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Located at: 2002 North Orient Road Tampa, Florida 33619

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Universal Waste & T r a n s i t O r ient Road

Tampa, F l o r i d a

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MASTER INDEX

CHAPTER 1: Introduction Tab A

CHAPTER 2: General Safety Manual Tab B

CHAPTER 3: Protective Clothing Guide Tab C

CHAPTER 4: Respiratory Training Program Tab D

APPENDIX 1: Respiratory Training Program I I Tab E

CHAPTER 5: Basic Emergency Training Guide Tab F

CHAPTER 6: F a c i l i t y Operations Manual Tab G

CHAPTER 7: Land Ban C e r t i f i c a t e s Tab H

CHAPTER 8: Employee C e r t i f i c a t i o n Statement Tab. I

CHAPTER ONE

INTRODUCTION

prepared by

Universal Waste & Transit

Orient Road

Tampa Florida

Introducti on STORAGE/TREATMENT PERSONNEL TRAINING PROGRAM A l l personnel i n v o l v e d i n any handling, t r a n s p o r t a t i o n , storage or treatment of hazardous wastes are re q u i r e d to s t a r t the enclosed t r a i n i n g program w i t h i n one-week a f t e r the i n i t i a t i o n of employment at Universal Waste & T r a n s i t . This t r a i n i n g program includes the f o l l o w i n g :

Safety Equipment Personnel P r o t e c t i v e Equipment F i r s t Aid & CPR Waste Handling Procedures Release Prevention & Response Decontamination Procedures F a c i l i t y Operations F a c i l i t y Maintenance T r a n s p o r t a t i o n Requirements Recordkeeping

We h i g h l y recommend t h a t a l l personnel i n v o l v e d i n the han d l i n g , t r a n s p o r t a t i o n , storage or treatment of hazardous wastes a c t i v e l y pursue a d d i t i o n a l t e c h n i c a l courses at e i t h e r the U n i v e r s i t y of South F l o r i d a , or Tampa Junior College. Recommended courses would i n c l u d e general chemistry; a n a l y t i c a l chemistry; environmental chemistry; t o x i c o l o g y ; and a d d i t i o n a l s a f e t y and h e a l t h r e l a t e d t o p i c s . Universal Waste & T r a n s i t w i l l pay a l l r e g i s t r a t i o n , t u i t i o n and book fees f o r any courses which are job r e l a t e d . The only requirement i s the successful completion of t h a t course. T r a i n i n g and r e l a t e d items are handled by the Universal Waste & T r a n s i t t r a i n i n g o f f i c e r , Mr. Paul S g r i c c i a , P. E.

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Pre-Employment Screening A l l p o t e n t i a l employees at Universal Waste & T r a n s i t are c a r e f u l l y screened p r i o r t o h i r i n g . This i n c l u d e s :

- i n depth i n t e r v i e w s - academic and experience requirements - medical e v a l u a t i o n

A l l p o t e n t i a l employees are informed t h a t they w i l l working w i t h hazardous or p o t e n t i a l l y hazardous m a t e r i a l s . A l l p o t e n t i a l employees w i l l v i s i t the f a c i l i t y t o determine " f i r s t hand" what the working environment e n t a i l s . A l l p o t e n t i a l employees are informed t h a t any sa f e t y v i o l a t i o n or improper handling of waste m a t e r i a l s / c o n t a i n e r s w i l l r e s u l t i n immediate d i s m i s s a l .

A l i s t of job r e l a t e d p r e r e q u i s i t e s i s i n d i c a t e d i n Table 1.

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TYPES OF TRAINING Four types of t r a i n i n g are employed at Un i v e r s a l Waste & T r a n s i t .

These are 1. A formal t r a i n i n g course f o r a l l new employees which

encompasses the areas p r e v i o u s l y mentioned. This course i s culminated by an examination at the end of the course. A review of a l l f o r m a l i z e d courses i s performed annually.

2. An i n f o r m a l weekly s a f e t y meeting d u r i n g which time new s a f e t y apparatus are discussed or t r a i n i n g f i l m s / s l i d e p r e s e n t a t i o n s are viewed. A l t e r n a t i v e t o t h i s are discussions on waste handling procedures; s i t e cleanup work; emergency response etc.

3 Attendance at commercially a v a i l a b l e s a f e t y or preparedness classes. Examples i n c l u d e : J.T. Baker's "Management and Disposal of Hazardous Chemical Wastes" or Safety Systems Inc. "Disaster Control School". These are both a v a i l a b l e w i t h i n the State of F l o r i d a . A l l s upervisory personnel must at t e n d these schools, or s i m i l a r classes.

4. An ongoing on-the-job t r a i n i n g program which a s s i s t s new employees i n f a m i l i a r i z i n g themselves w i t h the e x i s t i n g working c o n d i t i o n s and company p o l i c y . Also a v a i l a b l e to a l l employees i s a w e l l equipped t e c h n i c a l l i b r a r y .

I f an employee i s not kept w e l l informed of the company's a c t i v i t i e s he q u i c k l y loses i n t e r e s t and p r i d e i n his/her work. I n the area of hazardous waste management t h i s s i t u a t i o n cannot be t o l e r a t e d . Therefore, i t i s also company p o l i c y at Universal Waste & T r a n s i t t o have a weekly meeting t o discuss what work i s i n progress; what new jobs are a n t i c i p a t e d and to determine what questions or recommendations employees may have t o operate more e f f i c i e n t l y or s a f e l y .

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TRAINING PROGRAMS Contained w i t h i n are t r a i n i n g documents which are used i n c o n j u n c t i o n w i t h the formal t r a i n i n g program. A l l new employees are given copies of the f o l l o w i n g :

- General Safety Manual - Protective Clothing Guide - Respiratory Training Program - Basic Emergency Training Guide - F a c i l i t y Contingency Plan - Pocket Guide to Hazardous Materials - NIOSH Worker Safety B u l l e t i n f o r Hazardous Waste S i t e s

Each document i s reviewed w i t h the employee by the Universal Waste & T r a n s i t s a f e t y o f f i c e r . A l l p e r t i n e n t s a f e t y equipment usage i s discussed. This i n c l u d e s : r e s p i r a t o r s ; SCBA; ac i d s u i t s ; encapsulation s u i t s ; f i r e e x t i n g u i s h e r s & hose; evacuation horns and m a t e r i a l handling equipment. Each employee i s assigned t h e i r own r e s p i r a t o r and f i t t e s t e d as req u i r e d . Cleaning and maintenance of the r e s p i r a t o r i s explained. The l o c a t i o n s and usage of a l l s a f e t y and emergency response equipment i s d e t a i l e d .

A l l new employees are immediately informed as t o the procedures i n v o l v e d i n any s p i l l or release at the f a c i l i t y . This i n c l u d e s :

- employee warning s i g n a l s - agencies to contact - evacuation routes - response ac t i o n s

F i n a l l y each new employee i s shown how drums are inspected; opened; sampled; sealed; l a b e l e d ; moved; and the recordkeeping requirements. Upon completion of the t r a i n i n g program both an o r a l and w r i t t e n examination are r e q u i r e d . An annual review of a l l t r a i n i n g programs i s performed. Appended to t h i s are each of the t r a i n i n g documents p r e v i o u s l y described.

•6-

T i t l e

TABLE I Universal Waste & T r a n s i t

Job D e s c r i p t i o n P r e r e q u i s i t e s

F a c i l i t y Manager Masters degree i n ph y s i c a l science and two years experience i n waste management or four years experience i n waste management w i t h bachelors degree i n l i e u of masters degree. T r a f f i c Manager Bachelors degree i n ph y s i c a l science; engineering. F a c i l i t y Chemist Bachelors degree i n chemistry w i t h two years experience i n the waste management area. Hazardous Waste Technician Bachelors degree or associate degree i n environmental technology and one year experience i n waste management f i e l d or three years experience i n l i e u of degree. Emergency Response Crew Same as above a minimum. S i t e Cleanup Supervisor Bachelors degree p r e f e r r e d , associate degree accepted w i t h c o n s t r u c t i o n background. A n a l y t i c a l Technician Associates degree i n environmental technology or r e l a t e d d i s c i p l i n e . Waste Handling Technician Associates degree p r e f e r r e d , high school diploma r e q u i r e d w i t h in-house t r a i n i n g mandatory.

CHAPTER TWO

T r a i n i n g Manual No. 1 GENERAL SAFETY MANUAL

prepared by

Unive r s a l Waste & T r a n s i t

O r ient Road

Tampa F l o r i d a

CONTENTS

The Hazards You Face Ways You Can Be Exposed To Waste Hazards How To Protect Yourself Against These Hazards Work Safely Personal Protective Equipment Protective Clothing Splash Suits and Associated Clothing Fu l l y Encapsulating Suits Respirators A i r - P u r i f y i n g Respirators Atmosphere Supplying Respirators Respirator Usage Mechanical Equipment Safety Heat Stress Contamination/Decontamination Emergency Information Emergency Procedures Medical Surveillance Programs Health and Safety Programs

CHAPTER THREE

T r a i n i n g Manual No. 2

PROTECTIVE CLOTHING GUIDE

prepared by Universal Waste & T r a n s i t

O r ient Road Tampa, F l o r i d a

CONTENTS

Dress For the Occasion P r o t e c t i v e Suits Splash Suits P r o x i m i t y Suits Hand P r o t e c t i o n Eye/Face P r o t e c t i o n

Questions To Ask Yourself

Attachment 1 Level A P r o t e c t i o n Level B P r o t e c t i o n Level C P r o t e c t i o n Level D P r o t e c t i o n

Attachment 2 P r o t e c t i v e C l o t h i n g C o m p a t i b i l i t y w i t h Selected Chemical Hazards

Dress For The Occasion In order to determine what p r o t e c t i v e equipment i s r e q u i r e d f o r a c e r t a i n s i t u a t i o n you must ask y o u r s e l f or your supervisor a number of questions. These are:

1. What are the s p e c i f i c job hazards? 2. Is the contaminant a dust, m i s t , fume, vapor, gas, l i q u i d or

s o l i d ? 3. I s the s i t u a t i o n c l a s s i f i e d as immediately dangerous t o l i f e

and h e a l t h (IDLH)? 4. Is the need f o r f1ame-retardant equipment necessary? 5. Is the atmosphere oxygen d e f i c i e n t ? 6. Is the m a t e r i a l r e a d i l y absorbed through the s k i n or does i t

i r r i t a t e the eyes, nose or t h r o a t ? 7. W i l l the exposure be casual or d i r e c t ? 8. W i l l the exposure be sh o r t - t e r m or prolonged? 9. I s temperature or c l i m a t i c c o n d i t i o n s a consid e r a t i o n ?

10. W i l l s u f f i c i e n t back-up personnel be a v a i l a b l e t o a s s i s t me i n an emergency s i t u a t i o n ?

Answers to a l l of these items are necessary before an educated d e c i s i o n as to the amount and type of personnel p r o t e c t i v e equipment r e q u i r e d can be made. Remember, there are only three routes by which you can be exposed t o p o t e n t i a l hazards:

I n h a l a t i o n I n g e s t i o n Skin Contact

Be sure you take the necessary steps to reduce your p o t e n t i a l exposure. The p r o t e c t i v e c l o t h i n g r e q u i r e d , as w i t h r e s p i r a t o r s , v a r i e s dependent upon the immediate s i t u a t i o n . (See Attachment 1^ P r o t e c t i v e c l o t h i n g c o n s i s t s of s u i t s ; gloves; boots, eye/face p r o t e c t i o n ; g a u n t l e t s ; and so on. There are p r e s e n t l y many types, designs and s t y l e s of these items and the choice must be based upon the ma t e r i a l s which you a n t i c i p a t e encountering. (See Attachment 2)

t P r o t e c t i v e S u i t s

P r o t e c t i v e s u i t s f a l l i n t o f o u r general c a t e g o r i e s Splash s u i t s - disposable Splash s u i t s - reusable P r o x i m i t y s u i t s - f i r e P r o x i m i t y s u i t s - chemical

t

S

Splash Suits

Splash s u i t s are employed i n s i t u a t i o n s not immediately dangerous t o l i f e and h e a l t h . These s u i t s g e n e r a l l y c o n s i s t of coated c o t t o n or paper (disposable) or chemically r e s i s t a n t p o l y v i n y l c h l o r i d e (PVC) which i s reusable. The disposable s u i t s are e f f e c t i v e when working i n areas of low l e v e l contamination or i n areas which may r e q u i r e only minimum p r o t e c t i v e equipment. PVC s u i t s provide adequate p r o t e c t i o n f o r many acids; a l k a l i s ; o i l s ; and alcohols but a f f o r d only minimal p r o t e c t i o n i n areas immediately dangerous t o l i f e and h e a l t h . Both the disposable and reusable s u i t s can cause s u b s t a n t i a l heat s t r e s s i n warm envi ronments.

Proximity Suits

P r o x i m i t y s u i t s are f u l l - b o d y s u i t s which provide high l e v e l s of worker p r o t e c t i o n . The f i r e f i g h t i n g p r o x i m i t y s u i t i s g e n e r a l l y manufactured of aluminized nomex or aluminized rayon and provide up t o 90% r e f l e c t i v i t y of r a d i a n t heat. The chemical p r o x i m i t y s u i t s are g e n e r a l l y manufactured of PVC; coated PVC, or s y n t h e t i c or rubber compounds. Once again, c e r t a i n solvents can a t t a c k these m a t e r i a l s and shorten t h e i r u s e f u l l i f e expectancy.

Proximity s u i t s are g e n e r a l l y used i n c o n j u n c t i o n w i t h e i t h e r a i r l i n e r e s p i r a t o r s or s e l f contained b r e a t h i n g apparatus. Many are equipped w i t h a i r c o n d i t i o n i n g type systems which reduce the heat s t r e s s associated w i t h splash s u i t s . A l l p r o x i m i t y s u i t s are designed t o cover the worker from head to toe i n a f u l l y encapsulated environment. Your ease of m o b i l i t y i s s u b s t a n t i a l l y r e s t r i c t e d when using a p r o x i m i t y s u i t , e s p e c i a l l y one which i s employing an a i r - l i n e r e s p i r a t o r . You should be f u l l y f a m i l i a r w i t h the use and op e r a t i o n of a p r o x i m i t y s u i t before use. Workers have experienced cla u s t r o p h o b i a when confined i n a p r o x i m i t y s u i t and you should be aware of your l i m i t a t i o n s i n t h i s area. You should r e g u l a r l y p r a c t i c e various tasks i n these s u i t s t o determine your l i m i t a t i o n s .

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Hand P r o t e c t i o n I n order t o p r o t e c t your hands, w r i s t s and forearms, gloves are r e q u i r e d which meet the demand of your work s i t u a t i o n . I f splash s u i t s are employed, s u i t a b l e gloves must be chosen depending upon the m a t e r i a l which i s to be handled. Chemically r e s i s t a n t gloves are manufactured g e n e r a l l y of the f o l l o w i n g m a t e r i a l s :

P o l y v i n y l c h l o r i d e (PVC) Neoprene Natural rubber P o l y v i n y l alcohol N i t r i 1 e

The choice of glove m a t e r i a l i s h i g h l y dependent upon the items which w i l l be encountered. Table 1 l i s t s various glove m a t e r i a l and t h e i r r e s i s t a n c e to a number of chemical compounds. Some p r o x i m i t y s u i t s are already equipped w i t h gloves attached. Determine what these gloves are manufactured from and i f they are s u i t a b l e f o r your p a r t i c u l a r s i t u a t i o n . I f they are not, place a second p a i r of gloves of s u i t a b l e m a t e r i a l , over them. This, once again, reduces your work e f f i c i e n c y , but also insures t h a t you are adequately p r o t e c t e d . With p r o x i m i t y s u i t s , the glove/sleeve i n t e r f a c e i s bonded together e i t h e r p h y s i c a l l y or chemically so as to insure a sealed system. With splash s u i t s , however, t h i s i s not the case. The p o t e n t i a l e x i s t s at both the glove and sleeve i n t e r f a c e , as w e l l as the boot and pant leg i n t e r f a c e f o r the entrance of contaminants. An easy method to reduce t h i s p o t e n t i a l exposure, i s to place the sleeves over the gloves and the pants leg over the boot, and then t a p i n g both areas w i t h duct tape. This provides much b e t t e r exposure p r o t e c t i o n , but s i g n i f i c a n t l y reduces the a b i l i t y of your body t o cool i t s e l f : Be aware t h a t heat s t r e s s may r e ^ u l t .

f

t

Eye/Face P r o t e c t i o n

Anytime you are working i n a hazardous environment, eye p r o t e c t i o n i s a necess i t y . The eyes are the easiest organ to i n j u r e and the hardest to r e p a i r . Eye p r o t e c t i o n can come i n the form of s a f e t y glasses w i t h side panels; goggles, or face s h i e l d s . These eye p r o t e c t i o n systems are g e n e r a l l y manufactured of e i t h e r polycarbonate or p o l y e t h y l e n e , many of which are now manufactured w i t h a non-fogging c o a t i n g . Safety glasses and goggles should only be worn i n areas of very low p o t e n t i a l hazard, since a m a j o r i t y of the face i s s t i l l unprotected. Face s h i e l d s , or f u l l - f a c e r e s p i r a t o r s , provide s i g n i f i c a n t l y more f a c i a l p r o t e c t i o n . However, never enter the hazardous waste area w i t h o u t some form of eye p r o t e c t i o n . Contact lenses are not acceptable i n the work environment. S p e c i a l i z e d goggles which can accept c o r r e c t i v e lenses are a v a i l a b l e .

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t

Questions To Ask Yourself

I n summarizing the choice of p r o t e c t i v e c l o t h i n g , the f o l l o w i n g questions must be answered:

1. I s the s i t u a t i o n immediately dangerous t o l i f e and health? - I f so, p r o x i m i t y s u i t e s are re q u i r e d .

2. I s there a high p o t e n t i a l f o r f i r e ? - i f so, f i r e r e s i s t a n t or flame r e t a r d a n t c l o t h i n g i s r e q u i r e d .

3. What chemicals am I l i k e l y t o encounter? - assess the s i t u a t i o n and decide upon s u i t a b l e m a t e r i a l s f o r gloves, boots, and p r o t e c t i v e c l o t h i n g .

4. What are the c l i m a t i c conditions? - heat re q u i r e s c o o l i n g ; l i q u i d s and shortened work cycles; w h i l e c o l d c o n d i t i o n s r e q u i r e a d d i t i o n a l c l o t h i n g .

5. I s high v i s i b i l i t y required? - b r i g h t l y colored or f l u o r e s c e n t c l o t h i n g should be used.

6. Remember, always wear eye p r o t e c t i o n and cover as much of your body as p o s s i b l e .

Attachment 1

PERSONNEL PROTECTIVE EQUIPMENT REQUIRED FOR HAZARDOUS SITUATIONS

Level A P r o t e c t i o n HAZARD INVOLVED

S i t u a t i o n s immediately dangerous t o l i f e and h e a l t h . Oxygen d e f i c i e n t atmospheres. Unknown hazardous m a t e r i a l s . Chemicals which can be absorbed through the s k i n . M a t e r i a l s which cannot be removed w i t h an a i r p u r i f y i n g r e s p i r a t o r .

REQUIRED PERSONNEL PROTECTION EQUIPMENT Self - c o n t a i n e d b r e a t h i n g apparatus (SCBA) or a i r l i n e r e s p i r a t o r w i t h SCBA escape a i r system. F u l l Body Encapsulation Suit

ALL l i s t e d personal p r o t e c t i v e equipment i s re q u i r e d f o r any hazard s i t u a t i o n i n d i c a t e d .


Level B P r o t e c t i o n HAZARD INVOLVED

Oxygen d e f i c i e n t atmosphere where chemical composition of the ma t e r i a l i s known and f a l l s i n t o the c l a s s i f i c a t i o n of an i r r i t a n t .

REQUIRED PERSONNEL PROTECTION EQUIPMENT

Self contained b r e a t h i n g apparatus or a i r l i n e r e s p i r a t o r w i t h SCBA f o r emergency use. PVC splash s u i t w i t h hood. Neoprene/nitri1e/buty1 rubber arm le n g t h gloves. Steel toed rubber boots.

A l l l i s t e d personal p r o t e c t i v e equipment i s r e q u i r e d f o r any hazard s i t u a t i o n i n d i c a t e d .


Level C P r o t e c t i o n

HAZARD INVOLVED S i t u a t i o n s not immediately dangerous t o l i f e and h e a l t h . S u f f i c i e n t oxygen present to support l i f e . I r r i t a n t or c o r r o s i v e chemicals. Contaminated s o i l s . L i q u i d / s o l v e n t s not immediately dangerous t o l i f e and h e a l t h .

REQUIRED PERSONNEL PROTECTION EQUIPMENT F u l l face mask w i t h a i r p u r i f y i n g ( c a r t r i d g e ) r e s p i r a t o r . Or, h a l f face ( c a r t r i d g e ) r e s p i r a t o r w i t h goggles and face s h i e l d . PVC splash s u i t . P r o t e c t i v e gloves (type dependent on chemical being handled). Steel toed rubber boots.

A l l l i s t e d personnel p r o t e c t i v e equipment i s r e q u i r e d f o r any hazard s i t u a t i o n i n d i c a t e d .


Level D P r o t e c t i o n HAZARD INVOLVED

S i t u a t i o n s which conta i n no immediate hazard, but where there i s the p o t e n t i a l f o r a c c i d e n t a l release of a hazardous substance.

REQUIRED PERSONNEL PROTECTION EQUIPMENT Half face a i r p u r i f y i n g ( c a r t r i d g e ) r e s p i r a t o r . Safety goggles. Disposable c o v e r a l l s . Surgical rubber gloves or s u i t a b l e hand p r o t e c t i o n . Rubber boots.

A l l l i s t e d personnel p r o t e c t i v e equipment i s re q u i r e d f o r any hazard s i t u a t i o n i n d i c a t e d .

Chemical Hazard

Attachment 2

PROTECTIVE CLOTHING COMPATABILITY WITH SELECTED CHEMICAL HAZARDS

N a t u r a l Rubber Neoprene

P o l y v i n y l Alcoho1

E-Exce11enc G-Good F-Fair P-Poor

Po l y v i n y 1 C h l o r i d e N i c r i l e

Ace ta ldehyde

A c e t i c A c i d

A c e t i c A n h y d r i d e

A c e C o n i t r i l e

Acetone

A c r y l o n i t r i l e Alcohols Ammonis(lOOZ) Amyl Acetate An i l i n e Battery Acid Benzaldehyde Benzene Benzene S u l f i n i c Bromine Butyric Acid Cadmium Cyanide Carbolic Acid Carbon T e t r a c h l o r i d e Chlorine Chloroform Chlorosulfonic Acid Chromic Acid Cresol Cyanide Solution Cyclohexane Di o c t y l Phthalate

G E C G E F G G F F G F P P G F G F P F P P P G G P F

G E G G G G F G G G E P P G G G E E P F P F F G G G G

P F P G F F P P G F P E E P E F G F E E E F P F P E E

F G F G P F F E P G E P P E G G E E G G • P G G F F P P

F E G G P F E

G P E P P

G E P G P F P P G P P

E-ExceI lent C-Cood F-Fair P-Poor


Natural P o l y v i n y l P o l y v i n y l N i t r i l e Chemical Hazard Rubber Neoprene Alcohol Chloride N i t r i l e

Dimethyl Formamide E G P P P

D ioxane F F P P P

Ethanolamine F G P E P

Ethers G E E P P

Ethyl Acetate F G F P P

Ethyl Alcohol E E P G E

Ethylene Dichloride P P E P P Ethylene Glycol E E G E E

Formaldehyde E E P E E

Formic Acid G E P E F

Frem P F E P F

e l O i l P G E G P

Furf u r a l G G F F P

Gasoline (unleaded) P P F P E

Hexane P G E P E

Hydrobromic Acid (40%) G E P E E

Hydrochloric Acid (Conc .) G E P E E Hydrofluoric Acid (30Z) G E P G E Hydrogen Peroxide (30Z) G E P E E Isopropyl Alcohol E E P E E Kerosene P E E G E

Mercury G G P E E

Methyl Alcohol E E P G E Methylene Chloride P P G P P Methyl I s o b u t y l Ketone •F P F P P Methyl Methacrylate P P G P P Naphtha P P E F • E

Chemical Hazard


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N i t r i c A c i d ( lOZ)

N i t r i c A c i d (70Z)

N i t r i c A c i d (Fuming)

N i t robenzene

N i t rome thane

Oleum

P a r a t h i o n

Pentane

P e r c h 1 o r o e t h y l e n e

P e r c h l o r i c A c i d

Phenol

Phosphor i c A c i d

P i c k l i n g Baths

Potass ium H y d r o x i d e

P r o p y l e n e Oxide

P y r i d i n e

Sodium H y d r o x i d e

Sodium P e r o x i d e

S toddard S o l v e n t

S ty rene

S u l f u r i c A c i d

Tannic A c i d

T e t r a c h l o r o e t h y l e n e

T e t r a h y d r o f u r a n

Toluene

Toluene d i - i s o c y a n a t e

T r i c h l o r o e t h y l e n e

Xylene

P

P ^ P

P

F

P

P

P

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F

G

G

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F

F

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E-Exce1 l e n t C-Cood F - F a l r P-Poor


P h y s i c a l Pe r fo rmance N a t u r a l Rubber Neoprene

P o l y v i n y l A l c o h o l

P o l y v i n y l C h l o r i d e N i t r i l e

Tear Res i s t ance

A b r a s i o n R e s i s t a n c e

Heat R e s i s t a n c e

Flame R e s i s t a n c e

E l o n g a t i o n

G

G

F

P

E

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G

CHAPTER FOUR

Training Manual No. 3 RESPIRATORY TRAINING PROGRAM

prepared by Universal Waste & T r a n s i t

O r ient Road Tampa, F l o r i d a

t CONTENTS

RESPIRATORY PROTECTION

Figure 1. Respirator Selection According t o Hazard A i r P u r i f y i n g Respirators Table 1. Color Coding of Chemicals Cartridges Atmosphere Supplying Respiratory Protection Self Contained Breathing Apparatus

SPECIAL PROBLEMS WITH RESPIRATORS

Temperature Hair Corrective Lennses Communication

RESPIRATOR MAINTENANCE

# Respiratory Protection

The choice of a r e s p i r a t o r to be employed on an emergency response i n c i d e n t i s not an item t o be taken l i g h t l y . A l l too o f t e n r e s p i r a t o r s are chosen because they are comfortable; l i g h t weight; and r e a d i l y a v a i l a b l e . These are not the c r i t e r i a which are t o be employed to i n s u r e your s a f e t y and h e a l t h .

You have been assigned your own personal r e s p i r a t o r and have been f i t - t e s t e d to i n s u r e proper o p e r a t i o n . Read both t h i s document and Respirator T r a i n i n g Program I I (Appendix 1) c a r e f u l l y . This r e s p i r a t o r i s not meant f o r oxygen d e f i c i e n t atmospheres or areas immediately dangerous t o l i f e and h e a l t h . Check w i t h your supervisor before e n t e r i n g any unknown area.

C e r t a i n types of r e s p i r a t o r s provide c e r t a i n types of p r o t e c t i o n . Figure 1 shows a block diagram which o u t l i n e s various forms of r e s p i r a t o r y p r o t e c t i o n r e l a t i v e to the hazard i n v o l v e d .

Respiratory p r o t e c t i o n f a l l s i n t o two major c a t e g o r i e s : A i r p u r i f y i n g Atmosphere supplying

- 1 -

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Figure 1

A i r P u r i f y i n g R e s p i r a t o r s A i r p u r i f y i n g r e s p i r a t o r s do not supply a i r . They simply remove a p a r t i c u l a r contaminant from the surrounding environment t o reduce the p o t e n t i a l f o r occupational exposure. A i r p u r i f y i n g r e s p i r a t o r s f a l l i n t o a v a r i e t y of categories i n d i c a t e d below:

Single use, dust Quarter mask, dust Half mask, dust Half or quarter mask, high e f f i c i e n c y Half or quarter mask, fume F u l l facepiece, high e f f i c i e n c y Power, high e f f i c i e n c y Gas and vapor removing, h a l f mask Gas and vapor removing, f u l l facepiece

Mechanical f i l t e r type r e s p i r a t o r s employ a f e l t pad which p h y s i c a l l y removes p a r t i c u l a t e contamination from the a i r . They g e n e r a l l y do not remove chemical compounds and are not a i r supplying r e s p i r a t o r s . These f i l t e r s have a l i m i t e d l i f e t i m e dependent upon the c o n c e n t r a t i o n of the contaminant i n the environment i n which you are working. When breat h i n g r e s i s t a n c e becomes excessive i t i s necessary to replace the f i l t e r media. Chemical c a r t r i d g e type r e s p i r a t o r s g e n e r a l l y c o n t a i n s p e c i a l l y t r e a t e d a c t i v a t e d carbon which removes p a r t i c u l a r gases or fumes by means of e i t h e r absorption or r e a c t i o n . Once again, these types of r e s p i r a t o r s do not supply oxygen and must not be used i n e i t h e r an oxygen d e f i c i e n t environment or one which i s immediately dangerous t o l i f e or h e a l t h . Most c a r t r i d g e type r e s p i r a t o r s are s p e c i f i c f o r c e r t a i n groups of compounds, such as acids; ammonia; organic vapors; and so on. You must be c e r t a i n of the contaminant present before a d e c i s i o n can be made as t o the type of chemical c a r t r i d g e which i s r e q u i r e d f o r t h a t p a r t i c u l a r s i t u a t i o n . A l l c a r t r i d g e s are c o l o r coded and labeled f o r t h e i r s p e c i f i c use. These c o l o r codes are shown i n Table 1.

-2-

T a b l e 1

PERSONAL PROTECTIVE EQUIPMENT

RESPIRATOR

COLOR CODING OF CHEMICAL CARTRIDGES Atmospher ic C o n t a m i n a n t s to be

P r o t e c t e d A g a i n s t C o l o r s A s s i g n e d *

Acid gases Hydrocyanic acid gas

Chlorine gas

Organic vapors Ammonia gas Acid gases and ammonia gas

Carbon monoxide Acid gases and organic vapors Hydrocyanic acid gas and c h l o r o p i c r i n

vapor

Acid gases, organic vapors, and ammonia gases

Radioactive m a t e r i a l s , excepting t r i t i u m and noble gases

Particula t e s ( d u s t s , fumes, m i s t s , fogs, or smokes) i n combination with any of the above gases or vapors

A l l of the above atmospheric contaminants

White. White w i t h 1/2-inch green s t r i p e com

p l e t e l y around the c a n i s t e r near the bottom.

White w i t h 1/2-inch yellow s t r i p e comp l e t e l y around the c a n i s t e r near the bot torn.

Black. Green. Green w i t h 1 / 2 - i n c h w h i t e s t r i p e com

p l e t e l y a r o u n d t h e c a n i s t e r nea r the b o t t o m .

B l u e . Y e l l o w Y e l l o w w i t h 1 / 2 - i n c h b l u e s t r i p e com

p l e t e l y a r o u n d t h e c a n i s t e r nea r the b o t t o m .

Brown .

P u r p l e ( M a g e n t a ) .

C a n i s t e r c o l o r f o r c o n t a m i n a n t as d e s i g n a t e d a v o b e , w i t h 1 / 2 - i n c h g r a y s t r i p e c o m p l e t e l y a r o u n d t h e c a n i s t e r nea r the t o p .

Red w i t h 1 / 2 - i n c h g r a y s t r i p e c o m p l e t e l y a round t h e c a n i s t e r nea r the t o p .

*Gray s h a l l not be a s s i g n e d as t h e m a i n c o l o r f o r a c a n i s t e r d e s i g n e d t o remove acids or v a p o r s .

NOTE: Orange s h a l l be used as a c o m p l e t e body , o r s t r i p e c o l o r t o r e p r e s e n t gases no t i n c l u d e d i n t h i s t a b l e . The use r w i l l need t o r e f e r t o the c a n i s t e r l a b e l t o d e t e r m i n e t h e degree o f p r o t e c t i o n the c a n i s t e r ^ w i 11 a f f o r d .

Neither mechanical f i l t e r nor chemical c a r t r i d g e elements should be used when e n t e r i n g an atmosphere or area where any of the f o l l o w i n g contaminants are present:

Oxygen D e f i c i e n t Atmosphere Areas immediately dangerous to l i f e and h e a l t h Areas which c o n t a i n any of the f o l l o w i n g chemical contaminants:

A c r o l e i n Analine Arsine Boron Hydrides Bromine Carbon Dioxide Carbon D i s u l f i d e Carbon Monoxide Carbony1s Cyanogen Dimethyl Analine Dimethyl S u l f a t e Ethyl Cyanide F l u o r i n e Formaldihyde Hydrogen Cyanide Hydrogen F l u o r i d e Hydrogen Selenide

Hydrogen S u l f i d e Methyl Isocyanate Methyl Bromide Methyl Chloride Methyl Iodide Nitrobenzene Nitrogen Oxide Ni t rog1ycerine Nitromethane Ozone Perchlorethane Phosgene Phosphene Phosphorus T r i c h l o r i d e Stibene S u l f u r C hloride Toluene Diisocyanate V i n y l Chloride

Once again, i t i s important t o remember t h a t an assessment of the h e a l t h hazards i n v o l v e d i n a p a r t i c u l a r s i t u a t i o n are necessary to determine what type of r e s p i r a t o r y p r o t e c t i o n i s best s u i t e d f o r your p a r t i c u l a r needs.

Atmosphere Supplying Respiratory P r o t e c t i o n In some cases i t may be necessary to use a i r s u p p l i e d r e s p i r a t o r y p r o t e c t i o n when e n t e r i n g an area. This form of r e s p i r a t o r y p r o t e c t i o n f a l l s i n t o three c ategories i d e n t i f i e d below;

A i r l i n e r e s p i r a t o r Hose mask w i t h blower S e l f - c o n t a i n e d b r e a t h i n g apparatus

Both the a i r l i n e r e s p i r a t o r and the hose mask w i t h blower type systems employ outside sources f o r supplying b r e a t h i n g a i r . This outside source can e i t h e r be a compressor or b o t t l e d a i r . When using a compressor f o r supplying b r e a t h i n g a i r , i t i s necessary t h a t c e r t a i n precautions be observed:

1. The compressor must be located i n area where contaminated a i r w i l l not be drawn i n t o the system.

2. S u f f i c i e n t safeguards must be a p p l i e d t o in s u r e t h a t the compressor i t s e l f does not generate carbon monoxide, o i l m i s t s , or hydrocarbon vapor d u r i n g o p e r a t i o n .

3. I n s t a l l a t i o n of necessary f i l t e r i n g devices to remove any p a r t i c u l a t e contamination or o i l mi s t .

4. A separate "escape a i r " or SCBA system, whereby the user of the a i r l i n e r e s p i r a t o r can proceed to an uncontaminated area i n an emergency s i t u a t i o n .

5. Do not use a compressor f o r an a i r supply unless i n d i c a t e d by your supervisor.

-4-

A i r l i n e r e s p i r a t o r s and hose masks w i t h blowers provide the b e n e f i t of much longer working times, since a l i m i t e d a i r supply i s not a problem. But they also pose problems i n t h a t the hoses and/or a i r l i n e s are cumbersome and tend t o get i n the way d u r i n g work o p e r a t i o n , as w e l l as having the p o t e n t i a l f o r being cut or crushed. These systems, however, are acceptable i n oxygen d e f i c i e n t atmospheres so long as the requirements on the f o l l o w i n g page are met:

1. An a d d i t i o n a l escape a i r system, which allows s u f f i c i e n t time f o r e x i t i n g the contaminated area.

2. No more t h a t 150 f e e t of hose i s employed. 3. S u f f i c i e n t safeguard on the a i r supplying equipment to i n s u r e

t h a t contamination of the source does not occur.

•5-

Self Contained Breathing Apparatus (SCBA) The r e s p i r a t o r y p r o t e c t i o n of choice i n an oxygen d e f i c i e n t environment or t h a t which i s immediately dangerous to l i f e and h e a l t h (IDLH) i s the s e l f - c o n t a i n e d b r e a t h i n g apparatus. These systems c o n s i s t of a f u l l or h a l f - f a c e r e s p i r a t o r equipped w i t h p o r t a b l e c y l i n d e r a i r . The major disadvantage of the SCBA system i s i t s l i m i t e d supply of a i r . Most systems range from 30 minutes to one hour maximum w i t h t h i s value being h i g h l y dependent upon the l e v e l of a c t i v i t y as i n d i c a t e d below:

A c t i v i t y Oxygen Uptake L i t e r s / M i n u t e Seated 0.3 Ligh t work 0.66 Walking 1.0 Shoveling 1.5 - 2.0 ( r a t e and l i f t dependent)

A l l employees should be f a m i l i a r w i t h the l o c a t i o n and op e r a t i o n of SCBA's. They could save your l i f e !

I f an SCBA i s used, immediately recharge the c y l i n d e r when you are f i n i s h e d .

Special Problems w i t h R e s p i r a t o r s

Temperature Cold temperatures can cause a v a r i e t y of problems when wearing r e s p i r a t o r s . These i n c l u d e frozen valves; face p l a t e fogging; and b r i t t l e n e s s of the r e s p i r a t o r i t s e l f . Care must be exercised i n handling r e s p i r a t o r s i n cold weather so as not t o compromise t h e i r usefulness. V i s i o n fogging i s a serious problem when using f u l l - f a c e r e s p i r a t o r s . Nose cups can be obtained w i t h f u l l - f a c e r e s p i r a t o r s which s i g n i f i c a n t l y reduce facepiece f o g g i n g , A n t i f o g g i n g r e s p i r a t o r sprays appear to have l i m i t e d usefulness. Hair Both h a i r s t y l e s and f a c i a l h a i r can prove incompatible w i t h e f f e c t i v e r e s p i r a t o r usage. Clean, smooth s k i n i s r e q u i r e d f o r acceptable s e a t i n g and s e a l i n g of a r e s p i r a t o r . Even one day's growth of beard can impair a r e s p i r a t o r ' s e f f e c t i v e n e s s . C o r r e c t i v e Lenses When the user of a r e s p i r a t o r r e q u i r e s eye glasses, s p e c i a l precautions must be taken to insure t h a t these do not impair the r e s p i r a t o r s e f f e c t i v e n e s s . Special facepieces are a v a i l a b l e which can accommodate eye glasses. Contact lenses should never be worn when working w i t h hazardous m a t e r i a l s . The p o t e n t i a l f o r incompatible chemicals coming i n contact w i t h the contact lens and the eye i s s u b s t a n t i a l . When a i r s u p p l i e d r e s p i r a t o r s are worn, the incoming a i r has a tendency to dislodge the contact lens from the wearer's eye. Communications When wearing a r e s p i r a t o r , communication i s at best, d i f f i c u l t . You should l e a r n hand s i g n a l s f o r communication w i t h co-workers. When SCBA's are r e q u i r e d , you w i l l be su p p l i e d w i t h a ra d i o communication system.

Respirator Maintenance

In order f o r a r e s p i r a t o r t o f u n c t i o n e f f i c i e n t l y , i t must be r e g u l a r l y cleaned, maintained and s a f e l y s t o r e d . A f t e r each use, your r e s p i r a t o r should be cleaned w i t h soap and water, and d i s i n f e c t e d : the i n h a l a t i o n and e x h a l a t i o n valves should both be checked t o insure t h e i r s a t i s f a c t o r y working c o n d i t i o n ; c a r t r i d g e s and/or f i l t e r s should be changed; a i r l i n e s cleaned; c y l i n d e r s recharged; and st o r e d i n a clean, dry, and p r e f e r a b l y warm environment. Your r e s p i r a t o r provides you w i t h p r o t e c t i o n from p o t e n t i a l l y l i f e t h r e a t e n i n g s i t u a t i o n s and should be maintained w i t h t h a t i n mind.

Appendix 1

EMPLOYEE RESPIRATOR TRAINING PROGRAM I I

Universal Waste & T r a n s i t Orient Road

Tampa, F l o r i d a

CONTENTS

General Dual F i l t e r C a r t r i d g e Mask A i r l i n e Mask & Helmet Maintenance Emergency

General

A. A l l employees must be examined by a p h y s i c i a n to determine t h a t they are p h y s i c a l l y able to perform the work and use r e s p i r a t o r y p r o t e c t i o n equipment. The r e s p i r a t o r user's medical s t a t u s w i l l be reviewed annually.

B. Any employee using a mask type r e s p i r a t o r s h a l l be clean shaven t o increase s e a l i n g between face and mask.

C. Employees should f a m i l i a r i z e themselves w i t h the r e s p i r a t o r s by using them i n an uncontaminated area f o r an extended p e r i o d of time.

D. Employees s h a l l t e s t f o r leaks i n r e s p i r a t o r s before each use. E. Only NIOSH (Na t i o n a l I n s t i t u t e of Occupational Safety and Health)

approved r e s p i r a t o r s s h a l l be used. The r e s p i r a t o r f u r n i s h e d s h a l l provide adequate r e s p i r a t o r y p r o t e c t i o n against the p a r t i c u l a r hazard f o r which i t i s designed.

F. There s h a l l be re g u l a r i n s p e c t i o n and e v a l u a t i o n to determine the continued e f f e c t i v e n e s s of the program.

•1-

Dual F i l t e r C a r t r i d g e Mask

Limitations - Not to be used i n atmospheres immediately dangerous t o l i f e and/or d e f i c i e n t i n oxygen.

To f i t r e s p i r a t o r t o face: 1. P o s i t i o n r e s p i r a t o r on face, f i t t i n g wide p o r t i o n under c h i n ,

and narrow p o r t i o n over nose, wearing as low as p o s s i b l e . 2. Place one-piece lower headband around head below ears, and

s l i p f i t upper headband above ears, a d j u s t i n g f o r t i g h t yet comfortable f i t .

3. Test f o r proper seal of facepiece as f o l l o w s : 1. Remove e x h a l a t i o n valve guard. 2. Close e x h a l a t i o n valve w i t h thumb and exhale g e n t l y . 3. I f a i r leakage i s detected, r e a d j u s t headbands u n t i l

t i g h t seal of facepiece to face i s obtained. 4. F i n a l l y , replace e x h a l a t i o n valve guard.

Leave Area Immediately i f : 1. b r e a t h i n g becomes d i f f i c u l t 2. di z z i n e s s or other d i s t r e s s occurs 3. you t a s t e or smell contaminant

-2-

A i r l i n e Mask and Helmet Use - For p r o t e c t i o n against heavy exposures of dusts, fumes,

vapors, gases, mists and smoke. Limitations - Not to be used i n atmospheres immediately dangerous to

l i f e or those d e f i c i e n t on oxygen. Operating P r i n c i p l e

This i s a s u p p l i e d - a i r type r e s p i r a t o r and must be connected t o a s u i t a b l e source of r e s p i r a b l e a i r before use. A i r pressure at mask should be 10 - 25 p s i .

F i t t i n g Mask - A f t e r connecting r e s p i r a t o r to a i r supply l i n e , f i t as f o i l o w s :

1. Hold facepiece and p u l l a l l f i v e head straps out to the end tabs. Clasp temple and neck straps w i t h each hand, and s t r e t c h straps over head, f i t t i n g facepiece against chin f i r s t .

2. S t a r t i n g w i t h bottom straps p u l l t o i n s u r e a snug f i t , t i g h t e n i n g top s t r a p l a s t . This facepiece does not r e q u i r e excessive s t r a p pressure t o o b t a i n leakproof f i t .

3. The b e l t hook and br e a t h i n g tube from the mask to the a i r supply l i n e are assembled to be worn on the l e f t side. A f t e r mounting b e l t hook, t u r n the head toward the r i g h t side to make sure there i s no undue p u l l of the b r e a t h i n g tube on the facepiece. I f t h i s leaves too larg e a loop of the tube on the l e f t side when the head i s turned back, adj u s t the p o s i t i o n of the b e l t hook.

F i t t i n g Helmet-After connecting r e s p i r a t o r t o a i r supply l i n e , f i t as f o i l o w s :

Place helmet onto head and adj u s t headband. White shroud i s t o be placed underneath c l o t h i n g and draw s t r i n g i s to be p u l l e d u n t i l shroud f i t s snugly. Then p u l l yellow shroud over c l o t h i n g or p r o t e c t i v e s u i t . P u l l face mask down.

A i r Flow Regulation

A f t e r the facepiece and b r e a t h i n g tube are p r o p e r l y adjusted, the a i r flow can be regu l a t e d to s u i t the wearer. To decrease a i r flo w , unscrew adjustment nut on r e g u l a t i n g valve u n t i l d esired s e t t i n g i s reached. This a d j u s t i n g valve i s so constructed t h a t the a i r supply cannot be shut o f f completely when connected.

Leave Area Immediately i f : 1. Breathing becomes d i f f i c u l t 2. Dizziness or other d i s t r e s s occurs 3. You t a s t e or smell contaminant

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Maint enance A. Cartridges f o r r e s p i r a t o r s must be replaced immediately as soon as

employee can t a s t e or smell contaminant. Do not s u b s t i t u t e d i f f e r e n t types of c a r t r i d g e s .

B. Respirators s h a l l be cleaned and d i s i n f e c t e d d a i l y . R e s p i r a t o r s can be cleaned w i t h a m i l d detergent and water. D i s i n f e c t i o n can be accomplished by immersing masks i n a c h l o r i n e s o l u t i o n (2 tablespoons of bleach per g a l l o n of water) f o r two (2) minutes. Respirators are then to be generously r i n s e d and allowed t o a i r dry.

C. Respirators s h a l l be inspected d u r i n g cleaning. Worn or d e t e r i o r a t e d p a r t s s h a l l be replaced.

D. When not i n use r e s p i r a t o r s s h a l l be p r o t e c t e d from dust, s u n l i g h t , heat, extreme c o l d , excessive moisture, and damaging chemicals.

E. , R espirators should be placed i n re-usable p l a s t i c bags u n t i l r e issue. They s h a l l be s t o r e d i n a s i n g l e layer w i t h the facepiece and e x h a l a t i o n valve i n a more or less normal p o s i t i o n to prevent the rubber or p l a s t i c from t a k i n g a permanent d i s t o r t e d " s e t " .

F. Respirators s h a l l be stored i n a r i g i d storage cabinet or chest.

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Emergency In case of emergency, personnel i n the a i r s u p p l i e d r e s p i r a t o r s are responsible to a s s i s t and/or remove any i n j u r e d or unconscious employee(s) from the contaminated area to an uncontaminated area; administer necessary f i r s t a i d ; ( i n p a r t i c u l a r , mouth-to-mouth r e s u s c i t a t i o n ) , and summon medical assistance as per emergency phone numbers l i s t e d at the s i t e . Personnel should commit these emergency numbers to memory.

In a d d i t i o n , employees should leave the area immediately i f : 1. Breathing becomes d i f f i c u l t 2. Dizziness or other d i s t r e s s occurs 3. Employee t a s t e s or smells contaminant

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CHAPTER FIVE

Training Manual No. 4

BASIC EMERGENCY TRAINING GUIDE

prepared by Universal Waste & T r a n s i t , .

Orient Road Tampa, F l o r i d a

CONTENTS I n t r o d u c t i on T r a i n i n g Medical M o n i t o r i n g Medical M o n i t o r i n g Parameters Chemical C o m p a t i b i l i t y C o m p a t i b i l i t y Tree (Table 1) Chemical C o m p a t i b i l i t y Chart (Table 2) Spi11 Response A n t i c i p a t e d Response Actions For C e r t a i n Compounds

(Table 3) F i r e F i g h t i n g F i r e F i g h t i n g Equipment Contaminati on/Decontaminati on F i r s t Aid Worker Rights Under the Occupational Safety and Health Act

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I n t r o d u c t i o n

Universal Waste & T r a n s i t s p e c i a l i z e s i n the packaging; h a n d l i n g ; t r a n s p o r t a t i o n ; , storage and treatment of hazardous wastes. The company also responds to emergency i n c i d e n t s such as chemical or petroleum s p i l l s and abandoned waste disposal s i t e cleanup. You t h e r e f o r e could come i n t o contact w i t h a v a r i e t y of p o t e n t i a l l y hazardous m a t e r i a l s . These i n c l u d e :

Poisons Flammable Liquids Flammable Solids

Water or A i r Reactives Explosives Oxidizers Corrosives Aerosol Containers Gas Cylinders

A l l of these m a t e r i a l s are c l a s s i f i e d as hazardous and precautions are r e q u i r e d to insure your s a f e t y when responding to any emergency s i t u a t i o n .

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T r a i n i n g You are r e q u i r e d t o a t t e n d c e r t a i n t r a i n i n g sessions and t o s u c c e s s f u l l y pass these courses p r i o r to working on any Universal Waste & T r a n s i t job s i t e . These courses i n c l u d e :

1. Personnel P r o t e c t i v e Equipment 2. Respirator T r a i n i n g Program 3. F i r e Safety and Response 4. F a c i l i t y Operations 5. Basic F i r s t Aid 6. Cardiopulmonary R e s u s c i t a t i o n (CPR)

You are also r e g u i r e d t o f a m i l i a r i z e y o u r s e l f ( w i t h your supervisors assistance) w i t h the f o l l o w i n g documents.

1. Universal Waste & T r a n s i t Emergency Response Contingency Plan 2. Universal Waste & T r a n s i t Waste Analysis Plan 3. Universal Waste & T r a n s i t I n s p e c t i o n Plan 4. DOT Guide t o Hazardous M a t e r i a l s 5. CHRIS Manual 6. NIOSH Worker Safety B u l l e t i n 7. NSWMA 8 Part Brochure Series on Hazardous Waste 8. USEPA Hazardous Waste C r i t e r i a

These plans should be reviewed and completely understood p r i o r t o your p a r t i c i p a t i o n i n any a c t i o n s . Along w i t h t h i s , you should also f a m i l i a r i z e y o u r s e l f w i t h the equipment a v a i l a b l e to you during any emergency response. There w i l l be in-depth discussions about personnel p r o t e c t i o n equipment, but you should also become f a m i l i a r w i t h the operation of the necessary support equipment which i s r e q u i r e d such as pumps; compressors; generators; emergency l i g h t i n g ; containment and sorbent m a t e r i a l s ; heavy equipment; and even hand t o o l s . The time to lear n the o p e r a t i o n of these items i s not when you are already o n - s i t e . This equipment i s important t o you, both to insure a r a p i d response to an emergency s i t u a t i o n , as w e l l as f o r your own personal s a f e t y . Learn i t s proper operation and maintenance before you are r e q u i r e d to use i t .

t Medical M o n i t o r i n g Your personal s a f e t y i s of the utmost importance at a l l times. I n order f o r you t o be aware of your p h y s i c a l c o n d i t i o n , i t i s important t h a t a medical m o n i t o r i n g program be e s t a b l i s h e d f o r you. This mo n i t o r i n g program i s simply a screening which evaluates your general physical c o n d i t i o n , as w e l l as c e r t a i n parameters i n both blood and u r i n e samples. I t allows our p h y s i c i a n t o determine i f you have been exposed t o s p e c i f i c hazardous substances and also aids i n determining what personnel can be assigned to high s t r e s s work environments.

The frequency, type and number of examinations i s dependent upon the f o l l o w i n g items:

1. The degree of, or the p o t e n t i a l f o r , exposure to various compounds.

2. The p h y s i c a l , chemical, or b i o l o g i c a l m a t e r i a l s which may be encountered.

3. The p o t e n t i a l f o r acute ( s h o r t - t e r m ) or chronic (long-term) h e a l t h e f f e c t s .

At a minimum you w i l l have a complete medical review at l e a s t annually. A l l costs are covered by Universal Waste & T r a n s i t . I t should be remembered t h a t medical m o n i t o r i n g , or h e a l t h s u r v e i l l a n c e i s simply an a d d i t i o n a l means to help p r o t e c t your h e a l t h . Most exposures to hazardous m a t e r i a l s should be prevented by the e f f e c t i v e use of personnel p r o t e c t i v e equipment, engineered safeguards and safe working p r a c t i c e s . A l i s t i n g of recommended medical m o n i t o r i n g parameters i s included as Table 1.

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Table 1 MEDICAL MONITORING PARAMETERS

Blood Pressure Pul se R e s p i r a t i o n Pulmonary Function

Forced V i t a l Capacity E x p i r a t o r y Volume Reserve Volume

Blood Analyses - Chemical Screen U r i n a l y s i s

t chemical C o m p a t i b i l i t y

Since the end of World War I I there have been over 50,000 new chemicals created and over 1,000 new ones are produced each year. Some of these are not compatible w i t h others. When noncompatible m a t e r i a l s are mixed a number of re a c t i o n s can r e s u l t . These i n c l u d e :

release of heat p o l y m e r i z a t i o n (hardening) generation of gases f i r e explosion

A l l of these r e a c t i o n s are dangerous. I t i s your r e s p o n s i b i l i t y to insure t h a t non-compatible m a t e r i a l s remain segregated.

A l l containers are sampled before they enter the Universal Waste & T r a n s i t f a c i l i t y . These samples are analyzed at a c e r t i f i e d l a b o r a t o r y to determine t h e i r chemical composition. A f t e r a n a l y s i s these containers are labeled according to Department of T r a n s p o r t a t i o n (DOT) r e g u l a t i o n s . These l a b e l s or placards can help you keep non-compatible m a t e r i a l s segregated. Your "DOT Guide to Hazardous M a t e r i a l s " booklet describes what containers must be segregated.

Table 2 l i s t s chemical c o m p a t i b i l i t i e s f o r a v a r i e t y of compounds.

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S p e c i f i c a l l y , the f o l l o w i n g m a t e r i a l s should remain segregated from each other:

acids should not be placed w i t h a l k a l i n e wastes acids should not be placed w i t h c y a n i d e / s u l f i d e bearing wastes i g n i t a b l e s should be placed only i n the flammable storage area

Most waste m a t e r i a l s can be placed i n DOT approved s t e e l c o n t a i n e r s . Exceptions to t h i s would be c o r r o s i v e wastes (pH less than 2 or greater than 12.5); which should be placed i n DOT approved polyethylene co n t a i n e r s .

Your supervisor must t e l l you which containers are to be placed i n t o what storage l o c a t i o n . I f you have questions or concerns - Ask before A c t i n g ! ! ! Safety Always Comes F i r s t .

S p i l l Response The contingency plan d e t a i l s c e r t a i n a c t i o n s t o be taken f o r a s p i l l or release. Read I t C a r e f u l l y ! Emergency telephone numbers are posted above every telephone. I f a s p i l l occurs do not t r y to hide i t . Contact your supervisor immediately or sound the a i r horns l o c a t e d throughout the b u i l d i n g . Immediately t h e r e a f t e r put on the necessary p r o t e c t i v e equipment. ( l o c a t e d i n s a f e t y cabinets) A f t e r n o t i f i c a t i o n and p u t t i n g on p r o t e c t i v e equipment - co n t a i n the s p i 1 1 ! ! ! A wide v a r i e t y of containment equipment i s a v a i l a b l e i n c l u d i n g :

containment booms sorbent booms sorbent pads o i l - d r i plug and dike sealant overpack drums plug rugs

DO-.not use water t o c o n t a i n a s p i l l ! ! The "hazorb" m a t e r i a l i s chemically i n e r t . I t w i l l not react w i t h the s p i l l e d m a t e r i a l . This should be your f i r s t choice f o r containment. Members of the Universal Waste s p i l l response group are r e a d i l y a v a i l a b l e and w i l l be responsible f o r any f u r t h e r a c t i o n s . However, your immediate response to a s p i l l or release i s necessary to p r o t e c t the environment. Learn where a l l necessary s p i l l c o n t r o l m a t e r i a l s are kept and how to use them i n an emergency. Attached to t h i s as Table 3 are various response a c t i o n s f o r numerous chemicals. These are also included i n the contingency plan as w e l l as being kept i n the s a f e t y cabinets.

F i r e Fighting Flammable m a t e r i a l s are stored at UW&T. The room where these m a t e r i a l s are located has been designed to reduce, as much as p o s s i b l e , any f i r e hazard. You are the key to making t h i s system work! I f you f o l l o w c e r t a i n , simple r u l e s the hazard i n v o l v e d i s minimal. These are:

1. NO f o r k l i f t s or tow motors are allowed i n the flammable area. 2. Use a grounding s t r a p on every drum you move i n t o or out of

the flammable area. . 3. Use only non-sparking tools -^'-^

4. Never use any e l e c t r i c a l t o o l s or equipment i n the flammable area. Explosion-proof pumps and t o o l s are a v a i l a b l e . Ask your supervisor before using any of these.

5. Do not use f l a s h l i g h t s i n t h i s area. They can spark when turned on.

6. An e x p l o s i v i t y meter i s a v a i l a b l e - l e a r n I t s use - check the room before e n t e r i n g . The reading must be less than 15% of the lower explosive l i m i t (LEL). I f not contact your supervisor immediately.

7. Only drums w i t h "flammable" or "combustible" l a b e l s are t o be stor e d i n t h i s area.

You must think safety at a l l time. I f there i s any question about what you are asked to do - don't act u n t i l you are sure!

F i r e F i g h t i n g Equipment There are four classes of f i r e s . Those are: Class A Fires i n o r d i n a r y combustible m a t e r i a l s such as wood, c l o t h

or paper. Class B F i r e s i n flammable l i q u i d s or petroleum products such as

solvent or p a i n t . Class C F i r e s i n v o l v i n g e l e c t r i c a l equipment. Class D Fires i n combustible metals such as sodium or magnesium.

Throughout the b u i l d i n g are 10 pound f i r e e x t i n g u i s h e r s f o r class A, B or C f i r e s . These are c l e a r l y i d e n t i f i e d w i t h red markings. There are two s p e c i a l i z e d "halon" f i r e e x t i n g u i s h e r s i n the flammable room. These are e x c e l l e n t f o r class B and C f i r e s . They are i d e n t i f i e d by red markings. A complete d e s c r i p t i o n of r e a c t i o n to a f i r e i s given i n the Contingency Plan. Read and f a m i l i a r i z e y o u r s e l f w i t h these responses. You are r e q u i r e d to a t t e n d the f o l l o v / i n g f i r e p r e v e n t i o n p r e s e n t a t i o n s

Hazardous Waste & F i r e Service Using F i r e E x t i n g u i s h e r s - The Right Way

Your supervisor w i l l schedule these p r e s e n t a t i o n s .

Any v i o l a t i o n of the s a f e t y aspects of t h i s s e c t i o n are grounds f o r d i s m i s s a l .

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Contamination/Decontamination Whenever you respond to an emergency i n c i d e n t , you are g e n e r a l l y e n t e r i n g a "contaminated" area. The m a t e r i a l which you are encountering i s normally hazardous i n one form or another. The i n t e n t of your job i s t o remove t h a t hazard as q u i c k l y and as e f f i c i e n t l y as poss i b l e . You do not want to contaminate other areas. You should always make the assumption t h a t e v e r y t h i n g you are wearing i s contaminated. I f you are wearing disposable c l o t h i n g , these should be discarded i n t h e i r a p p r o p r i a t e c o n t a i n e r s . The f o l l o w i n g regimen f o r removal of contaminated c l o t h i n g i s suggested.

1. Remove gloves and d i s c a r d f o r e i t h e r disposal or cleaning. 2. Put on new disposable' gloves. 3. Remove p r o t e c t i v e c l o t h i n g and e i t h e r d i s c a r d or place aside

f o r c l e a n i n g . 4. Remove boots and e i t h e r d i s c a r d or set aside f o r cleaning. 5. Remove r e s p i r a t o r and eye p r o t e c t i o n - set aside f o r cleaning

and decontamination. 6. Remove gloves and d i s c a r d .

A shower w i l l be a v a i l a b l e between the contaminated area and clean area f o r both worker s a f e t y and to insure t h a t no a d d i t i o n a l contamination r e s u l t s . Clean c l o t h i n g would be a v a i l a b l e i n the uncontaminated area. The decontamination process should occur each time a worker leaves the contaminated area. Obviously no smoking, eating or d r i n k i n g i s acceptable i n the contaminated area.

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A l l contaminated p r o t e c t i v e c l o t h i n g should be e i t h e r disposed or cleaned i n the ap p r o p r i a t e s o l u t i o n s . Soap and water i s always a good s t a r t f o r decontaminating p r o t e c t i v e c l o t h i n g and equipment. Subsequent cleaning w i t h a d d i t i o n a l m a t e r i a l s may be re q u i r e d dependent upon the s p e c i f i c contaminant. You must allow s u f f i c i e n t time f o r the p r o t e c t i v e c l o t h i n g to dry before i t i s to be reused, or a s u f f i c i e n t q u a n t i t y of p r o t e c t i v e c l o t h i n g must be a v a i l a b l e so t h a t t h i s does not become a problem. You are supplied w i t h at l e a s t 5 sets of work uniforms, more are a v a i l a b l e as necessary. You are re q u i r e d to wear a c1ean uniform at the beginning of each working day. I f you are working w i t h containers of hazardous waste you must wear the f o l l o w i n g :

Disposable tyvek s u i t Disposable gloves Safety glasses Boots

When lea v i n g the storage/treatment area you are t o d i s c a r d a l l disposable items. When lea v i n g at the end of a work day a l l employees are re q u i r e d to change from t h e i r work uniform and enter t h e i r s t r e e t c l o t h e s . No. uniforms are to be taken home!_!_!

Any v i o l a t i o n of t h i s s e c t i o n i s grounds f o r d i s m i s s a l .

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F i r s t Aid

W i t h i n t h i r t y days a f t e r employment or as soon as p o s s i b l e you are r e q u i r e d to attend and complete the f o l l o w i n g courses:

Emergency F i r s t Aid CPR T r a i n i n g

These w i l l be scheduled during normal working hours,and. you w i l l be paid f o r the time spent i n class.

You and your co-workers depend h e a v i l y upon each other. You should never work i n the storage or treatment area alone. There must be at l e a s t one other person i n the immediate area.

In the event t h a t an emergency s i t u a t i o n should a r i s e , you should be aware of c e r t a i n steps which must be taken immediately. Most i m p o r t a n t l y , you should never enter a s i t u a t i o n immediately dangerous to l i f e and h e a l t h alone. At a minimum, two people should be a v a i l a b l e , both of which are equipped w i t h l i f e l i n e s and are p h y s i c a l l y capable of removing the other person should the need a r i s e . You should have undergone basic f i r s t a i d and cardiopulmonary r e s u s c i t a t i o n (CPR) t r a i n i n g . You should be able to i d e n t i f y c e r t a i n symptoms, e i t h e r from y o u r s e l f or your co-worker and be able to give emergency f i r s t a i d should the need a r i s e . Only severe emergency s i t u a t i o n s w i l l be discussed at t h i s time, but they could be of tremendous assistance to you or your co-workers.

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Chemical Burns Remove contaminated c l o t h i n g ; f l u s h w i t h l a r g e volumes of water immediately; do not apply n e u t r a l i z i n g or b u f f e r i n g agents; do not consider chemical a n t i d o t e s ; do not remove goggles u n t i l the head and face area have

, been thoroughly f l u s h e d . Contact a p h y s i c i a n i f necessary.

Chemical Burns of the eye - Remove glasses and f l u s h immediately w i t h tap water, eye

wash, or a ge n t l e stream of water from a hose. Time i s extremely important. The e y e l i d should be f o r c i b l y held apart so t h a t a l l areas of the eye are flushed. Minimum f l u s h i n g time i s t h i r t y minutes. Cover the eye and immediately t r a n s p o r t t o emergency f a c i l i t i e s .

Asphyxi at i on (poisoning by i n h a l a t i o n ) - Remove from the exposed area as soon as p o s s i b l e , keep

p a t i e n t warm and l y i n g down, and i f b r e a t h i n g has stopped begin cardiopulmonary r e s u s c i t a t i o n (CPR).

In the event of any accident, attempt to o b t a i n as much i n f o r m a t i o n as possi b l e concerning the route of exposure and the contaminant. Relay t h i s i n f o r m a t i o n to the a p p r o p r i a t e medical a u t h o r i t i e s .

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Warm weather can be deva s t a t i n g to a worker. During these periods of time you are normally working under high l e v e l s of s t r e s s and i n v o l v e d i n heavy manual labor. You are o u t f i t t e d i n garments and p r o t e c t i v e equipment which allow l i t t l e , i f any, body c o o l i n g . You are g e n e r a l l y burdened by uncomfortable, cumbersome, and p o s s i b l y heavy p r o t e c t i v e c l o t h i n g , a l l of which makes l i f e , i n general, q u i t e miserable. Your produ c t i o n of body heat, when combined w i t h the outside a i r temperature, w i l l g e n e r a l l y r e s t r i c t you to shortened work cycles. The t a b l e below i n d i c a t e s how much body heat i s produced dur i n g various a c t i v i t i e s i n a 160-lb man:

A c t i v i t y , Body Heat Produced ( k i l o c a l o r i e s / h o u r )

Rest (seated) 90 L i g h t machine work 200 Walking 300 Shoveling ( r a t e and l i f t dependent) 450-600 When the ambient a i r temperature exceeds 79 degrees and you are producing more than 300 k i l o c a l o r i e s per hour, your work e f f i c i e n c y i s g r e a t l y reduced. Man i s capable of a d j u s t i n g to hot environments, however, t h i s adjustment takes normally about a week, during which time the body w i l l undergo a s e r i e s of changes t h a t make f u r t h e r heat exposures more endurable. You should, wherever p o s s i b l e , d i s t r i b u t e your d a i l y work load i n t o shortened work-rest cycles. The r e s t p e r i o d gives your body an o p p o r t u n i t y to get r i d of excess heat; slows down the pr o d u c t i o n of i n t e r n a l body heat; and provides greater blood flow to the s k i n . During t h i s r e s t cycle you should proceed to the decontamination area, remove a l l contaminated c l o t h i n g to expose as much of your body as pos s i b l e t o the outside a i r ; and r e s t . F l u i d s should be taken as o f t e n as p o s s i b l e .

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WORKER RIGHTS UNDER THE OCCUPATIONAL SAFETY AND HEALTH ACT (OSHA)

Among your r i g h t s as an employee are the r i g h t t o :

a safe and h e a l t h f u l workplace as r e q u i r e d under the OSHAct; review copies of standards and other r u l e s , r e g u l a t i o n s and requirements under the OSHAct t h a t your employer should have r e a d i l y a v a i l a b l e ; speak to your employer about s a f e t y and h e a l t h hazards i n your workplace, about precautions t h a t may be taken, and procedures you should f o l l o w i f you are i n v o l v e d i n an accident or exposed to t o x i c substances; ask f o r an e v a l u a t i o n of your workplace by the National I n s t i t u t e of Occupational Safety and Health (NIOSH) or to f i l e a complaint w i t h OSHA requesting an i.nspection by OSHA i f you b e l i e v e hazardous c o n d i t i o n s or v i o l a t i o n of standards e x i s t i n your workplace, and the r i g h t t o ask OSHA not t o reveal your name; ob t a i n access to any of your medical records or records of exposure t o t o x i c substances which your employer may have; have your authorized employee r e p r e s e n t a t i v e accompany the OSHA compliance o f f i c e r during an i n s p e c t i o n of your workplace; respond to questions from the OSHA compliance o f f i c e r during an i n s p e c t i o n of your workplace;

p r o t e c t i o n from being f i r e d or punished i n any way f o r e x e r c i s i n g your r i g h t s under the OSHAct ( i f you've been f i r e d or punished, you must t e l l the nearest OSHA o f f i c e r w i t h i n 30 days).

Strong Acid r p H « 7

COMPATIBILITY TREE

J ^ ^ m ^ p ^ J j (non-radioactive)

pH

pH 5-9 1 p H » 7 Strong Base (check CN", S=)

ORP

l.Oxidizer 2.Reducing Agent

swirl

no density grcKiients

Water

O R P

1. Ox id izer

soluble

2. Reducing Agent

add water

insoluble

ORP

\ l .Oxidizer 2.Reduclng Agent

Water Reactive

floats sinks

density gradients

soluble 5 7o HCI

insoluble

check flash point

Organic Base

5 % NaOH

sol. insol.

Organic Acid (check FP)

Flammable Liquid

Non-flammable Liquid

Beilstein Test negative

positive

Halogenated Hydrocarbon (check PCB)

Hydrocarbon (check FP)

Hydrocarbon (check FP)

SCREENS F O R : 1. Strong Acids 2. Strong Bases 3. Oxidizers 4. Reducing Agents 5. Cyanides & Sulfides

6. Water Reactives 7. F lammable Liquids 8. Halogenated Hydrocarbons 9. PCB's

ACID STRENGTH

STRONG ACIDS HCLOi PERCHLORIC H2S0t| SULFURIC HCL HYDROCHLORIC HNO3 NITRIC

\€AK ACIDS H3POi4 PHOSPHORIC

HNO2 NITROUS

HF HYDROFLUORIC

CH3COOH ACETIC

H2CO3 CARBONIC HCN HYDROCYANIC H3BO4 BORIC

ACID SALTS NAHSOi SODIUM BISULFATE FECL3 FERRIC CHLORIDE FESOq FERROUS SULFATE

NAH2P0q SODIUM DIWDROGEN PHOSPHATE

BASE STRENGTH

KOH POTASSIUM HYDROXIDE (LYE)

NAOH SODIUM HYDROXIDE (CAUSTIC SODA)

CA(0H)2 CALCIUM HYDROXIDE (SLA<ED LIME)

NA2CO3 SODIUM CARBONATE (SODA ASH)

CACO3 CALCIUM CARBONATE (LIMESTONE)

MG(0H)2 MAGNESIUM HYDROXIDE

NAHCO3 SODIUM BICARBONATE

COfflON REDUCING AGENTS

FERROUS SALTS

HYDRIDES*

BOROHYDRIDES*

ORGANICS

TIN, IRON OR ZINC DUST

STANNOUS CHLORIDE

* WATER REACTIVE

COMMON OXIDIZING AGENTS

H2O2 HYDROGEN PEROXIDE

CL2 CHLORINE

HYPOCHLORITE SALTS

NAOCL SODIUM HYPOCHLORITE

CA(XL)2 CALCIUM WPOCHLORITE

PERMANGANATES

KMNO POTASSIUM PERMANGANATE

HCLO/4 PERCHLORIC ACID

H2S04 SULFURIC ACID

HNO3 NITRIC ACID

TTvUle COMPATIBILITY OF HAZARDOUS WASTES

Part 1 From "A Method for Determining Incompatibility of Hazardous Wastes",

EPA 600/2-80-076 April, 1980 SECTION t

METHOD FOR DETERMINING COMPATIBILITY OF HAZARDOUS WASTES

APPLICATION

This method is used to determine the compat ib i l i ty reactions of most binary combinations of most hazardous wastes. The method is applicable to four categories of wastes based on information available, namely: 1) compositions unknown, 2) compositions known specif ical ly, 3) compositions known nonspecifically by chemiceii classes or react iv i t ies, and li) compositions known nonspecifically by common or generic names only.

The method starts with a compat ibi l i ty analysis f low chart (Figure 1) indicating the analysis pathways for the four categories of wastes above, fol lowed by the compat ibi l i ty reaction cr i ter ia cind the stepwise precedures for determining compatib i l i ty .

COMPATIBILITY REACTION CRITERIA

The reactions between binary combinations of wastes are NOT COMPATIBLE according to this method when the fol lowing undesirable and hazardous consequences are produced:

Reaction Codes Reaction Consequences (RC)

H Generates heat by chemical reaction

F Produces f i re f rom extremely exothermic reactions, ignit ion of reaction mixtures or of the reaction products.

G Generates'innocuous gases such at N j , CO2, etc. but can cause pressurization and rupture of closed containers

GT Generates toxic gases such as HCN, H2S, etc.

GF Generates f lammable gases such as H2, C2H2, etc.

E Produces explosion due to extremely vigorous reactions or reactions producing enough heat to detonate unstable reactants or reaction products.

P Produces violent polymerization resulting in the generation of extreme heat and sometimes toxic and flammable gases.

S Solubilizes toxic substances including metals

8

1-1

The RC are used in the compatibi l i ty chart (Figure 6) to denote the potential hazardous reaction consequences that can result from the binary combinations of the wastes.

PROCEDURES FOR DETERMINING COMPATIBILITY

Five main steps are required in the step-by-step.procedures for determining the reaction compatibi l i ty of any Wastes A and B. The procedures are conducted wi th reference to Figure 1 (Flow Diagram for Determining Hazardous Wastes Compatibi l i ty), Figure 6 (Hazardous Wastes Compatibi l i ty Chart), Appendix 1 (List of Chemical Com-' pounds). Appendix 2 (List of Wastes Constituents by Chemical Classes and Reactivit ies, and Appendix 3 (List of Wastestreams by Common or Generic Names).

Step 1: Obtain as much information as possible about the history and compositions of the wastes. Such information can usually be obtained from the records of the waste producers, the manifests that accompany the wastes and examination of the processes that produced the wastes. When no information is available, collect representative samples of the wastes and submit them for. analysis. The analysis should provide information on the specific chemical constituents or classes of compounds in the wastes.

Step 2; Starting with Waste A, l ist down on the worksheet (Figure 2) on the column for Waste A, the chemical names or classes of compounds in the waste or the generic names of the waste. The composition of the waste is Known Specific'aJly when the constituents are listed by chemical names such as ethylene glycol, sodium nitrate, etc.; . Known Nonspecifically by classes when the constituents are identi f ied only by chemical classes or reactivit ies such as alcohols, caustics, mercaptans, etc. The waste is Known Nonspecifically by generic names when classified as spent caustic, tanning sludge, copper plating waste, etc.

Step 3; When the composition of Waste A is Known Specifically by chemical names, consult Appendix 1. Find the chemicals in the list and note down their respective Reactivity Group Numbers (RGN) in the Worksheet.. If a cherhical component is not listed in Appendix 1, look for its synonym(s) (Ref. 7, I'f, 21, 30, 32, 37, ^ 1 , Û, 59, 69, 70, 76) and note down its RGN (Section UA, Example 1, Note 2). When no synonym can be found, the RGN of the component may be alternatively determined based on its chemical class or react iv i ty (Section Â, Example 1, Note 3).

When the composition of the waste is Known Nonspecifically by chemical classes or reactivities only, consult Appendix 2 and note down the corresponding RGN on the Worksheet (Section kA, Example 2).

When the composition of the waste is Known Nonspecifically but classified, by common or generic names, consult Appendix 3 and note down the RGN in the Worksheet (Section Â, Example 3). ,

Step ^: Repeat steps 2 and 3 for Waste B and l ist down the information on the column for Waste B on the Worksheet.

Step 5: Consult the Hazardous Wastes Compatibi l i ty Chart in Section 5 and determine the Reaction Codes (RC) between any binary combinations of RGN of Wastes A against

1-2

B. Note all RC on the Worksheet. If no RC are listed, Wastes A and B are compatible and vice versa.

SPECIFIC EXAMPLES

The following examples illustrate the stepwise procedures for determining the compatibility of hazardous wastes:

Example 1 - Composition Known Specifically

Step 1; The manifests identify the constituents of the wastes specifically as follows:

Waste A contains ethylene glycol, chhlorobenzene, and hydrochloric acid.

Waste B contains isooctane and sodium sulfide.

List the components of Waste A on the column for Waste A on the Worksheet (Figure 2). Consult Figure 1 and follow the compatibility flow diagram for Composition Known Specifically.

Step 2: Find the RGN of the components ethylene glycol, chlorobenzene and hydrochloric acid in Appendix 1. Thus, the RGN for the components are: ethylene glycol - f, chlorobenzene - 17, and hydrochloric acid - I .

Step 3: Record the RGN of the components on the Worksheet.

^Step List the components of Waste B on the column for Waste B on the Worksheet. Repeat steps 2 and 3 for Waste B. thus, the RGN of the components of Waste B are as follows: Isooctane-29, and sodium suIfide-33.

Step 5: Pair up each listed RGN of Waste A against that of Waste B. Hence the following pairs are possible:' <5c 29, & 33, 17. & 29, 17 & 33, 1 & 29, 1 and 33. For each pair, find the Reaction Codes (RC) in the Hazardous Wastes Compatibility Chart (Figure 6). Record the corresponding RC for each pair in the Worksheet. Note that the RC for all binary ccxabinations of RGN for wastes A and B are blank except for RGN 1 dc 3 which are GF. The completed Worksheet is shown in Figure 3.

Conclusion: Waste A is incompatible with Waste B. Potential hazard of toxic (GT) and flammable (GF) gas formations are indicated if the wastes are mixed.

NOTE i : If Waste A contains a water reactive constituent (RGN 107) and Waste B contains an aqueous component, then water (RGN 106) should be listed as one of the hazardous components for Waste B in Step 1.

NOTE 2; If a chemical constituent is not listed in' Appendix 1, its synonym(s) can be obtained from chemical references (Ref. 7, I't, 21, 30, 32, 37, f l , 5 , 59, 69, 70, 76) and used to determine its RGN. For example, Pyranton is a chemical not listed in Appendix 1. By consulting the Merck Index (Ref. 5U), the synonym for this chemical is diacetone alcohol which is listed in Appendix I with RGN of 'f and 19. Thus, the

.compatibility of this compound with other waste constituents can be established in the 'same way as Example 1.

10

1-3

NOTE 3; When a synonym for an unl is ted compound cannot be found , the RGN under which i t is l i s ted may be der ived by molecular f unc t i ona l groups or chemica l r e a c t i v i t y . For example, isobutyl carb ino l is not l i s ted in Appendix 1. The Merck Index (Ref . 5^*), however, l is ts the compound as an a lcohol . There fo re , by consul t ing Appendix 2, isobutyl carb inol may be clcissif ied under RGN 4. When the compound contains more than one func t i ona l groups, al l appl icable RGN must be i d e n t i f i e d . A compound l i ke . peroxosul fur ic ac id is not l i s ted in Appendix 1. This compound, however, is known to be a strong minera l ac id as we l l as a very power fu l ox id iz ing agent. There fo re , the compound may be c lass i f ied under RGN 2.

Example 2 - Comp>osition Known Nonspec i f i ca l l y by Chemica l Classes or React i v i t i e s .

Step 1; The mani fests i d e n t i f y the wastes const i tuents as fo l l ows :

Waste A contains t ox i c meta ls , aldehydes and alcohols.

Waste B contains t ox i c meta ls and ox id iz ing agents.

L is t the components of Waste A on the co lumn fo r Waste A on the Worksheet (Figure 2). Consul t F igure 1 and f o l l ow the c o m p a t i b i l i t y f l o w diagram fo r compos i t ion Known Nonspec i f i ca l l y by Chemica l Classes or- R e a c t i v i t i e s .

Step 2: Find the RGN for t ox i c meta ls , aldehydes and alcohols iri Appendix 2. Thus, the RGN for the components are: t ox i c meta ls - 2^^, aldehydes -5 , and alcohols - , f.

Step 3: Record the RGN of the components on the Worksheet .

Step f : L is t the components of Waste B in the co lumn f o r Waste B on the Worksheet . Repeat steps 2 and 3 fo r Waste B. Thus, the RGN for the components of Waste B are: t ox i c meta ls - 2^ and ox id i z ing agents - lO'f.

Step 5; Determine the compiatibility of Waste A and B in the' same manner as in Step 5 of Example 1. The completed Worksheet for this example is shown in Figure k.

Conclusion: Waste A is i ncompa t ib le w i t h Waste B. Po ten t ia l for heat and f i r e generations (Hp) are ind ica ted i f the wastes are m ixed .

Example 3 - Compos i t i on Known Nonspec i f i ca l l y by Common or Gener ic Names of Wastes

Step 1; The mani fes ts describe the wastes as fo l l ows :

Waste A is a me ta l p la t ing waste.

Waste B is a pec t in waste f r o m the product ion of c i t rus products.

L is t the gener ic name of Waste A on the co lumn fo r Waste A on the Worksheet (Figure 2). Consul t F igure 1 and f o l l o w the c o m p a t i b i l i t y f l ow diagram fo r composi t ion Known Nonspec i f i ca l l y by Common or Gener ic Names of Waste.

11

1-4

Step 2; Find the RGN of "metal plating waste" according to Appendix 3. The RGN ^ôr this generic waste are 11 and l^t.

Step 3; Enter the RGN of Waste A on the Worksheet.

Step f i Enter the waste generic name of "Citrus Pectin Waste" on the column for Waste B on the Worksheet. Repeat steps 2 and 3 above for Waste B. Thus, the most likely RGN for this generic waste are I and t.

Step 5: Determine the compatibility of Waste A and B in the same manner as in Step 5 of Example 1. The completed Worksheet for this example is shown in Figure 5.

Conclusion: Waste A is incomp»atible with Waste B. Potential hazards of toxic and flammable gas formations ( GT^p) are indicated if the wastes are mixed. Also solubilization (S) of metals may occur.

12

1-5

WASTE A

Sitp 1 Obuin Aviiliblc Infoimii ion Abou( Waste

NO INFORMATION ON COMPOSITION

Perform Chcmicil Analytu

List Namei or Cl'ssci of Oiemicili in Wane or Generic Namct of Waste on the

Column for Waste A on the Worltjhcet, Figiire 2

COMPOSITION KNOWN SPECIFICALLY

COMPOSITION KNOWN NON SPECIFICALLY

BY CHEMICAL CLASSES OR REACTIVE PROPERTIES

Step 2 Find Chemical and

RGN'in Appendix 1

CHEMICAL CHEMICAL LISTED NOT LISTED

Step 3

Ste;-<

Step 5

Find Classes of Compounds and RGN in Appendix 2

Find Synonym

Determine Chemical Clauci

or Reactive Properties

List Correspondini R G N ' oti the Worksheet

Repeat Above Steps for Waste B. Note Names and RGN'on the

Column for Waste B on the Worksheet.

Determine and Note Compatibilities Using Figure 6

COMPOSITION KWOWN NON-SPECIFICALLY

BY COMMON OR GENERIC NAMES OF WASTE

Find Generic Names and RGN in Appendix 3

INCOMPATIBILITIES ARE INDICATED. WASTES SHOULD NOT BE MIXED.

NO INCOMPATIBILITIES ARE INDICATED. WASTES CAN BE MIXED.

Note: 1. Reactivity Croup Numbers

Figure 1. F low diagram fo r de te rmin ing hazardous waste compa t ib i l i ty .

13 i

1-6

WASTE B

Waste A

Waste B

Name of Waste Evaluation

Source

Source

Date

WASTE B ^ WASTE A^s^v

\ > \ (0 o \ / \ OJ »-

Reactivi ty x x ^ Name Group No. x ^

• Note: Refer to Figure 6 for the definitions of the Reaction Code entered on the

squares of this worksheet.

Figure 2, Worksheet for determining hazardous waste compatibi l i ty.

If

1-7

EXAMPLE 1

Waste A

Waste B


Source

Source

Date

X N . 0)

x-^ e X N . fO

X X ^ X ^ WASTE B

WASTE A x x ^

^ s X D. X X to o

X X OJ u X X Pi (J

React iv i ty \ x ^ Name Group No.

29

Isoo

ctan

e

33

Sodi

um

Sul

fide

Ethylene Glycol tt

Chlorobenzene 17

Hydrochloric Acid 1 GT

GF

Note: Refer to Figure 6 for the definitions of the Reaction Code entered on the squares of this worksheet.

Figure 3. Completed worksheet for determining hazardous waste compatibility when the wastestream compositions are known specifically.

15

1-8

EXAMPLE 2

Waste A

Waste B


Source

Source

Date

XX^^ (U XSv ^

X X z ^ x WASTE B

WASTE / V N X

^ s x . :> 2 ^ X X ^ Q-

X>v 1 => X T X "1 O X X x X ^ u

Reactivi ty ^ X X ^ Name Group No. x ^

2f

Tox

ic

Met

als

lO'f

Oxi

dizi

ng A

gent

Toxic Metals 2*

Aldehydes 5

Alcohols

•


Figure i . Completed worksheet for determining hazardous waste compatibility when the wastestrecun compositions are known non-specifically by chemical classes.

16

1-9

EXAMPLE 3

Waste A

Waste B


Source

Source

Date

x X 0)

X X ")

X X WASTE B ^ WASTE A^^^X

X x D. X X U 3

X X "J o X X OJ I-

. . X x [V i«j React iv i ty ^ S s ,

Name Group No.

li P

ectin

W

aste

Metal Plating Waste 11 ^"^GF

S


Figure 5. Completed worksheet for determining hazardous waste compatibility when wastestream compositions are known nor>-specificaIly by generic names.

17

1-10

SECTION 5

H A Z A R D O U S WASTES C O M P A T I B I L I T Y C H A R T

INTRODUCTION i

The char t (Figure 6) is the single most impo r t an t par t of this repo r t . I t is a quick and ready re ference f o r de te rmin ing the c o m p a t i b i l i t y react ions of most b inary combinations of hazardous wastes. It is used in conjunction with the detailed com-patibililty analysis procedures in Section k.

DESCRIPTION OF THE C H A R T

The k\ r e a c t i v i t y group c lass i f ica t ions of hazardous wastes l i s ted in Appendix 2 are presented in th is cha r t .

The f i r s t co lu lmn of the char t l ists the r e a c t i v i t y groups by R e a c t i v i t y Group Numbers (RGN) . The f i r s t S't RGN which are based on chemica l classes or molecular. . . func t iona l groups are l i s ted consecut ive ly f r o m 1 to 3k. The ' l as t 7 RGN wh ich are based on general chemica l reac t i v i t i es are l i s ted consecut ive ly f r o m 101 to 107. The second co lumn l is ts the corresponding r e a c t i v i t y group names. The f i r s t 3k- group names are each fo l l owed by a number of reac t ion squares equal to the i r respect ive R G N . In o ther words, RGN 1 is f o l l owed by 1 square, R G N 2 by 2 squares, e t c . The group names designated by R G N 101 to 107 are f o l l owed by 3k, 36, 37, 38, 39, kQ and ' t l squares, respect ive ly . The squares f o r m rows as wel l as columns of squares on the char t . A t e rm ina l square of a row represents a b inary combinat ion of one react ive group w i t h i t se l f and is label led w i t h i t s R G N . The t e r m i n a l squares serve as headings f o r the columns of squares and as a whole appear as a diagonal row of squares on the char t . A n addi t ional bo t tom row of-squares is correspondingly labe l led as the diagonal row of squares. The RGN on the f i r s t co lumn of the char t and those on the diagonal and bo t tom rows of squares prov ide the re fe rence coord inates fo r locat ing the potent ia l hazardous reac t ion consequences of any b inary combinat ions of the wastes r e a c t i v i t y groups.

The rest of the squares on the char t are e i ther blank or f i l l e d in w i t h Reac t ion Codes (RC). When a square is blank,, the wastes in the binary combina t ion represented by that square are compa t ib le . Conversely , any RC on the squares ind icate po ten t ia l incompat ib le react ions tha t can resul t f r o m the combina t ion of the wastes r e a c t i v i t y groups represented by the ind iv idual squares. The pred ic ted react ions are based on the combinat ions of the most reac t i ve chemicals in the respect ive r e a c t i v i t y groups. A l l the b inary wastes combinat ions designated w i t h RC are descr ibed in greater deta i l in Appendix k. Where waste combinat ions are bel ieved to be incompat ib le but no su f f i c ien t support ing data have been found in the l i t e r a t u r e , i ncompat ib le react ions are also noted and marked on the char t w i t h RC or " U " . The RC are i den t i f i ed in the

18

1-11

legend on the upper right hand corner of the chart and described in detail in Section k.2. The multiple RC are explained in Section 5A.

PROCEDURES FOR USING THE CHART

Step 1; For the binary combination of any reactivity groups, first find the Reactivity Group Number (RGN) of the first group on the first column of the chart.

Step 2; Find the RGN of the second group from the bottom squares of RGN.

Step 3; Find the intersecting reaction square for the two RGN.

Step k: Note the Reaction Code(s) (RC) in the square.

Step 5: Refer to the legend on the chart or Section 5A for the explanation of the RC.

Step 6; When no RC is found on the reaction square, the two groups of wastes are compatible. When any RC are noted on the square, the wastes are incompatible when mixed or allowed to come in contact with one another.

EXPLANATION OF THE MULTIPLE REACTION CODES

For'many binary combinations, multiple Reation Codes (RC) are used to denote the reaction consequences. The order In which these letter codes appear in the squares corresponds to the order in which the consequences can occur. For example, in RC (^PE), the first letter denotes the initial or primary hazardous consequence of a binary reaction which in this case is HEAT generation. The second and third letters denote the resulting secondary consequences of the production of FIRE and EXPLOSION from the heat generated by the primary reaction. In some cases the third letter code refers to a resulting tertiary consequence such as the evolution of a toxic gas from a f ire caused by excessive HEAT generation ( •^FG-J-). Where the codes GT^p appear, the GASES evolved are TOXIC and FLAMMABLE such as hydrogen sulfide,'hydrogen cyanide, or carbon disulfide. The relative positions of the letter codes to one another in this case bear no significance. The codes can also be written as G F ^ ^

LIMITATIONS OF THE CHART

The p>otential reaction consequences predicted by the chart are based on pure chemical reactions only at ambient temperature and pressure. Concentration, synergistic, and antagonistic effects have been assumed not to influence the reactions. The reactions have not as yet been validated on actual wastes containing the chemicals.

19

1-12

R U C T I V I T V C R O t r SO.

Ht AOIMT V CKOir .N KMl

1 A C K H . M t n . n l , N i i iM ix id i t i n f t

AcUh. M I n r n l . 0 > l i l i l l n |

An<K. O i , . n k G H 3

4 AkuhbU *nd C N e v h H "F H F

4

5 A k i r h x d n \ "F H F

}

i A m K t n H H CT k

r A m i n n . Al iphatle and Arumal ie H -CT H H -t .Aio CompuuMH. D la lu Cumpvumh and H> drar ln r t H

C H

0 1 M

C H

C H

• Carbamam H C

H CT \ »

10 Ca tn l k t H M H M H C 10

I I Cyan ldn CT CF

C I CF

C I CF C I I

| ] [> ( lh loc* rb .maln H cr

f CF

F I.

CT CF

CT "c

l i Esrcn H M F "c M 13

14 E l h m H "F

15 n u o r i d r t . Inorfanle CT CT CT

16 1

H y d n e v b w m . , \ r o m i l l e H F

17 Hatofmalcd Orjanin H CT

M F CT

H CT

H c

H cr

H

I t h o c t a n a i n H C

H

'cT H

C N

P H c

H F

C H

C f

19 ICr lo tm H ^ M c

H H

» Mfteaptam and O lh r r O r ^ n k S u l f t d n C I cr

H V CT

H C

Mt t i l v . AlkaK and Al l iaUnf CarIh. E J r m n l a l cr

H F

Cf H F

cr H F

ct H F

t f H F

CF H

CF H

CF H

CF H

CF H

cr H

u M m K . OtKr f E k n w i t a l A AIIo>t a» f o . d m . Vaporv ur S p o n f n cr

H r icr

H F

CF H F CT

f

••• j3 • Metah. Other Oemn t l a l k AStoyx at S>i«cft. R o d i . Dropa. Mbtd iny i . e tc . ' CF

n F

cr H

F

H

' c • l i Melah and Metal Compoundt . T o i l e t s 1 S S %

25 CF MF

H

'l C^

" H c H C

f CF H

cr H

2 t . Ntintn • M CT

CF \ T M c JT Nhro ComtKMjnd^ Oryanle ^

% I H " t

U H\.drt>cirbom. Al iphal lc . U n u l u r a i e d H H F

H

J» Hydioearbona. A l l pKa lk . Salura l .d H F

M N r e i W n and H , d r o p r r « « l d n . O r f j n k H C

M I

H F

H C

H C t %

I

l l F CT

l l t CT CT

J l rbenoJs and C r n o l l H M F

H C

3 ] O r ^ n o p h M p h a l r t . f h o t p h o t h i o a i n , f h o f p h o d l l h i o a l n M CT

H CT U H

t

13 SulfWSn. Inorfanle CJ CT

HF CT CT H c

34 Epoxidr t H t

H r

H H f .U H

F H r

H r

H r

U

101 Comtni i l lb lc and Flammable Ma l r t i ah . Mtv:etlan»««n H C

h r <rr . 10 ] \ \ H

I H c

M t

103 PoJ,m«Htabl« Compowndi r H

T H

r H

F H

F H

r H U

104 OnHlu in i Afenla. Strong N CT

H CT

H F

H F

H F CT CT

H t

H 'cT

H E CT CT

H F

101 Rrducing A f ^ l s . Sr rmt | H CF

H F CT "cF

H

"F t f CF

H H

CF H

C M

CT H

F

106 Water and Mlaturcs Conla ln in f Water H H C

107 Walct RraetlvT Sub i lanen F Y T o F M r i v ttparîvr* 107 Walct RraetlvT Sub i lanen

1 1 3 4 5 7 « • 10 I I 12 13

Figure 6. Hazartlous waste compatibility chart.

20

1-13

Example:

H

tiMt^rijucfWeA

H f j l f t . i t r rat i t tn

Fife

ln«t4H'uitu\ t n i l noit.f laniniaMe ,<n«ralittA

To\ i ( ' f i \ f%-n*nttiu\

F I j m n u M e ,a« ,\.neralit>n

E\|>l.>î..ii

(xtl)nv^ri/alMtn

5*iluhtlijaiii>n of lo\w %ut* titw*^

lav tv Ka/artJ>iUi hul unL.iiii«n

Hra l Frn^.rattoii. rirc. and toxk- |a> j t^tKral i tm

SI St

DO NOT MIX WITH ANY CHEMICAL OR WASTE MATERIAL! EXTREMELY REACTIVEr-

14 15 16 17 I t 14 :0 21 i9 JO Jl J2 JJ J4 101 l o : 10] 104 105 106 107

Figxjre 6. Hazardous waste compatibility chart (continued).

21

1-14

REFERENCES

1. A rm is tead , G. Safe ty in Pet ro leum Re f in ing and Re la ted Industr ies. John D. Simmons and Co. , Inc., New York , 1950.

2. Assessment of Indust r ia l Hazardous Waste P rac t i ce Series. U.S. Env i ronmenta l Pro tec t ion Agency, O f f i c e of Solid Waste Management Programs, Washington, D.C.

E lec t rop la t i ng and Meta l F in ish ing Industr ies - 3ob Shops. Ba t te l l e Columbus Labora tor ies , 1976.

Inorganic Chemica l Industry. Versar, Inc., 197^^.

Lea ther Tanning and Finishing Indust ry . SCS Engineers, Inc., 1976.

Meta ls Min ing Industry . M R I , Inc., 1976.

Organ ic Chemica ls , Pest ic ides, and Explosives Industr ies. TRW Systems, Inc.,, 1976.

Paint and A l l i ed Products Indust ry , C o n t r a c t Solvent Rec la im ing Operat ions, and Fac to ry App l ied Coat ings. Wapora, Inc., 1976.

Pe t ro leum Re f in ing Industry. 1976.

Pharmaceut ica l Industry. A . D . L i t t l e , Inc., 1976.

Rubber and Plast ic Industry. Foster D. Snel l , Inc., 1976.

Storage and Pr imary Bat te r ies Industr ies. Versar , Inc., 1975.

3. Ba t te l le M e m o r i a l I ns t i t u te . Program for the Management of Hazardous Waste. Volumes I and 2. U.S. Env i ronmenta l P ro tec t i on Agency , O f f i c e of Solid Waste Management Programs, Washington, D . C , 197'^.

k. Bonner, W.A. and A .3 . Cas t ro . Essentials of Modern Organ ic Chemis t r y . Reinhold Publishing Corpo ra t i on , New York , 1965.

5. Booz-A l len App l ied Research, Inc. A Study of Hazardous Waste Ma te r ia l s , Hazardous E f f e c t s , and Disposal Methods. U.S. Env i ronmen ta l P ro tec t ion Agency, C inc inna t i Labora to r ies , C inc inna t i , Ohio, 1972.

6. Brescia, F., 3. A ren ts , H. Me is l i ch , and A . Turk . Fundamentals of Chemis t r y . Academic Press, New Y o r k and London, 1970.

22

1-15

7. Bre ther ick , L. Handbook of Reac t i ve Chemica l Hazards. CRC Press, Inc., C leve land, Ohio, 1975.

8. Vector and Waste Management Sect ion Fi les. C a l i f o r n i a Depar tmen t of H e a l t h ; Berkeley, Los Angeles, and Sacramento, C a l i f o r n i a .

9. Ca l i f o rn ia Indust r ia l Waste Surveys. C a l i f o r n i a Depar tmen t of Hea l t h , Sacramento, Ca l i f o rn i a , 1977.

10. Ca l i f o rn ia L iqu id Waste Haulers Record . C a l i f o r n i a Depa r tmen t of H e a l t h , Sacramento, Ca l i f o rn i a , 1977.

11. Ca l i f o rn ia Manufac tu re rs Assoc ia t ion. C a l i f o r n i a Manu fac tu re rs Regis ter . Times M i r r o r Press, Los Angeles, Ca l i f o rn i a , 1975.

12. Case Histor ies of Acc idents in the Chemica l Indust ry . Manu fac tu r i ng Chemis ts Associat ion, Washington, D . C ; 1962, 1970, and 1976. Case H is to ry Nos. : 262, 1566, and 2172.

13 Chemica l Da ta Guide fo r Bulk Shipment by Water . U.S. Depar tmen t of Transpor ta t ion , Coast Guard, Washington, D . C , 1976.

Ik . Chemica l Hazards Response In fo rma t ion System, Hazardous Chemica l Da ta . Volumes 1 and 2. CG-^ ' *6 -2 , U.S. Depa r tmen t of T ranspor ta t ion , Coast Guard , Washington, D . C , January 197'f.

15. The Chemis t r y of A c r y l o n i t r i l e . Second Ed i t i on . Amer i can Cyanamid Co. , Pe t ro -Chemica l Dept . , New York , 1959.

16. The Chenri istry of the Amino Group. 5. Pata i , ed i to r . In tersc ience Publ ishers, New York , London, Sydney, Toronto , 1968.

17. The Chemis t r y of the Carbony l Group. 3. Zabicky, ed i to r . Interscience Publ ishers, New York , London, Sydney, Toronto , 1970.

18. The Chemis t ry of the Cyano Group. Z. Rappopor t , ed i to r . In tersc ience Publ ishers, New York , London, Sydney, Toronto , 1970.

19. The Chemis t r y of the N i t r o and N i t roso Groups, Part I. H. Feuer, ed i to r . In tersc ience Publishers, New Y o r k , London, Sydney, Toronto , 1969.

20. The Chemis t r y of the Th io l Group, Par t I. S. Pata i , ed i to r , In tersc ience Publishers, New York , London, Sydney, Toron to , 197^*.

2 1 . Concise Chemica l and Technica l D i c t i o n a r y . Th i rd Ed i t ion . H. Bennet t , ed i to r . Chemica l Publ ishing Co. , Inc., New Y o r k , NY , 197'i.

22. C o t t o n , F.A. and G. Wi lk inson. Advanced Inorganic Chemis t r y . Th i rd Ed i t ion . In tersc ience Publ ishers, John Wiley and Sons, Inc. , New Yo rk , London, Sydney, Toronto , 1972.

23. C R C Handbook of Chemis t r y and Physics. 5kXh Ed i t ion . R . C Weast, ed i to r .

. 2 3

1-16

CRC Press, Inc. , C leve land , Ohio, 1973.

2k. CRC Handbook o f Labora to ry Safe ty . N.V. Steere, ed i to r . The Chemica l Rubber Company, C leve land , Ohio, 1967.

25. Encyclopedia of Chemica l Technology, K i r k - O t h m e r . Second Ed i t ion . M. Grayson and D. Eck ro th , ed i to rs . John Wi ley and Sons, Inc. , New Y o r k , London, Sydney, Toronto , 1963-1972.

26. Env i ronmenta l l y Hazardous Waste Disposal F i les . Oregon Depa r tmen t of Env i ronmenta l Qua l i t y , Por t land , Oregon, 1976 and 1977.

27. ' Epoxy Resins. Advances in C h e m i s t r y Series No. 92. R.F. Gould , ed i to r . Amer i can Chemica l Society , Washington, D . C , 1970.

28. Eto, M. Organophosphorous Pest ic ides. Organ ic and Bio log ica l Chemis t r y . C R C Press, Inc., C leve land , Ohio, 197^*.

29. Fa i t h , W.L. , D.B. Keyes, and R.L. C l a r k . Indust r ia l Chemica ls . Th i rd Ed i t i on . John Wi ley and Sons, Inc. , New Y o r k , London, Sydney, 1966.

30. Farm Chemica ls Handbook, 1978. Me is te r Publ ishing Company, Wi l loughby, Ohio , 1978.

3 1 . Fieser, L .J . and M. Fieser. Advanced Organ ic Chemis t r y . Reinhold Publ ishing Corpora t ion , New Yo rk , 1961.

32. F i re Pro tec t ion Guide on Hazardous Ma te r ia l s . S ix th Ed i t i on . Na t iona l F i re P ro tec t ion Assoc ia t ion , Boston, Massachuset ts, 1975.

33. The Form of Hazardous Waste M a t e r i a l s . Rol l ins Env i ronmenta l Services, Inc., W i lm ing ton , De laware , 1972.

3k. Gardner, W. and E.I. Cooke. Chem ica l Synonyms and Trade Names. Seventh Ed i t ion . C R C Press, Inc. , C leve land , Oh io , 1971.

35. Geissman, T .A . Pr incip les of O rgan i c Chemis t r y . W.H. Freeman and Company, San Francisco, 1977.

36. Gorham In te rna t iona l , Inc. Study o f Sol id Waste Management Pract ices in the Pulp and Paper Industry . U.S. Env i ronmen ta l P ro tec t i on Agency, Washington, D . C , February 197^^.

37. Guide fo r Safety, in the Chemica l Labo ra to ry , Manu fac tu r i ng Chemists Assoc i a t ion . Second Ed i t ion . Van Nos t rand Rheinhold co. . New Y o r k , N Y , 1972.

38. Handl ing " Guide fo r Po ten t i a l l y Hazardous Ma te r i a l s . A . D . Baskin, ed i to r . M a t e r i a l Management and Safe ty , Inc . , N i les , IL , 1975.

39. Handl ing and Uses of the A l k a l i M e t a l s . Advances in Chemis t r y Series No. 19., A m e r i c a n Chemica l Society, Wash ing ton , D . C , 1957.

1-17

kO. Hawkins, E.G.E. Organ ic Peroxides. D. Van Nost rand Company, Inc., Toron to , New Y o r k , London, 1961.

' ^ l . Hawley , G.G. The Condensed Chemica l D i c t i o n a r y . E igh th Ed i t i on . Van Nost rand Reinho ld Company, New Y o r k , C i n c i n n a t i , To ron to , London, Melbourne, 1971.

k2. Hazardous Waste Disposal Damage Repor ts . U.S. Env i ronmenta l P ro tec t i on Agency, O f f i c e of Solid Waste Management Programs, Hazardous Waste Management D iv is ion , Washington, D . C , June 1976.

k3. Hazardous Waste Management Law, Regulat ions, and Guide l ines f o r the Hand l ing o f Hazardous waste. C a l i f o r n i a Depa r tmen t of H e a l t h , Sacramento , C a l i f o r n i a , February 1975.

kk. Hendr ickson, J .E, , D .J . C r a m , and G.S. Hammond . Organ ic Chemis t r y . Th i rd Ed i t i on . M c G r a w - H i l l Book Co. , New Yo rk , 1970.

k5. House, H.O. Modern Synthe t ic React ions. W.A. Ben jamin , Inc. , Menlo Park, Ca l i f o rn i a , 1972.

k6. Indust r ia l Hygiene and Tox ico logy. Volumes I - I I I . F.A. Pa t t y , ed i to r . In tersc ience Publ ishers, Inc. , New Yo rk , 1958.

k7. Indust r ia l Po l lu t ion Con t ro l Handbook. H.F. Lund, ed i to r . M c G r a w - H i l l Book Co. , New Y o r k , St. Louis, San Francisco, 1971.

k i , K i m b a l l , V.S. Waste O i l Recovery , and Disposal . Noyes Da ta Co rpo ra t i on , New Jersey, London, 1975.

k9. Kuhn , R.J . and H.W. Dorough. Carbamate Insect ic ides: Chemis t r y , B iochemis t ry , and Tox ico logy . CRC Press, Inc. , C leve land , Ohio , 1976.

50. Lawless, E.W., T .L . Ferguson, a n d . A . F . Meiners . Guidel ines fo r the Disposal of Smal l Quant i t ies of Unused Pest ic ides. U.S. Env i ronmen ta l P ro tec t i on Agency, O f f i c e of Research and Deve lopment , Na t iona l Env i ronmen ta l Research Cente r , C i n c i n n a t i , Oh io , June 1975.

51 . Marger ison, D. and G.L. East. I n t roduc t ion to Po lymer C h e m i s t r y . Pergamon Press, L t d . , O x f o r d , London, New York , 1967.

52. M C / B Chemica l Reference Manual . Volume I I . M C / B . Manu fac tu r i ng Chemis ts , No rwood , Oh io , June 1976.

53. M i l l a n , I. Ketones. Chemica l Publ ishing Co. , New Y o r k , 1968.

5k. The Merck Index. N in th Ed i t i on . Me rck and Company , Inc., Rahway, New Jersey, 1976.

55. Mor r i son , R.T. and R.N. Boyd. Organ ic C h e m i s t r y . Second Ed i t i on . A l l y n and Bacon, Inc . , Boston, 1969.

56. Nemerow, N .L . L iqu id Waste of Indust ry : Theor ies, P r a c t i c e , ' and T rea tmen t .

25

1-18

Addison-Wesley Publishing Co., Reading, MA, Menlo Park, CA, London, Don Mills, Ontario, 1972.

57. An Outline of Organic Chemistry, College Outline Series. F. Degering, editor. Barries and Noble, Inc., New YOrk, I9k6.

58. ' Osmond, R.G.D. Personal Communication. Department of the Environment, London, England, April 1977.

59. Pesticide Index. Fif th edition. W.J. Wiswesser, editor. The Entomological Society of America, College Park, Maryland, 1976.

50. Ruder, L.R., J.H. Cobbs, J.W. Field, Jr., W.D. Findley, S.L. Vokurka, and B.W. Rolfe. Review and Assessment of Deep Well Injection of Hazardous Waste.

. U.S. Environmental Protection Agency, National Environmental Research Center, •Solid and Hazardous Waste Research Laboratory, Cincinnati, Ohio, 1975.

61. Registry of Toxic. Substances. 1976 Edition. H.E. Christensen and E.J. Fairchild, editors. U.S. Department of Health, Education, and Welfare, Rockville, Maryland, June 1976.

62. Report to Congress: Disposal of Hazardous Wastes. U.S. Environmental Protection Agency, Office of Solid Waste Management Programs, Washington D.C, I97k.

63. Resource Conservation and Recovery'Act of 1976. PL 9't-580, 9'fth Congress, October 21, 1976.

6k. Riegel's Handbook of Industrial Chemisty, Seventh Edition. J.A. Kent, editor. Van Nostrand Reinhold Company, New York, Cincinnati, Toronto, • London, Melbourne, 197't.

65. Rinehart, K.L. Oxidation and Reduction of Organic Compounds. Prentice-Hall, Inc., Englewood Cliffs , New Jersey 1973.

66. Royals, E.E. Advanced Organic Chemistry. Prentice-Hall, Inc., Englewood Cliffs, New Jersey 1959.

67. Rutledge, T.F. Acetylenes and Allenes. Reinhold Book Corporation, New Yorl<, Amsterdam, London, 1969.

68. Sandler, S.R. and W. Karo. Polymer Synthesis. Volumes I and I I . Academic Press, Inc., New York, 197 *.

69. Sax, I.N. Dangerous Properties of Industrial Materials. Third Edition. Van Nostrand Reinhold Company, New York, 1968.

70. Schieler, L. and D. Pauze. Hazardous Materials. Delmar Publishers, Albany, New York, 1976.

71. Sidgwick, N.V. The Organic Chemistry of Nitrogen. ' Clarendon Press, Oxford, 1966.

; 26 .

1-19

72. SRI, In te rna t iona l , Handbook of Hazardous Waste. Federa l M i n i s t r y of the In te r io r , Federa l Republ ic of Germany, 197^*.

73. Standard Indus t r ia l C lass i f i ca t i on Manua l . Execu t i ve O f f i c e of the President , O f f i c e of Management and Budget , S ta t i s t i ca l Po l i cy D i v i s i on , Washington, D . C , 1972.

7k. Stone, R.B., P.L. Aamed t , M.R. Engler, and P. Maiden. Eva lua t ion of Hazardous Waste Emplacement in M ined Openings. U.S. Env i ronmen ta l P ro tec t i on Agency, Munic ipa l Env i ronmenta l Research Labo ra to ry , O f f i c e of Research and Deve lop ment , C i n c i n n a t i , Oh io , December 1975.

75. Szmant, H.D. Organ ic C h e m i s t r y . P r e n t i c e - H a l l , Inc. , Englewood C l i f f s , New Jersey, 1957.

76. Tox ic and Hazardous Indus t r ia l Chemica ls Safe ty Manual for Hand l ing and Disposal, w i t h T o x i c i t y and Hazard Da ta . The In te rna t i ona l Techn ica l I n f o rma t i on Ins t i tu te , Toranomon-Tach ikawa Bldg. 6-5, 1 Chome, N ish i -Sh imbash i , M i n a t o - K u , Tokyo, Japan, 1975.

77. TRW Systems, Inc. Recommended Methods of Reduc t ion , N e u t r a l i z a t i o n Recovery, or Disposal of Hazardous Waste. Volumes I - X V I . U.S. Env i ronmenta l Pro tec t ion Agency , Washington, D . C , 1973.

78. Wiberg, E., and E. Amberge r . Hydr ides of the Elements of Ma in Groups I-IV. Elsevier Publ ishing Co. , A m s t e r d a m , London, New Yo rk , 1971.

79. Zol l inger, H.. Azo and D iazo C h e m i s t r y : A l i p h a t i c and A r o m a t i c Compounds. Interscience Publ ishers, Inc. , New Yo rk , London, 1961.

27

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APPENDICES

APPENDIX I. LIST OF C H E M I C A L SUBSTANCES

This appendix l is ts the chemica l substances tha t may be found in hazardous wastestreams. The l i s t is not inc lus ive but represents the data compi led through a l i t e r a t u r e survey and examina t ion of hazardous waste management prac t ices . ,

The l i s t consists of t h ree co lumns. The f i r s t co lumn l is ts the chemica l or t rade names in a lphabet ica l order. The t rade names are denoted by asterisks (•) . The second co lumn l is t the synonyms or common names of the chemica l substances when ava i lab le . The t h i r d co lumn l is ts the r e a c t i v i t y group numbers (RGN) assigned to the substances as der ived in Appendix 2. A compound may be assigned more than one R G N .

This appendix is used to obtain the RGN of waste constituents when known specifically. The RGN is used to determine the compatibility of the combinations of wastes according to the compatibility method in Section k.

The chemical s'ubstances l i s ted were compi led f r o m several sources. The l i s t of Hazardous Wastes and Hazardous Ma te r ia l s and L i s t of Ex t r eme l y Hazardous Wastes and Ex t reme ly Hazardous Ma te r i a l s in Ca l i f o rn ia ' s Indus t r ia l Waste Law of 1972 (Ref . kk) served as the s ta r t i ng re fe rence . The p r imary sources of i n f o rma t i on consisted of published reports (Ref. 1, 7, 12, 13, I k , 32, and 52) i d e n t i f y i n g the hazardous chemica l substances in indust r ia l wastes t reams. Add i t i ona l chemica l ent r ies were aibstracted f r o m the Ca l i f o rn ia Waste Haulers Record f i les (Ref . 10), Ca l i f o rn i a Ex t reme ly Hazardous Waste Disposal P e r m i t f i les (Ref. 8), and the TRW Systems' repor t on recommended methods of reduc t ion , neu t ra l i za t i on , recovery , and disposal of hazardous wastes (Ref. 77).

Names

A b a t e * Acenaphthene Ace tamide Aceta ldehyde A c e t i c ac id A c e t i c anhydride Acetone Acetone cyanohydr in A c e t o n i t r i l e Acetophenone Ace toxybu tane Acetoxypentane A c e t y l acetone

Synonyms RGN

32 16 6 5 3

107 Dimethyl ketone 19 Hydroxyisobutyronitri le k, 26 Methyl cyanide 26

19 Butyl acetate 13 Amyl acetate 13 Amyl acetate

19

28

1 -21

Names Synonyms RGN

A c e t y l azide A c e t y l benzoyl peroxide A c e t y l bromide A c e t y l ch lor ide Ace ty lene A c e t y l n i t r a te A c e t y l peroxide Ac ro le i n A c r y l i c ac id A c r y l o n i t r i l e Ad ip i c ac id Ad ipon i t r i l e Aga l l o l

Aga loare tan

A ld ica rb A ld r i n A l k y l a luminum ch lor ide A l k y l resins A l lene A l l y l a lcohol A l l y l bromide A l l y l ch lor ide A l l y l ch lorocarbonate A l l y l ch lo ro fo rma te A l l y l t r i ch lo ros i lane A lum inum A luminum aminoborohydr ide A l u m i n u m borohydr ide A luminum bromide A lum inum carbide A luminum chlor ide A lum inum d ie thy l monochlor ide A lum inum f luor ide A lum inum hydr ide A lum inum hypophosphide A lum inum phosphide A luminum te t raaz idobora te Aminobenzene Aminobutane Aminoch lo ro to luene Aminod ipheny l Aminoethane Aminoethano l Aminoethano l amine Aminohexane Aminomethane Aminopentane Aminophenol

Aqua l in

Me thoxye thy lme r cur ie ch lor ide

M e t h o x y m e t h y l m e r c u r i c ch lor ide

Temik*

2 - P r o p e n - I - o l Bromopropene Chloropropene A l l y l ch l o ro fo rma te A l l y l ch lorocarbonate

17, 17, 27, 5, 3, 26,

.102 30 107 107 28 102 30 103 103 103 3 26 2k

2k 20 17 107 101 28 •

17 17 17 17 107

22, 23 107

13, 13,

Die thy la l um inum chlor ide

105,

105, 15,

An i l i ne Buty l amine Ch lo ro to lu id ine

E thy lamine

Hexy lamine M e t h y l am ine A m y l a m i n e

7,

7,

107 107 105 107 107 107 105 107 107 8 7 7 17 7 7 7 7 7 7 7 31

29

1-22

Names Synonyms RGN

Aminopropahe Isopropyl amine. 7 Amino prop ion i t r i le 7 , 26 Amino th iazo le 7, 8 Aminoto luene Tolu id ine 7 Ammon ia 10 Ammon ium arsenate 2k Ammon ium azide 102 Ammon ium b i f luor ide 15 Ammon ium ch lorate 102, lOk A m m o n i u m d ichromate 2k, 102 Ammon ium f luor ide 15 A m m o n i u m he xani t rocobal t a t e 2k, 102 Ammon ium hydroxide 10 Ammon ium hypophosphide 105 Ammon ium molybdate 2k Ammon ium n i t ra te 102 Ammon ium n i t r i doosm ate 2k, lOk Ammon ium n i t r i t e 102 Ammon ium perch lorate lO f A m m o n i u m per iodate 102, lOk Ammon ium permanganate 2k, 102, lOk A m m o n i u m persulf ate IQk Ammon ium picrate 102 Ammon ium sul f ide 33, 105 Ammon ium te t rach roma te 2k, lO'* A m m o n i u m te t rape roxych roma te 2k, 102, lOk Ammon ium t r i ch roma te 2k, lOk A m y l ace ta te Ace toxy pentane 13 A m y l a lcohol k A m y l ch lo r ide Chloro pentane 17 A m y l cyanide 26 A m y l a m i n e Aminopentane 7 Amy lene Pentene 28 A m y l mercaptar i Pentaneth io l 20 An i l ine 7 A n i m e r t * V -101 Tetrasul 20 Anisole Ik Anisole chlor ide 107 Anthracene 16 A n t i m o n y 23 , 2k An t imony chlor ide An t imony t r i ch lo r i de 2k, 107 A n t i m o n y f luor ide An t imony t r i f luor. ide 2k, 107 An t imony n i t r ide 2k , 25 A n t i m o n y oxychiloride 2k An t imony oxide An t imony t r i ox ide 2k. A n t i m o n y pentachlor ide 2k A n t i m o n y pentaf luor ide 2k A n t i m o n y pentasul f ide 2k, 33, 105 A n t i m o n y perch lora te 2k, lO f A n t i m o n y potassium t a r t r a t e 2k

30

1-23

Names Synonyms RGN

An t imony su l fa te A n t i m o n y sul f ide An t imony t r i b rom ide A n t i m o n y t r i ch lo r ide An t imony t r i f l u o r i d e A n t i m o n y t r i iod ide An t imony t r i ox ide A n t i m o n y t r i su l f a te A n t i m o n y t r i su l f i de A n t i m o n y t r i v i n y l Aqua l in Aqueous solutions & mix tu res A re t a n *

A r o c l o r * Arsen ic Arsen ic bromide Arsen ic chlor ide Arsen ic dis luf ide Arsen ic iodide Arsen ic oxide Arsen ic pentaselenide Arsen ic pentasul f ide Arsen ic pentoxide Arsen ic sul f ide Arsen ic t r i b romide Arsen ic t r i ch lo r ide Arsen ic t r i f l uo r i de Arsen ic t r i i od ide Arsen ic t r i su l f i de Ars ine Askare l Asphal t

Az idocarbony l guanidine Az ido -s - t r i azo le Azinphos e thy l Az i r i d i ne a ,a -Azod i i sobu ty ron i t r i l e A z o d r i n * B a k e l i t e * Banol Bar ium Bar ium azide Bar ium bromate Bar ium carbide Bar ium chlorate Bar ium chlor ide Bar ium chromate Bar ium f luor ide Bar ium f luos i l i ca te

A n t i m o n y t r i s u l f a t e A n t i m o n y t r i su l f i de

A n t i m o n y ch lor ide A n t i m o n y f l uo r ide

A n t i m o n y oxide A n t i m o n y su l fa te A n t i m o n y su l f ide

Ac ro l e i n

M e t h o x y e t h y l m e r cur ie ch lo r ide

Po lych lo r ina ted biphenyl

A rsen ic t r i b r o m i d e Arsen ic t r i ch lo r i de Arsen ic su l f ide Arsen ic t r i i od ide Arsen ic pentoxide

Arsen ic oxide Arsen ic d isu l f ide A rsen i c b romide Arsen ic ch lor ide

Arsen ic iodide

Po lych lo r ina ted biphenyl

E thy lene im ine

Monocrotophos

Carbanolate

2k,

2k,

2k,

2k,

21,

2k,

33, 2k, 2k, 2k, 2k,

2k 105 107 107 107 107

2k 2k

2k, 33 2k, 107 5, 103

106 2k 17 2k 107 107 105 107

2k 2k 33 2k 105 107 107

2k 107 105 105 17 101 102 8 32 103 26 32 101 9

107 102 lOk 107 \0k

2k lOk 2k 2k

2k, 2k, 33, 2k,

2k,

33, 2k, 2k,

2k, 33, 2k,

8.

7, 8,

2k, 2k, 2k, 05, 2k,

2k, 15,

31

1-24

Names Synonyms RGN

Barium hydride 2k, 105 Barium hydroxide 10, 2k Barium hypophosphide 2k, 105 Barium iodate 2k, \^k Barium iodide 2k Barium monoxide Barium oxide 10, 2k, 107 Barium nitrate 2k, \^k Barium oxide Barium monoxide 10, 2k, 107 Barium perchlorate 2k, lO'* Barium permanganate 2k, 10^ Barium peroxide 2k, \m Barium phosphate 2k Barium stearate 2k Barium sulfide 2k, 33, 105, 107 Barium sulfite 2k Bassa* BPMC 9 Bayer 251^*1 Fensulfothion 32 Baygori* 9 Benzadox Topcide* 6 Benzcd bromide 17 Benzal chloride 17 Benzaldehyde 5 Benz-a-pyrene 16 Benzene 16 Benzene diazonium chloride 8, 102 Benzene phosphorus dichloride 107 Benzidine 7 Benzoic acid 3 Benzonitrile 26 Benzophenone 19 Benzoquinone Quinone 19 Benzotriazole 8, 102 Benzotribromide 17 Benzotrichloride 17 Benzotrifluoride Trifluoromethylbenzene 17 Benzoyl chloride

Trifluoromethylbenzene 107

Benzoyl peroxide Dibenzoyl peroxide 30, 102 Benzyl alcohol k Benzylamine 7 Benzyl benzene Diphenylm ethane 16 Benzyl bromide Bromotoluene 17 Benzyl chloride Chlorotoluene 17 Benzyl chlorocarbonate Benzyl chloroformate 17 Benzyl chloroformate Benzyl chlorocarbonate 17 Benzyl silane

Benzyl chlorocarbonate 105, 107

Benzyl sodium 105 Beryllium 2k Beryllium copper alloy 2k Beryllium fluoride 15. 2k Beryllium hydride 2k, 105, 107

32

1 -7R

Names Synonyms RGN

Bery l l i um hydroxide 10, 2k Bery l l i um oxide 2k Bery l l i um sul f ide 33, 105 Bery l l i um te t rahyd robo ra te 2k, 105, 107 B i d r i n * 32 B ismuth 22, 23, 2k Bismuth chromate 2k Bismuth ic acid 2k Bismuth n i t r ide 2k, 25, 102 Bismuth penta f luor ide 2k, 107 B ismuth pentaoxide 2k Bismuth sul f ide 2k, 33, 105 B ismuth t r i b r o m i d e 2k Bismuth t r i ch lo r i de 2k Bismuth t r i i od ide 2k Bismuth t r i ox ide 2k Bismuth t r i su l f i de 2k, 33, 105 Blada-f u m * Sul fo tepp 32 Blue v i t r i o l Copper su l fa te 2k Bomyi 32 Borane 2k, 107 Bordeaux arsenites 2k Bor ic ac id 1 Boron a rseno t r ib romide 2k, 105 Boron bromodi iod ide 2k, 107 Boron d ibromoiod ide 2k, 107 Boron n i t r i de 2k, 25 Boron phosphide 2k, 107 Boron t r i az ide 2k, 102 Boron t r i b rom ide 2k, 107 Boron t r i ch lo r i de 2k, 107 Boron t r i f l u o r i d e 2k, 107 Boron t r i i od ide 2k, 107 Boron t r i su l f i de 2k, 33, 105 BPMC Bassa* 9 Brass 23 Bromic ac id 2 Bromine 104 Bromine azide 102 Bromine cyanide Cyanogen bromide 11 Bromine monof luor ide lOk, 107 Bromine penta f luor ide lOk, 107 Bromine t r i f l u o r i d e \0k, 107 . Bromoacety lene 17 Bromobenzoyl acet 'ani l ide 6, 19 Bromobenzy l t r i f l u o r i d e 17 Bromodiborane 105 Bromod ie thy la luminum 107 Bromod imethoxyan i l i ne \k Bromo fo rm Tr ib romomethane 17

33

1-26

Names

Bromomethane Bromophenol Bromopropene Bromopropyne Bromosilane Bromotoluene Bromotrichloromethane Bromotrifluom ethane Bromoxynil

Bronze Buna-N* Bunker fuel oil Butacarb Butadiene Butadiyne Butanal Butane Butanediol Butanethiol Butanetriol trinitrate Butanoi Butanone Butenal Butene Butene-2-one Butyl acetate n-Butyl acrylate Butylamine Butyl alcohol t-Butyl azidoformate Butyl benzene Butyl benzyl phthalate Butyl cellusolve* Butyl dichloroborane Butyl ether Butly formate Butyl fluoride Butyl glycidyl ether Butyl hydroperoxide t-Butyl hypochlorite n-Butyl lithium Butyl mercaptan Butyl peroxide Butyl peroxyacetate Butyl peroxybenzoate Butyl peroxypivalate t-Butyl perbenzoate t-Butyl-3-phenyl oxazirane Butyl trichlorosilane

Synonyms

Methyl bromide

Allyl bromide

Benzyl bromide

3,5-Dibromo-4-hydroxy benzonitrile

Diacetylene Butyraldehyde

Butyl mercaptan

Butyl alcohol Methyl ethyl ketone Crotonaldehyde

Methyl vinyl ketone Acetoxybutane

Aminobutane Butanoi

Phenylbutane

Dibutyl ether

Butanethiol

t-Butyl perbenzoate

Butyl peroxyacetate

3k

RGN

17 17, 31

17 17

105 17 17 17

17, 26, 31 23

101 101

9 28, 103

28 5

29 k

20 102

k 19 5

28 19 13

13, 103 7 k 8

16 13 k

105 Ik 13 17 3k 30

102, lOk 105, 107

20 30 30 30 30 30 3k

107

1-27

Names

Butyramide Butyraldehyde Butyric acid Butyronitrile Bux* Cacodylic acid Cadmium Cadmium acetylide Cadmium amide

Synonyms

Butanoi

Dimethylarsenic acid

2k, 2k,

RGN

6 5 3

26 9

2k 23, 2k

105, 107 10, 107

Cadmium azide 2k, 102 Cadmium bromide 2k Cadmium chlorate 2k, lOk Cadmium chloride 2k Cadmium cyanide 11, 2k Cadmium fluoride 15, 2k Cadmium hexamine chlorate 2k, 102 Cadmium hexamine perchlorate 2k, 102 Cadmium iodide 2k Cadmium nitrate 2k, 102, lOk Cadmium nitride 2k, 25, 102 Cadmium oxide 2k Cadmium phosphate 2k Cadmium sulfide 2k, 33, 105 Cadmium trihydrazine chlorate 2k, 102 Cadmium trihydrazine perchlorate . 2k, 102 Calcium 2k, 102 Calcium arsenate 2k Calcium arsenite 2k Calcium bromate \0k Calcium carbide 105, 107 Calcium chlorate lOk Calcium chlorite [Qk Calcium fluoride * 15 Calcium hexammoniate 105 Calcium hydride 105, 107 Calcium hydroxide Hydrated lime 10 Calcium hypochlorite Calcium oxychloride lOk Calcium hypophosphide 105 Calcium iodate lOk Caldum-manganese-silicon alloy * 23 Calciunri nitrate Lime ni t rate, nitrocalcite [Qk Calcium oxide Slaked lime 10, 107 Calcium oxychloride Calcium hypochlorite lOk Calcium perchromate iOk Calcium permanganate lOk Calcium peroxide lOk Calcium phosphide 107 Calcium sulfide 33, 105 Camphor oil 101 Capric acid 3

35 1-28

Names

Caproic acid Caprylic acid Caprylyl peroxide Carbacrol Car bar yl Carbetamide Carbanolate Carbofuran Carbolic acid Carbolic oil Carbon, activated, spent Carbon bisulfide Carbon disulfide Carbon tetrachloride Carbon tetrafluoride Carbon tetraiodide Castrix Catechol Caustic potash Caustic soda CDEC Cellulose ' Cellulose nitrate Cerium Cerium hydride Cerium trisulfide Cerous phosphide Cesium Cesium amide Cesium azide Cesium carbide Cesium fluoride Cesium hexahydroaluminate Cesium hydride Cesium phosphide Cesium sulfide Chloral hydrate Chlordane Chlorestol Chlorf envinphos Chloric acid Chloi-ine Chlorine azide Chlorine dioxide Chlorine fluoroxide Chlorine monofluoride Chlorine monoxide Chlorine pentafluoride Chlorine trifluoride Chlorine trioxide

Synonyms

Hexanoic acid

Octyl peroxide

Banol Furadan* Phenol

Carbon disulfide Carbon bisulfide Tetrachloromethane

Crimidine

Potassium hydroxide Sodium hydroxide

Nitro cellulose 27,

33,

Trichloroacetaldehyde

Polychlorinated biphenyl

105, 33,

2,

102, lO't, 102, iOk,

IQk, IQk, 102,

RGN 3 3 30 31 9 6 9 9 31 31 101 20 20 17 17 17 7 31 10 10 12 101 102 22 105 105 105 21 107 102 105 15 105 107 107 105 5 17 17 32

IQk lOk 102 107 m 107 IQk 107 107 lOk

36 1-29

Names Synonyms RGN

Chloroaceta ldehyde Ch lo roace t ic ac id Chloroacetone Chloroacetophenone Ch loroacety l ch lor ide Chloroacety lene Ch lo roac ry lon i t r i l e Chloroazodin Chlorobenzene Chlorobenzot r iazo le Chlorobenzoyl peroxide Chlorobenzyl idene ma lonon i t r i l e Ch lo robu ty ron i t r i l e Chloro chromic anhydr ide Chlorocreosol C hi orodi borane Chlorod i isobuty l a luminum Ch lo rod imethy lamine diborane Chlorod in i t robenzene Chloro d in i t ro to luene Chlorod ipropy l borane Chloroethane Chloroethanol Ch loroethy len imine Ch lo ro fo rm Chlorohydr in Chloromethane Ch lo romethy l me thy l e ther Ch lo romethy l phenoxyacet ic ac id Ch lo ron i t roan i l ine Chloroni t robenzene Chloro pentane Chlorophenol Chlorophenyl isocyanate Ch lo rop ic r in

Chloropropane Chloropropene Chloropropylene oxide Chlorosi lane Chlorosul f onic acid Ch lo ro th i on * Chloroto luene Chloro to lu id ine Ch lo ro t r in i t robenzene B-C hi oro v iny l d ichloroar sine Ch lo rp ic r in Chromic ac id

Monoch lo roace t i c ac id Monoch loroacetone Phenyl ch lo rome thy l ketone

Ch romy l ch lo r ide 2k,

Din i t roch lo robenzene

Ethy l ch lo r ide

T r i ch lo rom ethane

M e t h y l ch lo r ide

N i t roch lo robenzene A m y l ch lo r ide

C h l o r p i c r i n , T r i c h l o r o n i t r o m ethane

Isopropyl ch lo r ide . A l l y l ch lo r ide Ep ich lo rohydr in

Benzyl ch lo r ide

P ic ry l ch lo r ide Lew is i te T r i c h l o r o n i t r o m ethane Ch rom ic anhydr ide,

C h r o m i u m t r i ox ide

8, 17, 17, 17,

lO**, 17,

5, 17 3, 17 17, 19 17, 19

107 102

17, 26 8, 17

17 17 30 26 26 107 31 105

05, 107 105

17, 27 17, 27

105 17 , 7 17 17 17 17 17 17 27 27 17 31 107

3, 17, 17,

17, 18, 17, 27, 102

•"17 17

17, 3k 105

1 17, 32

17 7, 17

17, 27, 102 2k

17, 27, 102

2, 2k, \Qk 37

1-30

Names Synonyms R G N

Chromic anyhdride

Chromi Chromi Chromi Chromi Chromi Chromi Chromi Chromi Chromi Chromi

c ch lor ide c f luor ide c oxide c su l fa te um um sul fa te c sul f ide um t r i ch lo r i de um t r i f l u o r i d e um t r iox ide

Chromyl ch lor ide Chrysene CMME Coal oi l Coal tar Cobal t Cobal t bromide Cobal t ch lor ide Cobal t n i t r a t e Cobaltous bromide Cobaltous ch lor ide Cobaltous n i t r a te Cobaltous resinate Cobaltous su l fa te Cobal t resinate Cobal t su l fa te Col lodion Copper Copper acetoarsen i te Copper ace ty l ide Copper arsenate Copper arseni te Copper ch lor ide Copper ch lo ro te t razo le Copper cyanide Copper n i t r a t e Copper n i t r i de Copper su l fa te Copper su l f ide Compound 1836 Co roxon* Coumafu ry l Couma te t ra l y l Cresol Cresol g l yd icy l e ther Cresote C r im id ine

Ch rom ium t r i ox ide . C h r o m i c acid

C h r o m i u m t r i ch lo r i de Ch rom ium t r i f l u o r i d e

Ch rom ium su l fa te

Ch rom ic su l fa te

Ch rom ic ch lor ide C h r o m i c f l uo r ide C h r o m i c ac id .

C h r o m i c anhydr ide Ch loro ch romic anhydr ide

Me thy l ch lo romethy l ether

Cobal tous bromide Cobal tous chlor ide Cobal tous n i t r a te Coba l t bromide Coba l t ch lor ide Coba l t n i t r a t e Coba l t resihate Cobal t su l fa te Cobal tous resinate Cobal tous su l fa te Pyroxy l in

Paris Green

Cupr i c arsenate Cupr ic ars'enite Cupr i c ch lor ide

Cupr i c cyanide Cupr i c n i t r a t e

Cupr ic su l fa te . Blue v i t r i o l

D ie thy l ch lo rv iny l phosphate

Fumar in

2, 2k,

15,

23,

2k,

{Qk 2k 2k 2k 2k 2k 2k

33, 105 2k

15, 2k

2, 2k, 2k, lOk,

2k,

2k,

2k, 102,

Cast r i x

IQk 107

16 Ik, 17

101 31

22, 23, 2k 2k 2k

[Qk 2k 2k

IQk 2k 2k 2k 2k 27 2k 2k

107 2k 2k 2k 2k

11, 2k 2k, IQk

2k, 25 • 2k

33, 105 17, 32

32 19 19 31 3k 31

7

23,

105,

2k,

38

1-31

Names Synonyms RGN

Crotonaldehyde Butenal 5 C ro t y l a lcohol k C r o t y l bromide 17 C r o t y l ch lor ide 17 Cumene Isopropyl benzene 16 Cumene hydroperox ide D ime thy lbenzy l hydrop>eroxide 30 Cupr ic arsenate Copper arsenate 2k Cupr ic arsenite Copper arseni te 2k Cupr ic c±iloride Copper ch lor ide 2k Cupr ic cyanide Copper cyanide 11, 2k Cupr ic n i t r a t e Copper n i t r a t e 2k, IQk Cupr ic su l fa te Copper su l fa te 2k Cupr ie thy lened iamine 7, 2k Cyanoacet ic ac id Ma lon ic n i t r i l e 3, 26 Cyanochloropentane 17, 26 Cyanogen 26 Cyanogen bromide Bromine cyanide 11 Cyanophenphos Surec ide* 26, 32 Cyanur ic t r i az ide 102 Cyc loheptane 29 Cyclohexane 29 Cyclohexanol k Cyclohexanone 19 Cyclohexanone peroxide 30 Cyc lohexy lamine 7 Cyc lohexeny l t r i ch lo ros i lane 107 Cyc lohexy l phenol 31 Cyc lohexy l t r i ch lo ros i lane 107 Cyclopentane 29 Cyc lopentano l k Cyclopentene 28 Cyclopropane 29 Cyc lo t r ime thy lene t r i n i t r a a m i n e RDX 27, 102 Cymene 16 Cyo lan * Phospholan 20, 32 2,k-D Dich lorophenoxyacet ic ac id 3, 17 Dasan i t * Fensul fo th ion 32 DBCP Dibromochloropropane 17 DCB Dichiorobenzene 17 DDD 17 DDNP Diazod in i t ropheno l 8, 27, 102 DDT

Diazod in i t ropheno l 17

DDVP Dich lorovos, Vapona* 17, 32 DEAC D ie thy la lum inum chlor ide 105, 107 Decaborane 107 D ecahydr ona pht hal ene Decal in 29 Deca l ih Decahydronaphthalene 29 Decane 29 Decanol k Decene 28

39

1-32

Names

Decy l benzene Delnav* Demeton-s-methy l su l fox id Diacetone alcohol D iacety l Diacetylene Diamine Diaminobenzene Diaminohexane Diazidoethane D iaz inon* Diazodin i t rophenol Dibenzoyl peroxide Diborane Diboron hexahydride D ibu ty l ether D ibu ty l phthalate 3 ,5-Dibromo- ' f -hydroxybenzon i t r i le Dibromochloropropane Dibromoethane Dichloroacetone Dichloroamine Dichlororobenzene Dichlorobenzidine Dich lorod imethy is i lane Dichloroethane Dichloroethene Dich loroether D ich loroethy l arsine Ethy l dichlorosi lane Ethy l ether Dichloro isocyanur ic ac id Dichloromethane Dichlorophene Dichlorophenol Dich lorophenoxyacet ic ac id Dichloropropane Dichloropropanol D i chloropropene Dichloropropylene Dichloro-s-- t r iaz ine-2, '^ ,5- t r ione Dichlorovos D icumy l peroxide Di cyclopentadi ene D ie ld r in Diethanolamine D ie thy l a luminum chlor ide

Die thy lamine D ie thy l benzene

Synonyms

D ioxa th ion Metasys tox R*

Butadiyne Hydraz ine Phenylene d iamine H exam ethy lened iam ine

DDNP Benzoyl peroxide Diboron hexahydr ide Diborane Buty l e ther

B romoxyn i l DBCP, Fumazone* , Nemagon* Ethylene d ibromide

DCB

D i m e t h y l d ichlorosi lane Ethy lene d ich lor ide D ich lo roe thy lene D ich lo roe thy l ether

D ich lo roe ther D ich lo ro -s - t r i az ine -2 , ' t , 5 - t r i one Methy lene ch lor ide

2,k-D Propylene d ich lor ide

D ich loropropy lene Dich loropropene D ic l i lo ro isocyanur ic ac id DDVP

8;

8, 27, 30, 105, 105,

Aluminum diethylmonochloride, DEAL

kO

RGN 16 32 32 19 19 28 105 7 7

102 32 102 102 107 107

Ik 13

17, 26, 31 17 17 19

lO' 17 17 107 17 17

Ik, 17 2k, 107

107 Ik, 17

IQk 17 17 31 17 17 17 17 17

IQk 17, 32

30 28 17

^, 7

105, 107 7 16

17,

7,

17, 3,

1-33

Names

D ie thy l ch lo rov iny l phosphate D ie thy l d ichlorosi lane D ie thy lene dioxide D ie thy lene glycol d i n i t r a te D ie thy lene g lycol monobuty l

ether aceta te ethy lene t r i am ine e thy l ether e thy l ketone e thy l to luamide ethy l z inc esel oi l f luorophospl ior ic ac id g lyc idy l ether isobuty l ene isobuty l ketone isopropanolamine isopropyl t jenzene hydroperoxide isopropyl be ry l l i um

ether peroxydi carbonate

Synonyms

Compxsund 1836

Dioxane

D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D

isopropyl isopropyl m e c r o n * me fox m e t h y l acety lene m e t h y l amine me thy lam ino azobenzene m e t h y l arsenic ac id me thy lbenzy l hydroperox ide m e t h y l butane m e t h y l butyne me thy l d ichlorosi lane methy ld i th iophosphor ic ac id me thy l ether m e t h y l f o r m a l me thy l f o rmamide methy lhexane d ihydroperoxide me thy l hydrazine m e t h y l ketone me thy l magnesium methy ln i t robenzene me thy l n i t rosoamine m e t h y l sulf ide meton n i t robenzene n i t roch lorobenzene

2 , ' f -D in i t ro -6 -sec -bu ty l phenol D in i t roc reso l D in i t ropheno l D in i t ropheny l hydrazine D in i t ro to luene

Z inc e thy l

B is(2,3-epoxypropyl ) e ther

Isopropyl e ther Isopropyl percarbonate Phosphamidon Hanane*

M e t h y l ye l low Cacody l i c ac id Cumene hydroperox ide Neohexane

D ich lo rod ime thy i s i l ane

U D M H Acetone

N i t r oxy lene N -N i t r osod ime thy l amine M e t h y l su l f ide

Ch lo rod in i t robenzene Dinoseb D N O C , E lgeto l 30

RGN

17, 32 107

Ik 27, 102

13 7

I.'* 19 6

2k, 105, 107 101

. 1 3k 28 19 17 30

2k, IQk, 107 ik 30 32

6, 32 28

7 7, 8

2k 30 29 28 107 32 Ik 19 6 30 8 19

105, 107 27

7, 27 20 32 27

17, 27 27, 31 27, 31 27, 31 8, 27

27 ' ^ l 1-34

Names

Dinoseb Dioxacarb Dioxane Dioxathion Dipentaerythritol hexanitrate Dipentene Diphenamide Diphenyl Diphenyl acetylene Diphenylamine Diphenylamine chloroarsine Diphenyl ethane Diphenyl ethylene Diphenyl methane Diphenylmethane diisocyanate Diphenyl oxide Dipicryl amine Di propyl amine Disulfoton Disulfuric acid Disulfur dinitride Disulfuryl chloride Disyston* Dithane* M-k5 Dithione* DNOC Dodecene Dodecyl benzene Dodecyl trichlorosilane Dowco-139* Dowicide I Dowtherm Durene Dyf onate* Dynes Thinner Elgetol 30 Endolsulfan Endothall Endothion Endrin EPN Epichlorohydrin Epoxybutane Epoxybutene Epoxyethane Epoxyethylbenzene Bis(2-3-Epoxypropyl) ether Ethane Ethanethiol Ethanol

Synonyms

2,'t-Dinitro-6-sec-butyIphenol

Diethylene dioxide Delnav*

Phenylbenzene

Phenarsazine chloride

Stilbene Benzylbenzene

Hexanitrodiphenylamine

Disyston*

Disulfoton

Sulfotepp " Dinitrocresol

Mexacarbate o-Phenyl phenol

Fonof OS

Dinitrocresol Thiodan*

Exothion

Chloropropylene oxide

Ethylene oxide Diglycidyl ether Ethyl mercaptan Ethyl alcohol

k2

RGN 27, 31

9 Ik 32

27, 102 28 6 16 16 7

7, 2k 16 16 16

18, 107 Ik

7, 27, 102 7

32 1

25, 102 107 32 12 32

27, 31 28 16 107 9 31 16 16 32 101

27, 31 17, 20

3 32 17 32

17, 3k 3k 3k

3k, 103 3k 3k 29 20

k

1-35

Names Synonyms RGN

E th i on * N ia la te 32 Ethoxyethanol k, Ik Ethy l acetate 13 Ethy l acetylene 28 E thy lac ry la te 13, 103 Ethy l alcohol Ethanol k Ethy lamine Aminoe thane ' 7 Ethy l benzene Phenyl ethane 16 Ethy l butanoate E thy l b u t y r a t e 13 Ethy l bu ty ra te E thy l bu tanoate 13 Ethy l chlor ide Ch lo roe thane 17 E thy l ch lo ro fo rmate 13, 17 Ethy l dichioroarsine D ich lo roe thy la rs ine 2k, 107 E thy l dichlorosi lane 107 Ethy l ether D ie thy l e ther ik Ethylene 28 Ethylene chromic oxide : 2k, IQk Ethylene ch lorohydr in k, 17 Ethylene cyanohydr in Hyd roxyp rop ion i t r i l e k, 26 Ethylene diamine 7 Ethylene d ibromide D ib romoethane 17 Ethylene d ichlor ide D ich lo roe thane 17 Ethylene glycol k Ethylene glycol d i n i t r a t e G lyco l d i n i t r a te 27, 102 Ethylene glycol monomethy l ether k, I k , 17 Ethy lene imine Az i r i d i ne 7, 103 Ethylene oxide Epoxyethane 34, 103 Ethy l f o rma te 13-2-Ethy lhexy l ac ry la te 13, 103 Ethy l mercaptan E thaneth io l 20 Ethy l n i t ra te ' 27, 102 Ethy l n i t r i t e 27, 102 Ethy l propionate .13 Ethy l t r ich loros i lane 107 Exothion Endothion 32 Eugenol 31 Fensul foth ion Bayer 25141, Dasan i t * 32 Ferbam 12 Fe r r i c arsenate 2k Fer r i c sul f ide 33 Ferrous arsenate I ron arsenate 2k Ferrous sul f ide 33, 105 Fluoranthrene 16 Fluorene 16 F luor ine 104, 107 Fluor ine azide 102 Fluor ine monoxide Oxygen d i f luo r ide 104, 107 F luoroacetan i l ide

Oxygen d i f luo r ide 6, 17

F luoroacet ic ac id 3 F luorobor ic acid 1, 15

43

1-36

Names Synonyms RGN

Fluorosulfonic acid Fluosulfonic acid Fluosilicic acid Fonof OS* Formaldehyde Formamide Formetanate hydrochloride Formic acid Fostion* Freon* Fumaric acid Fumarin Fumazone* Furadan* Furan Furfural Furfuran Gas oil, cracked Gasoline Germanium sulfide Glutaraldehyde Glycerin Glycidol Glycol di acetate Glycol dinitrate Glycol ether Glycolic acid Glycol monolactate trinitrate Glycolonitrile Gold- acetylide Gold cyanate Gold fulminate Gold sulfide Grease Guaiacol Guanyl nitrosaminoguanylidene hydrazine Guanidine nitrate Gun cotton Guthion* Hafnium Hanane* Hemimellitene Heptachlor Heptane Heptanal Heptanol Heptanone Heptene Hexaborane Hexachlorobenzene

Fluosulfonic acid Fluorosulfonic acid

Dyfonate* Methanal

Methanoic acid Prothoate

Coumafuryl Dibromochloropropane Carbofuran Furfuran

33,

Ethylene glycol dinitrate

Gold fulminate Gold cyanate

Nitrocellulose

Dimef ox

27,

27, 105,

33,

8, 27, 27,

1, 107 1, 107 1, 15

32 5 6 6 3 32 17 3 19 17 9 14 5 14 101 101 105 5 4 34 13 102 14 3

102 26 107 102 102 105 101 31 102 104 102 32 22 32 16 17 29 5 4 19 28 105 17

6,

44

1-37

Names Synonyms RGN

Hexadecyl trichorosilane Hexaethyl tetraphosphate Hexafluorophosphoric acid Hexahydride diborane Hexamethyl benzene Hexam ethyl enediamine Hexamethylenetetraamine Hexanal Hexanitrodiphenylamine Hexanol Hexanoic acid Hexene Hexylamine Hexyl trichlorosilane Hexyne HMX Hopcide* Hydrated lime Hydrazine Hydrazine azide Hydra zoic acid Hydriodic acid Hydrobromic acid Hydrochloric acid Hydrocyanic acid Hydrofluoric acid Hydrogen azide Hydrogen bromide Hydrogen cyanide Hydrogen fluoride Hydrogen iodide Hydrogen peroxide' Hydrogen phosphide Hydrogen selenide Hydrogen sulfide Hydroquinone Hydroxyacetophenone Hydroxydibromobenzoic acid Hydroxydiphenol Hydroxyhydroquinone Hydroxyacetophenone Hydroxyisobutyronitrile Hydroxyl amine Hydroxypropionitrile Hypochlorous acid Indene Indium Inerteen Iodine monochloride Iodine pentoxide

107 32

1, 15 Diborane 105, 107

16 Diaminohexane 7

7 5

D i p i c r y l a m i n e 7, 27, 102 D i p i c r y l a m i n e 4

Capro i c ac id 3 28

Aminohexane 7 107 28

102 9

Ca l c i um hydrox ide 10 D iamine 8, 105

8, 102 Hydrogen azide 102 Hydrogen iodide 1 Hydrogen bromide 1, 107 M u r i a t i c ac id 1 Hydrogen .cyanide 1, 11 Hydrogen f l uo r i de 1, 15 Hyd razo i c ac id 102 Hyd rob rom ic ac id 1, 107 Hyd rocyan i c ac id 1, 11 H y d r o f l u o r i c ac id 1, 15 Hydro iod i c ac id 1

104 Phosphine 105

24, 105 33, 105

31 19, 31 3, 17

31 31

19, 31 Ace tone cyanohydr in 4, 26

105 Ethy lene cyanohydr in 4, 26

2 16

22, 23, 24 Po lych lo r ina ted biphenyl 17

107 104

45

1-38

j^âmes

• Iron

Synonyms RGN j^âmes

• Iron 23 Iron arsenate Ferrous arsenate 24

. Isobutane 29 Isobutanol 4 Isobutyl acetate 13 Isobutyl acrylate 13, 103 Isobutylene 28 Isodecyl acrylate 13 Isodurene 16 Isoeugenol 31 Isohexane 29 Isooctane Trim ethyl pentane 29 Isooctene 28 Isopentane Methylbutane 29 Isophorone 19 Isoprene Methyl butadiene 28, 103 Isopropanol 4 Isopropyl acetate 13 Isopropyl acetylene 28 Isopropylamine Aminopropane 7 Isopropyl benzene Cumene 16 Isopropyl chloride Chloropropane 17

^Îsopropyl ether ^psopropyl mercaptan

Diisopropyl ether 14 ^Îsopropyl ether ^psopropyl mercaptan 20

.^-Isopropylmethyl carbamate 9 a-Isopropyl methylphosphoryl fluoride . - -'. . 17, 32 Isopropyl percarbonate Diisopropyl peroxydicarbonate 30 Isotactic propylene 101 J-100. 101 Jet oil 101 Kerosene 101 Lacquer thinner 101 Lancirin* 9 Lannate* Methomyl 9, 20 Lauroyl peroxide 30 Lead 23, 24 Lead acetate 24 Lead arsenate Lead orthoarsenate 24 Lead arsenite 24 Lead azide 24, 102 Lead carbonate 24 Lead dilorite 24, 104 Lead cyanide 11, 24 Lead dinitroresorcinate 24, 27, 102 Lead mononitroresorcinate 24, 27, 102 Lead nitrate 24, 104 Lead orthoarsenate Lead arsenate 24

^^Lead oxide ^^'.ead styphnate

24 ^^Lead oxide ^^'.ead styphnate Lead trinitroresorcinate 24, 27, 102

Lead sulfide 24, 33, 104

46

1 -39

Names

Lead trinitroresorcinate Lewisite Lime nitrate Lindane Lithium Lithium aluminum hydride Lithium amide Lithium ferrosilicon Lithium hydride Lithium hydroxide Lithium hypochlorite Lithium nitride Lithium peroxide Lithium silicxm Lithium sulfide London purple Lye Magnesium Magnesium arsenate Magnesium arsenite Magnesium chlorate Magnesium fluoride Magnesium nitrate Magnesium perchlorate Magnesium peroxide Magnesium sulfide Malathion Maleic acid

•Malonic nitrile Maneb Manganese Manganese acetate Manganese arsenate Manganese bromide Manganese chloride Manganese methylcyclopentadienyl-

tricarbonyl Manganese nitrate Manganese sulfide Manganous arsenate • Manganous bromide Manganous chloride Manganous nitrate Mannitol hexanitrate Matacil* Mayer's reagent Medinoterb acetate MeobaJ Mercaptoben zothiazole Mercatoethanol

Synonyms RGN

Lead styphnate 24, 27, 102 3-Chlorovinyl dichioroarsine 24 Calcium nitrate 104

17 21, 107

105, 107 10, 107

107 105, 107

10 104 25

104, 107 107

33, 105 24

Sodium hydroxide 10 21, 22

24 24

104 15

104 104 104

33, 105 32

3 Cyanoacetic acid 3, 26

12 22, 23, 24

24 Manganous arsenate 24 Manganous bromide 24 Manganous chloride 24

24 Manganous nitrate 24, 104

24, 33, 105 Manganese arsenate 24 Manganese bromide 24 Manganese chloride 24 Manganese nitrate 104 Nitromannite 27, 102

9 Mercuric potassium iodide 24

13, 27 9

8, 20 20

47

1-40

Names Synonyms RGN

Mercarbam Mercu r i c acetate Mercu r i c ammonium ch lor ide Mercur i c benzoate Mercu r i c bromide Mercu r i c ch lor ide Mercu r i c cyanide Mercu r i c d ioxysu l fa te Mercu r i c lodicle Mercu r i c n i t r a te Mercu r i c o leate Mercu r i c oxide Mercu r i c oxycyanide Mercu r i c potassium iodide Mercu r i c sa l icy la te Mercu r i c subsul fate Mercu r i c su l fa te Mercu r i c sul f ide Mercu r i c th iocyanate Mercu r i c th iocyanide Mercuro l Mercurous bromide Mercurous gluconate . Mercurous iodide Mercurous n i t r a te Mercurous oxide Mercurous su l fa te Mercury Mercury (vapor) Mercury , ace ta te Mercu ry ammonium c±iloride Mercury benzoate" Mercury b isu l fa te Mercury ch lor ide Mercury cyanide Mercu ry f u l m i n a t e Mercury iodide Mercury n i t r a te Mercury nucleate Mercury o leate Mercury su l fa te Mes i ty lene Mes i ty l oxide Mesu ro l * Metasystox-R Met ham Methanal M ethane Methane th io l Methano ic acid

Mercury ammon ium chlor ide Mercu ry benzoate

Mercu ry ch lo r ide Mercury cyanide M e r c u r i c subsul fa te Mercury iodide Mercu ry n i t r a t e Mercu ry o lea te

Mayer 's reagent Sa l icy la ted mercu ry Mercu r i c d ioxysu l fa te Mercury su l fa te

Mercury th iocyan ide Mercu ry t h i ocyana te Mercury nuc leate

Mercury b i su l f a te

M e r c u r i c ace ta te Mercu r i c ammon ium c±iloride Mercu r i c benzoate Mercurous su l fa te Me rcu r i c ch lo r ide Mercu r i c cyanide

Mercu r i c iodide Mercu r i c n i t r a t e Mercu ro l M e r c u r i c o lea te Me rcu r i c su l fa te 1,3,5- t r im e thy l benzene

Demeton -S -me thy l su l fox id

Formaldehyde

Methy l mercap tan Form ic ac id

32 24 24 24 24 24

11, 24 24 24

24, 104 24 24

11, 24, 102 24 24 24 24

24, 33, 105 24 24 24 24 24 24

24, 104 24 24 24

22, 24 24 24 24 24 24

11, 24 24, 102

24 24, 104

24 24 24 16 19 9 32 12 5 29 20 3

48

1 -41

Names Synonyms RGN

Methanol M e t h y l a lcohol 4 Me thomy l L a n n a t e * 9, 20 Me thoxye thy lme rcu r i c chlor ide A g a l l o l a r e t a n * 24 Me thy l acetate 13 Me thy l acetone 101 Methy l acety lene M e t h y l butyne 28 Methy l ac ry la te 13, 103 Methy l alcohol Methano l 4 Methy l a luminum sesquibromide 105, 107 Methy l a luminum sesquichlor ide 105, 107 Methy l amine Aminomethane 7 Methy l amyl aceta te 13 N-Methy l ani l ine 7 Methyl az i r id ine Propy lene imine 7 Methy l benzene Toluene 16 Methy l bromide Bromomethane 17 Methy l butadiene Isoprene 28, 103 Methy l butane Isopentane 29 Methy l butene 28 M ethyl buty l ether 14 Me thy l t - b u t y l ketone 19 Methy l butyne Isopropyl acety lene 28 Methy l bu ty ra te 13 Methy l ch lor ide Ch lo romethane 17 Methy l c l i lo rocarbonate M e t h y l ch l o ro fo rma te 13, 17 Methy l ch lo ro fo rm 17 Methy l ch lo ro fo rma te M e t h y l ch lorocarbonate 13, 17 Methy l ch lo romethy l ether C M M E 14, 17 Methy l cyanide A c e t o n i t r i l e 26 Me thy l cyclohexane 29 Methy l d ichioroars ine 24 M ethyl d ichlorosi lane 107 Methy l ene chlor ide D ich lo romethane 17 M ethyl ene di isocyanate 18, 107 4,4-Methy lene b is(2-chloroani l ine) 7, 17 Methy l ethyl ch lor ide 17 MethyJ e thy l ether 14 MethyJ ethyl ketone Butanone 19 Methy l e thy l ketone peroxide 30 Methy l e thy l pyr id ine 7 Me thy l f o r m a t e 13 MethyJ hydrazine Monomethy l hydrazine 8 Methy l iodide 17 MethyJ isobutyl ketone 19 Methy l isocyanate 18, 107 Methy l isopropenyl ketone 19 Methy l magnesium bromide 105, 107 Methy l magnesium chlor ide 105, 107 Methy: magnesium iodide 105, 107 Methy l mercap tan Me thane th io l 20

49

1-42

Names Synonyms RGN

Methy l methacry la te 13, 103 Methy l naphthalene 16 Methy l parath ion 32 Methy l pentanoate M e t h y l va le ra te 13 Methy l propionate 13 Methy l n-propyl ketone 19 Methy l styrene 28, 103 Methy l su l f ide D i m e t h y l su l f ide 20 Methy l t r i ch lo ros i l ane 107 Methy l va le ra te M e t h y l pentanoate 13 Methy l v iny l ketone Butene-2-one 19 Me thy l ye l low D i m e t h y l a m i n o azobenzene 7, 8 Mevinphos Phosdr in * 32 Mexacarbate D o w c o - 1 3 9 * 9 M inera l sp i r i ts 101 M i n t a c o l * Paraoxon 32 M i p c i n * 9 M o b a m * 9 M o c a p * 32 Molybdenum 22, 23, 24 Molybdenum anhydr ide Mo lybdenum t r i ox ide 24 Molybdenum sul f ide 24, 33, 105 Molybdenum t r iox ide Mo lybdenum anhydr ide 24 Molybd ic acid 24 Monochloroacetone Ch lo roace tone 17, 19 Monoch lo roacet ic ac id C h l o r o a c e t i c ac id , O, . 17 Monocrotophos A z o d r i n * 32 Monoethanol amine ^, 7 Monof luorophosphor ic ac id 1 Monoisopropanolamine 4, 7 Monomethy l hydrazine M e t h y l hydrazine 8 Morphol ine 7 Munic ipa l sol id waste Refuse 101 M u r i a t i c acid H y d r o c h l o r i c ac id 1 Nabam 12 Nack . Sodium-potassium al loy 21 , 107 Nak Sodium-potassium al loy 2 1 , 107 Naptha 101 Naphthalene 16 Naphthol 31 Naphthy lamine T Naphthy l mercap tan 20 Napht i te T r in i t ronaph tha lene 27, 102 Nemagon* D ib romoch lo ropropane 17 Neohexane D i m e t h y l butane 29 4-NBP N i t r ob i pheny l 27 N iac i de * 12 N ia la te E th ion 32 N icke l 22, 24 N icke l ace ta te 24

50

1-43

Names Synonyms RGN

Nickel ant imonide 24, 107" Nickel arsenate Nickelous arsenate 24 Nickel arsenite Nicke lous arsen i te 24 Nickel carbonyl N icke l t e t r aca rbony l 24 Nicke l chlor ide Nickelous ch lo r ide 24 Nickel cyanide 11, 24 N icke l n i t r a te Nickelous n i t r a t e 24, 104 Nickelous arsenate N icke l arsenate 24 Nickelous arseni te N icke l arsen i te 24 Nickelous chlor ide N icke l ch lo r ide 24 Nickelous n i t ra te N icke l n i t r a t e 24, 104 Nicke l selenide 24 N icke l subsulf ide 24, 33, 105 Nicke l su l fa te 24 Nicke l te t racarbony l N icke l carbony l 24 N i t ran i l i ne N i t r oan i l i ne 7, 27 N i t r i c ac id 2 N i t roan i l i ne N i t r a n i l i n e 7, 27 Ni t robenzene N i t robenzo l 27 N i t robenzo l N i t robenzene 27 N i t rob ipheny l 4-NBP 27 N i t r o c a l c i t y Ca l c i um n i t r a t e 104 Ni t roce l lu lose Cel lu lose n i t r a t e , gun co t ton 27, 102 Ni t roch lorobenzene . Ch lo ron i t robenzene 17, 27 N i t rogen dioxide 104 N i t romann i te Mann i to l hexan i t ra te 27, 102 Ni t rogen mustard 7, 17 N i t rogen te t rox ide . 104 N i t rog l yce r i n T r i n i t r o g l y c e r i n 27, 102 N i t rohydroch lo r i c ac id 2 Ni t rophenol 27, 31 Ni t ropropane 27 N i t rosod imethy lamine D i m e t h y l n i t r o s i amine 7, 27 Ni t rosoguanidine 27, 102 N i t ros ta rch Starch n i t r a t e 27, 102 N i t roxy lene N i t r o x y l o l , D ime thy ln i t r obenzene 27 Ni t roxy los N i t r o x y l e n e , D ime thy ln i t robenzene 27 N-N i t rosod imethy lamine D i m ethy l n i t rosoamine 7, 27 Nonyl phenol 31 Nonyl t r i ch lo ros i lane 107 Nonane 29 Nonene 28 Nonanone 19 Nonanal 5 Nonanbl 4 Octadecy l t r i ch lo ros i lane 107 Octadecyne 28 Octamethy lpyrophosphoramide Schradan 6, 32 Octanal 5 Octane 29

51

1 -44

Names Synonyms RGN

Octanohe Octanol Octene Octyl peroxide Octyl trichlorosilane Oil of bergamot Oil of vitriol Oleum Orris root Orthozenol Osmium Osmium amine nitrate Osmium amine perchlorate Oxam yl Oxalic acid

Caprylyl peroxide

Sulfuric acid Sulfuric acid

o-Phenyl phenol

19 4

28 30

107 101

1 2, 24

101 31

23, 24 24, 104 24, 104

9

Oxygen d i f luor ide 104, 107 PCB Po lych lo r ina ted biphenyl 17 Paper 101 Paraoxon M i n t a c o l * 32 Parath ion 32 Paris green Copper acetoarsen i te 24 PETD Po ly ram c o m b i * 12 PETN P e n t a e r y t h r i t y l t e t r a n i t r a t e , , . . P e n t a e r y t h r i t o l t e t r a n i t r a t e 27, 102

Pentaborane 105 Pentachlorophenol - 17, 31 Pen tae ry th r i t o l t e t r a n i t r a t e P e n t a e r y t h r i t y l t e t r a n i t r a t e , PETN. 27, 102 Pen tamethy l benzene 16 Pentane 29 Pentaneth io l A m y l mercap tan 20 Pentanal Valer aldehyde 5 Pentanone 19 Pentene Amy lene 28 Penty lamine 7 Pentyne 28 Perace t i c ac id Peroxyace t i c ac id 3, 30 Perbromic a d d 2 Perch lo r ic ac id 2 Perch loroethy lene Te t rach lo roe thy lene 17 Perch lo romethy l mercap tan T r i ch lo romethy l su l f eny lch ior ide 17, 20 Perchlorous acid 2 Perch lory l f luor ide 104 Per iod ic a d d 2 Permonosu l fur ic ac id 1 Peroxyace t i c acid Perace t i c a d d 3, 30 ' F E T D Polyram c o m b i * 12 Pet ro leum naptha 101 Pet ro leum oi l 101 Phenanthrene 16 Phenarsazine chlor ide D ipheny lamine chloroars ine 7, 24

52

1-45

Names Synonyms RGN

Phenol Carbo l i c ac id 31 Phenyl ace t i c ac id 3 Phenyl a c e t o n i t r i l e 26 Phenyl acety lene 16 Phenylani l ine D ipheny lamine 7 Phenylbenzene Dipheny l 16 Phenylbutane Buty lbenzene 16 Pheny lch loromethy l ketone Chloroacetophenone 17, , 19 Phenyl d ich ioroars ine 24 Phenylene d iamine Diaminobenzene 7 Phenylethane Ethylbenzene 16 Phenyl hydrazine hydroch lor ide 8 o-Phenyl phenol Or thozeno l , Dow ic ide 1 31 Phenyl t r i ch lo ros i lane 107 Phenyl v a l e r y l n i t r i l e 26 Phenylpropane Propylbenzene 16 Phlorogluc inol 31 Phorate T h i m e t * 32 Phosdr in* Mevinphos 32 Phosphamidon D i m e c r o n * 32 Phosphine Hydrogen phosphide 105 Phospholan C y o l a n * 20, , 32 Phosphonium iod ide 105, 107 Phosphoric ac id 1 Phosphoric anhydr ide Phosphorus pentox ide 107 Phosphoric su l f ide Phosphorus pentasul f ide 33, 105, 107 Phosphorus (Amorphous red) 105, 107 Phosphorus (Whi te i -Yel low) 105 Phosphorus heptasu l f ide 33, 105 Phosphorus oxybromide Phosphoryl b romide 104, 107 Phosphorus oxych lor ide Phosphoryl ch lor ide 104, 107 Phosphorus pentach lor ide Phosphoric ch lor ide 107 Phosphorus pentasu l f ide Phosphoric su l f ide 33, 105, 107 Phosphorus pentox ide Phosphoric anhydr ide 107 Phosphorus sesquisul f ide Tetraphosphorus t r i su l f i de 33, 105, 107 Phosphorus t r i b r o m i d e 107 Phosphorus t r i ch lo r i de 107 Phosphorus t r i su l f i de 33, 105, 107 Phosphoryl bromide Phosphorus oxybromide 104, 107 Phosphoryl ch lor ide Phosphorus oxych lo r ide 104, 107 Phthal ic ac id 3 P ic ramide T r i n i t r oan i l i ne 7, 27, 102 P icr ic ac id T r in i t ropheno l 27, 31 , 102 Picr id ine

T r in i t ropheno l 7

P ic ry l d i l o r i d e Ch lo ro t r i n i t robenzene 17, 27, 102 Pi peri dine 7 P i r im ica rb 9 Polyglycol ether 14 Polyamide resin 101 Po lybrominated b iphenyl 17

53

1-46

Names Synonyms RGN

Polybutene Polychlorinated biphenyls

Polychlorinated triphenyls Pol ethylene Polyester resin Polymeric oil Polyphenyl polymethylisocyanate Polypropylene Polyram combi* Polysulfide polymer Polystyrene Polyurethane Polyvinyl acetate Polyvinyl chloride Polyvinyl nitrate Potasan Potassium Potassium acid fluoride Potassium aluminate Potassium arsenate Potassium arsenite Potassium bifluoride Potassium bichromate Potassium bromate Potassium butoxide Potassium cyanide Potassium dichloroisocyanurate Potassium dichromate Potassium dinitrobenzfuroxan Potassium fluoride Potassium hydride Potassium hydroxide Potassium nitrate Potassium nitride Potassium nitrite Potassium oxide Potassium perchlorate Potassium permanganate Potassium peroxide Potassium sulfide Promecarb' Propanal Propane Propanethiol Propanoic acid Propanol Propargyl bromide Propargyl chloride 2-Propen-l-oi

PCB, Askarel, Arochior*, Chlorextol, Inerteen

PETD

Potassium fluoride

Potassium fluoride Potassium dichromate

Potassium bichromate

Potassium acid fluoride

Caustic potash Sciltpeter

Propionaldehyde

Propyl mercaptan Propionic acid Propyl alcohol

Allyl alcohol

54

18, 28, 20,

27, 21,

24,

24,. 27, 105, 102,

24, 104, 33,

28 17 17 101 101 101 107 101 12 101 101 101 101 101 102 32 107 15 10 24 24 15 104 104 10 11 104 104 102 15 107 10 104 25 104 107 104 104 107 105 9 5 29 20 3 4 17 17 4

1 -47

Names Synonyms RGN

Propio lactone Propionaldehyde Propionamide Propion ic acid Prop ion i t r i l e Propyl aceta te Propy l alcohol Propy lamine Propy l benzene Propylene d ich lor ide Propylene g lycol Propylene glycol monomethy l ether Propylene oxide Propy lene imine Propy l ether Propy l f o r m a t e Propy l mercaptan Propy l Tr ich loros i lane Pro thoa te Pseudocumene Pyr id ine Pyrogal lo l Pyrosu l fu ry l ch lor ide Py roxy l i n Quinone^ Raney nickel R D X Refuse Resins Resorc ino l Rub id ium Sa l icy la ted mercu ry Sal igenin Sa l tpe ter Schradan

Selenious ac id Selenium Selenium d ie thy ld i t h ioca rbamate Selenium f luo r ide Selenous acid S i l icochlorof orm Si l icon te t rachor ide Si l icon t e t r a f l uo r i de Si lver acety l ide Silver azide Si lver cyanide Si lver n i t r a te Si lver n i t r ide Silver s typhnate

Propanal

Propanoic ac id

Propanol

Phenyl propane Dich loropropane

M e t h y l az i r id ine

Propaneth io l

Fos t i on * 1,2,4 t r ime thy lbenzene

D isu l f u r y l ch lor ide Co l lod ion Benzoquinone

C y c l o t r i m e t h y l e n e t r i n i t r a m i n e M u n i d p a l so l id waste

Mercu r i c sa l i cy la te

Potassium n i t r a t e O c t a m e t h y l pyrophosphoramide,

O M P A Selenous acid

Selenious ac id Tr ich lo ros i lane

13 5 6 3 26 13 4 7 16 17 4

4, 14 34, 103

7 14 13 20 107 32 16 7

31 107 27 19 22

27, 102 101 101 31 '21 24 31

102, 104

22, 6, 1, 23, 12, 15,

Silver t r i n i t r o r e s o r c i n a t e

24, 102,

24, 24,

32 24 24 24 24

1, 24 107 107

15, 107 105, 107 24, 102 11, 24

24, 104 25, 102 27, 102

55

1-48

.^James Synonyms RGN

Silver sulf ide Silver tet razene Silver t r i n i t ro reso rc ina te Slaked l ime Smokeless powder Sodamide Soda n i ter Sodium Sodium ac id f l uo r ide Sodium a luminate Sodium a luminum hydr ide Sodium amide Sodium arsenate Sodium arseni te Sodium azide Sodium b ichromate Sodium b i f luor ide Sodium bromate Sodium cacody la te Sodium carbonate Sodium carbonate peroxide

iSodium ch lo ra te Sodium c±i lori te Sodium chromate Sodium cyanide Sodium d ich loro isocyanurate Sodium d ichromate Sodium dim e thy l arsenate Sodium f luor ide Sodium hydr ide Sodium hydroxide Sodium hypoch lor i te Sodium hyposul f i te Sodium methy l a te Sodium methox ide Sodium molybdate Sodium monoxide Soidium n i t r a t e Sodium n i t r ide Sodium n i t r i t e Stxlium oxide Sodium pentachlorophenate Sodium perch lorate Sodium permanganate Sodium peroxide Sodium phenolsul fonate Sodium picxamate Sodium polysul f ide Sodium potassium al loy Sodium selenate

Si lver s typhnate C a l c i u m oxide

Sodium amide Sodium n i t r a t e

Sodium f l uo r ide

Sodamide

Sodium d ich romate Sodium f l uo r ide

Sodium d imethy la rsenate

24,

24,

21,

Sodium b ich romate Sodium cacody la te Sodium ac id f l uo r i de

Caus t i c soda, Lye

Sodium th iosu l fa te Sodium methox ide Sodium me thy la te

Sodium oxide Soda n i ter

Sodium monoxide

33, 24, 27, 10, 10, 105, 10, 105, 10,

24,

Nak, Nack

24,

105, 10, 10. 10, 10,

10,

24, 104, 27, 21,

105 102 102 107 102 107 104 107 15 105 107 107 24 24 102 104 15 104 24 10 104 104 104 24 11 104 104 24 15 107 10 104 105 107 107 24' 107 104 25 104 107 31 104 104 107 31 102 101 107 24

56

Names Synonyms RGN

Sodium sul f ide Sodium th iosu l fa te Stann ic chlor ide Stann ic sul f ide S tarch n i t r a te St i lbene Stoddard solvent S t ron t i um S t ron t i um arsenate S t ron t i um dioxide S t ron t i um monosul f ide S t ron t i um n i t r a te S t ron t i um peroxide S t ron t i um te t rasu l f i de Styphn ic ac id S ty rene Succ in ic ac id S u c d n i c a d d peroxide Su i fony l ch lor ide Su l fony l f lour ide Su l fo tepp Sul fur ch lor ide Sul fur (e lementa l ) Su l fu r i c ac id Su l f u r i c anhydride Sul fur monoch lor ide Sul fur mustard Su l fur oxych lor ide Su l fu r penta f luor ide Sul fur t r i ox ide Su l fu ry l ch lor ide Su l fu ry l f l uo r ide Suprac ide* Surec ide* Syn the t i c rubber T C D D TEDP TEL TEPA TEPP THF T M A T M L T N B T N T Ta l l o i l Ta l l ow Tar T e l l u r i u m hexaf luor ide T e m i k *

T in t e t r a c h l o r i d e

N i t r o s t a r c h D ipheny l e thy lene

S t ron t i um peroxide

S t ron t i um diox ide

T r i n i t r o reso rc i no l Viny lbenzene

24, 33, 27,

24,

24, 27, 16,

24, 33, 24,

33, 31, 28,

Su l fu ry l ch lo r ide

D i t h i o n e * , B l a d a - F u m * Sulfur monoch lor ide

O i l of V i t r i o l , O leum Sulfur t r i ox i de Sul fur ch lo r ide

Th iony l ch lo r ide

Su l fu r ic anhydr ide Sul fony l ch lor ide Sul fony l f l uo r i de U l t r a c i d e * Cyanophenphos

Te t rach lo rod ibenzo-p -d iox in T e t r e t h y l d i th ionopyrophosphate T e t r a e t h y l lead T r i s - ( l - a z i r i d i n y l ) phosphine oxide T e t r a e t h y l pyrophosphate Te t rahyd ro fu ran T r i m e t h y l a m i n e T e t r a m e t h y l lead Tr in i t robenzene T r i n i t r o to l uene

Aldicarb

24, 33, 105 105 107 105 102 16 101 24 24 104 105 104 104 105 102 103 3

30 107 107 32 107 101 107 107 107 20 107 107 107 107 107 32 32 101 17 32 24 32 32 14 7 24 102 102 101 101 101

15, 24 9, 20

2, 104,

15, 104,

6,

27, 27,

57

1-50

Names Synonyms RGN

Tet raborane 105 Te t rach lo rod ibenzo-p-d iox in TCDD 14, 17 Te t rach lo roe thane 17 Te t rach lo roe thy lene Perch loroethy lene 17 Te t rach lo romethane Carbon te t rach lo r i de 17 Tet rach loropheno l 17, 31 Te t rach lo ropropy l ether 14, 17 Tet radecene 28 T e t r a e t h y l d i th ionopyrophosphate TEDP 32 T e t r a e t h y l lead TEL 24 T e t r a e t h y l pyrophosphate TEPP 32 Te t rahyd ro fu ran THF 14' •Te t ramethy l enediamine 7 T e t r a m e t h y l lead T M L 24 T e t r a m e t h y l succ inon i t r i l e 26 T e t r a n i t r o m ethane 27, 102 Tet rapheny l ethy lene 16 Tetraphosphorus t r i su l f i de Phosphorus sesquisulf ide 33, 105, 107 Tet rase len ium t e t r a n i t r i d e 24, 25, 102 Tet rasu l A n i m e r t * V-101 20 Te t rasu l fu r t e t r a n i t r i d e 25, 102 Te t razene 8, 102 Tha l l i um 24 Tha l l i um n i t r ide 24, 25, 102 Tha l l i um sulf ide 24, 33, 105 Thal lous su l fa te 24

- T h i m e t * Phorate 32 Th iony l ch lor ide Sulfur oxych lo r ide 107

. Th iocarbony l ch lor ide Thiophosgene 107 T h i o d a n * Endosulf an 17, 20 Th ionaz in Zinophos* 32 Th iony l ch lor ide Sulfur oxych lo r ide 107 Thiophosgene Thiocarbony l chlor ide 107 Thiophospl iory l ch lor ide 107 Th i ram 12 Thor ium 22 , 23, 24 T in te t rach lo r i de Stannic c±iloride 24, 107 T i t a n i c ch lor ide T i tan ium te t rach lo r i de 24, 107 T i t an i um 22 , 23, 24 T i t an i um sesquisulf ide 24, 33, 105 T i t a n i u m sul fate 24 T i t a n i u m sul f ide 24, 33, 105 T i t an i um te t rach lo r ide T i tan i c ch lo r ide 24, 107 T M A T r i m e t h y l a m i n e 7 TNB Tr in i t robenzene 27, 102 T N T T r i n i t r o to l uene 27, 102 Tolualdehyde 5 Toluene To luo l , Methy lbenzene 16 Toluene di isocyanate 18, 107 To lu lc a d d 3

58

1-51

Names Synonyms RGN

Toluidine Toluol Topc ide* T ran id * Triamphos Tr ibromomethane T r i -n -bu ty l a luminum Tr icadmium d in i t r ide T r i ca lc ium d in i t r ide Tr icesium n i t r ide Tr ich loroaceta ldehyde Tr ich loroborane Tr ich loroethane Tr ich loroethene Tr ich loro isocyanur ic ac id Tr ich lo rom ethane Tr i ch lo romethy l su l feny l ch lor ide T r i ch lo ron i t romethane Tr ich lo rophenoxyacet ic ac id Tr i chl oro pro pane Tr ich loros i lane Tr i decene Tr ie thano lamine T r ie thy l a luminum Tr ie thy l an t imony T r ie thy l arsine T r ie thy l b ismuthine Tr ie thy lamine Tr ie thy lene phosphoramide

Tr ie thy lene te t raamine Tr ie thy l st ib ine Tr i f luoroethane Tr i f luo romethy lbenzene Tr i isobuty l a luminum Tr i lead d in i t r i de T r imercu ry d in i t r ide T r ime thy l a luminum Tr im e thy lamine T r ime thy l an t imony T r ime thy l arsine 1.2.4- Tr imethy lbenzene 1.3.5- T r i m ethyl benzene T r ime thy l b ismuthine T r ime thy l pentane Tr imethy ls t ib ine T r i - n - but yl borane Tr in i t roan i l i ne Tr in i t roan iso le Tr in i t robenzene

Amino to luene Toluene, Methy lbenzene Benzadox

Wepsyn* 155 B r o m o f o r m

Ch lo ra l hydra te

T r i ch lo roe thy lene

C h l o r o f o r m Pe rch lo rome thy l mercap tan C h l o r o p i c r i n

S i l i coch lo ro fo rm

T r i e t h y l s t i b i n e

T r i s ( l - a z i r i d i n y l ) phosphine oxide

T r i e t h y l an t imony

Benzo t r i f l uo r i de

9, 6,

24,

24, 5,

17,

7 16 6

26 32 17 07 25 25 25 17

107 17 17

104 17

17, 20 27, 102

3, 17 17

107 28

^, 7 107

24, 105, 105, 24,

107 107 24

7

6,

24, 105,

24, 24,

T M A T r i m e t h y l s t i b i n e .

Pseudocumene Mes i t y l ene

Isooctane

T r i m e t h y l an t imony

P ic ram ide T r i n i t r o p h e n y l m e t h y l ether TNB

24,

32 7

107 17 17 107 102 102 107 7

105 107 16 16 24 29

105, 107 105, 107

7, 27, 102 14, 27

27, 102

105, 25, 25, 105,

24, 24,

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Names Synonyms RGN

Trinitrobenzoic acid Trinitroglycerin Trinitronaphthalene Trinitrophenol Trinitrophenyl methyl ether Trinitroresorcinol Trinitrotoluene Trioctyl aluminum Triphenyl ethylene Triphenyl methane Tripropylamine Tripropyl stibine Trisilyl arsine

Tris-(l-aziridinyl) phosphine oxide

Trithion Trithorium tetranitride Trivinyl stibine Tsumacide* Tungstic acid Turpentine UDMH Ultracide* Undecene Unisolve Uranium nitrate Uranium sulfide Uranyl nitrate Urea formaldehyde Urea nitrate ,VC Valeraldehyde Valeramide Valeric acid Vanadic acid anhydride Vanadium oxytrichloride Vanadium pentoxide Vanadium sulfate Vanadium tetroxide Vanadium trichloride Vanadium trioxide Vanadyl sulfate Vapona* Vinyl acetate Vinyl azide Vinylbenzene Vinyl (±loride Vinyl cyanide Vinyl ethyl ether Vinyl isopropyl ether

Nitroglycerin Naphtite Picric acid Trinitroanisole Styphnic acid TNT

TEPA, Triethylene phosphoramide

Dimethyl hydrazine Supracide*

Uranyl nitrate

Uranium nitrate

Vinylidene chloride Pentanal

Vanadium pentoxide

Vanadic acid anhydride Vanadyl sulfate

Vanadium sulfate DDVP

Styrene

3, 27, 102 27, 102 27, 102

27, 31, 102 14, 27

27, 31. 102 27, 102 105, 107

16 16 7

24, 107 24, 107 6, 32

32 24, 25 24, 107

9 24 101 8 32 28 101

24, 104 24, 33, 105

24, 104 5

27, 102, 104 17, 103

5 6 3 24 24 24 24 24

24, 107 24 24 32

13, 103 102

16, 28, 103 17, 103 26, 103

14 17

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Names

Vinylidene chloride Vinyl toluene Vinyl trichlorosilane VX Water Waxes Wepsyn* 155 Wood Zectran* Zinc Zinc acetylide Zinc ammonium nitrate Zinc arsenate Zinc arsenite Zinc chloride Zinc dioxide Zinc ethyl Zinc cyanide Zinc fluoborate Zinc nitrate Zinc permanganate Zinc peroxide Zinc phosphide Zinc salts of dimethyl

dithiocarbamic acid Zinc sulfate Zinc sulfide Zineb* Zinophos* Zi ram*

. Zirconium Zirconium chloride Zirconium picramate Zirconium tetrachloride

Synonyms

VC

Triamiphos

Dowco 139*

Zinc peroxide Diethyl zinc

24,

RGN 17, 103 28, 103

107 20, 32

106 101

6, 32 101 9

22, 23, 24 24, 105, 107

24, 104 24 24 24

102, 104, 107 24, 105, 107

24 15 104

Zinc dioxide 24, 102,

104, 105,

11, 24,

24, 24, 104

104, 107 24, 107

TWoazin

Zirconium tetrachloride

Zirconium chloride

12, 24 24

24, 33, 105 12, 24

20 12, 24

22, 23, 24 24

24, 104 24

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APPENDIX 2. LIST OF WASTE CONSTITUENTS BY CHEMICAL CLASS AND REACTIVITY

This appendix categorizes the chemical substances in Appendix 1 into reactivity groups according to molecular functional groups, chemical classes, or chemical reactivities. The substances are divided into 41 Reactivity Group Numbers (RGN) and listed consecutively in the first two pages of this appendix. RGN 1 to 34 are categorized based on molecular functional groups, 101 to 107 on chemical reactivities. The reactivity groupings here are identical to those depicted in the Hazardous Wastes Compatibility Chart (Figure 6) in Section 5 of this report.

The succeeding pages of this appendix contain the tabulations of the chemical substances in Appendix 1 under their respective RGN. All trade names in the tables are denoted by asterisks (*) consistent with the notations used in Appendix 1.

This appendix is used to obtain the RGN of hazardous wastes when the waste constituents are known only by chemical classes, molecular functional groups, or

.chemical reactivities. The information is used to determine the compatibility of the ^combinations of the wastes according to the compatibility method in Section 4 of this 'eport.

; • The- listing was developed from the same primary references used in Appendix 1, namely Ref. 1, 7. 8, 10, 12, 13, 14, 32, 44, 52, and 77. The reactivity groupings of waste constituents presented here are not inclusive. Additions or deletions may be made in the future when more information is available from the management of hazardous wastes.

Reactivity Group Number

1 2 3 4 5 6 7 8 9

10 11 12 13 14 15 16

Group Name

Acids, Mineral, Non-oxidizing Acids, Mineral, Oxidizing Acids, Organic Alcohols and Glycols Aldehydes Amides Amines, Aliphatic and Aromatic Azo Compounds, Diazo Compounds, and Hydrazines Carbamates Caustics Cyanides Dithiocarbamates Esters Ethers Fluorides, Inorganic Hydrocarbons, Aromatic

62

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Reactivity Group Number

17 18 19 20 21 22

23

24 25 26 27 28 29 30 31 32 33 34

• 101 102 103 104 105 106 107

Group Name

Halogenated Organics Isocyanates Ketones Mercaptans and Other Organic Sulfides Metals, Alkali and Alkaline Earth, Elemental and Alloys Metals Other Elemental and Alloys in the Form of Powders, Vapors or Sponges Metals, Other Elemental, and Alloy, as Sheets, Rods, Moldings, Drops, etc Metals and Metal Compounds, Toxic Nitrides Nitriles Nitro Compounds Hydrocarbon, Aliphatic, Unsaturated Hydrocarbon, Aliphatic, Saturated Peroxides and Hydroperoxides, Organic Phenols and Creosols Organophosphates, Phosphothioates and Phosphodithioates Sulfides, Inorganic Epoxides

Combustible and Flammable Materials, Miscellaneous Explosives Polymerizable Compounds Oxidizing Agents, Strong Reducing Agents, Strong Water and Mixtures Containing Water Water Reactive Substances

GROUP 1 Acids, Mineral, Non-Oxidizing

Boric acid Chlorosulf onic acid Difluorophosphoric acid Disulfuric acid Fluoroboric acid Fluorosulfonic acid Fluosilicic acid Hexafluorophosphoric acid Hydriodic acid Hexafluorophosphoric acid Hydriodic acid Hydrobromic acid Hydrochloric acid Hydrocyanic acid Hydrofluoric acid Monofluorophosphoric acid

Permonosulf uric acid Phosphoric acid Selenous acid

GROUP 2 Acids, Mineral Oxidizing

Bromic acid Chloric acid Chromic acid Hypochlorous acid Nitric acid Nitrohydrochloric acid Oleum Perbromic acid Perchloric acid Perchlorous acid

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GROUP 2 Acids, Mineral Oxidizing cont'd

Periodic acid Sulfuric acid

GROUP 3 Acids, Organic (All Isomers)

Acetic acid Acrylic acid Adipic acid Benzoic acid Butyric acid Capric acid Caproic acid Caprylic acid Chloromethylphenoxyacetic acid Cyanoacetic acid Dichlorophenoxyacetic acid Endothal Fluoroacetic acid Formic acid Fumaric acid Glycolic acid Hydroxydibromobenzoic acid Maleic acid Monochloroacetic acid Oxalic acid Peracetic acid Phenyl acetic acid Phthalic acid Propionic acid Succinic acid Trichlorophenoxyacetic acid Trinitrobenzoic acid Toluic acid Valeric acid

GROUP 4 Alcohols and Glycols (All Iso-mers)

Acetone cyanohydrin Allyl alcohol Aminoethanol Amyl alcohol Benzyl alcohol Butanediol Butyl alcohol Butyl ceilosolve* Chloroethanol Crotyl alcohol Cydohexanol

Cyclopentanol Decanol Diacetone alcohol Dichloropropanol Diethanol amine Diisopropanol amine Ethanol Ethoxyethanol Ethylene chlorohydrin Ethylene cyanohydrin Ethylene glycol Ethylene glycol monomethyl ether Glycerin Heptanol Hexanol Isobutanol Isopropanol Mercaptoethanol Methanol Monoethanol amine Monoisopropanol amine Monoisopropanol amine Nonanol Octanol Propanol Propylene glycol Propylene glycol monomethyl ether Triethanolamine

GROUP 5 Aldehydes (All Isomers)

Acetaldehyde Acrolein Benzaldehyde Butyraldehyde Chloral hydrate Chloroacetaldehyde Crotonaldehyde Formaldehyde Furfural Glutaraldehyde Heptanal Hexanal Nonanal Octanal Propionaldehyde Tolualdehyde Urea formaldehyde Valeraldehyde

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GROUP 6 Amides (All Isomers)

Acetamide Benzadox Bromobenzoyl acetanilide Butyramide Carbetamide Diethyltoluamide Dimethylformamide Dimefox Diphenamide Fluoroacetanilide Formamide Propionamide Schradan Tris-(I-aziridinyl) phosphine oxide Wepsyn* 155 Valeramide

GROUP 7 Amines, Aliphatic and Aromatic (AH Isomers)

Aminodi phenyl Aminoethanol Aminoethanol amine Aminophenol Aminopropionitrile Amylamine Aminothiazole Aniline Benzidine Benzylamine Butylamine Chlorotoluidine Crimidine Cupriethylenediamine Cyclohexylamine Dichlorobenzidine Diethanolamine Diethylamine Diethyl enetriamine Diisopropanolamine Dimethyl amine Dimethylaminoazobenzene Diphenylamine Diphenylamine chloroarsine Dipicrylamine Dipropylamine Ethylamine Ethylenediamine Ehtyl eneimine Hexamethylenediamine

Hexamethylenetetraamine Hexylamine Isopropylamine Methylamine N-Methyl aniline 4,4-Methylene bis(2-chloroaniline) Methyl ethyl pyridine Monoethanol am ine Monoisopropanolamine Morpholine Naphthylamine Nitroaniline Nitroaniline

. Nitroaniline Nitrogen mustard Nitrosodimethylamine Pentylamine Phenylene diamine Picramide Picridine Piperidine Propylamine Propyleneimine PyricJine Tetramethylenediamine Toluidine Triethanolamine Triethylamine Triethylenetetraamine Trimethylamine Tripropylamine

GROUP 8 Azo Compounds, Diazo Compounds and Hydrazines (All Isomers)

Aluminum tetraazidoborate Aminothiazole

. Azidocarbonyl guanidine Azido-s-triazole a,a-Az6diisobutyronitrile Benzene diazonium chloride Benzotriazole t-Butyl azidoformate Chloroazodin Chlorobenzotriazole Diazodinitrophenol Diazidoethane Dimethylamino azobenzene Dimethyl hydrazine

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GROUP 8 Azo Compounds, Diazo Compounds and Hydrazines (All Isomers) cont'd

Dinitrophenyl hydrazine Guanyl nitrosoaminoguanylidine hydrazine Hydrazine Hydrazine azide 'Methyl hydrazine Mercaptoben zothiazole Phenyl hydrazine hydrochloride Tetrazene

GROUP 9 Carbamates

Aldicarb Bassa* Baygon* Butacarb Bux* Carbaryl Carbanolate Dioxacarb Dowco* 139 Formetanate hydrochloride Furadan* Hopcide* N-Isopropylmethylcarbamate Landrin* Matacil* Meobal Mesurol* Methomyl Mipcin* Mobam* Oxamyl Pirimicarb Promecarb Tranid* Tsumacide*

GROUP 10 Caustics

Ammonia Ammonium hydroxide Barium hydroxide Barium oxide Beryllium hydroxide Cadmium amide Calcium hydroxide Calcium oxide Lithium amide

Lithium hydroxide Potassium aluminate Potassium butoxide Potassium hydroxide Sodium aluminate Sodium amide Sodium carbonate Sodium hydroxide Sodium . hypochlorite Sodium methylate Sodium oxide

GROUP 11 Cyanides

Cadmium cyanide Copper cyanide Cyanogen bromide Hydrocyanic acid Lead cyanide Mercuric cyanide Mercuric oxycyanide Nickel cyanide Potassium cyanide Silver cyanide Sodium cyanide Zinc cyanide

GROUP 12 Dithiocarbamates

CDEC Dithane* M-45 Ferbam Maneb-Metham Nabam Niacide* Polyram-combi* Selenium diethyl dithiocarbamate Thiram Zinc salts of dimethyl dithiocarbamic acid Zineb Ziram

GROUP 13 Esters (All Isomers)

Allyl chlorocarbonate Amyl acetate Butyl acetate

66

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GROUP 13 Esters (All Isomers) cont'd

Butyl acrylate Butyl benzyl phthalate Butyl formate Dibutyl phthalate Diethylene glycol monobutyl ether acetate Ethyl acetate Ethyl acrylate Ethyl butyrate Ethyl chloroformate E^hyl formate 2-Ethyl hexylacrylate Ethyl propionate Glycol diacetate Isobutyl acetate Isobutyl acrylate Isodecyl acrylate Isopropyl acetate Medinoterb acetate Methyl acetate Methyl acrylate Methyl amyl acetate Methyl butyrate Methyl chloroformate Methyl formate Methyl methacrylate Methyl propionate Methyl valerate Propiolactone Propyl acetate Propyl formate Vinyl acetate

GROUP 14 Ethers (All Isomers)

Anisole Butyl ceilosolve* Bromodimethoxyaniline Dibutyl ether Dichloroethyl ether Dimethyl ether Dimethyl formal Dioxane Diphenyl oxide Ethoxyethanol Ethyl ether Ethylene glycol monomethyl ether Furan Glycol ether Isopropyl ether Methyl butyl ether

Methyl chloromethyl ether Methyl ethyl ether Polyglycol ether Propyl ether Propylene glycol monomethyl ether TCDD Tetrachloropropyl ether Tetrahydrofuran Trinitroanisole Vinyl ethyl ether Vinyl isopropyl ether

GROUP 15 Fluorides, Inorganic

Aluminum fluoride Ammonium bifluoride Ammonium fluoride Barium fluoride Beryllium fluoride Cadmium fluoride Caldum fluoride Cesium fluoride Chromic fluoride Fluoroboric acid Fluorosilidc acid Hexafluorophosphoric acid Hydrofluoric acid Magnesium fluoride Potassium fluoride Selenium fluoride Silicon tetrafluoride Sodium fluoride Sulfur pentafluoride Tellurium hexafluoride Zinc fluoroborate

GROUP 16 Hydrocarbons, Aromatic (All Isomers) ~

Acenaphthene Anthracene Benz-a-pyrene Benzene n-Butyl benzene Chrysene Cumene Cymene Decyl benzene Diethyl benzene Diphenyl

67

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G R O U P 16 Hydrocarbons, A r o m a t i c (A l l Isomers) cont 'd

Diphenyl acety lene Diphenyl ethane Diphenyl e thy lene Diphenyl methane Dodecyl benzene Dowthe rm Durene E thy l benzene F luoranthrene Fluorene H e m i m e l l i t e n e Hexamethy l benzene Indene Isodurene Mes i ty lene M e t h y l naphthalene Naphtha lene Pen tamethy l benzene Phenanthrene Phenyl acety lene Propy l benzene Pseudocumene Styrene Te t rapheny l e thy lene Toluene St i lbene Tr ipheny le thy lene T r i phenylm ethane

G R O U P 17 Halogenated Organics (A l l Isomers)

A c e t y l bromide A c e t y l ch lor ide A l d r i n A l l y l bromide A l l y l ch lor ide A l l y l ch lorocarbonate A m y l ch lor ide Benzal bromide Benzal ch lor ide Benzo t r ib romide Benzo t r i ch lo r ide Benzyl bromide Benzyl ch lor ide Benzyl ch lorocarbonate Bromoacety lene Bromobenzy l t r i f l u o r i d e B r o m o f o r m

Bromophenol Bromopropyne B romo t r i ch lo rome thane B r o m o t r i f l u o r o m e t h a n e Bromoxyn i l Bu ty l f l uo r i de Carbon t e t r ach lo r i de Carbon t e t r a f l u o r i d e Carbon te t ra iod ide Ch lo ra l hydra te Chlordane Ch lo roaceta ldehyde Ch lo roace t i c ac id Chloroacetophenone C h l o r o a c r y l o n i t r i l e Ch lo roazod in Ch lorobenzene Ch lo robenzo t r i azo le Ch lo robenzoy l peroxide Ch lorobenzy l idene ma lonon i t r i l e C h l o r o b u t y r o n i t r i l e Ch lo rocreso l Ch lo rod in i t r o to luene Ch lo roe thano l C h l o r o e t h y l e n i m i m e C h l o r o f o r m Ch lo rohyd r i n C h l o r o m e t h y l me thy l ether C h l o r o m e t h y l phenoxyacet ic ac id Ch lo ron i t roan i l i ne Ch loropheno l Ch lo ropheny l isocyanate Ch lo rop i c r i n Ch lo ro th ion Ch lo ro to lu id ine C M M E C r o t y l b romide C r o t y l ch lo r ide D D D D D T DDVP Dibromoch lo ropropane D ich lo roace tone Dich iorobenzene D ich lo robenz id ine D ich lo roe thane D ich lo roe thy lene D i c h l o r o e t h y l e ther D i ch lo rome thane

68

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GROUP 17 Halogenated Organics (All Isomers) cont'd

Dichlorophenol Dichlorophenoxy acetic acid Dichloropropane Dichloropropanol Dichloropropylene Dieldrin Diethyl chloro vinyl phosphate Dichlorophene Dinitrochlorobenzene Endosulf an Endrin Epichlorohydrin Ethyl chloroformate Ethylene chlorohydrin Ethylene dibromide Ethylene dichloride Fluoroacetanilide Freons* Heptachlor Hexachlorobenzene Hydroxydibromobenzoic acid Isopropyl chloride a-Isopropyl methyl phosphoryl fluoride Lindane Methyl bromide Methyl chloride Methyl chloroform Methyl chloroformate Methyl ethyl chloride Methyl iodide Monochloroacetone Nitrochlorobenzene Nitrogen mustard Pentachlorophenol Perchloroethylene Pechl orom ethylm er captan Picryl chloride Polybrominated biphenyls Polychlorinated biphenyls Polychlorinated triphenyls Propargyl bromide Propargyl chloride TCDD Tetrachloroethane Tetrachlorophenol Tetrachloropropyl ether Trichloroethane Trichloroethylene Trichlorophenoxyacetic add

Tri chloropropane Trifluoroethane Vinyl chloride Vinylidene chloride

GROUP 18 Isocyanates (All Isomers)

Chlorophenyl isocyanate Diphenylmethane diisocyanate Methyl isocyanate Methylene diisocyanate Polyphenyl polymethylisocyanate Toluene diisocyanate

GROUP 19 Ketones (All Isomers)

Acetone Acetophenone Acetyl acetone Benzophenone Bromobenzoyl acetanilide Chloroacetophenone Coumafuryl Coumatetralyl Cydohexanone Diacetone alcohol Diacetyl Dichloroacetone Diethyl ketone Diisobutyl ketone Heptanone Hydroxyacetophenone Isophorone Mesityl oxide Methyl t-butyl ketone • Methyl ethyl ketone Methyl isobutyl ketone Methyl isopropenyl ketone Methyl n-propyl ketone Methyl vinyl ketone Monochloroacetone Nonanone Octanone Pentanone Quinone

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GROUP 20 Mercaptans and Other Organic Sulfides (All Isomers)

Aldicarb Amyl mercaptan Butyl mercaptan Carbon disulfide Dimethyl sulfide Endosulf an Ethyl mercaptan Mercaptobenzothiazole Mercaptoethanol Methomyl Methyl mercaptan Naphthyl mercaptan Perchloromethyl mercaptan Phospholan Polysulfide polymer Propyl mercaptan Sulfur mustard Tetrasul Thionazin VX

GROUP 21 Metals, Alkali and Alkaline Earth, Elemental

• Barium Calcium Cesium Li th ium Magnesium Potassium Rubidium Sodium Sodium-potassium alloy Strontium

GROUP 22 Metals, Other Elemental and Alloys in the Form of Pow ders, Vapors or Sponges

Aluminum Bismuth Cerium Cobalt Hafnium Indium Magnesium Manganese Mercury (vapor) Molybdenum

Nickel Raney nickel Selenium Titanium Thorium Zinc

Zirconium

GROUP 23 Metals, Other Elemental and Alloys as Sheets, Rods, Mold ings, Drops, etc.

Aluminum Antimony Bismuth Brass Bronze Cadmium Calcium-manganese-silicon alloy Chromium Cobalt Copper Indium Iron Lead Manganese Molybdenum Osmium Selenium Titanium Thor.ium Zinc Zirconium

GROUP 24 Metals and Metal Com pounds, Toxic

Ammonium arsenate Ammonium dichromate Ammonium hexanitrocobaltate Ammonium molybdate Ammonium nitridoosmate Ammonium permanganate Ammonium tetrachromate Ammonium tetraperoxychromate Ammonium tr ichromate Antimony Antimony nitr ide Antimony oxychloride

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GROUP 24 Metals and Metal Com-pounds. Toxic

Antimony pentachloride Antimony pentafluoride Antimony pentasulfide Antimony perchlorate Antimony potassium tartrate Antimony sulfate Antimony tribromide Antimony trichloride Antimony triiodide Antimony trifluoride Antimony trioxide Antimony trisulfide Antimony trivinyl Arsenic Arsenic pentaselenide Arsenic pentoxide Arsenic pentasulfide Arsenic sulfide Arsenic tribromide Arsenic trichloride Arsenic trifluoride Arsenic triiodide Arsenic trisulfide Arsines Barium Barium azide Barium carbide Barium chlorate Barium chloride Barium chromate Barium fluoride Barium fluosilicate Barium hydride Barium hydroxide Barium hypophosphide Barium iodate Barium iodide Barium nitrate Barium oxide Barium perchlorate Barium permanganate Barium peroxide Barium phosphate Barium stearate Barium sulfide Barium sulfite Beryllium Beryllium-copper alloy Beryllium fluoride

Beryllium hydride Beryllium hydroxide Beryllium oxide Beryllium tetrahydroborate Bismuth Bismuth chromate Bismuthic acid Bismuth nitride Bismuth pentafluoride Bismuth pentoxide Bismuth sulfide Bismuth tribromide Bismuth trichloride Bismuth triiodide Bismuth trioxide Borane Bordeaux arsenites Boron arsenotribromide Boron bromodiodide Boron dibromoiodide Boron nitride Boron phosphide Boron triazide Boron tribromide Boron triiodide Boron trisulfide Boron trichloride Boron trifluoride Cacodylic acid Cadmium Cadmium acetylide Cadmium amide Cadmium azide Cadmium bromide Cadmium chlorate Cadmium chloride Cadmium cyanide Cadmium fluoride Cadmium hexamine chlorate Cadmium hexamine perchlorate Cadmium iodide Cadmium nitrate Cadmium nitride Cadmium oxide Cadmium phosphate Cadmium . sulfide

. Cadmium trihydrazine chlorate Cadmium trihydrazine perchlorate Caldum arsenate

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GROUP 24 Metals and Meta l C o m pounds, Tox ic cont 'd

Calcium arsenite Lead oxide Chromic chloride Lead styphnate Chromic fluoride Lead sulfide Chromjd oxide Lewisite Chromic sulfate London purple Chromium Magnesium arsenate Chromium sulfide Magnesium arsenite Chromium trioxide Manganese Chromyl chloride Manganese acetate Cobalt Manganese arsenate Cobaltous bromide Manganese bromide Cobaltous chlor.'de Manganese chloride Cobaltous nitrate Manganese methylcyc Cobaltous sulfate bonyl Cobaltous resinate Manganese ni t rate Copper Manganese sulf ide Copper acetoarsenite Mercuric acetate Copper acetylide Mercuric ammonium Copjjer arsenate Mercuric benzoate Copper arsenite Mercuric bromide Copper chloride ' Mercuric chloride

• Copper chlorotetrazole Mercuric cyanide Copper cyanide Mercuric iodide Copper nitrate Mercuric n i t rate Copper nitride • Mercuric oleate Copper sulfate Mercuric oxide Copper sulfide Mercuric oxycyanide Cupr ie thy lene diamine Cyanochloropentane D ie thy l zinc Di isopropyl bery l l ium Diphenylamine chloroars ine Ethy l dichioroarsine Ethylene chromic ox ide Fe r r i c arsenate Ferrous arsenate Hydrogen selenide Indium Lead_ Lead acetate Lead arsenate Lead arseni te Lead azide Lead carbonate Lead ch lo r i te Lead cyanide Lead d in i t r o reso rdna te Lead mononi t ro resorc inate Lead n i t r a te

M e r c u r i c potassium iodide M e r c u r i c sa l i cy la te M e r c u r i c subsulfate. M e r c u r i c su l fa te M e r c u r i c su l f ide M e r c u r i c th iocyan ide Mercu ro l Mercurous bromide Mercurous g luconate Mercurous iod ide Mercurous n i t r a t e Mercurous oxide Mercurous s u l f a t e M e r c u r y Mercu ry f u l m i n a t e M e t h o x y e t h y l m e r c u r i c ch lor ide M e t h y l d ich ioroars ine Mo lybdenum Molybdenum sul f ide Molydbenum t r i ox i de Mo lybd i c ac id N i cke l

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GROUP 24 Meta ls and Me ta l C o m pounds, Tox ic cont 'd

Nicke l ace ta te N icke l ant imonide Nicke l arsenate N icke l arseni te N icke l carbonyl N icke l ch lor ide N icke l cyanide N icke l n i t r a te Nicke l selenide N icke l subsulf ide N icke l su l fa te Osmium Osmium amine n i t r a t e Osmium amine perch lo ra te Phenyl d ichioroars ine Potassium arsenate Potassium arseni te Potassium d c h r o m a t e Potassium permanganate Selenium Selenium f luo r ide Selenium d ie thy l d i t h i oca rbamate Selenous ac id Silver ace ty l ide Silver azide Si lver cyanide Silver n i t r a te Si lver n i t r i de Silver .styphnate Silver su l f ide Silver te t razene Sodium arsenate Sodium arseni te Sodium cacody la te Sodium chromate Sodium d ichromate Sodium molybdate Sodium permanganate Sodium selenate Stannic chlor ide Stannic sul f ide St ront ium arsenate St ront ium monosul f ide St ron t ium n i t r a t e St ront ium peroxide St ront ium te t rasu l f i de Te l lur ium hexaf luor ide . Te t rae thy l lead Te t ramethy l lead

Tet rase len ium t e t r a n i t r i d e Thallium Tha l l i um n i t r i de Tha l l i um su l f ide Thal lous su l fa te Thor ium T i t an i um T i t an i um su l fa te T i t an ium sesquisul f ide T i t an ium te t rach lo r i de T i t an i um su l f ide T r i c a d m i u m d in i t r i de T r i ces ium n i t r i de T r i e t h y l arsine T r i e t h y l b ismuth ine T r i e t h y l s t ib ine T r i l ead d in i t r i de T r i m e r c u r y d i n i t r i de T r i m e t h y l arsine T r i m e t h y l b ismuth ine T r i m e t h y l s t ib ine T r ip ropy l s t ib ine T r i s i l y l arsine T r i t h o r i u m t e t r a n i t r i d e T r i v i n y l s t ib ine Tungst ic ac id Uran ium su l f ide Urany l n i t r a t e Vanadic ac id anhydr ide Vanadium oxy t r i ch lo r i de Vanadium te t rox ide Vanadium t r i ox ide Vanadium t r i c h l o r i d e Vanadyl su l fa te Z inc Zinc ace ty l i de Z inc ammon ium n i t r a t e Zinc arsenate Zinc arseni te Zinc ch lor ide Zinc cyanide Zinc f l uobora te Zinc n i t r a t e Zinc permanganate Zinc peroxide Zinc phosphide Zinc sal ts of d ime thy l d i t h i o ca rbamic ac id Zinc su l fa te Zinc su l f ide

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GROUP 24 Meta ls and. Me ta l C o m pounds, Tox ic cont 'd

Z i rcon ium Zi rconium chlor ide Z i rconium p ic ramate

GROUP 25 N i t r ides

A n t i m o n y n i t r i de Bismuth n i t r i de Boron n i t r i de Copper n i t r i de D isu l fu r d in i t r i de L i t h i u m n i t r ide Potassi l im n i t r i de Silver n i t r ide Sodium n i t r ide • Tetraselenium t e t r a n i t r i d e Te t rasu l fu r t e t r a n i t r i d e Tha l l ium n i t r ide T r i cadmium d in i t r i de T i c a l d u m d in i t r ide Tr ices ium n i t r i de Tr i lead d in i t r ide T r i m e r c u r y d in i t r i de T r i t h o r i u m t e t r a n i t r i d e

GROUP 26 N i t r i l e s (A l l Isomers)

Acetone cyanohydr in Ac :s ton i t r i le A c r y l o n i t r i l e Ad ipon i t r i l e Am inop rop ion i t r i l e A m y l cyanide a ,a -Azod i i sobu ty ron i t r i l e Benzon i t r i l e Bromoxyn i l Bu t y ron i t r i l e Ch lo roac ry l on i t r i l e Chlorobenzy l idene ma lonon i t r i l e Ch lo robu t y ron i t r i l e Cyanoace t i c ac id Cyanochloropentane Cyanogen Ethylene cyanohydr in G l yco lon i t r i l e Phenyl a c e t o n i t r i l e Phenyl v a l e r y l n i t r i l e P rop ion i t r i l e S u r e d d e *

T e t r a m e t h y l succ inon i t r i l e T r a n i d * Vinyl cyanide

G R O U P 27 N i t r o Compounds (A l l Iso-mers)

A c e t y l n i t r a t e Ch lo rod in i t ro luene Ch lo ron i t r oan i l i ne Ch lo rop i c r i n Co l lod ion D iazod in i t ropheno l D ie thy lene g lyco l d i n i t r a t e D in i t robenzene D in i t roch lo robenzene D in i t r oc reso l D in i t ropheno l D in i t ropheny l hydraz ine D in i t r o to l uene Dinoseb D i p e n t a e r y t h r i t o l hexan i t ra te D i p i c r y l amine Ethy l n i t r a t e E thy l n i t r i t e G lyco l d i n i t r a t e G lyco l mono lac ta te t r i n i t r a t e Guanid ine n i t r a t e Lead d in i t ro reso rc ina te Lead monon i t ro resorc ina te Lead s typhnate Mann i to l hexan i t ra te Med ino te rb ace ta te N i t roan i l i ne N i t robenzene N i t rob ipheny l N i t roce l l u lose N i t roch lo robenzene N i t r o g l y c e r i n N i t ropheno l N i t rop ropane N-N i t r osod ime thy lam ine Ni t rosoguani dine N i t r o s t a r c h N i t r oxy lene P e n t a e r y t h r i t o l t e t r a n i t r a t e P ic ramide P ic r i c ac id P ic ry l ch lo r ide

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GROUP 27 Nitro Compounds (All Iso-mers) cont'd

Polyvinyl nitrate Potassium dinitrobenzf uroxan RDX Silver styphnate Sodium picramate Tetranitrom ethane Trinitroanisole Trinitrobenzene Trinitrobenzoic acid Trinitronaphthalene Trinitroresorcinol Trinitrotoluene Urea nitrate

GROUP 28 Hydrocarbons, Aliphatic, Unsaturated (All Isomers)

Acetyl ene Allene Amylene Butadiene Butadiyne Butene Cyclopentene Decene Dicyclopentadiene Diisobutyl ene Dimethyl acetylene Dimethyl butyne Dipentene Dodecene Ethyl acetylene Ethylene Heptene Hexene Hexyne Isobutyl ene Isooctene Isoprene Isopropyl acetylene Methyl acetylene Methyl butene Methyl butyne Methyl styrene Nonene Octadecyne Octene Pentene Pentyne

Polybutene Polypropylene Propylene Styrene Tetradecene Tridecene Undecene Vinyl toluene

GROUP 29 Hydrocarbons, Aliphatic, Sat urated

Butane Cycloheptane Cydohexane Cyclopentane Cyclopropane Decalin Decane Ethane Heptane Hexane Isobutane Isohexane Isooctane Isopentane Methane Methyl cyclohexane Neohexane Nonane Octane Pentane Propane

GROUP 30 Peroxides and Hydroperoxides Organic (All Isomers)

Acetyl benzoyl peroxide Acetyl peroxide Benzoyl peroxide Butyl hyeiroperoxide Butyl peroxide Butyl peroxyacetate Butyl peroxybenzoate , Butyl peroxypivalate Caprylyl peroxide Chlorobenzoyl peroxide Cumene hydroperoxide Cyclohexanone peroxide

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GROUP 30 Peroxides and Hydroperoxides Organic (All Isomers) cont'd

Dicumyl peroxide Diisopropylbenzene hydroperoxide Diisopropyl peroxydicarbonate Dimethylhexane dihydroperoxide Isopropyl percarbonate Lauroyl peroxide Methyl ethyl ketone peroxide Peracetic acid Succinic acid peroxide

GROUP 31 Phenols, Cresols (All Iso-mers)

Amino phenol Bromophenol Bromox^^nil ^ .. .>.v- • " Carbacrol Carbolic oil Catecol Chlorocresol Chl orophenol Coal tar Cresol Creosote Cyclohexyl phenol Dichlorophenol Dinitrocresol Dinitrophenol Dinoseb Eugenol Guaiacol Hydroquinone Hydroxyacetophenone Hydroxydiphenol Hydroxyhydroquinone Isoeugenol Naphthol Nitrophenol Nonyl phenol Pentachlorophenol Phenol o-Phenyl phenol Phloroglucinol Picric acid Pyrogallol Resorcinol Saligenin Sodium pentachlorophenate Sodium phenolsulf onate

Tetrachlorophenol Thymol Tri chlorophenol Trinitroresorcinol

GROUP 32 Organophosphates, Phospho thioates, and Phosphodithio ates

Abate* Azinphos ethyl Azodrin* Bidrin* Bomyl* Chlorf envinphos Chlorothion* Coroxon* DDVP Demeton Demeton-s-methyl sulfoxid Diazinon*' Diethyl chlorovinyl phosphate Dimethyldithiophosphoric acid Dimefox Dioxathion Disulfoton Dyfonate*: Endothion EPN • • Ethion* Fensulfothion Guthion* Hexaethyl tetraphosphate Malathion Mecarbam Methyl parathion Mevinphos Mocap* a-Isopropyl methylphosphoryl fluoride Paraoxon Parathion Phorate Phosphamidon Phospholan Potasan Prothoate Shradan Sulfotepp Supracide*

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G R O U P 32 Organophosphates, Phosphoth ioa tes , and Phosphodithio-ates cont 'd

Shradan Sul fo tepp Supraci de * Surec ide* T e t r a e t h y l d i th ionopyrophosphate Te t rae thy l pyrophosphate Th ionaz in T r i s - ( l - a z i r i d i n y l ) phosphine oxide VX Wepsyn* 155

G R O U P 33 Sul f ides, Inorganic

A m m o n i u m su l f ide A n t i m o n y pentasu l f ide A n t i m o n y t r i su l f i de Arsen ic pentasul f ide Arsen ic su l f ide Arsen ic t r i su l f i de Bar ium su l f ide Bery l l i um sul f ide B ismuth su l f ide Bismuth t r i su l f i de Boron t r i su l f i de Cadmium sul f ide Ca lc ium sul f ide Ce r i um t r i su l f i de Cesium su l f ide Ch rom ium sul f ide Copper su l f ide F e r r i c su l f ide Ferrous su l f ide German ium sul f ide Gold su l f ide Hydrogen su l f ide Lead su l f ide L i t h i u m sul f ide Magnesium su l f ide Manganese su l f ide M e r c u r i c su l f ide Molybdenum sul f ide N icke l subsul f ide Phosphorous heptasul f ide Phosphorous pentasul f ide Phosphorous sesquisulf ide Phosphorous t r i su l f i de Potassium sul f ide Si lver su l f ide

Sodium sul f ide Stannic sul f ide S t ron t ium monosu l f ide S t ron t ium te t rasu l f i de Tha l l ium sul f ide T i t an ium sesquisul f ide T i t an ium sul f ide Uran ium su l f ide Z inc sul f ide

G R O U P 34 Epoxides

Buty l g lyc idy l e ther t -Bu ty l -3 -pheny l oxaz i rane Cresol g lyc idy l e ther D ig l yc i dy l e ther Ep ich lorohydr in Epoxybutane Epoxybutene Epoxyethy lbenzene Ethy lene oxide G lyc ido l Phenyl .g lyc idy l e ther Propylene oxide

G R O U P 101 Combus t ib le and F lammab le Ma te r i a l s , Miscel laneous

A l k y l resins Asphal t B a k e l i t e * B u n a - N * Bunker fue l oi l Camphor oi l Carbon, a c t i v a t e d , spent Cel lu lose Coal oi l Diesel o i l Dynes th inner Gas o i l , c racked Gasol ine Grease Isotact ic: propylene J-100 Jet o i l Kerosene Lacquer th inner M e t h y l acetone

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GROUP 101 Combust ib le and F lammab le Mater ia ls , Miscel laneous cont 'd

Mineral sp i r i ts Naphtha Oi l of bergamot Orr is root Paper Pet ro leum naphtha Pet ro leum o i l Polyamide resin Polyester resin po lyethy lene Po lymer i c o i l Polypropylene Polystyrene Polysul f ide polymer Polyurethane Polyv iny l ace ta te Polyv iny l ch lor ide Refuse Resins Sodium polysul f ide Stoddard solvent Sul fur (e lementa l ) Synthet ic rubber Ta l l o i l Ta l low Tar Turpent ine Unisolve Waxes Wood

GROUP 102 Explosives

A c e t y l az ide A c e t y l n i t r a te Ammon ium azide Ammon ium ch lora te Ammon ium hexan i t rocoba l ta te Ammon ium n i t r a te Ammon ium n i t r i t e Ammon ium per iodate Ammon ium permanganate Ammon ium p ic ra te Ammon ium te t rape roxych roma te Az idocarbony l guanidine Barium azide Benzene diazonium chlor ide Benzot r iazo le

Benzoyl perox ide B ismuth n i t r i de Boron t r i az i de Bromine azide Bu tane t r io l t r i n i t r a t e t - B u t y l hypoch lo r i t e Cadmium azide Cadmium hexamine ch lo ra te • Cadmium hexamine perch lo ra te Cadmium n i t r a t e Cadmium n i t r i d e Cadmium t r i hyd raz ine ch lo ra te C a l d u m n i t r a t e Cesium azide Ch lo r ine az ide Ch lo r ine d iox ide Ch lor ine f l uo rox ide Ch lo r ine t r i o x i d e Ch lo roace ty lene Ch lo rop i c r i n Copper ace ty l i de Cyanur i c t r i a z i d e D iaz idoethane D iazod in i t ropheno l D ie thy lene g lyco l d i n i t r a te D i p e n t a e r i t h r i t o l hexan i t ra te D i p i c r y l amine D isu l fu r d i n i t r i d e E thy l n i t r a t e E thy l n i t r i t e F luor ine az ide Glyco l d i n i t r a t e G lyco l mono lac ta te t r i n i t r a t e Gold f u l m i n a t e Guanyl n i t rosaminoguany l idene hydraz ine H M X Hydraz ine az ide Hydrazo ic ac id Lead azide Lead d in i t r o reso rc ina te Lead monon i t ro reso rc ina te Lead s typhnate Mann i to l hexan i t r a te Me rcu r i c oxycyan ide Mercu ry f u l m i n a t e N i t r o c a r b o n i t r a t e

' N i t roce l l u lose N i t r o g l y c e r i n

78

GROUP 102 Explosives cont'd

Nitrosoguanidine Nitrostarch Pentaerythritol tetranitrate Picramide Picric acid Picryl chloride Polyvinyl nitrate Potassium dinitrobenzf uroxan Potassium nitrate RDX Silver acetylide Silver azide Silver nitride Silver styphnate Silver tetrazene Smokeless powder Sodium azide Sodium picramate Tetranitromethane Tetraselenium tetranitride Tetrasulfur tetranitride Tetrazene Thallium nitride Trilead dinitride Trimercury dinitride Trinitrobenzene Trinitrobenzoic acid Trintironaphthalene Trinitroresorcinol Trinitrotoluene Urea nitrate Vinyl azide Zinc peroxide

GROUP 103 Polymerizable Compounds

Acrol ein Acrylic acid Acrylonitrile Butadiene n-Butyl acrylate Ethyl acrylate Ethylene oxide Ethylenimine 2-Ethylhexyl acrylate Isobutyl acrylate Isoprene Methyl acrylate Methyl methacrylate 2-Methyl styrene

Propylene oxide Styrene Vinyl acetate Vinyl chloride Vinyl cyanide Vinylidene chloride Vinyl toluene

GROUP 104 Oxidizing Agents, Strong

Ammonium chlorate Ammonium dichromate Ammonium nitridoosmate Ammonium perchlorate Ammonium periodate Ammonium permanganate Ammonium persulfate Ammonium tetrachromate Ammonium tetraperoxychromate Ammonium trichromate Antimony perchlorate Barium bromate Barium chlorate Barium iodate Barium nitrate Barium pjerchlorate Barium permanganate Barium peroxide Bromic acid Bromine Bromine monofluoride Bromine pentafluoride Bromine trifluoride t-Butyl hypochlorite Cadmium chlorate Cadmium nitrate Calcium bromate Caldum chlorate Calcium chlorite Calcium hypochlorite Calcium iocJate Calcium nitrate Calcium perchromate Calcium permanganate Caldum peroxide Chloric acid Chlorine Chlorine dioxide Chlorine fluoroxide Chlorine monofluoride

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G R O U P 104 Ox id iz ing Agents , cont 'd

Strong

Ch lo r ine monoxide Chlor ine penta f luor ide Ch lor ine t r i f l uo r i de Chlor ine t r iox ide Ch rom ic acid Chromy l ch lor ide Cobal tous n i t r a t e Copper n i t r a te D ich lo roamine D ich lo ro isocyanur ic ac id Ethy lene chromic ox ide F luor ine F luor ine monoxide Guanid ine n i t r a t e Hydrogen peroxide Iodine pentoxide Lead ch lo r i te Lead n i t r a t e L i t h i u m hypoch lor i te L i t h i u m peroxide Magnesium ch lora te Magnesium n i t r a t e Magnesium perch lo ra te Magnesium peroxide Manganese n i t r a t e M e r c u r i c n i t r a te Mercurous n i t r a t e N i cke l n i t r a t e N i t rogen diox ide Osmium amine n i t r a t e Osmium amine perch lo ra te Oxygen d i f luo r ide Perch lo ry l f l uo r ide Phosphorus oxybromide Phosphorus oxych lor ide Potassium b romate Potassium d ich loro isocyanurate Potassium d ich romate Potassium n i t r a te Potassium perch lo ra te Potassium permanganate Potassium peroxide Si lver n i t ra te Sodium bromate Sodium carbonate peroxide Sodium ch lora te Sodium ch lo r i te Sodium d ich loro isocyanura te Sodium d ichromate

Sodium hypoch lo r i t e Sodium n i t r a t e Sodium n i t r i t e Sodium perch lo ra te Sodium permanganate Sodium peroxide S t ron t ium n i t r a t e S t ron t ium peroxide Sul fur t r i ox i de T r i ch lo ro i socyanur i c ac id Urany l n i t r a t e Urea n i t r a t e Zinc ammon ium n i t r a t e Z inc n i t r a t e Zinc permanganate Z inc peroxide Z i r con ium p i c rama te

G R O U P 105 Reducing Agents , Strong

A l u m i n u m borohydr ide A l u m i n u m carbide A l u m i n u m hydr ide A l u m i n u m hypophosphide A m m o n i u m hypophosphide A m m o n i u m sul f ide A n t i m o n y pentasu l f ide A n t i m o n y t r i s u l f i d e Arsen ic su l f i de Arsen ic t r i s u l f i d e Ars ine Bar ium carb ide Bar ium hydr ide Bar ium hypophosphide Bar ium su l f ide Benzyl s i lane Benzyl sodium Be ry l l i um hydr ide Bery l l i um su l f ide Be ry l l i um te t rahyd robora te B ismuth su l f ide Boron a rseno t r ib romide Boron t r i s u l f i d e Bromodiborane Bromosi lane Bu ty l d ich loroborane n-Buty l l i t h i u m Cadmium ace ty l ide Cadm ium su l f ide

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GROUP 105 Reducing Agents, Strong cont'd

Calcium Calcium carbide Calcium hexammoniate Caldum hydride Calcium hypophosphide Calcium sulfide Cerium hydride Cerium trisulfide Cerous phosphide Cesium carbide Cesium hexahydroaluminate Cesium hydride Cesium sulfide Chlorodiborane Chlorodiisobutyl aluminum Chlorodimethylamine diborane Chlorodi propyl borane Chlorosilane Chromium sulfide Copper acetylide Copper sulfide Dilborane Diethyl aluminurn chloride Diethyl zinc Diisopropyl beryllium Dimethyl magnesium Ferrous sulfide Germanium sulfide Gold acetylide Gold sulfide Hexaborane Hydrazine Hydrogen selenide Hydrogen sulfide Hydroxyl amine Lead sulfide Lithium aluminum hydride Lithium hydride Lithium sulfide Magnesium sulfide Manganese sulfide Mercuric sulfide Methyl aluminum sesquibromide Methyl aluminum sesqui chloride Methyl magnesium bromide Methyl magnesium chloride Methyl magnesium iodide Molybdenum sulfide Nicd<el subsulfide

Pentaborane Phosphine Phosphonium iodide Phosphorus (red amorphous) Phosphorus (white or yellow) Phosphorus heptasulfide Phosphorus pentasulfide Phosphorus sesquisulfide Phosphorus trisulfide Potassium hydride Potassium sulfide Silver acetylide Silver sulfide Sodium Sodium aluminate Sodium aluminum hydride Sodium hydride Sodium hyposulfite Sodium sulfide Stannic sulfide Strontium monosulfide Strontium tetrasulfide Tetraborane Thallium sulfide Titanium sesquisulfide Titanium sulfide Triethyl aluminum Triethyl stibine Triisobutyl aluminum Trimethyl aluminum Trimethyl stibine Tri-n-butyl borane Trioctyl aluminum Uranium sulfide Zinc acetylide Zinc sulfide

GROUP 106 Water and Mixtures Con-taining Water

Aqueous solutions and mixtures Water

GROUP 107 Water Reactive Substances

Acetic anhydride Acetyl bromide Acetyl chloride Alkyl aluminum chloride

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GROUP 107 Water Reac t i ve Substances cont 'd

A l l y l t r ich loros i lane A luminum aminoborohydr ide A luminum borohydr ide A luminum bromide Aluminum ch lor ide A luminum f l uo r ide A luminum hypophosphide A luminum phosphide A luminum te t rahyd robo ra te A m y l t r i ch lo ros i lane Anisoyl ch lor ide An t imony t r i b r o m i d e An t imony t r i ch l o r i de An t imony t r i f l u o r i d e An t imony t r i i od ide An t imony t r i v i n y l Arsenic t r i b rom ide Arsenic t r i ch lo r i de Arsenic t r i i o d d e Bar ium Bar ium carbide Barium oxide Barium sulf ide Benzene phosphorus d ich lor ide Benzoyl ch lo r ide Benzyl silane ' Benzyl sodium Bery l l ium hydr ide Bery l l ium te t rahyd robora te Bismuth penta f luor ide Borane Boron bromodi iod ide Boron d ibromoiodide Boron phosphide Boron t r i b rom ide Boron t r i ch lo r i de Boron t r i f l uo r i de Boron t r i iod ide Bromine monof luor ide Bromine penta f luor ide Bromine t r i f l u o r i d e Bromo d ie thy la luminum n-Buty l l i t h i um n-Buty l t r i ch lo ros i lane Cadmium acety l ide Cadmium amide C a l d u m C a l d u m carbide C a l d u m hydr ide

C a l d u m oxide Ceilcium phosphide Cesium amide Cesium hydr ide Cesium phosphide Ch lor ine d iox ide Ch lor ine mono f luo r ide Ch lor ine pen ta f luo r ide Ch lo r ine t r i f l u o r i d e Ch lo roace ty l ch lo r ide Ch lo rod i i sobu ty l a luminum Chloropheny l isocyanate Ch romy l ch lo r ide Copper ace ty l i de Cyc lohexeny l t r i ch lo ros i lane C y d o h e x y l t r i ch lo ros i l ane Decaborane Diborane D ie thy l a luminum chlor ide D ie thy l d ich loros i lane D ie thy l z inc Di isopropy l be ry l l i um D i m e t h y l d ich loros i lane D i m e t h y l magnesium Dipheny l d ich loros i lane D ipheny lmethane d i isocyanate D i su l f u r y l ch lo r ide Dodecy l t r i ch lo ros i l ane E thy l d ich ioroars ine E thy l d ich loros i lane Ethy l t r i ch lo ros i lane Fluor ine F luor ine monox ide F luorosu l fon ic ac id Gold ace ty l ide Hexadecy l t r i ch lo ros i l ane Hexy l t r i ch lo ros i lane Hyd rob romic ac id Iodine monoch lor ide L i t h i u m L i t h i u m a luminum hydr ide L i t h i u m amide L i t h i u m fe r ros i l i con L i t h i u m hydr ide L i t h i u m peroxide L i t h i u m s i l icon M e t h y l a luminum sescjuibromide M e t h y l a luminum sesquichlor ide M e t h y l d ich loros i lane

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GROUP 107 Water Reac t i ve Substances cont 'd

Methy lene d i isocyanate Me thy l isocyanate Methy l t r i ch lo ros i lane Me thy l magnesium bromide Methy l magnesium ch lor ide Me thy l magnesium iodide N icke l ant imonide Nonyl t r i ch lo ros i lane Octadecy l t r i ch lo ros i lane O c t y l t r ich loros i lane Phenyl t r i ch lo ros i lane Phosphonium iodide Phosphoric anhydr ide Phosphorus oxych lor ide Phosphorus pentasul f ide Phosphorus t r i su l f i de Phosphorus (amorphous red) Phosphorus oxybromide Phosphorus oxych lo r ide Phosphorus pentachlor ide Phosphorus sesquisulf ide Phosphorus t r i b rom ide Phosphorus t r i ch l o r i de Polyphenyl po l yme thy l isocyanate Potassium Potassium hydride Potassium oxide Potassium peroxide Propyl t r i ch lo ros i lane Pyrosu l fu ry l ch lor ide Si l icon te t rach lo r ide Silver acety l ide Sodium Sodium aluminum hydr ide Sodium amide Sodium hydride

Sodium m e t h y l a t e Sodium oxide Sodium peroxide Sodium-potassium al loy Stannic ch lor ide Sul fonyl f l uo r i de Su l fur ic ac id (>70%) Sulfur ch lor ide Sulfur pjentaf luor ide Sulfur t r i ox ide Sul fury l ch lor ide Th iocarbony l ch lo r ide Thiony l ch lor ide Thiophosphoryl ch lor ide T i tan ium te t rach lo r i de Toluene d i isocyanate Tr ich loros i lane T r i e t hy l a luminum Tr i i sobu ty l a lum inum T r i m e t h y l a luminum T r i - n - b u t y l a luminum T r i - n - b u t y l borane T r i o c t y l a luminum Tr ich lo roborane T r i e t hy l arsine T r i e t hy l s t ib ine T r i m e t h y l arsine T r i m e t h y l s t ib ine Tr ip ropy l s t ib ine T r i s i l y l arsine T r i v i ny l s t ib ine Vanadium t r i ch lo r i de Vinyl t r i ch lo ros i lane Zinc ace ty l ide Zinc phosphide Zinc peroxide

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APPENDIX 3. INDUSTRY INDEX AND LIST OF GENERIC NAMES OF WASTE-STREAMS

This appendix consists of two separate but related tables. Table 1 is the Industry Index which lists names of industries alphabetically with their corresponding Standard Industrial Classification (SIC) code numbers. Table 2 is the list of Generic Names of Wastestreams.

This appendix is used to determine the RGN of wastestreams when their compositions are not known specifically but are identified by their generic or common names. The SIC code number of one wastestream produced by a given industry is obtained from the Industry Index table (Table 1). This number is located in the List of Generic Names of Wastestreams (Table 2). Then the corresponding industry source, generic name of the waste, and its RGN are noted from the table. The process is repeated for the second waste. The RGN for the two types of wastes are entered in the compatibility worksheet (Figure 2) and the compatibility method in Section 4,

The primary references used in the compilation of the following tables are the same ones used in Appendix 1, namely Ref. 1, 7, 8, 10, 12, 13, 14, 32, 44, 52, and 77.. The lists are in no way complete nor are the assignments of RGN to particular wastestreams absolute. Changes in manufacturing processes and practices may change the waste compositions thus resulting in different generic types of wastes.

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TABLE 1. INDUSTRY INDEX TABLE

I

DO

Industry SIC code

Chemical products, miscellaneous 289 Chemicals, agricultural 287 Chemicals, industrial inorganic 281 Chemicals, industrial organic 286 Drugs 283 Food and kindred products 20 Furniture and fixtures 25 Instruments, measuring

analyzing and control 38 Leather and leather products 31 Lumber and wood products 24 Machinery, except electrical 35 Machinery, equipment and supplies

electrical and electronic 36 Metal industries, primary Metal products, fabricated

33 Metal industries, primary Metal products, fabricated 34

Industry

Mining, bituminous coal and lignite Mining,. metal Paints, varnishes, lacquers, enamels

and allied products Paper and allied products Petroleum refining and related industries Plastic materials and synthetic resins Printing, publishing and allied industries Rubber and miscellaneous plastic products Services, business Services, electrical, gas and sanitary Soap, detergents and cleaning preparations Stone, clay, glass and concrete products Textile mill products Transportation equipment

SIC code

12 10

285 26 29

282 27 30 73 49

284 32 22 37

TABLE 2. GENERIC NAMES OF WASTESTREAMS

SIC code Industry source Generic name of wastes Reactivity group nos.

10 Metal mining 10 Metal mining

12 Bituminus coal ic lignite mining

Ore extraction wastes Ore flotation, leach, & electrolysis wastes

Coal processing wastes

1, 24 10, 24

24, 31, 101

Table 2. (Continued)

Reactivity iC code Industry source Generic name of wastes group nos.

20 Food 6c kindred products Coffee caffeine extraction chaff 17 20 Food <!c kindred products Citrus pectin wastes i,

22 Textile mill products Cotton processing wastes 1, 10, 24 22 Textile mill products Orion production wastes 24, 31 22 Textile mill products Wool processing wastes I, 3, 24 22 Textile mill products Textile dyeing 6c finishing wastewater sludge 17, 24

24 Lumber & wood products Plywood production phenolic resin wastes 31 24 Lumber <5c wood products Wood preserving spent liquors 15, 17, 24, 27, 31 24 Lumber. & wood products Softwood anti-stain process wastes 7, 17, 31

25 Furniture & fixtures Furniture paint stripping wastes 10, 24, 101

26 Paper 6c. allied products Wood processing wastes 13, 16, 28, 29, 101 26 Paper 6c allied products Chemical pulping wastes I, 101 26 Paper 6c allied products Dimethyl sulfate still bottoms 1 26 Paper <5c allied products Paperboard productions wastes 24-, 31 26 Paper 6c allied products Paperboard caustic sludge 10, 33 26 Paper 6c allied products Paper making 6c printing wastes 16, 24

27 Printing, publishing <5c Newspaper printing 6c equipment allied ind. cleaning wastes 4, 14, 16, 29

27 Printing, publishing 6c Packaging materials paint sludge allied ind. <5c solvent 4, 13, 24

27 Printing, publishing <!c Photofinishing wastes 10 allied ind.

27 Printing, publishing 6c Chromate printing wastes 24, 104 allied ind.

281 Industrial inorganic chemicals Nitrous oxide mfg. wastes 10, 104 281 Industrial inorganic chemicals Titanium dioxide mfg.-chloride

process wastes 1, 24



I 00 o

281 Industrial inorganic chemicals Acetylene mfg . sludge 10 281 Industrial inorganic chemicals Industrial gas scrubber wastes 10 281 Industrial inorganic chemicals Antimony oxide mfg . wastes 33 281 Industrial inorganic chemicals Antimony pentafluoride production wastes 15, 24 281 Industrial inorganic chemicals Chrome 6c zinc pigments mfg . wastes 11, 24 281 Industrial inorganic chemicals Hydrogen chloride mfg . wastes 1 281 Industrial inorganic chemicals Chlorine fume control wastes 1 281 Industrial inorganic chemicals* Fluoride salt production wastes 15 281 Industrial inorganic chemicals Mercuric cyanide mfg . wastes 11, 24 281 Industrial inorganic chemicals Barium compounds mfg . wastes 11, 24, 33 281 Industrial inorganic chemicals Dichromate production wastes 24 281 Industrial inorganic chemicals Fluorine mfg. wastes 15, 104

282 Plastics materials & synthetics Adhesives <5c coating mfg . wastes 10, 17, 19, 29 282 Plastics materials & synthetics Polyvinyl acetate emulsion sludge 101, 103 282 Plastics materials <5c synthetics Plywood liquid resin plant wastes 4, 5, 10, 31 282 Plastics materials 6c synthetics Organic peroxide catalyst product4on wastes 3, 101 282 Plastics materials & synthetics Latex mfg. wastes 13, 101, 103 282 Plastics materials <5c systhetics Acry l ic resin production wastes 3, 13, 26, 28, 103 282 Plastics materials <5c synthetics Cellulose ester production wastes 1, 3, 4, 13, 14, 24, 103 282 Plastics materials & synthetic:s Ethylene 6c vinyl chloride mfg . residue 17, 24, 29 282 Plastics materials 6c synthetics Urea 6c melanine resin mfg. wastes 6, 10, 24 282 Plastics materials 6c syntheticrs Vinyl resin mfg . wastes 17, 31 282 Plastics materials <k synthetics Adiponitr i le production wastes 11, 26, 101, 103 282 Plastics materials 6c synthetics Urethane mfg . wastes 16, 24 282 Plastics materials 6c synthetics Synthetic rubber mfg . wastes 14, 16, 17, 27 282 Plastics materials <5c synthetics Rayon fiber m fg . wastes 24

283 Drugs Arsenic pharmaceutical wastes 24 283 Drugs Blood plasma fract ions production

wastes 4



283 Drugs Alkaloids extraction wastes 4, 16, 17, 19, 29, 101 283 Drugs Mercurical pharmaceutical wastes 16, 24 283 Drugs Antibiotic mfg. wastes 13, 1 I '* , 19

284 Soaps 6c detergents Chemical deanlng compounds mfg. wastes 24, 104

284 Soaps 6c detergents Bleach 6c detergient mfg. wastes 10

285 Paints, varnishes, lacquers Paint wash solvent wastes 101 285 Paints, varnishes, lacquers Glycerin sludge 4 285 Paints, varnishes, lacquers Solvent based paint sludge 11, 13, 16, 17, 19, 24, 101 285 Paints, varnishes, lacquers Water based paint sludge 24, 101, 103 285 Paints, varnishes, lacquers Lacquer paints mfg. wastes 13, 16, , 19, 24 285 Paints, varnishes. lacquers Putty 6c misc. paint products

mfg. wastes 24, 101

286 Industrial organic chemicals Benzene sulfonate phenol production Industrial organic waste 1, 16

286 Industrial organic chemicals Phenol production wastes from Industrial organic cnjmene oxidation 17, 101

286 Industrial organic chemicals Phenol production wastes from Industrial organic chlorination benzene 17, 31

286 Industrial organic chemicals Organic dye mfg. wastes 1. 7, , 24, 31 286 Industrial organic chemicals Chromate pigments and dye wastes ^ 7, 24, , 27, 33 286 Industrial organic chemicals Cadmium-selenium pigment wastes 24 286 Industrial organic chemicals Nitrobenzene production wastes 27 286 Industrial organic chemicals Toluene diisocyanate production wastes 18, 101 286 Industrial organic chemicals Pitch 6c creosote equipment cleaning Industrial organic

wastes 10 286 Industrial organic chemicals Chlorinated solvents refining wastes 16, . 17, 19 286 Industrial organic chemicals Transformer oil mfg. wastes 17, 28 286 Industrial organic chemicals Ethylene mfg. wastes by thermal pyrolysis 17, 31



286 Industrial organic chemicals. Ethylene chloride mfg. wastes from organic chemicals. oxychlorination of ethylene 17

286 Industrial organic chemicals Ethylene glycol mfg. wastes 14, 17 286 Industrial organic chemicals Freon mfg. wastes 1, 24 286 Industrial organic chemicals Formaldehyde mfg. wastes 17, 24 286 Industrial organic chemicals Epichlorohydrin mfg. wastes ff, 17 286 Industrial organic chemicals Mfg. wastes from n-butane dehydrogenation 17, 33 286 Industrial organic chemicals Acetaldehyde still bottoms from ethylene oxid. 5, 17 286 Industrail organic chemicals Acetone mfg. wastes 17, 31 286 Industrial organic chemicals Methanol mfg. wastes-carbon monoxide organic chemicals

synthesis 17, 24 286 Industrial organic chemicals Methyl methacrylate resin mfg.

wastes 3, 13, 16, 26, 28, 31, 103 286 Industrial organic chemicals Maleic anhydride production wastes 3, 4, 28, 103 286 Industrial organic chemic:als Lead alkyl production wastes 24 286 Industrial organic chemicals Perchloroethylene production wastes 17, 28, 31 286 Industrial organic chemicals Propylene glycol mfg. wastes 14, 17. 28 286 Industrial organic chemicals Acrylonitrile production wastes 26, 101, 103 286 Industrial organic chemicals Adipic acid production wastes-organic chemicals

cyclohexane oxid. 3, 24 286 Industrial organic chemicrals Vinyl chloride mfg. wastes 17, 31

287 Agricnjltural chemicals Buctril production caustic wash 3 , 10, 16, 17, 31 287 Agricultural chemicals DCP tar 17, 31 287 Agricultural chemicals MCP production wastes I, 3, 13, 17, 31 287 Agricultural chemicals DDT formulation wastes 10, 16, 17 287 Agricultural chemic:als Arsenic pesticide formulation wastes 24 287 Agricultural chemicals Atrazine production wastes 3, 10, 11 287 Agricultural chemicals Malathion production wastes 16, 32 287 Agricultural chemicals Parathion production wastes 1, 32 287 Agricultural chemicals Trifluralin mfg. wastes 16, 17, 27



287 Agricultural chemicals Phosphoric acid production wastes 1, 24

289 Misc. chemical products TNT production wastes 8, 16, 24, 27, 102 289 Misc. chemical products TNT red water wastes 3, 27, 102 289 Misc. chemical products Penite production wastes 24 289 Misc. chemical products Acidic cleaning compounds i

29 Petroleum refining 6c related ind. Coke product wastes 2'f, 101 29 Petroleum refining 6c related ind. Catalyst wastes 24, lOl 29 Petroleum refining 6c related ind. Alkane production wastes 4, 7, 10, 16 29 Petroleum refining 6c related ind. Wastewater treatment air floatation unit floe 10 29 Petroleum refining 6c related ind. Spent caustic 10, , 20 , 24, 31, 33 29 Petroleum refining 6c related ind. Dissolved air floatation emulsion 16, 2 , 31, 33, 101 29 Petroleum refining 6c related ind. Catacarb rinse water 24 29 Petroleum refining 6c related ind. Catalyst sludge 10, 24 29 Petroleum refining 6c related ind. API separator sludge 11, 16, 24, 31, 33, 101 29 Petroleum refining 6c related ind. Liquified petroleum gas proc. wastes 16, 101 29 Petroleum refining 6c related ind. VLE alkylation sludge 10, 15 29 Petroleum refining 6c related ind. Fluid catalytic cracker fines 11 , 16 1 24, 31 29 Petroleum refining 6c related ind. Spent lime from boiler feed water

treatment 10 24, 31 29 Petroleum refining 6c related ind. HF alkylation sludge, neutralized 15, 2*, 31, 101 29 Petroleum refining 6c related ind. Non-leaded gasoline tank bottoms 16, 2% 31, 101 29 Petroleum refining 6c related ind. Leaded-gasoline tank bottoms 16, Ik, 31. 101 29 Petroleum refining 6c related ind. Refinery storm water run off silt 11, 16, 24, 31, 101 29 Petroleum refining (5c related ind. Waste biodegradation sludge 11 1 24, 31 29 , Petroleum refining 6c related ind. Coke fines 24, 31 29 Petroleum refining 6c related ind. Lube oil filter days 16 . 24, 31 29 Petroleum refining 6c related ind. Kerosene filter days 16, 31, 101 29 Petroleum refining 6c related ind. Cooling tower sludge 11, 16, 2*, 31, 101 29 Petroleum refining 6c related ind. Slop oil emulsion solids 16, 24, 31, 101 29 Petroleum refining 6c related ind. Exchange bundle deaning sludge 16, 24, 31, 101



1 CO

29 Petroleum ref ining 6c related ind. Once through cooling water sludge 2 *, 31, 101 29 Petroleum ref ining 6c related ind. Crude tank bottoms 16, 24, 31, 101 29 Petroleum ref ining 6c related ind. Sour refinery waste 10, 11, 20 , 31. 33 29 Petroleum ref ining 6c related ind. Still bottoms 24 29 Petroleum ref ining <5c related ind. Waste brine sludge 24 29 Petroleum ref ining 6c related ind. Gasoline blending wastes 24, 101 29 Petroleum ref ining 6c related indo Soda ash alkaline solution 10 29 Petroleum ref ining 6c related ind. Acid sludge 1 29 Petroleum ref ining & related ind. Caustic cleaning solution 10 29 Petroleum ref ining 6c related ind. Alky spent caustic 10 29 Petroleum ref ining <5c related ind. Lime sludge from raw water treatment 10 29 Petroleum ref ining 6c related ind. Lube oil <5c grease reclaimer's residue 24 29 Petroleum ref ining 6c related ind. Waste lube oil 3c grease 24 29 Petroleum reJ ining <Jc related ind. Recycled oil spent sulfuric acid 1 29 Petroleum rel ining 6c related ind. Recycled oil acid sludge 1 , 16, 28 29 Petroleum rel ining 6c related ind. Recycled oil caustic sludge 10, 24 29 Petroleum ref ining 6c related ind. Recycled oil spent clays. 101 29 Petroleum rei ining 6c related ind. Recycled oil still bottoms 31 29 Petroleum rel ining 6c related ind. Recycled oil wastewater 31

30 Rubber 6c misc. plastic products 30 Rubber 6c misc. plastic products 30 Rubber ic misc. plastic products 30 Rubber 6c misc. plastic products 30 Rubber <5c misc. plastic products 30 Rubber 6c misc. plastic products

31 Leather and leather products 31 Leather and leather products 31 Leather and leather products 31 Leather and leather products

Tires <5c inner tube mixing process wastes Tires 6c inner tube mixing preparation wastes Tires 3c inner tube cleaning process wastes Tires 3c inner tube mfg. wastes Medical product washings Medical product dispersion casting

Tanning solvents Sulfide dehairing sludges Tanning wastes Chrome tan liquor

17, 24, 101 18 17 28 4 16

5, 16, 17, 24,

4, 19 33

10, 13, 24, 101 24, 33


React iv i ty code Industry source Generic name of wastes group nos.

32 Stone, clay, g ass 3c concrete prod. Glass etching wastes 1, 32 Stone, clay, g ass 3c concrete prod. Mirror production wastes 24 32 Stone, clay, gl ass 3c concrete prod. Piezoelectric ceramics compounding

process wastes 24 32 Stone, clay, g ass 3c concrete prod. Piezoelectric ceramics calcining

process wastes 24. 32 Stone, clay, g. ass 3c concrete prod. Piezoelectric ceramics grinding wastes 24 32 Stone, clay, g ass 3c concrete prod. Piezoelectric ceramics pressing wastes 24 32 Stone, clay, gl ass 3c concrete prod. Piezoelectric ceramics polarization wastes 24

33 Primary metal industries Steel mfg. waste oil 24, 101 33 Primary metal industries Stainless steel pickling liquor 1, 2, 24 33 Primary metal industries Pig iron production wastes . 10, 11, 31 33 Primary metal industries Steel finishing wastes 11, 24 33 Primary metal industries Steel mfg. wastes 1, 24, 31 33 Primary metal industries Coke plant raw waste sludge 7, 11, 16, 31 33 Primary metal industries Carbon tubing undercoating process wastes 3, 24 33 Primary metal industries Metal smelting 3c refining wastes 1, 24 33 Primary metal industries Spent battery acid 1 33 Primary metal industries Barium compounds smelting 3c ref ining wastes 24 33 Primary metal industries Aluminum scrap melt ing wastes 23, 25, 107 33 Primary metal industries Metal reclaiming wastes 1, 2, 24 33 Primary metal industries Brass mi l l wastes 1, 24, 104 33 Primary metal industries Aluminum extrusion solvents 4 33 Primary metal industries Aluminum degreasing solvents 19 33 Primary metal industries Aluminum fluodizing process wastes I 33 Primary metal industries Aluminum extrusion equipment cleaning wastes 10, 101 33 Primary metal industries Aluminum foundry wastes 15. 101 33 Primary metal industries Wire 3c cable f iber spinning wash 1 33 Primary metal industries Wire 3c cable spent scrubber solution 15


Reactivity

I 00

code Industry source Generic name of wastes group nos.

34 Fabricated metal products Metal cleaning wastes 1, 2, 3, 24 34 Fabricated metal products Can mfg. wastes 1, 29, 101 34 Fabricated metal products Steel pickling bath wastes 1 34 Fabricated metal products Metal drum reconditioning wastes 10, 24 34 Fabricated metal products Submerged burnishing wastes 11, 24 34 Fabricated metal products Acid plating solution 2 34 Fabricated metal products Programate sludge 10, 11, 24 34 Fabricated metal products Metal stripping wastes 11, 24 34 Fabricated metal products Plating rack stripping wastes 2 34 Fabricated metal products Oxidizing sludge 24 34 Fabricated metal products Plating wastes 11, 24 34 Fabricated metal products Steel fabrication waste oil 101 34 Fabricated metal products Metal plating degreasing solvents 19, lOl 34 Fabricated metal products Copper plating wastes 11, 24 34 Fabricated metal products Brass plating wastes 11, 24 34 Fabricated metal products Aluminum anodizing wastes 1, 24 34 Fabricated metal products Chrome plating wastes 11, 24 34 Fabricated metal products Metal coating phosphate sludge 24, 101 34 Fabricated metal products Aluminum pickling bath 1, 2 34 Fabricated metal products Nickel stripping wastes 11 34 Fabricated metal products Anodizing tank wastes I 34 Fabricated metal products Chemical milling spent caustic 10, 24, 33 34 Fabricated metal products Galvanizing pickling bath 10 34 Fabricated metal products Galvanizing wastes 1 34 Fabricated metal products Wire products metal milling wastes 1, 2, 24 34 Fabricated metal products Rolling mill solvents 24, 101

35 Machinery except electrical Rotogravure printing plate wastes 10, 24 35 Machinery except electrical Duplicating 3c photoequipment mfg. wastes 10, 24 35 Machinery except electrical Electric circuits mfg. acid solution 1, 2, 24 35 Macrhinery except electrical Electric circuits mfg. solvents 4, 16, 19

Table 2. v^ntinued)


35 Machinery except electrical Chromic acid bath 1, 24, 104 35 Machinery except electrical Electric computer metal plating wastes 1, 2, 24 35 Machinery except electrical Computer mfg. wastes 11, 15, 17. 24, 101 35 Machinery except electrical Machinery chemical milling acids 1, 2, 24

36 Electrical 3c electronic equip. Electronic equipment dip 3c cleaning wastes 10, 17, 24, 101 3c sup.

36 Electrical 3c electronic equip Electronic components plating wastes 1, 2, 24 3c sup.

36 Electrical 3c electronic equip. Fiberglass form mfg. wastes 17, 19, 101 3c sup.

36 Electrical 3c electronic equip. Electronic components mfg. solvents 4, 13, 16, 17, 19, 101 3c sup.

36 Bectrical 3c electronic equip. Machine parts cleaning solvents 4 , 17, 19 3c sup.

36 Electrical 3c electronic equip. Electronic components etching solution 10, 15 3c sup.

36 Electrical 3c electronic equip. Copper plating cyanide stripping solution 11 3c sup.

36 Electrical 3c electronic equip. T.V. picture tube mfg. wastes 1, 2 3c sup.

36 Electrical 3c electronic equip. Miniature equip, chemical milling wastes 10, 16 3c sup.

36 Electrical 3c electronic equip. Telephone answering device mfg, wastes ^ 17 3c sup. -

36 Electrical 3c electronic equip. Electronic tube production wastes 1, 24 3c sup.

36 Electrical 3c electronic equip. Metal finishing wastewater treatment sludge 10, 24 3c sup.

36 Electrical 3c electronic equip. Semi-conductor mfg. wastes 1, 2, 24, 104 3c sup



36 Electrical 3c sup.

3c electronic equip. Silicon etching solution 1, 2


3c electronic equip. Electronic components paint sludge , 16, 19, 101, 107


3c electronic equip. Ceramic capacitor production waste solvent 16, 17, 19


3c electronic equip. Magnetic tape mfg. wastes 24, 104


3c electronic equip. Magnetic recorder head laminating proc wastes 4, 14, 17, 19

36 Electrical 3c electronic equip. Battery reclamation wastes 1 • 3c sup. 36 Electrical

3c sup. 3c electronic equip. Storage battery mfg. wastes 10, 24

37 Transportation equipment Automobile paint application 3c clean up wastes 24, 31 37 Transportation equipment Automobile electro deposition primer paint wastes 19, 24, 31 37 Transportation equipment Automobile paint sludge 10, 24, 31 37 Transportation equipment Automobile mfg. wastewater treatment residue 24, 31 37 Transportation equipment Aircraft alkaline cleaning solution 10, 104 37 Transportation equipment Aircraft aluminum etching wastes 10, 33 37 Transportation equipment Aircraft parts acid plating wastes 1, 24, 104 37 Transportation equipment Aircraft parts anodizing wastes I 37 Transportation equipment Chrome plating wastes 24, 104 37 Transportation equipment Aluminum hot-seal wastes 24, 104 37 Transportation equipment Chrome destruct sludge 10, 24 37 Transportation equipment Rail car metal cleaning wastes 1, 24, 101

38 Measuring, analyzing 3c controlling Chlorinated cleaning solvents 17 instruments

38 Measuring, ana lyzing 3c controlling Microfilm production wastes 4, 14, 19 instruments


Reactivity ; code Industry source Generic name of wastes group nos.

38 Measuring, analyzing 3c controll ing Graphic arts adhesive mfg . wastes 16, 28, 101 instruments

49 Electr ic gas 3c sanitary service Askarel liciuid 17

73 Business services Printed c i rcui t board laboratory wastes 24 73 Business services Photographic f ix ing solution 10, 11 73 Business services Film processing acid wastes 3, 5 73 Business services Ship line flush wastes 4, 10, 13, 16 73 Business Services Equipment 3c f loor cleaning caustic wastes 10 73 Business services Acidic chemical cleaning solution 1 73 Business services Railroad equipment cleaning caustic wastes 10, 101 73 Business services Boiler wash 1 73 Business services Solvent recovery tank bottoms 4, 19, 24, 101 73 Business, services Solvent recovery sludge 4, 17, 19, 27, 101 73 Business services Chlorinated solvent recovery st i l l bottoms 17, 24, 101

T A B L E 3

ANTICIPATED RESPONSE ACTIONS FOR CERTAIN COKPOUNDS

0) u u

u u OJ

a:

c o

c t>c-

u u

t J m a) a:

CJ CO >

OJ <n

:=) c q E

PC

o • i - <

B OJ

i - l u I-l

OQ 01

3 - a c

a 01

• r - l OJ

i - l c o

o

CO c: o

o •<-< LJ ±J

3 >~. « OJ U

u o tt> CV. -•-< O i J C •-I OS O) S3 E U ^'^ U <v o o <U Q. C

a : CO M

A c e t a l d e h y d e X X

A c e t i c A c i d

A c e t i c A n h y d r i d e

Acetone X X

A c e t o n i t r i l e X X

Acetophenone

Acetyl Bromide X

Acetyl Chloride X X

Acetylene X X

Ac r o l e i n X X

Acrylamide X

A c r y l o n i t r i l e X X

A l d r i n X

A l k y l Benzene Sulfonic Acids X

A l l y l Alcohol X X

A l l y l C h l o r i d e X X

Aluminum Chloride

Aluminum F l u o r i d e

Aluminum N i t r a t e X X

Anmjonia, anhydrous X

X

X

X

X

X

.X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

1.2

1.2

1.2

1.3,4

1.2

2.9

1,2,5.8,11

1.2.3,5.8.]

1.4,6,20

1,2,5,6

1,2

1.2.5.12,19

1,2,9,12

2,18

1.2.3,5.12

1.2.5.12

1.2,5,8,11.

1,12

1.2

1.2.5.11,20

ANTICIPATED RESPONSE ACTIONS FOR CERTAIN COMPOUNDS

00 U u

CJ •t-l u to V

c o

c

o .•-4 u to (U

3 CJ to >

0) CO

c to B 3 EC u I-l 1-1 to 01

01 m 3

10

o

CO 0)

0) 10

to 3 c

0) 01

• I - l 10 i-l e o o

to c o 0 -I-l 1.1 i - l

3 >> to 01 u i>d 0) c p o 4) Of - I - l U i - l CS I - l eO 0) 10 E 0) o o 01 CL c D i CO

Ammonium B i f l u o r i d e X

Ammonium Ch l o r i d e

Ammonium Dichromate X

Ammonium F l u o r i d e X

Ammonium Hydroxide** X

Ammonium Molybdate X

jnmonium N i t r a t e X

Ammonium Oxalate X

Ammonium Pentaborate X

Aimnonium P e r c h l o r a t e X

Ammonium S u l f i d e X

Ammonium Thiocyanate X

Amyl Acetate X

Iso-Amyl N i t r i t e l f o n i c Acids X

n-Amyl Al c o h o l X

n-Amyl N i t r a t e X

n - A m y l t r i c h l o r o s i l a n e X

A n i l i n e X

Antimony P e n t a c h l o r i d e X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

7

X

?

1.2,18

1.2

1,2,3.7,8.12,21

1.2.18

1,2

7,12

1 .2

i.2

2.7

1.2,5,6.8.12

.1,2

1.2

1,2 ,3,5,6,8.12 .19

1.3

1,2.12,21

1,2,8,11,12,18,21

1.2.12,19

1 ,2 ,8,18

**Dilute and disperse only when other c o r r e c t i v e methods cannot be used.

ANTICIPATED RESPONSE ACTIONS FOR CERTAIN COMPOUNDS OJ 01

f - t C9 OJ to C

c CO OJ ••-( o o CO V i O

tn •w i j i - l i - l <o i J c m 3 0 ) to B 3 >^ to o c B u •o OJ u o 3 CO c « OJ c

< M rc ( b M u o 01 O l •!-<

i j i_l OJ i - l i - l i J O i - l

u o i - l o o U c C I - l t o • I-l - i H to • r ^ • • •-( • I-l 01 to e

U 3 U I-l i J 0 } U l i r i u i - l i J C J i - l i J i - l i - l OJ U o 00 to to to to ai - c l i - l 01 U - l 0 ) 01 > OJ OJ 01 o OJ n. c oi Pi Qi • Q: Qi • ri r / i I - l

Arsenic Acid

Arsenic T r i c h l o r i d e

Arsenic Trioxide

Barium Chlorate

Barium N i t r a t e

Barium Perchlorate

Benzaldehyde

Benzene

Benzophenone

Benzoyl Chloride

B e r y l l i u m , m e t a l l i c

B e r y l l i u m N i t r a t e

B e r y l l i u m Oxide

Boron T r i c h l o r i d e

Bromine

Butadiene, i n h i b i t e d

Butane

1,4-Butanediol

n-Butyl Acetate

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

1 .2

X X X 1,2,18

• X • 'X • ••, X • 1,2,5,8,18

X X X 1,2

X - X 1 ,2 ,7

X X 1.2,7

X X . 1.2,7

X X 1,2

X X X 1.2.4,15

X 2 .•

X . X X 1,2,5,11,12,18

, 1,2.21

X X X 1,2,18,2 1

X X X 1.2,21

X 1,2,5,8,11,18,21

X X X \ 1,2,5,8

X 1,2,4,6,20

X 1,2,4,6,20

X X 2

X 1,2,19


to a> OJ O CJ <

o I - l

i - l to OJ

c o

c

I-l

01 a:

CO 3 CJ to >

fx3

o. to

C3

C to B 3

EC

o • r4

V i i _ l OJ 01

P i

OJ O)

E3

to

o • I-l

u i - l CO OJ

oti

CO 3

c

<n OJ 01 01

OS 3

c • r i to

i - l c o

o

to c o

0 - I - l X J i J

3 to

OJ u ^ ai c

u o OJ O l t - l U i-l C r-H OJ 01 OJ e P • r^ Vi 01 O O

U-i O) U-l OJ O. C

t o 1-1

n-Butyl Alcohol X

Butylamine X

Butylene Oxide. " - .. - X

t e r t - B u t y l Hydroperoxide X

N-Butyl Mercaptan X

Butyraldehyde X

Cadmium Nit r a t e ;." X

Calcium Carbide X

Calcium Chlorate . X

Calcium Chromate X

Calcium Cyanide X

Calcium Hypochlorite X

Calcium, metallic X

Carbon B i s u l f i d e - X

Carbon Monoxide X

Carbon Tetrachloride X

Caustic Soda Solution X

Chlordane X

Chlorine X

Chlorine T r i f l u o r i d e X

X

X

X

X

X

X

X

X

X

X

X

X

X

X X

X X

X X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

1,2,5,6

.1,2,3,4,5,6,14

1.2.7

1.2,5.6,12

1.2

1.2 ,3,7

2 ,10,1.1

1.2 .7

1.2 .

1,2,5,21

1,2

2,8,10,21

1.2,5,6,12

1,5,6,14,20,21

1.2.5

2,8

1.2.9,12

1 ,2 ,5,8,11 ,20

1,2.5,7,8,11,20,2


1—1 OJ 09 c

c CO . OJ • i - < o o to I-l o • H

to •ri ES i - l x J i J

ID i - l C CO 3 OJ • i H to B 3 >> to u c B U T3 OJ CJ o 3 to C 01 c

•< t-i EC • i ( -1 u o OJ P i • H

i - l i - l OJ i - l i - l i - l u i - l

CJ o i - l C I u o c c: ^ to • i H •r.1 to • l - l • I-l • r i • I - l OJ to B

I-l >-• 3 u u I-l to I-l • r J | J

i - l i - l CJ i - i i - l X J i - l OJ o o 01 CO M 01 0 } 01 OJ c t i - l OJ u-l OJ 01 > 0) 01 OJ m o 01 O. C Pi P i W ai oc! OS ES o Pd CO I-l

X X X . X 1.2 .12

X X X X • 1.2 .12

Chlorobenzene

C h l o r o f o r m

C h l o r o m e t h y l M e t h y l Ether .

C h l o r o p i c r i n , l i q u i d

C h l o r o E u l f o n i c A c i d

Chromyl C h l o r i d e

J l l o d i p n

Copper N i t r a t e

Crefsols

Cro tona ldehyde

Cumene H y d r o p e r o x i d e

Cyanogen

Cyanogen Bromide

Cyanogen C h l o r i d e

Cyclohexane

Cyclohexanone

C y c l o h e x y l a m i n e

Cyc lopen tane

Cyclopropane

X • . . X ... X TC . - X . .- X : . ? 1 . 2 , 3 . 5 , 6 . 7 , 1 0 . 1 2

, 18 .

X X X . X X " 1 ,2 , 5 , 8 , 2 1

X X X .. X X 1,2 , 5 , 8 , 1 1

X X X X X 1 , 2 . 5 . 6 , 7 , 1 1 , 1 8

X X .X . • . X • ? 1 ,5 ,6 ,12 -

X X X X. 1,2 , 3 , 7

X ., X X X X 1,2.12

X X ' X i ,2

X X . . • X -v^X rX'^ " 1 , 2 , 3 , 8 , 1 2 , 2 1

X X X . X - X X 1 , 2 i 5 ,6 ,12 ,20

X X X X • X 1 ,2 ,5 ,12

• X X X . .:;X ; ; X 1 ,2 , 5 ,12 ,20

X X X X X 1,2 ,4

X X 1 ,2 ,19

X X X 1,2 ,19

X X X X ? 1 , 2 , 4 , 6 , 1 4

• X X X X 1 ,2 , 4 , 6 , 1 4 , 2 0

ANTICIPATED RESPONSE ACTIONS FOR CERTAIN COMPOUNDS 01 to

ED

to

. . . OJ a c c O l 0) • r i o o E 3 to I-l O - H

to • i- l E 3 i - l i - l i - l CO i - l c to 3 OJ to e 3 to

o c B e X ) OJ u u 3 to e OJ C

< 1—1 u. I - l P o OJ ft. - r i

i_l i - l 01 i - l i - l i - l CJ i-l C J u i - l CJ u u c c ^ to

• r i 0 ) •r.1 • r i • r i • r i OJ to E I-l 3 t-i I-l I-l to >-l - r i C

i - l i - l u i - l i J i - l i - l 0) o o tn to to tn 01 01 c ti-l OJ u-l 0) OJ > OJ <U 01 o 0) (X c

Pi w (A Pi Pd o Q i r/1 t-4

DDD - - . X- - X X X 1 ,2

DDT X X X X X X 2 ,9

Decaborane X X X X X X 1 , 2 , 4 , 1 5

D i a z i n o n X X X X 1 , 2 , 3 , 9 , 1 2

Dibenzoy l Peroxide X X X X 1 , 2 , 7

Dichlcjrobenzene X X 2 .12

. D i c h l o r o d i f l u o r o m e t h a n e (Freon 22) ' X 1

1,2-Dichloroethylene ' X X X ' X 1,2,3,5,6.9,12

Dichloromethane X X X X 1,2,12

2,4-Dichlorophenoxy Acetic

Acid X X X X 1 ,2

Dich lo ropropane X X X X 1 ,2 ,12

D i e t h y l z i n c X X X 1 , 2 , 8 , 1 0 , 2 1

Dimethylamine X X X X 1 , 2 , 3 , 2 0

D i m e t h y l d i c h l o r o a i l a n e X X X X 1 , 2 , 3 , 5 , 6 , 8 , 1 1

Dimethyl formamide X . X X X X X 1,2

1 , 1 - D i m e t h y l h y d r a z i n e X X X X X X 1 , 2 , 5 , 1 2

D i m e t h y l S u l f a t e X X X X X 1 , 2 , 8 , 1 2

D i m e t h y l S u l f i d e . X X X X X ? 1 , 2 , 5 , 6 , 1 2 , 1 9

D i m e t h y l z i n c X X X X 1 , 2 , 6 , 8 , 1 0 , 2 1


OJ o u

<: u

• r i u i-l IO OJ

Di

c o

c 60

U • r i u

i-l 00 OJ

P i

to 3 o CO >

OJ CO

E3

C to B 3

EC

u

Vi i-l n OJ

P i

01 in

to Fx.

u •I-l u i-l to 01

P i

3

c

u • r i

Vi

01 OJ OJ CO

P i E3

• r i to i-J c o u

to c o 0 -I-* i-l i-J

3 to

OJ u i<i OJ c

Vi O OJ P i • H CJ xJ C r-l 0) OJ to 0 Vi . r i C OJ o o

U-l 0) u- l -01 a, c

p i CO I-l

2,4-Dinitroaniline - X

Dinitrobenzene- • X X

2 ,4-Dinitrophenol - X

2,4-Dinitrotoluene • X - X

1,4-Dioxane X . X

Endrin X

Ethyl Acetateoromethane X X

Ethyl Acrylate " / . " ' .• X X

Ethyl Alcohol X X

Ethylaliuni-num" Dichlorijde . ' X • X

Ethylamine " ;X X

Ethylbenzene' ; X X

Ethyl Chloroformate "X X

Ethy l d i c h l o r o s i l a n e X.. X

Ethylene X X

Ethylene Glycol

Ethylene Glycol Monoethyl Ether

'Jthylene Glycol Monomethyl ,ther

X

X

X

.X

•X

X

X

.X.

±

X .

X

X

-X

X

X

. X 1,2,12.

X 1,2,3,21 -

X 1,2,12.-

X 1.-2.3-.21

I , 2,3

X 1 ,2 ,12

X 1 ,2

X i . ; 2 ,19 ' •

3 •

. i;-2^3V5;i5i8,10, I I , 18,21 •

1,2,5,6,8,12,20

X 1,2',19

1,2,3,8,12,18

1.2,3.5,6,8,11,1 18,21

1,2,4,6,20

None


IS CO OJ u o < u

• r i Vi x i 01 0)

Pi

c o

c 00

o • r i

Vi

0) P i

to 3 o 00

>

c to B 3

o • r i

Vi X J tn OJ

Pi

OJ 01

E3

to f«i

CJ • I-l

V i i - l <o 01

Pi

00 3

•O c

in OJ 01 00

oi E3

c • r i to

i_l c o

o

to c o

3 >-. 10 Ol o

t . i OJ C Vi o

01 ft, • r i CJ i-l C •—I CO Ol 10 B

• r i V i O) u o

>x-l 01 u- l Ol Ou C

P i CO >-»

Ethyl Formate

Ethyleneiminee

Ethylene Oxide

Ethyl Ether

Ethyl Mercaptan

Fe r r i c N i t r a t e

Fluorine

Fluosulfonic Acid

Formaldehyde Solution

Formic Acid

Fumaric Acid

Furfura1

F u r f u r y l Alcohol

Heptachlor

Hept ane

Heptanol

Hexane

Hydrazine

Hydrochloric Acid

H y d r o f l u o r i c Acid

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

1 .2 ,3.5,6

1,2,5

1 ,2,6,20

1 ,2 .4,6.14

1,2.5,6,12.19

1 ,2 ,3,7

1,2,5,8,20

1 ,2 ,5,8,11 ,18

1 ,2

1,2.8

1,2

1,2

1,2

1,2.21

1.2.4,15

1 .2,4.15

1.2.5,6

1,2,8

1 ,2 ,8,20


r - l (0 01 to c

c in OJ • r i o o E3 to Vi o • r i

in • r i ED XJ X J i - l CO i - l C Ol 3 OJ • r i 10

rra 3 >-. 10

u c E rra

•o 01 o o CO 3 to c Ni OJ c < • - i ns Cx, I - l

OJ Pr

io

X J X J 01 X J X J x J u XJ CJ CJ x J O CJ o c c .—1 to

• f - l • r - l to • r - l • r i • r i • r i OJ to e Vi V i 3 Vi Vi U a Vi • r i Vi XJ XJ U XJ xJ X J X J OJ o o 0} to to Ol in in <u c u- l OJ u- l OJ 01 > 01 01 OJ to o 01 a. C

p i p i w p i P i P i : 3 o P i CO

Hydrogen Bromide

Hydrogen Chloride

Hydrogen Cyanide

Hydrogen Peroxide

Hydrogen Sulfide

Hydroquinonete

Isobutane

Is o b u t y l Acetated

I s o b u t y l Alcohol

Isobutylamine

I s o b u t y r o n i t r i l e

Isopentane

Isopropyl Alcohol

Isopropylamine

Isopropyl Mercaptan

Isovaleraldehyde

Lauroyl Peroxide

Lauryl Mercaptan

Lead N i t r a t e

êad Tetracetate

X X X 1,2,5,8,18,20

X X X X X 1 ,2 ,5,8, 11 ,20

X X X X X X 1,2,5,11,20

X X X X 1,2,7

X X X X X X 1,5,20

X X X 1,2

X X X. X 1.4,6,14,20

X X X 1,2

X X X X 1.2,3

X X X X X X 1,2,5,6,8

X X X X ? 1,2,5,6,12

X X X X X 1 ,2 .4

X X 1

X X X X X X 1.2.5,6.12

X X X X X X 1.2,5.6,12

X X X X X ? 1,2,4,5,6,14

X X X X X X 2,7,17,21

X X X 1,2,12

X X X X X 1,2,7

X X X X X 1,2,3,7,8


1—1 to OJ ca C

c O l 0) • r i o o ED 01 Vi o • r i

01 • r i ED i - l X J X J

CO X J C to 3 01 • r i CO B 3 >> to O c E Vi •a 01 u CJ 60 3 to c Ni 0> d < h-l h-l

01 Pr

io

X J X J OJ XJ XJ XJ o XJ CJ ( J X J O o CJ C c •—1 to

• r - l • H to • r i • r i • r i - r i 01 CO B V i V i 3 V i u V i OJ u • r i u

i - l i - l CJ X J X J X J i - l 01 U o tn m to 01 01 tn OJ c I X i 01 O i

01 OJ > 01 OJ 01 01 o OJ cx c P i P i P i P i P i ED P i CO

X X X 1,2 Lead Thiocyanate

L i q u i f i e d N a t u r a l Gas X X X

L i q u i f i e d Petroleum Gas : X X X

L i t h i u m Aluminum Hydr ide X X X . X

L i t h i u m Hydride X X X

L i t h i u m , m e t a l l i c . X X X

Magnesium X

Magnesium Perchlorate X X X

Malathion • X X

Mercuric N i t r a t e . X X X

Mercury X

Mesityl Oxide X X X

Methaneylaraine X X X

Methoxychlor X X

Methyl Acetate X X X X

Methyl Acrylate X X X X

Methyl Alcohol X X

Methylamine X X X X

Methyl Bromide X X X

X

X

X

X

X

X

X

X

X

X

1,2,4,6,14,20

1,2,4,6,14,20-

2,8,10,11

1,2,3,5,6,7,8. 1 1 ,16,21

I , 2,3,5,6,7,8, I I , 16,21

2 1

I ,2 ,7,21

1.2,9,12

1.2,3,7.21

2,13

1.2,3,4,8,14.1

1 ,2 ,4,6,14,20

1.2 1.2.3,5,6

1,2

1,2,3

1,2 ,3,5,6,8,12

1,2,5,12,20


— t—1 01 OJ to c c to OJ • r i o

o ED in U . O •'H to • r i E3 X J X J X J CO X J C to 3 OJ • r i to E 3 > i to u C B U •o 01 CJ u 60 3 to c N i 01 C < • H i EC ( x . I - l Vi O

OJ OJ P i —*

X J i - l OJ i - l i - l X J U X J

o CJ x J O o CJ c C I - l CO - r i • r i to • r i • r i • H • r i 01 to E

V i V i 3 V i V i . V i to V i - r i C J - l X J o i - l X J X J i - l V U G 01 m CO 01 m to OJ c u - l OJ u - l OJ 01 > 01 OJ OJ 10 o OJ o- c

P i P i W p i OS o i ED t J ai rn t-l X X X X 1 , 2 , 5 . 1 2

X X X X X X 1 . 2 , 3 , 8 ,

X . X X

-• X ? 1 . 2 . 4 , 6 .

Methyl Chloride

Methyl Chloroformate

Methylcyclopentane

HethyId ichloros i l a n e

Methyl Ethyl Ketone

Methyl Formate

Methylhydrazine

Methyl I s o b u t y l Ketone

Methyl Mercaptan

Methyl Methacrylate

Methyl V i n y l Ketone

Nickel Carbonyl

Nickel N i t r a t e

Nicotine

N i t r i c Acid

Nitrobenzene

Nitrogen, l i q u i f i e d

Nitrogen Tetroxide

Nitromethane

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

1,2,3.5,6,8,11.1 18.21

1.2

1.2,3.5,6.12

1 ,2.3,5,6,8,21

1,2,19

1 ,2,3,4,5,6,20

1.2 •

1,2,3.5.6,8.21

1,2,3,5.6,8,9.12

1.2,7

1.2,12

1.2,5,7,8

2 ,12

2 ,20

l\2,5,8,20

1.3


r—1 m OJ 1 0 c

c 0 1 0 1 • r i o o ED I O V - O • r i

t o • r i ED X J X J X J

CO X J C CO 3 OJ • r i to B 3 >^ to u c E B -o OJ O

u 6 0 3 CO c N i OJ C < I - i 32 [ X i t - i V i O

0 1 O i - r i X J X J OJ x J X J

o r O X J

u o i - l O U o r c C t - l t o - - i • r i CO • r i • r i • rW • r i OJ 10 E

V i V i 3 V i V' U to U • r i V i

X J i_ l CJ X J i - l X J X J 0) o o 0 1 o: 10 0 1 0 1 0 1 0 1 C u - l OJ u - l

0 1 0 1 > OJ 0 ) OJ to o OJ a . c P i P i UJ PS Pi p i 3 CJ p i CO l-<

X X X X X 1 ,2 ,21 Ni t rophenol

Ni t rous Oxide X X

Octane X X

Oils, f u e l : No. 1 (kerosene) ID, 2D. 3. 4, 5, & 6 X X

Oleum X

Oxalic Acid X

Oxygen, l i q u i f i e d X X

Paraformaldehyde X

Parathion, l i q u i d X

Pentaborane • • X X

Pentachlorophenol X

Pentane X X

Perchloric Acid X X

Petroleum Naptha X X

Phenol X

Phosgene X

Phosphoric Acid X

Phosphorus Oxychloride X

Phosphorus Pentasulfide X X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

1,2,20

1,2,4,14

2.4,15

1 ,2 ,8,11 ,18

1 ,2 ,6 ,7 ,20,2 1

1 ,2 ,6.7.20 .2 1

1 ,2

1 ,2

1.2

1.4

1 ,2 .8,18

2,4,15

1.2.12,19

1.2.5.11.20

2.8

1.2.5,11,18

1,2.5,11,18


i - < 03 OJ to C

C m a) o O ED CO P O . r i

to • (H '—1 x J XJ X j o> XJ C 01 3 0) - r i to e 3 to u c E Vi - a OJ u U 6 0 3 c e c N i O J C

< t - l ac U i M P o OJ PLI - r i

X J X J O J X J X J X J CJ xJ U U XJ U CJ CJ C C i — 1 1 0

• r i - r i t o - r i • r i • r i • r i OJ tO E Vi Vi 3 > V i U Vi to V i T i V i

XJ x J CJ X j X J XJ X j ' O J C j O m 01 to to CO o i O J C U - i o i U - i Ol OJ > o j / o j o j c o o o j c i ^ c

P i p i W . o i OS p i E D C J p i C O H - l

Phosphorus, red ' X X X 2,12

Phosphorus Tribromide X X . X 1,2,5,8,11,18

Phosphorus T r i c h l o r i d e - X X X X X 1,2,5,11,18

Phosphorus, white X X X X " 1,2,5,12-

Polychlorinated Biphenyl X X X X 2

Polyphosphoric Acid X 2,8

Potassium Arsenate X X X 1,21 -

Potassium Chlorate ^ X X X X . X 1,2 ,-7,21

Potassium Chromate X X X X X 1,2,7,8,2 1

Potassium Hydrojcide ' X • 1.2,8

Potassium, m e t a l l i c X X 2,7,16

•Potassium Peroxide X "X X 1,2,7,8,11,21

Propane X X X 1,2,4,6,14,20

Propionaldehyde X X X 1,2

Propylene Oxide X X X 1.2,3

Propyleneimine, i n h i b i t e d X X X X X X 1,2,5,6,8,12

Propyl Alcohol X X 1,3

Pyridine X X X X 1,2,3,5

Resorcinol X X X 1,2

S i l i c o n T e t r a c h l o r i d e X X X 1,2,5,11,18


Sodlum

Sodium Amide

Sodium Azide

Sodium Borohydride

Sodium Chromate

Sodium Cyanide

Sodium Hydride

Sodium Hydroxide

Sodium Methylate

Sodium N i t r i t e

Styrene

S u l f u r i c Acid

Sulfur Dioxide

Sulfuryl Chloride

Tetrachloroethane

Tetraethyl Lead

Tetrahydrofuran

Thiophosgene

Thorium Nitrate

Titanium Tetrachloride

01 01 OJ o CJ <

i - l u

c o

c 6 0

10 OJ

to 3 u to >

U J

OJ m

c 10 E 3

E C

ui 01

OJ tn

ED

CO

3 -O

c

Pi

c o P i ED U

CO 01 01 to

01 c o

0 " i X J X J

3 > ^ 10 01 U

N: OJ c Vi o

OJ ft, • « U X J C r ^ CO o) CO E Vi • r i Vi 0 , 0 0

u-l 0, u- l OJ C L c

p i CO I - l

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X.

X

X

X

X

X

X

X

X

2 , 6 . 1 0 . 1 2 . 16

1 .2 . 5 , 8 . 1 1

1 ,2 ,21

1 ,2 ,6 ,10

1 . 2 . 7 , 8 . 2 1

1,2,5

2 , 6 , 1 0 , 1 1

2,8

1 .2 . 3 , ^ . 8 , 1 ! , !

1,2

1 ,2

2 ,8

1 , 2 , 5 , 8 , 1 1 , 2 0

1 , 2 , 5 , 8 . 1 1 , 1 8

1.2

1 ,2 .5 ,12

1.2

1,2 , 5 , 8 , 1 0 . 1 2 .

1 , 2 , 3 , 7 , 1 8 , 2 1

1 ,2 , 8 , 1 1 , 1 8

RESPONSE ACT IONS FOR CERTAIN COMPOUNDS

f—1 t o OJ to C

c t n 01 • r i o o ED Vi o • r i

0 ] • r i is i - l X J X J

CO X J C t n 3 01 • r i 10 B 3 10

o c E u •n 01 o o 6 0 3 t o c Ni OJ c < H i rc P u t-l Vi o

OJ p i • I - l

i - l x J 01 X J X J X J u X J

u O X J O O O c c I - i to • r i • r i 10 • r i • r i • r i • r i OJ to B u V i 3 V i V i V i 10 V i • r i Vi i - l X J o X J i - l X J i - l 01 o o t n t n to 0 1 t n 01 OJ c U i 01 t x j

OJ OJ > OJ 01 OJ 10 o OJ a. c P i P i UJ P i oi a ED u P i CO I - l

X X X X X X 1.2 ,3 . 5 1 8 , 20

X X X X X 1.2 .4 , 1

X X X X 1.2 .2 1

V i n y l t r i c h l o r o s i l a n e

Xylene

Zinc Arsenate

Zinc Borate 1 ,2

REFERENCY KEY TO RESPONSE INDEX 1. Avoid i n h a l a t i o n . Vapors or dust are i r r i t a t i n g or t o x i c . 2. Avoid d i r e c t c o ntact. Contact w i t h s k i n or eyes can cause i r r i t a t i o n

or burns. 3. No i g n i t i o n hazard once m a t e r i a l i s d i s s o l v e d , reacted, or covered

w i t h water. 4. Burning may be p r o h i b i t e d by a n t i - a i r p o l l u t i o n laws and r e g u l a t i o n s . 5. Poisonous gas or vapor danger. Substance i s h i g h l y v o l a t i l e . 6. Flammable or explosive gas or vapor danger. Substance i s h i g h l y

v o l a t i l e . 7. Powerful oxidant - explosion and/or f i r e hazard i n the presence of

organic matter. 8. Highly c o r r o s i v e , p a r t i c u l a r l y t o eyes and s k i n . 9. Sorbs s t r o n g l y on bottom sediments. Substance i s not at a l l s o l u b l e

or r e a c t i v e . 10. Reacts w i t h water t o form explosive or flammable gas or vapor. 11. Water r e a c t i v e compound which re a c t s v i g o r o u s l y or v i o l e n t l y .

Disperse or n e u t r a l i z e contaminated waters a f t e r r e a c t i o n subsides.

12. Burning not recommended; f i r e d i f f i c u l t to c o n t r o l and/or poisonous gas i s formed.

13. Cover w i t h organic s u l f u r - c o n t a i n i n g compounds or f r e e s u l f u r . 14. Clean burning. 15. Sooty burning. 16. DO NOT ADD water t o chemical; AFTER the chemical has reacted w i t h

water, the r e s u l t i n g a l k a l i n e s o l u t i o n can be d i l u t e d . 17. F l o a t i n g s o l i d s . 18. Strong a c i d formed i n water. 19. F i r s t t r y t o co n t a i n and skim; THEN d i l u t e and disperse what has

dis s o l v e d i n water. 20. Chemical shipped as gas or l i q u i f i e d compressed gas; depending on

atmospheric c o n d i t i o n s , a l a r g e p r o t i o n of the hazard w i l l be d i s s i p a t e d w i t h no a c t i o n necessary.

21. Has unusual f i r e or t o x i c i t y hazards. See the hazardous chemical data sheets f o r chemical.

22. May f l o a t or sink as i n s o l u b l e substance or d i s s o l v e l i k e m i s c i b l e substance. See the hazardous chemical data sheets f o r chemical.

RESPONSE DEFINITIONS A. CAUTIONARY RESPONSES 1. R e s t r i c t Access - This response i s invoked when appreciable danger

a r i s e s from a flammable or t o x i c s p i l l , and the general p u b l i c (spectators) should be kept from the s p i l l area. Access i s r e s t r i c t e d i f i g n i t i o n i s considered p o s s i b l e ( r e s t r i c t i g n i t i o n ) , or i f evacuation i s recommended.

2. R e s t r i c t I g n i t i o n - This response i s invoked when chemicals are in v o l v e d which develop flammable vapors.

3. Evacuate - This response i s invoked when there i s a very r e a l danger t h a t a h i g h l y flammble or t o x i c s p i l l may spread, or develop a d e t r i m e n t a l r e a c t i o n w i t h water. This category i n c l u d e s flammable chemicals and extremely t o x i c chemicals, e.g., poisonous gases.

4. R e s t r i c t Human Use - This response i s invoked when mostly s o l u b l e substances or those which are e x c e p t i o n a l l y t o x i c are i n v o l v e d i n a s p i l l . The primary danger i s t h a t of i n g e s t i n g the chemicals i n d r i n k i n g water.

5. R e s t r i c t Farm Use - This response i s invoked when a t o x i c chemical contaminant i s s p i l l e d i n water used f o r i r r i g a t i o n or animals.

6. R e s t r i c t I n d u s t r i a l Use - This response i s invoked when the s p i l l contains chemicals which could corrode machinery, or i f the p o s s i b i l i t y of i g n i t i o n from h i g h l y flammable organics i s developed. Those chemicals which upon h e a t i n g could release poisonous gases could also cause t h i s response t o be invoked; as could those which might form an i n s u l a t i n g f i l m on i n t e r n a l b o i l e r surfaces.

REACTIVITY GROUPS

1• Non-Oxidizing Mineral Acids Hydrochloric Acid H y d r o f l u o r i c Acid Phosphoric Acid

2. S u l f u r i c Acids Spent S u l f u r i c Acid S u l f u r i c Acid (98% or less)

N i t r i c Acid N i t r i c Acid (70% or less!

4. Organic Acids Acetic Acid B u t y r i c Acid Formic Acid Propionic Acid A c r y l i c Acid ( i n h i b i t e d )

5 . Caustics Caustic Potash S o l u t i o n Caustic Soda S o l u t i o n Cresylate Spent Caustic S o l u t i o n Sodium Hydrosulfide S o l u t i o n

(45% or less)

7 • A l i p h a t i c Amines Butylamine Cyclohexylamine

:Dibutylamine ; Diethylamine i D i e t h y l e n e t r i a m i n e ; Diisopropylamine '' Dimethylamine '. Di-n-propylamine Ethylamine

: Ethylenediamine ' Hexamethyleneimine ; Methylamine , Morpholine i Propylamine i Tetraethylenepentamine ;Tr i e t h y l a m i n e

' 8.Alkanolamines Aminoethylethanolamine

: Diethanolamine Diethylethanolamine Diisopropanolamine

! Dimethylethanolamine i Ethanolamine i Propanolamine j Triethanolamine

9-Aromatic Amines

6 . Ammonia Ammonia, Anhydrous Ammonium Hydroxide (28% or less) Ammonium N i t r a t e , Urea, Water

Solutions ( c o n t a i n i n g Ammonia!

A n i l i n e P y r i d i n e 2-Methyl-5-Ethylpyridine

10. Amides Dimethylformamide

11. Organic Anhydrides Acetic Anhydride P h t h a l i c Anhydride Propionic Anhydride

12. Isocyanates Diphenylmethane Diisocyanate Polyphenyl Polymethylene-

isocyanate Toluene Diisocyanate

13. Vynyl Acetate V i n y l Acetate ( i n h i b i t e d )

14. A c r y l a t e s B u t y l A c r y l a t e ( i n h i b i t e d ) B u t y l Methacrylate ( i n h i b i t e d ) Decyl A c r y l a t e ( i n h i b i t e d ) E t h y l A c r y l a t e ( i n h i b i t e d ) 2-Ethylhexyl A c r y l a t e ( i n h i b i t e d ) E t h y l Methacrylate ( i n h i b i t e e d ) Methyl A c r y l a t e ( i n h i b i t e d ) Methyl Methacrylate ( i n h i b i t e d )

15. S u b s t i t u t e d A l l y l s A c r y l o n i t r i l e ( i n h i b i t e d ) A l l y l Alcohol A l l y l Chloride 1,3-Dichloropropene

16. Alkylene Oxides Propylene Oxide Butylene Oxide

i 17. E p i c h l o r o h y d r i n E p i c h l o r o h y d r i n

18. Ketones Acetone Camphor O i l Cyclohexanone D i i s o b u t y l Ketone Isophorone M e s i t y l Oxide Methyl E t h y l Ketone

i Methyl I s o b u t y l Ketone

, 19. Aldehydes Acetaldehyde A c r o l e i n ( i n h i b i t e d ) Butyraldehyde

• Decaldehyde Ethylhexaldehyde

' Formaldehyde ' Glutaraldehyde S o l u t i o n ; Glyoxal S o l u t i o n Methylbutyraldehyde O c t y l Aldehyde Pentyl Aldehyde Propionaldehyde Valeraldehyde

20 Alcohols, Glycols Amyl Alcohol B u t y l A l c o h o l 1,3-Butylene Glycol Cyclohexanol Decyl Alcohol Diacetone Alcohol D i i s o b u t y l C arbinol Dodeconol Ethanol Ethoxylated Alcohols

C -C 11 15

E t h y l Alcohol E t h y l b u t a n o l Ethylene Chlorohydrin Ethylene Cyanohydrin Ethylene Glycol 2-Ethyl Hexanol F u r f u r y l Alcohol G l y c e r i n Hexanol Hexylene Glycol Methanol Methyl Alcohol Methylamyl Alcohol M e t h y l i s o b u t y l Carbinol Octyl Alcohol Nonyl Alcohol Pentadecanol Propyl Alcohol Propylene Glycol S o r b i t o l Tallow F a t t y Alcohol Tetradecanol Tridecanol Undecanol

li Butylene i Decene , Dicyclopentadiene D i i s o b u t y l e n e Dodecene Ethylene Hexene Isoprene ( i n h i b i t e d ) Methyl Acetylene, Propadiene

Mixture ( s t a b i l i z e d ) (alpha-) Methyl Styrene

( i n h i b i t e d ) Nonene Octene Pentene Polybutene Polypropylene

'. Propylene Propylene Butylene Polymer

;Propylene Tetramer Styrene ( i n h i b i t e d ) V i n y l Toluene ( i n h i b i t e d ) Tetradecene Tridecene Turpentine Undecene

21 Phenols and Cresols Carbolic O i l Creosote, Coal Tar Cresols Nonyl Phenol Phenol

22. Caprolactam S o l u t i o n Caprolactam S o l u t i o n 23-29 Unassigned 3 0. O l e f i n s Butadiene ( i n h i b i t e d ) Butene

31 P a r a f f i n s Butane C y c l o a l i p h a t i c Resins Cyclohexane Decane Dodecane Ethane Heptane Hexane Methane Nonane Octane Pentane Propane

32. Aromatic Hydrocarbons Benzene Benzene, Toluene, Xylene (crude) Cumene Cymene Decylbenzene Diethylbenzene Dodecylbenzene Ethylbenzene Naphthalene Tetradecylbenzene Tetrahydronaphthalene Toluene Tridecylbenzene TriethyIbenzene Undecylbenzene Xylene

33. Misc. Hydrocarbon Mixtures Asphalt Asphalt Blending Stocks Diphenyl - Diphenyl Oxide D i s t i l l a t e s Gas O i l , Cracked Gasoline Blending Stocks Gasolines Jet Fuels Kerosene Mineral S p i r i t s Naphtha O i l s , Crude O i l s , Diesel O i l s , Coal O i l s , Fuel (No. 1 t h r u No. 6) O i l s , Residual O i l s , Road O i l s , Transformer Petrolatum Petroleum Naphtha

Amyl T a l l a t e |! B u t y l Acetate 1 B u t y l Benzyl Phthalate I Castor O i l ; Coconut O i l Cottonseed O i l D i b u t y l Phthalate

'i Diethylene Glycol Monobutyl i Ether Acetate I , D i h e p t y l Phthalate : D i i s o d e c y l Phthalate I Dinonyl Phthalate

D i o c t y l Phthalate Diundecyl Phthalate E t h y l Acetate

'Ethylene G l y c o l Monobutyl .; Ether Acetate , Ethylene G l y c o l Monoethyl

Ether Acetate 1 E t h y l h e x y l T a l l a t e ij Fish O i l j G lycol Diacetate ji L a r d I Methyl Acetate jl Methyl Amyl Acetate ji O c t y l Epoxy T a l l a t e ;i O l i v e O i l I Palm O i l j Peanut O i l Propyl Acetate

I Safflower O i l I Soybean O i l I Tallow ; Tucum O i l \ Vegetable O i l

35. V i n y l Halides V i n y l Chloride ( i n h i b i t e d ) V i n y l i d e n e Chloride ( i n h i b i t e d )

3 4. Esters Amyl Acetate Chloroform Dichiorobenzene 1,1-Dichloroethane D i c h l o r o e t h y l Ether Dichloromethane 1.1- Dichloropropane 1.2- Dichloropropane E t h y l Chloride Ethylene Dibromide Ethylene D i c h l o r i d e Methyl Chloride Pentachloroethane Perchloroethylene 1,1,2,2-Tetrachloroethane 1,2,4-Trichlorobenzene T r i c h l o r o e t h y l e n e

37. N i t r i l e s A c e t o n i t r i l e A d i p o n i t r i l e 38. Carbon D i s u l f i d e

j' 36 • Halogenated Hydrocarbons y Carbon T e t r a c h l o r i d e Chlorobenzene Ethylene Glycol Monomethyl Ether

Nonylphenol, Ethoxylated Polyethylene Glycols

i Polypropylene Glycols i Polypropylene Glycol Methyl i Ether j Soybean O i l , Epoxidized i Tetraethylene Glycol ; T r i e t h y l e n e G l y c o l

41 Ethers

39 Sulfolane

.Butyl Ether I, 1, 4-Dioxane E t h y l Ether Methyl Formal (Dimethyl

Formal) Propyl Ether Tetrahydrofuran

; i ! 4 2. Nitrocopounds (mono-) Nitrobenzene 1- or 2-Nitropropane

;• N i t r o t o l u e n e

40. Glycol Ethers Diethylene Glycol Diethylene Glycol Monobutyl Ether

Diethylene Glycol Monoethyl Ether

Diethylene Glycol Monomethyl Ether

Dipropylene Glycol Ethoxy T r i g l y c o l Ethylene Glycol Monobutyl Ether

Ethylene Glycol Monethyl Ether

43 Miscellaneous Water Solutio n s Ammonium N i t r a t e , Urea, Water Solution s (not c o n t a i n i n g Ammonia)

Corn Syrup Dextrose S o l u t i o n Latex Solutions Tetrasodium S a l t of EDTA So l u t i o n

CHAPTER SIX Training Manual No.5

FACILITY OPERATIONS MANUAL

prepared by


Orient Road

Tainpa F l o r i d a

CONTENTS

Topi c I n t r o d u c t i on Incoming M a t e r i a l Manifests Manifest - E x h i b i t 1 Labe1ing Piacarding Storage Empty Drum Handling Basic Safety P o l i c i e s D r i v e r I n f o r m a t i o n DOT I n c i d e n t Report - E.xhibit 2 T r a n s p o r t a t i o n Routes C e r t i f i c a t i o n Statement

I n t r o d u c t i o n

This manual i s designed to f a m i l i a r i z e you w i t h basic p r a c t i c e s at the Universal Waste & T r a n s i t storage and treatment f a c i l i t y . Much of your t r a i n i n g i n t h i s area w i l l be on-the-job.

Do not be a f r a i d to ask questions!! This i s your t r a i n i n g p e r i o d . We want you to be as safe and comfortable w i t h your d u t i e s as p o s s i b l e . We w i l l a s s i s t you as much as we can.

Remember - i f you have a question or concern about performing a task always ask before a c t i n g ! !

Incoming M a t e r i a l

A l l incoming m a t e r i a l i s to be placed i n t o the "incoming s t a g i n g area" immediately. Do not take these containers anywhere else u n t i l n o t i f i e d to do so by your supervisor.

F a c i l i t y personnel w i l l inspect these containers to i n s u r e t h e i r contents are c o r r e c t and o b t a i n QC samples.

A l l o f f - l o a d i n g should be performed manually i f p o s s i b l e , A "drum t r u c k " should be used. I f however a drum i s too heavy a tow motor equipped w i t h a drum handling attachment w i l l be employed. Never move a drum or container using the f o r k s on a tow motor. There i s always a p o t e n t i a l f o r p u n c t u r i n g the drum.

Manifests For a l l waste movement, e i t h e r bulk or drum l o t s , a manifest f o r the movement of such waste must be prepared e i t h e r by the generator or by Universal Waste & T r a n s i t . The f o l l o w i n g procedure i s to be used; 1. Manifest i s to be prepared before shipment t o the extent p o s s i b l e 2. Manifest i s to i n c l u d e :

a. DOT shipping name b. Hazard Class D e s c r i p t i o n c. A l l r e q u i r e d ID Numbers

3. Manifest must be signed by generator and t r a n s p o r t e r . 4. A copy of the signed manifest must be given to the generator at

the time of shipment. 5. The manifest i s t o be signed by a r e p r e s e n t a t i v e of t h a t

designated treatment/storage/disposal f a c i l i t y (TSDF). 6. The t r a n s p o r t e r i s t o r e t a i n one (1) copy of the manifest and

leave a l l other copies at the treatment/storage/disposal f a c i l i t y , 7. The treatment/storage/disposal f a c i l i t y w i l l r e t u r n the manifest

to the generator. 8. For pickup of drum l o t s f o r t r a n s f e r to the Universal Waste &

T r a n s i t storage f a c i l i t y , the manifest must in c l u d e a l l r e q u i r e d c e r t i f i c a t i o n statements.

9. Other requirements as d i c t a t e d by s p e c i f i c disposal s i t e s such as work order number and code number must be addressed as necessary.

A t y p i c a l manifest and c e r t i f i c a t i o n statements are attached.

3-

EXHIBIT 1 UNIVERSAL WASTE & TRANSIT, INC.

UNIFORM HAZARDOUS WASTE MANIFEST

1. G e n e r a l o r ' j US EPA 10 No, M a n i f e i t Document No.

2. Page 1

of

I n lo rma f ion in the shodeci oreos it not requiretJ by Federa l l aw .

3. G e n e f o t o r ' j N a m e a n d Mo i l i ng Address

4. Generator 's Phone ( )

A. Stole M o n i f e j t OocumenI Numbe r

B. S la te Generator 's 10

5. Transporter 1 Company N o m e US EPA 10 Number C. Stole Transporter 's ID

0 . Transporter 's Phone

7. Transporter 7 Compony Nome US EPA ID Number E. State Tronsporter 's ID

F. Transporter 's Phone

9. Des ignated Facility N a m e a n d Site Address 10. US EPA ID Number G . Stole Focili ly's ID

H. Facility's Phone

11. US DOT Description [Including Proper Shipping Name, Hazard Class, and 10 Number)

!HM

12. Containers

No. Type

13. Total

Quon t i t y

14. Unit

W l / V o l Waste No .

E N E R A T O

J . Additional Descriptions for Materials Listed Above K. Hand l i ng Codes for Wastes Listed Above

IS. Special Hand l ing Instructions a n d Add i t i ona l In fo rmat ion

16. GENERATOR'S CERTIFICATION: I he reby dec la re t h a i the contents of this consignment are ful ly a n d accurate ly descr ibed obove by p rope r sh ipp ing name a n d are classi f ied, p a c k e d , m a r k e d , a n d l a b e l e d , a n d are in a l l respects in p roper condi t ion for t ransport by h ighway accord ing to app l i cab le in te rnat iona l a n d na t i ona l governmenta l regulat ions.

Oote

Pr in ted /Typed Nome Signature Month Ooy Yto,

T

I N S P 0 R T E R

17. Transporter 1 Acknowledgement of Receipt of Moter io ls Dole

Pr in ted /Typed Nome Signature Month Day y . o ,

18. Transporter 2 Acknowledgement of Receipt of Mater ia ls Dolt

Pr in ted /Typed Nome Signature Month Ooy y*a,

19. Discrepancy Indicat ion Space

' 2 0 . Facility Owner or Ope ra to r : Cert i f icat ion of receipt of hazardous mater ia ls covered by this manifest except as no ted in Item 19.

Dot* ' P r in ted /Typed Nome

1 Signature Monfh Ooy ftor

•• 1 • 1 • ORIGINAL-RETURN TO GENERATOR

Labeling

Before shipment of any drum l o t wastes, a l l EPA and DOT r e q u i r e d l a b e l must be a p p l i e d . This includes DOT shipping name, hazard l a b e l and a completed hazardous waste l a b e l .

A l l r e q u i r e d EPA and DOT l a b e l s must be a p p l i e d t o the top o n e - t h i r d (1/3) of the container. The DOT shipping name and number should appea l e g i b l y on the top of the container.

Piacarding

The t r u c k used t o t r a n s p o r t hazardous m a t e r i a l s must be placarded. I n general, the plac a r d used on the t r u c k w i l l c o i n c i d e w i t h the hazard l a b e l on the drums being t r a n s p o r t e d .

M a t e r i a l Placard Flammable L i q u i d Flammable Flammable S o l i d Flammable Corrosive L i q u i d Corrosive Poison B Poison Mixed Loads Dangerous ORM-E None Required

I f you are unsure as to the plac a r d r e q u i r e d , contact the o f f i c e f i r s t .

storage

RCRA requ i r e s t h a t r e a c t i v e m a t e r i a l s be s t o r e d i n such a manner as to minimize the p o s s i b i l i t y of dangerous r e a c t i o n s o c c u r r i n g i n case of a leak or other accident. The storage area has taken t h i s requirement i n t o account duri n g the design phases.

A l l flammable and combustible wastes are s t o r e d i n a separate, s p e c i f i c a l l y designed area. No other area i s acceptable f o r the storage of these wastes.

A l l other wastes are s t o r e d f o r t r a n s p o r t to t h e i r u l t i m a t e disposal l o c a t i o n . The r o u t i n g supervisor or f a c i l i t y manager w i l l i n f o r m you as t o these s p e c i f i c l o c a t i o n s .

A l l waste t r a n s p o r t a t i o n v e h i c l e s should be parked i n the loading/unloading areas during non-working hours.

Empty Drum Handling

A l l l a b e l s on empty drums are e i t h e r to be removed or paint e d over such t h a t the name of the generator of the waste; the DOT hazard l a b e l and markings; as w e l l as the hazardous waste l a b e l are no longer d i s c e r n i b l e . Any l a b e l s which i n d i c a t e t h a t the drum once contained a hazardous waste must also be removed except i f the waste i s one l i s t e d i n paragraph "e" Part 261.33 ("P" Wastes).

A l l empty drums w i l l e i t h e r be crushed f o r reclamation or b u r i a l or they may be cleaned and reused dependent upon the previous contents.

An empty drum i s one which contains less than one inch of residue; or no more than 3% by weight of the t o t a l c apacity of a container having a volume of 110 ga l l o n s or less (0.3% f o r l a r g e r c o n t a i n e r s ) . Compressed gas c y l i n d e r s must be at atmospheric pressure t o bfe considered empty. Containers h o l d i n g a c u t e l y hazardous waste must have been t r i p l e d r i n s e d w i t h a s u i t a b l e solvent to be considered empty.

Basic Safety P o l i c i e s 1. A b s o l u t e l y no smoking i n the f a c i l i t y . 2. A l l employees/visitors are r e q u i r e d to wear eye p r o t e c t i o n . 3. A l l f1ammable/combustib1e drums must be s t o r e d i n the flammable

area. 4. Acid r e s i s t a n t c l o t h i n g must be worn v;hen handl i n g c o r r o s i v e

mat e r i a 1s. 5. Safety shoes are r e q u i r e d f o r any employees moving drums. 6. Gloves must be worn at a l l times when handling v/aste containers

(open or c1osed). 7. Spark proof t o o l s must be used on flammable v;aste containers,_ 8. A l l drums must remain p r o p e r l y sealed unless being sampled,

con s o l i d a t e d or t r e a t e d . 9. Forks on tow motor must be completely lov;ered when not i n use.

Only use drum haridler to move drums. 10. No food or d r i n k s p e r m i t t e d i n f a c i l i t y , 11. A l l employees must change from the work un i f o r m before l e a v i n g f o r

the day, 12. A l l designated a i s l e s and e x i t s must be kept c l e a r at a l l times. 13. Wear hardhats and/or s a f e t y glasses i n customer's p l a n t s as

r: e q u ;i r e d . Nearly a l l p 1 a n l; :i: r e q u i r e e y e p r o t. e c t i o n . 14. The main gate is to be closed at all times except for ingress i

egress of v e h i c l e s . The overhead doors can remain open during normal working hours.

15. No unescorted v i s i t o r s p e rmitted i n the f a c i l i t y .

-8-

D r i v e r I n f o r m a t i o n For S p i l l s Onto Roadways Contain s p i l l w i t h sorbent m a t e r i a l s . N o t i f y Universal Waste & T r a n s i t Emergency Response Coordinator (ERC)

Pamela Day @ 963-0177 or Sharon Roehm @ 864-2166

A l l s p i l l s i n v o l v i n g t r a n s p o r t a t i o n must be repo r t e d to the National Response Center. Universal Waste & T r a n s i t , ERC w i l l n o t i f y the National Response Center. I f ERC can not be contacted c a l l NRC at

1-800-424-8802 N o t i f y l o c a l a u t h o r i t i e s . For i n f o r m a t i o n on cleanup procedures, c a l l ChemTrec

1-800-424-9300 I f s p i l l r e s u l t s i n any of the f o l l o w i n g , the Department of T r a n s p o r t a t i o n must be n o t i f i e d at :1-202-426-1830

1. A person i s k i l l e d 2. A person i s h o s p i t a l i z e d 3. Property damage exceeds $50,000.00 4. Continuing danger e x i s t s f o r a f a c i l i t y or personnel

A l l s p i l l s of hazardous waste must be reported using the attached DOT i n c i d e n t r e p o r t form. ( E x h i b i t 2) Your d r i v e r s guide l i s t s the r e p o r t a b l e q u a n t i t i e s (RQ) t h a t must be reported to the National Response Center from the t o t a l number of containers i n v o l v e d .

T r a n s p o r t a t i o n Routes

Follow only c i t y / c o u n t y t r u c k routes d u r i n g a l l t r a n s p o r t whenever po s s i b l e . Only leave these roads f o r m a t e r i a l pickup. Use the most d i r e c t route to the generator when l e a v i n g a t r u c k route.

When le a v i n g the f a c i l i t y f o l l o w only t h i s t r u c k route i f p o s s i b l e : Orient Road to 1-4 or Orient Road t o Crosstown Expressway

Attempts should be made to l i m i t t r u c k access and egress to the f a c i l i t y t o normal working hours (7:00 a.m. to 5:00 p.m.).

•10-

f O R H A 2 A R D 0 U S W A S T E S R E L E A S E O R S P I L L S

EXHIBIT 2

DEPARTMENT OF TRANSPORTATION ro,m Approved 0MB Ho. Oi.SHJ

HAZARDOUS MATERIALS INCIDEMT REPORT h . . « O C T I O H S : S u b m i t l h i « r e p o r t i n d u p l i c a t e t o t h e S e c r e l e r y , H » i e r d o u s M a t e r i a l s R c E u l a l i o n s B o a r d , D e p a r t m e n t o f

f r a n s p o r l J l i o n , W a s h i n e l o n , D . C . 2 0 5 9 0 . ( A T T N : O p . D i v . ) . I f s p a c e p r o v i d e d f o r a n y i t e m i s i n a d e q u a t e , c o m p l e t e t h a t i t e m u n d e r S e c t i o n H , " R e m a r k s " , k e y i n g t o t h e e t s t r y n u m b e r b e i n g c o m p l e t e d . C o p i e s o f t h i s f o r m , i n l i m i t e d q u a n t i t i e s , m a y b e o b t a i n e d f r o m t h e S e c r e t a r y , H a z a r d o u s M a t e r i a l s R e g u l a t i o n s B o a r d . A d d i t i o n a l c o p i e s i n t h i s p r e s c r i b e d f o r r n a t m a y be r e p r o d u c e d a n d u s e d , i f o n t h e s a m e s i z e a n d k i n d o f p a p e r .

A I M C I D E H T I . T Y P E o r O P E R A T I O N F R E I G H T

I Q A I R 2 Q H I G H W A Y 3 Q B A I U 4 Q W A T E R S Q F O R W A R D E R 6 Q W A S T E

I . DATE AND TIME OF INCIDENT (Month - D»r - Y^mr)

p . m .

3 . L O C A T I O M O F I N C I D E N T

R E P O R T I N G C A R R I E R , C O M P A H Y OR I N D I V I D U A L 4 . F U L L N A M E

E P A I D E N T I F I C A T I O N C O D E N O .

5. ADDRESS (Numhar, 5(r»«(, City, Simlm mnd Zip Codm)

S. T Y P E O F V E H I C L E OR F A C I L I T Y

S H I P M E N T I N F O R M A T I O N

7. NAME AND ADDRESS OF SHIPPER (Origin mddrmim) 8. NAME AND ADDRESS OF CONSIGNEE (Dm mllnmlitfri 'mddrt m t )

9 . S H I P P I N G P A P E R I D E N T I F I C A T I O N N O . 1 0 . S H I P P I N G P A P E R S I S S U E D B Y

C A R R I E R I I S H I P P E R

[ 1 OTHER (IdmniUr)

D E A T H S , I N J U R I E S , L O S S A N D D A M A G E

D U E T O H A Z A R D O U S M A T E R I A L S I N V O L V E D

I I . N U M B E R P E R S O N S I N J U R E D 1 2 . N U M B E R P E R S O N S K I L L E D

1 « . E S T I M A T E D T O T A L Q U A N T I T Y O F H A Z A R D O U S M A T E R I A L S R E L E A S E D

13. ESTIMATED AMOUNT OF LOSS AND/OR PROPERTY DAMAGE INCLUDING COST OF DECONTAMINATION fRsunif o/r In dollmrm)

H A Z A R D O U S M A T E R I A L S I N V O L V E D

I S . C L A S S I F I C A T I O N ( S . e . 1 7 2 . ^ )

1 6 . SHI P P I N C N A M E ( S . e . 1 7 2 . 5 )

1 7 . T R A D E N A M E

N A T U R E O F P A C K A G I N G F A I L U R E

18. (Chmck mil mppltcmbim bonmt}

(1) D R O P P E D I N H A N D L I N G (2) E X T E R N A L P U N C T U R E (31 D A M A G E B Y O T H E R F R E I G H T

(41 W A T E R D A M A G E (5) D A M A G E F R O M O T H E R L I Q U I D (6) F R E E Z I N G

(7) E X T E R N A L H E A T (8) I N T E R N A L P R E S S U R E (91 C O R R O S I O N O R R U S T

MOI D E F E C T I V E F I T T I N G S , V A L V E S . OR C L O S U R E S

M l ) L O O S E F I T T I N G S , V A L V E S O R C L O S U R E S

(12 ) F A I L U R E O F I N N E R R E C E P T A C L E S

(131 B O T T O M F A I U U R E (14) B O D Y O R SI O E F A I L U R E ( 151 W E L D F A I L U R E

( 161 C H I M E F A I L U R E ( 17) OTHER CONDITIONS (Idmrttllf) 19. SPACE FOR DOT USE ONLY

F o r m D O T F 5 8 0 0 . 1 ( 1 0 - 7 0 )

92

CHAPTER SEVEN

LAND BAN CERTIFICATION

p.repared by


Orient Road

Tampa Florida

INSTRUCTIONS FOR CUSTOMER NOTIFICATION AND CERTIFICATION The Hazardous and S o l i d Waste Amendments of 1984 r e q u i r e r e s t r i c t i o n s

on land d i s p o s a l of un t r e a t e d hazardous wastes to be implemented i n several phases. The f i r s t phase, covering c e r t a i n s o l v e n t and d i o x i n wastes, was e f f e c t i v e November 8, 1986. The sevond phase ( c o v e r r i n g " C a l i f o r n i a L i s t " wastes) was e f f e c t i v e J u l y 8, 1987. There are very-l i m i t e d variances from these r e s t r i c t i o n s , and a d d i t i o n a l wastes w i l l be covered i n f u t u r e phases. For your convenience, a l i s t of r e s t r i c t e d wastes and a p p l i c a b l e variances i s attached. Complete r e g u l a t i o n s concerning land ban r e s t r i c t i o n s are published by the Environmental P r o t e c t i o n Agency i n 40 CFR, Part 268.

I n order t o comply w i t h f e d e r a l and s t a t e requirements you must si g n a statement ( e i t h e r a n o t i f i c a t i o n or a c e r t i f i c a t i o n ) f o r each waste stream you ship. A copy of t h i s statement of the waste, except f o r the u n r e s t r i c t e d waste n o t i f i c a t i o n .

Determine which statement below a p p l i e s to your waste and mark the app r o p r i a t e corresponding n o t i f i c a t i o n or c e r t i f i c a t i o n on the reverse tide of t h i s form. U n r e s t r i c t e d Waste N o t i f i c a t i o n

I f you generate a hazardous waste which i s not a s o l v e n t , d i o x i n , or " C a l i f o r n i a L i s t " waste which i s r e s t r i c t e d from land d i s p o s a l w i t h o u t p r i o r treatment (by a p p r o p r i a t e treatment standard described i n 40 CFR 268 Subpart D, or t o the l e v e l s s p e c i f i e d i n 40 CFR 268.32), mark t h i s space and l i s t a p p r o p r i a t e treatment" standard. R e s t r i c t e d Waste Variance C e r t i f i c a t i o n

I f you generate a sol v e n t (F001-F005), d i o x i n , or " C a l i f o r n i a L i s t " waste which does not r e q u i r e treatment p r i o r to land d i s p o s a l becouse of a variance ( i n c l u d i n g case-by-case extencion under 40 CFR 268.5, nationwide variance under 40 CFR 268 Subpart C,. a no-migration p e t i t i o n under 40 CFR 268.6, or s o i l or d e b r i s from a CERCLA response a c t i o n or RCRA c o r r e c t i v e a c t i o n ) , mark t h i s space and l i s t the a p p r o p r i a t e variance. Treated Waste C e r t i f i c a t i o n

I f you t r e a t a s o l v e n t (F001-F005), d i o x i n , or " C a l i f o r n i a L i s t " waste t o the degree i t i s no longer s u b j e c t t o land d i s p o s a l r e s t r i c t i o n s ( e i t h e r the perfomance standards described i n 40 CFR 268 Subpart D of the a p p l i c a b l e l e v e l s described i n 40 CFR 268.32), mark t h i s space. Mark t h i s kspace whether you are the o r i g i n a l generator t r e a t i n g the waste of a 'treatment f a c i l i t y o p e rator. You must also a t t a c h a n a l y t i c a l documentation t h a t demonstrates r e q u i r e d treatment has been achieved, and a copy of the o r i g i n a l g e n e r a t o r ( s ) n o t i f i c a t i o n which was sent to you w i t h the waste. ONLY STATEMENTS WITH ORIGINAL SIGNATURES WILL BE ACCEPTED!

CUSTOMER NOTIFICATION AND CERTIFICATION Generator Name/Location:. EPA ID Number: Waste P r o f i l e or ARF Number; Manifest Nmuber: EPA Hazardous Waste Number(s):( ) ( ) ( ) Waste Analysis A v a i l a b l e ? Yes No I f yes, please a t t a c h copy.

U n r e s t r i c t e d Waste N o t i f i c a t i o n I n o t i f y t h a t I p e r s o n a l l y have examined and am f a m i l i a r w i t h the waste through a n a l y s i s and t e s t i n g or through knowledge of the waste to support t h i s n o t i f i c a t i o n t h a t the waste i s not r e s t r i c t e d as s p e c i f i e d i n 40 CFR 268, Subpart D and a l l a p p l i c a b l e p r o h i b i t i o n s set f o r t h i n 40 CFR 268.32 or RCRA Section 3004(d).

R e s t r i c t e d Waste Variance C e r t i f i c a t i o n I c e r t i f y under pe n a l t y of law t h a t I p e r s o n a l l y have examined and am f a m i l i a r w i t h the waste through a n a l y s i s and t e s t i n g or through knowledge >f the waste t o support t h i s c e r t i f i c a t i o n t h a t the waste complies w i t h ^he treatment standards s p e c i f i e d i n 40 CFR Part 268, Subpart D and a l l p p l i c a b l e p r o h i b i t i o n s set f o r t h i n 40 CFR 268.32 or RCRA Section

3004(d). I b e l i e v e t h a t the i n f o r m a t i o n I submitted i s t r u e , accurate, and complete. I am aware t h a t there are s i g n i f i c a n t p e n a l t i e s s f o r s u b m i t t i n g a f a l s e c e r t i f i c a t i o n , i n c l u d i n g the p o s s i b i l i t y of a f i n e and imprisonment. A p p l i c a b l e Variance:

Treated Waste C e r t i f i c a t i o n I c e r t i f y under pe n a l t y of law t h a t I have p e r s o n a l l y examined and am f a m i l i a r w i t h the treatment technology and o p e r a t i o n of the treatment process used t o support t h i s c e r t i f i c a t i o n and t h a t , based on my i n q u i r y of those i n d i v i d u a l s immediately r e s p o n s i b l e f o r o b t a i n i n g t h i s i n f o r m a t i o n , I b e l i e v e t h a t the treatment process has been operated and maintained p r o p e r l y so as to comply w i t h the performance l e v e l s s p e c i f i e d i n 40 CFR Part 268, Subpart D and a l l a p p l i c a b l e p r o h i b i t i o n s set f o r t h i n 40 CFR 268,32 or RCRA Section 3004(d) w i t h o u t d i l u t i o n of the p r o h i b i t e d waste. I am aware t h a t there are s i g n i f i c a n t p e n a l t i e s f o r s u b m i t t i n g a f a l s e c e r t i f i c a t i o n , i n c l u d i n g the p o s s i b i l i t y of f i n e and imprisonment.

SIGNATURE : DATE : PRINT NAME: TITLE: ONLY STATEMENTS WITH ORIGINAL SIGNATURES WILL BE ACCEPTED!

SOLVENT WASTES FOOl The f o l l o w i n g spent halogentated s o l v e n t s used i n degreasing

t e t r a c h l o r o e t h y l e n e , t r i c h l o r o e t h y l e n e , methylene c h l o r i d e , 1 , 1 , 1 - t r i c h l o r o e t h a n e , carbon t e t r a c h l o r i d e , and c h l o r i n a t e d f l u o r o c a r b o n s ; a l l spent s o l v e n t mixtures/blends used i n degreasing c o n t a i n i n g , before use, a t o t a l of ten percent or more (by volume) or one or more of the above halogenated solvents or those solvents l i s t e d i n F002, F004, F005 and s t i l l bottoms from the rec o v e r r y of these spent s o l v e n t and spent solvent m i x t u r e s .

F002 The f o l l o w i n g spent halogenated s o l v e n t s : t e t r a c h l o r o e t h y l e n e , methylene c h l o r i d e , 1 , 1 , 1 - t r i c h l o r o e t h a n e ; chlorobenzene, 1 , 1 , 2 - t r i c h l o r o - l , 2, 2 - t r i f l u o r o e t h a n e , ortho-dichlorobenzene, and t r i c h l o r o f l u o r o m e t h a n e ; a l l spent s o l v e n t mixtures/blends used i n degreasing c o n t a i n i n g , before use, a t o t a l of ten percent or more (by volume) of one or more of the above halogenated solvents or those solvents l i s t e d i n FOOl, F004, and F005; and s t i l l bottoms from the r e c o v e r r y of these spent solvents and spent solvent m i x t u r e s .

F003 The f o l l o w i n g spent non-halogenated s o l v e n t s : xylene, acetone, e t h y l a c e tate, e t h y l benzene, e t h y l e ther, methyl i s o b u t y l ketone, cyclohexanone, and methanol; a l l spent solvent mixtures/blends c o n t a i n i n g , before use, only the above spent non-halogenated s o l v e n t s , and a t o t a l of ten percent or more (by volume) of one or more of those solvents l i s t e d i n FOOl, F002, F004, and F005; and s t i l l bottoms from the recovery of these spent s o l v e n t s and spent s o l v e n t m i x t u r e s .

F004 The f o l l o w i n g spent non-halogenated s o l v e n t s : c r e s o l s , and c r e y s y l i c a c i d , and nitrobenzene; a l l spent s o l v e n t mixtures blends c o n t a i n i n g , before use, a t o t a l of ten percent or more (by volume) of one or more of the above non-halogenated solvents or those solvents l i s t e d i n FOOl, F002, and F005; and s t i l l bottoms from the recovery of these spent s o l v e n t s and spent so l v e n t m i x t u r e s .

F005 The f o l l o w i n g spent non-halogenated s o l v e n t s : toluene, methyl e t h y l ketone, carbon d i s u l f i d e , i s o b u t a n o l , p y r i d i n e , benzene, 2-ethoxyethanol, and 2-nitropropane; a l l spent s o l v e n t mixtures/blends c o n t a i n i n g , before use, a t o t a l of ten percent or more (by volume) of one or more of the above non-halogenated solvents or those solvents l i s t e d i n FOOl, F002, and F004; and s t i l l bottoms from the recovery of these spent solvents and spent s o l v e n t m i x t u r e s .

SOLVENT WASTES APPLICABLE VARIANCES (A) The m a t e r i a l i s an i n o r g a n i c s o l i d c o n t a i n i n g 1% or less F001-F005

so l v e n t . (B) The m a t e r i a l contains a blend of F001-F005 (TOTAL) so l v e n t s at

concentrations of less tha 10% p r i o r t o use. '(C) The m a t e r i a l i s pure, un-used P or U - l i s t e d s o l v e n t s . (D) The m a t e r i a l i s waste water w i t h less than 1% t o t a l F001-F005 l i s t e d

s o l v e n t s . (E) Other.

DIOXIN WASTES F020 Wastes (except waste water and spent carbon from the p r o d u c t i o n

or manufacturing use (as a r e a c t a n t , chemical i n t e r m e d i a t e , or compnent i n a f o r m u l a t i n g process) of t r i - or t e t r a c h l o r o p h e n a l , or of i n t e r m e d i a t e s used t o produce t h e i r p e s t i c i d e d e r i v a t i v e s . (This l i s t i n g does not i n c l u d e wastes from the p r o d u c t i o n of lexachlorophena from h i g h l y p u r i f i e d 2 , 4 , 5 - t r i - c h l o r o p h e n o l . )

F021 Wastes (except waste water and spent carbon from hydrogen c h l o r i d e p u r i f i c a t i o n ) from the p r o d u c t i o n or manufacturing use (as a r e a c t a n t , chemical i n t e r m e d i a t e , or compnent i n a f o r m u l a t i n g process) of pentachlorophenol, or of i n t e r m e d i a t e s used t o product i t s d e r i v a t i v e s .

F022 Wastes (except waste water and spent carbon from hydrogen c h l o r i d e p u r i f i c a t i o n ) from the manufacturing used i n t e r m e d i a t e , or component i n a f o r m u l a t i n g process) of t e t r a - , penta-, or hexachlorobenzenes under a l k a l i n e c o n d i t i o n s .

F023 Wastes (except waste water and spent carbon from hydrogen c h l o r i d e p u r i f i c a t i o n ) from the p r o d u c t i o n of m a t e r i a l s on equipment p r e v i o u s l y used f o r the p r o d u c t i o n or manufacturing use (as a r e a c t a n t , chemical i n t e r m e d i a t e , or component i n a f o r m u l a t i n g process) of t r i - and t e t r a c h l o r o p h e n o l s . (This l i s t i n g does not i n c l u d e wastes from equipment used only f o r the p r o d u c t i o n or use of Hexachlorophene from h i g h l y p u r i f i e d 2 , 4 , 5 - t r i c h l o r o p h e n o l . )

F026 Wastes (except waste water and spent carbon from hydrogen , c h l o r i d e p u r i f i c a t i o n ) from the p r o d u c t i o n of m a t e r i a l s on

equipment p r e v i o u s l y used f o r the manufacturing use (as a r e a c t a n t , chemical i n t e r m e d i a t e , or component i n a f o r m u l a t i n g process) of t e t r a - , penta-, or hexachlorobenzene under a l k a l i n e c o n d i t i o n s .

F027 Discarded unused formulatons c o n t a i n i n g t r i - , t e t r a - or pentachlorophenol or discarded unused f o r m u l a t i o n c o n t a i n i n g compounds d e r i v e d from these chlorophenols. (This l i s t i n g does not i n c l u d e f o r m u l a t i o n s c o n t a i n i n g hexachlorophene synthesized from p r e - p u r i f i e d 2 , 4 , 5 - t r i c h l o r o p h e n o l as the sole component.)

"CALIFORNIA LIST" WASTES L i q u i d hazardous wastes, i n c l u d i n g f r e e l i q u i d s associated w i t h any s o l i d or sludge, c o n t a i n i n g f r e e cyanides a t co n c e n t r a t i o n s g r e a t e r than or equal t o 1,000 mg/1. L i q u i d hazardous wastes, i n c l u d i n g f r e e l i q u i d s associated w i t h any s o l i d or sludge, c o n t a i n i n g the f o l l o w i n g metals (or elements) or compounds of these metals (or elements) at con c e n t r a t i o n s g r e a t e r than or equal t o those s p e c e i f i e d below:

arsenic and/or compounds (as As) 500 mg/1 cadmium and/or compounds (as Cd) 100 mg/1 chromium (VI and/or compounds [as Cr V I ] ) 500 mg/1 lead and/or compounds (as Pb) 500 mg/1 mercury and/or compounds (as Hg) 20 mg/1 n i c k e l and/or compounds (as Ni) 134 mg/1 selenium and/or compounds (as Se) 100 mg/1 t h a l l i u m and/or compounds (as T i ) 130 mg/1

Note: These m a t e r i a l s must be RCRA Regulated Wastes f o r the • r e s t r i c t i o n s t o apply. M a t e r i a l s which c o n t a i n selenium or t h a l l i u m , out which are not RCRA wastes are not a f f e c t e d by the d i s p o s a l r e s t r i c t i o n s . L i q u i d hazardous waste having a pH less than or equal to two (2.0) . L i q u i d hazardous waste c o n t a i n i n g p o l y c h l o r i n a t e d biphenyls at conc e n t r a t i o n s g r e a t e r than or equal t o 50 ppm.

' Hazardous wastes c o n t a i n i n g halogenated organic compounds i n t o t a l c o n c e n t r a t i o n g r e a t e r than or equal t o 1,000 mg/kg.

"CALIFORNIA L1ST" APPLICABLE VARIANCES (A) L i q u i d hazardous wastes t h a t c o n t a i n HOCs i n t o t a l c o n c e n t r a t i o n

g r e a t e r than or equal t o 1,000 mg/1 but are not waste waters. (B) N o n - l i q u i d hazardous wastes c o n t a i n i n g HOCs i n t o t a l c o n c e n t r a t i o n s

g r e a t e r than or equal t o 1,000 mg/1. (C) S o i l or d e b r i s generated from a CERCLA response a c t i o n or a

c o r r e c t i v e a c t i o n taken under Sections 3004 or 3008 or RCRA. (D) Case-by-case extension. (E) No-migration p e t i t i o n .

CUSTOMER NOTIFICATION AND CERTIFICATION Generator Name/Location:

EPA ID Number; -

Waste Profile

Manifest Number:

EPA Hazardous Waste Number(s): ( ) (_

Waste Analysis Available? Yes No If yes, please attach copy.

Unrestricted Waste Notification (Category I) I notify that 1 personally have examined and am familiar with the waste through analysis and testing or through knowledge

of the waste to support this notification that the waste is not restricted as specified in 40 CFR 268, Subpart D and all applicable prohibitions set forth in 40 CFR 268.32 or RCRA Section 3004(d).

Restricted Waste Notification (Category 2) I notify that I personally have examined and am familiar with the waste through analysis and testing or through knowledge

of the waste to support this notification that the waste does not comply with the treatment standards specified in 40 CFR 268, Subpart D and all applicable prohibitions setforth in 40 CFR 268.32 or RCRA Section 3004(d). Therefore, the waste must be treated by the appropriate regulatory treatment standard or in such a manner which renders it non-liquid by chemical fixation or solidification prior to land disposal.

Corresponding Treatment Standard: Restricted Waste Variance Certification/Notification (Category 3) I notify pursuant to 40 CFR 268.7(a)(3) and certify under penahy of law that 1 personally have examined and am familiar

with the waste through analysis and testing or through knowledge of the waste to support this certification that the waste complies with the treatment standards specified in 40 CFR Part 268, Subpart D and all applicable prohibitions set forth in 40 CFR 268.32 or RCRA Section 3004(d). I believe that the information I submitted is true, accurate, and complete. 1 am aware that there are significant penalties for submitting a false certification, including the possibility of a fine and imprisonment.

Applicable Variance: Treated Waste Certification (Category 4)

• I certify under penalty of law that I have personally examined and am familiar with the treatment technology and operation of the treatment process used to support this certification and that, based on my inquiry of those individuals immediately responsible for obtaining this information, I believe that the treatment process has been operated and maintained properly so as to comply with the performance levels specified in 40 CFR Part 268, Subpart D and all applicable prohibitions set forth in 40 CFR 268.32 or RCRA Section 3004(d) without dilution of the prohibited waste. I am aware that there are significant penalties for submitting a false certification, including the possibility of fine and imprisonment.

Soft Hammer Waste Certification (Category 5) —(5A) I certify under penalty of law that the requirements of 40 CFR 268.8(a)(1) have been met and that disposal in a landfill

or surface impoundment is the only practical alternative to treatment currently available. 1 believe that the information submitted is true, accurate, and complete. I am aware that there are significant penalities for submitting false information, including the possibility of fine or imprisonment.

—(5B) I certify under penalty of law that the requirements of 40 CFR 268.8(a)(1) have been met and that I have contracted to treat my waste (or will otherwise provide treatment) by the practically available technology which yields the greatest environmental benefit, as indicated in my demonstration. I believe that the information submitted is true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.

—(5C) I certify under penalty of law that I have personally examined and am familiar with the treament technology and operation of the treatment process used to support this certification and that, based on my inquiry of those individuals immediately responsible for obtaining this information, I believe that the treatment process has been operated and maintained properly so as to comply with treatment as specified in the generator's demonstration. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.

SIGNATURE: DATE:

PRINT NAME: TITLE: .

ONLY STATEMENTS WITH ORIGINAL SIGNATURES WILL BE ACCEPTED!

September 23. 1988

Sheet 1 of . Sheets

Generator Name/Location:

EPA ID Number: Manifest Number:

Drum Number, Waste Profile

Category No. Slate EPA

Waste Number(s) Corresponding Treatment Standard/

Applicable Variance/Other Information

SIGNATURE:

PRINT NAME: ONLY ORIGINAL SIGNATURES WILL BE ACCEPTED!

DATE:

TITLE: September l i . 1988

• For Treatment Standards Expressed as Concentration, Please Enter the Legend Number from the Legend Below for the Constituents contained in the Waste.

LEGEND FOR TREATMENT STANDARDS EXPRESSED AS CONCENTRATION TABLE CCWE-CONSTITUENTS IN WASTE EXTRACT

F C O I - F 0 0 5 s p t n l so lvents

C o n c e n t r a t i o n <ln m g / 1 ) W a s t e w a y s A t ! o l t i c r C o n t a i n i n g Spent

. Spent S o l v e n t So lven ts Wastes

r-020-F02.1 a n d F026-F028 d i o x i n C o n t a i n i n g Was te L e g e n d * C o n s t i t u e n t N a m e

27 H x C C D - A l t H e x a c l i l o r o d i b e n i o - p - d i o x i n s 28 H x C D F - A l l H e x a c h l o r o d i b e n i o f urans 29 P e C d d - A l l P e n t a c h l o r o d i b e n z o - p - d l o x l n s . . 30 P e C D F - A I I P e n l a c h l o r o d i b e n z o r u r a n s 3 t T C D D - A l t T e t r a c l i t o r o d i b e n r o - p - d l o x i n s . . 32 T C D F - A l l T e t r a c h l o r o d i b e n z o r u r a n s 33 2 . 4 . 3 - T r i c h l o r o p t i e n o t 34 2 . 4 . 6 - T r i c t i I o r o p h e n o t . . 35 2 . 3 . 4 . 6 - T e t r a c h l o r o p h e n o l 36 P e n t a c h t o r o p i i e n o !

(Continued on following pages)

C o n c e n t r a t i o n L e g e n d

1 2 3 4 5 6 7 8 9

10 t I 12

J 3

)t 16 17 18 19 20 21 22 23

24 25 26

# C o n s t i t u e n t N a m e A c e t o n e 0.03 n - B u t y l a l c o h o l 5.0 C a r b o n d i s u l f i d e 1.05 C a r b o n t e t r a c t i l o r i d e .05 c h l o r o b e n z e n e .15 Cresols ( a n d c resy l ic ac id ) 2 .82 C y c l o h e x a n o n e .125 1 .2-d ich torobenzene .65 E t h y l acetate .05 E t h y l e benezenc .05 E t h y l ether .05 I s o b u t a n o l — 5.0 M e t h a n o l .25 M e t h y l e n e c h l o r i d e .20 M e t h y l e n e c h l o r i d e ( f r o m the p h a r m a c e u t i c a l I n d u s t r y ) 12.7 M e t h y l e t h y l ke tone 0.05 M e t h y l i s o b u t y l k e t o n e 0.05 N i t r o b e n z e n e 0 .66 P y n d i n e 1.12 T e t r a c h l o r o e t h y l e n e 0.079 T o l u e n e 1.12 l . J . J - T r i c h l o r o e t h a n e 1.05 1 . 2 . 2 - r l c h l o r o - l . 2 .2 -t r i r i u r o e t h a n e 1.05 T r i c h l o r o e t h y l e n e 0 .062 T r l c h l o r o f t u o T o m e t h a n e 0.05 X y l e n e 0.05

0.59 5.0 4 .81

.96

.05

.75

.75

.125

.75

.053

.75 5.0

.75

.96

.96 0.75 0.33 0.125 0.33 0.05 0.33 0.41

0.96 0.091 0 .96 0.15

I p p b 1 p p b I ppb I ppb 1 ppb I ppb

0.05 p p m 0.05 p p m 0.10 p p m 0.01 p p n i

Subpart D—Treatment Standards (continued) 9. In § 268.41 (a) in the F001-F005

spent solvents table. Methylene chloride (from the pharmaceutical industry) and its corresponding concentrations is removed, and the following subtables are added to read as follows; § 268.41—Treatment standards expressed as concent ration.s in waste extract, (a)* * *

TABLE CCWE.—CONSTITUENT CONCENTRATIONS IN WASTE EXTRACTF 37

43

F006 nonwaslewaiers (see also Table CCW in §268:43)

Concentration (in mg/1)

0.066 5.2

.51

.32

.072 Reserved

Chromium (Total) 0.066 5.2

.51

.32

.072 Reserved

Lead

0.066 5.2

.51

.32

.072 Reserved

Nickel

0.066 5.2

.51

.32

.072 Reserved

Silver

0.066 5.2

.51

.32

.072 Reserved Cyanides (Total)

0.066 5.2

.51

.32

.072 Reserved

0.066 5.2

.51

.32

.072 Reserved

38 KOOI nonwasiewaters (see also

Table in § 268.43) Concentra

tion (in mg/1)

Lead 0.51 0.51

39 K022 nonwaslewaiers (see also Table

CCW in § 268.43) Concentra

tion (in mg/I)

5.2 0.32 Nickel 5.2 0.32 5.2 0.32

40 , K046 nonwaslewaters (Nonteaclive

Subcategory) Concentra

tion (in mg/1)

Lead 0.18 0.18

41 K048, K049, K050. K05I and K052

nonwaslewaters (see also Table CCW in § 268.43


Arsenic 0.004 1.7 .048 .025

Chromium (Tola!) 0.004 1.7 .048 .025

Nickel

0.004 1.7 .048 .025 Selenium

0.004 1.7 .048 .025

0.004 1.7 .048 .025

42 K06I nonwaslewaiers (Low Zinc

Subcategory—less than 15% total zinc) Concentra

tion (In mg/1)

Cadmium 0.14 5.2

.24

.32

Chromium (Total 0.14 5.2

.24

.32 Lead

0.14 5.2

.24

.32 Nickel

0.14 5.2

.24

.32

0.14 5.2

.24

.32

K06I nonwaslewaters (High Zinc Subcategory—151'> or greater total

zinc): effective until 8/8/90


0.14 5.2 .24 .32

0.14 5.2 .24 .32

Lead

0.14 5.2 .24 .32 Nickel

0.14 5.2 .24 .32

0.14 5.2 .24 .32

44

K062 nonwaslewaiers Concentra

tion (in mg/1)

0.094 0.37 Lead 0.094 0.37 0.094 0.37

45

K07I nonwaslewaters Concentra

tion (in mg/1)

0.025 0.025

46 K086 nonwaslewaters (Solvent

Washes Subcategory) see also Table CCW in § 268.43

Concenlra-lion (in mg/1)

Chromium (Total) 0.094 .37 Lead

0.094 .37

0.094 .37

47 K087 nonwaslewaiers (see also Table

CCW in § 268.43) Concentra

tion (in mg/1)

Lead 0.51 0.51

48 KIOl and KI02 nonwaslewaters (Low

Arsenic Subcategory—less than l i t Total Arsenic) (set also Table CCW in § 268.43)


Cadmium 0.066 5.2 .51 .32

Chromium (Total) 0.066 5.2 .51 .32

Lead

0.066 5.2 .51 .32 Nickel

0.066 5.2 .51 .32

0.066 5.2 .51 .32

§ 268.42 Treatment - standards expressed as specified technologies,

( a ) * * •

(2) Nonliquid hazardous wastes containing halogenated organic compounds (HOCs) in total concentration greater than or equal to 1,000 mg/kg and liquid HOC-containing wastes that are prohibited under § 268.32(e)()) of this part must be incinerated in accordance with the requirements of Part 264 Subpart 0 or Part 265 Subpart 0, or in boilers or industrial furnaces burning in accordance with applicable regulatory standards. These treatment standards do not apply where the waste is subject to a Part 268 Subpart C treatment standard for a specific HOC (such as a hazardous waste chlorinated solvent for which a treatment standard is established under § 268.41(a). § 268.43 - Treatment standards expressed as waste concentrations.

(a) Table CCW identifies the restric-ed wastes and the concentrations of their associated hazardous constituents which may not be exceeded by the waste or treatment residual (not an extract of such waste or residual) for the allowable land disposal of such waste or residual.

TABLE CCW—CONSTITUENT CONCENTRATIONS IN WASTES

49 FOOl, F002, F003, F004 and F005

wastewaters (Pharmaceutical Industry)

Methylene chloride..

Conccnira-lion (in mg/1)

0.44

50 F006 nonwaslewaters (see also Table

CCWE in § 268.41)

Cyanides (Total)..

Concentration (in mg/kg)

Reserved

51 KOOI nonwaslewaiers (see also Table

CCWE in 5 268.41)

Naphthalene Pentachlorophenol Phenanthrene Pyrene Toluene Xylenes


8.0 37 1.0 7.3 .14 .16

52

KOOI wastewaters

Naphthalene Pentachlorophenol Phenanihrcnc Pyrene Toluene Xylenes Lead

§ 268.43 Treatment Standards fxpressed as Waste Concentrations Continued)

53 Concentra

KOISwastewaleri tion (in mg/1)

1.0 .28

Benio (b and/or k) (luoranthene .29 Phenanthrene .27

.15 Chromium (Total) .32 Nickel .44 .44

54 Concentra

K0I6 nonwaslewaiers tion (in mg/kg)

28 Hexachlorobutadiene 5.6 Heiachlorocyclopentadiene 5.6 Hexachloroelhane 28 Telrachloroethene 6.0

55 Concentra

K0I6 wastewaters tion (in mg/1)

HtxachlOTobeniene Hexachlorobutadiene Hexachlorocyclopentadiene. Hexachloroethane

ittachloroethene

0.033 .007 .007 .033 .007

ConcentraK0I8 nonwaslewaters tion (in mg/kg)

6.0 1,1-Dichloroethane 6.0

6.0 28

Hexachlorobutadiene 5.6 Hexachloroethane 28

5.6 l.l,l-TiicMoro«th«n« 6.0

57 Concentra

K0I8 wastewaters tion (in mg/1)

0.007 .007

1,1-Dichloroethane .007 .007

Hexachlorobenzene .033 Hexachlorobutadiene .007

.007 1,1,1-Trichlorothane .007

58 Concentra

K0I9 nonwaslewaters tion (in mg/kg)

:2<hloroethyl)etha. lorobeniene

Jotoform 1,2-Dichloroethane Hexachloroethane Naphthalene Phenanthrene Tettachloroelhene 1,2.4-Trlchloroben/ene 1.1.1-Trichloroethane..

5.6 6.0 6.0 6.0

28 5.6 5.6 6.0

19 6.0

59

K0I9 wastewaters

Bis(2-<hloroelhyl)ether Chlorobenzene Chloroform p-Dichiorobenzene 1,2-Dichloroelhane Ruorene. Hexachloroelhane Naphthalene Phenanthrene 1,2,4.5-Telrachlorobenzene Telrachloroethene 1,2,4-Trichlorobenzene 1,1,1-Trichloroclhane

60

K020 nonwaslewaters

61

K020 wastewaters

62

K022 nonwaslewaters (see also Table CCWE in § 268.41)

63

K024 nonwaslewaters

Phthalic acid..

64

K024 wastewaters

Phthalic acid..

65

K030 nonwaslewaters


0.007 ,006 .007 .008 .007 .007 .033 .007 .007 .017 .007 .023 .007

1,2-Dichloroethane 1,1,2,2-Telrachloroethane Telrachloroethene


6.0 5.6 6.0

1,2-Dichloroethane l,l,2.2-Tetrachloroelhane, Telrachloroethene


0.007 .007 .007

Acetophenone Sum of Diphenylamine and Diphenyl-

nitrosamine Phenol Toluene

Concentration (in mg/

kg)

19

13 12 0.034

Concentration in mg/

kg)

28

Hexachlorobutadiene Hexachlorethane Hexachloropiopcne Pentachlorobenzene Pentachloroethane 1,2,4,5-Telrachlotobenzene Tetrachlorothene 1,2,4-Trichlorobcnzene


I)

0.54


kg)

5.6 28 19 28 5.6

14 6.0

19

66

K030 nonwaslewaiers

o-Dichlorobenzene p-Pichlorobenzene Hexachlorobutadiene Hexachloroelhane Pentachloroethane 1,2.4,5-Tetrachlorobenzene. Tetrachloroelhene 1,2.4-Trichlorobenzenc

67 K037 nonwaslewaters

Disulfoton.. Toluene

68

K037 wasiewaiers

Disulfoton.. Toluene

69


70

K048 wasiewaiers


I)

0 DOR ,008 ,007 033 ,001 ,017 ,007 ,023

Concenlra-lion (in mg/

kg)

0,1 28

Conccntra-lion (in mg/

1)

0,003 ,028

Benzene Benzo(a)pyrene Bis(2-eihylhexyl)phthalate Chrysene Di-n-butyl phthalate Ethylbenzene Naphthalene Phenanthrene Phenol Pyrene Toluene Xylenes Cyanides frolal)


kg)

9.5 .84

37 2.2 4.2

67 (Reserved)

7,7 2,7 20 9,5

IReservedl 1,8

Benzene Benzo(a)pytene Bis(2-tthylhexyl)phthalate Chrysene Di-n-bulyl phthalate Ethylbenzene Fluorene Naphthalene Phenanthrene Phenol Pyrene Toluene Xylenes Chromium (Total) Lead


I)

0.011 .{M7 .013 .043 .060 .Oil .050 .033 ,039 ,047 .045 ,011 .011 ,20

0,37

§ 268.43 Treatment Standards Expressed as Waste Concentrations Continued) 1

76 80

K049 nonwaslewaters (see also Table CCWE in § 268,41)

Anthracene Benzene Benio(«)pyrene Bis(2-elhylheiyl)phihalaie. Chrysene Ethylbenzene Naphthalane Phenanthrene Phenol Pyrene Toluene Xylenes (Cyanides (Total)

72

K049 wastewaters

Anthracene Benzene Benzo(a)pyrene Bis(2-ethylhexyl)phlha)ale.. Carbon disulfide Chrysene 2,4-Dimclhylphenol Ethylbenzene

phthalene lenanthrene

K049 wastewaleti

74

K050 nonwaslewaters (see also Table CCWE in § 268.41

75

K050 wastewaters


kg)

6,2 9,5 0,64

37 2,2

67 (Reserved) 7,7 2,7 2.0 9,5

(Reserved) 1.8

Phenol Pyrene !..., Toluene Xylenes Chromium (Total), Lead

Concentration (in mgV

1)

0.039 Oil .047 .043 .011 .043 .033 .Oil .033 .059


I)

,047 .045 .Oil Oil .20 .037

Benzo(a)pyTene.. Phenol Cyanides (Total).


k j )

0.S4 2.7 1.8

Bcnzo(a)pyrene Phenol Chromium (Total)

id


I)

0,047 .047 .20 .037


Anthracene Benzene Benzo(a)anthracene Benzo(s)pyrene Bis(2-ethylhexyl)phthalale, Chrysene Di-n-bulyl phthalate Ethylbenzene Naphthalene Phenanthrene Phenol Pyrene Toluene Xylenes Cyanides (Total)

77

K05I wastewaters

78

K052 nonwaslewaiers (see also Table CCWE in § 268,41)

79

K052 wastewaters

Concentration in mg/

kg)

6.2 9.5 1,4 .84

37 2,2 4.2

67 (Reserved) 7,7 2.7 2,0 9.5

(Reserved) 1.8

Acenaphthene Anthracene Benzene Benzo(a)anlhracene Benzo(a)pyrene Bis(2-elhylhexyl) phthalate, Chrysene Di-n-bulyl phthalate Ethylbenzene Flourene Naphthalene Phenanthrene Phenol Pyrene Toluene Xylenes Chromium (Total) Lead

Concenira-lion (in mg/

I)

0.050 .039 .Oil .043 .047 .043 .043 .060 .Oil .050 .033 .039 .047 .045 .011 .011 .20 .037

Benzene. Bcnzo(a)pyrene.. 0-Cresol p-Cresol Ethylbenzene Naphthalene Phenanthrene Phenol Toluene Xylenes Cyanides (Total).

Concentration (in mg/)

kg)

9,5 0.84 2.2 0,90

67 (Reserved) 7.7 2.7 9.5

(Reserved) 1.8

Benzene Ben70(a)pyrene o-Cresol p-CresoI 2,4-Dimelhylphenol Ethylbenzene Naphthalene Phenanthrene Phenol Toluene Xylenes Chromium (Total), Lead


I)

0,011 .047 .011 .011 .033 .011 .033 .039 .047 .01! .011 ,20 .037

K062 wastewaters

Chromium (Total), Lead Nickel


1)

0,32 .04 .44

K086 nonwaslewaters—Solvent Washes Subcategory (see also Table

CCWE in § 268,41)

Acetone Bis(2-elhylhexyl) phthalate. n-Butyl alcohol Cyclohexanone l,2-Dichloroben;ene Ethyl acetate Ethyl benzene Methanol Methylene chloride Methyl ethyl ketone Methyl isobulyl ketone Naphthalene Nitrobenzene Toluene 1,1,1,-Trichloroethane Trichloroethylene Xylenes

83

K036 wasiewaiers—Solvent Washes Subcategory

Acetone bis(2-elhylhexyl)phthalale..

84

K086 wastewaters-Solvent Washes Subcategory


kg)

0,37 ,49 ,37 ,49 ,49 .37 .031 .37 .037 .37 .37 .49 .49 ,031 .tV44 .031 .015


I)

0,015 .044

n-Butyl alcohol Cyclohexanene 1.2-Dichlorobenzene Ethyl acetate Ethyl benzene Methanol Methylene chloride Methyl ethyl ketone Methyl isobutyl ketone. Naphthalene Nitrobenzene Toluene I,I,I,-Trichloroethane.. Trichloroethylene Xylenes Chromium flotsl) Lead


I)

.031

.022

.044

.031 ,015 ,031 .031 .031 .031 ,044 .044 ,029 ,031 ,029 ,015 ,32 .037

4: 268.43 Treatment Standards pressed as Waste Concentrations

Continued) 85

90 95

K0S7 nonwaslewaleis (see also Table CCWE in § 268.41)

Acenaphihalene Benzene Chrysene Fluoranlhene Indeno (1,2,3-cd) pyrene. Naphthalene Phenanihrene Toluene Xylenes

86

K067 wasiewaiers

K099 nonwaslewaiers

88

K099 wastewaters

89

Acenaphihalene Benzene Chrysene Fluoranlhene Indeno (1,2,3-cd) pyrene. Naphthalene Phenanihrene Toluene Xylenes Lead

2,4-Dichlorophenoxyaceiic acid Hexachlorodibenzo-p-dioxins,.., Hexachlorodibenzofurans Penlachlortxlib^nzo-p-dioxins.,. Penlachlorodibenzorurans Tetrachlorodibenzo-p-dioxins,,., Tetrachlorodiberuolurans

2.4-Dichlorophenoxyacelic acid, Hexachlorodibenzo-p-dioxins.... Hexachlorodibenzofurans Penlachlorodibenzo-p-dioxins,.., Penlachlorodibenzofurans Telrachlorodibenzo-p-dioxins.... Tetrachlorodibenzofurans

KIOI nonwaslewaiers (Low Arsenic Subcategory—less than 1^ total arsenic)

(See also Table CCWE in § 268.41)


kg)

3,4 .071 3,4 3,4 3,4 3 4 3,-t ,65 .070

Concenira-lion in mg/

1)

0,028 .014 .028 .028 ,028 .028 .028 ,008 .014 ,037

Concenira-tion (in mg/

kg)

1.0 ,001 ,001 ,001 .001 ,001 ,001

Concentration (in mg/)

I)

1.0 .001 ,001 ,001 .001 .001 .001

Iho-Nitroaniline,.


kg)

ConcentraKIOI wastewaters tion (in mg/

1)

Orlho-Niiroaniline 0,27 Arsenic 2.0

.24 Lead .11

,027

91 KI02 nonwaslewaters (Low Arsenic Concentra

Subcategory—less than Wt total arsenic) tion in mg/ (see also Table CCWE in § 268.41) kg)

Orlho Nitrophenol 13

92 Concentra

K102 wastewaters tion (in mg/ 1)

Ortho-Nilrophenol 0.028 Arsenic 2.0 Cadmium .24 Lead .11 Mercury .027

93 Concenlta-

KI03 nonwaslewaters lion in mg/ kg)

Aniline 5.6 6,0 5.6

Nitrobenzene 5.6 Phenol 5.6 5.6

94 Concentra

KI03 wastewaters tion (in mg/ 1)

Aniline... 4.5 Benzene .15

,61 .073

Phenol 1.4 1.4

KI04 nonwaslewaters Concentra

tion (in mg/) kg)

5,6 6,0 5,6 5.6 5,6 1.8

5,6 6,0 5,6 5.6 5,6 1.8

5,6 6,0 5,6 5.6 5,6 1.8

5,6 6,0 5,6 5.6 5,6 1.8

Phenol

5,6 6,0 5,6 5.6 5,6 1.8

5,6 6,0 5,6 5.6 5,6 1.8

5,6 6,0 5,6 5.6 5,6 1.8

96

KI(M wflstcwfltcrs Concenlta-

lion (in mg/ 1)

4.5 ,15 ,61

Benzene 4.5

,15 ,61 2,4-Dinilrophenol

4.5 ,15 ,61

4.5 ,15 ,61

98

KI04 wastewaters Concentra

tion (in mg/ 1)

.073 1,4 2,7

Phenol .073

1,4 2,7 Cyanides (Total)

.073 1,4 2,7

.073 1,4 2,7

SUMMARY OF LAND DISPOSAL RESTRICTIONS

WASTES AFFECTED BY THE LAND DISPOSAL RESTRICTIONS Exhibit #1 Iist.s all of the waste streams restricted fromland disposal (except by deep well injection). The list includes both the solvent and dioxin wastes banned on November 8, 1986 and the California List banned on July 8, 1987. NOTE: Appendix III to Part 268-Lists out the halogenated organic compounds (HOC) regulated under the

California List.

I I . VARIANCES Currently there are nationwide variances and exemptions that allow certain restricted wastes to be landfill under specific conditions. The specific are listed in Exhibit #2. Below are some examples of variances: A. F001-F005 wastes that contain less than 1% of the listed solvents are entitled to a 2 year national

variance effective November 8, 1986 due to the lack of existing treatment capacity (40 CFR 268,30). Exception: Methylene Chloride wastewater from pharmaceutical manufacturing. The variance is due to end on November 8, 1988.

B. Liquid HOC wastes that contain greater than 1,000 mg/1 HOCs which are not wastewaters and non-liquid HOC wastes that contain greater than 1000 mg/1 HOCs are restricted from land disposal. Both are entitled to a national capacity variance effective until November 8, 1988 due to the lack of national capacity (40 CFR 268.32).

C. Small quantity generators that produce less than 100 kg per month are exempted from the land disposal restrictions by regulations.

D. Those wastes that are not RCRA regulated but do contain regulated constituents are not restricted from land disposal (i.e. nickel, thallium) by regulation.

E. K048-K052 and K071 are entitled to a 2 national capacity variance effective August 8, 1988 due to lack of existing treatment capacity (40 CFR 268.30).

I I I . TREATMENT STANDARDS Restricted wastes that are treated prior to land disposal must meet certain treatment standards which may be required by treatment technology or concentration levels in treatment residues. Exhibit #3 lists the specific standards required under the Rule (40 CFR 268.41 and 268.42).

REGULATIONS EFFECTIVE AUGUST 8, 1988

1. First third waste codes that have had treatment standards developed:

F006 KOOI K004 K008 KOI."5 K016 KOI 8 KOI 9 K020 K021 K022 K024 K025 K030 K036 K037 K044 K045 K046 K047 K04B K049 K050 K051 K052 K060 K061 K062 K069 K071 K073 K0n3 KOBR K0B7 K099 KlOO KIOI K102 K103 K104

II. Those waste cod OS that have received a two year national capacity v;i iriance.

K048 K049 K050 K051 K052 K071

IIL Rescission of earlier variances: (A) F001-F005 - Pharmaceutical wastewater for Methylene Chloride/BDAT - steam stripping. (B) Hazardous wastes containing halogenated organic compounds (HOC), Appendix III, in concentrations

greater than or equal to 1,000 mg/1, except for California list HOC contaminated soils/BDAT-lncineration (Effective November 8, 1988).

(C) Solvent waste generated from section 104 or 106 response actions under CERCLA or RCRA corrective action, except where the waste is contaminated soil and debris.

Exhibit #1

SOLVENT WASTES

FOOl. . . Tht; following spent halogenated solvents used in degreasing: tetrachloroethylene, trichloroethylene, methylene chloride, 1,1,1-trichloroethane, carbon tetrachloride, and chlorinated fluorocarbons; all spent solvent mixtures/blends used in degreasing containing, before use, a total of ten percent or more (by volume) or one or more of the above halogenated solvents or those solvents listed in F002, F004, F005 and still bottoms from the recovery of these spent solvent and spent solvent mixtures.

F002. . . The following spent halogenated solvents: tetrachloroethylene, methylene chloride, 1,1,1-trichloroethanc, chlorobenzene, 1,l,2-(richloro-l,2,2-trinuoroethane, ortho-dichlorobenzene, and trichlorofluoromethane; all spent solvent mixtures/blends used in degreasing containing, before use, a total of ten percent or more (by volume) of one or more of the above halogenated solvents or those solvents listed in FOOl, F004, and F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures,

F003. . . The following spent non-halogenated solvents: xylene, acetone, ethyl acetate, ethyl benzene, ethyl ether, methyl isobutyl ketone, cyclohexanone, and methanol; all spent solvent mixtures/Blends containing, before use, only the above spent non-halogenated solvents, and a total of ten percent or more (by volume) of one or more of those solvents listed in FOOl, F002, F004, and F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures.

F004. . . The following spent non-halogenated solvents: cresols, and creysylic acid, and nitrobenzene; all spent solvent mixtures/blends containing, before use, a total of ten percent or more (by volume) of one or more of the above non-halogenated solvents or those solvents listed in FOOl, F002, and F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures.

05. . . The following spent non-halogenated solvents: toluene, methyl ethyl ketone, carbon disulfide, isobutanol, pyridine, benzene, 2-ethoxyethanol, and 2-nitropropane; all spent solvent mixtures/blends containing, before use, a total of ten percent or more (by volume) of one or more of the above non-halogenated solvents or those solvents listed in FOOl, F002, and F004; and still bottoms from the recovery of these spent solvents and spent solvent mixtures.

September 23, 1988

Exhibit #1

DIOXIN WASTES

F020. . . Wastes (except wastewater and spent carbon from the production or manufacturing use (as a reactant, chemical intermediate, or component in a formulating process) of tri- or tetrachlorophenal, or of intermediates used to produce their pesticide derivatives, (This listing does not include wastes from the production of hexachlorophena from highly purified 2,4,5-tri-chlorophenol.)

F021. . . Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production or manufacturing use (as a reactant, chemical intermediate, or component in a formulating process) of pentachlorophenol, or of intermediates used to product its derivatives.

F022. . . Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the manufacturing used intermediate, or component in a formulating process) of totra-, penta-, or hexachlorobenzenes under alkaline conditions.

F023. . . Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production of materials on equipment previously used for the production or manufacturing use (as a reactant, chemical intermediate, or component in a formulating process) of tri- and tetrachlorophenols. (This listing does not include wastes from equipment used only for the production or use of Hexachlorophene from highly purified 2,4,5-trichlorophenol.)

F026. . . Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production of materials on equipment previously used for the manufacturing use (as a reactant, chemical intermediate, or component in a formulating process) or tetra-, penta-, or hexachlorobenzene under alkaline conditions.

\ l . . . Discarded unused formulations containing tri-, tetra-, or pentachlorophenol or discarded unused formulation containing compounds derived from these chlorophenols. (This listing does not include formulations containing Hexachlorophene synthesized from pre-purified 2,4,5-trichlorophenol as the sole component.)

September 23, 1988

Kxhibil * l Solveiil.s aiitt Dioxln.s On November 7. 1986, EPA pro-

mtilgaled a final rule thai established a framework for Implementing the congres-sionally mandated land disposal prohibitions (."il FR 4 0 5 72), The rule e.stablishod procedures for eslablishing Ircalment standards, for granting nationwide variances from slatulory effective dates, for granting extensions of effective dales on a ca.to-by-case basis, for evaluating petilion.t allowing variances from the trcalmeni .standard, and for evaluating petllion.s demonstrating tlial conlinunil land dispcsal is protective of human health and the enviroiimeni. In addition, the November 7, 19Bfi final rule established Ireatment standards and effective dates for wastiis included in Ihe first phase of the land disposal prohibllioii.s: certain solvent-containing and dioxin-containing hazardous wastes,

California List

Today's rule addresses the second phase of Iho land disposal restrictions i.e., Ihe California list wastes. The California list consists of liquid hazardous wastes containing certain metals, free cyanides, polychlorinated biphenyls (PCBs), corrosives with a pII of less than or equal to two (2,0), and liquid and nonliquid hazardous wastes containing halogenated organic compounds (HOCs) as described below

(A) Liquid hazardous wastes, including free liquids associated with any solid or sludge, containing free cyanides at con-centralions greater than or equal to 1.000 mg/1.

(B) Liquid hazardous wa.stes. including free liquids associated with any solid or sludge, containing the following melals (or elements) or compounds of these metals (or elements) at concentrations greater than or equal to those specified below:,

(i) Arsenic and/or compounds (as As) 500 mg/1;

(ii) Cadmium and/or compounds (as Cd) 100 mg/1;

(iii) Chmmium (VI and/or compounds (as Cr VI)) 500 mg/1;

(iv) Lead and/or compounds (as Pb) 500 mg/1;

(v) Mercury and/or compounds (as Hg) 20 mg/1;

(vl) Nickel and/or compounds (as Ni) 134 mg/1

(vii) Selenium and/or compounds (as Se) 100 mg/1; and

(viii) Thallium and/or compounds (as Tl) 130 mg/1;

(C) Liquid hazardous wastes having a pH less than or equal to two (2.0).

(D) Liquid hazardous wastes containing polychlorinated biphenyls at concentrations greater than or equal to 50 ppm.

(E) Hazardous wastes containing halogenated organic compounds in tolal concentration greater than or equal to 1,000 mg/kg.

(ôIleclivL'ly, these hazardous wastes are referred to as Ihe California list because the Stale of California developed regulations lo restrict the land disposal of hazardous wastes containing these constituents, and Congress subsequonlly incor-poraled these prohibitions into the lOH l Amendments lo RCRA, (RCRA sections 3004(d)(1) and (2). 42 U.S.C. 6924(d)(1). and (2)), Congress intended the California list prohibitions as a starling point in carrying out Ihe congressional mandate to ininiinize land flis|iosal of hazardous wasle. Congress' intent in specifying lhr(!sliold levels for the land disposal of Califiirnia list wastes was lo avoiti time-consuming litigalion over Ihe selection of a|)propriate Itivels However, section 3l)()4(d)(2) of RCRA directs Ihe Agency lo substituli! more stringent concontralion levels where necessary lo protect human health and Ihe environment. Appendix I I I to Part 200—List of Halogenated Organic Compounds Regulated Under § 268.32.

In deteriiiining the concontralion of HOCs in a hazardous wasle for purposes of Ihe § 2()R,.'12 land disjjosal prohibition, HPA has defined the ll(3Cs thai mu.sl be included in the calculation as any compounds having a carbon-halogen bond which are listed in this Appendix (see § 268.2), Ajipendix III lo I'arl 26B consists of Ihe following coinpounds: Voln(il(;.<i liroinodicliloroiueth.iiic UroinoiiKithane Carbon Tetrachloride Chlorobenzene 2-Chloro-1.3-butadiene Chlorodibromomothano Chloroethane 2- Chloroethyl vinyl ether Chloroform Chloromethane 3- Chloropropene 1.2-IJibronio-3-chloropropane 1,2-rJibromomelhane nibroinoniothane Trans-1.4-Dichloro-2-bulcne Dichlorodif luoromethane 1.1- DichIoroothane 1.2- Dichloroelhanc 1.1- Dichloroolhylene Trans-1,2-Dichloroethene 1.2- Dichloropropane Trans-1,3-Dichloropropene cis-1,3-Dichloropropene lodornethane Methylene chloride 1.1.1,2-Tetrachloroethane 1.1.2.2-Tolrachloroethane Telrachloroethene Tribroinomelhnne 1.1.1-Trichloroelhane 1.1.2-Trichloroethane Trichloroethane Trich loromonofluoromelhane 1.2.3-Trichloropropane Vinyl chloride

.Sf!tn/i'o/a(//e.9 Bis(2-chloroelhoxy)elhane Bis(2-chloroelhyl)elher Bis(2-chloroisopropyl)ether p-Chloroaniline Clilnrobonzilate p-C;hloro-m-cresnl 2-Chloronaphlhalene 2- Chlorophenol 3- Chloropropionilrile m-Dichlorobenzene o-Dichlorobenzene p-Dichiorobenzene 3.3- Dichlorobenzidine 2.4- Dichlnrophenol 2.6-Dichlorophonol Hexachlorobenzene I lexachlorobuladione 1 lexachlorocyclopentadiene Hexachloroelhane Hexachloroprophene Hnxachloropropene 4.4-Methylenobis(2-chloroaniline) I'entachlorohenzene flcntachloroothane Pentachloronitrobenzeiie Pentachlorophenol Pronamido 1.2.4.5-Telrat:hlorohonzcnc 2.3.4.6-Tetrachloroplienol 1.2.4-Trichlorobenzene 2.4.5-Trichlorophenol 2.4.6-Trichlorophenol Tris(2,3-dibromopropyl)phosphale Orgnnnrh Inrine Pnsticiclns Aldrin aplha-IlHC bota-BHC dolta-BHC gamma-BHC Chlordane DDD DDE DDL Dieldrin Endosulfan 1 Endosulfan II Endrin Endrin aldehyde I leplachlor Heptachlor epoxide Isodrin Kepone Melhoxyclor Toxaphone Phenoxyacolic Acid Herbicides 2,4-Dichlorophenoxyacetic acid Si Ivex 2,4,5-T

Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260 IX;BS not otherwise specified Dioxins and Fiirans Hexachlorodibenzo-p-dioxins Hexachlorodibenzofuran Penlachlorodibenzo-p-dioxins rVintachlorodibenzofuran 'l'elraclilorodibenzo-|)-dioxins Telrachlorodibonzofuran 2.3.78-Telrachlorodibenzo-p-dioxin

September 23, 1988

Exhibit »1

THOSE WASTES CODES UNDERLINED ARE WASTES THAT HAVE TREATMENT STANDARDS SET,

THE REMAINDER ARE SOFT HAMMER WASTES

§268,10 Identification of wastes lo bo evaluated by August H. 1988.

EPA wil l take action under sections 3004(g)(5) and 3004(m). of Ihe Resource Conservation and Recovery Act. by August 8. 1988, for the following wastes (for ease of understanding the wastes have been listed by Ihe section of 40 CFR r^rt 261 under which they wore listed):

§261.31 Wastes F006 — Wastewater treatment sludges

from electroplating operations except from the following processes: (1) Sulfuric acid anodizing of aluminum; (2) tin plating on carbon steel; (3) zinc plating (segregated basis) on carbon steel; (4) aluminum or zinc-aluminum plating on carbon steel; (5) cleaning/stripping associated with t in. zinc and aluminum plating on carbon steel; and (6) chemical etching and milling of aluminum.

F007 — Spent cyanide plating bath solutions from electroplating operations.

F008 — Plating bath sludges from (he bottom of plating baths from electroplating operations where cyanides are used in the process.

F009 —Spent stripping and cleaning bath solutions from electroplating operations where cyanides are used in the process.

Foist — Wn.stewater Ireiitineiil sludges from the chemical conversion coating of aluminum.

§261.32 Wisln.s KOOI — Botloiii sediment sludge from

the treatment of wastewaters from wood preserving processes that use creosote and/or pentachlorophenol.

K004 — Wastewater treatment sludge from the production of zinc yellow pigments.

KOOB — Over residue from the production of chrome oxide green pigment.?.

KOll — Bottom stream from the wastewater stripper in the production of acrylonitrile.

K013— Bottom stream from the acetonitrile column on the production of acrylonitrile.

K014 — Bottoms from Ihe acetonitrile purification column in the production of acrylonitrile.

K015 — Still bottoms from the distillation of benzyl chloride.

K016 — Heavy ends or distillation residues from the production of carbon tetrachloride.

K017 — Heavy ends (still bottoms) from the purification column in the production of epichlorohydrin.

K018 — Heavy ends from the fractionation column in ethyl chloride production.

K020 — Heavy ends from the distillation of vinyl chloride in vinyl chloride monomer production.

K021 — Atjueous spent antimony catalyst waste from fluoromethanes production.

K022 — Distillation bottom tars from the production of phenol/acetone from cumane.

K024 — Distillation bottoms from the production of phthalic anhydride from naphthalene,

K030 — Column bottom or heavy ends from the combined production of trichloroethylene and perchloroethylene.

K031 — By-producis salts generated in the production of MSMA and cacodylic acid,

K035 — Wastewater treatment sludges generated in the production of creosote.

K036 —Still bottoms from toluene reclamation distillation in the production of disulfoton. _J<037 - Wastewnter trentment sludge

from the production of disulfoton. K044 — Wastewater treatment sludges

from the manufacturing and processing of explosives. _K045 — Spent carbon from the treatment of wastewater containing explosives.

K046 ~ Wastewater treatment sludges from the manufacturing, formulation and loading of lead-based initiating compounds.

K047 — Pink/red water from TNT operations.

K04B — Dissolved air flotation (DAF) K049 — Stop oil emulsion solids from

the petroleum refining industry. K050 — Heat exchange bundle clean

ing sludge from Ihe petroleum refining industry.

K051 — API separator sludge from the petroleum refining indutitry.

K052 — Tank bolloins (leaded) from the petroleum refining industry.

K019 — Heavy Ends from the Distillation of Ethylene Dichloride Production

K025 — Distillation bottoms from the production of nitrobenzene by the nitration of benzene.

KtOO — Waste l>eaching Solution from Acid Ijcachlng of Emission Control Dust/Sludge from Secondary Lead Smelting.

K060 — Ammonia still lime sludge from coking operations.

K061 — Emission control dust/sludge from the primary production of steel in electric furnaces.

K062 — Spent pickle liquor from steel finishing operations in chlorine production.

K069 — Emission control dust/sludge from secondary lead smelting.

K071 —- Brine purification muds from the mercury cells process in chlorine production, where separately prepurified brime is not used.

K073 — Chlorinated hydrocarbon waste from the purification step of the diaphragm cell process using graphite anodes.

K083 — Distillation bottoms from aniline production.

K084 — Wastewater treatment sludges generated during the production of veterinary pharmaceuticals from arsenic or organo-arscnic compounds.

K0B5 — Distillation of fractionation column bolloms from Ihe prodiictioit of chlorobenzenes.

K086 — Solvent washes and sludges; caustic washes and sludges, or water washes and sludges from cleaning tubs and oqui|)iiiont used in the furmulntlon of ink from pigments, driers, soaps, and stabilizers containing chromium and lead.

K0B7 — Decanter tank tar sludge froin coking operations.

K099 — Untreated wastewater from the production of 2,4,-D.

KIOI — Distillation tar residues from the distillation of aniline-based compounds in the production of veterinary pharmaceuticals from arsenic or organo-arsenic compounds.

K102 — Residue from the use of activated carbon for decolorization in the production of veterinary pharmaceuticals from arsenic or organo-arsenic compounds.

K103 — Process residues from aniline extraction from (he production of aniline.

Kxhibil #1

§261.32 Wastes continued.

K104 — Combined wastewater streams generated from nitrobenzene/aniline production.

K106 — Waste wntor lieatnKMit sludge from Ihc mert;ury cell |)roi;ess in chlorine production.

§261.33le) Wastes Pool—Warfarin, when present at con

centration greater than 0.3% P004—Aldrin P005—Allyl alcohol POlO—Arsenic acid Poll—Arsenic (V) oxide P012—Arsenic (111) oxide P015—Beryllium tjusl P016—Bis-(chloromelhyl)elher P018—Brucine P020—Dinoseb P030—Soluble cyanide salts not

elsewhere specified P036—Dichlorophenylarsine P037—Dieldrin P039—Disulfoton P041—Diethyl-p-nitrophenyl phosphate P048—2.4 Dinitrophenol P050—Endosulfan P058—Fluoracetic acid sodium salt P059—Heptachlor P063—Hydrogen cyanide P068—Methyl Hydrazine P0B9—Methyllactonitrile P(J7t)-'Aldicarb POTl—Methyl parathion P081—Nitroglycerine P082—N-Nitrosodimethylamine P084—N-Nitrosomethylvinylamino P087—Osmium tetraoxide P089—Parathion P092—Phenylmercuric acetate P094—Phorate P097—Famphur P102—Propargyl alcohol P105—Sodium azide P108—Strychnine and salts PllO—Tetraethyl lead P115—Thallium (I) sulfate P120—Vanadium pentoxide P122—Zinc phosphide, when present at

concentrations greater than 10% P123—Toxaphene

§261.33(0 Wastes U007—At;rylamide U009—/icrylonilrile tlOlO—Mitomycin C UOI2~AniliiU! U016—Bonz(c)acridine IIOIB—Benz(a)anthracene U019—Benzene U022 —nenzo(a)pyreiie U029—Methyl bromide U031—n-Butanol U036—Chlordane, technical U037—Chlorobenzene U041—n-Chloro-2,3-epoxy propane U043—Vinyl chloride U044—Chloroform U046—Chloromethyl methyl ether U050—Chrysene U051—Creosote U053—Crotonaldehyde U061—DDT

U063—Dibenz o (a,b) anthracene U064—2,2.7.8 Dibenzopyrene U066—Dibromo-3-chloropropane 1,2-U067—Ethylene dibromide U074—l,4-Dichloro-2-butene U077—Ethane. 1,2-dichloro-t.KlTB—Dichloroethylene, 1,1-U08fi—N,N Diethylhydrazine U089—Diothylstilbestrol U103—Dimethyl sulfate U105—2,4-DinilrotoIuene UlOB—Dioxane, 1.4 UI15—Elhylone oxide 11122—Formaldehyde U124 —Furan

U129—Lindane U130—HexachlorocyclopentadieiK^ U133—Hydrazine (1134 - I lytlrofluorii; ni:id t)137—Indeno (1.2,:i-cd)|)ynMie U151—Mercury U154—Methanol U155—MelhapyrileiK! UI57—3-Methyli;holanthrune U158—4,4-Methylenc-bis-(2-

chloroanilinc) U159—Methyl ethyl ketone Ul71—Nitropropane, 2-U177—N-Nitroso-N-melhylurei) UlBO—N-Nilôsopyrolidin(! Ul85— Penlachloronitrobenzene UIBB—Phenol 11192—Pronamido U200—Reserpine 11209—Tetrachloroothane. 1.1.2.2 U210—Tetrachloroethylene U211—Carbon tetrachloride U219—Thiourea U220—Toluene U221—Toluenediamine U223—Toluene diisocyanate t.l220—Methy Ichloroform U227—Trichloro(!thano, 1,1.2-U228—Trichloroethylene 1)2,37—Uracil inuslard IJ238—Ethyl carb.imale U241)—Warfarin, when present at

concentrations of 0.3% or less U249—Zinc phosphide, when prosont

at concentrations of 10% or less

Exhibit #2

Subpart C—Prohibitions on Land Disposal. S 268.30 Waste specific prohibitions— Solvent wastes.

(a) Effective November 8, 1986. the spent solvent wastes specified in 40 CFR 261.31 as EPA Hazardous Waste Nos. FOOl, F002, F003, F004, and F005, are prohibited from land disposal (except in an injection well) unless one or more of the following conditions apply:

(1) The generator of the solvent waste is a small quantity generator of 100-1000 kilograms of hazardous waste per month; or

(2) The solvent waste is generated from any response action taken under the Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA) or any corrective action taken under the Resource Conservation and Recovery Act (RCRA), except where the waste is contaminated soil or debris not subject to the provisions of this chapter until November 8, 1908; or

(3) The solvent wasle is a solvonl-walor mixture, solvent-containing sludge, or solvent-contaminated soil (non-CERCLA or RCRA corrective action) containing less than 1 percent total F001-F005 solvent constituents listed in Table CCWE of § 268.41 of this part.

(4) The solvent waste is a residue from treating a waste described in paragraphs (a)(1). (a)(2), or (a)(3) of this section; or the solvent waste is a residue from treating a waste not described in paragraphs (a)(1), (a)(2), or (n)(3) of this section provided such residue belongs to a different treatability group than the wasle as initially generated and wastes belonging lo such a treatability group are described in paragraph (a)(3) of this section.

(b) Effective November 8, 1988, the F001-F005 solvent wastes listed in paragraphs (a)(1), (2), and (3) of this sec-lion are prohibited from land disposal. Between November 8, 1986, and November 8, 1988. wastes included in paragraphs (a)(1), (2), and (3) of this section may be disposed of in a landfill or surface impoundment only if the facility is in compliance with the requirements specified in S 268.5(h)(2).

(c) The requirements of paragraphs (a) and (b) of this section do not apply if:

(1) The wastes are treated to meet the standards of Subpart D of this part; or

(2) The wastes are disposed at a facility that has been granted a petition under 5 268.6; or

(3) An extension has been granted under § 268.5.

§ 268.32 Waste specific prohibitions— California list wn.stos.

(a) Effective july 8, 1987, the following hazardous wastes are prohibited from land disposal (except in injection wells):

(1) Liquid hazardous wastes having a pH less than or equal to two (2.0);

(2) Liquid )i;iz;irdoiis wastes containing polychlorinated biphenyls (PCBs) at concentrations greater than or equal to 50 ppm;

(3) Liquid hazardous wastes that are primarily water and contain halogenated organic compounds (HOCs) in tolal concentration greater than or equal lo l.ono mg/1 and less than 10.000 mg/1 HOCs.

(b) -(c) jResorved] (d) The requirements of paragraph (a)

of this section do not apply until November 8, 1988 where the wastes are contaminated soil or debris resulting from a response action taken under sec-lion 104 or 108 of the Comprehensive Environmental Response, Compensation, and Liability / \ f . l or a corrective action required under RCRA Subtitle C.

(c) Effective july 8, 1989, the following hazardous wastes are prohibited froin land disposal (subject to any regulations that may be promulgated with respect to disposal in injection wells):

(1) Liquid hazardous wastes that contain HOCs in total concentration greater than or equal to 1,000 mg/1 and are not prohibited under paragraph (a)(3) of this section; and

(f) Between )uly 8, 1987 and July B, 1989, the wastes described in paragraphs (e)(1) and (e)(2) of ibis section may be disposed of in a landfill or surface impoundment only if Ihe -facility is in compliance with the requirements specified in § 268.5(h)(2).

(g) The roquiremenis of paragraphs (a) and (c) of this section do not apply if:

(1) Persons have been granted an exemption from a prohibition pursuant to a petition under § 208.6, with respect to those wastes and units covered by the petition (except for liquid hazardous wastes containing polychlorinated biphenyls at concentrations greater than or equal to 500 ppm which are nol eligible for such exemptions); or

(2) l\;rsons have been granted an extension to the effective dale of a prohibition pursuant to § 268.5, with respect to those wastes covered by Ihe extension; or

(.() The wastes meet the applicable stanilards specified in Subpart D of this part or, where treatment standards are not specified, the wastes are in compliance with Ihe applicable prohibitions sot forth in this section or RCRA section 3004(d).

(h) The prohibitions and effective dates specified in paragraphs (a)(3) and (e) of Ibis section do not apply where the wasle is subject to a Part 268 Subpart C prohibition and cfftsctivo date for a specified HOC (such as a hazardous waste chlorinated solvent, see e.g.. § 268.03(a).

(i) To determine whether or not a wasle is a liquid tinder paragraphs (a) and (e) of this section and under RCRA section 3004(d), the following lest must be used: Method 9095 (Fînt Filler Liquids Test) as described in "Test Methods for Evaluating Solid Wastes. Physical/Chemical Methods," EPA Publication No. SW-846.

(j) Except as otherwise provided in this paragraph, tho waste analysis and recordkeeping requirements of § 268.7 are applicable to wastes prohibited under this ftrt or RCRA section 3004(d):

(1) The initial generator of a liquid hazardous waste must test his waste (not on extract or filtrate) in accordance with Ihe procedures specified in 5 261.22(a)(1), or use knowledge of the waste, to determine if the waste has a pH less than or etiual to two (2.0). If the liquid wasle has a pi I less than or equal to two (2,0), it is restricted from land disposal and all requirements of Part 268 are applicable, except as otherwise specified in this seclion.

(2) The iii i l ial generator of either a liquid hazardous waste containing polychlorinated biphenyls (PCBs) or a liquid or nonliquid hazardous wasle containing halogenated organic compounds (HOCs) must test his waste (not an extract or filtrate), or use knowledge of the waste, lo dclermine whether Ihe concentration levels in the waste equal or ex-ceeil Ihe prohibition levels specified in this section. If the concentration of PCBs or HOCs in Ihe wasle is greater than or equal lo the prohibition levels specified in this section, the waste is restricted from land disposal and all requirements of Pari 268 are applicable, except as otherwise specified in this section.

TO BE UPDATED UPON ISSUANCE OF RE(;ULATIONS Seplcmber 23, 1988

Exhibit *J

Subpart D—Treatment Standards } 268.40 Applicability of treatment standards.

(a) A restricted waste identified in this subpart may be land disposed without further treatment only if an extract of the waste or of the treatment residue of the waste developed using the test method in Appendix I of this part does not exceed the value shown in Thble CCWE of 5 268.41 for any hazardous constituent listed In the "niblo CCWE for that waste.

(b) A restricted waste for which a treatment technology is specified under f 268.42(a) may be land disposed after it is treateiJ using that specified technology or an equivalent treatment method approved by the Administrator under the procedures set forth in § 268.42(b). S 268.41 Treatment Standards expressed as concentrations in waste extract.

(a) Table CCWE identifies the restricted wastes and the concentrations of their associated hazardous constituents which may not be exceeded by the extract of a waste treatment residual developed using the test method in Appendix I of this part for the allowable land disposal of such waste. (Appendix II of this part provides Agency guidance on treatment methods that have been shown lo achieve the Tible CCTWE levels for Ihe respective wastes. Appendix II is not a regulatory requirement but is provided to assist generators and owners/operators in their selection of appropriate treatment methods.)

TABLfe CCWE-CONSTITUKN I'S IN WfSTE EXTRACT

F020-F023 and F026-F028 dioxin containing waslos

fCOI-fOOi spent sdvenls

Acetone n-Bulyt alcotiol Carbon disulfide Carbon tetrachloride Ctilorotsenzene.. Cresois (and cresylic acid) Cyclotioxanone 1.2-dictilorobenzeno Eltiyl acetate Eltiyle benzene Eltiyl eltwr Isobutanol Melt<anol Methylene chloride Melhylerie chloride (from Ihe phsr

maceulical industry Iêthyl ethyl ketone Methyl Isobutyl Itelone Nitrobenzene Pyndine Telrachloroelhyfene Toluene 1.1.1- Trichloroethane 1.2.2- Trichloro-1.2,2-liilluroelhane Trichloroolhytono Trichlorofluoromethane Xylene

Conceniralion (in itig/I)

Wasiewiys All oltiei conlaming spent

spent scilveni solvenis wastes

0,05 0,59 5,0 5,0 1,05 4,81 ,05 ,96 .15 .05

2 82 ,75 ,125 ,75 ,65 ,125 ,05 ,75 .05 ,053 05 ,75

5,0 5,0 ,25 ,75 .20 ,96

12,7 .96 0.05 0.75 0,05 0,33 0,66 0,125 1 12 0,33 0 079 0,05 1 12 0 33 1,05 0 41 1,05 0 96 0052 0 091 005 0,96 0,05 0,15

HxCDD—AII Hexachiofodibenzo-p-dioxins, HxCDF—All Hexachlofodibenzolurans

' PeCDD—All Peniachlorodibenzo p-dioxins PeCOF—All Penlachlorodibenzolufans TCDD—All Telrachlorodibenzo-p-dioxtns,,, TCDF—All Telrachlorodibenzofurans 2.4.5- Trichlorophenol 2.4.6- Trichioropheno) 2.3.4.6-Telrachlorophenol Pentachlorophenol

Concentration

1 ppb 1 ppb 1 ppb 1 ppb 1 ppb 1 ppb

0,05 ppm 0,05 ppm 0,10 ppm 0,01 ppm

(b) when wastes with differing treatment standards for a constituent of concern are combined for purposes of treatment, Ihc treatment residue must meet the lowest treatment standard for Ihe constituent of concern. 5 268,42 Treatment standards expressed as specified technologies.

(a) The following wastes must be treated using the identified technology or technologies, or an equivalent method approved by the Administrator.

(1) Liquid hazardous wastes containing polychlorinated biphenyls (PCBs) at concentrations greater than or equal to 50 ppm but less than 500 ppm must be incinerated in accordance with the technical requirements of 40 CFR 761.70 or burned in high efficiency boilers in accordance with the technical requirements of 40 CFR 761.60. Liquid hazardous wastes containing polychlorinated biphenyls (PCBs) at concentrations greater than or equal to 500 ppm must be incinerated in accordance with the technical requirements of 40 CFR TTJI.TD, Thermal treatment under this section must also be in compliance with applicable regulations in Parts 264, 265, and 266.

(2) Nonliquid hazardous wastes containing halogenated organic compounds (HOCs) in total concentration greater than or equal lo 1,000 mg/kg and liquid HOC-containing wastes that are prohibited under § 268.32(e)(1) of this part must be incinerated in accordance with the requirements of Part 264 Subpart 0 or Par\ 265 Subpart 0. These Ireatment standards do not apply where the wasle is subject to a F^rt 268 Subpart C Ireatment standard for a specific HOC (such as a hazardous wasle chlorinated solvent for which a treatment standard is established under $ 268.41(a)).

(b) Any person may submit an application to the Administrator demonstrating that an alternative treatment method can achieve a measure of performance equivalent to that achitivablc by methods specified in paragr.ipli (a) of this section. The applicant must submit information demonstrating that his Ireatment method is in coiiiplianco with fedoial. state, and local requiiemonts and is protective ol human health and tho environment. On the basis of such information and any

other available information, the Administrator may approve the use of the alternative treatment method if he finds that the alternative treatment method provides a measure of perforinance equivalent to that achieved by methods specified in paragraph (a) of this section. Any approval must be stated in writing and may contain such provisions and conditions as the Administrator deems appropriate. The person lo whom such approval is issued must comply with all limitations cnnlninod in such a determination.

September 23, 1988

TO BE UPDATED UPON ISSUANCE OF REGULATIONS

CHAPTER EIGHT

EMPLOYEE CERTIFICATION STATEMENT

prepared by

Un.iversal Waste & Transit

Orient Road

Tampa Florida

CERTIFICATION STATEMENT I hereby c e r t i f y t h a t I attended the DOT/RCRA T r a i n i n g Course

presented by Universal Waste & T r a n s i t .

C e r t i f i e d by: Date:

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