WORLD CONGRESS III OF CHEMICAL ENGINEERING September 21(Sun)—25(Thur), 1986 Keio Plaza Hotel Tokyo, Japan Volume IV UNIVERSITATSBIBLIOTHEK HANNOVER TECHNISCHE INFORMATIONSBIBLIOTHEK Sponsored by : The Asian Pacific Confederation of Chemical Engineering The Interamerican Confederation of Chemical Engineering The European Federation of Chemical Engineering Organized by : The Organizing Committee of the World Congress III of Chemical Engineering The Society of Chemical Engineers, Japan TIB/UB Hannover 89 liiniinillll
Transcript
WORLD CONGRESS IIIOF
CHEMICAL ENGINEERING
September 21(Sun)—25(Thur), 1986Keio Plaza Hotel
Tokyo, Japan
Volume IV
UNIVERSITATSBIBLIOTHEKHANNOVER
TECHNISCHEINFORMATIONSBIBLIOTHEK
Sponsored by :The Asian Pacific Confederation of Chemical EngineeringThe Interamerican Confederation of Chemical Engineering
The European Federation of Chemical Engineering
Organized by:The Organizing Committee of the World Congress III of Chemical Engineering
The Society of Chemical Engineers, Japan
TIB/UB Hannover 89
liiniinillll
VOLUME IV
SESSION 9. REACTION ENGINEERING
9a. Reaction Kinetics
Chairmen: T. Akehata (Tokyo Institute of Technology)S. Asai (University of Osaka Prefecture)J. M. Asua (University of Paris Vasco)T. Furusawa (University of Tokyo)V. Hlavacek (State University of New York)M. Kwauk (Institute of Chemical Metallurgy
Academia Sinica)K. C. Kwon (Tuskegee University)K. Koide (Tokyo Institute of Technology)W. Y. Lee (Seoul National University)R. Mezaki (Mitsubishi Chemical Industries, Co., Ltd.)T. Okazaki (Tokushima University)C. N. Satterfield(MIT)M. M. Sharma (University of Bombay)T. Sugawara (Akita University)T. Tadaki (Tohoku University
9a-I01 Kinetics of aldehyde oxidation including two-phase reaction by usinga heterogenizing homogeneous catalyst
T. C. Chou and B. J. Hwang IV-1
9a-102 Reduction of the number of independent parameters in chemical kineticsregression analysis
V. G. Dovi, E. P. Arato, O. Paladino, A. Isimbaldi andB. Canepa IV-4
9a-103 Reducing overestimation in chemical kinetics regression analysisV. G. Dovi, O. Paladino, E. P. Arato, A. Isimbaldi andB. Canepa IV-8
9a-104 Effect of segregation on multiple steady states in a stirred reactorN. Vatistas and P. F. Marconi IV-12
9a-105 Kinetics of aqueous SO2 oxidation in presence of calciumW. Pasiuk-Bronikowska and J. Ziajka IV-16
(66)
9a-106 Kinetics of solid production accompanying gas-liquid reactionH.Yagi IV-20
9a-107 The rate analysis of CO oxidation by a pulse microreactorK. Toyoda and S. Morikawa 1V-24
9a-108 Evolution of hydrodesulfurization of dibenzothiophene over hydro-treating catalysts
K. L. Kim and K. S. Choi IV-28
9a-109 Nonisobaric diffusion of gases in bidisperse porous catalyst pelletsM. Asaeda, S. Wakaki and C. McGreavy IV-31
9a-110 High temperature decomposition of CaMg (CO3)2
A. Casalonga Olalde, J. C. Mora and R. S. Bes IV-35
9a-l 11 Kinetic study on isotopic exchange reaction between hydrogen and watervapor over a hydrophobic platinum-supported catalyst
K. Kawakami, Y. Takao and K. Kusunoki IV-38
9a-112 Chemical kinetics and reaction mechanism of thermal decomposition ofaluminum hydroxide at high temperature (973-1123 K)
I. Chen, S. K. Hwang and D. W. Shiue IV-42
9a-113 Analysis of gas-solid reactions from the changes of pore structureG. Dogu, U. Koyuncu and T. Dogu IV-46
9a-114 Comparative kinetics of fluidized bed combustion of Australian oilshale chars
B. G. Charlton and P. G. Alfredson IV-50
9a-115 Dissolution kinetics of iron oxide from Egyptian clays in sulphuric acidF. H. A. Mohammad and Sh. I. El-Shawarby IV-54
9a-116 Kinetic study of sulfonation of tolueneS. Issa, G. El Diwani, Q. Hafez and S. Hawash IV-58
9a-201 Front instability and fingering effects in noncatalytic exothermicreactions
J. Puszynski and V. Hlavacek IV-62
9a-202 The kinetic modelling of the combustion of ethane in a refractory tubeburner
L. D. Pfefferle and S. W. Churchill 1V-68
9a-203 Diffusion-controlled kinetics of the two-stage oxidation of carbondispersed in coal wastes
H. Y. Sohn and R. Padilla IV-72
(67)
9a-204 Kinetics of the catalysts regeneration by coke burning under conditionsin which diffusion influences
A. T. Aguayo, J. Bilban, M. Olazar and J. M. Arandes IV-76
9a-205 Pyrolysis behaviour of Australian oil shales in a 20 kg/h processdevelopment unit
N. V. Dung, G. C. Wall, G. Kastl and P. G. Alfredson IV-80
9a-206 Steam pyrolysis of virgin and hydrotreated heavy oilsE. Ranzi, M. Dente, S. Pierucci, S. Barendregt and P. Cronin . .IV-84
9a-207 Investigation of changes in diffusion and sorption parameters withconversion in non-catalytic gas-solid reactions by pulse-responseexperiments
T. Dogu, A. Keskin, G. Dogu and J. M. Smith IV-88
9a-208 Thermal effects on coal liquefactionK. C. Kwon and N. Vahdat IV-92
9a-251 The predigestion stage of a new phosphoric acid processS. v/d Sluis, Z. Murach, J. A. Wesselingh andG. M. van Rosmalen IV-96
9a-253 A mathematical model for computer simulation of a direct continuousesterification process between terephthalic acid and ethylene glycol
T. Yamada, Y. Imamura, O. Makimura and H. Kamatani . . . .IV-104
9a-254 Modeling of free radical polymerization of ethylene—Prediction ofpolymer quality
M. Pons, L. Blavier, J. L. Greffe and J. Villermaux IV-108
9a-255 Continuous solution polymerization under periodic controlW. Geiseler IV-112
9a-256 Non-isothermal kinetic analysis of the transesterification stage duringthe manufacture of poly (ethylene terephthalate)
M. J. Barandiaran and J. M. Asua IV-116
9a-257 Kinetics of simultaneous absorption of ethylene and chlorine in waterand hydrochloric acid in an agitated vessel with a flat gas-liquid interface
H. Hikita, H. Ishikawa, T. Okamoto and K. Mogami IV-120
9a-301 Change in catalytic activity of silica-alumina catalysts during sinteringat high temperature and steam atmosphere
K. Hashimoto, T. Masuda, T. Nakamori and K. Isobe IV-124
(68)
9a-302 The effect of catalyst deactivation on the dehydration of ethanol overzeolite 13X
P. L. Yue and N. Zafaris IV-128
9a-303 Catalyst lifetime improvement in phthalic anhydride production ofo-xylene and/or naphthalene on the same catalyst
G. Bellini and S. Covelli IV-132
9a-304 Effects of temperature on product selectivity in the Fischer-Tropschsynthesis on iron catalysts
C. N. Satterfield, D. K. Matsumoto and R. T. Hanlon IV-136
9a-305 Kinetics of hydrogen storage in LaNi5 and CaNi5
K. S. Nahm, W. B. Jung and W. Y. Lee IV-140
9a-306 Reactors for heterogeneously catalyzed hydrogenation of rape seed oilR. Milan, S. Petr, S. Jiri and K. Frantisek IV-144
9a-307 Analysis of the effect of the local capacity level of the functional groupson the catalytic activity for the sulfonated macroreticular styrene-divinylbenzene copolymers
S. K. Ihm, J. Klein and H. Widdecke IV-148
9a-308 Reaction engineering of anhydride synthesisJ. L. Herce-Vigil, A. K. Hale, R. Bugarel IV-152
9a-351 Rates of isotopic exchange between hydrogen and aminomethanecatalyzed by potassium and lithium methylamides
J. M. Malcolm and F. D. Otto IV-156
9a-352 A study on the kinetics and curing mechanism of polyimide formicroelectronics
O. C. C. Lin, W. T. Whang, M. L. Tzeng, S. C. Wu andJ. S. King IV-160
9a-353 The continuous manufacturing of terpinM. O. Maia, J. B. Romero, and C. A. Bernardo IV-164
9a-354 Intensification of heterogeneous reactions through hydrotropy—Alkalinehydrolysis of esters and oximation of cyclododecanone
A. Pandit and M. M. Sharma IV-166
9b. Reactor Design
Chairmen: K. Hashimoto (Kyoto University)Y. G. Kim (Korea Advanced Institution of Science
and Technology)Z. Leszcynski (Institute of Industrial Chemistry)
(69)
M. Nakamura (Nagoya University)T. C. Tan (National University of Singapore)S. Toyama (Nagoya University)P. Trambouze (Institution Francais du Petrole)
9b-151 Enrichment of the combustion air with oxygen in a FCCU regeneratorJ. M. Arandes, M. J. Azkoiti, J. Bilbao, A. T. Aguayo, M. Olazarand J. Rodrigo IV-169
9b-152 Gas-liquid downflow, upflow and countercurrent flow in packed beds—Reactor performance for a gas-limiting reaction
E. G. Beaudry, P. L. Mills and M. P. Dudukovic IV 173
9b-153 Direct simulation of turbulent mixing with irreversible chemical reactionA. D. Leonard and J. C. Hill IV-177
9b-154 Flow of non-Newtonian fluids through chemical reactorsJ. M. Aragon, L. G. Jodra and M. C. Palancar IV-181
9b-155 Simulation of a catalytic reforming plantA. A. Ballut, S. A. Husain and N. A. Farugi IV-185
9b-156 On the transient behaviour of vertical upflow, downflow and horizontalflow transport reactors
S. Sivakumar, M. Chidambaram and H. S. Shankar IV-187
9b-157 Statistical theory of liquid flow in trickle-bed reactorsF. O. Fox and L. T. Fan IV-191
9b-158 Modeling of bubble column reactorsW. D. Deckwer IV-195
9b-l 59 Effect of catalyst deactivation on the steady-state behaviour of counter-current bubble column slurry reactors
M. Chidambaram IV-199
9b-160 Optimization procedure and operative ranges for the design ofmechanically stirred gas-liquid CSTR reactors
A. Brucato, V. Brucato and L. Rizzuti IV-203
9b-161 A simplified method for the design of a chemical flow reactor in thepresence of axial dispersion
P. V. Lad and O. T. Hanna IV-207
9b-162 The interrelation between mixing of coal particles, combustion reactionsand sulfur dioxide emission during combustion in the fluidized bed
D. Bellgardt, M. Schoessler and J. Werther IV-211
(70)
9b-163 The tubular reactor with laminar flow regime—An integral equationapproach (I): Homogeneous reaction with arbitrary kinetics
P. E. Arce, A. E. Cassano and H. A. Irazoqui 1V-215
9b-164 Comparison between the optimal temperature policies of reactors withparallel and series catalyst deactivation
J. R. Gonzales-Velasco, M. A. Gutierrez-Ortiz, J. A. Gonzales-Marcos and J. I. Gutierrez-Ortiz IV-219
9b-251 Direct determination of absolute light intensity profiles in heterogeneousphotoreactors
H. Funayama, T. Sugawara and H. Ohashi IV-223
9b-252 Hydrogen reduction of metal sulphides in the presence of calcium oxideJ. D. Ford and T. C. Tan IV-227
9b-253 Analysis of a CVD reactor instabilities by a non linear thermodynamicsirreversible process model
R. S. Bes, J. C. Mora, S. Benet and B. Armas IV-231
9b-254 Transient behaviour of reactors with convective transport inside catalystsR. Ferreira, C. Costa and A. Rodrigues IV-235
9b-255 The unsteady-state solution for a dispersion-type tubular reactor packedwith bidispersed porous catalysts
D. H. Kim and K. S. Chang IV-239
9b-256 Improvements in the design of multitubular reactors for highly exothermicprocesses
A. Stankiewicz, Z. Leszczynski and D. Adamska-Rutkowska . . . . 1V-243
9b-257 Petrov-Galerkin finite element formulations for chemically reacting systemsT. E. Tezduyar, H. A. Deans, Y. J. Park and P. W. Park IV-247
9b-301 Flow of iron and slag in the blast furnace hearthW. B. U. Tanzil, P. Zulli and W. V. Pinczewski IV-251
9b-302 Peculiarities of catalytic processes' realization in transport-line reactors(TLR)
V. A. Makhlin, A. S. Evenchik, M. G. Slin'ko IV-255
9b-303 Selective hydrogenation of triglycerides in a trickle-bed reactor usingchromia promoted nickel-silica catalyst
D. Krishnaiah and S. Sarkar IV-259
9b-304 Hydrodynamics and solid-liquid contacting effectiveness in an upflowmultiphase reactor
I. Mazzarino, S. Sicardi and G. Baldi IV-263
(71)
9b-305 Simultaneous measurement of radial distributions of gas and liquidflow rates in trickle bed reactor
M. Nakamura, H. Mori, K. Iwai, Y. Mizutani, T. Matsuzawa andS. Toyama IV-267
9b-306 Prediction of gas holdup in pressurized bubble column reactorsI. G. Reilly, D. S. Scott, T. de Bruijn, A. Jain and J. Piskorz IV-27I
9b-307 Slurry circulation, gas holdup and pressure drop in solid-suspendedbubble column with draught tube
K. Koide, H. Kawabata, M. Kimura and K. Oshikawa IV-275
9b-308 Generalized design correlations for the liquid-phase RTD in packed-bedreactors during trickle-flow
J. O. Valderrama and M. A. Yanez 1V-279
9b-351 Simulation of a jet-spouted bed reactor with catalyst circulationJ. Bilbao, M. Olazar, A. Romero and J. M. Arandes IV-283
9b-352 A unified approach to the modelling of catalytic fluidized bed reactorsS. Dutta IV-287
9b-353 Behaviour of solids in a fast fluidized bedT. Kojima, K. Ishihara, M. Kuramoto and T. Furusawa VI-291
9b-354 Fluidized bed reactor modeling for production of silicon by silanepyrolysis
M. P. Dudukovic, S. Lai and P. A. Ramachandran IV-295
9c. Catalysis
Chairmen: H. S. Fogler (University of Michigan)H. Komiyama (University of Tokyo)Y. Murakami (Nagoya University)E. Rodrigues (University of Porto)
9c-201 Characterization of bimetallic catalysts by gas titration and analyticalelectron microscopy
A. G. Shastri and J. Schwank IV-299
9c-202 Hydrogenation activity of amorphous Pd-Zr alloysT. Takahashi, N. Ostuji and Y. Nishi IV-302
9c-203 Catalytic activity and chemisorption of supported nickel catalystH. Inoue and M. Funakoshi IV-306
9c-204 A new catalyst preparation—Silica supported nickel catalyst by chemicalvapor decomposition
Y. Tsugo, H. Ooi, M. Yano and Y. Harano IV-310
(72)
9c-205 Effects of drying conditions on physical and catalytic properties ofnickel/alumina catalysts
Y. Uemura, Y. Hatate and A. Ikari 1V-314
9c-206 Kinetics of dehydration of ethanol to ethylene with mordeniteG. Raman and S. K. Raman 1V-318
9c-207 Gas-phase isomerization of ethylbenzene over various Y-zeolitesupported catalysts
G. D. Lee and H. I. Lee IV-322
9c-208 Methanol conversion to hydrocarbon over heteropoly compounds andmordenites
T. M. Kwon, M. J. Lee and W. Y. Lee IV-326
9c-209 Catalysis of heterogeneous basic copper—(II) complexes for the oxidativecoupling reaction of 2, 6-dimethylphenol
T. Takaki, S. Nishiyama, S. Tsuruya and M. Masai IV-330
9c-210 Methanol synthesis from synthesis gasW. Tanthapanichakoon, S. Limtrakul, S. Chanchamchoy,S. Phuangphuaksook, T. Inui and Y. Takegami IV-334
9c-211 Catalytic pyrolysis of almond shells in fluidized bedF. Ruiz, R. Font, A. Marcilla, E. Verdii and J. Devesa IV-338
9c-212 Prediction of transport parameters for fixed bed reactorsC. McGreavy and E. A. Foumeny IV-342
9c-213 Dynamics of a slurry reactor by time-domain analysisB. J. Ahn, M. Lazaro and F. Recasens IV-346
9c-214 Rapid estimation of catalyst life by periodic pulse techniqueT. Hattori, S. Komai, A. Miyamoto and Y. Murakami 1V-35O
9c-215 Efficient conversion of benzophenone azine into hydrazine by phase-transfer acid catalysis
H. Hayashi, J. Somei and T. Okazaki IV-354
9c-216 Multiplicity, stability and oscillations of lumped parameter reactionsystems
I. Polizopoulos and C. G. Takoudis IV-358
9c-251 Kinetic behavior of partially reduced metal catalysts and their surfaceproperties
S. H. Moon, K. E. Yoon and Y. G. Kim IV-362
(73)
9c-252 Effect of metal-zeolite interaction on the catalytic properties of Ruin the Fischer-Tropsch synthesis
Y. W. Chen, J. N. Liaw and W. T. Liu IV-366
9c-253 Optimal catalyst activity profiles in pelletsA. Varma, M. Morbidelli, R. Chemburkar and C. K. Lee IV-370
9c-254 Reaction kinetic correlation for predicting gasoline yield in fluid catalyticcracking
L. C. Yen IV-374
9c-255 Modelling of the periodic composition forcing of catalytic reactionsC. Li, R. R. Hudgins and P. L. Silveston IV-378
9c-256 A transient experimental technique for the study of dynamic responseof fixed bed catalytic reactors
C. McGreavy, A. N. Ikponmwosa, E. A. Foumeny IV-383
9c-257 Steady-state and transient kinetic studies of an industrial vinyl acetatecatalyst
A. Rabl, R. Doepper and A. Renken IV-387
9c-301 Studies on the merox processA. Leitao, C. Costa and A. Rodrigues IV-391
9c-302 Dissolution instabilities and semiconductor band energies and their rela-tion to accelerated mineral dissolution
S. E. LeBlanc and H. S. Fogler IV-395
9c-303 Solid electrolyte aided studies of hydrogen oxidation on nickel andmethane ammoxidation to hydrogen cyanide
M. Stoukides, C. Saranteas, D. Eng and S. Seimanides IV-399
9c-304 The disproportionations of trichlorosilane and dichlorosilaneS. Morimoto, K. Kawashiro, H. Yoshida, F. Tamura, M. Tochino,M. Watanabe and S. Shimosaki IV-403
9c-305 Study of the operating conditions in the polymerization of gaseonsbenzyl alcohol on acidic catalyst
M. Olazar, A. T. Aguayo, A. Romero and J. Bilbao IV-407
9c-306 The selective catalytic hydrogenation of acetylenes in an industrialbutadiene feedstock
I. Kummerow, D. L. Trimm and M. S. Wainwright IV-411
9c-307 Hydroisomerization of cyclohexane and n-heptane using Ni-Mo andNi-W catalysts supported on silica-alumina
A. S. Nasution IV-415
(74)
9c-308 The new Ruhrchemic/Rhone-Poulenc version of the Oxo synthesis—Hydroformylation with water-soluble catalysts
B. Cornils, W. Konkol, W. Gick, E. Wiebus and H. Bach IV-419
9c-351 A comparative study of catalysis by amorphous/crystalline Ni-Zr alloysand metallic Ni
Y. Egashira, S. Sumiya, H. Komiyama, S. Ohnuma, Y. Nakanouchiand T. Masumoto IV-422
9c-352 Bimetallic sulfide cluster catalystsL. T. Thompson, Jr., M. David Curtis and J. Schwank 1V-426
9c-353 Characterization of supported iron clusters prepared from solvated metalatom techniques
S. I. Woo and G. A. Ozin IV-430
9c-354 Selectivity in supported catalyst pellets of arbitrary geometry for non-uniform distribution of catalytic activity
B. C. Sutradhar, P. Ray and B. K. Dutta IV-434
SESSION 11. MATERIALS
lla. Materials and Their Applications
Chairmen: M. P. Dudukovic (Washington University)H. Hojyo (Tokyo Institute of Technology)O. C. C. Lin (Materials Research Laboratories)H. Okada (Nippon Steel Co., Ltd.)T. Shinohara (Toyo Engineering Co., Ltd.)D. W. Yarbrough (Tenessee Technological University)
1 la-201 Effect of slurry flow on erosion of plasticsH. Hojo, K. Tsuda and K. Arai IV-438
1 la-202 Recent development of corrosion control by organic coatings andproblems
S. Okuda IV-442
1 la-203 A new in-situ system for monitoring phase and property change inchemical engineering systems
M. I. Ismail IV-446
I la-204 A remedy for stress corrosion cracking by altering the residual stressesM. Takemoto and T. Shinohara IV-450
I la-301 The migrations of various anions into crevices or stress corrosioncracks and their effects on crevice corrosion and SCC
J. Y. Zuo, Z. Q. Jin and M. Zhou IV-454
(75)
1 la-302 Survey on external stress corrosion cracking failures in JapanT. Kawamoto IV-458
lla-303 Hydrogen diffusion and trapping in Cr-Mo-V steelsM. Leoni, G. Fame, R. Grimaldi and G. Randi IV-461
1 la-304 Studies on DX-A performance in mitigating corrosion of iron and ironalloys in acidic environment
Dhirendra IV-465
lla-305 Effect of some drag reducing polymers on the corrosion of zinc inphosphoric acid
R. S. Al-Ameeri and M. S. E. Abdo IV-469
1 la-306 Flow-dependent corrosion within copper alloyed tubes due tocontaminated saline waters
B. Haase IV-473
1 la-307 Materials for pressure chemical reactors—Stainless steelsM. I. Ismail IV-477
lla-308 Some results of new additives evaluation for electrolytical nickel platingprocesses
L. M. Blanco, A. Ruiz, J. Hernandez and J. Muiiiz IV-481
lla-351 Wear of chemical engineering materials due to turbulent liquid-solidflows
R. Liebe IV-485
lla-352 A stochastic approach to inter-fiber bonding of cellulosic systemsY. M. Haddad IV-491
lla-353 The adhesion behavior of liquid rubber modified epoxy resinY. D. Lee and W. K. Chin IV-495
lla-354 Resin flow and voids formation during curing of reinforced graphitecomposites
J. L. Kardos, M. P. Dudukovic and R. Dave IV-499
lib. Polymer Processing
Chairmen: S. Arai (Toray Co., Ltd.)A. S. Mujumdar (McGill University)M. R. Kamal (McGill University)
I lb-201 Extrudate swells of polimeric fluidsK. Adachi and M. Yamano IV-503
(76)
1 lb-202 Cold plasma polymerisation of ethyleneE. Hedayati, J. C. Mora and R. S. Bes IV-507
1 lb-203 Preparation of microcapsules with styrene slurry polymerizationin droplets
Y. Hatate, H. Hamada, Y. Kurokawa, A. Ikari andF. Nakashio IV-510
1 lb-204 The thermal stability of polyphenylene sulfide and polyether etherketone resins and composites
C. C. M. Ma., H. C. Hsia, B. Shieh, W. L. Liu andJ. T. Hu IV-514
llb-205 The study on die swell, fiber length distribution and crystallinity ofPP composite through extrusion
W. Y. Chiu and G. D. Shyu IV-518
1 lb-251 Numerical simulations of non-isothermal molten polymersP. A. Tanguy and A. Fortin IV-522
1 lb-252 A comprehensive CAD/CAM model for microstructureM. R. Kamal and E. Chu IV-526
1 lb-253 Computational analysis of melt flow through a short extruder dieH. J. Park, J. W. Lee and K. J. Lee 1V-53O
llb-254 Computer-aided analysis of the wire-coating processE. Mitsoulis and R. Wagner IV-534
1 lb-255 The correlations of processing variables for optimizing the pultrusionprocess (II)
C. C. M. Ma and J. S. Hwang IV-538
llb-256 Multiple solutions for profiles in film blowingJ. J. Cain and M. M. Denn IV-542
1 lb-257 Transient rheological behaviour of polymeric liquid crystalsP. Moldenaers and J. Mewis IV-546
SESSION 12. COMPUTER APPLICATIONS IN CHEMICALSENGINEERING
12a. Application of Knowledge Engineering
Chairmen: H. Nishimura (University of Tokyo)R. G. H. Prince (University of Sydney)
(77)
12a-101 Knowledge-based system for process synthesisC. D. Mehta and L. T. Fan 1V-550
12a-102 An integrated computer-aided engineering information managementsystem for chemical plant design
M. Benayoune and P. E. Preece IV-554
12a-103 A knowledge engineering approach to oxygenation reactions productionrules for singlet oxygen reactions
K. Yamaguchi, Y. Ikeda, H. Fukui and T. Fueno IV-558
12a-104 Distillation control system synthesis by expert systemsK. Niida, I. Koshijima and T. Umeda 1V-562
12a-105 A knowledge-based consultation system for designing distillation processS. Ohe IV-566
12a-106 Expert system based fault diagnosis in fluidized catalytic crackingprocesses
D. Q. Qian and Y. Z. Lu IV-570
12a-107 A consultant system for the operation at the emergency of thechemical plant
H. Matsuyama, H. Kayano and K. Tano IV-574
12a-108 The development of an engineering information management system(EIMS) for CAD/CAE software integration
P. E. Preece and M. Benayoune 1V-578
12b. Computer Aided Design
Chairmen: G. V. Reklaitis (Purdue University)T. Umeda (Chiyoda Chemical Engineering &Construction Co., Ltd.)
12b-151 A new strategy of net decomposition in process simulationL. Zhou, Z. Han and K. Yu IV-582
12b-152 Least squares updates for quasi-Newton methods in process designand simulation
J. Lee and W. K. Lee IV-586
12b-153 Experience with advanced computer methods in mechanical and processengineering
R. Liebe IV-590
12b-154 Synthesis of cascaded refrigeration systemsT. R. Colmenares and W. D. Seider IV-595
(78)
12b-155 A planning method for power plant capacity allocation with a viewpoint of rational energy utilization
Y. Shimizu IV-599
12b-156 An infeasible path hybrid method for sequential modular optimizationT. P. Kisala, H. I. Britt, J. F. Boston and L. B. Evans 1V-603
12c. Flexible Design and Control
Chairmen: H. Matsuyama (Kyushu University)M. Morari (California Institute of Technology)
12c-201 A design method for the optimal heat exchanger network with thefixed tolerance
Y. Kutsuwa, H. Nishitani and E. Kunugita 1V-607
12c-202 Computer aided analysis and design of chemical processes in thepresence of modeling uncertainty—A practical application to afluidized catalytic cracker
A. N. Palazoglu and T. Khambanonda IV-611
12c-203 A strategy for flexible process designC. McGreavy and L. Y. Han IV-615
!2c-204 A concept of the flexible process systemL. Badea IV-619
12c-205 Optimality and flexibility of distillation column designS. H. Wong and S. Y. Lee IV-622
12c-206 Development of batch process operating systemS. Tomita, H. Yuhki, M. Mohri, T. Sawa and E. O'Shima IV-626
12c-207 Flexible scheduling algorithm for the parallel processor problemS. Hasebe, I. Hashimoto and T. Takamatsu IV-630
12c-208 Computer aided multivariable control system design—A case study ofrobust control in absorption
D. Petkovski IV-634
12c-251 Linear and nonlinear inferential control of a catalytic fixed-bed reactorC Y. Chen IV-638
12d. Adaptive and Predictive Control
Chairmen: S. Matsubara (Nagoya University)S. Shioya (Kyoto University)
(79)
12d-252 Adaptive controllers of a batch polymerization reactorT. Takamatsu, S. Shioya, Y. Okada IV-641
12d-253 Simulation of an on-line frequency domain adaptive controllerP. A. Karpe and K. P. Madhavan IV-645
12d-254 Application of model reference adaptive system to chemical reactorcontrol
N. Katoh, T. Yoshida and K. Nakamichi IV-649
12d-255 Application of a model predictive control system to a multiproductdistillation unit
A. Brambilla IV-653
12d-256 Non-linear feed forward controlA. Naimpally, M. Fardghassemi, M. Santina,and R. Houshiarnejad IV-657
12d-257 pH control of industrial sewages by predictive control schemeP. Davalloo, M. H. Nehrir and R. Ghayour IV-660
12e. Process Modelling Technique and Dynamics
Chairmen: I. Hashimoto (Kyoto University)C. McGreavy (University of Leeds)
12e-101 The multiplicity domain in the control-parameter space of a CSTRM. Matsubara, N. Watanabe and K. Shimizu IV-664
12e-102 Singular value and partial coherency assessment of experimental datafor identification
T. Takamatsu, I. Hashimoto, M. O'Shima and N. Ueyama . . . .1V-668
12e-103 Sensitivity analysis of dynamic systems—Application to chemicalreaction models
D. M. Espie and S. Macchietto IV-672
12e-104 Distributed-parameter filtering and estimation with dynamicmeasurements and multiple time domains
W. F. Ramirez and W. S. Gaafar IV-676
12e-105 On modelling distributed parameter systems for estimation and controlC. McGreavy and A. Guidoum IV-680
12e-106 Simulation of systems with a chemical reaction on a supercomputerV. Hlavacek IV-684
12e-107 DIVA—A dynamic process flowsheet simulatorW. Marquardt, P. Holl, E. D. Gilles IV-687
(80)
12f. Multivariable Process Control
Chairmen: L. T. Fan (Kansas State University)T. J. McAvoy (University of Maryland)
12f-151 Control loop interaction relaxation strategy using steady process simula-tion for distillation column
W. T. Wu, S. H. Wong, J. S. Heh and M. Y. Lay 1V-691
12f-152 Design of interaction decouplers without process dynamic informationS. W. Yu IV-695
12f-153 Decoupling control insensitive to operating condition changes of adistillation column
Y. Hashimoto, Y. Togari, I. Hashimoto and T. Takamatsu . . . .IV-699
12f-154 Multivariable control of CSTR with uncertain parametersE. Nakanishi, J. Nishizawa and L. Tao IV-703
12f-155 Multivariable control strategies for a plasticating extruderB. Weinstein and W. K. Lee 1V-707
12f-156 Analysing composition control schemes for heat integrated distillationtowers using the relative disturbance gain
T. J. McAvoy and Y. Wang IV-711
12g. Design and Control of Batch Process
Chairmen: D. W. T. Rippin (Eidgenossische Technische Hochschule)J. Wang (Zhejiang University)
12g-301 Some practical aspects of optimal batch distillation operation andcontrol
J. Wang IV-715
12g-302 Optimal design of multicomponent batch distillation columnU. M. Diwekar and K. P. Madhavan IV-719
12g-303 Automatic control system for batch evaporation crystallizationV. Kurula, J. Kyottinen and M. Mattila IV-723
12h. pH Control
Chairmen: M. Imaeda (Tokushima University)W. A. Walker (Royal Melbourne Institute of Technology)
12h-301 Simulation of the dynamics of a waste neutralization unitM. C. Palancar, J. M. Aragon and P. Lardiez IV-727
(81)
12h-302 Nonlinear state feedback synthesis for pH controlR. Wright and C. Kravaris IV-731
12h-303 Design criteria for pH control systemsW. A. Walker and Y. Liu IV-735
12i. Controller Tuning
Chairmen: M. Imada (Tokushima University)W. A. Walker (Royal Melbourne Institute of Technology)
121-301 Optimal tuning of a practical PID controller for second order withdelay process
Y. C. Chao, H. S. Lin, Y. W. Guu and Y. H. Chang IV-739
12i-302 Self-tuning for digital PID control systemM. Imaeda, K. Hashimoto and R. K. Wood 1V-743
12i-303 A method of optimal tuning in the direct digital control systemY. Togari, Y. Hashimoto, K. Hibino, A. Yoneya, H. Goto IV-747
12j. Fundamental sof CAD
Chairmen: G. Luft (Technical University of Darmstadt)S. K. Stoyanov (Higher Institute of Chemical
Technology)
12J-301 Automatic generation of local adaptive approximations to equilibriumratios
S. M. Clark and G. V. Reklaitis IV-751
12J-302 Computer model for tubular high-pressure polyethylene reactors
B. Tilger and G. Luft IV-757
12k. Computer Aided Operation
Chairmen: N. Aoki (Tokyo Gas Co.)H. J. Lin (National Cheng Kung University)
12k-301 LPG vaporizer simulation studyN. Aoki, H. Hasegawa, H. Iwamoto and M. Sasaki IV-761
12k-302 Computer color mixing and formulation for coatings
F. H. J. Lin IV-765
121. Modelling and Simulation in Distillation & Other Mass Transfer Operations
Chairman: W. Tanthapanichakoon (Chulalongkorn University)
(82)
121-301 The simulation of three-phase flash and distillation processesT. M. Guo IV-769
121-302 Modeling of an existing oil refinery's topping columnW. Tanthapanichakoon and P. Chan-urai IV-773
121-303 Computation of multistage separation processes by transient-statemethod
S. Wasylkiewicz 1V-777
121-304 Integration of multiphase equations applied to drying of solids usingDPDES algorithm from IMSL
P. Legues and M. E. Young IV-781
12m. Modelling of Reaction Kinetics and Reactor
Chairmen: W. I. Patterson (McGill University)E. Ranzi (Politecnico di Mirano)
12m-301 Isothermal trickle-bed reactor modeling for reactions with a gas-phaselimitant reactant
E. C. Biscaia, Jr. and E. A. Cid IV-784
12m-302 Simulate and optimize the ethylene oxide plant
S. Wei and D. Pang IV-787
12n. Simulation and Control of Industrial Processes
Chairman: F. D. Otto (University of Alverta)
12n-301 Advanced control applications at aramco gas plantsV. Mahalec IV-791
12n-302 Process control developments in palm oil productionA. Shafii and Z. Muhamad IV-794
12n-303 Distributed computer control system of automotive windshieldmanufacturing process
H. Usui, S. Seki and K. Kitaya 1V-798
12n-304 Improved design of amine treating units by simulation using personalcomputers
R. A. Tomcej and F. D. Otto IV-802
12o. Computer Application for Energy Saving
Chairmen: M. Ishida (Tokyo Institute of Technology)W. D. Seider (University of Pennsylvania)
(83)
12o-301 Computer-aided process system synthesis by applying a graphicsimulator gschemer
M. Ishida and D. Zheng IV-806
12o-302 Energy conservation in an industrial processP. A. Loeken IV-810
12o-303 Simulation analysis conserves energy and resources in chemicalprocess plant design and operation
W. Huang IV-814
12o-304 Some improvements on the zone method for radiative heat transferB. L. Ning IV-8I8
12o-305 "Supertargeting", or the optimisation of heat exchanger networksprior to design
B. Linnhoff and S. Ahmad 1V-822
12o-306 Computer aided design of activated sludge process with minimumenergy requirement
T. Aratani, L. E. Higa and K. Miyanami IV-826
12o-307 Simple calculation method for multicomponent separationin staged cascades
