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The Holocene 23(8) 1105–1114 © The Author(s) 2013 Reprints and permissions: sagepub.co.uk/journalsPermissions.nav DOI: 10.1177/0959683613483619 hol.sagepub.com Introduction The ice core stable isotope records from Greenland (e.g. NGRIP Project Members, 2004) showed positive δ 18 O (ice) excursions as the Northern Hemisphere witnessed an average increase in tem- perature of c. 7°C during the transition from the Younger Dryas (YD) to Holocene (Alley et al., 1993). A number of proxy-based records indicate variations in both temperature and precipitation over the Holocene and relate them to changing solar insolation, latitudinal shifts in the average position of the Inter-Tropical Con- vergence Zone (ITCZ) (Haug et al., 2001; Kutzbach and Street- Perrott, 1985), varying activity of El-Niño Southern Oscillation (ENSO) (Conroy et al., 2008; Moy et al., 2002;) and fresh and cold water events in the North Atlantic (Bond et al., 1997). The early part of the Holocene (up to c. 6 cal. kyr BP) was associated with a thermal optimum when the Northern Hemisphere received more solar radiation during the summer months (Kutzbach and Street-Perrott, 1985). A stronger monsoonal circulation during this interval caused wet conditions in the drylands of Africa, Mid- dle East, India and North America. Gradual cooling during the late Holocene led to a weak monsoon and drying of these areas (Gasse, 2000; Street-Perrott et al., 1991). The drylands of northern Mexico are part of the Chihuahua Desert. The climatic and environmental information from the region over the Holocene comes from lacustrine sediments, speleo- thems and packrat middens (i.e. the Estancia Basin, Guadalupe Mountains, Playa Valley, San Bernardino Ciénega, Palomas Basin and palaeolakes Babicora and Encinillas, Figure 1a) present in the northern part of the desert (Asmerom et al., 2007; Brunelle et al., 2010; Castiglia and Fawcett, 2006; Chávez-Lara et al., 2012; Hol- mgren et al., 2003; Menking and Anderson, 2003; Metcalfe et al., 1997, 2002; Minckley et al., 2011; Roy et al., 2012a, 2012b). These proxy-based archives have associated the varying effective humidity with changing regimes of dominant summer as well as winter precipitation. For example, Minckley et al. (2011) related the change from a stream flow regime to a stable wetland at c. 7.2 cal. kyr BP at the San Bernardino Ciénega to more watershed soil moisture and higher groundwater levels as a result of an increase in winter precipitation. The dominance of grassland vegetation and an increase in the frequency of forest fires post c. 5.4 cal. kyr BP in the 483619HOL 23 8 10.1177/09596 83613483619The HoloceneRoy et al. 2013 1 Instituto de Geología, Universidad Nacional Autónoma de México, México 2 USAI, Facultad de Química, Universidad Nacional Autónoma de México, México 3 Instituto de Geofísica, Universidad Nacional Autónoma de México, México 4 University of Nottingham, UK 5 French Institute of Pondicherry, India Corresponding author: Priyadarsi D Roy, Instituto de Geología, Departamento de Geoquímica, Universidad Nacional Autónoma de México, Ciudad Universitaria, Del. Coyoacán, México D.F., 04510, México. Email: [email protected], [email protected] A record of Holocene summer-season palaeohydrological changes from the southern margin of Chihuahua Desert (Mexico) and possible forcings Priyadarsi D Roy, 1 Axel Rivero-Navarette, 1 Nayeli Lopez-Balbiaux, 2 Ligia L Pérez-Cruz, 3 Sarah E Metcalfe, 4 G Muthu Sankar 5 and Jose Luis Sánchez-Zavala 1 Abstract Proxy records of runoff, lake water salinity and aeolian activity, reconstructed by analyzing the concentrations of Ti, Ca and Zr/Ti in the sediments of palaeolake Las Cruces, provide information about millennial-scale summer season palaeohydrological changes at the southern margin of Chihuahua Desert over the last 8.4 cal. kyr BP. The data indicate generally higher-than-average runoff between c. 8.4 and 5 cal. kyr BP, correlative to the early Holocene Thermal Maximum. Except for the c. 2.2–2 cal. kyr BP humid event, runoff was lower than average over the last c. 5 cal. kyr BP. Latitudinal shifts in average position of the Inter-Tropical Convergence Zone (ITCZ) caused by long-term changes in summer insolation was the principal forcing behind the varying summer season precipitation and El Niño Southern Oscillation (ENSO) activity may explain some of the hydrological variability (e.g. higher-than-average summer precipitation during c. 2.2–2 cal. kyr BP). In general, the basin received more runoff during the periods of less frequent and weak ENSO, similar to the modern response to ENSO activity of the region. Significant increases in lake water salinity and aeolian activity over the last 2 cal. kyr BP correspond to stronger and more frequent ENSO during the late Holocene. Keywords Chihuahua Desert, forcing, geochemistry, Holocene, Mexico, palaeoclimate, summer precipitation Received 3 September 2012; revised manuscript accepted 19 February 2013 Research paper
Transcript

The Holocene

23(8) 1105 –1114

© The Author(s) 2013

Reprints and permissions:

sagepub.co.uk/journalsPermissions.nav

DOI: 10.1177/0959683613483619

hol.sagepub.com

IntroductionThe ice core stable isotope records from Greenland (e.g. NGRIP

Project Members, 2004) showed positive δ18O (ice) excursions as

the Northern Hemisphere witnessed an average increase in tem-

perature of c. 7°C during the transition from the Younger Dryas

(YD) to Holocene (Alley et al., 1993). A number of proxy-based

records indicate variations in both temperature and precipitation

over the Holocene and relate them to changing solar insolation,

latitudinal shifts in the average position of the Inter-Tropical Con-

vergence Zone (ITCZ) (Haug et al., 2001; Kutzbach and Street-

Perrott, 1985), varying activity of El-Niño Southern Oscillation

(ENSO) (Conroy et al., 2008; Moy et al., 2002;) and fresh and

cold water events in the North Atlantic (Bond et al., 1997). The

early part of the Holocene (up to c. 6 cal. kyr BP) was associated

with a thermal optimum when the Northern Hemisphere received

more solar radiation during the summer months (Kutzbach and

Street-Perrott, 1985). A stronger monsoonal circulation during

this interval caused wet conditions in the drylands of Africa, Mid-

dle East, India and North America. Gradual cooling during the

late Holocene led to a weak monsoon and drying of these areas

(Gasse, 2000; Street-Perrott et al., 1991).

The drylands of northern Mexico are part of the Chihuahua

Desert. The climatic and environmental information from the

region over the Holocene comes from lacustrine sediments, speleo-

thems and packrat middens (i.e. the Estancia Basin, Guadalupe

Mountains, Playa Valley, San Bernardino Ciénega, Palomas Basin

and palaeolakes Babicora and Encinillas, Figure 1a) present in the

northern part of the desert (Asmerom et al., 2007; Brunelle et al.,

2010; Castiglia and Fawcett, 2006; Chávez-Lara et al., 2012; Hol-

mgren et al., 2003; Menking and Anderson, 2003; Metcalfe

et al., 1997, 2002; Minckley et al., 2011; Roy et al., 2012a, 2012b).

These proxy-based archives have associated the varying effective

humidity with changing regimes of dominant summer as well as

winter precipitation. For example, Minckley et al. (2011) related

the change from a stream flow regime to a stable wetland at c. 7.2

cal. kyr BP at the San Bernardino Ciénega to more watershed soil

moisture and higher groundwater levels as a result of an increase in

winter precipitation. The dominance of grassland vegetation and an

increase in the frequency of forest fires post c. 5.4 cal. kyr BP in the

483619 HOL23810.1177/0959683613483619The HoloceneRoy et al.2013

1Instituto de Geología, Universidad Nacional Autónoma de México,

México2USAI, Facultad de Química, Universidad Nacional Autónoma de

México, México3Instituto de Geofísica, Universidad Nacional Autónoma de México,

México4University of Nottingham, UK5French Institute of Pondicherry, India

Corresponding author:

Priyadarsi D Roy, Instituto de Geología, Departamento de Geoquímica,

Universidad Nacional Autónoma de México, Ciudad Universitaria, Del.

Coyoacán, México D.F., 04510, México.

Email: [email protected], [email protected]

A record of Holocene summer-season

palaeohydrological changes from the

southern margin of Chihuahua Desert

(Mexico) and possible forcings

Priyadarsi D Roy,1 Axel Rivero-Navarette,1 Nayeli Lopez-Balbiaux,2

Ligia L Pérez-Cruz,3 Sarah E Metcalfe,4 G Muthu Sankar5 and

Jose Luis Sánchez-Zavala1

AbstractProxy records of runoff, lake water salinity and aeolian activity, reconstructed by analyzing the concentrations of Ti, Ca and Zr/Ti in the sediments of

palaeolake Las Cruces, provide information about millennial-scale summer season palaeohydrological changes at the southern margin of Chihuahua Desert

over the last 8.4 cal. kyr BP. The data indicate generally higher-than-average runoff between c. 8.4 and 5 cal. kyr BP, correlative to the early Holocene

Thermal Maximum. Except for the c. 2.2–2 cal. kyr BP humid event, runoff was lower than average over the last c. 5 cal. kyr BP. Latitudinal shifts in average

position of the Inter-Tropical Convergence Zone (ITCZ) caused by long-term changes in summer insolation was the principal forcing behind the varying

summer season precipitation and El Niño Southern Oscillation (ENSO) activity may explain some of the hydrological variability (e.g. higher-than-average

summer precipitation during c. 2.2–2 cal. kyr BP). In general, the basin received more runoff during the periods of less frequent and weak ENSO, similar to

the modern response to ENSO activity of the region. Significant increases in lake water salinity and aeolian activity over the last 2 cal. kyr BP correspond

to stronger and more frequent ENSO during the late Holocene.

KeywordsChihuahua Desert, forcing, geochemistry, Holocene, Mexico, palaeoclimate, summer precipitation

Received 3 September 2012; revised manuscript accepted 19 February 2013

Research paper

1106 The Holocene 23(8)

same location were attributed to less summer precipitation

(Brunelle et al., 2010). As the modern-day precipitation regimes in

the region are ENSO-modulated, Castiglia and Fawcett (2006)

associated the high lake stands identified in the Palomas Basin to an

increase in the magnitude and frequency of El Niño over the Holo-

cene. Menking and Anderson (2003) associated the mid-Holocene

droughts in the Estancia Basin to frequent La Niña events and

Asmerom et al. (2007) observed that the La Niña-like conditions

were frequent during intervals of higher solar activity.

Compared with the northern part of the Chihuahua Desert,

late-Quaternary records are absent from the central and southern

parts. In this paper, we present a new multiproxy record of Holo-

cene climatic variability from the southern margin. Geochemical

and mineral magnetic data from a new 226 cm long sediment

sequence from palaeolake Las Cruces were used to reconstruct

the millennial-scale hydrologic variability over the last 8.4 cal.

kyr BP. The proxy-based records of runoff, lake water salinity and

aeolian activity are compared with summer insolation at 20°N

(Huybers, 2006) and palaeo-archives that reflect shifts in the

average position of the ITCZ (Peterson and Haug, 2006) and

ENSO activity (Conroy et al., 2008; Moy et al., 2002) in order to

understand the possible forcing mechanisms.

Material and methods

Study site

The Chihuahua Desert spreads over at least five different states in

northern Mexico (Chihuahua, Coahuila, Durango, Zacatecas and

San Luis Potosi). Palaeolake Las Cruces is located at the southern

margin of the desert (22°39′20.2″N, 101°53′05.4″W; 2106 m

a.s.l., Figure 1a). This ephemeral and endorheic palaeolake is c. 2

km long and up to c. 0.8 km wide and is present in a NW–SE

trending tectonic basin (Figure 1b and c). The meteorological data

between AD 1977 and 2009 from a station located at c. 20 km

southeast of Las Cruces (Salinas de Hidalgo) recorded annual

rainfall varying between c. 130 and 1280 mm, with an average

annual precipitation of c. 380 mm (Source: CONAGUA, Mexico,

Figure 2a). An average 75% (c. 290 mm) of the precipitation

occurs during the summer months (May–September: average

temperature of 19–21°C), whereas the winter precipitation

(November–March: average temperature of 12–16°C) constitutes

less than 20% of the total.

In the modern era, enhanced subsidence over northern Mexico

and a southward shift in the ITCZ decrease summer rainfall and

cause drought conditions over most of Mexico during El Niño

years (Magaña and Quintanar, 1997; Magaña et al., 2003; Pavia et

al., 2006). Higher summer precipitation during La Niña years

results from a northward shift in the ITCZ, weaker subsidence

over the northern Mexico, a stronger monsoon and an increase in

the number of hurricanes in the Atlantic (Magaña et al., 2003).

This pattern is the opposite from that observed in the southwest-

ern USA and the extreme north and northwest of Mexico. In gen-

eral, the summer season rainfall (%) between AD 1977 and 2009

shows an inverse relationship with the Ocean Niño Index (ONI,

Source: National Weather Service, NOAA) (Figure 2b). Summer-

season precipitation contributed more than 85% of annual rainfall

Figure 1. Location of both continental and marine proxy records from the region (a). Palaeolake Las Cruces lying in a tectonic basin on the southern margin of the Chihuahua Desert (b), and the geology of the surroundings comprising Cretaceous, Tertiary and Quaternary volcanic and sedimentary rocks (c).

Roy et al. 1107

during the years of negative ONI indicative of La Niña condi-

tions (e.g. AD 1978, 1989–1990, 1995–1996, 1999–2000 and

2007–2008). During El Niño (positive ONI) years (e.g. AD 1982–

1983 and 1997–1998), summer precipitation decreased and com-

prised less than 50% of the annual precipitation.

The Las Cruces basin is surrounded by Cretaceous, Tertiary

and Quaternary volcanic as well as sedimentary rocks (Figure 1c).

Tertiary sandstone, polimictic conglomerate, rhyolite and rhyo-

litic tuff are the dominant rock types around the basin. Minor

exposures of Quaternary basalt and basaltic tuff are present in the

northern part of the basin, whereas Cretaceous andesite, sand-

stone and limestone are present in the southwestern part (Servicio

Geologico Mexicano, 2007).

Sampling and analysis

A number of pits were dug in the central and eastern parts of the

palaeolake Las Cruces during an expedition in May 2011 and

sampling was carried out in a pit from the central part of the

basin (Figure 1c). We restricted the sample collection to the

depth of 226 cm because of groundwater influx. The chronology

of the sedimentary sequence is based on four AMS 14C dates on

bulk organic matter present in the sediments collected at depths

of 17, 49, 81 and 221 cm. A total of 113 sediment samples were

collected continuously at an interval of 2 cm (i.e. 0–2 cm, 2–4

cm, 4–6 cm, etc.). All the samples were oven dried (40°C),

homogenised and ground with an agate pestle. Identification of

the minerals and their relative abundance were carried out in ten

bulk powdered samples collected at different depths using a Phil-

ips 1130/96 x-ray diffractometer (XRD).

The concentrations of total carbon (TC), total sulphur (TS)

and total nitrogen (TN) were measured in 23 samples (sampling

interval of 10 cm) in a Perkin Elmer Series II CHNS/O elemental

analyzer. The concentration of total organic carbon (TOC) was

measured in an elemental analyzer after removing the carbonates

by treating with 10% HCl. Total inorganic carbon (TIC) content

was calculated by subtracting the TOC from TC. Concentrations

of Ti, Fe, K, Ca and Zr were obtained in all 113 samples using a

Thermo Scientific handheld Niton XL3t x-ray fluorescence

(XRF) analyzer and corrected as per Roy et al. (2012a). The low

field magnetic susceptibility (K) was measured in all the samples

using a Bartington MSE High Resolution Surface Scanning Sen-

sor at a high spatial resolution (3.8 mm × 10.5 mm) at 2 kHz.

Results

Stratigraphy and mineralogy

The sediment column is divided into four different stratigraphic

units (Figure 3a). The mineralogical association and a qualitative

estimation of the relative abundance of each mineral in the differ-

ent stratigraphic units are presented by XRD diffractograms of

four different samples (Figure 3b). The basal unit IV (80–226 cm)

consists of massive brown-reddish silt with the presence of ran-

domly oriented gypsum lenses at some intervals. The gypsum

lenses are 5 to 10 cm long and partly developed into desert roses.

Quartz and gypsum are the most abundant minerals in this unit

and both are present in similar proportions. Halloysite, kaolinite

and calcite are present in trace amounts.

The overlying unit III (50–80 cm) comprises massive brown-

reddish silt and lacks gypsum lenses. However, randomly ori-

ented millimetre-scale evaporite crystals are visible in this unit.

Sediments of this unit contain abundant quartz, minor calcite and

gypsum, and trace amounts of halloysite and kaolinite. The sedi-

ments of unit II (18–50 cm) are massive calcareous grey silty-clay

with randomly oriented angular calcrete nodules (1–2 cm long).

Quartz is the most abundant mineral, followed by minor calcite

and gypsum. Plagioclase, halloysite and kaolinite are present in

trace amounts. The uppermost unit I (0–18 cm) consists of mas-

sive grey silty-sand with remnants of plant roots and vertical des-

iccation fissures (up to 5 cm long). Quartz and gypsum are the

most abundant minerals followed by calcite. Halloysite and

kaolinite are present in trace amounts. Trace amounts of magne-

tite are identified only in the sediments of units I and II.

Age model

The age model was constructed after calibrating the AMS 14C

dates using the IntCal 09 curve and Calib 6.0 program (Reimer et

al., 2009) (Table 1). The age versus depth diagram (Figure 4) was

generated by using the calibrated ages in the free software R (R

Development Core Team, 2009) and includes uncertainties

between 88 and 130 years between the tie points. The rate of sedi-

mentation (calculated between two consecutive dates) varies

between 0.009 and 0.073 cm/yr. Age of the samples present

between depths of 17 and 221 cm was estimated by interpolating

the sedimentation rates calculated between the consecutive 14C

dates. The base of the sediment column (226 cm) was assigned an

age of c. 8.4 cal. kyr BP by extrapolating the sediment rate calcu-

lated between sediments present at depths of 81 and 221 cm. As

the basin remains dry for an extended period during every year

and aeolian deflation causes erosion of the surface sediments, the

topmost part of the sampled sediment column may not represent

Figure 2. (a) Average monthly precipitation (dark bars) and temperature (dotted line) registered at the meteorological station located at Salinas de Hidalgo (see Figure 1b). (b) Comparison between summer season precipitation (solid line) and Ocean Niño Index (ONI, dotted line) during AD 1977–2009.

1108 The Holocene 23(8)

Figure 3. (a) Stratigraphy of the sediment core collected from Las Cruces and location of the four AMS 14C dates along the depth. (b) The mineralogical association and relative abundance of each mineral is presented by the XRD diffractograms.

kyr BP). The sediments representing the last c. 1 cal. kyr BP are

characterized by the highest TOC (1.0–1.3%).

Sediments show total nitrogen (TN) concentration of

0–0.2%. The relative dominance of terrestrial or lacustrine

plants on the bulk organic carbon is identified by the TOC/

TN (C/N) ratios (Meyers and Ishiwatari, 1995; Talbot and

Johannessen, 1992). Organic matter sourced from the aquatic

plants is characterized by C/N values <10 as nitrogen is

enriched in the cellulose lacking phytoplankton, whereas ter-

restrial plants with woody tissue and cellulose have lower

concentrations of nitrogen and their increasing dominance

results in higher C/N values. The sediments of Las Cruces

have C/N values between 1.6 and 30 (Figure 5). Higher C/N

values (17–30) are indicative of the greater influence of ter-

restrial plants on the organic matter deposited during c. 7.5–7

cal. kyr BP and lower values of C/N (<10) suggest that the

Table 1. Radiocarbon dates of the sediments collected at different depths from palaeolake Las Cruces, southern Chihuahua Desert.

Lab. code Sample code Depth (cm) AMS 14C age

(yr BP)

2-sigma range

(cal. yr BP)

Calibrated age

(cal. yr BP)

δ13C (‰)

Beta-321660 LC 16-18 17 1780±30 1614–1814 1714 −16.4

Beta-307213 LC 48-50 49 2140±30 2004–2302 2153 −15.6

Beta-301167 LC 80-82 81 4720±40 5323–5583 5453 −13.6

Beta-301168 LC 220-222 221 7470±40 8196–8372 8284 −22.2

the present day. Similarly, the occurrence of deflation events dur-

ing other drier intervals over the last 8.4 cal. kyr BP cannot be

ruled out. Within the limitations of this age model, we consider

that the sediments of stratigraphic unit I are representative of last

c. 1.7 cal. kyr BP. Sediments of unit II were deposited during c.

2.2–1.7 cal. kyr BP, unit III is constrained between c. 5.3 and 2.2

cal. kyr BP and the gypsum lenses present in unit IV were depos-

ited during c. 8.4–5.3 cal. kyr BP.

Organic carbon (TOC) and C/N

The total organic carbon (TOC) concentration varies between 0.1

and 1.3% (Figure 5): it remains homogeneous and low (0.1–0.3%)

in the lower part of the sediment profile (stratigraphic units III

and IV, c. 8.4–2.4 cal. kyr BP) and shows a gradual increasing

trend (0.5–1.3%) in the upper part (units II and I, last c. 2.4 cal.

Roy et al. 1109

organic matter was sourced dominantly from lacustrine algae

in the rest of the sequence.

Carbonate (CaCO3) and sulphate (CaSO4)

As calcite is the only carbonate mineral and gypsum is the only

sulphate mineral present in the sediments of Las Cruces, we

expressed total inorganic carbon (TIC) as calcite (CaCO3) and

total sulphur (TS) as gypsum (CaSO4) (Figure 5). The calcite con-

tent varies between 1.7 and 13.4% with higher values observed in

the sediments deposited during c. 4.5–3.5 cal. kyr BP (7.3–7.9%)

and over the last c. 2 cal. kyr BP (9.6–13.4%). In the rest of the

sediments, calcite shows an abundance of 1.7–5.7%. The gypsum

content fluctuates between 0 and 3% and higher values are

observed in the sediments of c. 8–6 cal. kyr BP (up to 3%), c. 2.5

cal. kyr BP (2.5%) and c. 1 cal. kyr BP (2.1%). The varying abun-

dance of calcite and gypsum suggests that the brine composition

changed between Ca-HCO3 and Ca-SO4 rich conditions through

time. Both Ca and HCO3 were derived from the weathering of

sandstone, limestone and volcanic rocks exposed in the catchment

of the basin, whereas SO4 could be partially from the bedrocks and

partially oceanic (Eugster and Hardie, 1978). The salt assemblage

indicates an inflow with composition of Ca>HCO3. After the cal-

cite precipitation, the subsequent brine evolution yielded precipi-

tation of Ca-bearing sulphate (gypsum) (Cohen, 2003). We do not,

however, have sufficient data resolution to make high-resolution

interpretations from the abundance of evaporite minerals.

Magnetic susceptibility

Magnetic susceptibility (K) of the sediments varies between 10.1 and

21.9×10−5 SI. Sediment of units I (16.7–21.9×10−5 SI) and II (19.4–

26.3×10−5 SI) show higher values compared with the sediments of

units III (10.1–16.5×10−5 SI) and IV (12.1–19.8×10−5 SI) (Figure 6).

Lower K values are associated with silt-dominated sediments with or

without gypsum lenses deposited during c. 8.4–2.2 cal. kyr BP.

Higher K values are associated with the silty-clay and silty-sand

dominated sediments deposited over the last c. 2.2 cal. kyr BP.

The abundance and type of magnetic minerals affect K-values

measured in the bulk sediments and the presence of ferromagnetic

minerals has a dominant influence over the diamagnetic and para-

magnetic minerals (Blanchet et al., 2007; Thompson and Old-

field, 1986; Urrutia-Fucugauchi, 1981; Urrutia-Fucugauchi et al.,

1997). Except for the trace amounts of ferromagnetic magnetite

identified in the sediments of units I and II, the sediments of the

palaeolake show a mineralogical assemblage dominated by dia-

magnetic quartz, calcite and gypsum. Paramagnetic halloysite and

kaolinite are present in trace amounts and their occurrence does

not show any significant variation in the sediment profile. Higher

K-values are observed with the sediments of stratigraphic units I

and II showing presence of magnetite.

Multi-element concentrations

The concentration of Ti varies between 0.18 and 0.30%, Fe fluc-

tuates between 1.8 and 3.0%, K varies from 2.0 to 3.0%, Ca

shows variation between 1.3 and 6.0% and Zr fluctuates between

146 and 235 ppm along the depth profile (Figure 6). The distribu-

tions of Ti, Fe and K are similar (R2=0.7–0.8) and Ca shows a

distribution opposite to Ti (R2= −0.8) and Fe (R2= −0.9). The dis-

tribution of Zr is similar to Ti (R2= −0.2) in some parts of the

profile and comparable with Ca (R2=0.4) in others.

Ti, Fe, K and Zr are present in the detrital minerals such as sili-

cates and oxides sourced from the erosion of rocks present in the

catchment of the basin. Higher sediment–water interaction during the

transportation of primary minerals and lower oxidation-reduction

potential (Eh) in the water column causes dissolution of a part of the

Fe and K present in the detrital minerals (Cohen, 2003; Mason and

Moore, 1982). The released Fe and K re-precipitate as secondary clay

minerals and authigenic carbonates and evaporites (Cohen, 2003).

The similar distribution of Ti, Fe and K suggests that the sediment–

water interaction was low and the basin did not have anoxic condi-

tion of deposition. The different distribution of Zr compared with Ti,

Fe and K could be due to the fact that different geomorphological

processes (i.e. pluvial and aeolian) were associated with the transpor-

tation of Ti, Fe and K-bearing and Zr-bearing minerals into the basin.

We present Zr/Ti as a proxy to demarcate the intervals with higher

influx of Zr-bearing minerals compared with Ti-bearing ones into the

basin (Figure 6). Abundance of Zr-bearing minerals is higher in the

sediments of the last c. 5 cal. kyr BP (stratigraphic units I, II and III)

compared with the sediments deposited during c. 8.4–5 cal. kyr BP

(stratigraphic unit IV) and the highest values are associated with the

sediments deposited over the last c. 2 cal. kyr BP.

The positive coefficient of correlation between Ca and TIC

(R2=0.8) suggests that higher Ca-values are associated with sedi-

ments with more calcite precipitation and represent intervals of

more saline lake water and arid conditions. The similar distribu-

tion of Zr/Ti and Ca (R2=0.8) suggests that the Zr-bearing miner-

als were deposited during arid intervals and hence transported

into the basin by aeolian processes. The negative coefficient of

correlation between Zr/Ti and Ti suggests that Ti, Fe and

K-bearing minerals were transported into the basin during humid

intervals by pluvial discharge (runoff). It is interesting to observe

that the magnetic susceptibility is comparable with Ti in some

parts of the sequence and similar to Zr/Ti and Ca in other parts

(Figure 6). This suggests that the magnetic minerals were trans-

ported both by pluvial and aeolian processes into the basin.

Discussion

Proxy interpretations and palaeohydrological

reconstructions

Over the last c. 8.4 cal. kyr BP, the variations in climatic condi-

tion at the southern margin of the Chihuahua Desert (palaeolake

Figure 4. Age model (age versus depth) created from the calibrated AMS 14C dates in the free software R (R Development Core Team, 2009). The age model has uncertainties of 88 to 130 years between the tie points.

1110 The Holocene 23(8)

Las Cruces) are documented using proxies for runoff, lake water

salinity and aeolian activity. The abundance of Ti-bearing min-

erals estimated from Ti concentration in the sediments of Las

Cruces is interpreted as a proxy for runoff of detrital minerals

into the basin and therefore an estimation of regional summer

precipitation. The intervals of higher Ti values reflect periods of

more summer rainfall and vice versa for intervals of lower Ti

values (e.g. Haug et al., 2001; Metcalfe et al., 2010; Roy et al.,

2012a, 2012b). The abundance of calcite (CaCO3) estimated

from the Ca concentration is interpreted as a proxy for carbonate

precipitation and therefore an estimation of lake water salinity.

The intervals of higher Ca values demarcate periods of higher

lake water salinity and vice versa. Similarly, Zr/Ti values

estimate the abundance of Zr-bearing minerals deposited in the

basin by aeolian processes and higher Zr/Ti values demarcate

the periods with enhanced aeolian activity in the basin surround-

ings. Magnetic susceptibility is considered as a proxy to identify

the intervals of higher influx of magnetic minerals into the basin

both by pluvial and aeolian processes. The proxy records are

standardized (e.g. Kirby et al., 2010) by subtracting the mean

value and dividing by the standard deviation of the distribution

from the measured proxy value in order to document the inter-

vals with hydrological conditions different from the average of

last c. 8.4 cal. kyr BP (Figure 7). For example, positive Ti excur-

sions represent periods of higher than the average runoff and

vice versa.

Figure 5. Concentrations of total organic carbon (TOC), C/N, CaCO3 and CaSO4 in the sediments against depth (cm) and age (cal. kyr BP) (for the stratigraphic description see Figure 3).

Figure 6. Distribution of magnetic susceptibility (K) and concentrations of Ti, Fe, Zr, Ca and Zr/Ti against depth (cm) and age (cal. kyr BP) in the sediments of palaeolake Las Cruces (for the stratigraphic description see Figure 3).

Roy et al. 1111

Characterized by millennial-scale variations, the sediments

between 226 and 75 cm have generally average and higher than aver-

age Ti concentrations and represent an interval of higher runoff into

the basin during c. 8.4–5 cal. kyr BP. This interval of more than aver-

age summer rainfall is contemporary to the Holocene Thermal Maxi-

mum (Haug et al., 2001). The palaeohydrological variations during

this interval are reflected by gypsum precipitation at certain depths as

intervals of lower rainfall and increasing salinity and evaporation.

Lower than average runoff are identified at c. 7.5 (183–187 cm), 7

(147–150 cm) and 6.2–6 (111–123 cm) cal. kyr BP. The positive val-

ues of standardized Ca indicate that lake water salinity was higher

than average at c. 7 cal. kyr BP and c. 6.2–6 cal. kyr BP. Similarly, the

average to lower than average Zr/Ti mirrors the weak aeolian activity

in the surroundings of Las Cruces during the entire interval.

Except for the c. 2.2–2 cal. kyr BP interval, the sediments

deposited over the last c. 5 cal. kyr BP (75–0 cm) have lower than

average Ti and represent a period of lower than average summer

precipitation (Figure 7). However, the runoff into the basin was

relatively higher and the lake water salinity lower between c. 5

and 2.3 cal. kyr BP compared with the last 2 cal. kyr BP. This is

suggested by the relatively higher Ti and lower Ca in the sedi-

ments at depths of 75–50 cm compared with 30–0 cm. The abun-

dance of calcite is also lower between c. 4.5 and 3.5 cal. kyr BP

compared with the last c. 2 cal. kyr BP. Transportation of Zr-bearing

minerals into the basin by aeolian processes increased post c. 5

cal. kyr BP. The dominant aeolian activity over the last 2 cal. kyr

BP corresponds to an interval of lowest runoff (i.e. Ti) and highest

calcite abundance (i.e. Ca) (Figure 7). An abrupt increase in Ti at

depths between 50 and 33 cm suggests higher-than-average sum-

mer precipitation during c. 2.2–2 cal. kyr BP. During this event,

increased runoff transported magnetic minerals into the basin and

the dilute lake water precipitated less than average calcite.

Possible forcing mechanisms

We compared the runoff record of Las Cruces with summer inso-

lation variation at 20°N (Huybers, 2006) and palaeorecords of

latitudinal shifts in the position of ITCZ (Peterson and Haug,

2006) and ENSO activity (Conroy et al., 2008; Moy et al., 2002)

in order to understand the possible forcing mechanisms (Figure 8).

Palaeoreconstructions suggest higher summer precipitation in the

Northern Hemisphere during the intervals of solar insolation

modulated northward ITCZ and vice versa (Haug et al., 2001;

Hodell et al., 1991). Based on Ti concentrations in sediments of

the Cariaco Basin (Figure 1a), Haug et al. (2001) and Peterson

and Haug (2006) reported a northward shift in the mean position

of ITCZ between c. 10.5 and 5.4 cal. kyr BP and a gradual south-

ward shift with millennial-scale fluctuations post c. 5.4 cal. kyr

BP (Figure 8). The proxy record of runoff from Las Cruces shows

a first order positive relationship with the position of the Inter-

Tropical Convergence Zone (ITCZ) and summer insolation. Gen-

erally higher than average runoff (c. 8.4–5 cal. kyr BP) occurred

during the interval of higher summer insolation and northerly

ITCZ. Except for the c. 2.2–2 cal. kyr BP event, the lower than

average runoff over the last c. 5 cal. kyr BP is similar to the grad-

ual reduction in summer insolation and southerly shifting of ITCZ

over the middle and late Holocene. This suggests that the summer

season precipitation at the southern margin of the Chihuahua Des-

ert over the Holocene was mainly controlled by the summer inso-

lation driven latitudinal shifts in the average position of ITCZ.

In order to explain the higher-than-average summer precipita-

tion during c. 2.2–2 cal. kyr BP and observe the influence of ENSO

on the precipitation variation in the southern Chihuahua Desert, we

compared the proxy runoff record with the palaeo-ENSO archives

of Moy et al. (2002) and Conroy et al. (2008) (Figure 8). The pal-

aeo-ENSO records were obtained from the inorganic clastic

Figure 7. Standardized proxy records indicating variations in clastic input (K), runoff into the basin (Ti), lake water salinity (Ca) and aeolian activity (Zr/Ti) over the last c. 8.4 cal. kyr BP. The positive values indicate more than average and vice versa.

1112 The Holocene 23(8)

laminae in a sediment core from Laguna Pallcacocha (southern

Ecuador, Figure 1a) and sand content in another sediment core

from the El Junco Crater Lake (Galápagos Islands). The Laguna

Pallcacocha record documents millennial-scale moderate-to-strong

El Niño events. It records the first statistically significant ENSO

activity at c. 7 cal. kyr BP and maximum ENSO frequency at c. 1.2

cal. kyr BP (Moy et al., 2002). The record from the El Junco Crater

Lake indicates an increase in the frequency and magnitude of

Figure 8. Comparison of the runoff (precipitation) record at Las Cruces (a) with palaeo-archives indicating latitudinal shift in the mean position of ITCZ (b, Peterson and Haug, 2006), summer insolation at 20°N (c, Huybers, 2006), palaeo-ENSO archives obtained from Laguna Pallcacocha (d, Moy et al., 2002) and El Junco Crater Lake (e, Conroy et al., 2008).

Figure 9. Comparison of the proxy record of summer precipitation in the southern Chihuahua Desert with other regional continental (Babicora: Roy et al. (2012a); San Bernardino Ciénega: Brunelle et al. (2010); Yuma: Bacon et al. (2010); Guadalupe Mountains: Asmerom et al. (2007); and Estancia Basin: Menking and Anderson (2003)) and marine records from the Gulf of California (Gonzalez-Yajimovich et al., 2005; Pérez-Cruz, 2012) and Gulf of Mexico (Poore et al., 2004).

Roy et al. 1113

ENSO after c. 4.2 cal. kyr BP and highest ENSO variance during

2–1.5 cal. kyr BP (Conroy et al., 2008). Despite the discrepancies,

both the records suggest weak or non-existent ENSO during the

early part of the middle Holocene and an increase in ENSO fre-

quency and amplitude over the late Holocene. The runoff record of

palaeolake Las Cruces shows a first-order negative correlation with

the palaeo-ENSO archive obtained from Laguna Pallcacocha.

More than average runoff during c. 8.4–5 cal. kyr BP and c. 2.2–2

cal. kyr BP corresponds to the intervals of weak or non-existent

moderate-to-strong ENSO. Less than average runoff between c. 5

and 2.3 cal. kyr BP occurred during an interval of gradual increase

in the frequency of El Niño. Arid conditions with the lowest sum-

mer precipitation over the last c. 2 cal. kyr BP coincide with the

period of highest ENSO frequency and amplitude towards the late

Holocene (i.e. dominant El Niño state). The inverse relationship

between the proxy records of summer precipitation in the southern

Chihuahua Desert and ENSO activity suggests that the ENSO forc-

ing on regional precipitation was present throughout the

Holocene.

Comparison with regional records

Figure 9 compares the Las Cruces record with both continental

and marine palaeoclimatic archives from the region (see Figure

1a for locations). Higher summer precipitation over the early part

of the middle Holocene and its gradual decrease over the middle

to late Holocene are registered in marine sediments from the Gulf

of Mexico and Gulf of California (Gonzalez-Yajimovich et al.,

2005; Pérez-Cruz, 2012; Poore et al., 2004, 2005). Based on the

planktonic foraminifer G. sacculifer in cores from the Gulf of

Mexico, Poore et al. (2005) suggested an enhanced North Ameri-

can Monsoon during c. 7–4.7 cal. kyr BP and severe multicentury

drought centered at c. 1.6 cal. kyr BP. Similarly, the mass accumu-

lation rate and terrigenous input in the Alfonso Basin located in

the southern Gulf of California also indicate gradually reducing

summer precipitation as a result of solar insolation controlled

southward movement of ITCZ over the last 6 cal. kyr BP (Gonza-

lez-Yajimovich et al., 2005; Pérez-Cruz, 2012). We observe

remarkable similarity between the palaeohydrological conditions

at Las Cruces and the forest fire record obtained from the domi-

nantly summer precipitation-fed San Bernardino Ciénega located

in southeastern Arizona and northern Sonora (Brunelle et al.,

2010). The rare fire occurrence between c. 8.1 and 5.3 cal. kyr BP

was related to higher regional summer precipitation and the

increase in forest fire frequency post c. 5.3 cal. kyr BP was associ-

ated with higher winter-precipitation taxa. The interval of more-

than-average summer precipitation at Las Cruces during c. 2.2–2

cal. kyr BP is contemporary with the high magnitude flooding

events occurring between c. 2.4 and 1.1 cal. kyr BP at the San

Bernardino Ciénega. Similarly, the events of lower precipitation

at c. 7.5, 3 and 1 cal. kyr BP are contemporary to the drought

conditions/desiccations observed at palaeolake Babicora (north-

ern Mexico) (Chávez-Lara et al., 2012; Roy et al., 2012a).

The proxy records indicating variations in regional winter pre-

cipitation are in contrast to the observations from Las Cruces

(Figure 9). For example, Menking and Anderson (2003) reported

drought conditions at the Estancia Basin between c. 7 and 5 cal.

kyr BP and related those to a La Niña-like state. Bacon et al.

(2010) observed 900 years of alluvial aggradation during c. 3.2–

2.3 cal. kyr BP near Yuma (southwestern Arizona). A centennial-

scale speleothem record from the Guadalupe Mountains (New

Mexico) recorded less winter precipitation during c. 8–7 cal. kyr

BP and at c. 2.2–2 cal. kyr BP (Asmerom et al., 2007). The contri-

bution of winter moisture to mean annual precipitation increased

over the late Holocene (i.e. at c. 3.3 and c. 2.7 cal. kyr BP).

Although the records are of different resolutions, the c. 6.2–6 cal.

kyr BP event is registered both at Las Cruces (lower summer pre-

cipitation) and Guadalupe Mountains (higher winter moisture).

ConclusionsHigh resolution proxy-based palaeoclimatic records are scarce in

the central and southern parts of the Chihuahua Desert. Poor pres-

ervation of biological indicators and the presence of hiatuses in

the sediment sequences are some of the major obstructions to the

reconstruction of Holocene climate of the region. We provide use-

ful information about the summer season palaeohydrological con-

ditions over the last 8.4 cal. kyr BP at the southern margin of the

Chihuahua Desert by studying multi-element concentrations and

magnetic susceptibility of sediments from palaeolake Las Cruces.

Our main conclusions can be summarized as:

• Variation in summer season precipitation at the southern

margin of Chihuahua Desert is mainly driven by long-

term changes in solar insolation and associated latitudinal

shifts in the average position of ITCZ and ENSO activity.• Higher-than-average summer season precipitation between

c. 8.4 and 5 cal. kyr BP occurred during an interval of

northerly ITCZ and weak to non-existent ENSO.• Over the last c. 5 cal. kyr BP, the lower-than-average summer

precipitation was caused by southward movement of the

average position of ITCZ and increasing ENSO activity.• Higher summer precipitation during c. 2.2–2 cal. kyr BP is

contemporary to an interval of weak or non-existence of

moderate to strong ENSO. However, it is interesting that

the event is observed only in the continental records from

the region and not in the marine sediments.

Acknowledgements

We are thankful to the staffs of Presidencia Municipal and Casa de

Cultura of Salinas de Hidalgo (SLP) for their help during the sam-

pling expeditions. The critical comments and observations of both

anonymous reviewers are gratefully acknowledged. Technical as-

sistance was provided by Marcela Patricia Charles-Polo, Rufino

Lozano Santacruz, Victor Lemus and Susana Sosa-Najera.

Funding

The data presented in this paper were generated with financial

support from the Papiit-UNAM project (IN100413) to PDR.

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