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Xstrata NiCu Smelter Metallurgical Modelling

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    Advanced Metallurgical Modellingof Ni-Cu Smelting at

    Xstrata Nickel Sudbury Smelter

    N. Tripathi, P. Coursoland P. MackeyXstrata Process SupportM. Kreuh and D. Tisdale

    Xstrata Nickel

    N. Tripathi, P. Coursoland P. MackeyXstrata Process Support

    andM. Kreuh and D. Tisdale

    Xstrata Nickel, Sudbury smelter

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    Xstrata Process Support

    Aerial view of Xstrata Process SupportFalconbridge, Ontario, Canada

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    Xstrata Process Support

    Business Objective

    An independent business providing high-endtechnical services to the metallurgical industryincluding:

    Providing strategic operational and technicalsupport to significantly impact the efficiency andgrowth of Xstrata

    Identifying, developing and transferringtechnology of high value to Xstrata businesses

    Providing high value services to external

    customers

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    Advanced Metallurgical Modellingof Ni-Cu Smelting at

    Xstrata Nickel Sudbury Smelter

    1. Introduction

    2.Brief review of smelter process with regardto model development

    3.Modelling approach

    4.Applications of the model

    5.Conclusions

    Outline of Presentation

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    Advanced Metallurgical Modelling

    of Ni-Cu Smelting at

    Xstrata Nickel Sudbury Smelter

    Aerial view of the Xstrata Nickel Sudbury smelterFalconbridge, Ontario, Canada

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    Introduction Xstrata Nickels Sudbury smelter is located at Falconbridge

    township some 15 km northeast of Sudbury, Ontario, Canada.

    The plant has been in operation since 1930. It has undergonea number of expansions and modifications since that time.The present plant consists of fluid bed roasters, an electricfurnace and converters, together with an acid plant.

    The plant typically processes 550,000 tonnes/year of nickel-

    copper concentrate material producing about 67,000tonnes/year nickel in the finished matte shipped to Norwayfor final refining.

    Currently the smelter is reviewing environmental performanceand capacity aspects and a new comprehensive process modelwas desirable.

    This paper discusses the development of this model.

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    Process Flowsheet: Schematic Diagram

    SCV SMC FV FV

    discard

    slag

    concentrate

    Fluid bed roasters

    matte matte

    Electric Furnace slag

    discardslag

    matte granulation

    Acid Plant

    Off-gas

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    Process Operations: Roaster

    One of the two, 6.1 mdiameter fluid bed

    roasters at the plant.

    The fluid bed roasterswere modeled using astandard heat and

    mass balance module.

    Controllers were usedto set the targetdegree of sulphur

    elimination.

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    Process Operations: Electric Furnace

    Interior of the single 45MW electric furnace sized

    10 m by 30 m

    Electric furnace smeltingrequires a large amount ofinput heat energy. Reliable

    modelling requires goodknowledge of slag andmatte properties. Amolecular approach wasadopted to model the

    liquid phases in thepresent work

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    Process Operations: Converter Aisle

    The present converteraisle includes fourvessels

    Experimental datawere incorporated into

    METSIM to allow forreliable modelling ofthe converteroperations

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    Process Operations: Acid Plant

    View of the acid plantused to treat roasteroff-gas

    The acid plant was notmodeled in the presentphase of the work

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    Advanced Metallurgical Modellingof Ni-Cu Smelting at

    Xstrata Nickel Sudbury Smelter

    Modelling approach

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    METSIM model - I

    Plant data

    Experimentaldata

    FACTSAGEdata

    Process modelon METSIM platform

    Validation with existing plant data Emphasis on reliability, accuracy and robustness

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    METSIM model - II1. To model the slag and matte phases, conventional

    molecular theory was applied:

    Adequately accounted for first nearest neighbor pairs

    With an careful selection of high temperature mineralsand/or pseudo-components using FACTSAGE, the heatbalance can be calculated with the required accuracy

    2. FeS, NiS, Cu2S, Ni, Fe and Co were chosen as the componentsconsidered to model the matte phase (the matte is partlymetallized)

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    METSIM model - III3. Thermodynamic data for a number of components in slag and

    matte were cross-checked between FACTSAGE and METSIM.Agreement was generally good

    4. For the slag phase, pseudo-components like Fe2SiO4, Mg2SiO4,

    MgSiO3, Ca2SiO4, CaSiO3 etc. were chosen

    5. Thermodynamic data were not available in METSIM for certainpseudo-components, hence data were taken from FACTSAGE

    6. Heat capacity of slag and matte phases were verified with

    FACTSAGE and experimental data to ensure reliable heatbalance

    7. The gas phase was assumed to follow ideal behavior

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    METSIM and FACTSAGE model development

    Inputs Feed data (feed rate, chemical and mineralogical data)

    Operating data, heat losses, etc.

    Experimentally determined data

    FACTSAGE output (liquidus)

    Outputs Process data (slag, matte and off-gas data)

    Consumables (coke, oxygen, power, natural gas) Emissions (CO2 and SO2)

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    Process Parameters

    Degree of sulphur elimination

    Slurry density

    Oxygen enrichment

    Calcine temperature

    METSIM model : Roasters

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    METSIM model : Electric Furnace

    Process Parameters

    Melt and freeboard temperatures Matte grade

    Slag and matte partitioncoefficients

    Coke behavior

    Sulfate decomposition in free

    board

    Magnetite level in slag

    (3 site reaction)

    Gas Solid

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    Process Parameters

    Temperature

    Magnetite level in slag

    Fe/SiO2 ratio

    Slag and matte partition coefficients

    Fe level in finish matte

    Degree of matte entrainment

    All unit operations are linked together for mass and heat flow

    METSIM model : Peirce-Smith converters

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    METSIM model: Example of dynamic

    data exchange

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    Advanced Metallurgical Modellingof Ni-Cu Smelting at

    Xstrata Nickel Sudbury Smelter

    Applications of the model

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    Applications of the model

    The model has been used extensively atthe Xstrata Nickel smelter for:

    Scenario planning (shut down/maintenance, equipmentavailability, dealing with feed changes, removing oradding new vessels.)

    Environmental aspects (CO2 and SO2 emissions)

    Alternative operating options(technical and economic feasibility studies)

    Helping to identify potential options for piloting

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    XPS Modelling expertiseMetallurgical modelingIn addition to the case study discussed here (Nickel smelter), XPSis/has been involved in advanced metallurgical modeling work in

    a number of different projects:

    Nickel and PGM smelting (Africa) Copper smelting (Canada and Chile) Ferronickel smelting (world-wide)

    Techno-Economic modelingBy linking Metsim (and FACTSAGE) with economic data, forexample, an Excel sheet/file, a powerful techno-economic toolbecomes possible.

    XPS is currently building such models for the Xstrata smelters andExternal smelters.

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    Conclusions

    An accurate, reliable and robust process model of the XstrataNickel smelter was built and used for exploring differentoperating scenarios

    The approach of incorporating FACTSAGE information, whenrequired, into METSIM makes it a very powerful modeling toolreflecting overall operations

    XPS is ready to assist you with modeling work

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    Acknowledgements

    Thanks are given toXstrata Nickel and XPS

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    Thank you for your kind attention

    Any questions


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