XXXX AB Incinerator Model XXX 2016 CAT-XXXX...Overall Aim of the Monitoring Campaign Special...

ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland

Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL

Stack Emissions Testing Report Commissioned by

XXX 2016

Job Reference NumberCAT-XXXX

Installation Name & Address

Report Written byXXX

XX XX 2016Report Date

TE1 TE2 TE3 TE4

Stack Reference

PPC Permit: None

Signature of Report Approver

Version 1

MM XX XXXMCERTS Level 2

Team Leader

Team Leader

TE1 TE2 TE3 TE4MM XX XXX

MCERTS Level 2

XXXReport Approved by

Dates of the Monitoring Campaign

Version

Exova Catalyst, Unit C6, Emery Court, The Embankment Business Park, Heaton Mersey, Stockport, SK4 3GLT: 0800 328 1821 (or + 44 161 432 3286 from overseas)

E: [email protected] Exova Catalyst Contact: Toby Campbell (07825 130 074)

XXXXXXXX

Company XXXX

XXXXCannock

XXXX

Company XXXX

XXXX AB Incinerator Model

CAT-RT (Version BJ)Incinerator report

TITLE PAGE

CONTENTS

EXECUTIVE SUMMARY

Monitoring Objectives

Monitoring Results

Monitoring Dates & Times

Process Details

Monitoring & Analytical Methods

Summary of Method Deviations

Sampling Location

Plant Photos / Sample Points

APPENDIX 1 - Monitoring Personnel & List of Equipment

APPENDIX 2 - Raw Data, Sampling Equations & Charts

4

7

7

CONTENTS

2

9

3

5

6

8

Opinions and interpretations expressed herein are outside the scope of Exova Catalyst's ISO 17025 accreditation.

This test report shall not be reproduced, except in full, without the written approval of Exova Catalyst.

CAT-RT (Version BJ)Page 2 of 106

Company XXXX


Job Number: CAT-XXXX, Version 1Sample Date/s: XXX 2016

PPC Permit: None

Overall Aim of the Monitoring Campaign

Special Requirements

Target Parameters

Company XXXX, XXXX AB Incinerator Model

XXX 2016

(Page 1 of 7)

Exova Catalyst were commissioned by Company XXXX to carry out stack emissions testing on the XXXX AB Incinerator Model at .

The aim of the monitoring campaign was to perform testing, as requested by the customer, for a number of prescribed pollutants..

There were no special requirements.

Total Particulate Matter, Hydrogen Chloride, Mercury, Nickel, Arsenic, Cadmium, Copper, Chromium, Manganese, Lead, Dioxins & Furans, Sulphur Dioxide, Hydrogen Fluoride, Total VOCs (as Carbon), Oxides of Nitrogen (as NO₂), Carbon Monoxide

MONITORING OBJECTIVES

Executive Summary


Company XXXX



PPC Permit: None

where MU = Measurement Uncertainty associated with the Result

Parameter

Total Particulate Matter ¹

Hydrogen Chloride ¹ - -

Mercury ¹ - -

Nickel ¹ - -

Arsenic ¹ - -

Cadmium ¹ - -

Copper ¹ - -

Chromium ¹ - -

Manganese ¹ - -

Lead ¹ - -

Dioxins & Furans (NATO I-TEQ) Dioxins & Furans ¹

Dioxins & Furans (WHO TEQ Humans / Mammals) ¹

Dioxins & Furans (WHO TEQ Fish) ¹

Dioxins & Furans (WHO TEQ Birds) ¹

Dioxins & Furans (NATO I-TEQ) ¹

Dioxins & Furans (WHO TEQ Humans / Mammals) ¹

Dioxins & Furans (WHO TEQ Fish) ¹

Dioxins & Furans (WHO TEQ Birds) ¹

Sulphur Dioxide ¹ - -

Hydrogen Fluoride ¹ - -

Total VOCs (as Carbon) ¹ - -

Oxides of Nitrogen (as NO₂) ¹ - -

Carbon Monoxide ¹ - -

Oxygen Dry

Water Vapour

Stack Gas Temperature

Stack Gas Velocity

¹

- -NOTE: VOLUMETRIC FLOW RATE DATA TAKEN FROM AN AVERAGE OF ALL OF THE ISOKINETIC RUNS.

¹ Reference Conditions (REF) are: 273K, 101.3kPa, dry gas.

5

1.4 100

0.38

(Page 2 of 7)

-mg/m³

°C

Volumetric Flow Rate (ACTUAL)

-

0.02 0.004

0.002 0.0002

mg/m³

ng/m³

174

10.3

63.9

% v/v

m/s

0.30

947

1.9g/hr

mg/m³ 0.28

0.81

2297

m³/hrVolumetric Flow Rate (REF)

0.71

6.6

7.4 350

0.19

m³/hr

0.56

g/hr

mg/m³ 3.8

% v/v

5.9

489

0.42


µg/hr

0.005

0.04

µg/hr

0.001

mg/m³

mg/m³

mg/m³

g/hr

0.002

5

g/hr

-

-

-

g/hr 0.0008 0.0001 -

Dioxins & Furans Upper Limit (worst case where <LOD = LOD)

Dioxins & Furans Lower Limit (best case where <LOD = 0)

0.01 0.002

ng/m³

5.0

0.001

µg/hr

Executive Summary

mg/m³

-

0.006 0.001

Mass Emission

-

100.25

- µg/hr

-

MONITORING RESULTS

0.04 30 0.26

mg/m³

µg/hr

-

1

0.18

Result Limit

0.01

0.53

µg/hr

-

500

mg/m³

MU

ng/m³

ng/m³

ng/m³

0.002

0.02

2.4

0.002

0.01

0.35 g/hr

0.007 0.001 -

mg/m³

µg/hr

mg/m³ 0.008 0.0014

µg/hr

Company XXXX,

XXX 2016

g/hr 0.120.36

+/-

0.002

0.01

Units Result

0.002

Concentration

-

0.01 0.001

0.002

-

MU

0.01

0.0001

0.01

0.01

0.01

0.0006

mg/m³

0.0007

g/hr

g/hr

0.10

0.0003

Limit

+/-

0.0001

0.003

0.0003

-

0.0007

Units

0.005 0.001 -

0.006 0.001

g/hr

mg/m³

0.0001

300

-

-

-

ng/m³

0.01

0.0006

0.0002

ng/m³

0.36

0.004

0.20

0.0002 0.20

0.002

-

-

0.02

0.0001 5

0.0006

-

0.01

ng/m³ 0.001 -0.01

-

-

0.002

g/hr 0.0004 0.0001 -

-

0.002

-

0.0001 1 g/hr

g/hr0.001

20 g/hr

85.0 11.7

-

mg/m³ 0.02 0.003 5 g/hr 0.01 0.002 -


Company XXXX



PPC Permit: None

Parameter

R1 - -

R1 - -

R1 - -

R1 - -

R1 - -

R1 - -

R1 - -

R1 - -

R1 - -

R1 - -

(NATO) R1 - -

R1 - -

R1 - -

R1 - -

R1 - -

R1 - -

R1 -

R1

All results are expressed at the respective reference conditions.

24/07/2015

120

174

23/07/2015

12:34 - 14:34

12:34 - 14:340.19

120

0.0004 60

24/07/2015

24/07/2015

60

60

60

360

60

2.4

23/07/2015

23/07/2015

0.006Dioxins & Furans

Manganese

0.008Hydrogen Fluoride

mg/m³

0.02

g/hr

0.01

Sulphur Dioxide

g/hr

Oxides of Nitrogen (as NO₂)

Total VOCs (as Carbon)

mg/m³ 3.8 g/hr

0.38

Oxygen

mg/m³ 23/07/2015

23/07/2015

1.9

mg/m³ 0.0007 11:55 - 12:55

11:55 - 12:55

23/07/2015

08:43 - 14:43

g/hr

0.005

60

60

g/hr

09:40 - 10:40

10:44 - 11:44

mg/m³

Carbon Monoxide

120

mg/m³

0.002 11:55 - 12:55

mg/m³

mg/m³ 11:55 - 12:55

0.0003

g/hr

0.26

g/hrMercury 0.0007

0.0003

0.0008

0.007

0.0006

ng/m³

0.002

60

60

60

mg/m³

23/07/2015

23/07/2015

12:34 - 14:34

120

0.0006

mins

12:34 - 14:34

23/07/2015

mg/m³

10.3

0.003

23/07/2015

mg/m³

11:55 - 12:55

11:55 - 12:5523/07/2015

mg/m³

0.18

Company XXXX,

60

Duration

0.53Hydrogen Chloride

Executive Summary

Sampling

Times

13:12 - 14:12Total Particulate Matter

Units

(Page 3 of 7)

0.36

MONITORING DATE(S) & TIMES

XXXX AB Incinerator ModelXXX 2016

Units Concentration

23/07/2015

Sampling

Velocity & Volumetric Flow Rate

g/hr 85.0

g/hr

% v/v

13:12 - 14:12

Date(s)

Mass Emission

g/hr

23/07/2015

Nickel

5.0

µg/hr

Chromium

Copper

Cadmium mg/m³

g/hr

g/hr

g/hr

g/hr

0.01

mg/m³

11:55 - 12:55

Arsenic

23/07/2015 11:00 - 11:05

Lead mg/m³ 0.02 g/hr 0.01 23/07/2015 11:55 - 12:55 60


Company XXXX



PPC Permit: None

Standard Operating Conditions

Normal Operation

Abatement System

Abatement System Running Status

Chamber Volume = 0.54m³

(Page 4 of 7)Executive Summary

PROCESS DETAILS

Parameter

Capacity (of 100%) and Tonnes / Hour

Continuous or Batch Process

Waste Wood Grade A, B & C

XXXX AB Incinerator ModelXXX 2016

Operational

Continuous

Feedstock (if applicable) Waste Wood Grade A, B & C

Fuel

Plume Appearance

Control Processing Unit consisting of filter and lime injection

Visible Heat Haze

Value

Process Status

Company XXXX,


Company XXXX



PPC Permit: None

CAT

No

Mercury

Executive Summary

Testing

N/A

CAT-AP-01

CAT-TP-03

CAT-AP-01

RPS

MONITORING & ANALYTICAL METHODS

Velocity & Vol. Flow Rate

Deviation

(with short name reference as appears in the table above)

Exova Catalyst (CAT)

Scientific Analysis Laboratories Ltd (SAL)

RPS Laboratories Ltd (RPS)

ANALYSIS LABORATORIES

1 At the request of the customer no blank tests were performed.

Run

SUMMARY OF SAMPLING DEVIATIONS

Parameter

No

RPS

Company XXXX,

XXX 2016

N/A

CAT

Dry Zirconia Cell by Horiba PG-250CAT


Oxygen

Yes

EN 14789 CAT-TP-21 Yes

EN 16911-1 (MID) CAT-TP-41

Yes

EN 14792

Yes

0.001 mg/m³

IC

Yes

EN 14385

M31 ICP-MS

CAT-TP-21

CAT-TP-06

No RPS

MID 13211

CAT

N/A Yes RPS

No

EN 13284-1

No

CAT

No

Yes

Gravimetric

MCERTS17025

Testing

0.13 mg/m³

Hydrogen Chloride0.0003 mg/m³

EN 14385

ICP-MS

ICP-MS

0.0003 mg/m³No

Sulphur Dioxide EN 14791 CAT-TP-09

(Page 5 of 7)

GC-HRMS

Testing

Total Particulate Matter

Analysis

Dioxins & Furans

Arsenic

Hydrogen Fluoride

0.001 mg/m³

0.03 mg/m³

ProcedureAnalytical

TechniqueAnalytical

CAT-AP-01

M112

(Average)

N/A

ISO

Copper

EN 14385 CAT-TP-06 No N/A

0.002 ng/m³

Yes

CAT-TP-11BS EN 1911

Yes SAL No

IC

ProcedureLOD

Yes

EN 14385 CAT-TP-06 No

Cadmium

CAT-TP-01 Yes

Lab

Flame Ionisation Detection by Sick 3006 FID

CAT-TP-06


Standard

EN 1948

Lab

Yes No

No

No

CAT-TP-06 No

Technical ISO

Yes

Parameter

Lead EN 14385 CAT-TP-06 No 0.001 mg/m³

0.001 mg/m³

RPS

N/A M31 ICP-MS Yes RPS No

CAT-TP-07

Nickel

No

EN 14385

No

No N/A

Manganese EN 14385 No 0.0005 mg/m³

M31 ICP-MS Yes RPS

0.02 mg/m³

Yes

CAT-TP-06

ICP-MSN/A Yes

No N/A M31 ICP-MS

CAT-TP-06

Yes SAL

Chromium

Monitoring

CAT

Analysis

0.32 mg/m³CAT-TP-20

CAT Yes

CV-AFS

Water Vapour

N/A No 0.001 mg/m³


Total Particulate Matter, Hydrogen Chloride, Mercury, Nickel, Arsenic, Cadmium, Copper, Chromium, Manganese, Lead,Dioxins & Furans, Sulphur Dioxide, Hydrogen Fluoride

NDIR by Horiba PG-2500.10 %

0.74 mg/m³

Yes 1.2 m/s

ISO 17025 Accreditation Number: 4279



Carbon Monoxide

CAT Pitot Tube and Thermocouple

Yes

Yes

CAT

GravimetricCAT-TP-05

Yes

Yes

EN 15058

0.41 mg/m³

CAT

YesEN 12619:2013

Yes

Chemiluminescence by Horiba PG-250

CAT-TP-05 YesEN 14790

No

ISO 15713 CAT-TP-10 No

RPS

N/A

YesCAT

SOP 1C

M31

M31

M31

0.03 mg/m³SAL

17025 Analysis

IC

CAT-TP-21

0.10 % v/v


Company XXXX



PPC Permit: None

Duct Characteristics Location of Sampling Platform

Platform Details

Sampling Location / Platform Improvement Recommendations

EN 15259 Homogeneity Test Requirements

Sampling Plane Validation Criteria (from EN 15259

4" BSP

-

Lowest Differential Pressure

Value

-

-

0.00

-

Highest Gas Velocity

Area

Yes

0.00 0.00

-

2

0.00Ratio of Above : 1 Yes

< 15°

< 3 : 1

No Local Negative Flow

Platform has vertical base boards (approx. 0.25m high)

> 5 Pa Yes

-

Yes

No

m

Lowest Gas Velocity

m/s

Yes

-

6.41

-

-

Required

-

0.10

-

-

Orientation of Duct

EA Technical Guidance Note M1 / EN 15259 Platform Requirements

Pa

-

-

-

Yes

Traverse 1

m/s

Easy Access Available

-

Platform has chains / self closing gates at top of ladders

-6.41

Value

Depth

6.41

Vertical

Yes

Parameter

There are no obstructions present which hamper insertion of sampling equipment

-

All platforms should be designed in accordance with the requirements in the Environment Agency's Technical Guidance Note M1 and EN 15259.

Sample Port Size

There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.

8.6

Circular

Value

Safe Access Available

-

-

- -

Port Depth

(Page 6 of 7)

1.00

°

-

--

-

-

m²

m

Permanent / Temporary Platform

Inside / Outside

Width

Compliant

Yes

14

Units

Yes

SUITABILITY OF SAMPLING LOCATION

General Platform Information

Units

-

Temporary

-

Mean Velocity

Outside

-

-

-

-

--m/s

Maximum Angle of Swirl

Executive Summary

cm

Yes

-

-

Sufficient working area to manipulate probe and operate the measuring instruments

Criteria in EN 15259

-

Type

-

0.35

Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)

Yes

-


Company XXXX



PPC Permit: None

Photo 2

Photo 3

SAMPLE POINTS

Executive Summary

PLANT PHOTOS

(Page 7 of 7)

Photo 1

Line A

Line B where = isokinetic point sampled at

= isokinetic point not sampled at

= combustion gases sample point

A1

= non-isokinetic sample point


Company XXXX



PPC Permit: None

APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used

APPENDIX 2 - Summaries, Calculations, Raw Data and Charts

APPENDICES

APPENDIX CONTENTS


Company XXXX



PPC Permit: None

-

CAT 3.84Equipment Type

CAT 4.454

Manganese

Nickel

Arsenic

Miscellaneous Items

CAT 7.12Equipment I.D.

CAT 9.7

Position

Equipment I.D.Digital Manometer (1)Horiba PG-250

Oven Box (2)

Copper

-

CAT 14.53

Name

CAT-TP-10

CAT-TP-09

CAT-TP-07

CAT-TP-06

CAT-TP-06

CAT-TP-06

CAT-TP-06

CAT-TP-06

CAT-TP-06

CAT-TP-06

CAT-TP-11

CAT-TP-20

CAT-TP-05

EN 12619:2013

BS EN 1911

CAT 23.13

Instrumental Analysers

EN 14792

-Laboratory Balance CAT 1.18 / 1.18aTape Measure CAT 16.42

Stack Thermocouple (3)Stack Thermocouple (2)

--

CAT 12.34

CAT 3.31-

Equipment I.D.

STACK EMISSIONS MONITORING PERSONNEL

APPENDIX 1

-

JCT JCC P1 Cooler

CAT 13.32

Equipment Type

Technical Endorsements

Team Leader XXXX MCERTS Level 2

Extractive Sampling

LIST OF EQUIPMENT

MCERTS Accreditation

Stopwatch

CAT 4.185

-

Umbilical (2) Servomex 5200MPOven Box (1)

--

EN 14791

Mass View (2)

CAT 12.93

-

EN 14385

EN 14385

EN 14385

EN 14385

Sulphur Dioxide

EN 14790

Oxygen

ISO 15713

EN 16911-1 (MID) CAT-TP-41

Mass Flow Controller (2) CAT 6.20Mass View (1) CAT 25.24

20m Heated Line (2)

EN 15058

Parameter

Total Particulate Matter

Chromium

CAT-TP-21

EN 14385

EN 1948

Single Channel Heater Controller

S-Pitot (2) --

15m Heated Line (1)

CAT 17.22L-Pitot

-

Barometer

Digital Manometer (2)

Umbilical (1)Box Thermocouples (2)Box Thermocouples (1)

CAT 11.22Easylogger EN-EL-12 Bit CAT 11.23

Dual Channel Heater Controller -1Kg Check Weight CAT 17.22Last Impinger Arm CAT 4.179 / 4.180Callipers

- 20m Heated Line (1)-

METHODS & TECHNICAL PROCEDURES USED

Tubes Kit Thermocouple -

Carbon Monoxide

Bernath 3006 FID CAT 8.12

EN 14789

Water Vapour

CAT-TP-21

CAT-TP-21



- 1m Heated Line (2)

Mass Flow Controller (1)Heated Probe (3) -

CAT 6.19

-

S-Pitot (1)

Control Box DGM (2)

-ABB AO2020-URAS26

MM XX XXX TE1 TE2 TE3 TE4

Technician XXXX MCERTS Level 1 MM XX XXX TE1

EN 14385

Lead EN 14385 CAT-TP-06

Hydrogen Fluoride

MID 13211

Heated Probe (2)--

CAT 3.31

Gasmet DX4000

Horiba PG-250Digital Temperature MeterServomex 4900

-

5m Heated Line (1) CAT 20.33

500g Check Weight

M&C PSS

Hydrogen Chloride

1m Heated Line (3)

Control Box DGM (1)

CAT 3.84-

-

CAT 21S.43

Mercury

Stack Thermocouple (1)

Gasmet Sampling SystemCAT 5.35

MCERTS Number

Equipment Type

Easylogger EN-EL-12 Bit

Cadmium

Dioxins & Furans

1m Heated Line (1)

-

EN 13284-1

Technical ProcedureStandard

Heated Probe (1)

CAT-TP-01

Eco Physics CLD 822Mh

Velocity & Vol. Flow Rate

Bioaerosols Temperature Logger -Electronic Refrigerator -


Company XXXX



PPC Permit: None

General Stack Details

Stack Gas Composition & Molecular Weights

CO₂ (Estimated)

O₂

Moisture (H₂O)

Where: p = M / 22.41

pi = r x p

Calculation of Stack Gas Densities

Where: P STD = sum of component concentrations, kg/m³ (not including water vapour)

P STW = sum of all wet concentrations / 100 x density, kg/m³ (including water vapour)

P Actual = P STD x (TSTP / (PSTP)) x ((Pstatic + Pb) / Ta)

P ActualW (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)

Calculation of Stack Gas Volumetric Flowrate, Q

Gas Volumetric Flowrate (Actual)

-0.00

-

1.2498

44.01

456

Gas Volumetric Flowrate REF ¹

%

0.8037

Result

1.9635

-

-

0.1026

m³/hr

REF ¹

0.287

Dry Density (Actual), P Actual

m³/hr

kg/m³

Gas Volumetric Flowrate (STP, Wet)

Moisture

Conc

0.2160

Pa

11.00

975

101.2

% v/v

Units

0.00

kg/m³ 1.314

Duct gas flow conditions

485

2221

0.294

Wet Density (STP), P STW

-

1.4277 0.1465-

Units

Temperature

N₂

-

Units

Average Pitot Tube Calibration Coefficient, Cp

ppm kg/m³

Average Stack Gas Pressure

Conc

5.92

Conc

M

Wet

r% v/v

kg/m³

m³/hr

Total Pressure

Average Wet Density (Actual), P ActualW

5.92

78.74 0.9841

1.347

74.08

Dry Density (STP), P STD

18.02

Determinand

0.1100

456

kg/m³

kPa

0.0592

9.66

p pi

Mass

Component

m³/hr

Result

°C

kg/m³

0.7874 28.01

Fraction

Density

Dry

0.0476

10.26 32.00

Actual

10.35

Volume

8.6

Molar Conc

0.10Stack Area, A

APPENDIX 2

mStack Width, W

975

Average Barometric Pressure, Pb

m

Stack Details (from Traverse)

101.3

°C

Average Stack Static Pressure, Pstatic kPa

kPa

0.83

Value

0.35

101.2

Average Stack Gas Temperature, Ta

-0.03

m²

-

Units

PRELIMINARY STACK SURVEY: CALCULATIONS

Stack Diameter / Depth, D

Gas Volumetric Flowrate (from Traverse)

Gas Volumetric Flowrate (STP, Dry)


Company XXXX



PPC Permit: None

Parameter Parameter

Date of Survey Initial Pitot Leak CheckTime of Survey Final Pitot Leak CheckAtmospheric Pressure Orientation of DuctAverage Stack Static Pressure Pitot Tube, Cp

Result of Pitot Stagnation Test Number of Lines AvailableAre Water Droplets Present? Number of Lines UsedDevice Used

--

--

----

---------

-

---

-

-

- -

-975.0

-

-

--

- -

--

--

-

-

-

-

-

-

-

-

-

-

-

-

-

- -

-

-

-

-

-

- -

-

--

-

-

--

6.41

-

8.6 -Mean

-

- --

-- -

8.6

-- -

kg/m³Point -

-

975.02.0

0.287

m/sPa

0.287

m

0.181

--° -°C-25.0

Pass

-Swirl

Yes

kPa

-

-

-

-

Vertical

Pass

Traverse Depth

-

Velocity

Units

APPENDIX 2

6.41STATIC (Units: Pa)

Value

∆P --

-

101.2

Temp

--11:00 - 11:05

Sampling Line A

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID)

-

(1 of 1)

1

Pass

-

-

Wet Density

Pa

1

23/07/2015

Value

-

Units

-25 -

-

0.83

S-Type Pitot with KIMO MP 200 (500Pa)


Company XXXX



PPC Permit: None

Performance characteristics (Uncertainty Components) UnitsValueUncertainty

0.00053-

Standard Uncertainty on the coefficient of the Pitot TubeStandard Uncertainty associated with the mean local dynamic pressures- Resolution- Calibration

Standard uncertainty associated with the mean velocity (95% Confidence)Standard uncertainty associated with the mean velocity (95% Confidence), relativeStandard uncertainty associated with the volume flow rate (95% Confidence) Uc(qV,w)

0.00445- 21929

u(k) 0.005u(∆pi)

u(vi) 0.401u(v) 0.401

Uc(v) 0.786Uc,rel(v) 12.26

- Drift- Lack of Fit

u(φH₂O) 0.302u(φO₂,w) 0.297

K

- Overall corrections to dynamic measurementsStandard uncertainty associated with the molar mass of the gas- φO₂,w- φCO₂,w- Oxygen, dry- Carbon Dioxide, dry- Water Vapour- Oxygen, wet

--

-

- Carbon Dioxide, wetStandard uncertainty associated with the stack temperatureStandard uncertainty associated with the absolute pressure in the duct- Atmospheric Pressure- Static PressureStandard uncertainty associated with the density in the ductStandard uncertainty associated with the local velocitiesStandard uncertainty associated with the mean velocity

u(pc) 175.695 Pau(patm) 175.692u(pstat) 1.045

u(ρ) 0.00155

- 148.1Uc,rel(qV,w) 13.07

%

%

-Pa

m/sm/s

- u(qV,w)Standard uncertainty associated with the volume flow rate (95% Confidence), relative

u(φCO₂,d) 0.337

u(cal) 0.008u(drift) 0.083u(fit) 0.001u(Cf)

Pau(res) 0.00087

1.045

0.093u(M) 0.00006

u(Tc) 6.367

APPENDIX 2

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID) - MEASUREMENT UNCERTAINTY(1 of 1)

290.2 m³/hr

- u²(qV,w)

9.657- 10.349

u(φO₂,d) 0.314

u(φCO₂,w) 0.319

- u²(a)/a²- u²(qV,w)/q²V,w

-


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

General Sampling Information

FORMAT: Number Used / Number Required


Reference Conditions

Reference Conditions are: 273K, 101.3kPa, dry gas.

Number of Sampling Lines Used 1 / 1

Number of Sampling Points Used 1 / 1

g/hr 0.18

Uncertainty ±mg/m³ 0.25 0.25

Units

0.36

0.32 0.32

0.12

±% v/vUncertainty

Filter Size and Material

Out Stack

Mass Emission

Technical Procedure CAT-TP-01

Standard

47mm Glass Fibre

Parameter

EN 13284-1

Sample Point I.D.'s

5.82

Titanium

Filter Housing Material Titanium

Probe Material

Water Vapour

Parameter Units

5.82% v/v

Value

Positioning of Filter

Run 1

A1

TOTAL PARTICULATE MATTER: RESULTS SUMMARY

Mean

0.12

APPENDIX 2

0.18

mg/m³ 0.36

Run 1

Concentration

Uncertainty ±g/hr

Company XXXX,

Mean


Parameter


Company XXXX



PPC Permit: None

Absolute pressure of stack gas, Ps

Volume of water vapour collected, Vwstd

Volume of gas metered dry, Vmstd

Moisture content, Bwo & Rwv

Bwo as a percentageReported Water Vapour, checked with Tables in EN 14790, RwvVolume of gas metered wet, Vmstw

Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂

Molecular weight of dry gas stream, Md

CO₂ (Estimated)

O₂

Molecular weight of stack gas (wet), Ms

Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)

Percent isokinetic, %I

Velocity pressure coefficient, Cp

m³/min N/A

% v/v

1.0314

Nozzle area, An

N/AQstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd)

mmH₂O

0.0638

Volume of gas sample through gas meter, Vm m³Gas meter correction factor, Yd

45.3

Vmstw = (Vmstd)(100/(100 - Rwv))

APPENDIX 2

% v/v

Average dry gas meter temperature, Tm °C 27.1

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³

TOTAL PARTICULATE MATTER: ISOKINETIC SAMPLING CALCULATIONS

Test Units

Total mass collected in impingers (silica trap)

% v/v 5.82

m³

Vwstd = (0.001246)(Vlc)

-2.5

51.2g

m³

mmH₂O

5.9

Barometric pressure, Pb

g

Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³ N/A

Total mass of liquid collected, Vlc g

m³/min

Total mass collected in impingers (liquid trap)

5.82

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

% v/v

1.0952

1.2260

% v/v

-

Nozzle diameter, Dn

0.83

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)

0.9230

Run 1

-

Stack static pressure, Pstatic

%

933.2

0.900.95

81.00

% oxygen reference condition, REF%O₂ % v/v N/A% dry oxygen measured in gas stream, ACT%O₂d

O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)

106.1

m/s

-

Average stack gas temperature, Ts

m³/min

Average of velocity heads, ∆Pavg mmH₂O

Total sampling time, q

0.10

m³

0.3592

Area of stack, As m²

Average square root of velocity heads, √∆P

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)

%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))

% v/v 19.00

mm

m³/min

Bwo = Vwstd / (Vmstd + Vwstd) 0.0582

197.67

% wet oxygen measured in gas stream, ACT%O₂w

35.1

758.8Ps = (Pb + (Pstatic / 13.6) mmHg

759.0mmHg

min 60

% v/v

°C

Total

8.4Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min 7.9

29.96

mm²

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)Conversion factor (K/mm.Hg), Cf

9.00

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) 6.42

N₂

- N/A

Average pressure drop across orifice, ∆H

-

15.86

N/A

Qa = (60)(As)(Vs)

√mmH₂O

Vmstd@X%oxygen = (Vmstd) / (O₂REFd)

Velocity of stack gas, Vs

N/A

N/A

-

m³

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

N/A

34.97

Yes

Pitot tube velocity constant, Kp

-

g/gmol 29.26

10.00

37.1

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)

% v/vg/gmol


Company XXXX



PPC Permit: None

Sample Runs

Filter I.D. Number

Probe Rinse I.D. Number

Where: ISO stands for Manual Isokinetic Sampling Train

Volume Sampled (REF) m³

mg

g 3.04284

0.37

Start Filter Mass

Total Mass in Probe Rinse

13:12 - 14:12

Sampling Dates

g

-

End Probe Rinse Mass

g

0.14076

0.14024

Total Mass Collected

End Filter Mass

-

Parameter

g

TOTAL PARTICULATE MATTER: SAMPLING DETAILS

mg/m³

0.13

-0.00052

-

Balance Uncertainty / LOD

Calculated Concentration

g

g

Sampling Times

APPENDIX 2

-

Units

mg/m³

-

23/07/2015

Total Mass on Filter

47-27619

Start Probe Rinse Mass

0.00089

Sampling Device

PR-47-27619

Run 1

0.36

1.0314

ISO

3.04373


Company XXXX



PPC Permit: None

Sample Runs

Run 1

MU (Concurrent Water Vapour)

Leak Test Acceptable -

Less than 50% Faded

Units

Run 1

Units Run 1

APPENDIX 2

°C

mg/m³ 0.50

Water Droplets

%

Ambient Temperature Recorded? -

-

Units Run 1

Test Conditions Units

Allowable Weighing Uncertainty

95 - 115

180

Run 1

Overall Weighing Uncertainty ± mg

20

°C

Yes

0.23

%MU Acceptable

Run 1

Leak Test Results

Yes

Pre-Sampling Leak Rate l/min 0.10

Isokinetic Variation

Yes%

106.1

Isokinetic Criterion Compliance

Isokineticity Acceptable - Yes

Weighing Uncertainty Acceptable

TOTAL PARTICULATE MATTER: QUALITY ASSURANCE

160

No

%

Units

Filter Temperatures

Allowable Leak Rate

l/min 0.18

Allowable MU

(PAGE 1 OF 2)

Yes

-

Silica Gel (Concurrent Water Vapour) Units

Maximum Filter Temperature

Run 1

Post-Sampling Leak Rate

Are Water Droplets Present

l/min

Post-Conditioning Temperature

5.5

0.38

Units

Measurement Uncertainty (MU)

Allowable Isokinetic Range %

%

Units Run 1

Mean Sampling Rate l/min 18.9

0.24

± mg/m³

Weighing Uncertainty Criteria

160

Yes

Overall Weighing Uncertainty

Pre-Conditioning Temperature °C

ELV [Daily ELV for IED] mg/m³ 10


Company XXXX



PPC Permit: None

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

Run Number(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)

(PAGE 2 OF 2)

At the request of the customer no blank tests were performed.

Nature of Deviation

APPENDIX 2

TOTAL PARTICULATE MATTER: QUALITY ASSURANCE


Company XXXX



PPC Permit: None

Sampled Volume (Actual)

Sampled Gas Temperature

Sampled Gas Pressure

Sampled Gas Humidity

Leak

Mass of Particulate

Uncollected Mass





Leak

Mass of Particulate

Uncollected Mass

Sampled Volume (STP)

Leak

Mass of Particulate

Uncollected Mass


Leak

Mass of Particulate

Uncollected Mass

O₂ Correction Factor

Stack Gas O₂ Content

MU for O₂ Correction

Combined uncertainty

Expanded uncertainty (95% confidence), without Oxygen Correction

Expanded uncertainty (95% confidence), with Oxygen Correction

Expanded uncertainty (95% confidence), estimated with Method Deviations

Reported Uncertainty





ρm 101.2

≤2%

≤1%

0.13

1.03

0.25

300.1

Units

Vm m³

uHm

0.02

% v/v

uρm

1.23

0.00

<5% of ELV

% 69.1

mg -

Uncertainty in Result

0.00

0.97

mg/m³ 0.25

Measured Quantities

0.00Hm

0.37

Symbol Run 1

%

uVm m³

≤1%

% 1.00

0.13

Measured Quantities

uUCM

Lr mg

mg

% 1.26

mg/m³

mg/m³ 0.00

%

N/A

%

Run 1

2.00

Symbol Units

69.1

Uncertainty as a Percentage

N/A

Parameter

mg/m³

-

Run 1 Requirement of Standard

1.00

UCM

%

Run 1Measured Quantities

- N/A

≤1%

mg/m³ 0.25

% 0.95

mg/m³

mg/m³ 0.01

-Overall MU For O₂ Measurement

mg/m³ N/A

≤2%

0.35

mg/m³

Symbol Units Run 1

% v/v N/A

L 0.95

APPENDIX 2

TOTAL PARTICULATE MATTER: MEASUREMENT UNCERTAINTY CALCULATIONS

Value Standard uncertainty

Measured Quantities

0.67

%

kPa

m

0.97

mg

Vm

-uL %

Tm uTm K 2.00

0.50

Units

0.00

-

0.49

mg/m³

0.13

0.00

% N/A

Units

Run 1

UCM

L

Run 1

%

Uncertainty in Measurement Units Sensitivity Coefficient

%

Units Run 1

1.00

69.1

0.37

Oxygen Correction Part of MU Budget

Measured Quantities

um


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -






APPENDIX 2

Yes


Titanium

0.32

Run 1

Parameter

Absorption Solution HPLC Grade Water

Mean


Sample Point I.D.'s A1

5.82

±% v/v

0.53

Impinger Material

Mass Emission

Uncertainty

0.04

Out Stack

Date of Sample Analysis 28/07/2015

Number of Sampling Lines Used

Run 1

5.82

Borosilicate Glass

CAT

Analytical Laboratory's Procedure

Filter Housing Material


CAT-AP-01

Uncertainty ±mg/m³

Probe Material

Name of Analytical Laboratory

47mm Glass FibreFilter Size and Material

Concentration mg/m³ 0.53

1 / 1

ISO 17025 Accredited Analysis?

Uncertainty

Mean

g/hr

Titanium

Parameter

Value

0.26

0.04

Water Vapour % v/v

Company XXXX,

0.32

Units

0.26

0.04

UnitsParameter


±g/hr

HYDROGEN CHLORIDE: RESULTS SUMMARY

BS EN 1911Standard

0.04


Company XXXX



PPC Permit: None








CO₂ (Estimated)

O₂




%


-

mm

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd)

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

m³/min

0.83

% v/v

60

-

m³ N/A

9.00

minTotal sampling time, q


% oxygen reference condition, REF%O₂

933.2

mm²

m³ 1.0314

0.90

-

% v/v

-2.5

5.9

Test Units

0.9230

% wet oxygen measured in gas stream, ACT%O₂w % v/v% dry oxygen measured in gas stream, ACT%O₂d

10.00

m³

Vwstd = (0.001246)(Vlc)

34.97

°C

mmHg

N/A



mmH₂O

Run 1

APPENDIX 2

g

% v/v N/A


Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)

Total mass collected in impingers (liquid trap)

mmH₂O

m³


Average dry gas meter temperature, Tm

% v/v

45.3

35.1

759.0

N₂ % v/v 81.00

-


19.00

Average pressure drop across orifice, ∆H27.1

m/s°C

Vmstw@X%oxygen = (Vmstw) / (O₂REFw)

758.8

0.0638

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

0.95

0.0582

29.26

N/A

mmHg

m³

m³

Yes

m³/min



N/A

g/gmol

-

15.86Nozzle diameter, Dn

N/A

m³

Ps = (Pb + (Pstatic / 13.6)


√mmH₂O

% v/v N/A

HYDROGEN CHLORIDE: ISOKINETIC SAMPLING CALCULATIONS

1.2260

Average of velocity heads, ∆Pavg

Bwo = Vwstd / (Vmstd + Vwstd)

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol 29.96


5.82

37.10.10

m³/min 8.4Conversion factor (K/mm.Hg), Cf

7.9m³/min N/A

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))

Qa = (60)(As)(Vs) m³/min

197.67

mmH₂O

Total mass of liquid collected, Vlc

1.0952

-

% v/v


5.82

Volume of gas sample through gas meter, Vm

51.2

Gas meter correction factor, Yd

Total% v/v

-




0.3592

106.1

N/A

g

6.42

Nozzle area, An

Total mass collected in impingers (silica trap) g


Company XXXX



PPC Permit: None

Sample Runs

-

-

-

-

-

-

-

-


Mass in Front Impingers 541.0

Volume in Back Impinger ml 121.0

m³ 1.0314

HYDROGEN CHLORIDE: SAMPLING DETAILS

Sampling Times

Sampling Dates

0.53

0.07

-

µg

Units

µg

Laboratory Result for Back Impinger

Parameter

1.96

Volume Sampled (REF)

-

Laboratory Result for Front Impingers


µg/ml

Mass in Back Impinger

ml

-

276.0

13:12 - 14:12

548.8

APPENDIX 2

µg 7.9

Volume in Front Impingers

µg/ml

ISO

23/07/2015

Sampling Device

mg/m³Calculated Concentration

Run 1


Company XXXX



PPC Permit: None

Sample Runs

0 7 0 7

Filter Temperatures

Units

No

Yes

Allowable Absorption Efficiency

% 98.6


N/A

Run 1

% Yes


Run 1

Absorption Efficiency

Run 1

l/min

Allowable MU

Run 1

%

Mean Sampling Rate l/min

5.5

-

0.38

APPENDIX 2

Units

Less than 50% Faded

Run 1

Water Droplets

-

Isokinetic Criterion Compliance Units

%

Yes

Run 1

Yes

Pre-Sampling Leak Rate


N/A

106.1

°C

Test Conditions

Units

18.9

% Yes


HYDROGEN CHLORIDE: QUALITY ASSURANCE(PAGE 1 OF 2)

Leak Test Results Units

%

Units

160

95 - 115

-

%

Units Run 1

l/min 0.10


Leak Test Acceptable -

Silica Gel (Concurrent Water Vapour)

Run 1

Allowable Isokinetic Range


Absorption Efficiency Acceptable

Allowable Leak Rate

Units

Post-Sampling Leak Rate l/min

20

%

0.18

MU Acceptable


Isokineticity Acceptable


Company XXXX



PPC Permit: None

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

APPENDIX 2



Nature of Deviation

HYDROGEN CHLORIDE: QUALITY ASSURANCE(PAGE 2 OF 2)


Company XXXX



PPC Permit: None





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













mg/m³

Sensitivity Coefficient

% 0.67

≤2%

0.00

Measured Quantities

-

uHm

mg/m³

0.04

Uncertainty in Measurement Units

0.00

Symbol Units

Run 1

%

kPa

2.50

mg/m³

mg/m³

1.00

Parameter Units Run 1

APPENDIX 2

%

Run 1

No Requirement

uTm K 2.00

Measured Quantities

0.00

Lr

m³


% 0.49

Hm

mg/m³

L

0.01

Units

≤1%

≤2%

300.1

m³1.23Vm

Measured Quantities

0.50

0.02

Run 1

≤1%

%

% 2.50

1.00

Symbol Units

% v/v

uρm

L 0.95

%

1.03

Run 1

2.00

%

Requirement of Standard

≤1%

%

Units

mg/m³ N/A

% N/A

%

7.3


0.04

0.04

mg/m³

7.3

7.3

Run 1

Tm

Symbol

HYDROGEN CHLORIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

uVm

mg/m³ 0.01

mg/m³

N/A

Lr

1.00

Measured Quantities

-uL

ρm 101.2

0.52

0.95

Vm

%uLr

mg/m³ 0.01

1.00


Run 1

0.02

-

% v/v N/A

% N/AOverall MU For O₂ Measurement

- N/A


Measured Quantities Units Run 1


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -






Absorption Solution Nitric Peroxide & Potassium Dichromate

Positioning of Filter Out Stack

Filter Size and Material 47mm Quartz Fibre

CAT-TP-06



Sample Point I.D.'s

Yes


Name of Analytical Laboratory RPS


Standard MID 13211

0.24

M112


4.47

Technical Procedure

Parameter

Probe Material Titanium


Impinger Material

0.24

Value

Borosilicate Glass

A1

0.0015

Uncertainty

Mean



Mass Emission

±mg/m³

0.0001

g/hr 0.0007 0.0007

APPENDIX 2

MERCURY: RESULTS SUMMARY

Company XXXX,


Water Vapour % v/v 4.47

Uncertainty ±% v/v

0.00020.0002

Uncertainty ±g/hr 0.0001

Parameter Units Run 1 Mean


Company XXXX



PPC Permit: None








CO₂ (Estimated)

O₂





N/A

0.83Pitot tube velocity constant, Kp -

g/gmol 29.16

Conversion factor (K/mm.Hg), Cf

%

m²

-Velocity pressure coefficient, Cp

Qa = (60)(As)(Vs)

mmH₂O

% v/v

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)8.0

33.9

m³/min 37.8-

4.47

Nozzle diameter, Dn

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A

% dry oxygen measured in gas stream, ACT%O₂d


% v/v

Total

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w) - N/A

Gas meter correction factor, Yd - 0.9230

0.9774

N/AQstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)

0.90


9.00


m³/min 8.4

g/gmol

mm 15.86

Total sampling time, q min 60Nozzle area, An mm² 197.67

√mmH₂O

758.8

m/s

34.97


m³

0.95

- N/A

N/A


- Yes

% v/v

N/A

5.00

6.56

28.66

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))

% v/v

% v/v 4.47

Vmstw = (Vmstd)(100/(100 - Rwv)) m³


Total mass collected in impingers (liquid trap) g 29.7Total mass collected in impingers (silica trap) g 7.0

mmHg

% wet oxygen measured in gas stream, ACT%O₂w % v/v N/A% v/v N/A

14.00

m³

1.0231

Ps = (Pb + (Pstatic / 13.6)Stack static pressure, Pstatic mmH₂O -2.5


g 36.7

mmH₂O

mmHg 759.0

MERCURY: ISOKINETIC SAMPLING CALCULATIONS

Test Units Run 1



m³/min


Bwo = Vwstd / (Vmstd + Vwstd) m³ 0.0447

m³/min

0.3592

Vwstd = (0.001246)(Vlc) m³ 0.0457

% v/v 86.00


Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

m³

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)

N₂


1.1520


Area of stack, As 0.10

APPENDIX 2

°C 959.7



% v/v

99.2


Company XXXX



PPC Permit: None

Sample Runs

<

-

Mass in Final Impinger -

-

-

-


Mass on Filter / in Rinse µg 0.03

-

1.38

APPENDIX 2

MERCURY: SAMPLING DETAILS

Parameter Units

Sampling Dates

µg

Sampling Times -


23/07/2015

µg 0.08

Mass in Front Impinger/s

Volume Sampled (REF) m³ 0.9774

1.48

11:55 - 12:55

µg

mg/m³ 0.0015

- ISO


mg/m³ 0.0015

Sampling Device

Reported Concentration

Run 1


Company XXXX



PPC Permit: None

Sample Runs

N/A

Run 1

Run 1

Mean Sampling Rate l/min


l/min

Concentration Acceptable

%


Units Run 1

Impingers Exit Temperature

5.4


% 99.2

°C 17

Allowable MU % 20


Maximum Temperature Recorded


Less than 50% Faded %

Maximum Filter Temperature °C 185

Units

Allowable Isokinetic Range % 95 - 115

°C 30


Filter Temperatures Units

Allowable Concentration µg/m³ 2.0

Yes

Run 1

Units Run 1

Yes

-

l/min 0.12

Run 1

Where the emissions are < 30% of the ELV, MID 14385 does not require the 95% absorption efficiency requirement to be applied

Run 1

Concentration in Final Impinger


0.08

UnitsWater Droplets

17.7

APPENDIX 2

-

Units

Concentration in Final Impinger


No

0.35

94.8

Absorption Efficiency Units Run 1

%


Allowable Leak Rate

MERCURY: QUALITY ASSURANCE(PAGE 1 OF 2)


N/A

MU Acceptable % Yes

µg/m³

Yes


Maximum Allowable Temperature


%

Units Run 1

Units Run 1


Test Conditions

Leak Test Acceptable

-

Exit Temperature Acceptable - Yes

Ambient Temperature Recorded? - Yes

-


Company XXXX



PPC Permit: None

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

Nature of Deviation Run Number(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)


APPENDIX 2

MERCURY: QUALITY ASSURANCE(PAGE 2 OF 2)


Company XXXX



PPC Permit: None





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













Standard uncertainty

0.02

≤1%

MERCURY: MEASUREMENT UNCERTAINTY CALCULATIONS

% -

Vm

uL % -


uVm m³

Run 1

Lr 6.00

%

1.15

Measured Quantities Symbol Symbol

uLr

Units Run 1


APPENDIX 2

%

0.0001

12.9

Measured Quantities Units

0.0002

%


12.9

%

1.00

mg/m³

Overall MU For O₂ Measurement % N/A

0.0001

mg/m³

0.0000

% v/v N/A

- N/A

101.2ρm

0.00Hm

0.68

mg/m³

2.00

Value

Lr

2.00

1.00

0.0001

1.00

0.0000

6.00

≤2%


Symbol

L

Run 1

%

Units

N/A

mg/m³

%

0.98

% N/A

297.6

≤2%

mg/m³ 0.0000

0.68

uHm

% 0.49

Measured Quantities

uTm KTm

12.9

mg/m³

m³ 0.00

Units Run 1

Run 1

0.0002

uρm kPa 0.50

≤1%

≤1%

%

mg/m³

Measured Quantities

% v/v

1.00

Run 1

mg/m³


Vm

%

L

mg/m³ 0.0002

No Requirement

0.67

mg/m³



- N/A


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -






Yes

Standard EN 14385


Out Stack


0.24Uncertainty


Analytical Laboratory's Procedure M31


0.005

APPENDIX 2

Impinger Material

Mass Emission g/hr 0.003

Borosilicate Glass

Absorption Solution Nitric Peroxide


4.47

Company XXXX,

NICKEL: RESULTS SUMMARY


Parameter

Parameter

0.001



±% v/v 0.24


A1



Sample Point I.D.'s

Uncertainty ±mg/m³ 0.001

Units Run 1 Mean


0.001

Value



0.003



Company XXXX



PPC Permit: None








CO₂ (Estimated)

O₂





N₂ % v/v 86.00

9.00

mmH₂OAverage dry gas meter temperature, Tm °C 24.6


Vwstd = (0.001246)(Vlc)

% wet oxygen measured in gas stream, ACT%O₂w % v/v

29.16

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol 28.66

7.0

% v/v

Test Units Run 1

g

m³

Barometric pressure, Pb mmHg

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w) - N/AO₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)

Total mass collected in impingers (silica trap)

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol

759.0

N/A

0.9774

Total % v/v 14.00

% oxygen reference condition, REF%O₂ % v/v N/A

Total mass collected in impingers (liquid trap) g 29.7

% dry oxygen measured in gas stream, ACT%O₂d % v/v N/A

Vmstd@X%oxygen = (Vmstd) / (O₂REFd) m³ N/A

% v/v 4.47


Ps = (Pb + (Pstatic / 13.6) mmHg 758.8Stack static pressure, Pstatic mmH₂O -2.5


m³ 0.0457



% v/v 5.00

1.0231

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction) - Yes

APPENDIX 2

NICKEL: ISOKINETIC SAMPLING CALCULATIONS

Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³ N/A

m³ 1.1520Gas meter correction factor, Yd - 0.9230

g 36.7

Pitot tube velocity constant, Kp - 34.97Velocity pressure coefficient, Cp - 0.83Average of velocity heads, ∆Pavg mmH₂O 0.90

- N/A

33.9

% v/v 4.47


Average square root of velocity heads, √∆P √mmH₂O 0.95Average stack gas temperature, Ts °C 959.7Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s 6.56

Area of stack, As m² 0.10Qa = (60)(As)(Vs) m³/min 37.8Conversion factor (K/mm.Hg), Cf - 0.3592Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273) m³/min 8.4Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min 8.0QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min N/AQstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A

Nozzle diameter, Dn mm 15.86Nozzle area, An mm² 197.67Total sampling time, q min 60%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100)) % 99.2


Company XXXX



PPC Permit: None

Sample Runs

-

-

Mass in Back Impinger -

-

-

-


APPENDIX 2

NICKEL: SAMPLING DETAILS


Total Mass Collected µg 5.25

Mass in Front Impingers µg 0.23

µg 0.02

Sampling Times - 11:55 - 12:55

Sampling Dates - 23/07/2015

Sampling Device - ISO



Calculated Concentration mg/m³ 0.0054

Reported Concentration mg/m³ 0.0054


Company XXXX



PPC Permit: None

Sample Runs

Detection Limit Acceptable

Allowable Detection Limit

- Yes

µg/m³ 5.0

APPENDIX 2

NICKEL: QUALITY ASSURANCE(PAGE 1 OF 2)

Leak Test Results Units Run 1



Post-Sampling Leak Rate l/min 0.12

Allowable Leak Rate l/min 0.35

Absorption Efficiency Acceptable - N/A

Detection Limit Units Run 1Where the emissions are < 30% of the ELV, MID 14385 does not require the 90% absorption efficiency requirement to be applied

Detection Limit µg/m³ 0.58

Leak Test Acceptable - Yes


Absorption Efficiency % 99.6

Allowable Absorption Efficiency % N/A

Water Droplets Units Run 1

Are Water Droplets Present - No

MU (Concurrent Water Vapour) Units Run 1

Measurement Uncertainty (MU) % 5.4

Allowable MU % 20

MU Acceptable % Yes

Silica Gel (Concurrent Water Vapour) Units Run 1

Less than 50% Faded % Yes

Isokinetic Criterion Compliance Units Run 1

Isokinetic Variation % 99.2



Filter Temperatures Units Run 1


Impingers Exit Temperature Units Run 1

Maximum Temperature Recorded °C 17

Maximum Allowable Temperature °C 30


Test Conditions Units Run 1



Company XXXX



PPC Permit: None

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

APPENDIX 2

NICKEL: QUALITY ASSURANCE(PAGE 2 OF 2)




Company XXXX



PPC Permit: None





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













mg/m³ 0.001

mg/m³ N/A

uρm kPa 0.50

Units

APPENDIX 2

% 20.3

% 20.3

% 20.3

% N/A

K 2.00

mg/m³ 0.001

mg/m³ 0.001


mg/m³ 0.0006


≤1%

% v/v

Measured Quantities

ρm 101.2

Run 1

% 10.0

≤1%

uVm m³ 0.02Tm 297.6 uTm

N/A

Units Run 1

%



Measured Quantities

Measured Quantities Units Run 1 Requirement of Standard

≤1%

% 0.49

1.00

Run 1


- N/A


Lr mg/m³ 0.0005

Overall MU For O₂ Measurement %

1.00

No Requirement

1.00

L

Vm m³ 0.98 0.01

N/A

mg/m³ 0.0000

mg/m³ 0.0005

Run 1

%

Symbol

N/A

uHm % v/v 1.00

L 0.68 uL % -

Vm 1.15

mg/m³ 0.0001

% 2.00 ≤2%

% 0.67

Symbol Units Run 1

mg/m³ 0.0000

%

Measured Quantities Symbol Run 1

Hm 0.00

0.68 ≤2%

Lr 10.0 uLr % -

NICKEL: MEASUREMENT UNCERTAINTY CALCULATIONS



Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -






APPENDIX 2

ARSENIC: RESULTS SUMMARY



Concentration mg/m³ 0.0006 0.0006

Run 1 Mean

Standard EN 14385


M31

ISO 17025 Accredited Analysis? Yes




Probe Material

Borosilicate Glass








g/hr 0.0003

Uncertainty ±% v/v 0.24 0.24

Parameter Value

Titanium


Impinger Material

4.47

0.0003

Uncertainty ±g/hr 0.00005 0.00005

Parameter Units


Mass Emission


Company XXXX



PPC Permit: None








CO₂ (Estimated)

O₂





Volume of gas sample through gas meter, Vm m³

Total % v/v 14.00

Pitot tube velocity constant, Kp - 34.97

% v/v 4.47

m³/min

Total mass of liquid collected, Vlc gm³ 0.0457

N/A

1.0231

1.1520Gas meter correction factor, Yd -

24.6


N/A


959.7

Velocity pressure coefficient, Cp - 0.83

Test Units Run 1

% v/v

Stack static pressure, Pstatic mmH₂O

0.90

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s

-

m³

36.7Vwstd = (0.001246)(Vlc)

0.9230Average dry gas meter temperature, Tm °C

% v/v 4.47

Total mass collected in impingers (silica trap) g 7.0

758.8Ps = (Pb + (Pstatic / 13.6) mmHg

Total mass collected in impingers (liquid trap) g 29.7

6.56

759.0

APPENDIX 2

ARSENIC: ISOKINETIC SAMPLING CALCULATIONS

37.8

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w) -


g/gmol 29.16

% v/v


m³/min

Total sampling time, q min 60

mmH₂O 33.9Average pressure drop across orifice, ∆H

9.00

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³ 0.9774


°C

0.0447

- Yes



Average square root of velocity heads, √∆P √mmH₂O

0.10

N/A

N/A

5.00


Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³ N/AVmstd@X%oxygen = (Vmstd) / (O₂REFd) m³ N/A

Qa = (60)(As)(Vs)

%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100)) % 99.2

-

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol

Nozzle area, An


Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

0.95

28.66


% v/v


m³/min 8.4Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)

N₂ % v/v 86.00

Nozzle diameter, Dn mm 15.86



197.67

N/A

0.3592

m³

-2.5

m³/minm³/min N/A

mm²

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

8.0



Company XXXX



PPC Permit: None

Sample Runs

<

<

Mass in Back Impinger <

<

<

-



0.069Mass in Front Impingers µg

ARSENIC: SAMPLING DETAILS

Parameter Units

Mass on Filter / in Rinse

Total Mass Collected µg

µg

Sampling Device -

Run 1


Sampling Dates

0.030µg

- 11:55 - 12:55

ISO

Sampling Times

0.500

- 23/07/2015

0.9774

APPENDIX 2

0.599

Volume Sampled (REF) m³


Company XXXX



PPC Permit: None

Sample Runs

Yes

5.0

20Measurement Uncertainty (MU) % 5.4


%

-

0.12

Test Conditions Run 1


Yes

95 - 115

Allowable Absorption Efficiency %

l/min 0.10

Allowable MU


µg/m³

%

No

- Yes

%

Run 1

Detection Limit 0.61


Pre-Sampling Leak Rate

l/min 17.7

Allowable Leak Rate l/min

MU Acceptable

Detection Limit Acceptable

Units Run 1

µg/m³

Run 1

Yes


Mean Sampling Rate

0.35

Units Run 1

Water Droplets Units

Isokineticity Acceptable

Units

°C

%


Less than 50% Faded

-



-

N/A



-

MU (Concurrent Water Vapour) Units

Yes


Run 1


Detection Limit Units Run 1


APPENDIX 2

ARSENIC: QUALITY ASSURANCE(PAGE 1 OF 2)



% 100.0


Ambient Temperature Recorded?

Yes

185

°C

Filter Temperatures

99.2

17°C

30


Maximum Temperature Recorded


Company XXXX



PPC Permit: None

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

ARSENIC: QUALITY ASSURANCE

APPENDIX 2


(PAGE 2 OF 2)



Company XXXX



PPC Permit: None





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













mg/m³ N/A

% N/A

N/A

1.00%

L mg/m³

Run 1

% v/v N/A

mg/m³

ARSENIC: MEASUREMENT UNCERTAINTY CALCULATIONS

0.0000


2.00

Symbol

≤2%

mg/m³


0.0000

% 2.00

kPa 0.50

0.02

Parameter

mg/m³

% 12.0

%

Measured Quantities

0.67

0.98

Run 1

No Requirement

Tm

Units

Value

Run 1

0.0000

≤1%

12.0

0.00

Units



-

% N/AOverall MU For O₂ Measurement %

1.00

0.00007

N/A

Run 1

UnitsMeasured Quantities


0.0000



1.00

ρm 101.2

-

Hm 0.00

Units

0.68

Lr

m³

m³

uρm

K

APPENDIX 2

uLr % -

L 0.68

Vm 1.15 uVm

uL %

uHm % v/v

Run 1

Units Requirement of Standard

mg/m³ 0.00007

0.00004

297.6

% 0.49

%

% 5.50

≤1%

Measured Quantities

Vm

mg/m³

1.00Lr mg/m³ 0.0000

12.0

uTm

≤2%%

Run 1

5.50


mg/m³

%

mg/m³ 0.00007

Symbol

≤1%


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -






4.47

Uncertainty ±% v/v

APPENDIX 2

CADMIUM: RESULTS SUMMARY

0.0002

Uncertainty 0.0001

Parameter

Value

Concentration mg/m³

0.24

0.0002









0.24



Impinger Material

0.0003

Uncertainty ±mg/m³


0.0003

±g/hr

0.0006

Borosilicate Glass




Standard EN 14385

UnitsParameter

Parameter

Units Run 1 Mean


Mean

Mass Emission g/hr

Run 1

0.0001

0.0006


Company XXXX



PPC Permit: None








CO₂ (Estimated)

O₂





m³ 0.0447


Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

-


m³ 1.0231


60Nozzle area, An

m³/min

0.90



N/A

0.9774

mmH₂O

m³


4.47

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))

% v/v

N/A


8.4


99.2

6.56

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)Conversion factor (K/mm.Hg), Cf

0.10

m³/min-

Qa = (60)(As)(Vs)


m/s

m³/minm²Area of stack, As

0.3592

m³/min 8.0

0.95√mmH₂OAverage square root of velocity heads, √∆P

m³/min N/A

37.8

min


% v/v

Total % v/v

N/A

14.00


% v/v

0.0457

Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³


Volume of gas sample through gas meter, Vm m³

Vwstd = (0.001246)(Vlc) m³

28.66Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol

- N/A

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)

Average stack gas temperature, Ts °C 959.7

N/A

%

4.47

% v/v N/A

1.1520


IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction) - YesN/A


Total mass of liquid collected, Vlc g


-2.5

Total mass collected in impingers (liquid trap)Total mass collected in impingers (silica trap) g 7.0

15.86

Ps = (Pb + (Pstatic / 13.6) mmHg

Vmstd@X%oxygen = (Vmstd) / (O₂REFd) m³

% v/v 86.00g/gmol 29.16

% v/v

- 34.97Velocity pressure coefficient, Cp - 0.83

% v/v 5.00

g

Units Run 1

APPENDIX 2

CADMIUM: ISOKINETIC SAMPLING CALCULATIONS

Test

36.7


759.0Barometric pressure, Pb mmHg

9.00

N₂

758.8

29.7


Nozzle diameter, Dn mmmm² 197.67

mmH₂O 33.9

N/A


Company XXXX



PPC Permit: None

Sample Runs

-

<

Mass in Back Impinger <

-

-

-


APPENDIX 2

0.500µg

0.9774



- 11:55 - 12:55

CADMIUM: SAMPLING DETAILS

Parameter

0.0006


mg/m³

m³

- 23/07/2015

Sampling Times

Sampling Device

Sampling Dates

- ISO


0.020


µg

µg 0.566

Mass on Filter / in Rinse

Units Run 1


Company XXXX



PPC Permit: None

Sample Runs

Yes


Yes

Yes

-

17


Exit Temperature Acceptable



Units Run 1

-

% 99.2




Allowable MU % 20

MU Acceptable % Yes






Maximum Temperature Recorded °C






Allowable Detection Limit µg/m³ 5.0






(PAGE 1 OF 2)








APPENDIX 2

CADMIUM: QUALITY ASSURANCE

Detection Limit Acceptable -

- Yes


Company XXXX



PPC Permit: None

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

CADMIUM: QUALITY ASSURANCE(PAGE 2 OF 2)

APPENDIX 2




Company XXXX



PPC Permit: None





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













-

0.00


mg/m³ N/A

0.68

0.49

Units

Hm


SymbolMeasured Quantities

mg/m³

Units

0.98

m³

- N/A

% v/v N/A

% N/A

Units


Run 1

L

Units

No Requirement

% 2.00

Lr

mg/m³ 0.0002

0.00

≤1%

%

Units Run 1 Requirement of Standard

0.0001

Run 1


mg/m³

Value

%

Parameter


mg/m³


15.0

≤2%

L

1.00

101.2

uVm

uHm % v/v

uTm K 2.00Tm 297.6

≤1%

≤1%

%

1.15 0.02

Run 1

15.0


ρm

% -


0.50

Symbol

uLr

APPENDIX 2

Vm

29.9

mg/m³ 0.0002

mg/m³ 0.0002

29.9

≤2%

% 0.67

Run 1 Run 1

% N/A

mg/m³ 0.0000 1.00Lr mg/m³

mg/m³

0.0001

%

%

% 29.9

uρm kPa

CADMIUM: MEASUREMENT UNCERTAINTY CALCULATIONS

0.0000

%

Vm


Measured Quantities

0.0000

Measured Quantities

1.00

0.68

0.0001 1.00

uL %

m³


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -







±% v/v

COPPER: RESULTS SUMMARY

Mean

Concentration


Value

EN 14385

Parameter

1 / 1

Units Run 1

1 / 1Number of Sampling Lines Used



Technical Procedure


0.0001

RPS

Standard

Uncertainty

Mean

0.0008

CAT-TP-06

±g/hr

0.0016

±mg/m³ 0.0002

0.24

0.0001

47mm Quartz Fibre

Titanium


4.47

Borosilicate Glass



g/hr 0.0008

mg/m³ 0.0016

Parameter


Mass Emission

Probe Material

Uncertainty

0.24


Uncertainty

Number of Sampling Points Used

0.0002


Impinger Material

APPENDIX 2



Company XXXX



PPC Permit: None








CO₂ (Estimated)

O₂





99.2

m³

Nozzle area, An


Vwstd = (0.001246)(Vlc)

-

959.7


Total sampling time, q min 60%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))

mm² 197.67

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s

m³ 1.1520

m³/min

0.83

APPENDIX 2

m³


%

% v/v N/A

mmH₂O 0.90

Units

Ps = (Pb + (Pstatic / 13.6) mmHg-2.5




759.0

Yes

5.00

m³

9.00


N/AVmstw@X%oxygen = (Vmstw) / (O₂REFw)


Run 1


29.7

m³/min 37.8

% v/v



28.66

0.95

% v/v N/A

g/gmol

N/A

√mmH₂O


Area of stack, As m² 0.10

Conversion factor (K/mm.Hg), Cf - 0.3592Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273) m³/min 8.4

Qa = (60)(As)(Vs)

°C

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min N/A


4.47

m³ 1.0231

Average dry gas meter temperature, Tm

-

0.0447


Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min 8.0

0.9230

N/A


0.9774



Total % v/v

N/A

-

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

Vmstd@X%oxygen = (Vmstd) / (O₂REFd) m³ N/A


Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol 29.16

6.56

4.47

N₂

°C

g 36.7

% v/v

% v/v

% v/v

% v/v 86.00


-

14.00


24.6


7.0

mmH₂O

0.0457

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)

g

33.9

Total mass collected in impingers (liquid trap) gTotal mass collected in impingers (silica trap)

mmH₂Om³

Test

COPPER: ISOKINETIC SAMPLING CALCULATIONS

758.8


Company XXXX



PPC Permit: None

Sample Runs

-

-


-

-

-


Run 1

APPENDIX 2

COPPER: SAMPLING DETAILS

Parameter Units

1.000Mass on Filter / in Rinse µg




µg 0.460

µg 0.099

- ISO


Sampling Device

Mass in Front Impingers




Company XXXX



PPC Permit: None

Sample Runs

Yes




Units Run 1

Units

µg/m³ 0.7

Yes

185


0.35

APPENDIX 2

COPPER: QUALITY ASSURANCE(PAGE 1 OF 2)

Leak Test Results

-Leak Test Acceptable


Yes

20

MU Acceptable %



Isokineticity Acceptable -



Detection Limit




% 5.4

Allowable MU %

Filter Temperatures Units

%

5


Units Run 1


Units


Water Droplets


% Yes





Allowable Leak Rate l/min

Run 1

Detection Limit Acceptable - Yes

- N/A

µg/m³



N/A

Run 1

Run 1

Run 1

Less than 50% Faded

Maximum Filter Temperature °C



Company XXXX



PPC Permit: None

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -



APPENDIX 2

COPPER: QUALITY ASSURANCE(PAGE 2 OF 2)


Company XXXX



PPC Permit: None





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













% N/A

mg/m³ N/A

mg/m³ 0.0002

mg/m³ 0.0002

% 12.9

% 12.9

% 12.9

mg/m³ 0.0001


mg/m³ 0.0001

mg/m³ 0.0002



- N/A

% v/v N/A

% N/AOverall MU For O₂ Measurement % N/A



mg/m³ 0.0000

mg/m³ 0.0000

Vm m³ 0.98 0.00

L mg/m³ 0.0000 1.00Lr mg/m³ 0.0001 1.00

% 0.68 ≤2%

% 6.00 No Requirement


Measured Quantities Symbol Units Run 1 Run 1



% 2.00 ≤2%

% 0.67 ≤1%

% 0.49 ≤1%

% 1.00 ≤1%

L 0.68 uL % -Lr 6.00 uLr % -

Tm 297.6 uTm K 2.00ρm 101.2 uρm kPa 0.50Hm 0.00 uHm % v/v 1.00

APPENDIX 2

COPPER: MEASUREMENT UNCERTAINTY CALCULATIONS


Measured Quantities Symbol Run 1 Symbol Units Run 1

Vm 1.15 uVm m³ 0.02


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -














Parameter Value

Standard EN 14385




Impinger Material Borosilicate Glass





Water Vapour % v/v 4.47 4.47






Mass Emission g/hr 0.007 0.007

APPENDIX 2

CHROMIUM: RESULTS SUMMARY


Company XXXX



PPC Permit: None








CO₂ (Estimated)

O₂






QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min N/AQstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A

Nozzle diameter, Dn mm 15.86Nozzle area, An mm² 197.67Total sampling time, q min 60

Area of stack, As m² 0.10Qa = (60)(As)(Vs) m³/min 37.8Conversion factor (K/mm.Hg), Cf - 0.3592Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273) m³/min 8.4Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min 8.0

Velocity pressure coefficient, Cp - 0.83Average of velocity heads, ∆Pavg mmH₂O 0.90Average square root of velocity heads, √∆P √mmH₂O 0.95Average stack gas temperature, Ts °C 959.7Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s 6.56

Total % v/v 14.00N₂ % v/v 86.00Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol 29.16



O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d) - N/AVmstw@X%oxygen = (Vmstw) / (O₂REFw) m³ N/AVmstd@X%oxygen = (Vmstd) / (O₂REFd) m³ N/A

% v/v 5.00% v/v 9.00

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction) - Yes% wet oxygen measured in gas stream, ACT%O₂w % v/v N/A% dry oxygen measured in gas stream, ACT%O₂d % v/v N/A% oxygen reference condition, REF%O₂ % v/v N/AO₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w) - N/A

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³ 0.9774

Bwo = Vwstd / (Vmstd + Vwstd) m³ 0.0447% v/v 4.47% v/v 4.47

Vmstw = (Vmstd)(100/(100 - Rwv)) m³ 1.0231

Vwstd = (0.001246)(Vlc) m³ 0.0457

Volume of gas sample through gas meter, Vm m³ 1.1520Gas meter correction factor, Yd - 0.9230Average dry gas meter temperature, Tm °C 24.6Average pressure drop across orifice, ∆H mmH₂O 33.9

Stack static pressure, Pstatic mmH₂O -2.5Ps = (Pb + (Pstatic / 13.6) mmHg 758.8

Total mass collected in impingers (liquid trap) g 29.7Total mass collected in impingers (silica trap) g 7.0Total mass of liquid collected, Vlc g 36.7

APPENDIX 2

CHROMIUM: ISOKINETIC SAMPLING CALCULATIONS

Test Units Run 1

Barometric pressure, Pb mmHg 759.0


Company XXXX



PPC Permit: None

Sample Runs

-

-


-

-

-





µg 3.575




APPENDIX 2

CHROMIUM: SAMPLING DETAILS






Company XXXX



PPC Permit: None

Sample Runs

YesAmbient Temperature Recorded? -





95 - 115








Allowable MU % 20

MU Acceptable % Yes










Absorption Efficiency Acceptable - N/AWhere the emissions are < 30% of the ELV, MID 14385 does not require the 90% absorption efficiency requirement to be appliedDetection Limit Units Run 1








APPENDIX 2

CHROMIUM: QUALITY ASSURANCE(PAGE 1 OF 2)




Company XXXX



PPC Permit: None

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

Nature of Deviation

APPENDIX 2



CHROMIUM: QUALITY ASSURANCE(PAGE 2 OF 2)


Company XXXX



PPC Permit: None





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













Hm 0.00

Vm 1.15

Symbol

APPENDIX 2

CHROMIUM: MEASUREMENT UNCERTAINTY CALCULATIONS



Lr 5.50


No Requirement

%

% -

%

ρm 101.2 kPa 0.50



% 2.00

Run 1

Run 1

Vm m³ 0.98

≤2%

0.67

uTm K 2.00

uVm m³

% 0.68

L


0.02

0.68

% v/v 1.00

Run 1

uHm

Tm 297.6

%

uρm

≤1%0.49

mg/m³ 0.0008

% 1.00

≤2%

≤1%

Units

%



1.00

1.00

0.0004

mg/m³


uLuLr % -

5.50

mg/m³

0.0016

0.0001

- N/A

Run 1

%

%

12.0


Symbol Units Run 1Measured Quantities

≤1%

Lr mg/m³ 0.0007

% 12.0


mg/m³

N/A

12.0

mg/m³

0.0016


%

0.0001

0.01

N/A

L

% v/v N/A

mg/m³ N/A

mg/m³

mg/m³ 0.0007

mg/m³ 0.0016


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -








Units

±% v/v

Titanium

04/08/2015


M31

Date of Sample Analysis

0.0007 0.0007

Parameter Value

47mm Quartz Fibre


Technical Procedure


Titanium

Filter Housing Material

Yes

Parameter

1 / 1

Sample Point I.D.'s


4.47

Run 1 Mean

Probe Material


0.0001

APPENDIX 2

EN 14385

CAT-TP-06

Out Stack


g/hr 0.0004

% v/v 4.47

MANGANESE: RESULTS SUMMARY



Parameter

Mass Emission

Standard

0.24


Units Run 1

Water Vapour

Uncertainty

0.0001

0.0004


0.24

A1


Mean


Company XXXX



PPC Permit: None








CO₂ (Estimated)

O₂






24.6- 0.9230

N/A

-2.5

N/A


86.00

°C



-


m³/min 8.4

mmHg 759.0Stack static pressure, Pstatic

MANGANESE: ISOKINETIC SAMPLING CALCULATIONS

Vwstd = (0.001246)(Vlc) m³

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s 6.56

Area of stack, As

% v/v 9.00Total % v/v 14.00

Units Run 1


Ps = (Pb + (Pstatic / 13.6) mmHg 758.8

4.47



mmH₂OAverage dry gas meter temperature, Tm

m³/min


% dry oxygen measured in gas stream, ACT%O₂d % v/v N/A

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol 29.16

1.0231

g 29.7



Nozzle area, An mm² 197.67

28.66

37.8

% v/v 5.00

N/Am³

Qa = (60)(As)(Vs)m²

m³/min 8.0Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)

Average of velocity heads, ∆Pavg mmH₂O 0.90Average square root of velocity heads, √∆P


m³

min 60

959.7

Conversion factor (K/mm.Hg), Cf - 0.3592

m³ 0.9774

Bwo = Vwstd / (Vmstd + Vwstd) m³ 0.0447% v/v 4.47

°C

Test

- Yes

Velocity pressure coefficient, Cp - 0.83

N₂ % v/v

√mmH₂O 0.95

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)

g/gmol


m³ N/A

APPENDIX 2

g 7.0g


QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A

Total mass collected in impingers (liquid trap)Total mass collected in impingers (silica trap)

% v/v

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

mmH₂O


m³ 1.1520



36.7


33.9

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

% v/v

0.10

0.0457

O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d) - N/A


Company XXXX



PPC Permit: None

Sample Runs

-

-


-

-

-


Parameter Units

APPENDIX 2

MANGANESE: SAMPLING DETAILS



0.184

µg

Mass in Front Impingers µg




m³ 0.9774


Run 1



0.020


Company XXXX



PPC Permit: None

Sample Runs

Yes

Units

0.10

N/AWhere the emissions are < 30% of the ELV, MID 14385 does not require the 90% absorption efficiency requirement to be applied



Absorption Efficiency Acceptable -

Run 1Absorption Efficiency








Allowable MU % 20

MU Acceptable % Yes



-

APPENDIX 2

MANGANESE: QUALITY ASSURANCE(PAGE 1 OF 2)


Pre-Sampling Leak Rate l/min



















Company XXXX



PPC Permit: None

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

APPENDIX 2

MANGANESE: QUALITY ASSURANCE(PAGE 2 OF 2)




Company XXXX



PPC Permit: None





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













mg/m³ N/A

% N/A

N/AOverall MU For O₂ Measurement % N/A

-

APPENDIX 2

MANGANESE: MEASUREMENT UNCERTAINTY CALCULATIONS



uVm m³ 0.02

ρm uρm kPa 0.50

uTm K 2.00

1.00

% 0.68


Lr mg/m³ 0.0000

0.00008

mg/m³ 0.0000

L 0.68

Measured Quantities

% 0.49

% 5.00


Symbol Units Run 1

11.2

mg/m³ 0.0000

Parameter Units

11.2

mg/m³

mg/m³ 0.00008

mg/m³ 0.00004

Run 1

%


Run 1

% 11.2

≤1%

% 1.00

m³ 0.98 0.00

Tm 297.6

≤2%

% v/v N/A

%

mg/m³ 0.0000

≤1%

Hm 0.00

101.2

%


% 2.00

≤1%

Run 1


Vm 1.15

mg/m³

- N/A

0.00008

1.00



uHm % v/v 1.00

Lr 5.00



Vm

%

No Requirement

-

L mg/m³ 0.0000

uLr %

≤2%

% 0.67

uL


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -






Units Run 1 Mean



APPENDIX 2

LEAD: RESULTS SUMMARY


Parameter





4.47


Parameter Value

Standard EN 14385
















Company XXXX



PPC Permit: None








CO₂ (Estimated)

O₂





APPENDIX 2

LEAD: ISOKINETIC SAMPLING CALCULATIONS

Test Units Run 1

Barometric pressure, Pb mmHg 759.0Stack static pressure, Pstatic mmH₂O -2.5Ps = (Pb + (Pstatic / 13.6) mmHg 758.8

Total mass collected in impingers (liquid trap) g 29.7Total mass collected in impingers (silica trap) g 7.0Total mass of liquid collected, Vlc g 36.7Vwstd = (0.001246)(Vlc) m³ 0.0457

Volume of gas sample through gas meter, Vm m³ 1.1520Gas meter correction factor, Yd - 0.9230Average dry gas meter temperature, Tm °C 24.6Average pressure drop across orifice, ∆H mmH₂O 33.9Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³ 0.9774

Bwo = Vwstd / (Vmstd + Vwstd) m³ 0.0447% v/v 4.47% v/v 4.47

Vmstw = (Vmstd)(100/(100 - Rwv)) m³ 1.0231

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction) - Yes% wet oxygen measured in gas stream, ACT%O₂w % v/v N/A% dry oxygen measured in gas stream, ACT%O₂d % v/v N/A% oxygen reference condition, REF%O₂ % v/v N/AO₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w) - N/AO₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d) - N/AVmstw@X%oxygen = (Vmstw) / (O₂REFw) m³ N/AVmstd@X%oxygen = (Vmstd) / (O₂REFd) m³ N/A

% v/v 5.00% v/v 9.00

Total % v/v 14.00N₂ % v/v 86.00Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol 29.16


Pitot tube velocity constant, Kp - 34.97Velocity pressure coefficient, Cp - 0.83Average of velocity heads, ∆Pavg mmH₂O 0.90Average square root of velocity heads, √∆P √mmH₂O 0.95Average stack gas temperature, Ts °C 959.7Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s 6.56

Area of stack, As m² 0.10Qa = (60)(As)(Vs) m³/min 37.8Conversion factor (K/mm.Hg), Cf - 0.3592Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273) m³/min 8.4Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min 8.0QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min N/AQstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A

Nozzle diameter, Dn mm 15.86Nozzle area, An mm² 197.67Total sampling time, q min 60%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100)) % 99.2


Company XXXX



PPC Permit: None

Sample Runs

-

-


-

-

-


APPENDIX 2

LEAD: SAMPLING DETAILS








µg 0.030





Company XXXX



PPC Permit: None

Sample Runs

APPENDIX 2

LEAD: QUALITY ASSURANCE(PAGE 1 OF 2)










Absorption Efficiency Acceptable - N/AWhere the emissions are < 30% of the ELV, MID 14385 does not require the 90% absorption efficiency requirement to be appliedDetection Limit Units Run 1








Allowable MU % 20

MU Acceptable % Yes
















Company XXXX



PPC Permit: None

Method Deviations

1

X

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

APPENDIX 2

LEAD: QUALITY ASSURANCE(PAGE 2 OF 2)




Company XXXX



PPC Permit: None





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













APPENDIX 2

LEAD: MEASUREMENT UNCERTAINTY CALCULATIONS





% 2.00

≤1%

% 1.00 ≤1%

Vm 1.15 uVm m³ 0.02Tm 297.6 uTm K 2.00ρm 101.2 uρm kPa 0.50

1.00

Measured Quantities

N/A

Vm m³ 0.98 0.02

L mg/m³

L 0.68 uL % -

Measured Quantities Symbol Units Run 1 Run 1

Lr 6.50 uLr % -

% 13.8

0.003

Run 1

% 0.68 ≤2%

% 6.50 No Requirement


Hm 0.00 uHm % v/v 1.00

≤2%

% 0.67 ≤1%

0.0001 1.00Lr mg/m³ 0.0015

-


% 0.49

% v/v N/A

% N/AOverall MU For O₂ Measurement % N/A


mg/m³

mg/m³ 0.002

mg/m³ 0.003

mg/m³ N/A

mg/m³ 0.003


% N/A

% 13.8

% 13.8

mg/m³ 0.0006

mg/m³ 0.0001

mg/m³ 0.0015


Units Run 1


Company XXXX



PPC Permit: None

Sample Runs (UPPER NATO I-TEQ)

- -

- -

- -

- -

- -

Sample Runs (UPPER WHO TEQ Humans / Mammals)

- -

- -

- -

- -

- -

Sample Runs (UPPER WHO TEQ Fish)

- -

- -

- -

- -

- -

Sample Runs (UPPER WHO TEQ Birds)

- -

- -

- -

- -

- -

µg/hr 0.006

Uncertainty ±µg/hr

Concentration

Units Run 1

0.001

Parameter

0.004 0.004

Mass Emission µg/hr 0.010 0.010

0.001

DIOXINS & FURANS: RESULTS SUMMARY

Company XXXX,

Concentration ng/m³ 0.012

(PAGE 1 OF 3)

Uncertainty ±ng/m³ 0.002


Parameter Units

0.006

Uncertainty ±µg/hr 0.001

APPENDIX 2

Run 1

0.002

Mean

0.002


TEQ1 - UPPER LIMITS (worst case where <LOD = LOD)


0.002

Mean

Concentration ng/m³ 0.011 0.011

Parameter Units

Mass Emission

0.012

Units

0.001

Concentration ng/m³ 0.010

0.002

Mass Emission

±ng/m³

Parameter

±ng/m³

0.005


Uncertainty

ng/m³ 0.020 0.020

Uncertainty

±ng/m³ 0.002

0.010

Uncertainty

0.0020.002

Mean

Run 1 Mean

µg/hr 0.005

Run 1


Company XXXX



PPC Permit: None

Sample Runs (LOWER NATO I-TEQ)

- -

- -

- -

- -

- -

Sample Runs (LOWER WHO TEQ Humans / Mammals)

- -

- -

- -

- -

- -

Sample Runs (LOWER WHO TEQ Fish)

- -

- -

- -

- -

- -

Sample Runs (LOWER WHO TEQ Birds)

- -

- -

- -

- -

- -

0.006

0.002

0.002

µg/hr 0.006

0.006

0.010


Mean

0.010


Mass Emission µg/hr 0.010

0.002

Uncertainty ±µg/hr

0.012

Uncertainty

(PAGE 2 OF 3)


TEQ2 - LOWER LIMITS (best case where <LOD = 0)


±ng/m³

Run 1

0.004 0.004

Mass Emission

0.001Uncertainty

Parameter Units

±ng/m³ 0.002

0.010

Uncertainty

0.002

0.012

0.011 0.011

0.001

APPENDIX 2


0.002

Mass Emission

±ng/m³ 0.002

Mean

Concentration ng/m³


Parameter

µg/hr

Mean



Uncertainty

±µg/hr 0.001


Units Run 1

0.001 0.001

Concentration ng/m³ 0.020 0.020

Uncertainty ±ng/m³

0.006


Company XXXX



PPC Permit: None

- -

- -

- -






Date of Sample Analysis

1 / 1



SOP 1C

07/08/2015

Parameter Value

XAD-2Absorption Material

APPENDIX 2

4.29

EN 1948

0.24

Filter Housing Material Borosilicate Glass

Standard


Sample Point I.D.'s

Probe Material Borosilicate Glass

Glassware Material Borosilicate Glass

Uncertainty ±% v/v 0.24

Yes

Out Stack



4.29



Water Vapour % v/v

A1

90mm Quartz Fibre


(PAGE 3 OF 3)

Company XXXX,

Mean


Name of Analytical Laboratory SAL



Company XXXX



PPC Permit: None








CO₂ (Estimated)

O₂




Total % v/v 19.00


% dry oxygen measured in gas stream, ACT%O₂d % v/v

°C 24.2Average dry gas meter temperature, Tm


N₂ % v/v

°C 922.5


4.29

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min


Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273) m³/min 9.7

% v/v

m³ 4.9720

% v/v

√mmH₂O

N/A

g


Barometric pressure, Pb mmHg 757.5

Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³


% v/v


Vwstd = (0.001246)(Vlc) m³ 0.1885

Qa = (60)(As)(Vs)

4.3967

Total mass collected in impingers (liquid trap)Total mass collected in impingers (silica trap) 12.7

mmH₂O

% v/v 10.00

N/A% oxygen reference condition, REF%O₂ % v/v N/A

N/AVmstd@X%oxygen = (Vmstd) / (O₂REFd)

Test

N/A

m³

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)N/AYes


138.6

4.2082


g


APPENDIX 2

DIOXINS & FURANS: ISOKINETIC SAMPLING CALCULATIONS

Ps = (Pb + (Pstatic / 13.6) mmHg 757.3


% v/v 4.29

Average pressure drop across orifice, ∆H mmH₂O 15.6

Total mass of liquid collected, Vlc g 151.3

42.5Area of stack, As m² 0.10

Velocity pressure coefficient, Cp - 0.83Pitot tube velocity constant, Kp

Units Run 1

7.36Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s

-

9.3

m³/min

29.96

114.37

-

81.00

Nozzle area, An mm²


Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol

9.00

- 0.3592

Total sampling time, q min 360

N/A

-3.0



QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min

1.10

m³ N/A




- 34.97

Average square root of velocity heads, √∆P1.20mmH₂O


Company XXXX



PPC Permit: None


2378-TCDD

12378-PeCDD

123478-HxCDD

123678-HxCDD

123789-HxCDD

1234678-HPeCDD

OCDD

Total Dioxins

2378-TCDF

12378-PeCDF

23478-PeCDF

123478-HxCDF

123678-HxCDF

234678-HxCDF

123789-HxCDF

1234678-HPeCDF

1234789-HPeCDF

OCDF

Total Furans

Totals

Total Concentration

Limit of Detection

Where: ND stands for Non Detected

DL stands for Analytical Detection Limit

TEQ1 refers to Non Detected Congeners at the Detection Limit

TEQ2 refers to Non Detected Congeners at Zero

% Rec stands for the Recovery Percentage of the Sample

0.0120

ng

0.0010

0.0000

0.0023

0.00020.0210

0.0022

0.0493

0.0117

ng

ng

0.0014

0.0008

0.0001ng

ng

0.0118

0.1800

0.0077

0.0012

0.0000

-

0.0000

0.0011

0.0170

0.0023

% Rec

0.0018

-ng

0.0113

0.00900.2655 -

-

RUN 1

0.0040

0.0736

0.0077

ng

ng

ng

0.0019

0.0011

0.0170

0.0033

0.0040

0.0077

0.0014

0.0018

0.0002

0.0023

0.0103

0.0475

0.0113

0.0475 0.0836

0.0199

0.0433

0.0103

0.0001

0.0003

0.0008 0.0008

ng/m³ -

0.0121 0.0121

0.0019

0.0002

ng/m³

0.0100 0.0100

0.0493

0.0117

0.0090

-

88

60

-

-

0.0008

0.0000

0.0031

0.0330

0.0580

-

-

ng 0.5340 0.0836

0.0199

0.0023


0.0002

0.0014

ng

0.0012

0.0001

0.0001

0.0000

0.0008

0.0001

0.0118ng

0.0002

0.0007

0.0102

APPENDIX 2

DIOXINS & FURANS: SAMPLING DETAILS

TEQ2

0.0340

TEQ2

0.0019 - 0.0024 -

0.0033

0.0040

0.0077

0.0040

0.0018

0.0002

0.0433

0.0028

0.0001

0.0064

0.0028

0.0340

0.0006

0.0023

-

98

93

0.0140

0.0022

0.0064

96

92

0.0023

0.0023

0.0019

0.0011

0.0018

0.0000

0.0385 0.0312

ng

0.0000

0.0770

0.0018

0.0014

0.0018

0.0032

0.0001

0.0077

0.0002

0.0000

0.0002

99

0.0375

0.0033

0.0736

0.0940

ng

08:43 - 14:43Sampling Times

Sampling Dates

Sampling Device

0.0001

0.0010

0.0014

TEQ1 TEQ2 TEQ1

m³

Value

ng

ISO

0.0000

Units

-

-

-

DL

24/07/2015

0.0023

0.0400

0.0340

0.0007

0.0102

0.0033

0.0002

Parameter Units Result

0.0170

0.01900.0190

0.0220

TEQ1

Parameter

4.2082

NATOI-TEQ

WHO Humans / Mammals

WHOFish

0.0312 0.0375

0.0006

0.0040

71

0.0056

0.0033

950.0057

0.0023

0.0012

WHOBirds

0.0033

TEQ1 TEQ2

0.0810

0.1500

0.0001

0.0001

0.0000

0.0077

0.0014

0.0018

ng

1020.0037

0.0032

0.0031

0.0064

0.0006

0.0001

0.0008

90

0.0064

0.0023

0.00640.0064

0.0023

0.0040

0.0077

0.0014

0.0064

0.0023

0.0037

0.0120

79

82

- -

ng

ng

-

- 0.0022

0.0190

-

0.0033

0.0040

0.0077

0.0014

0.0033

ng

0.0022

0.0019

ng

0.0027

0.0040

0.0000

-

-0.0029

0.0003

0.0001

0.0018

0.0008

0.0002

0.0011

0.0170

0.5340

0.0330 0.0025

0.0025

0.0008

0.0008

0.0032

0.0006

0.0000

0.0385

0.0030

0.0008

0.0012

0.0082


Company XXXX



PPC Permit: None

Sample Runs


Yes

5.5

20

0.12Pre-Sampling Leak Rate

APPENDIX 2

DIOXINS & FURANS: QUALITY ASSURANCE

Mean Sampling Rate


Units

°C 20

Run 1

- Yes


-

No

l/min 12.7

l/min 0.12

Leak Test Results

Yes

% 106.2


(PAGE 1 OF 2)

Run 1

- Yes


Run 1


l/min

MU Acceptable %

Units Run 1

Units

Run 1


Allowable MU %

%

-

Units


Measurement Uncertainty (MU) %

Allowable Isokinetic Range 95 - 115



°C 125




Filter Temperatures

Test Conditions

Condenser Exit Temperature Units Run 1

19

Exit Temperature Acceptable


Maximum Temperature Recorded °C


Company XXXX



PPC Permit: None

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

(PAGE 2 OF 2)

Nature of Deviation

APPENDIX 2


DIOXINS & FURANS: QUALITY ASSURANCE



Company XXXX



PPC Permit: None





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













Overall MU For O₂ Measurement

- N/A

0.002

% 20.3

Lr 10.0

≤5%

%

≤2%

-


1.00

0.50

%

0.0011

2.00

ng/m³

- N/A

% v/v N/A

20.3

uLr

ng/m³ 0.0001

ng/m³

ng/m³ 0.001

Lr

0.002

20.3

ng/m³

ng/m³ 0.0003

Run 1

%

ng/m³

%

Units

Run 1

101.0

Tm

%


0.94

0.67 ≤1%

K

%

0.00

2.00

APPENDIX 2

DIOXINS & FURANS (NATO I-TEQ): MEASUREMENT UNCERTAINTY CALCULATIONS


Measured Quantities

-

0.10

%

Run 1

0.00

Run 1

m³ 4.21

uTm

≤1%


Measured Quantities

Vm

N/A

1.00

297.2

0.94

10.0

ρm

Units Run 1

% N/A


Measured Quantities

0.002

%

uL

4.97

Symbol Units

ng/m³ 0.0011

L

Symbol Units Run 1

Parameter

ng/m³

Hm

Vm

ng/m³

%

uHm

Run 1

1.00

0.0001L

%

kPa 0.50

uVm

Units

Symbol

≤1%

m³

uρm


Measured Quantities

% N/A

% v/v 1.00

No Requirement

Requirement of StandardMeasured Quantities Units Run 1


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -







Name of Analytical Laboratory SAL

Parameter Value

Probe Material Stainless Steel


47mm Quartz Fibre

CAT-AP-01

0.37

Run 1

9.01Water Vapour % v/v

Impinger Material Quartz Glass

Absorption Solution 0.3% Hydrogen Peroxide

Positioning of Filter Out Stack Heated Head


1 / 1



B1

Mean

APPENDIX 2

Units


0.35

CAT-TP-09

Sample Point I.D.'s

1 / 1

EN 14791

Technical Procedure


Parameter Units

9.01

0.37

5.0Concentration mg/m³


5.0

Standard

Uncertainty

Uncertainty

Yes


±g/hr 0.36 0.36

2.4

±% v/v

g/hr 2.4

Run 1

Mass Emission

Mean

SULPHUR DIOXIDE: RESULTS SUMMARY

Company XXXX,

Parameter


Company XXXX



PPC Permit: None

Sample Runs

-

-

-

-

-

<

-

-

Where: MFC stands for Mass Flow Controller, MV stands for Mass View Flowmeter

1565.2

Total Mass Of Water Vapour g 39.4

Calculated Water Vapour % v/v 9.01


Liquid Trap Start Mass g 1178.8

Liquid Trap End Mass g 1212.2

Silica Trap Start Mass g 1559.2

Silica Trap End Mass g

Mass in Back Impinger µg 3.6


Laboratory Result for Front Impingers

Laboratory Result for Back Impinger

Volume in Front Impingers

Volume in Back Impinger

µg/ml

µg/ml

ml

ml

11.26

0.05

219.0

71.0

Sample Flow Rate l/min 7.99



Volume Sampled (STP, Dry) m³ 0.4957

0.5448


mins 60

m³

Run 1


Sampling Device - MFC / MV

Volume Sampled (STP, Wet)

Duration

APPENDIX 2

SULPHUR DIOXIDE: SAMPLING DETAILS

Parameter Units


Company XXXX



PPC Permit: None

Sample Runs

² The concentration is less than 30% of the ELV, therefore no assessment against an allowable efficiency is required. 1 7 0 8

Method Deviations

1

x

- - - - -

- - - - -

- - - - -


Mean Sampling Rate

Yes

0.05

(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)



Nature of Deviation

Units Run 1


Allowable MU % 20




APPENDIX 2

SULPHUR DIOXIDE: QUALITY ASSURANCE


l/min 7.99



MU Acceptable % Yes



Run Number

Units Run 1




Allowable Absorption Efficiency % N/A ²

Absorption Efficiency Acceptable - N/A ²


Run 1


Company XXXX



PPC Permit: None


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













N/A-

%

mg/m³ 0.02

mg/m³

Measured Quantities

0.02

Run 1

Units

1.00

Measured Quantities

% 6.9

Overall MU For O₂ Measurement


Lr

0.50

Units Run 1

1.00


6.9

mg/m³

mg/m³ 0.14

N/A


uLr

6.9

%

mg/m³ 0.35

- N/A

% v/v

Vm



≤2%

% 2.90

10.0


APPENDIX 2


mg/m³

mg/m³ 0.10

m³

Lr

2.00 ≤2%

uVm

L 0.63

% -

-

Run 1 Requirement of Standard

SULPHUR DIOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

mg/m³ 0.35

mg/m³ 0.35

Measured Quantities Symbol Units Run 1

Vm 0.50 m³ 0.01

uL %

mg/m³ N/A

% N/A

%

No Requirement

2.90

L

Parameter

0.18

% N/A

Units Run 1

0.14

% 0.63

Value


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -







Impinger Material Polyethylene

Absorption Solution 0.1 mol/l Sodium Hydroxide

Positioning of Filter Out Stack Heated Head


Parameter Value

Probe Material Monel


Sample Point I.D.'s B1

Filter Housing Material Monel

Water Vapour % v/v 10.4 10.4

Uncertainty ±% v/v


Standard


CAT-AP-01


0.44 0.44

SAL


1 / 1


ISO 15713






APPENDIX 2

HYDROGEN FLUORIDE: RESULTS SUMMARY

Units Run 1 Mean

Company XXXX,


Parameter


Company XXXX



PPC Permit: None

Sample Runs

-

-

-

-

-

-

-

-

Where: MFC stands for Mass Flow Controller, MV stands for Mass View Flowmeter

Volume Sampled (STP, Dry) m³ 0.5347

Silica Trap Start Mass g 1487.9

Mass in Back Impinger µg 6.1


Silica Trap End Mass g 1500.8

Total Mass Of Water Vapour

10.43Calculated Water Vapour % v/v

Laboratory Result for Back Impinger µg/ml 0.05

Volume in Front Impingers ml 210.0


Duration 60


g 50.0

Liquid Trap Start Mass g 1191.6

Sampling Device

Sampling Dates

Volume in Back Impinger ml 121.0

g 1228.7


Sample Flow Rate l/min 8.62


mg/m³ 0.02

Laboratory Result for Front Impingers µg/ml 0.01

- 24/07/2015

- MFC / MV

mins

Volume Sampled (STP, Wet) m³ 0.5970

Units Run 1

Liquid Trap End Mass

APPENDIX 2

HYDROGEN FLUORIDE: SAMPLING DETAILS

Parameter


Company XXXX



PPC Permit: None

Sample Runs

² The concentration is less than 30% of the ELV, therefore no assessment against an allowable efficiency is required. 1 7 0 8

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)


%




Less than 50% Faded

%

MU Acceptable % Yes


Absorption Efficiency Acceptable - N/A ²

Allowable MU

No


Nature of Deviation Run Number

APPENDIX 2

HYDROGEN FLUORIDE: QUALITY ASSURANCE

Leak Test Results


Yes

l/min

Allowable Absorption Efficiency N/A ²

8.62


Are Water Droplets Present -

Units Run 1

20


%

- Yes



Mean Sampling Rate




Company XXXX



PPC Permit: None


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













-

%

% v/v N/A

No Requirement

% 6.6

N/A

- N/A


Measured Quantities

Run 1

≤2%

% N/A

% 2.65

% 6.6

Units

m³


Symbol

%

mg/m³ 0.001

%

Lr 2.65

0.01

L 1.16


0.001

uVm m³

mg/m³

mg/m³

mg/m³

0.001

1.16

%

Parameter

1.00

Overall MU For O₂ Measurement N/A

Vm

mg/m³

Units Run 1


Measured Quantities

1.00L

0.001

≤2%

%

Run 1

6.6

- N/A


Measured Quantities

0.53

mg/m³ 0.0001

0.03



mg/m³

mg/m³

Units Run 1

0.53

0.0003

APPENDIX 2

HYDROGEN FLUORIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

uL % -

mg/m³

Units

2.00


0.0004

0.0004

Run 1

Vm

uLr

Units

0.0001

Run 1

Lr mg/m³

Symbol


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -


This is the blended concentration of both propane cylinders





Zero Gas Type

0.28±g/hr

Mean

APPENDIX 2

Mass Emission

Concentration

180°C

Span Gas Set Point (ppm) 86.01

Standard

23/12/2019 | 15/07/2020

Uncertainty

Value

Span Gas Reference Number

Sample Point I.D.'s

mg/m³

0.56

Span Gas Uncertainty (%)

Company XXXX,

86.97 | 80.8

0.19 0.19

Heated Line Temperature

CYL 1.0131 in N₂ | CYL 1.0185 in AIR

Span Gas Start Pressure (bar) 180 | 180

Gas Cylinder Concentration (ppm)

TOTAL VOCs (as CARBON): RESULTS SUMMARY

0.38

CAT-TP-20

1 / 1

A1



2 | 2

Yes

9% O₂ in N₂ (5 Grade)

Span Gas Expiry Date

0.28

Parameter

0.38

g/hr



Filtration Type / Size 0.1µm Glass Fibre



Heated Head Filter Used

EN 12619:2013

Technical Procedure

Span Gas Type Propane in 9% O₂ in N₂ (5 Grade)


Company XXXX



PPC Permit: None

Graphical Trend of Data

APPENDIX 2

TOTAL VOCs (as CARBON): DATA TREND

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

9.0

10.0

12:3

412

:37

12:4

012

:43

12:4

612

:49

12:5

212

:55

12:5

813

:01

13:0

413

:07

13:1

013

:13

13:1

613

:19

13:2

213

:25

13:2

813

:31

13:3

413

:37

13:4

013

:43

13:4

613

:49

13:5

213

:55

13:5

814

:01

14:0

414

:07

14:1

014

:13

14:1

614

:19

14:2

214

:25

14:2

814

:31

14:3

4

Conc

entr

atio

n (m

g/m

³)

Total VOCs At Reference Conditions

- Run 1


Company XXXX



PPC Permit: None

Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

- - -

- - -

12:34 - 14:34

Zero Drift Acceptable

Span Down Sampling Line (Post)

86.0

Run 1

TOTAL VOCs (as CARBON): SAMPLING DETAILS & QUALITY ASSURANCE

Span Gas Value

Span Drift Acceptable

Allowable Span Drift ± ppm 4.30

Yes

-0.20ppm

Span Down Sampling Line (Pre)

Span Drift

ppm 86.0

-

ppm

Zero Down Sampling Line (Post) ppm

ppm 0.00

APPENDIX 2

± ppm

-0.20

Sampling Dates

Units Run 1

Parameter

°C

Run Number

Zero Drift

Zero Down Sampling Line (Pre)

Instrument Range ppm

0.00

Run 1

Units Run 1

23/07/2015

ppm 86.0

Nature of Deviation

(x = deviation applies to the associated run)

Test Conditions

CAL

1

-

ppm

100

Units

4.30Allowable Zero Drift

Units

Sampling Times

There are no deviations associated with the sampling employed.

Run Ambient Temperature Range 15 - 18

CAL

1

- Yes

-


Company XXXX



PPC Permit: None

k =

Uncertainty of calibration gas 0.01

Atmospheric pressure dependence 0.01

mg/m³

Standard deviation of repeatability at span level 0.00mg/m³

Drift -0.19

120

% of value/kPaAmbient temperature dependence 1.40

mg/m³

Dependence on voltage 0.06

% full scale

secondsNumber of readings in measurement

% full scaleVolume or pressure flow dependence 1.60

Measured concentration

mg/m³

0.45

mg/m³

Combined interference

mg/m³Volume or pressure flow dependence 0.00 mg/m³

% full scale/10VLosses in the line (leak) 0.00 % of valueUncertainty of calibration gas 2.83 % of value

Repeatability at span level 0.00 % full scaleDeviation from linearity 0.15 % of valueZero drift -0.23 % full scaleSpan drift 0.00

% of full scaleAtmospheric pressure dependence 0.30

% full scale/10K

TGN M2 Allowable MULimit value

Expanded uncertainty 1.96 0.56 mg/m³Uncertainty corrected to std conds. (O₂) mg/m³ (REF)

RUN 1 UnitsExpanded uncertainty (no O₂) - at 95% Confidence 147.08 % of ValueExpanded uncertainty (no O₂) - at 95% Confidence 2.81 % at ELVOverall Allowable uncertainty (no O₂) - at 95% Confidence 15.0

mg/m³Combined interference (from MCERTS Certificate) 0.04

mg/m³

Conversion 1.61

Dependence on voltage

mg/m³

mg/m³

% range

Losses in the line (leak) 0.00

Measurement uncertainty

0.56

0.50

Requirement for SRM is that Uncertainty should be <15% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 15% + the uncertainty associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.

-

N/A % of ValueRUN 1 Units

% at ELVResult of Compliance with Uncertainty Requirement in M2 COMPLIANT

0.20

mg/m³

Expanded uncertainty (with O₂) - at 95% Confidence

Result 0.38 mg/m³Combined uncertainty 0.29

RUN 1 Units

-Repeatability at zero 2.00

Range Used 100.0

Performance characteristics RUN 1mg/m³ (REF)

15.0

mg/m³

Performance characteristics

APPENDIX 2

Units20.0

Expanded uncertainty (with O₂) - at 95% Confidence N/A % at ELVOverall Allowable uncertainty (with O₂) - at 95% Confidence N/A % at ELVResult of Compliance with Uncertainty Requirement in M2 N/A -

160.6

RUN 1 UnitsStandard deviation of repeatability at zero

Lack of fit 0.01

mg/m³Lower of [A] or [B]

ppmRange Used [A]

TOTAL VOCs (as CARBON): MEASUREMENT UNCERTAINTY CALCULATIONS

RUN 1 UnitsResponse time 45

15.0 mg/m³Cal gas conc. 138.2

%0.38 mg/m³ (STP, dry)

Ambient temperature dependence

mg/m³Cal gas conc. 86.0 ppm

use rep at spanPerformance characteristic

ppm to mg/m³MCERTS Range [B] 15.0


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -


NOTE: Dilution performed to achieve correct span value





Date & Result of Last Converter Check 14/07/2015 - 96.8%


Zero Gas Type

Mass Emission

11.7±g/hr

Parameter

Span Gas Start Pressure (bar) 100

Gas Cylinder Concentration (ppm)

180°C

11.7

g/hr 85.0 85.0

1 / 1

174


Nitrogen (5 Grade)

7.4

174


2

A1

Span Gas Reference Number CYL 4.0142


Run 1

EN 14792

0.1µm Glass Fibre

Uncertainty


Value

Company XXXX,

412

Yes


Parameter Units Mean



Span Gas Uncertainty (%)

Sample Point I.D.'s

Filtration Type / Size

CAT-TP-21


Standard

Technical Procedure

APPENDIX 2

20/01/2019

OXIDES OF NITROGEN (as NO₂): RESULTS SUMMARY

Span Gas Type Nitrogen Monoxide


Company XXXX



PPC Permit: None


APPENDIX 2

OXIDES OF NITROGEN (as NO₂): DATA TREND

0.0

50.0

100.0

150.0

200.0

250.0

12:3

412

:37

12:4

012

:43

12:4

612

:49

12:5

212

:55

12:5

813

:01

13:0

413

:07

13:1

013

:13

13:1

613

:19

13:2

213

:25

13:2

813

:31

13:3

413

:37

13:4

013

:43

13:4

613

:49

13:5

213

:55

13:5

814

:01

14:0

414

:07

14:1

014

:13

14:1

614

:19

14:2

214

:25

14:2

814

:31

14:3

4

Conc

entr

atio

n (m

g/m

³)

Oxides of Nitrogen (as NO₂) At Reference Conditions

- Run 1


Company XXXX



PPC Permit: None

Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

Nature of Deviation

Zero Drift

Run Ambient Temperature Range °C

- Yes

Zero Down Sampling Line (Pre) ppm

Average Temperature °C 2.7


Allowable Temperature

0.10

Sampling Dates

Temperature Acceptable

Units

500

-

Zero Drift Acceptable -

ppm 0.70

Run 1

Run 1

Allowable Span Drift


Run Number

± ppm 8.53

Span Drift Acceptable - Yes

Allowable Zero Drift

ppmInstrument Range

Span Gas Value ppm

Span Down Sampling Line (Pre) ppm 172.6

Run 1

APPENDIX 2

OXIDES OF NITROGEN (as NO₂): SAMPLING DETAILS & QUALITY ASSURANCE

Parameter

171

CAL

1

Run 1

Zero Down Sampling Line (Post) ppm 0.80

CAL

1

Yes

23/07/2015

Conditioning Unit Temperature Units



15 - 18

Units

Span Down Sampling Line (Post) ppm 176.0

ppm 3.40

Units

Span Drift

4.0

± ppm 8.53

< °C


Company XXXX



PPC Permit: None

k =

APPENDIX 2

OXIDES OF NITROGEN (as NO₂): MEASUREMENT UNCERTAINTY CALCULATIONS

Performance characteristics RUN 1

%173.89

500.0

Units

Cal gas conc. 350.0 mg/m³Lower of [A] or [B] 125.0 mg/m³

Range Used

mg/m³ (REF)10.0

350.0

Performance characteristics RUN 1 Units

mg/m³ (STP, dry)5 %

ppmRange Used [A] 1026.1 mg/m³Cal gas conc. 170.5 ppmConversion 2.05 ppm to mg/m³MCERTS Range [B] 125.0 mg/m³

Ration NO / NO₂Measured concentrationTGN M2 Allowable MULimit value

secondsNumber of readings in measurement 120 -Repeatability at zero 0.40 % full scaleRepeatability at span level 0.40 % full scaleDeviation from linearity 0.53 % of valueZero drift 0.41 % full scaleSpan drift 1.97 % full scale

Response time 60

Volume or pressure flow dependence 0.40 % of full scaleAtmospheric pressure dependence 0.30 % of value/kPaAmbient temperature dependence 0.18 % full scale/10KCombined interference 0.60 % rangeDependence on voltage 0.40 % full scale/10V

96.8 %Converter efficiencyLosses in the line (leak) 0.00 % of valueUncertainty of calibration gas blending 1.40 % of valueUncertainty of calibration gas 2.00 % of value

Performance characteristic RUN 1 UnitsStandard deviation of repeatability at zero use rep at span mg/m³Standard deviation of repeatability at span level 0.04 mg/m³Lack of fit 0.38 mg/m³Drift 2.80 mg/m³Volume or pressure flow dependence 0.00 mg/m³Atmospheric pressure dependence 0.11 mg/m³Ambient temperature dependence 0.03 mg/m³Combined interference (from MCERTS Certificate) 0.43 mg/m³Dependence on voltage 0.05 mg/m³

0.16 mg/m³Converter efficiencyLosses in the line (leak) 0.00 mg/m³Uncertainty of calibration gas blending 1.41 mg/m³Uncertainty of calibration gas 2.01 mg/m³

RUN 1 UnitsMeasurement uncertainty Result 173.89 mg/m³Combined uncertainty 3.79 mg/m³Expanded uncertainty 1.96 7.44 mg/m³Uncertainty corrected to std conds. (O₂) 7.44 mg/m³ (REF)

Expanded uncertainty (with O₂) - at 95% Confidence N/A % at ELVOverall Allowable uncertainty (with O₂) - at 95% Confidence N/A % at ELVResult of Compliance with Uncertainty Requirement in M2 N/A -


RUN 1 UnitsExpanded uncertainty (no O₂) - at 95% Confidence 4.28 % of ValueExpanded uncertainty (no O₂) - at 95% Confidence 2.12 % at ELVOverall Allowable uncertainty (no O₂) - at 95% Confidence 10.0 % at ELVResult of Compliance with Uncertainty Requirement in M2 COMPLIANT -

RUN 1 UnitsExpanded uncertainty (with O₂) - at 95% Confidence N/A % of Value


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -

- -

- -








1.4


1 / 1


0.71

1.9

Gas Cylinder Concentration (ppm) 402.64

Span Gas Uncertainty (%) 2

Run 1

Mass Emission g/hr

APPENDIX 2


Parameter Units

Company XXXX,

Uncertainty

Concentration

Value

mg/m³ 3.8

Span Gas Reference Number CYL 2.0083

Sample Point I.D.'s


±g/hr

16/10/2018

Span Gas Start Pressure (bar) 140

Parameter


0.71

Mean

CARBON MONOXIDE: RESULTS SUMMARY


Filtration Type / Size 0.1µm Glass Fibre

Zero Gas Type

Yes

Heated Line Temperature 180°C

A1


Standard EN 15058

Nitrogen (5 Grade)

1.9

3.8

Span Gas Type Carbon Monoxide


Company XXXX



PPC Permit: None


CARBON MONOXIDE: DATA TREND

APPENDIX 2

0.0

2.0

4.0

6.0

8.0

10.0

12.0

14.0

16.0

18.0

20.0

12:3

412

:37

12:4

012

:43

12:4

612

:49

12:5

212

:55

12:5

813

:01

13:0

413

:07

13:1

013

:13

13:1

613

:19

13:2

213

:25

13:2

813

:31

13:3

413

:37

13:4

013

:43

13:4

613

:49

13:5

213

:55

13:5

814

:01

14:0

414

:07

14:1

014

:13

14:1

614

:19

14:2

214

:25

14:2

814

:31

14:3

4

Conc

entr

atio

n (m

g/m

³)

Carbon Monoxide At Reference Conditions

- Run 1


Company XXXX



PPC Permit: None

Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

Instrument Range ppm 200

ppm 80.0

YesSpan Drift Acceptable -


°C 15 - 18

Nature of Deviation

4.00

Zero Down Sampling Line (Post)

Conditioning Unit Temperature

-

Allowable Zero Drift ± ppm

Units

80.1

ppm 0.10


CAL

1

Zero Drift

Average Temperature

Allowable Temperature < °C 4.0

ppm -2.00

Span Down Sampling Line (Post)

Yes

Units

Sampling Times

ppm 78.0

Span Gas Value

APPENDIX 2

Zero Drift Acceptable -

ppm

12:34 - 14:34

Run 1

Yes

Units

Zero Down Sampling Line (Pre)

Span Drift

ppm

Allowable Span Drift ± ppm



Run Ambient Temperature Range

0.60

°C 2.7

Temperature Acceptable -

Test Conditions

4.00

Units Run 1

Run Number

CARBON MONOXIDE: SAMPLING DETAILS & QUALITY ASSURANCE

Parameter

Run 1

Run 1

CAL

1

Units Run 1

ppm

0.50


Company XXXX



PPC Permit: None

k =

Range Used 200.0 ppmRange Used [A] 249.8 mg/m³Cal gas conc. 80.1 ppmConversion 1.25 ppm to mg/m³

mg/m³Lower of [A] or [B] 95.0MCERTS Range [B] 95.0

mg/m³Cal gas conc. 100.0 mg/m³

APPENDIX 2

CARBON MONOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

Performance characteristics RUN 1 UnitsResponse time 60 secondsNumber of readings in measurement 120 -Repeatability at zero 0.40 % full scaleRepeatability at span level 0.40 % full scaleDeviation from linearity 0.24 % of valueZero drift 0.63 % full scaleSpan drift 0.00 % full scaleVolume or pressure flow dependence 0.40 % of full scaleAtmospheric pressure dependence 0.30 % of value/kPaAmbient temperature dependence 0.05 % full scale/10KCombined interference 0.73 % rangeDependence on voltage 0.40 % full scale/10VLosses in the line (leak) 0.12 % of valueUncertainty of calibration gas blending 1.40 % of valueUncertainty of calibration gas 2.00 % of value

Performance characteristic RUN 1 UnitsStandard deviation of repeatability at zero use rep at span mg/m³Standard deviation of repeatability at span level 0.04 mg/m³Lack of fit 0.13 mg/m³Drift 0.36 mg/m³Volume or pressure flow dependence 0.00 mg/m³Atmospheric pressure dependence 0.08 mg/m³Ambient temperature dependence 0.01 mg/m³Combined interference (from MCERTS Certificate) 0.40 mg/m³Dependence on voltage 0.05 mg/m³Losses in the line (leak) 0.00 mg/m³Uncertainty of calibration gas blending 0.03 mg/m³Uncertainty of calibration gas 0.04 mg/m³

RUN 1 UnitsMeasurement uncertainty Result 3.84 mg/m³Combined uncertainty 0.69 mg/m³Expanded uncertainty 1.96 1.35 mg/m³Uncertainty corrected to std conds. (O₂) 1.35 mg/m³ (REF)

% of ValueExpanded uncertainty (no O₂) - at 95% Confidence 1.35 % at ELVOverall Allowable uncertainty (no O₂) - at 95% Confidence 6.0 % at ELVResult of Compliance with Uncertainty Requirement in M2 COMPLIANT -

RUN 1 UnitsExpanded uncertainty (with O₂) - at 95% Confidence N/A % of Value

N/A % at ELVResult of Compliance with Uncertainty Requirement in M2 N/A -


Measured concentrationTGN M2 Allowable MULimit valuePerformance characteristics RUN 1 Units

100.0 mg/m³ (REF)6.0 %

3.84 mg/m³ (STP, dry)

RUN 1 UnitsExpanded uncertainty (no O₂) - at 95% Confidence 35.30

Expanded uncertainty (with O₂) - at 95% Confidence N/A % at ELVOverall Allowable uncertainty (with O₂) - at 95% Confidence


Company XXXX



PPC Permit: None

Sample Runs

- -

- -

- -





OXYGEN: RESULTS SUMMARY

0.1µm Glass Fibre

Heated Head Filter Used Yes

APPENDIX 2

180°C

Span Gas Reference Number

Units Run 1


10.3 10.3



CYL 11.0204

Concentration % v/v

Span Gas Uncertainty (%) 2

Zero Gas Type Nitrogen (5 Grade)



EN 14789



Filtration Type / Size

Parameter

Span Gas Expiry Date 31/12/2019

Span Gas Start Pressure (bar)

Value

Standard

Parameter

40

Gas Cylinder Concentration (% v/v) 20.88


Mean

Span Gas Type Synthetic Air (5 Grade)


Company XXXX



PPC Permit: None


APPENDIX 2

OXYGEN: DATA TREND

0.0

2.0

4.0

6.0

8.0

10.0

12.0

14.0

16.0

18.0

20.0

12:3

412

:37

12:4

012

:43

12:4

612

:49

12:5

212

:55

12:5

813

:01

13:0

413

:07

13:1

013

:13

13:1

613

:19

13:2

213

:25

13:2

813

:31

13:3

413

:37

13:4

013

:43

13:4

613

:49

13:5

213

:55

13:5

814

:01

14:0

414

:07

14:1

014

:13

14:1

614

:19

14:2

214

:25

14:2

814

:31

14:3

4

Conc

entr

atio

n (%

v/v

)

Oxygen Oxygen

- Run 1


Company XXXX



PPC Permit: None

Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

Run Number

% v/v 0.04

Allowable Zero Drift ± % v/v 0.45

Zero Drift

CAL

1



9.08

% v/v

% v/v



Span Down Sampling Line (Post) % v/v

Allowable Temperature < °C

Average Temperature °C 2.7

-

-

9.04

APPENDIX 2

OXYGEN: SAMPLING DETAILS & QUALITY ASSURANCE

Nature of Deviation

Zero Drift Acceptable

Allowable Span Drift ± % v/v 0.45

12:34 - 14:34


Sampling Times

Zero Down Sampling Line (Post) % v/v

% v/v 9.00

Temperature Acceptable - Yes

Span Drift Units

Conditioning Unit Temperature Units Run 1

Instrument Range % v/v 25

Span Gas Value

Run 1

0.10

Yes

Units Run 1

4.0

CAL

1

Zero Down Sampling Line (Pre) % v/v 0.02

Span Drift Acceptable - Yes


Run Ambient Temperature Range °C 15 - 18

0.08


Company XXXX



PPC Permit: None

k =

APPENDIX 2

OXYGEN: MEASUREMENT UNCERTAINTY CALCULATIONS

Performance characteristics RUN 1 Units

% of valueUncertainty of calibration gas

N/A %vol6.0 %

10.26 %volRange Used 25.0 %volCal gas conc. 20.9 %vol

Performance characteristics RUN 1 UnitsResponse time 60 secondsNumber of readings in measurement 120 -Repeatability at zero 0.04 % full scaleRepeatability at span level 0.04 % full scaleDeviation from linearity 0.05 % of value

% of value

Expanded uncertainty (no O₂) - at 95% Confidence 4.07 % of ValueResult of Compliance with Uncertainty Requirement in M2 COMPLIANT -

Requirement for SRM is that Uncertainty should be 0.5%vol absolute or 6% relative whichever is the lower, on a dry gas basis. Ref EA TGN M2.

Combined interference (from MCERTS Certificate) 0.08 %volDependence on voltage 0.00 %volLosses in the line (leak) 0.00 %volUncertainty of calibration gas 0.12 %vol

RUN 1 UnitsMeasurement uncertainty Result 10.26 %volCombined uncertainty

RUN 1 Units

0.21 %vol

Performance characteristic RUN 1 Units

Combined interference 0.56 % range

Measured concentrationTGN M2 Allowable MULimit value

Expanded uncertainty 1.96 0.42 %vol

Atmospheric pressure dependence 0.30 % of value/kPaAmbient temperature dependence

Zero drift 0.88 % full scaleSpan drift 0.44 % full scaleVolume or pressure flow dependence 0.20 % of full scale

-0.07 % full scale/10K

Dependence on voltage 0.02 % full scale/10VLosses in the line (leak) 0.00

Standard deviation of repeatability at zero use rep at span %volStandard deviation of repeatability at span level 0.00 %volLack of fit 0.01 %volDrift 0.13 %volVolume or pressure flow dependence 0.00 %volAtmospheric pressure dependence 0.02 %volAmbient temperature dependence -0.01 %vol


Company XXXX



PPC Permit: None

Date post:	26-Apr-2020
Category:	Documents
Upload:	others
View:	4 times
Download:	0 times

XXXX AB Incinerator Model XXX 2016 CAT-XXXX...Overall Aim of the Monitoring Campaign Special...

Documents