PowerPoint 2


( e V
(1.68×10-27 kg)
L: 2s, 2p, (1+3)×2=8
M: 3s, 3p, 3d, (1+3+5)×2=18
N: 4s, 4p, 4d, 4f, (1+3+5+7)×2=32
1.
M 3s 3p 3d
Q. 3
M 3s 3p 3d
web

6

11
λ = 2
(2 − 2)
n = 2, m = 3, 4, 5, 6b = 364.6, 364.6, 364.6, 364.5 nm
λ = /
(R∞ )

(2)
14

− 2
2
2
2 +
2
2 +
2
2 , , + (, , ) , , = , ,
= − 1
(e
/ 3 )
r ()
20
R2,0 = 1/2 2 /0 3/2 2 − /0 −/20
R2,1 =1/2 6 /0 3/2 /0 −/20
R3,0 =2/81 3 /0 3/2 27 − 18/0 + 222/0
2 −/30
2 −/30
2 −/30
R2,0 = 1/2 2 /0 3/2 2 − /0 −/20
R2,1 =1/2 6 /0 3/2 /0 −/20
R3,0 =2/81 3 /0 3/2 27 − 18/0 + 222/0
2 −/30
2 −/30
2 −/30
Q.
i/ 2(Y1,1+Y1,-1 )=1/2 3/π (y/r)
Y2,0 = 15/16π(3z2−r2)/r2
i/ 2(− Y2,2+Y2,-2 ) = 15/4π xy/r2
i/ 2(Y2,1+Y2,-1 ) = 15/4π yz/r2
1/ 2(− Y2,1+Y2,-1 ) = 15/4π zx/r2
Yl,m (=Ψ)
(
( e V
( e V
K Ca
0.50 0.02


0.98 1.57 2.04 2.55 3.04 3.44 3.98
Na Mg Al Si P S Cl Ar
1.21 1.63 1.37 2.03 2.39 2.65 3.54 3.36
0.93 1.31 1.61 1.9 2.19 2.58 3.16
K Ca
1.03 1.3
0.82 1.00
30


2

0.98 1.57 2.04 2.55 3.04 3.44 3.98
Na Mg Al Si P S Cl Ar
1.21 1.63 1.37 2.03 2.39 2.65 3.54 3.36
0.93 1.31 1.61 1.9 2.19 2.58 3.16
K Ca
1.03 1.3
0.82 1.00
Q1. 2
Q5. sp21
Q6. M// 32