estimated Overall the results of the validation concluded that the data are of good quality and are suitable for their intended use

Summary

The September 2005 sampling event was completed on September 13 2005 and consisted of sampling the residences designated for quarterly sampling Woodard amp Curran Inc completed the sampling The next monitoring event is scheduled to take place in December 2005 and will consist of monitoring locations designated for quarterly sampling

If you have any questions regarding the enclosed materials or sampling program please contact me af (207)685-7333

Sincerely

WOODARD amp CURRAN INC

^-^-lffvlt^i-~ ^ ^ ^ t _ - ^ - o u _

Florence L Clauson Project Chemist

20529706 Enclosures

ex Rebecca Hewett MRDEP Mark Beliveau Pierce Atvvood

205279069_05summary reportdoc

Table 1 Summary of Quarterly Sampling Results

Residential Tap Water Program Plymouth Maine

PARAMETER (ugl)

Chloroform

11-Dichloroethene

cis-12-Dichloroethene

trans-12-Dichloroethene

12-Dichloropropane

Methylene chloride

Tetrachloroethene

124-Trichlorobenzene

111-Trichloroethane

Trichloroethene

Vinyl chloride

mp-Xylenes

o-Xylene

Xylenes (total)

WELL SAMPLE ID DATE

RESULT TYPE

LOT7 WSHC(7)MELANSON 091405 Primary

9

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt1

lt05

lt15

LOT8-1 WSHC8-1)FOSS 091305 Primary

lt059U

lt05

lt05

lt05

lt05

lt05

lt05

lt0S

lt05

lt05

lt05

lt1

lt05

lt15

LOT8-1 WSHC(8-1)FOSS DUP 091305 Duplicate 1

lt074U

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt1

lt05

lt15

LOT11-1 WSHC(11-1)GO 091305 Primary

lt05

lt 0 5

lt05

lt05

lt05

lt05

lt05 shy

lt05

lt05J

lt05

lt05

lt1

lt05

lt15

lt = Not detected at indicated reporting limit

J = Estimated U bull Result revised to non-detected due to blank contamination

qjartmonxls995037

PARAMETER (ugl)

Chloroform

11-Dichloroethene

cis-12-Dichloroethene

trans-12-Dichloroethene

12-Dtchloropropane

Methylene chloride

Tetrachtoroethene

124-Trichlorobenzene

111-Trichloroethane

Trichloroethene

Vinyl chloride

mp-Xylenes

o-Xylene

Xylenes (total)

WELL SAMPLE ID DATE RESULT TYPE

LOT11-3 WSHC(1t-3gtDERAPS 091305 Primary

lt05

lt05J

lt05

lt05

lt05

lt05J

lt05

lt05

lt05

lt05

lt05

lt1

lt05

lt15

Table 1 Summary of Quarterly Sampling Results

Residential Tap Water Program Plymouth Maine

LOTH-4 LOT21-16 WSHC(11-4)SAWYER WSHC(21 -16JLEVESQUE

091305 091305

Primary Primary

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05J lt05J

lt05 lt05

lt05 lt05

lt1 lt1

lt05 lt05

lt15 lt15

LOT31 WSHC(31)GHO 091305 Primary

lt05

lt05J

lt05

lt05

lt05

lt05J

bull=05

lt05

lt05

lt05

lt05

lt1

lt05

ltia

lt - Not detected at indicated reporting limit

J = Estimated U = Result revised to non-detected due to blank contamination

quartmon xlS995037

WOODARDampCURRAN Engineering gt Science bull Operations

bulli

LABORATORY ANALYTICAL RESULTS RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05summary reportdoc

_

Llt ID laquo V lt 7 7 9 Sample Date- o s -

Dat 9

Qiydegse ^ t r a c t e d b y

f r a c t i o n Methn Ana lys i s flate 1153

W A r E R deg 9 2 8 2 O 0 s Analys is MethrH M ^ i L a b P r e p trade d = S P A S 2 4 3 S o l i d s WA ^ts ^ r C h bullraquobulllaquo

Compound 75 -Ol - i V i laquo y l c h l o r i d e raquo F l a g s 75-35-4 R e s u l t s l - 5 5 - S ^ - I gt i C h l o r o e t l l a i i e rr DP

7 S - 0 l - S 8 0 5 0 1-0 pound laquobullbulllaquo K M 0 5 0 T r i c h l ^ D e t i i e n e

0 5 0 0 5 0 7 5 - D g - 2 tJ 1 0 0 2 0 0 5 0 0 5 0 0 5 0 156-592 17 1 -0 0 13 O50 0 5 0 OSQ 15S-60-5 ff 1 0 O50 0 13

0 5 0 0 5 0 D 1 078-B7-5 0 5 0 0 1 1 0 5 0 0 5 0 1 01 2 7 - I H ^ O 0 2 2 0 5 0 0 50 T e t laquo c h l o t o e t h e n e 1 a

05D m + P ^ 7 i a n e 3 0 5 0 0 5 0 0-50

0 13 9 S - 4 7 - g cr 1 -0 0 5 0 013

degXylene u 0 5 0 I 0 0 5 0 3 0 - 2 0 - 7 0 5 0 013

Xylenes ( t o t a l ) cr 10 1 0 10 05Q

0 14 10 0 5 0 D 1 0 57-ES-3 O50 0 2 4 D50 1-5 I 0 4 G 0 - 0 Q - 4 O l o 1 5 15 0 5 0 i 02195-59- 0 5 0 0 34 0 50 0-5S

D 4 0 5 0 0 50 oas D l C h l o ^ e n 2 e n e - 1 0 B l l

012 64

Page 01 0 f 0 1 P8B3 7

Sample natQ o_

KATAHDIH ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Project HOWS CORNER QUARTERLY

PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA

Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1

CAS Compound F l a g s Results DF PQL Adj PQL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0

75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0

71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0

79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0

75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0

156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0

15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50

78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0

127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0

m+p-Xylenes c 1 0 1 0 1 0 1 0

95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0

1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5

120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0

67-S6-3460-00-4

Chloroform P-Bromafluorobenzene

u JBT 0 7 4 56

1 0 0 5 0 0 50

2199-69-1 12-Dichlorobenzene-D4 6 4

Page 01 o f 01 F8B38D

AdjMDL 0 2 0 0 13 D13 0 1 1

0 22 0 13 0 13 0 13 0 14 0 24

0 1 0 0 34

Q2S

0 1 2

Sample Data Summary A0000004

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY

PO Na Sample Date 091305 Received Date 091505

Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA

Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1

CAS Compound Flags Results DF PQL ampdjPQL

75-01-4 Vinyl chloride U 050 10 050 050

75-35-4 11-Dichloroethene n 050 10 050 050

71-55-679-01-6

If1J1-Trichlaraethane Trichioroethene

u u 3 050

050

10

10

050

D50

050

050

75-09-2 Methylene Chloride n 050 10 050 05O

156-59-2 cis-l2-Dichloroethene D 050 10 050 050

15G-S0-5 trans-12-Dichloroethene D 050 10 050 050

7B-87-5 12-Dichloropropane a 050 10 050 050

127-10-4 Tetrachloroethene D 050 10 050 050

m+p-xylenes O 10 10 10 10

95-47-6 o-Xylena D 050 10 050 050

133D-20-7 Xylenes (total) U 15 10 15 15

120-82-1 124-Trichlorobenzene u 050 10 050 050

67-66-3 Chloroform u 050 10 050 050

460-00-4 P-Brotnofluorobenzene Bl

2199-69-1 12-Dichlorobenzene-D4 65

Page 01 Of 01 F8783D

Adj MD]

020

013

013

011

022

013

013

013

014

024

010

034

026

012

Sample Data Summary A0000005

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64

Page 01 of 01 F8764D

Sample Data Summary A0000006

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA

CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014

rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V

Page 01 Of 01 F87B5D

Sample Data Summary A0000007

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u o J

05D

O50

10

10

05O

050

050

050

013

013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014

m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64

Page 01 of 01 F8786D

Sample Data Summary A0O00OOS

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL

75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u c J O50

0 5 0 1 0

1 0

0 5 0

0 5 0 bull 50 D50

0 13

0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2

Methylene Chloride cis-12-Dichloroethene

u D or 0 5 0

0 5 0 1 0

1 0

0 5 0 OSO

O50 05D

0 22 0 13

156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7

Page 01 of 01 F8B01D

Sample Data Summary A0000009

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

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The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

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Comments

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V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

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Validator

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A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 2: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

WOODARD ampCURRAN Engineering bull Science bull Operations

Data Validation

The validation report indicates that chloroform was detected in one of the method blanks associated with the selected September 2005 samples indicating potential low level false positive concentrations of this compound in associated samples As a result concentrations of chloroform in associated samples below a calculated action level were qualified as non-detect Non-compliant continuing calibration results were reported for 111-trichloroethane and 11-dichloroethene resulting in qualification of positive and non-detect concentrations of these compounds in associated samples as estimated In addition non-compliant methylene chloride results were reported in one laboratory control sample therefore positive and non-detect methylene chloride results in associated samples were qualified as estimated Overall the results of the validation concluded that the data are of good quality and are suitable for their intended use

Summary

The September 2005 sampling event was completed on September 13 2005 and consisted of sampling the residences designated for quarterly sampling Woodard amp Curran Inc completed the sampling The next monitoring event is scheduled to take place in December 2005 and will consist of monitoring locations designated for quarterly sampling

If you have any questions regarding the enclosed materials or sampling program please contact me af (207)685-7333

Sincerely

WOODARD amp CURRAN INC

^-^-lffvlt^i-~ ^ ^ ^ t _ - ^ - o u _

Florence L Clauson Project Chemist

20529706 Enclosures

ex Rebecca Hewett MRDEP Mark Beliveau Pierce Atvvood

205279069_05summary reportdoc

Table 1 Summary of Quarterly Sampling Results

Residential Tap Water Program Plymouth Maine

PARAMETER (ugl)

Chloroform

11-Dichloroethene

cis-12-Dichloroethene

trans-12-Dichloroethene

12-Dichloropropane

Methylene chloride

Tetrachloroethene

124-Trichlorobenzene

111-Trichloroethane

Trichloroethene

Vinyl chloride

mp-Xylenes

o-Xylene

Xylenes (total)

WELL SAMPLE ID DATE

RESULT TYPE

LOT7 WSHC(7)MELANSON 091405 Primary

9

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt1

lt05

lt15

LOT8-1 WSHC8-1)FOSS 091305 Primary

lt059U

lt05

lt05

lt05

lt05

lt05

lt05

lt0S

lt05

lt05

lt05

lt1

lt05

lt15

LOT8-1 WSHC(8-1)FOSS DUP 091305 Duplicate 1

lt074U

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt1

lt05

lt15

LOT11-1 WSHC(11-1)GO 091305 Primary

lt05

lt 0 5

lt05

lt05

lt05

lt05

lt05 shy

lt05

lt05J

lt05

lt05

lt1

lt05

lt15

lt = Not detected at indicated reporting limit

J = Estimated U bull Result revised to non-detected due to blank contamination

qjartmonxls995037

PARAMETER (ugl)

Chloroform

11-Dichloroethene

cis-12-Dichloroethene

trans-12-Dichloroethene

12-Dtchloropropane

Methylene chloride

Tetrachtoroethene

124-Trichlorobenzene

111-Trichloroethane

Trichloroethene

Vinyl chloride

mp-Xylenes

o-Xylene

Xylenes (total)

WELL SAMPLE ID DATE RESULT TYPE

LOT11-3 WSHC(1t-3gtDERAPS 091305 Primary

lt05

lt05J

lt05

lt05

lt05

lt05J

lt05

lt05

lt05

lt05

lt05

lt1

lt05

lt15

Table 1 Summary of Quarterly Sampling Results

Residential Tap Water Program Plymouth Maine

LOTH-4 LOT21-16 WSHC(11-4)SAWYER WSHC(21 -16JLEVESQUE

091305 091305

Primary Primary

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05J lt05J

lt05 lt05

lt05 lt05

lt1 lt1

lt05 lt05

lt15 lt15

LOT31 WSHC(31)GHO 091305 Primary

lt05

lt05J

lt05

lt05

lt05

lt05J

bull=05

lt05

lt05

lt05

lt05

lt1

lt05

ltia

lt - Not detected at indicated reporting limit

J = Estimated U = Result revised to non-detected due to blank contamination

quartmon xlS995037

WOODARDampCURRAN Engineering gt Science bull Operations

bulli

LABORATORY ANALYTICAL RESULTS RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05summary reportdoc

_

Llt ID laquo V lt 7 7 9 Sample Date- o s -

Dat 9

Qiydegse ^ t r a c t e d b y

f r a c t i o n Methn Ana lys i s flate 1153

W A r E R deg 9 2 8 2 O 0 s Analys is MethrH M ^ i L a b P r e p trade d = S P A S 2 4 3 S o l i d s WA ^ts ^ r C h bullraquobulllaquo

Compound 75 -Ol - i V i laquo y l c h l o r i d e raquo F l a g s 75-35-4 R e s u l t s l - 5 5 - S ^ - I gt i C h l o r o e t l l a i i e rr DP

7 S - 0 l - S 8 0 5 0 1-0 pound laquobullbulllaquo K M 0 5 0 T r i c h l ^ D e t i i e n e

0 5 0 0 5 0 7 5 - D g - 2 tJ 1 0 0 2 0 0 5 0 0 5 0 0 5 0 156-592 17 1 -0 0 13 O50 0 5 0 OSQ 15S-60-5 ff 1 0 O50 0 13

0 5 0 0 5 0 D 1 078-B7-5 0 5 0 0 1 1 0 5 0 0 5 0 1 01 2 7 - I H ^ O 0 2 2 0 5 0 0 50 T e t laquo c h l o t o e t h e n e 1 a

05D m + P ^ 7 i a n e 3 0 5 0 0 5 0 0-50

0 13 9 S - 4 7 - g cr 1 -0 0 5 0 013

degXylene u 0 5 0 I 0 0 5 0 3 0 - 2 0 - 7 0 5 0 013

Xylenes ( t o t a l ) cr 10 1 0 10 05Q

0 14 10 0 5 0 D 1 0 57-ES-3 O50 0 2 4 D50 1-5 I 0 4 G 0 - 0 Q - 4 O l o 1 5 15 0 5 0 i 02195-59- 0 5 0 0 34 0 50 0-5S

D 4 0 5 0 0 50 oas D l C h l o ^ e n 2 e n e - 1 0 B l l

012 64

Page 01 0 f 0 1 P8B3 7

Sample natQ o_

KATAHDIH ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Project HOWS CORNER QUARTERLY

PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA

Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1

CAS Compound F l a g s Results DF PQL Adj PQL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0

75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0

71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0

79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0

75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0

156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0

15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50

78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0

127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0

m+p-Xylenes c 1 0 1 0 1 0 1 0

95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0

1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5

120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0

67-S6-3460-00-4

Chloroform P-Bromafluorobenzene

u JBT 0 7 4 56

1 0 0 5 0 0 50

2199-69-1 12-Dichlorobenzene-D4 6 4

Page 01 o f 01 F8B38D

AdjMDL 0 2 0 0 13 D13 0 1 1

0 22 0 13 0 13 0 13 0 14 0 24

0 1 0 0 34

Q2S

0 1 2

Sample Data Summary A0000004

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY

PO Na Sample Date 091305 Received Date 091505

Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA

Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1

CAS Compound Flags Results DF PQL ampdjPQL

75-01-4 Vinyl chloride U 050 10 050 050

75-35-4 11-Dichloroethene n 050 10 050 050

71-55-679-01-6

If1J1-Trichlaraethane Trichioroethene

u u 3 050

050

10

10

050

D50

050

050

75-09-2 Methylene Chloride n 050 10 050 05O

156-59-2 cis-l2-Dichloroethene D 050 10 050 050

15G-S0-5 trans-12-Dichloroethene D 050 10 050 050

7B-87-5 12-Dichloropropane a 050 10 050 050

127-10-4 Tetrachloroethene D 050 10 050 050

m+p-xylenes O 10 10 10 10

95-47-6 o-Xylena D 050 10 050 050

133D-20-7 Xylenes (total) U 15 10 15 15

120-82-1 124-Trichlorobenzene u 050 10 050 050

67-66-3 Chloroform u 050 10 050 050

460-00-4 P-Brotnofluorobenzene Bl

2199-69-1 12-Dichlorobenzene-D4 65

Page 01 Of 01 F8783D

Adj MD]

020

013

013

011

022

013

013

013

014

024

010

034

026

012

Sample Data Summary A0000005

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64

Page 01 of 01 F8764D

Sample Data Summary A0000006

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA

CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014

rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V

Page 01 Of 01 F87B5D

Sample Data Summary A0000007

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u o J

05D

O50

10

10

05O

050

050

050

013

013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014

m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64

Page 01 of 01 F8786D

Sample Data Summary A0O00OOS

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL

75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u c J O50

0 5 0 1 0

1 0

0 5 0

0 5 0 bull 50 D50

0 13

0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2

Methylene Chloride cis-12-Dichloroethene

u D or 0 5 0

0 5 0 1 0

1 0

0 5 0 OSO

O50 05D

0 22 0 13

156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7

Page 01 of 01 F8B01D

Sample Data Summary A0000009

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

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Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

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The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

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COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

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II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

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Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

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BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

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List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

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V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

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Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

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3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

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Coiiiincnts

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EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

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OLM032

OLCU2I

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Walcr Spit 35-lTT23120_

40-110

Uccurcry

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Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

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Recovery Recovery R ceo very

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Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

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Advisory Surrogates - OLM032

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EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

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VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

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EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

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Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

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VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

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SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

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XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

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Reported Vitue

Not Delected Compound

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XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 3: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

Table 1 Summary of Quarterly Sampling Results

Residential Tap Water Program Plymouth Maine

PARAMETER (ugl)

Chloroform

11-Dichloroethene

cis-12-Dichloroethene

trans-12-Dichloroethene

12-Dichloropropane

Methylene chloride

Tetrachloroethene

124-Trichlorobenzene

111-Trichloroethane

Trichloroethene

Vinyl chloride

mp-Xylenes

o-Xylene

Xylenes (total)

WELL SAMPLE ID DATE

RESULT TYPE

LOT7 WSHC(7)MELANSON 091405 Primary

9

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt1

lt05

lt15

LOT8-1 WSHC8-1)FOSS 091305 Primary

lt059U

lt05

lt05

lt05

lt05

lt05

lt05

lt0S

lt05

lt05

lt05

lt1

lt05

lt15

LOT8-1 WSHC(8-1)FOSS DUP 091305 Duplicate 1

lt074U

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt05

lt1

lt05

lt15

LOT11-1 WSHC(11-1)GO 091305 Primary

lt05

lt 0 5

lt05

lt05

lt05

lt05

lt05 shy

lt05

lt05J

lt05

lt05

lt1

lt05

lt15

lt = Not detected at indicated reporting limit

J = Estimated U bull Result revised to non-detected due to blank contamination

qjartmonxls995037

PARAMETER (ugl)

Chloroform

11-Dichloroethene

cis-12-Dichloroethene

trans-12-Dichloroethene

12-Dtchloropropane

Methylene chloride

Tetrachtoroethene

124-Trichlorobenzene

111-Trichloroethane

Trichloroethene

Vinyl chloride

mp-Xylenes

o-Xylene

Xylenes (total)

WELL SAMPLE ID DATE RESULT TYPE

LOT11-3 WSHC(1t-3gtDERAPS 091305 Primary

lt05

lt05J

lt05

lt05

lt05

lt05J

lt05

lt05

lt05

lt05

lt05

lt1

lt05

lt15

Table 1 Summary of Quarterly Sampling Results

Residential Tap Water Program Plymouth Maine

LOTH-4 LOT21-16 WSHC(11-4)SAWYER WSHC(21 -16JLEVESQUE

091305 091305

Primary Primary

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05J lt05J

lt05 lt05

lt05 lt05

lt1 lt1

lt05 lt05

lt15 lt15

LOT31 WSHC(31)GHO 091305 Primary

lt05

lt05J

lt05

lt05

lt05

lt05J

bull=05

lt05

lt05

lt05

lt05

lt1

lt05

ltia

lt - Not detected at indicated reporting limit

J = Estimated U = Result revised to non-detected due to blank contamination

quartmon xlS995037

WOODARDampCURRAN Engineering gt Science bull Operations

bulli

LABORATORY ANALYTICAL RESULTS RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05summary reportdoc

_

Llt ID laquo V lt 7 7 9 Sample Date- o s -

Dat 9

Qiydegse ^ t r a c t e d b y

f r a c t i o n Methn Ana lys i s flate 1153

W A r E R deg 9 2 8 2 O 0 s Analys is MethrH M ^ i L a b P r e p trade d = S P A S 2 4 3 S o l i d s WA ^ts ^ r C h bullraquobulllaquo

Compound 75 -Ol - i V i laquo y l c h l o r i d e raquo F l a g s 75-35-4 R e s u l t s l - 5 5 - S ^ - I gt i C h l o r o e t l l a i i e rr DP

7 S - 0 l - S 8 0 5 0 1-0 pound laquobullbulllaquo K M 0 5 0 T r i c h l ^ D e t i i e n e

0 5 0 0 5 0 7 5 - D g - 2 tJ 1 0 0 2 0 0 5 0 0 5 0 0 5 0 156-592 17 1 -0 0 13 O50 0 5 0 OSQ 15S-60-5 ff 1 0 O50 0 13

0 5 0 0 5 0 D 1 078-B7-5 0 5 0 0 1 1 0 5 0 0 5 0 1 01 2 7 - I H ^ O 0 2 2 0 5 0 0 50 T e t laquo c h l o t o e t h e n e 1 a

05D m + P ^ 7 i a n e 3 0 5 0 0 5 0 0-50

0 13 9 S - 4 7 - g cr 1 -0 0 5 0 013

degXylene u 0 5 0 I 0 0 5 0 3 0 - 2 0 - 7 0 5 0 013

Xylenes ( t o t a l ) cr 10 1 0 10 05Q

0 14 10 0 5 0 D 1 0 57-ES-3 O50 0 2 4 D50 1-5 I 0 4 G 0 - 0 Q - 4 O l o 1 5 15 0 5 0 i 02195-59- 0 5 0 0 34 0 50 0-5S

D 4 0 5 0 0 50 oas D l C h l o ^ e n 2 e n e - 1 0 B l l

012 64

Page 01 0 f 0 1 P8B3 7

Sample natQ o_

KATAHDIH ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Project HOWS CORNER QUARTERLY

PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA

Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1

CAS Compound F l a g s Results DF PQL Adj PQL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0

75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0

71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0

79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0

75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0

156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0

15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50

78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0

127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0

m+p-Xylenes c 1 0 1 0 1 0 1 0

95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0

1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5

120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0

67-S6-3460-00-4

Chloroform P-Bromafluorobenzene

u JBT 0 7 4 56

1 0 0 5 0 0 50

2199-69-1 12-Dichlorobenzene-D4 6 4

Page 01 o f 01 F8B38D

AdjMDL 0 2 0 0 13 D13 0 1 1

0 22 0 13 0 13 0 13 0 14 0 24

0 1 0 0 34

Q2S

0 1 2

Sample Data Summary A0000004

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY

PO Na Sample Date 091305 Received Date 091505

Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA

Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1

CAS Compound Flags Results DF PQL ampdjPQL

75-01-4 Vinyl chloride U 050 10 050 050

75-35-4 11-Dichloroethene n 050 10 050 050

71-55-679-01-6

If1J1-Trichlaraethane Trichioroethene

u u 3 050

050

10

10

050

D50

050

050

75-09-2 Methylene Chloride n 050 10 050 05O

156-59-2 cis-l2-Dichloroethene D 050 10 050 050

15G-S0-5 trans-12-Dichloroethene D 050 10 050 050

7B-87-5 12-Dichloropropane a 050 10 050 050

127-10-4 Tetrachloroethene D 050 10 050 050

m+p-xylenes O 10 10 10 10

95-47-6 o-Xylena D 050 10 050 050

133D-20-7 Xylenes (total) U 15 10 15 15

120-82-1 124-Trichlorobenzene u 050 10 050 050

67-66-3 Chloroform u 050 10 050 050

460-00-4 P-Brotnofluorobenzene Bl

2199-69-1 12-Dichlorobenzene-D4 65

Page 01 Of 01 F8783D

Adj MD]

020

013

013

011

022

013

013

013

014

024

010

034

026

012

Sample Data Summary A0000005

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64

Page 01 of 01 F8764D

Sample Data Summary A0000006

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA

CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014

rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V

Page 01 Of 01 F87B5D

Sample Data Summary A0000007

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u o J

05D

O50

10

10

05O

050

050

050

013

013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014

m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64

Page 01 of 01 F8786D

Sample Data Summary A0O00OOS

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL

75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u c J O50

0 5 0 1 0

1 0

0 5 0

0 5 0 bull 50 D50

0 13

0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2

Methylene Chloride cis-12-Dichloroethene

u D or 0 5 0

0 5 0 1 0

1 0

0 5 0 OSO

O50 05D

0 22 0 13

156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7

Page 01 of 01 F8B01D

Sample Data Summary A0000009

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 4: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

PARAMETER (ugl)

Chloroform

11-Dichloroethene

cis-12-Dichloroethene

trans-12-Dichloroethene

12-Dtchloropropane

Methylene chloride

Tetrachtoroethene

124-Trichlorobenzene

111-Trichloroethane

Trichloroethene

Vinyl chloride

mp-Xylenes

o-Xylene

Xylenes (total)

WELL SAMPLE ID DATE RESULT TYPE

LOT11-3 WSHC(1t-3gtDERAPS 091305 Primary

lt05

lt05J

lt05

lt05

lt05

lt05J

lt05

lt05

lt05

lt05

lt05

lt1

lt05

lt15

Table 1 Summary of Quarterly Sampling Results

Residential Tap Water Program Plymouth Maine

LOTH-4 LOT21-16 WSHC(11-4)SAWYER WSHC(21 -16JLEVESQUE

091305 091305

Primary Primary

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05 lt05

lt05J lt05J

lt05 lt05

lt05 lt05

lt1 lt1

lt05 lt05

lt15 lt15

LOT31 WSHC(31)GHO 091305 Primary

lt05

lt05J

lt05

lt05

lt05

lt05J

bull=05

lt05

lt05

lt05

lt05

lt1

lt05

ltia

lt - Not detected at indicated reporting limit

J = Estimated U = Result revised to non-detected due to blank contamination

quartmon xlS995037

WOODARDampCURRAN Engineering gt Science bull Operations

bulli

LABORATORY ANALYTICAL RESULTS RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05summary reportdoc

_

Llt ID laquo V lt 7 7 9 Sample Date- o s -

Dat 9

Qiydegse ^ t r a c t e d b y

f r a c t i o n Methn Ana lys i s flate 1153

W A r E R deg 9 2 8 2 O 0 s Analys is MethrH M ^ i L a b P r e p trade d = S P A S 2 4 3 S o l i d s WA ^ts ^ r C h bullraquobulllaquo

Compound 75 -Ol - i V i laquo y l c h l o r i d e raquo F l a g s 75-35-4 R e s u l t s l - 5 5 - S ^ - I gt i C h l o r o e t l l a i i e rr DP

7 S - 0 l - S 8 0 5 0 1-0 pound laquobullbulllaquo K M 0 5 0 T r i c h l ^ D e t i i e n e

0 5 0 0 5 0 7 5 - D g - 2 tJ 1 0 0 2 0 0 5 0 0 5 0 0 5 0 156-592 17 1 -0 0 13 O50 0 5 0 OSQ 15S-60-5 ff 1 0 O50 0 13

0 5 0 0 5 0 D 1 078-B7-5 0 5 0 0 1 1 0 5 0 0 5 0 1 01 2 7 - I H ^ O 0 2 2 0 5 0 0 50 T e t laquo c h l o t o e t h e n e 1 a

05D m + P ^ 7 i a n e 3 0 5 0 0 5 0 0-50

0 13 9 S - 4 7 - g cr 1 -0 0 5 0 013

degXylene u 0 5 0 I 0 0 5 0 3 0 - 2 0 - 7 0 5 0 013

Xylenes ( t o t a l ) cr 10 1 0 10 05Q

0 14 10 0 5 0 D 1 0 57-ES-3 O50 0 2 4 D50 1-5 I 0 4 G 0 - 0 Q - 4 O l o 1 5 15 0 5 0 i 02195-59- 0 5 0 0 34 0 50 0-5S

D 4 0 5 0 0 50 oas D l C h l o ^ e n 2 e n e - 1 0 B l l

012 64

Page 01 0 f 0 1 P8B3 7

Sample natQ o_

KATAHDIH ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Project HOWS CORNER QUARTERLY

PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA

Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1

CAS Compound F l a g s Results DF PQL Adj PQL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0

75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0

71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0

79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0

75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0

156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0

15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50

78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0

127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0

m+p-Xylenes c 1 0 1 0 1 0 1 0

95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0

1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5

120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0

67-S6-3460-00-4

Chloroform P-Bromafluorobenzene

u JBT 0 7 4 56

1 0 0 5 0 0 50

2199-69-1 12-Dichlorobenzene-D4 6 4

Page 01 o f 01 F8B38D

AdjMDL 0 2 0 0 13 D13 0 1 1

0 22 0 13 0 13 0 13 0 14 0 24

0 1 0 0 34

Q2S

0 1 2

Sample Data Summary A0000004

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY

PO Na Sample Date 091305 Received Date 091505

Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA

Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1

CAS Compound Flags Results DF PQL ampdjPQL

75-01-4 Vinyl chloride U 050 10 050 050

75-35-4 11-Dichloroethene n 050 10 050 050

71-55-679-01-6

If1J1-Trichlaraethane Trichioroethene

u u 3 050

050

10

10

050

D50

050

050

75-09-2 Methylene Chloride n 050 10 050 05O

156-59-2 cis-l2-Dichloroethene D 050 10 050 050

15G-S0-5 trans-12-Dichloroethene D 050 10 050 050

7B-87-5 12-Dichloropropane a 050 10 050 050

127-10-4 Tetrachloroethene D 050 10 050 050

m+p-xylenes O 10 10 10 10

95-47-6 o-Xylena D 050 10 050 050

133D-20-7 Xylenes (total) U 15 10 15 15

120-82-1 124-Trichlorobenzene u 050 10 050 050

67-66-3 Chloroform u 050 10 050 050

460-00-4 P-Brotnofluorobenzene Bl

2199-69-1 12-Dichlorobenzene-D4 65

Page 01 Of 01 F8783D

Adj MD]

020

013

013

011

022

013

013

013

014

024

010

034

026

012

Sample Data Summary A0000005

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64

Page 01 of 01 F8764D

Sample Data Summary A0000006

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA

CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014

rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V

Page 01 Of 01 F87B5D

Sample Data Summary A0000007

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u o J

05D

O50

10

10

05O

050

050

050

013

013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014

m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64

Page 01 of 01 F8786D

Sample Data Summary A0O00OOS

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL

75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u c J O50

0 5 0 1 0

1 0

0 5 0

0 5 0 bull 50 D50

0 13

0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2

Methylene Chloride cis-12-Dichloroethene

u D or 0 5 0

0 5 0 1 0

1 0

0 5 0 OSO

O50 05D

0 22 0 13

156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7

Page 01 of 01 F8B01D

Sample Data Summary A0000009

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

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The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 5: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

WOODARDampCURRAN Engineering gt Science bull Operations

bulli

LABORATORY ANALYTICAL RESULTS RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05summary reportdoc

_

Llt ID laquo V lt 7 7 9 Sample Date- o s -

Dat 9

Qiydegse ^ t r a c t e d b y

f r a c t i o n Methn Ana lys i s flate 1153

W A r E R deg 9 2 8 2 O 0 s Analys is MethrH M ^ i L a b P r e p trade d = S P A S 2 4 3 S o l i d s WA ^ts ^ r C h bullraquobulllaquo

Compound 75 -Ol - i V i laquo y l c h l o r i d e raquo F l a g s 75-35-4 R e s u l t s l - 5 5 - S ^ - I gt i C h l o r o e t l l a i i e rr DP

7 S - 0 l - S 8 0 5 0 1-0 pound laquobullbulllaquo K M 0 5 0 T r i c h l ^ D e t i i e n e

0 5 0 0 5 0 7 5 - D g - 2 tJ 1 0 0 2 0 0 5 0 0 5 0 0 5 0 156-592 17 1 -0 0 13 O50 0 5 0 OSQ 15S-60-5 ff 1 0 O50 0 13

0 5 0 0 5 0 D 1 078-B7-5 0 5 0 0 1 1 0 5 0 0 5 0 1 01 2 7 - I H ^ O 0 2 2 0 5 0 0 50 T e t laquo c h l o t o e t h e n e 1 a

05D m + P ^ 7 i a n e 3 0 5 0 0 5 0 0-50

0 13 9 S - 4 7 - g cr 1 -0 0 5 0 013

degXylene u 0 5 0 I 0 0 5 0 3 0 - 2 0 - 7 0 5 0 013

Xylenes ( t o t a l ) cr 10 1 0 10 05Q

0 14 10 0 5 0 D 1 0 57-ES-3 O50 0 2 4 D50 1-5 I 0 4 G 0 - 0 Q - 4 O l o 1 5 15 0 5 0 i 02195-59- 0 5 0 0 34 0 50 0-5S

D 4 0 5 0 0 50 oas D l C h l o ^ e n 2 e n e - 1 0 B l l

012 64

Page 01 0 f 0 1 P8B3 7

Sample natQ o_

KATAHDIH ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Project HOWS CORNER QUARTERLY

PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA

Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1

CAS Compound F l a g s Results DF PQL Adj PQL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0

75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0

71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0

79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0

75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0

156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0

15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50

78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0

127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0

m+p-Xylenes c 1 0 1 0 1 0 1 0

95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0

1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5

120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0

67-S6-3460-00-4

Chloroform P-Bromafluorobenzene

u JBT 0 7 4 56

1 0 0 5 0 0 50

2199-69-1 12-Dichlorobenzene-D4 6 4

Page 01 o f 01 F8B38D

AdjMDL 0 2 0 0 13 D13 0 1 1

0 22 0 13 0 13 0 13 0 14 0 24

0 1 0 0 34

Q2S

0 1 2

Sample Data Summary A0000004

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY

PO Na Sample Date 091305 Received Date 091505

Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA

Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1

CAS Compound Flags Results DF PQL ampdjPQL

75-01-4 Vinyl chloride U 050 10 050 050

75-35-4 11-Dichloroethene n 050 10 050 050

71-55-679-01-6

If1J1-Trichlaraethane Trichioroethene

u u 3 050

050

10

10

050

D50

050

050

75-09-2 Methylene Chloride n 050 10 050 05O

156-59-2 cis-l2-Dichloroethene D 050 10 050 050

15G-S0-5 trans-12-Dichloroethene D 050 10 050 050

7B-87-5 12-Dichloropropane a 050 10 050 050

127-10-4 Tetrachloroethene D 050 10 050 050

m+p-xylenes O 10 10 10 10

95-47-6 o-Xylena D 050 10 050 050

133D-20-7 Xylenes (total) U 15 10 15 15

120-82-1 124-Trichlorobenzene u 050 10 050 050

67-66-3 Chloroform u 050 10 050 050

460-00-4 P-Brotnofluorobenzene Bl

2199-69-1 12-Dichlorobenzene-D4 65

Page 01 Of 01 F8783D

Adj MD]

020

013

013

011

022

013

013

013

014

024

010

034

026

012

Sample Data Summary A0000005

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64

Page 01 of 01 F8764D

Sample Data Summary A0000006

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA

CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014

rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V

Page 01 Of 01 F87B5D

Sample Data Summary A0000007

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u o J

05D

O50

10

10

05O

050

050

050

013

013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014

m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64

Page 01 of 01 F8786D

Sample Data Summary A0O00OOS

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL

75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u c J O50

0 5 0 1 0

1 0

0 5 0

0 5 0 bull 50 D50

0 13

0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2

Methylene Chloride cis-12-Dichloroethene

u D or 0 5 0

0 5 0 1 0

1 0

0 5 0 OSO

O50 05D

0 22 0 13

156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7

Page 01 of 01 F8B01D

Sample Data Summary A0000009

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

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-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

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A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

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f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

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Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

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Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 6: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

_

Llt ID laquo V lt 7 7 9 Sample Date- o s -

Dat 9

Qiydegse ^ t r a c t e d b y

f r a c t i o n Methn Ana lys i s flate 1153

W A r E R deg 9 2 8 2 O 0 s Analys is MethrH M ^ i L a b P r e p trade d = S P A S 2 4 3 S o l i d s WA ^ts ^ r C h bullraquobulllaquo

Compound 75 -Ol - i V i laquo y l c h l o r i d e raquo F l a g s 75-35-4 R e s u l t s l - 5 5 - S ^ - I gt i C h l o r o e t l l a i i e rr DP

7 S - 0 l - S 8 0 5 0 1-0 pound laquobullbulllaquo K M 0 5 0 T r i c h l ^ D e t i i e n e

0 5 0 0 5 0 7 5 - D g - 2 tJ 1 0 0 2 0 0 5 0 0 5 0 0 5 0 156-592 17 1 -0 0 13 O50 0 5 0 OSQ 15S-60-5 ff 1 0 O50 0 13

0 5 0 0 5 0 D 1 078-B7-5 0 5 0 0 1 1 0 5 0 0 5 0 1 01 2 7 - I H ^ O 0 2 2 0 5 0 0 50 T e t laquo c h l o t o e t h e n e 1 a

05D m + P ^ 7 i a n e 3 0 5 0 0 5 0 0-50

0 13 9 S - 4 7 - g cr 1 -0 0 5 0 013

degXylene u 0 5 0 I 0 0 5 0 3 0 - 2 0 - 7 0 5 0 013

Xylenes ( t o t a l ) cr 10 1 0 10 05Q

0 14 10 0 5 0 D 1 0 57-ES-3 O50 0 2 4 D50 1-5 I 0 4 G 0 - 0 Q - 4 O l o 1 5 15 0 5 0 i 02195-59- 0 5 0 0 34 0 50 0-5S

D 4 0 5 0 0 50 oas D l C h l o ^ e n 2 e n e - 1 0 B l l

012 64

Page 01 0 f 0 1 P8B3 7

Sample natQ o_

KATAHDIH ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Project HOWS CORNER QUARTERLY

PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA

Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1

CAS Compound F l a g s Results DF PQL Adj PQL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0

75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0

71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0

79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0

75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0

156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0

15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50

78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0

127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0

m+p-Xylenes c 1 0 1 0 1 0 1 0

95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0

1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5

120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0

67-S6-3460-00-4

Chloroform P-Bromafluorobenzene

u JBT 0 7 4 56

1 0 0 5 0 0 50

2199-69-1 12-Dichlorobenzene-D4 6 4

Page 01 o f 01 F8B38D

AdjMDL 0 2 0 0 13 D13 0 1 1

0 22 0 13 0 13 0 13 0 14 0 24

0 1 0 0 34

Q2S

0 1 2

Sample Data Summary A0000004

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY

PO Na Sample Date 091305 Received Date 091505

Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA

Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1

CAS Compound Flags Results DF PQL ampdjPQL

75-01-4 Vinyl chloride U 050 10 050 050

75-35-4 11-Dichloroethene n 050 10 050 050

71-55-679-01-6

If1J1-Trichlaraethane Trichioroethene

u u 3 050

050

10

10

050

D50

050

050

75-09-2 Methylene Chloride n 050 10 050 05O

156-59-2 cis-l2-Dichloroethene D 050 10 050 050

15G-S0-5 trans-12-Dichloroethene D 050 10 050 050

7B-87-5 12-Dichloropropane a 050 10 050 050

127-10-4 Tetrachloroethene D 050 10 050 050

m+p-xylenes O 10 10 10 10

95-47-6 o-Xylena D 050 10 050 050

133D-20-7 Xylenes (total) U 15 10 15 15

120-82-1 124-Trichlorobenzene u 050 10 050 050

67-66-3 Chloroform u 050 10 050 050

460-00-4 P-Brotnofluorobenzene Bl

2199-69-1 12-Dichlorobenzene-D4 65

Page 01 Of 01 F8783D

Adj MD]

020

013

013

011

022

013

013

013

014

024

010

034

026

012

Sample Data Summary A0000005

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64

Page 01 of 01 F8764D

Sample Data Summary A0000006

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA

CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014

rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V

Page 01 Of 01 F87B5D

Sample Data Summary A0000007

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u o J

05D

O50

10

10

05O

050

050

050

013

013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014

m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64

Page 01 of 01 F8786D

Sample Data Summary A0O00OOS

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL

75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u c J O50

0 5 0 1 0

1 0

0 5 0

0 5 0 bull 50 D50

0 13

0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2

Methylene Chloride cis-12-Dichloroethene

u D or 0 5 0

0 5 0 1 0

1 0

0 5 0 OSO

O50 05D

0 22 0 13

156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7

Page 01 of 01 F8B01D

Sample Data Summary A0000009

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

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Page 7: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

KATAHDIH ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Project HOWS CORNER QUARTERLY

PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA

Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1

CAS Compound F l a g s Results DF PQL Adj PQL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0

75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0

71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0

79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0

75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0

156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0

15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50

78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0

127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0

m+p-Xylenes c 1 0 1 0 1 0 1 0

95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0

1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5

120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0

67-S6-3460-00-4

Chloroform P-Bromafluorobenzene

u JBT 0 7 4 56

1 0 0 5 0 0 50

2199-69-1 12-Dichlorobenzene-D4 6 4

Page 01 o f 01 F8B38D

AdjMDL 0 2 0 0 13 D13 0 1 1

0 22 0 13 0 13 0 13 0 14 0 24

0 1 0 0 34

Q2S

0 1 2

Sample Data Summary A0000004

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY

PO Na Sample Date 091305 Received Date 091505

Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA

Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1

CAS Compound Flags Results DF PQL ampdjPQL

75-01-4 Vinyl chloride U 050 10 050 050

75-35-4 11-Dichloroethene n 050 10 050 050

71-55-679-01-6

If1J1-Trichlaraethane Trichioroethene

u u 3 050

050

10

10

050

D50

050

050

75-09-2 Methylene Chloride n 050 10 050 05O

156-59-2 cis-l2-Dichloroethene D 050 10 050 050

15G-S0-5 trans-12-Dichloroethene D 050 10 050 050

7B-87-5 12-Dichloropropane a 050 10 050 050

127-10-4 Tetrachloroethene D 050 10 050 050

m+p-xylenes O 10 10 10 10

95-47-6 o-Xylena D 050 10 050 050

133D-20-7 Xylenes (total) U 15 10 15 15

120-82-1 124-Trichlorobenzene u 050 10 050 050

67-66-3 Chloroform u 050 10 050 050

460-00-4 P-Brotnofluorobenzene Bl

2199-69-1 12-Dichlorobenzene-D4 65

Page 01 Of 01 F8783D

Adj MD]

020

013

013

011

022

013

013

013

014

024

010

034

026

012

Sample Data Summary A0000005

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64

Page 01 of 01 F8764D

Sample Data Summary A0000006

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA

CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014

rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V

Page 01 Of 01 F87B5D

Sample Data Summary A0000007

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u o J

05D

O50

10

10

05O

050

050

050

013

013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014

m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64

Page 01 of 01 F8786D

Sample Data Summary A0O00OOS

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL

75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u c J O50

0 5 0 1 0

1 0

0 5 0

0 5 0 bull 50 D50

0 13

0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2

Methylene Chloride cis-12-Dichloroethene

u D or 0 5 0

0 5 0 1 0

1 0

0 5 0 OSO

O50 05D

0 22 0 13

156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7

Page 01 of 01 F8B01D

Sample Data Summary A0000009

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

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The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

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EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

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Comments

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V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

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Validator

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A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

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Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

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Validator ^ J IJ^J ^^JfiAjLuiati_ shy

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EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

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Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

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bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

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bull

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Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 8: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY

PO Na Sample Date 091305 Received Date 091505

Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA

Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1

CAS Compound Flags Results DF PQL ampdjPQL

75-01-4 Vinyl chloride U 050 10 050 050

75-35-4 11-Dichloroethene n 050 10 050 050

71-55-679-01-6

If1J1-Trichlaraethane Trichioroethene

u u 3 050

050

10

10

050

D50

050

050

75-09-2 Methylene Chloride n 050 10 050 05O

156-59-2 cis-l2-Dichloroethene D 050 10 050 050

15G-S0-5 trans-12-Dichloroethene D 050 10 050 050

7B-87-5 12-Dichloropropane a 050 10 050 050

127-10-4 Tetrachloroethene D 050 10 050 050

m+p-xylenes O 10 10 10 10

95-47-6 o-Xylena D 050 10 050 050

133D-20-7 Xylenes (total) U 15 10 15 15

120-82-1 124-Trichlorobenzene u 050 10 050 050

67-66-3 Chloroform u 050 10 050 050

460-00-4 P-Brotnofluorobenzene Bl

2199-69-1 12-Dichlorobenzene-D4 65

Page 01 Of 01 F8783D

Adj MD]

020

013

013

011

022

013

013

013

014

024

010

034

026

012

Sample Data Summary A0000005

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64

Page 01 of 01 F8764D

Sample Data Summary A0000006

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA

CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014

rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V

Page 01 Of 01 F87B5D

Sample Data Summary A0000007

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u o J

05D

O50

10

10

05O

050

050

050

013

013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014

m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64

Page 01 of 01 F8786D

Sample Data Summary A0O00OOS

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL

75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u c J O50

0 5 0 1 0

1 0

0 5 0

0 5 0 bull 50 D50

0 13

0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2

Methylene Chloride cis-12-Dichloroethene

u D or 0 5 0

0 5 0 1 0

1 0

0 5 0 OSO

O50 05D

0 22 0 13

156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7

Page 01 of 01 F8B01D

Sample Data Summary A0000009

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

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The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 9: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL

75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64

Page 01 of 01 F8764D

Sample Data Summary A0000006

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA

CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014

rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V

Page 01 Of 01 F87B5D

Sample Data Summary A0000007

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u o J

05D

O50

10

10

05O

050

050

050

013

013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014

m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64

Page 01 of 01 F8786D

Sample Data Summary A0O00OOS

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL

75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u c J O50

0 5 0 1 0

1 0

0 5 0

0 5 0 bull 50 D50

0 13

0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2

Methylene Chloride cis-12-Dichloroethene

u D or 0 5 0

0 5 0 1 0

1 0

0 5 0 OSO

O50 05D

0 22 0 13

156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7

Page 01 of 01 F8B01D

Sample Data Summary A0000009

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 10: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA

CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014

rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V

Page 01 Of 01 F87B5D

Sample Data Summary A0000007

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u o J

05D

O50

10

10

05O

050

050

050

013

013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014

m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64

Page 01 of 01 F8786D

Sample Data Summary A0O00OOS

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL

75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u c J O50

0 5 0 1 0

1 0

0 5 0

0 5 0 bull 50 D50

0 13

0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2

Methylene Chloride cis-12-Dichloroethene

u D or 0 5 0

0 5 0 1 0

1 0

0 5 0 OSO

O50 05D

0 22 0 13

156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7

Page 01 of 01 F8B01D

Sample Data Summary A0000009

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

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Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

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The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

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Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

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EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

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II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

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Comments

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Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

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BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

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V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

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Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

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3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

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Coiiiincnts

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EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

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40-110

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Walcr Soil IU-11U 21-113

15-115

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nnclgtNMHml Method QC Acceptance CrUcrln

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Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

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V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

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VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

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EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

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Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

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VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

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SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

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XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

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Reported Vitue

Not Delected Compound

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XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

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bull

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-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 11: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u o J

05D

O50

10

10

05O

050

050

050

013

013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014

m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64

Page 01 of 01 F8786D

Sample Data Summary A0O00OOS

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL

75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u c J O50

0 5 0 1 0

1 0

0 5 0

0 5 0 bull 50 D50

0 13

0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2

Methylene Chloride cis-12-Dichloroethene

u D or 0 5 0

0 5 0 1 0

1 0

0 5 0 OSO

O50 05D

0 22 0 13

156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7

Page 01 of 01 F8B01D

Sample Data Summary A0000009

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

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Sampling variability is not assessed in data validation

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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

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EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

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Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

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II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

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Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

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Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

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A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

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V BLANK ANALYSIS Co

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Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

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V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

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EPA-NE - Data Validation Worksheet

V O A S V - V I I

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List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

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Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 12: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA

CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL

75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6

11-Dichloroethene 111-Trichloroethane

u c J O50

0 5 0 1 0

1 0

0 5 0

0 5 0 bull 50 D50

0 13

0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2

Methylene Chloride cis-12-Dichloroethene

u D or 0 5 0

0 5 0 1 0

1 0

0 5 0 OSO

O50 05D

0 22 0 13

156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14

m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7

Page 01 of 01 F8B01D

Sample Data Summary A0000009

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

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The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 13: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA

CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4

m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62

Page 01 c f 01 F 8 7 a 8 D

Sample Data Summary A0000010

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

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Page 14: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA

CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014

tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84

2199-69-1 l2-Dichlorobenzene-D4 65

Page 01 Of 01 FSB3 9D

Sample Data Summary A0000011

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

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The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

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EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 15: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA

CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene

m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4

Page 0 1

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030

Flag

u u u 0

U

V

D

C

D

U

V

0

D

0

o f 0 1

Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1

5

cr

Resu l t s 0 5 0

0 5 0

0 5 0

0 5 0

OSO

0 5 0

OSO

0 5 0

0 5 0

1 0

aso 1 5

Q 5 0

0 5 0

7 0

7 5

F H 7 7 7 D

DF

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

1 0

PQL

0 5 0

0 5 0

0 5 0

0 5 0

0 5 D

0 5 0

0 5 0

0 5 O

0 5 0

1 0

DSO

1 5

0 5 0

0 5 O

A r i j P Q L

0 5 0

0 5 0

0 5 0

DSO

0 5 0

D 5 0

D 5 0

0 5 D

0 5 0

1 0

0 5 0

1 5

0 5 0

0 5 0

A d j M D

0 2 0

0 1 3

0 1 3

0 1 1

a 22

0 1 3

0 13 0 1 3

0 1 4

0 2 4

0 1 0

0 3 4

0 2 6

0 1 2

Sample Data Summary A0000012

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

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N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

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Sampling variability is not assessed in data validation

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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

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EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

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Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

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II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

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Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

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A-NE - Data Validation Worksheet

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BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

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List the blank contamination below Contacted Ye Company

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Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 16: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

KATAHDIN ANALYTICAL SERVICES Report of Analytical Results

C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER

PO No

Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S

E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2

R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER

S o l i d s NA

CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e

7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e

7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e

1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e

7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e

m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e

67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4

P a g e

SDG WV4779

E x t r a c t e d b y

E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT

A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1

F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34

u D50 1 0 0 5 0 0 50 02G

o 0 5 0 1 0 0 5 0 a so 0 12 89 89

01 o f Dl FB77BD

Sample Data Summary A0000013

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

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The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

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EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

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Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

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Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

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List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

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V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

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3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

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EPA-N - Data Valtdntiou Worksheet

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40-110

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15-115

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nnclgtNMHml Method QC Acceptance CrUcrln

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Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

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Advisory Surrogates - OLM032

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EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

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EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

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Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

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Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

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EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

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SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

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XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

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XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

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REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

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yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

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This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

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REMARKS

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FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

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(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

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FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

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(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

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FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

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WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

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t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

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WEST SITEHOWS CORNER PLYMOUTH MAINE

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WEST SITEHOWS CORNER PLYMOUTH MAINE

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(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

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WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

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(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

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WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

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Time Purge - Stop Sampled

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LAB ANALYSES lt tA 1 amp~^

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ft ft ft

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(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

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Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

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Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

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I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

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T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

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THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 17: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA

CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G

11-Dichloroethene l11-Trichloroethaue

U D r 050

050 10

10

050

050

050

050

013

013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014

ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V

Page 01 of 01 FB79SD

Sample Data Summary A0000016

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

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WEST SITEHOWS CORNER PLYMOUTH MAINE

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I WEST SITEHOWS CORNER PLYMOUTH MAINE

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FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

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(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

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FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

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(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

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FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

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bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

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Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

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THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 18: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

KATAHDIK ANALYTICAL SERVICES Report of Analytical Results

Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA

CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4

m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3

Page 03 of 01 F87BDD

Sample Data Summary A0000017

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

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The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 19: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

WOODARDampCURRAN Engineering bull Science bull Operations

pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING

SEPTEMBER 2005

205279069_05sumTnary reportdoc

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

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The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

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EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

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Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

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BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

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List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

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V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

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3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

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VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

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40-110

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Walcr Soil IU-11U 21-113

15-115

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nnclgtNMHml Method QC Acceptance CrUcrln

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Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

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Advisory Surrogates - OLM032

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EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

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VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

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EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

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EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

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SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

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XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

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Validator

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XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

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1

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Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

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REMARKS

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FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

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Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

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WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

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FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

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FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

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(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

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REMARKS

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FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

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REMARKS A- vAftx ^XQfu

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I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

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| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

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(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

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REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

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I WEST SITEHOWS CORNER PLYMOUTH MAINE

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A n u l

ft ft ft

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REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

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FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

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SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

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REMARKS

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FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

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WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

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FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

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Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

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WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

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ft ft ft

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WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

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WEST SITEHOWS CORNER PLYMOUTH MAINE

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li^ ^f (Soe A g c r o

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Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

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Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

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I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

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T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

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THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 20: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida

Engineering bull Science bull Operations Operational offices throughout the US

October 3 2005

Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i

Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine

Dear Mr Connelly

Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report

Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters

bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification

The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported

41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

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Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

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Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

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THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 21: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us

for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection

Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results

A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results

A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision

The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report

Sincerely Woodard amp Curran Inc

gtfVlt^-A^ Jpvw^gtnj-shy

David Dinsmore Data Validator AUachmcnl

41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

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The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

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EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

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Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

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List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

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V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

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3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

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VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

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Method

OLM032

OLCU2I

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Walcr Spit 35-lTT23120_

40-110

Uccurcry

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Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

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Advisory Surrogates - OLM032

Validator

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EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

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EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

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EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

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VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

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SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

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XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

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Validator

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XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

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1

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Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

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FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

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REMARKS ^bullKWt

bullbull$amp

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FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

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340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

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COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

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v ^ O ^ ^ r t i S C J M ) ft rvf

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COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 22: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM

092005 DATA VALIDATION REPORT

SEPTEMBER 2005

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 23: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

A summary of the quality control results is included in the following subsections

I Data Completeness

The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete

II Sample Preservation and Technical Holding Times

All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances

III GCMS Instrument Performance (heck

The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory

IV Initial and Continuing Calibration Results

Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification

Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences

WOODARDampniRRAN (20529701) 1 100305

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 24: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

V Blanks

Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory

Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely

Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds

Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)

VI Surrogate Recoveries

Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory

VTI Internal Standard Areas and Retention Times

Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results

VIII Laboratory Control Samples

Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for

WOODARD amp CURRAN (20529701) 2 100305

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 25: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences

IX Field Duplicates

Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable

X Target Compound Identification

Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples

XI Summary and Overall Assessment of Data

Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results

Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site

WOODARD amp UJRRAN (20529701) 3 1W03QS

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 26: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG

PLYMOUTH ME SEPTEMBER 2005

SDG

WV4779

Analysis Completed USEPA-5242

Matrix

Water

Associated Samples

Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson

WOODASD amp CURRAN (20529701) 4

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 27: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242

HOWS CORNER SUPEREUND SITE PLYMOUTH ME

Compound Reporting Limit (pgL) Matrix

Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water

WOODARD amp CURRAN (20529701) 5 100305

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 28: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

WOODARDampCURRAN Engineering gt Science bull Operations

( ATTACHMENT 1 DATA VALIDATION WORKSHEETS

HOWS CORNER SLTPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

205279069_05 summary reportdoc

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 29: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No

REGION I ORGANIC DATA VALIDATION

The following data package has been validated

^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy

N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff

Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade

Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^

TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)

^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation

The data were evaluated based upon the following parameters

- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance

Region I Definitions and Qualifiers

A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples

Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t

amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^

1296

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

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f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

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mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 30: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n

Data Validation Repon components)

1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form

2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables

3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)

4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods

V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications

bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da

for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier

d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull

t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation

f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei

to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form

The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem

in response to EPA-KE data validation oversight findings

12

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 31: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11

VOLATILE ORGANICS

DQO (list all DQOs) Sampling andor Analytical Mctbod

Appropriate

Measurement Error _

Analytical Error Sampling Error1

Sa Vari

Yes or No

| o twtoi-for Qonob ^fttS-of

Wgtlaquo^c^--lti

-fampk^( di^Iv^ kJbWri d i s ^

The evaluation of sampling error cannot be completely assessed in data validation

Sampling variability is not assessed in data validation

Vi^Ll^st^~M^Validator

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

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Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 32: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm

SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method

Appropriate Yes or No

bull The evaluation of sampling error cannot be completely-jessed in data validation

+ Sampling variability is not assessed in data validation

Validator

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 33: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

pound bull

EPA-NE - Data Validation Worksheet VOASV - PestPCB

COMPLETE SDG FILE (CSF) AUDIT

Organic Fractions

Missing Information Date Lab Contacted Date Received

amp

Date Validator

1296

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 34: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

EPA-NE - Dntn Validation VOASV-r -1CIM

Dale Contacted Yes No Company Sample or X0K

Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes

Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)

Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c

Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 35: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy

II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)

LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria

Volnt l lc Instrument PciTorumnce Chcctt

(Compound Nninc)

Annljsts Dnlc unit Mine

Instrument Arrccfetl

Percent Itclntlvc

Atjtmtlnii i- UilVHs-1

Sntnples

Q-2I Q 2 T 9 amp 2 Mtn shy

Comments

mdash mdash mdash i mdash [ mdash bull - bull

Srin lvolnt l lc Instrument Perform nttcc Check

Ann lysis Dnlc IITTU Time

Instrument Ioraquo(s) Arfcclctl

Percent Rclntlve

QC Limits

Sniiiplcs

(Compound Nnme) Atmuilniice

i

Comments i

1

If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet

Validator M^^^d^^v

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 36: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

A-NE - Data Validation Worksheet

VOASV-III

BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria

Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL

Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi

Comments

Validator

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

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A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

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i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

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Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 37: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

EPA-N bull Data Vnlidniiun Worksheet VOASV-IV

List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION

l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp

M QiLpt(tfr

Comments

j^WdJ ^Lw^ O^^Tf^g -Validator

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

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Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

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XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

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-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

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FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 38: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

A-NE - Data Validation Worksheet vOASV-1MtICU-V-A

V BLANK ANALYSIS Co

List the blank contamination below Contacted Ye Company

Sampler _

L^onuory Mcdod Stornc mid M n m r i U N

Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2

Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc

77 IP BukraquoC

firq pom

Validator

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 39: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

I

A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ

3 Blank Actions - List the maximum coneciilnlions of blank compounds

Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level

(units) units)

T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y

Coiiiincnts

VnlUhlun ^ k J y j ^ ^ D

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

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FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 40: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

VI

EPA-NE - Dain VnlklaUon Worfesteset

V 0 A V I H raquo ^ n n u n d recoveries thai arc outside

VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc

Volnttle MHlinrt PC Acceptance CrUcrln

DCE-d Oilier Mettiml Talueitc-il BPB

Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138

Validator |^1fij V^^U

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 41: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

EPA-N - Data Valtdntiou Worksheet

T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^

OLM032

OLCU21

Oilier gmmtlc NunibcrMntrlt

Method

OLM032

OLCU2I

Otlicr Snnmlc Ni i in l tcrMnhIx

Walcr Spit 35-lTT23120_

40-110

Uccurcry

Phcnol-d

Walcr Soil IU-11U 21-113

15-115

Recovery

nnclgtNMHml Method QC Acceptance CrUcrln

TPH-dn lfrDCB-d

Water Soil -rj-lfiTsOTlS

30-110

Water Soil 33^141 18-137

20-MU

Water Soil I6-11UZU-I3U

NA

Recovery Recovery R ceo very

Acid Me Hit) J QC AcccptnnccCrKcrtn^

2-PP 24C-TBP 2-CP-d

Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130

Uccovery Recovery Recovery

15-110

Oilier

Re

Oilier

R

Advisory Surrogates - OLM032

Validator

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 42: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

bull

EPA-NE - Data Validation Worksheet

V O A S V - V I I

INTERNAL STANDARD PERFORMANCE VII

List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta

IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _

IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J

Count nti i l or Number Atinlyzed [IS IVI Criteria

(TIW) bull

j f^ lnW

f A

bull I

Validator ^ J IJ^J ^^JfiAjLuiati_ shy

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 43: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

i

EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH

VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW

criteria

Use a separate worksheet for each MSMSD pair

Mnlr ix Sample _

MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI

Rcc Rcc TJlisplketl MS Rec RPD Sample

i

-

f gt _

Validator _

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 44: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

EPA-N Dala Validation Worksheet VOASv - PcslFCIMX

IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria

Use a separate worksheet Tor each field duplicate pair

Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^

Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc

SQL 2xSQL SQL 2xSQL

M OK

i

Pur instances where one duplicate result is ND (or reported lefts than the sample QL)

Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N

Comments _ _ _ bull bull

Sampler Name Contractor Name Date Contacted

Reason Tor Contact and resolution obtained

Q^)fLv i i M n i - I A I lti A X shy- Dure

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 45: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X

X SENSITIVITY CHECK (Method Detection Limit Study)

List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin

Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J

bull Instrument iD Same as samples _ Same ns samples bull Column ID

Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa

I

ITnn MDL study tins not been submitted use only the LFB results to evaluate data

(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs

bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand

MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh

gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft

J bull i r

bull

Validator1 hr^^^^^vLAn^^ Date fCo

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 46: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

EPA-r bull Data Validation Worksheet

VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a

I - ) lt raquoltraquogtlaquo tol a r e ^ ^

SDG No

Arc tnorc

CASE

than one-half of the PESanalylcs within criteria Tor each parameter v-

Cone Region I EIA Non-EPA P Mnfrlx Annlyle

PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number

Number

For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT

+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)

Validator

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 47: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc

Sniiiplc Numdcr Cuiiipuuint MS I out run v

-

bull r

~

L _ _

bull

bull shy

bull

i

gt

mdash

Validator

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 48: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU

XIII SAMPLE QUANTITATION

Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe

Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__

Cnleulnllon Fraction

YOA

Simple No

He ported Compound

Reported Vilue

Not Detected Compound

Rrponed Qujmiudon Limit

UNA

Simple No i

Reported Compound

Reported Vlaquotue I lt

Not Detected Compound

Rrpoitctl Quantitation Limit

TMlklde^rCn

Simple No Reported Compounit

bull

Reported Vitue

Not Delected Compound

tltpotttil Quiniititton Limit bull bull

Validator

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 49: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV

XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)

List tlic 5 TICs having (lie highest concentration for each sample parameter

Snmplc Number Pnm ureter Compound jtSrr Est Co

-

bull

-

l

- m

-

1

-

1

Validator

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 50: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE

^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^

^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r

SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o

EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE

TPOPO ACTION FYI DV COMPLETION DATE IQfoZif

ANALYTICAL DATA QUALITY SUMMARY

bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check

bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull

yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)

AREAS OF CONCERN (m items) M l 0lt3

^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy

This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality

Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations

Jidator hhJU Q L ^ Date O0Zc6mdashmdash

INSTRUCTIONS ON REVERSE SIDE

129

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 51: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

JJI i u E i d i u UJ v_ltiic IgtiOS^

Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call

Laboratory Name

Lab Contact

Region

Regional Contact

Call Initiated By Laboratory Region

In reference to datarfbr the following sample numberCs)

Summary of QuestionsIssues Discussed

Summary of Resolution

Signature Date

Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 52: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

WOODARDampCURRAN Engineering bull Science bull Operations

ATTACHMENT 2 FIELD SAMPLING WORKSHEETS

HOWS CORNER SUPERFUND SITE PLYMOUTH ME

SEPTEMBER 2005

20527906905 summary reportdoc

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 53: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well amp ~( F^5J

Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr

Sampled plusmn^plusmnlt^

SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]

(Specify)

WELL SPECIFICATIONS

LAB ANALYSES C u J tVj^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) t laquo mdash J raquo F m - t d

Depth Depth Depth

A K-Uraquol i ^ t i f

ft ft ft

U- t^uA i

deg^poundc (j-i^rshBA^ 3

ff J

V J P

J^f

REMARKS

T k_ pound v

ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy

WWWR I

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 54: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ D orr^r

Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f

Sampled - lt W J ~

SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti

u^gtC Ct2 gtflarr^J(^pyj4 A

REMARKS fjj oyovf j q^^uj^r

MftBWR

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 55: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

FIGURE 4

WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well )~T- ( J u t t f l

Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt

Sampled AampSampL

SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci

bull^sfhtc ( i i i UU^^A f | n)ft _JL

REMARKS T^U^-IJLamp _ ^^^^Jtar

wsewR

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 56: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

I I

FIGURE 4

WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well ll-t 6-0 ampo v

Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy

Sampled lt pound f V

SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt

0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4

REMARKS

wsewR

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 57: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

WEST SITOHOWS CORNER PLYMOUTH MAINE

Residential Well A laquo o g h J -

Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO

Sampled tegt3

SAMPLING POINT Kitchen Sink Outside Sillcock Other

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA

t^SHt ( - 3 ^ K^ L^vrTTTrnr 1

REMARKS A- vAftx ^XQfu

f

048SWR

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 58: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well ^ f G- f o p K t n

rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC

| Sampled V ^ 4 i

SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]

(Specify)

WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft

(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J

L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL

REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_

MaewR

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 59: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS

I WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well 3 Z - - shy H t x ^ B J

DateTime Purge - StartTime Purge - Stop

Sampled

~ y | ~ampf amp y-p 7 0 0 700

Weather Samplerfs) Y -vST

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

J J_

WELL SPECIFICATIONS

LAB ANALYSES

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) I M SL

Depth Depth Depth

A n u l

ft ft ft

TZ- bull~KJr mdashti

L ^ C (L--poundI-lta^ o (H jA A fi

REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r

fslpoundW - R T N ^ - N T

OWBWR

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 60: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well amp~)mdash[ G^co^

Date Weather_ __^^_^M I

Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi

SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft

(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4

b^s yt_(es-06- ltltvv Cs 1 5) A amp

REMARKS

I ^ J Q J - S 4 - poundbull-gt laquo n

bull

ltBevw

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 61: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

FIGURE 4

WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well l H t U w ^ laquo v

Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o

Sampled namp

SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft

(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL

L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt

(M-l)

REMARKS g^- t l t j shy

y ^ ^

tweewR

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 62: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

I

I

FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Well - f 9 c u v y laquo C

I

bull

Date Time Purge-Start

Time Purge - Stop Sampled

lt lt3J

raquo^_ii^ 7^J

nif

Weather Sampler^)

SAMPLING POINT

WELL SPECIFICATIONS

LAB ANALYSES lt tA 1 amp~^

Kitchen Sink [ Outside Sillcock [ J_ Other [ ]

(Specify)

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify) s kx FlTl^cd

Depth Depth Depth

ft ft ft

At-Hl^yt -r ~Ullaquo-tullt-^t3

LJJSIHCX I-H 6 laquogt ( t n U A

REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^

BWrf poundj--^ r c y poundltxLjyJiT

1 OWWVR

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 63: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

I FIGURE 4

WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER

PLYMOUTH MAINE

Residential Well p - j) altc^pT

Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ

Sampled totgt

SAMPLING POINT Kitchen Sink [ ]

Outside Sillcock Other i )

(Specify)

WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft

(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM

HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A

r 5

REMARKS ^bullKWt

bullbull$amp

W86WR

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 64: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS

WEST SITEHOWS CORNER PLYMOUTH MAINE

Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^

Date Time Purge - Start Time Purge - Stop

Sampled

li^ ^f (Soe A g c r o

Weather Samplerfs) ^ ^ g mdash

SAMPLING POINT Kitchen SinkOutside SillcockOther

(Specify)

[ [

[

] s_

]

WELL SPECIFICATIONS

LAB ANALYSES c u ^

Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]

(Specify)

Depth Depth Depth

iniV bull

ft ft ft

C-raquo- -ukAi- t i

UsftleuroL (i vsi (OOAO-N (ltfrvv (

4 _pound

REMARKS ^-kW^

-

olaquoewR

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

Client Contact Phone Fax

dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

TTvptsk fl shy

_pound_ shy

fraquo sVJ ^oraquon fl

shy

OC c q ) ^ mdash

5 vi I V ^ c (7^ ^ I - fc=raquoraquo

ltsv) ^y y deg zi

F-feU Tfa^W ft j fii n i I~L plusmnL I V

COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

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THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 65: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

340Connt)gt Road No 5

PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092

Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of

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dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q

Bill (if different than above) Address 0shySampler (PrintSign) Copies To

e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE

PRESERVATIVES LAB USE ONLY

KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS

SHIPPING INFO bull FED EX n UPS bull CLIENT

AIRBILL NO

TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT

Date Time No of Sample Description Matrix colld Cntrs

^ T C y J_

gtamp C j-~lCUWltfyK 7

pound p V gt

pound

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_pound_ shy

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COMMENTS

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS

KAS-COC1 CUSTOMER COPY

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

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COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712
Page 66: WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The next monitoring event is scheduled to take place in December 2005 and will consist

340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of

Client Contact Phone Fax

lticgtrA f C^f3 p v v

Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code

Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote

Bill (if different than above) Address A

Sampler (PrintSign) ( Copies To -N T

WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt

I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn

SHIPPING INFO l~l FEDEX bull UPS bull CLIENT

AIRBILL NO

TEMPC D TEMP BLANK bull INTACT O NOT INTACT

Date Time No ofSample Description Matrixcolld Cntrs

7Jltgt=gt V T laquo

rf1

v ^ O ^ ^ r t i S C J M ) ft rvf

AiiLL

t o t

B i 6raquor

3 Zi^ Oo

J3 J amprr

3

1 gtoo

COMMENTS pound LZI

Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)

T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)

k j i f l ^nm

THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY

  1. barcode 251712
  2. barcodetext SDMS DOC ID 251712

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