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This article was downloaded by: [Dr M. M. El Nady]On: 09 February 2015, At: 03:50Publisher: Taylor & FrancisInforma Ltd Registered in England and Wales Registered Number: 1072954 Registeredoffice: Mortimer House, 37-41 Mortimer Street, London W1T 3JH, UK
Energy Sources, Part A: Recovery,Utilization, and Environmental EffectsPublication details, including instructions for authors andsubscription information:http://www.tandfonline.com/loi/ueso20
The Subsurface Geology and SourceRocks Characteristics of Some Jurassicand Cretaceous Sequences in the WestQarun Area, North Western Desert,EgyptM. M. Hammad a , S. A. Awad b , M. M. El Nady a & D. A. Moussa aa Exploration Department , Egyptian Petroleum Research Institute ,Cairo, Egyptb Geology Department, Faculty of Science , Ain Shams University ,Cairo, EgyptPublished online: 10 Aug 2010.
To cite this article: M. M. Hammad , S. A. Awad , M. M. El Nady & D. A. Moussa (2010) The SubsurfaceGeology and Source Rocks Characteristics of Some Jurassic and Cretaceous Sequences in the WestQarun Area, North Western Desert, Egypt, Energy Sources, Part A: Recovery, Utilization, andEnvironmental Effects, 32:20, 1885-1898, DOI: 10.1080/15567030701715955
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Energy Sources, Part A, 32:1885–1898, 2010
Copyright © Egyptian Petroleum Research Institute
ISSN: 1556-7036 print/1556-7230 online
DOI: 10.1080/15567030701715955
The Subsurface Geology and Source Rocks
Characteristics of Some Jurassic and Cretaceous
Sequences in the West Qarun Area,North Western Desert, Egypt
M. M. HAMMAD,1 S. A. AWAD,2 M. M. EL NADY,1
and D. A. MOUSSA1
1Exploration Department, Egyptian Petroleum Research Institute,
Cairo, Egypt2Geology Department, Faculty of Science, Ain Shams University,
Cairo, Egypt
Abstract The lithostratigraphic cross sections, thickness variations, and lithofaciesof some Jurassic and Cretaceous rock units are discussed in order to distinguish the
shape and the extent of sedimentary basins and the environment of deposition. Thegeochemical study assisted in the identification of potential source intervals within
the studied rock units. The results showed that the Middle Jurassic source rocks aremature and have good to very good organic richness with mixed kerogen type (III/II).
The Cretaceous source rocks vary from poor to very good with mixed oil and gas andcharacterized by immature to marginally mature in the study area.
Keywords Egypt, geochemical characteristics, source rock, subsurface setting, WestQarun area
Introduction
West Qarun area is located in the Western Desert to the southwest of Cairo, between
latitudes 29ı and 30ı N and longitudes 30ı and 31ı 200 E (Figure 1). The purpose of
this work is concerned on the study and integration of the lithostratigraphic models by
constructing isopach and lithofacies maps, to identify the various implicated basins, and
to assess the depositional environments. Also, organo-geochemical characteristics need
to be known for the source rocks of some Jurassic and Cretaceous units to identify the
organic richness, types of organic matter, and thermal maturation.
The geochemical characteristics of the Jurassic and Cretaceous source rocks in the
North Western Desert have been discussed by many authors including: Zein El Din and
El Hamzy (1980), Parker (1982), Awad (1984), Shahin et al. (1987), Hammad (1988),
Shahin and Shehab (1988), Abd El Aal et al. (1990), Abd El Aziz (1994), Nemec (1996),
Tammam (1996), Abd El Aziz et al. (1998), El Nady and Hammad (2000), El Nady
(2001), Sharaf and El Nady (2003), and others.
Address correspondence to Mohamed M. El Nady, Exploration Department, Egyptian Petro-leum Research Institute, Nasr City, Hai Al-Zehour, Cairo 11727, Egypt. E-mail: [email protected]
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Figure 1. Location map of the investigated wells in the West Qarun area, Egypt.
Materials
The fundamental materials which applied in this work include “7” composite logs and
“78” ditch samples, which were collected from seven wells (Wadi Rayan-1x, Gindi Deep-
1x, North Qarun-1x, El Sagha-1A, E.WD19-1x, Gebel Rissu-1, and Kattaniya) (Figure 1).
These samples are representative of Middle Jurassic (Khatatba Formation), Lower Creta-
ceous (Alam El Bueib and Kharta formations), and Upper Cretaceous (Bahariya and Abu
Roash formations) (Figure 2). The logs and samples were supplied by Qarun Petroleum
Company after General Egyptian Petroleum Corporation (EGPC) approval.
Methodology
1. Regional lithostratigraphic and simplified structural cross sections were con-
structed to illustrate the different rock units and structural configuration between
the wells.
2. Isopach and lithofacies maps were established to show the thickness and facies
variation of different rock units in the study area.
3. The ditch samples were thoroughly washed in cold water for removal of any
contaminations. The washed samples were then air dried at room temperature to
prevent any loss of “free hydrocarbons” and subsequently crushed to a homoge-
nous powder and bagged for the pyrolysis analyses by using Rock Eval 6 Model,
carried out in the laborites of the Egyptian Petroleum Institute.
Results and Discussion
Lithostratigraphic Cross Section
The lithostratigraphic cross section (Figure 3) shows that the Jurassic rock units (Wadi
El Natrun, Khatatba, and Masajid formations), as well as the Lower Cretaceous rock
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Source Rocks Characteristics 1887
Figure 2. Generalized stratigraphic column of the West Qarun area, Egypt.
units (Alamein and Alam El Bueib formations), are not easy to correlate. The Upper
Cretaceous rock units (Kharita, Bahariya formations, and Abu Roash members) are good
correlated (Figure 3), where they are well represented in all the studied wells. In Gebel
Rissu-1 well, the thickness of the Upper Cretaceous rock units decrease, which may be
due to an uplift taking place during the deposition followed by erosion leading in the
same time to disappearance of Abu Roash, Khoman formations, and Tertiary rock units
in the western part of the study area. Toward the east in North Qarun-1x, El Sagha-1A,
and E.WD19-1x wells the drilling stopped at Kharita Formation and the wells describe
nearly a complete sequence of rock units from Cretaceous to Tertiary rocks. The Kharita,
Bahariya, Abu Roash, Khoman, Appolonia, Dabaa, and Moghra formations are well
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Figure 3. Lithostratigraphic cross section through wells Kattaniya-1x, Gebel Rissu-1x, North
Qarun-1x, El Sagha-1A, and E.WD19-1x in the West Qarun area, Egypt.
represented with increasing thickness toward the east direction (Figure 3). On the other
hand, these formations show a noticeable decrease in their thickness in the west direction
at Gebel Rissu-1 and Kattaniya-1 wells. This may be due to the tectonic regime prevailing
in the area.
Structural Cross Sections
The structural cross section takes the orientation W-E direction (Figure 4) and shows
that several faults take place in the West Qarun area which have directions NE-SW and
NW-SE confirmed by EGPC (1992) as in Kattaniya horst and the direction NW-SE near
the Gindi basin. The fault between well Kattaniya-1 and Gebel Rissu-1 (F1) affects the
Jurassic and Lower Cretaceous rock units and die through the upper rock units with a
downthrow towards the SW direction. The fault (F2) takes place near Gebel Rissu-1 well
with NW-SE direction and appears to affect the rock units from Kharita Formation toward
the upper rock units. As a result of it there is uplift in the area resulting the removal of
the Late Cretaceous rock units from Abu Roash “E” Member upward. The third fault (F3)
oriented toward NW-SE direction between wells El Sagha-1A and E.WD19-1x forming
the uplift of the Late Cretaceous rock units toward the NW direction.
Isopach and Lithofacies Maps
The isopach map of Kharita Formation (Figure 5A) shows the increase in its thickness
from east to west direction. Also, it reflects two main sub-basins of deposition. The first
one occupies the western part at Kattaniya-1 well with maximum thickness reaching
1,780 m. The second depocenter locates at the central part around El Sagha-1A well
(697 m). Moreover, there is a remarkable thinning of this formation towards the eastern
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Source Rocks Characteristics 1889
Figure 4. Simplified structural cross section through wells Kattaniya-1x, Gebel Rissu-1x, North
Qarun-1x, El Sagha-1A, and East WD19-1x in the West Qarun area, Egypt.
part of the study area, where its thickness reaches to zero at Gindi Deep-1x well. This
may be due to the uplifting followed by erosion of Kharita Formation at this area or may
be tectonically high and not received any material of sedimentation. Furthermore, the
intensive contour lines at the northwestern part of the study area indicates the occurrence
of subsidence movement of this part leading to the main depocenter of deposition. The
shale percentage map (Figure 5B) exhibits two areas of high shale content. The first is
the central part around El Sagha-1A well (51%). The second is toward the west around
Kattaniya-1 well (27%). This indicates that the shale percentage of the Kharita Formation
increases gradually toward the northern part of the study area and completely disappears
toward the east around Gindi Deep-1x well. The sandstone percentage map (Figure 5C)
shows an increase in sandstone content gradually from east direction at Gindi Deep-1x
area towards the northeastern part at E.WD19-1x well (84%) and to the southern parts of
the study area at Wadi Rayan-1x well (87%). These facies reflect the fluvio-deltaic shallow
marine environment. On the other hand, the intensive gradient between North Qarun-1x
and El Sagha-1A wells (Figure 5B and C) reflects the synchronous sedimentation during
the deposition of this formation.
The isopach map of Bahariya Formation (Figure 6A) shows a remarkable thickening
toward the northeast direction where its thickness reaches a maximum value at E.WD19-
1x well (600 m). The thinning is recorded toward the north direction in the vicinity of
Gebel Rissu-1 well (123 m). This map exhibits one basin of deposition that occupies the
northeast part around E.WD19-1x well.
The shale percentage map of the Bahariya Formation (Figure 6B) shows a general
increase in shale content from the south at Wadi Rayan-1x well (23%) to the northwestern
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Figure 5. Isopach (A), shale percentage (B), and sandstone percentage (C) maps of Kharita
Formation in the West Qarun area, Egypt.
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Figure 6. Isopach (A), shale percentage (B), and carbonate percentage (C) maps of Bahariy
Formation in the West Qarun area, Egypt.
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1892 M. M. Hammad et al.
part of the study area around Kattaniya-1 well (66%). The intensive gradient in contour
lines between Kattaniya-1 and Gebel Rissu-1 wells in the northwestern part reflects the
syndepositional subsiding, which occurred with the uplifting of the eastern and southern
part of the study area. The carbonate percentage map (Figure 6C) exhibits three areas
with high carbonate contents. The first one is located in the southern part at Wadi Rayan-
1x well (32%), the second is located in the central northern part around North Qarun-1x
(24%), and the third is located around E.WD19-1x well (22%) at the northeastern part
of the area. The low content of the carbonate facies occupies the eastern part around
Gindi Deep-1x well and Kattaniya-1 well in the northwestern part of the study area. The
distribution of shale and carbonate contents reveal shallow marine environments of the
Bahariya Formation.
The isopach map of Abu Roash “G” Member (Figure 7A) reflects an increase in the
thickness gradually from the east at E.WD19-1x well (79 m) to the western part of the
study area around Gebel Rissu-1 well. This thickness shows that the main depocenter
of Abu Roash “G” Member is located around the northwestern part of the study area at
Gebel Rissu-1 well with a maximum value reaching 412 m.
The shale percentage map of Abu Roash “G” Member (Figure 7B) shows a gradual
increase in shale content from the south to the north direction of the study area with a little
shifting towards the northeastern direction. The highest concentration of shale content
is located at El Sagha-1A well with a maximum value reaching 77%, while the lowest
content is around Wadi Rayan-1x well (48%). On the contrary, with the shale percentage
map of Abu Roash “G” Member and the carbonate percentage map (Figure 7C), there is
an obvious shifting in the locations of the high and low values (Figure 7B and 7C) where
the carbonate contents gradually increase from the northeastern part at E.WD19-1x well
(24%) to the southern part at Wadi Rayan-1x well (37%).
Organic Richness
The Khatatba Formation has total organic carbon content (TOC) values ranging from
1.29 wt% to 4.64 wt%, free hydrocarbons S1 from 0.67 to 5.54 mg/g and generating
source potential S2 from 1.93 to 8.89 mg/g (Table 1). The organic richness is rated good
to very good, except for a few samples, which are ranged from poor to good organic
richness (Figure 8A). Alam El Bueib Formation has a TOC value of 0.97 wt%, S1 is
0.16 mg/g, and S2 is 0.84 mg/g (Table 1), which reflects source rocks of poor to fair
organic richness (Figures 8A–8C). Kharita Formation has organic richness varying from
poor to good (Figures 8A–8C) with TOC values ranging from 0.6 to 1.32 wt%, S1 from
0.11 to 2.83 mg/g, and S2 from 0.43 to 5.24 mg/g (Table 1).
The Upper Cretaceous Bahariya Formation has TOC values ranging from 0.52 to
0.99 wt%, S1 and S2 from 0.06 to 0.55 mg/g and 0.35 to 3.59 mg/g, respectively (Table 1
and Figures 8A–8C). Abu Roash “G” Member has TOC values ranging from 0.56 to 1.06
wt%, S1 from 0.05 to 0.55 mg/g, and S2 from 0.49 to 2.97 mg/g (Table 1), indicating
poor to fair source rocks (Figures 8A and 8B). Abu Roash “F” Member has organic
richness varying from poor to very good. This conclusion is indicated by TOC, S1, and
S2 values ranging from 1.29 to 2.15, 0.05 to 0.55, and 2.74 to 9.8, respectively (Table 1
and Figures 8A–8C). Abu Roash “E” Member is characterized by TOC values range from
0.51 to 1.52 wt%, S1 from 0.06 to 0.26 mg/g, and S2 from 0.28 to 3.55 mg/g (Table 1)
revealing poor to fair organic richness (Figures 8A–8C). Also, Abu Roash “D”, “C”, “B”,
and “A” member have nearly the same characters. The TOC, S1, and S2 values range
from 0.55 to 0.78 wt%, 0.06 to 0.30 mg/g, and 0.35 to 3.63 mg/g, respectively (Table 1)
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Source Rocks Characteristics 1893
Figure 7. Isopach (A), shale percentage (B), and carbonate percentage (C) maps of Abu Roash
“G” Member in the West Qarun area, Egypt.
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Table 1
Geologic information and pyrolysis analysis of the studied source rock samples in the
West Qarun area, Egypt
Wells Fms
Depth,
m
TOC,
wt %
S1,
mg/g
S2 ,
mg/g
Tmax ,ıC
HI,
mg/g
OI,
mg/g PI
Kattaniya–1 Khatatba 3,090–3,332 1.29–2.34 0.67–1.24 1.93–4.39 433–443 150–203 34–55 0.22–0.26
Gebel Rissu–1 2,273–2,601 1.58–4.71 1.66–5.54 2.20–8.89 433–444 139–189 32–88 0.38–0.43
Gebel Rissu–1 *AEB 1,319 0.97 0.16 0.84 430 87 55 0.16
El Sagha–IA Kharita 2,895–3,380 0.60–0.97 0.11–0.26 0.43–1.54 427–436 59–160 78–209 0.09–0.21
Wadi Rayan–1x 2,160–2,209 0.70–0.89 0.15–0.21 0.67–0.87 431–434 75–118 75–96 0.18–0.22
Kattaniya–1 809–1,895 0.79–1.32 0.68–2.83 1.09–5.21 404–424 138–188 46–188 0.31–0.39
E. WD19–lx 3,502–3,983 0.60–0.99 0.31–0.55 1.33–4.20 419–436 222–424 92–108 0.11–0.12
Gindi Deep–lx Bahariya 3,090–3,157 0.68–0.91 0.11–0.14 0.55–0.82 434–436 80–90 78–122 0.12–0.20
El Sagha–1A 2,550–2,809 0.52–0.91 0.06–0.28 0.43–0.81 428–433 70–109 77–113 0.12–0.30
Wadi Rayan–1x 2,041–2,063 0.66–0.70 0.18–0.19 0.70–0.35 428–429 53–100 117–248 0.20–0.35
N. Qarun–lx 2,803 0.57 0.06 0.44 434 77 146 0.12
E. WD19–lx �A/R “G” 4,328 0.85 0.25 1.98 426 233 105 0.11
Gindi Deep–lx Mb. 2,739–2,773 0.67–0.72 0.05 0.49–0.52 431–433 72–73 82 0.09
El Sagha–IA 2,142–2,355 0.79–0.83 0.26–0.55 1.13–1.49 425–428 138–189 61–89 0.16–0.29
Wadi Rayan–1x 1,813–2,352 0.56–1.06 0.06–0.36 0.60–2.97 423–435 107–280 80–233 0.08–0.32
E. WD19–lx A/R “F” 3,383 1.29 0.23 2.74 429 212 72 0.08
El Sagha–1A Mb. 2,078–2,099 1.85–2.15 0.24–0.67 8.58–9.80 418–421 399–464 51–57 0.03–0.07
N. Qarun–lx 2,117 1.64 0.27 6.92 422 422 59 0.04
E. WD19–lx A/R “E” 3,197–3,297 1.01–1.38 0.20–0.26 2.08–3.55 428–429 206–257 124–149 0.07–0.09
Gindi Deep–Ix Mb. 2,517–2,584 0.96–1.52 0.06–0.15 0.64–1.62 430–434 67–107 30–78 0.05–0.09
El Sagha–IA 1,849–1,983 0.52–0.81 0.13–0.24 0.28–0.56 423–429 34–69 135–179 0.21–0.43
Wadi Rayan–1x 1,648 0.60 0.18 0.42 425 70 193 0.30
N. Qarun–1x 2,078 0.64 0.11 0.35 429 55 163 0.24
Wadi Rayan–1x A/R “D” 1,517 0.55 0.23 0.63 424 115 218 0.27
Mb.
Gindi Deep–lx A/R “C” 2,328 0.61 0.06 1.93 426 316 85 0.03
Wadi Rayan–1 Mb. 1,438 0.63 0.30 0.80 426 127 183 0.27
El Sagha–1A A/R “B” 1,532 0.78 0.09 0.35 426 45 38 0.20
Mb.
E. WD19–lx A/R “A” 2,392 0.70 0.09 3.63 421 519 83 0.02
Mb.
TOC: Total organic carbon in weight percent; S1 : Free hydrocarbons percent in the rock (mg HC/g rock); S2 : Residual
petroleum potential (mg HC/g rock); Tmax: Temperature at which maximum emission of high temperature (S2) hydrocarbons
occurs (ıC). HI: Hydrogen Index (mg HC/g TOC); OI: Oxygen Index (mg CO2 /g TOC); PI: Production Index (S1=S1 C S2).�AEB: Alam El Bueib Formation; *A/R: Abu Roash members.
and indicate that the organic richness of these members have poor to fair source rock
(Figures 8A–8C).
Genetic Type of Organic Matter
In this study, the hydrogen index (HI) values of the Khatatba Formation range from 139 to
203 mg/g and oxygen index (OI) from 32 to 88 mg/g (Table 1). These data reflect that the
main expected kerogen type is III/II (mixed type) as shown in the modified Van Krevelen
diagram (Figure 9). On the contrary, Alam El Bueib, Kharita, and Bahariya formations
have source rocks capable of producing mainly gas (type III kerogen) (Figure 9), where
the majority of the samples (HI) values are less than 150 mg/g (i.e., 87 for Alam El Buieb
Formation, 59 to 147 mg/g for Kharita Formation, and 53 to 109 mg/g for Bahariya
Formation, Table 1), except some samples from Kharita and Bahariya formations have
hydrocarbon potentiality to produce mixed oil and gas (Figure 9) where hydrogen index
values range from 160 to 225 and 222 to 424 mg/g, respectively (Table 1). On the other
hand, the hydrogen index and oxygen index values of Abu Roash Formation (“G” to “A”
members) range from 34 to 519 and 30 to 248 mg/g, respectively (Table 1). This data
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Source Rocks Characteristics 1895
Figure 8. Organic richness of the studied formations and members as indicated by TOC, S1, and
S2 (Peters, 1986) in the West Qarun area, Egypt. (Source: Peters, 1986.)
Figure 9. Organic matter types of the studied formations and members as indicated by oxygen
index and hydrogen index (Espitalie et al., 1977) in the West Qarun area, Egypt. (Source: Espitalie
et al., 1977.)
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reflects that the source rocks of Abu Roash members have the capability to generate
mixed oil and gas (Figure 9). Some samples of Abu Roash “F” Member have HI and OI
values of 212 to 472 mg/g and 51 to 72 mg/g, respectively, at depth 2,078 to 3,383 m
(Table 1) indicating source rocks have a capability for generating oil (Figure 9).
Thermal Maturation
The thermal maturity level of the source rocks has been determined by Rock-Eval
temperature pyrolysis Tmax and production index (Peters, 1986).
The Middle Jurassic Khatatba Formation has Tmax values ranging from 433ıC to
444ıC and a production index of 0.22 to 0.43 (Table 1) indicating mature source rocks,
where the majority of all samples lie within the oil generation stage (Figures 10A and
10B), except two samples have Tmax values of 433ıC (Table 1) and revels marginally
mature (Figure 10A). The relation between Tmax and hydrogen index (Figure 11) confirms
this conclusion.
The Lower Cretaceous source rocks (Alam El Bueib and Kharita formations) have
Tmax ranging from 417ıC to 436ıC, and PI from 0.09 to 0.48 (Table 1) reveals immature
to marginally mature stage (Figures 10A and 10B) except some samples from Kharita
Formation have production index values ranging from 0.45 to 0.48 (Table 1) indicating
mature source rocks where they lie within oil and gas generation stage (Figure 10B).
Furthermore, the relation between hydrogen index and Tmax values (Figure 11) shows
that the organic matter of these formations varies from marginally mature to mature.
Figure 10. Maturation of the studied froformations and members as indicated by Tmax and PI in
the West Qarun area, Egypt.
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Source Rocks Characteristics 1897
Figure 11. Tmax vs. hydrogen index (Espatelie et al., 1985) showing maturity of organic matter
in the studied froformations and members in the West Qarun area, Egypt. (Source: Espitalie et al.,
1985.)
On the other hand, the Upper Cretaceous rock units were characterized by Tmax values
ranging from 419ıC to 436ıC for Bahariya Formation and from 418ıC to 435ıC for Abu
Roash members (Table 1). These data indicate that the Upper Cretaceous formations have
source rocks varying from immature to marginally mature (Figure 10A). This conclusion
is enhanced by the cross plot of production index (PI) and depth (Figure 10B) and the
cross plot of the pyrolysis Tmax and HI (Figure 11).
Conclusions
1. The lithostratigraphic cross sections revealed that the Jurassic rock units are not
correlated, while the Upper Cretaceous rock units are well correlated.
2. Structural cross sections reflected three main faults that affect the Jurassic and
Cretaceous rock units in NE-SW and NW-SE direction and NNE-SSW and NW-
SE directions.
3. The isopach and lithofacies maps showed that Kharita Formation has increased
in thickness from east to west and deposited in fluvio-deltaic shallow marine
environment. Bahariya Formation shows thickening toward the northeast direction,
and deposited in shallow marine environment. Abu Roash “G” Member shows
thickening toward the central part and deposited in marine environments.
4. The geochemical data reflected that Middle Jurassic source rocks are mature
and have good to very good organic richness with mixed kerogen type (III/II).
The Lower Cretaceous source rocks vary from poor to fair in Alam El Buieb
Formation and from poor to good in Kharita Formation with mixed oil and gas.
The Upper Cretaceous has poor to good organic richness except in the Abu
Roash “F” Member, which has poor to very good. The Cretaceous source rocks
are immature to marginally mature in the study area.
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Acknowledgments
The authors are grateful to the authorities of the Egyptian General Petroleum Corporation
(EGPC) and Qarun Petroleum Company for providing the composite logs and ditch
samples needed for permitting publication of this work.
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