Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Report Title Air Emissions Compliance Monitoring Emissions Report
Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre,
Caherdavin, Park, Ennis Road, Limerick V94 NT63.
Stack Emissions Testing Report Commissioned by Pfizer Ireland Pharmaceuticals
Facility Name The Pfizer Biotech Campus at Grange Castle
Contact Person Gerard Shannon
EPA Licence Number P0652-01
Licence Holder Pfizer Ireland Pharmaceuticals
Stack Reference Number A1-1, A1-2 & A1-3
Dates of the Monitoring Campaign 19-07-2016
Job Reference Number PFGRTL4190716
Report Written By Gregory Dempsey
Report Approved by Mr. Mark McGarry
Stack Testing Team Mr. David Noonan
Report Date 09-08-2016
Report Type Test Report Compliance Monitoring
Version 1
Signature of Approver Operations Manager
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Opinions and interpretations expresses herein will be outside the scope of Air Scientific Limited INAB accreditation. This test report shall not be reproduced, without the written approval of Air Scientific Limited.
All sampling and reporting is completed in accordance with Environmental Protection Agency Air Guidance Note 2 requirements.
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Executive Summary
Monitoring Objectives
Overall Aim of the monitoring Campaign
The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values as specified in the site licence.
Special Requirements There were no special requirements.
Target Parameters
Total Particulate Matter (TPM)
Oxides of Nitrogen (NOx) as NO2
Sulphur Dioxide (SO2)
Volumetric Flow Rates (m3.hr-1)
Emission Limit Values
A1-1 mg.m-3
TPM 5
NOx as NO2 75
SO2 35
Volume (m3.hr-1) 13,755
Reference Conditions
Reference Conditions Value
Oxygen Reference % 3
Temperature K 273.15
Total Pressure kPa 101.3
Moisture % Dry
Emission Limit Values
A1-2 mg.m-3
TPM 5
NOx as NO2 75
SO2 35
Volume (m3.hr-1) 13,755
Reference Conditions
Reference Conditions Value
Oxygen Reference % 3
Temperature K 273.15
Total Pressure kPa 101.3
Moisture % Dry
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Emission Limit Values
A1-3 mg.m-3
TPM 5
NOx as NO2 75
SO2 35
Volume (m3.hr-1) 13,755
Reference Conditions
Reference Conditions Value
Oxygen Reference % 3
Temperature K 273.15
Total Pressure kPa 101.3
Moisture % Dry
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Executive Summary
Overall Results
A1-1 Concentration
Parameter Units Result MU +/- Limit Compliant
Total Particulate Matter (TPM) mg.m-3 <0.96 0.51 5 Yes
Oxides of Nitrogen (NOx) as NO2 mg.m-3 32.6 3.3 75 Yes
Sulphur Dioxide (SO2) mg.m-3 <6.1 9.2 35 Yes
Volumetric Flow Rate (Ref.) m3.hr-1 6,526 0.64m.s-1 13,755 Yes
A1-2 Concentration
Parameter Units Result MU +/- Limit Compliant
Total Particulate Matter (TPM) mg.m-3 <2.62 0.65 5 Yes
Oxides of Nitrogen (NOx) as NO2 mg.m-3 55.5 4.8 75 Yes
Sulphur Dioxide (SO2) mg.m-3 <6.1 7.6 35 Yes
Volumetric Flow Rate (Ref.) m3.hr-1 5,671 2.72m.s-1 13,755 Yes
A1-3 Concentration
Parameter Units Result MU +/- Limit Compliant
Total Particulate Matter (TPM) mg.m-3 <0.56 0.50 5 Yes
Oxides of Nitrogen (NOx) as NO2 mg.m-3 45.2 4.7 75 Yes
Sulphur Dioxide (SO2) mg.m-3 <6.1 9.5 35 Yes
Volumetric Flow Rate (Ref.) m3.hr-1 6,579 2.25m.s-1 13,755 Yes
Blank for 19-07-16 Concentration
Parameter Units Result ELV <10% of ELV
Compliant
Total Particulate Matter (TPM) mg.m-3 <0.56 5 No*
*Note: Blank >10% of ELV due to extremely low Emission Limit. No dust was detected on the blank sample.
Accreditation details
Air Scientific Limited INAB Number: 319T
External Analytical Laboratory Accreditation number: UKAS 1549
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Executive Summary
Process details
Stack Name A1-1
Process status Normal
Capacity (per/hour) (if applicable) Variable
Continuous or Batch Process Continuous
Feedstock N/a
Abatement System No
Abatement Systems Running Status N/a
Fuel Natural Gas
Plume Appearance No
Other information N/a
Stack Name A1-2
Process status Normal
Capacity (per/hour) (if applicable) Variable
Continuous or Batch Process Continuous
Feedstock N/a
Abatement System No
Abatement Systems Running Status N/a
Fuel Natural Gas
Plume Appearance No
Other information N/a
Stack Name A1-3
Process status Normal
Capacity (per/hour) (if applicable) Variable
Continuous or Batch Process Continuous
Feedstock N/a
Abatement System No
Abatement Systems Running Status N/a
Fuel Natural Gas
Plume Appearance No
Other information N/a
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Executive Summary
Monitoring, Equipment & Analytical Methods
Parameter Standard Technical Procedure
Accredited Testing
Analytical Technique
Equipment / Media
Equipment ID Used on Site
Total Particulate Matter (TPM)
EN13284 -1:2002
2000 Yes Gravimetric Isokinetic
Equipment
ASLLK12EQ525 ASLLK12EQ527 ASLLK13EQ503 ASLLK13EQ504 ASLLK13EQ506 ASLLK13EQ508 ASLLK14EQ503 ASLLK14EQ510 ASLLK14EQ513 ASLLK16EQ503
Oxides of Nitrogen (NOx) as NO2
EN14792:2006 2002 Yes Chemiluminescence Horiba
Sulphur Dioxide (SO2)
NDIR AG2 2003 Yes Non Dispersive
Infra Red Horiba
Oxygen (%) EN14789 2008 Yes Paramagnetic/
Zirconia Horiba
Stack Gas Temperature
EN 16911:2013 2005 Yes Thermocouple Thermocouple
Stack Gas Velocity
EN 16911:2013 2005 Yes Pitot tubes Meter / Pitot
Volumetric Flow Rate
EN 16911:2013 2005 Yes Manometer / Pitot /
Calculation
Manometer / Pitot /
Calculation
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Sampling Deviations
Parameter: A1-1 Deviation
EN13284 -1:2002 One port available.
EN14792:2006 None
NDIR AG2 Uncertainty >10% due to low concentrations in the
gas and low ELV
EN14789 None
EN 16911:2013 One port available. Flow Rates - in accordance
with MID 6911-1
Parameter: A1-2 Deviation
EN13284 -1:2002 One port available. Differential Pressure <5Pa.
Ratio of flow >3:1. Constant flow used.
EN14792:2006 None
NDIR AG2 Uncertainty >10% due to low concentrations in the
gas and low ELV
EN14789 None
EN 16911:2013
One port available. Differential Pressure <5Pa. Ratio of flow >3:1.Flow uncertainty >10%.Flow. Constant Flow used. Rates - in accordance with
MID 6911-1
Parameter: A1-3 Deviation
EN13284 -1:2002 One port available.
EN14792:2006 None
NDIR AG2 Uncertainty >10% due to low concentrations in the
gas and low ELV
EN14789 None
EN 16911:2013 One port available. Flow Uncertainty >10%. Flow
Rates - in accordance with MID 6911-1
Reference Documents
Risk Assessment (RA) SOP 1011
Site Review (SR) SOP 1015
Site Specific Protocol (SSP) SOP 1015
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Suitability of Sample Location
General Information A1-1
Permanent/Temporary Permanent
Inside/ Outside Inside
Platform Details
Irish EPA Technical Guidance Note AG1 / BS EN 15259 Platform Requirements
Value Comment
Sufficient Working area to manipulate probe and measuring instruments
Yes -
Platform has 2 handrails (approx. 0.5m & 1.0 m high) Yes -
Platform has vertical base boards (approx. 0.25 m high) Yes -
Platform has chains / self-closing gates at top of ladders Yes -
There are no obstructions present which hamper insertion of sampling equipment
Yes -
Safe Access Available Yes -
Easy Access Available Yes -
Sampling Location / Platform Improvement Recommendations
None
BSEN 15259 Homogeneity Test Requirements
1.
Select Option : 1: There is no requirement to perform a BSEN15259 Homogeneity Test on this stack 2: Test results were obtained from previous Homogeneity test carried out by ASL 3: Test results were obtained from previous Homogeneity test carried out by Alternative contractor 4: Homogeneity Test is required on this stack and the client has been informed of this requirement.
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Suitability of Sample Location
General Information A1-2
Permanent/Temporary Permanent
Inside/ Outside Inside
Platform Details
Irish EPA Technical Guidance Note AG1 / BS EN 15259 Platform Requirements
Value Comment
Sufficient Working area to manipulate probe and measuring instruments
Yes -
Platform has 2 handrails (approx. 0.5m & 1.0 m high) Yes -
Platform has vertical base boards (approx. 0.25 m high) Yes -
Platform has chains / self-closing gates at top of ladders Yes -
There are no obstructions present which hamper insertion of sampling equipment
Yes -
Safe Access Available Yes -
Easy Access Available Yes -
Sampling Location / Platform Improvement Recommendations
None
BSEN 15259 Homogeneity Test Requirements
1.
Select Option : 1: There is no requirement to perform a BSEN15259 Homogeneity Test on this stack 2: Test results were obtained from previous Homogeneity test carried out by ASL 3: Test results were obtained from previous Homogeneity test carried out by Alternative contractor 4: Homogeneity Test is required on this stack and the client has been informed of this requirement.
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Suitability of Sample Location
General Information A1-3
Permanent/Temporary Permanent
Inside/ Outside Inside
Platform Details
Irish EPA Technical Guidance Note AG1 / BS EN 15259 Platform Requirements
Value Comment
Sufficient Working area to manipulate probe and measuring instruments
Yes -
Platform has 2 handrails (approx. 0.5m & 1.0 m high) Yes -
Platform has vertical base boards (approx. 0.25 m high) Yes -
Platform has chains / self-closing gates at top of ladders Yes -
There are no obstructions present which hamper insertion of sampling equipment
Yes -
Safe Access Available Yes -
Easy Access Available Yes -
Sampling Location / Platform Improvement Recommendations
None
BSEN 15259 Homogeneity Test Requirements
1.
Select Option : 1: There is no requirement to perform a BSEN15259 Homogeneity Test on this stack 2: Test results were obtained from previous Homogeneity test carried out by ASL 3: Test results were obtained from previous Homogeneity test carried out by Alternative contractor 4: Homogeneity Test is required on this stack and the client has been informed of this requirement.
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Stack Diagram
No cameras allowed on site
c. 10 m
Ports 1
c. 4 metres
Ground Level
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Stack Name
Example Note: Platform located on second platform 2 Ports 2 Lines 4 points per line
Port
Port
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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1. APPENDICES
Appendix I Monitoring Personnel & Equipment
Stack Emissions Monitoring Personnel
Team Leader Name David Noonan
System approval ASL Team Leader Approved
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Appendix II Stack Raw Data
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Title: Determination of Total Particulates Method: EN 13284-1
Test Date: 19/07/2016 Uncertainty Data Laboratory Used: SAL
Certificate Numbers: 588644-1 Temperature at Pump 24.554 Deg C
Stack Name A1-1 Pressure at Pump 76.499 kPa
Test Time 12:21:03
Air Volume at Pump 0.9494 m3
Moisture Content 11.44 % Humidity at Pumps 0 %
Reference Oxygen 3 % Filter Weight 0.3 mg
Measured Oxygen 3.9 % Front End Weight 0.3 mg
Stack Flow Rate 7759 Nm3/hr Adjusted Stack Flow Rate 6526 Nm3/hr, dry @ % Oxygen
Volume of Air Sampled 0.6579 Nm3
Balance Calibration Weight 500.0 500.0 g
1000.0 1000.0 g
Impinger Weights Initial Final Difference 1 470.2 506.6 36.4 2 461 471 10 3 365 369.3 4.3 4 613.9 631.5 17.6 Volume of Air Sampled 0.6579 Nm3 68.3 Moisture Content (EN 14790) 11.44 %
Leak Check Results Result
% Leak
Before Blank 0 l/min 0.0 After Blank 0 l/min 0.0 Before Sample 1 0 l/min 0.0 After Sample 1 0 l/min 0.0 Average Flow Rate 21.785 l/min 0.0 Standard Maximum 0.4357 l/min 2% Back Pressure 69 kPa
Standard Criteria to be Met Result Standard Requirement
Angle of Flow Pass <15 Degrees Negative Flow in the Stack Pass None Pitot Pressure Difference Pass >5Pa Ratio of Flow Measurement Pass <3:1 Stagnation Test Pass <10Pa Pitot Tube Leak Check Result
Positive Pressure Pass - Negative Pressure Pass - Number of Ports 1 2 Straight length before sample point Pass > 5 Hydraulic Diameters
Straight length after sample point Pass > 5 Hydraulic Diameters
Sample Calculations Blank (Filter and Front Wash Combined) 0.35 mg
Sample 1 (Filter and Front Combined) 0.6 mg Volume of Air Sampled 0.6579 Nm3 Blank Result 0.53 mg/Nm3, dry 0.56 mg/Nm3, dry @ Ref O2
Sample Result 0.91 mg/Nm3, dry 0.96 mg/Nm3, dry @ Ref O2
Uncertainty of Measurement 0.51 mg/Nm3 Emission Limit Value 5 mg/Nm3, dry @ Ref O2
Blank as Percentage of ELV 11.2 % Standard Requirement <10% ELV
Isokinetic Criterion Compliance Isokinetic Variation % 0
Allowable Isokinetic Range % From - 5 to + 15 Isokinetic Acceptable - Yes
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Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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DUCT AND GAS SPECIFICATION Name
PFIZER.A1.1
Section
Circular
Diameter
[m] 1.035
Area
[m2] 0.841
Port B [#] 1
Points P [#] 8
Density ρn [kg/m3] 1.317
Carbon dioxide CO2 [%] 8.6
Oxygen O2 [%] 3.7
Water vapor ratio rw [0;1] 0.08
Nozzle nz [mm] 14
Turbolence factor ft [sec] 9
DUCT FLOW RATE Dry actual QVa [m3/h] 10497
Moist actual Q'Va [m3/h] 11412
Moist standard [Tnorm Pnorm] Q'Vn [m3/h] 7759
Dry standard [Tnorm Pnorm] QVn [m3/h] 7138
AVERAGE VALUES Total Points
[#] 1
Velocity v'a [m/sec] 3.768
Stack temperature ta [°C] 124.071
Stack Static Pressure Pastatic [kPa] 100.178
Isokinetic Deviation DI [%] 0
Velocity at nozzle v'N [m/sec] 3.77
Probe temperature tprobe [°C] 25.689
Box temperature tbox [°C] 25.983
Aux1 temperature taux1 [°C] 35.862
Aux2 temperature taux2 [°C] 24.87
Stack Differential Pitot Pressure dPpitot [Pa] 8.318
Ambient Pressure Pamb [kPa] 100.271
SAMPLED VOLUMES Elapsed time et [hh:mm:ss] 00:30:00
Total encoder impulses
[#] 18988
Standard Volume [Tnorm Pnorm] Vgn [m3] 0.6579
Moist Volume at stack conditions V'ga [m3] 0.7912
Volume at dgm conditions Vdgm [m3] 0.9494
Gas meter temperature tgm [°C] 24.554
Gas Meter Pressure Pdgm [kPa] 76.499
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start ts Port Point Distance Elapsed
Time rw avg tfumes avg Pa avg
dP pitot avg
[timestamp] [###] [###] [cm] [hh:mm:ss] [0;1] [°C] [kPa] [Pa]
19/07/2016 1 1 3.4 00:01:00 0.08 125.159 100.197 11.053 12:06:21
19/07/2016 1 2 10.9 00:01:00 0.08 123.005 100.193 10.732 12:07:22
19/07/2016 1 3 20.1 00:01:00 0.08 125.651 100.198 11.248 12:08:30
19/07/2016 1 4 33.5 00:01:00 0.08 128.033 100.202 12.769 12:09:31
19/07/2016 1 5 70.1 00:01:00 0.08 128.877 100.195 13.293 12:10:32
19/07/2016 1 6 83.5 00:01:00 0.08 129.542 100.19 12.72 12:11:32
19/07/2016 1 7 92.7 00:01:00 0.08 129.578 100.181 10.742 12:12:35
19/07/2016 1 8 100.2 00:01:00 0.08 128.828 100.185 9.621 12:13:41
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
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Title: Determination of Combustion Flue Gases Method: EN 14792 / EN 14789 / EN 12039 / TGN M21 Test Date: 19/07/2016
Stack Name A1-1
Reference Conditions Measured Oxygen 3.9 %
Reference Oxygen 3 %
Parameter
NO SO2 O2 Emission Limit Values mg.m-3 ref
75 35
Instrument Range ppm
500 1000 25 Span Gas Value ppm
305 630 20.9
Acceptable Gas Range -
Yes Yes Yes Calibration Gas Uncertainty %
0.6 0.8 0.5
Quality Assurance Units Conditioning Unit Temperature C
2 2 2 Average Temperature < C
2 2 2
Allowable Temperature -
4 4 4 Temperature Acceptable -
Yes Yes Yes
Pump flow rate l/min.
0.5 0.5 0.5
Zero Drift Units Zero (Pre) ppm
0 -1 0 Zero (Post) ppm
-0.5 -3 0
Zero drift ppm
-0.5 -2 0 Allowable Zero Drift (Less than) ppm
6.1 12.6 0.418
Adjustable Zero Drift (Less than) ppm
15.25 31.5 1.045 Zero Drift Failure (Greater than) ppm
15.25 31.5 1.045
Zero Drift Acceptable -
Yes Yes Yes
Span Drift Units Span Down (Pre) ppm
304 628 20.9 Span Down (Post) ppm
303 625 20.8
Span Drift ppm
-1 -3 -0.1 Allowable Span Drift (less than) ppm
6.1 12.6 0.418
Adjustable Span Drift (Less than) ppm
15.25 31.5 1.045 Span Drift Failure (Greater than) ppm
15.25 31.5 1.045
Span Drift Acceptable (Y/N) -
Yes Yes Yes
Leak Check Span Gas Conc. ppm
305 630 20.9
Recorded Conc. down Line ppm
304 628 20.9 Leak Detected ppm
-1 -2 0
Leak check acceptable (< 2%) ppm
6.1 12.6 0.418 Pass (Y/N)
Yes Yes Yes
Test Conditions Units Run Ambient Temperature Range C
25.6 25.6 25.6
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Raw Data
Date/Time Data source
NOx O2 SO2
ppm vol% ppm
19/07/2016 11:09
14.9 5.3 <6.1 19/07/2016 11:10
15.7 4.1 <6.1 19/07/2016 11:11
15.6 3.6 <6.1 19/07/2016 11:12
15.8 3.1 <6.1 19/07/2016 11:13
15.6 2.9 <6.1 19/07/2016 11:14
15.5 3.1 <6.1 19/07/2016 11:15
15.2 3.4 <6.1 19/07/2016 11:16
15.6 2.7 <6.1 19/07/2016 11:17
15.6 2.6 <6.1 19/07/2016 11:18
16.2 2.6 <6.1 19/07/2016 11:19
16.3 2.7 <6.1 19/07/2016 11:20
15.3 3.5 <6.1 19/07/2016 11:21
14.7 4.2 <6.1 19/07/2016 11:22
14.2 4.8 <6.1 19/07/2016 11:23
14.3 4.8 <6.1 19/07/2016 11:24
14.6 4.8 <6.1 19/07/2016 11:25
14.5 5.0 <6.1 19/07/2016 11:26
14.5 4.9 <6.1 19/07/2016 11:27
14.5 4.5 <6.1 19/07/2016 11:28
14.4 4.5 <6.1 19/07/2016 11:29
14.8 4.0 <6.1 19/07/2016 11:30
14.8 3.9 <6.1 19/07/2016 11:31
14.6 4.4 <6.1 19/07/2016 11:32
14.5 4.1 <6.1 19/07/2016 11:33
14.7 4.3 <6.1 19/07/2016 11:34
14.6 4.3 <6.1 19/07/2016 11:35
14.6 4.2 <6.1 19/07/2016 11:36
15.1 3.8 <6.1 19/07/2016 11:37
15.0 3.9 <6.1 19/07/2016 11:38
15.5 3.9 <6.1
Average
15.0 3.9 <6.1
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
21 of 33
Referenced Data
NOx SO2
mg/Nm3 Reference O2
19/07/2016 11:09
35.1 <6.1 19/07/2016 11:10
34.3 <6.1
19/07/2016 11:11
33.1 <6.1 19/07/2016 11:12
32.5 <6.1
19/07/2016 11:13
31.9 <6.1 19/07/2016 11:14
32.1 <6.1
19/07/2016 11:15
31.9 <6.1 19/07/2016 11:16
31.5 <6.1
19/07/2016 11:17
31.2 <6.1 19/07/2016 11:18
32.5 <6.1
19/07/2016 11:19
33.0 <6.1 19/07/2016 11:20
32.2 <6.1
19/07/2016 11:21
32.2 <6.1 19/07/2016 11:22
32.5 <6.1
19/07/2016 11:23
32.5 <6.1 19/07/2016 11:24
33.4 <6.1
19/07/2016 11:25
33.5 <6.1 19/07/2016 11:26
33.3 <6.1
19/07/2016 11:27
32.4 <6.1 19/07/2016 11:28
32.2 <6.1
19/07/2016 11:29
32.1 <6.1 19/07/2016 11:30
31.9 <6.1
19/07/2016 11:31
32.5 <6.1 19/07/2016 11:32
31.8 <6.1
19/07/2016 11:33
32.3 <6.1 19/07/2016 11:34
32.3 <6.1
19/07/2016 11:35
32.3 <6.1 19/07/2016 11:36
32.4 <6.1
19/07/2016 11:37
32.4 <6.1 19/07/2016 11:38
33.4 <6.1
Average
32.6 <6.1 Uncertainty of Measurement
3.3 9.2
Uncertainty as % of ELV
4.35 26.33 Standard Requirement
<10% <10%
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
22 of 33
Title: Determination of Total Particulates Method: EN 13284-1
Test Date: 19/07/2016 Uncertainty Data Laboratory Used: SAL
Certificate Numbers: 588644-1 Temperature at Pump 25.987 Deg C
Stack Name A1-2 Pressure at Pump 80.162 kPa
Test Time 13:21:36
Air Volume at Pump 0.7875 m3
Moisture Content 11.50 % Humidity at Pumps 0 %
Reference Oxygen 3 % Filter Weight 1 mg
Measured Oxygen 5.3 % Front End Weight 0.3 mg
Stack Flow Rate 7352 Nm3/hr Adjusted Stack Flow Rate 5671 Nm3/hr, dry @ % Oxygen
Volume of Air Sampled 0.5690 Nm3
Balance Calibration Weight 500.0 500.0 g
1000.0 1000.0 g
Impinger Weights Initial Final Difference 1 506.6 542.7 36.1 2 471 478.2 7.2 3 369.3 372.5 3.2 4 631.5 644.4 12.9 Volume of Air Sampled 0.5690 Nm3 59.4 Moisture Content (EN 14790) 11.50 %
Leak Check Results Result
% Leak
Before Blank 0 l/min 0.0 After Blank 0 l/min 0.0 Before Sample 1 0.2 l/min 1.1 After Sample 1 0.2 l/min 1.1 Average Flow Rate 18.887 l/min 1.1 Standard Maximum 0.37774 l/min 2% Back Pressure 69 kPa
Standard Criteria to be Met Result Standard Requirement
Angle of Flow Pass <15 Degrees Negative Flow in the Stack Pass None Pitot Pressure Difference No >5Pa Ratio of Flow Measurement No <3:1 Stagnation Test Pass <10Pa Pitot Tube Leak Check Result
Positive Pressure Pass - Negative Pressure Pass - Number of Ports 1 2 Straight length before sample point Pass > 5 Hydraulic Diameters
Straight length after sample point Pass > 5 Hydraulic Diameters
Sample Calculations Blank (Filter and Front Wash Combined) 0.35 mg
Sample 1 (Filter and Front Combined) 1.3 mg Volume of Air Sampled 0.5690 Nm3 Blank Result 0.62 mg/Nm3, dry 0.71 mg/Nm3, dry @ Ref O2
Sample Result 2.28 mg/Nm3, dry 2.62 mg/Nm3, dry @ Ref O2
Uncertainty of Measurement 0.65 mg/Nm3 Emission Limit Value 5 mg/Nm3, dry @ Ref O2
Blank as Percentage of ELV 14.1 % Standard Requirement <10% ELV
Isokinetic Criterion Compliance Isokinetic Variation % -8.4
Allowable Isokinetic Range % From - 5 to + 15 Isokinetic Acceptable - Yes
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
23 of 33
DUCT AND GAS SPECIFICATION Name
PFIZER.A1.2 Section
Circular Diameter
[m] 1.035
Area
[m2] 0.841 Port B [#] 1 Points P [#] 8 Density ρn [kg/m
3] 1.313 Carbon dioxide CO2 [%] 7.6 Oxygen O2 [%] 5.5 Water vapor ratio rw [0;1] 0.08 Nozzle nz [mm] 14 Turbolence factor ft [sec] 9
DUCT FLOW RATE Dry actual QVa [m3/h] 9881
Moist actual Q'Va [m3/h] 10740 Moist standard [Tnorm Pnorm] Q'Vn [m3/h] 7352 Dry standard [Tnorm Pnorm] QVn [m3/h] 6763
AVERAGE VALUES Total Points
[#] 1 Velocity v'a [m/sec] 3.546 Stack temperature ta [°C] 121.203 Stack Static Pressure Pastatic [kPa] 100.13 Isokinetic Deviation DI [%] -8.4 Velocity at nozzle v'N [m/sec] 3.247 Flowrate Deviation DF [%] -0.4 Probe temperature tprobe [°C] 26.866 Box temperature tbox [°C] 26.924 Aux1 temperature taux1 [°C] 36.468 Aux2 temperature taux2 [°C] 25.759 Stack Differential Pitot Pressure dPpitot [Pa] 7.421 Ambient Pressure Pamb [kPa] 100.241
SAMPLED VOLUMES Elapsed time et [hh:mm:ss] 00:30:00
Total encoder impulses
[#] 15750 Standard Volume [Tnorm Pnorm] Vgn [m3] 0.569 Moist Volume at stack conditions V'ga [m3] 0.6873 Volume at dgm conditions Vdgm [m3] 0.7875 Gas meter temperature tgm [°C] 25.987 Gas Meter Pressure Pdgm [kPa] 80.162
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
24 of 33
start ts Port Point Distance Elapsed
Time rw avg tfumes avg Pa avg
dP pitot avg
[timestamp] [###] [###] [cm] [hh:mm:ss] [0;1] [°C] [kPa] [Pa]
19/07/2016 1 1 3.4 00:01:00 0.08 122.87 100.165 7.222 13:10:35
19/07/2016 1 2 10.9 00:01:01 0.08 123.657 100.165 5.221 13:11:39
19/07/2016 1 3 20.1 00:01:00 0.08 122.782 100.163 2.644 13:12:41
19/07/2016 1 4 33.5 00:01:00 0.08 121.2 100.147 2.598 13:13:43
19/07/2016 1 5 70.1 00:01:00 0.08 120.115 100.166 3.165 13:14:44
19/07/2016 1 6 83.5 00:01:00 0.08 119.495 100.158 2.067 13:15:45
19/07/2016 1 7 92.7 00:01:00 0.08 118.102 100.156 2.537 13:16:47
19/07/2016 1 8 100.2 00:01:00 0.08 117.578 100.149 2.625 13:17:51
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
25 of 33
Title: Determination of Combustion Flue Gases Method: EN 14792 / EN 14789 / EN 12039 / TGN M21 Test Date: 19/07/2016
Stack Name A1-2
Reference Conditions Measured Oxygen 5.3 %
Reference Oxygen 3 %
Parameter
NO SO2 O2 Emission Limit Values mg.m-3 ref
75 35
Instrument Range ppm
500 1000 25 Span Gas Value ppm
305 630 20.9
Acceptable Gas Range -
Yes Yes Yes Calibration Gas Uncertainty %
0.6 0.8 0.5
Quality Assurance Units Conditioning Unit Temperature C
2 2 2 Average Temperature < C
2 2 2
Allowable Temperature -
4 4 4 Temperature Acceptable -
Yes Yes Yes
Pump flow rate l/min.
0.5 0.5 0.5
Zero Drift Units Zero (Pre) ppm
0 -1 0 Zero (Post) ppm
-0.5 -2 0
Zero drift ppm
-0.5 -1 0 Allowable Zero Drift (Less than) ppm
6.1 12.6 0.418
Adjustable Zero Drift (Less than) ppm
15.25 31.5 1.045 Zero Drift Failure (Greater than) ppm
15.25 31.5 1.045
Zero Drift Acceptable -
Yes Yes Yes
Span Drift Units Span Down (Pre) ppm
305 628 20.9 Span Down (Post) ppm
304 626 20.9
Span Drift ppm
-1 -2 0 Allowable Span Drift (less than) ppm
6.1 12.6 0.418
Adjustable Span Drift (Less than) ppm
15.25 31.5 1.045 Span Drift Failure (Greater than) ppm
15.25 31.5 1.045
Span Drift Acceptable (Y/N) -
Yes Yes Yes
Leak Check Span Gas Conc. ppm
305 630 20.9
Recorded Conc. down Line ppm
305 628 20.9 Leak Detected ppm
0 -2 0
Leak check acceptable (< 2%) ppm
6.1 12.6 0.418 Pass (Y/N)
Yes Yes Yes
Test Conditions Units Run Ambient Temperature Range C
25.6 25.6 25.6
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
26 of 33
Raw Data
Date/Time Data source
NOx O2 SO2
ppm vol% ppm
19/07/2016 12:00
23.5 5.4 <6.1 19/07/2016 12:01
23.7 5.2 <6.1 19/07/2016 12:02
23.6 5.1 <6.1 19/07/2016 12:03
23.6 5.1 <6.1 19/07/2016 12:04
23.9 5.1 <6.1 19/07/2016 12:05
24.9 5.2 <6.1 19/07/2016 12:06
25.4 5.2 <6.1 19/07/2016 12:07
26.4 5.0 <6.1 19/07/2016 12:08
26.6 5.1 <6.1 19/07/2016 12:09
26.6 5.3 <6.1 19/07/2016 12:10
26.7 5.4 <6.1 19/07/2016 12:11
26.9 5.4 <6.1 19/07/2016 12:12
26.0 5.4 <6.1 19/07/2016 12:13
26.1 5.3 <6.1 19/07/2016 12:14
25.9 5.4 <6.1 19/07/2016 12:15
26.0 5.5 <6.1 19/07/2016 12:16
25.7 5.3 <6.1 19/07/2016 12:17
25.9 5.1 <6.1 19/07/2016 12:18
24.3 4.8 <6.1 19/07/2016 12:19
23.3 5.1 <6.1 19/07/2016 12:20
19.7 5.6 <6.1 19/07/2016 12:21
19.7 5.4 <6.1 19/07/2016 12:22
19.7 5.4 <6.1 19/07/2016 12:23
19.8 5.4 <6.1 19/07/2016 12:24
20.1 5.4 <6.1 19/07/2016 12:25
20.2 5.4 <6.1 19/07/2016 12:26
20.3 5.4 <6.1 19/07/2016 12:27
20.1 5.4 <6.1 19/07/2016 12:28
21.1 5.2 <6.1 19/07/2016 12:29
23.4 5.0 <6.1
Average
23.6 5.3 <6.1
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
27 of 33
Referenced Data
NOx SO2
mg/Nm3 Reference O2
19/07/2016 12:00
55.5 <6.1 19/07/2016 12:01
55.5 <6.1
19/07/2016 12:02
55.1 <6.1 19/07/2016 12:03
55.0 <6.1
19/07/2016 12:04
55.4 <6.1 19/07/2016 12:05
58.1 <6.1
19/07/2016 12:06
59.4 <6.1 19/07/2016 12:07
60.9 <6.1
19/07/2016 12:08
62.1 <6.1 19/07/2016 12:09
62.9 <6.1
19/07/2016 12:10
63.1 <6.1 19/07/2016 12:11
63.8 <6.1
19/07/2016 12:12
61.7 <6.1 19/07/2016 12:13
61.4 <6.1
19/07/2016 12:14
61.4 <6.1 19/07/2016 12:15
61.9 <6.1
19/07/2016 12:16
60.3 <6.1 19/07/2016 12:17
60.2 <6.1
19/07/2016 12:18
55.4 <6.1 19/07/2016 12:19
54.2 <6.1
19/07/2016 12:20
47.2 <6.1 19/07/2016 12:21
46.6 <6.1
19/07/2016 12:22
46.7 <6.1 19/07/2016 12:23
46.8 <6.1
19/07/2016 12:24
47.6 <6.1 19/07/2016 12:25
47.9 <6.1
19/07/2016 12:26
47.9 <6.1 19/07/2016 12:27
47.6 <6.1
19/07/2016 12:28
49.4 <6.1 19/07/2016 12:29
54.0 <6.1
Average
55.5 <6.1 Uncertainty of Measurement
4.8 7.6
Uncertainty as % of ELV
6.34 21.82 Standard Requirement
<10% <10%
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
28 of 33
Title: Determination of Total Particulates Method: EN 13284-1
Test Date: 19/07/2016 Uncertainty Data Laboratory Used: SAL
Certificate Numbers: 588644-1 Temperature at Pump 26.666 Deg C
Stack Name A1-3 Pressure at Pump 75.064 kPa
Test Time 14:24:23
Air Volume at Pump 1.0102 m3
Moisture Content 11.68 % Humidity at Pumps 0 %
Reference Oxygen 3 % Filter Weight 0.05 mg
Measured Oxygen 4.4 % Front End Weight 0.3 mg
Stack Flow Rate 8081 Nm3/hr Adjusted Stack Flow Rate 6579 Nm3/hr, dry @ % Oxygen
Volume of Air Sampled 0.6821 Nm3
Balance Calibration Weight 500.0 500.0 g
1000.0 1000.0 g
Impinger Weights Initial Final Difference 1 542.7 589.4 46.7 2 478.2 486.3 8.1 3 372.5 378.3 5.8 4 644.4 656.3 11.9 Volume of Air Sampled 0.6821 Nm3 72.5 Moisture Content (EN 14790) 11.68 %
Leak Check Results Result
% Leak
Before Blank 0 l/min 0.0 After Blank 0 l/min 0.0 Before Sample 1 0 l/min 0.0 After Sample 1 0 l/min 0.0 Average Flow Rate 22.602 l/min 0.0 Standard Maximum 0.45204 l/min 2% Back Pressure 69 kPa
Standard Criteria to be Met Result Standard Requirement
Angle of Flow Pass <15 Degrees Negative Flow in the Stack Pass None Pitot Pressure Difference Pass >5Pa Ratio of Flow Measurement Pass <3:1 Stagnation Test Pass <10Pa Pitot Tube Leak Check Result
Positive Pressure Pass - Negative Pressure Pass - Number of Ports 1 2 Straight length before sample point Pass > 5 Hydraulic Diameters
Straight length after sample point Pass > 5 Hydraulic Diameters
Sample Calculations Blank (Filter and Front Wash Combined) 0.35 mg
Sample 1 (Filter and Front Combined) 0.35 mg Volume of Air Sampled 0.6821 Nm3 Blank Result 0.51 mg/Nm3, dry 0.56 mg/Nm3, dry @ Ref O2
Sample Result 0.51 mg/Nm3, dry 0.56 mg/Nm3, dry @ Ref O2
Uncertainty of Measurement 0.50 mg/Nm3 Emission Limit Value 5 mg/Nm3, dry @ Ref O2
Blank as Percentage of ELV 11.1 % Standard Requirement <10% ELV
Isokinetic Criterion Compliance Isokinetic Variation % -0.3
Allowable Isokinetic Range % From - 5 to + 15 Isokinetic Acceptable - Yes
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
29 of 33
DUCT AND GAS SPECIFICATION Name
PFIZER.A1.3 Section
Circular Diameter
[m] 1.035
Area
[m2] 0.841 Port B [#] 1 Points P [#] 8 Density ρn [kg/m
3] 1.317 Carbon dioxide CO2 [%] 8.5 Oxygen O2 [%] 4.2 Water vapor ratio rw [0;1] 0.08 Nozzle nz [mm] 14 Turbolence factor ft [sec] 9
DUCT FLOW RATE Dry actual QVa [m3/h] 10917
Moist actual Q'Va [m3/h] 11866 Moist standard [Tnorm Pnorm] Q'Vn [m3/h] 8081 Dry standard [Tnorm Pnorm] QVn [m3/h] 7434
AVERAGE VALUES Total Points
[#] 1 Velocity v'a [m/sec] 3.918 Stack temperature ta [°C] 122.928 Stack Static Pressure Pastatic [kPa] 100.045 Isokinetic Deviation DI [%] -0.3 Velocity at nozzle v'N [m/sec] 3.906 Probe temperature tprobe [°C] 27.599 Box temperature tbox [°C] 27.69 Aux1 temperature taux1 [°C] 37.345 Aux2 temperature taux2 [°C] 26.808 Stack Differential Pitot Pressure dPpitot [Pa] 8.997 Ambient Pressure Pamb [kPa] 100.161
SAMPLED VOLUMES Elapsed time et [hh:mm:ss] 00:30:00
Total encoder impulses
[#] 20204 Standard Volume [Tnorm Pnorm] Vgn [m3] 0.6821 Moist Volume at stack conditions V'ga [m3] 0.8266 Volume at dgm conditions Vdgm [m3] 1.0102 Gas meter temperature tgm [°C] 26.666 Gas Meter Pressure Pdgm [kPa] 75.064
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
30 of 33
start ts Port Point Distance Elapsed
Time rw avg tfumes avg Pa avg
dP pitot avg
[timestamp] [###] [###] [cm] [hh:mm:ss] [0;1] [°C] [kPa] [Pa]
19/07/2016 1 1 3.4 00:01:00 0.08 125.105 100.091 11.271 14:13:09
19/07/2016 1 2 10.9 00:01:00 0.08 125.467 100.073 11.275 14:14:13
19/07/2016 1 3 20.1 00:01:00 0.08 125.831 100.077 10.489 14:15:14
19/07/2016 1 4 33.5 00:01:00 0.08 125.71 100.085 9.882 14:16:16
19/07/2016 1 5 70.1 00:01:00 0.08 125.375 100.072 8.36 14:17:34
19/07/2016 1 6 83.5 00:01:00 0.08 125.166 100.066 8.586 14:18:36
19/07/2016 1 7 92.7 00:01:00 0.08 124.979 100.068 8.719 14:19:39
19/07/2016 1 8 100.2 00:01:00 0.08 124.642 100.062 7.641 14:20:41
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
31 of 33
Title: Determination of Combustion Flue Gases Method: EN 14792 / EN 14789 / EN 12039 / TGN M21 Test Date: 19/07/2016
Stack Name A1-3
Reference Conditions Measured Oxygen 4.4 %
Reference Oxygen 3 %
Parameter
NO SO2 O2 Emission Limit Values mg.m-3 ref
75 35
Instrument Range ppm
500 1000 25 Span Gas Value ppm
305 630 20.9
Acceptable Gas Range -
Yes Yes Yes Calibration Gas Uncertainty %
0.6 0.8 0.5
Quality Assurance Units Conditioning Unit Temperature C
2 2 2 Average Temperature < C
2 2 2
Allowable Temperature -
4 4 4 Temperature Acceptable -
Yes Yes Yes
Pump flow rate l/min.
0.4 0.4 0.4
Zero Drift Units Zero (Pre) ppm
0 -2 0 Zero (Post) ppm
-1 -4 0
Zero drift ppm
-1 -2 0 Allowable Zero Drift (Less than) ppm
6.1 12.6 0.418
Adjustable Zero Drift (Less than) ppm
15.25 31.5 1.045 Zero Drift Failure (Greater than) ppm
15.25 31.5 1.045
Zero Drift Acceptable -
Yes Yes Yes
Span Drift Units Span Down (Pre) ppm
304 627 20.8 Span Down (Post) ppm
302 624 20.8
Span Drift ppm
-2 -3 0 Allowable Span Drift (less than) ppm
6.1 12.6 0.418
Adjustable Span Drift (Less than) ppm
15.25 31.5 1.045 Span Drift Failure (Greater than) ppm
15.25 31.5 1.045
Span Drift Acceptable (Y/N) -
Yes Yes Yes
Leak Check Span Gas Conc. ppm
305 630 20.9
Recorded Conc. down Line ppm
304 627 20.8 Leak Detected ppm
-1 -3 -0.1
Leak check acceptable (< 2%) ppm
6.1 12.6 0.418 Pass (Y/N)
Yes Yes Yes
Test Conditions Units Run Ambient Temperature Range C
25.6 25.6 25.6
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
32 of 33
Raw Data
Date/Time Data source
NOx O2 SO2
ppm vol% ppm
19/07/2016 12:43
20.3 4.6 <6.1
19/07/2016 12:44
20.6 4.7 <6.1
19/07/2016 12:45
20.9 4.5 <6.1
19/07/2016 12:46
20.7 4.4 <6.1
19/07/2016 12:47
20.7 4.2 <6.1
19/07/2016 12:48
21.3 4.4 <6.1
19/07/2016 12:49
20.7 4.5 <6.1
19/07/2016 12:50
20.4 4.3 <6.1
19/07/2016 12:51
20.6 4.1 <6.1
19/07/2016 12:52
20.4 4.3 <6.1
19/07/2016 12:53
20.7 4.2 <6.1
19/07/2016 12:54
20.3 4.5 <6.1
19/07/2016 12:55
20.3 4.4 <6.1
19/07/2016 12:56
20.5 4.3 <6.1
19/07/2016 12:57
20.2 4.2 <6.1
19/07/2016 12:58
20.3 4.2 <6.1
19/07/2016 12:59
20.6 4.3 <6.1
19/07/2016 13:00
20.1 4.3 <6.1
19/07/2016 13:01
20.2 4.3 <6.1
19/07/2016 13:02
19.9 4.5 <6.1
19/07/2016 13:03
19.8 4.7 <6.1
19/07/2016 13:04
20.2 4.3 <6.1
19/07/2016 13:05
20.3 4.2 <6.1
19/07/2016 13:06
20.0 4.4 <6.1
19/07/2016 13:07
19.3 4.4 <6.1
19/07/2016 13:08
19.9 4.4 <6.1
19/07/2016 13:09
20.4 4.4 <6.1
19/07/2016 13:10
20.2 4.4 <6.1
19/07/2016 13:11
20.4 4.3 <6.1
19/07/2016 13:12
20.1 4.4 <6.1
Average
20.3 4.4 <6.1
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EPA Export 07-02-2017:02:12:38
Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1
33 of 33
Referenced Data
NOx SO2
mg/Nm3 Reference O2
19/07/2016 12:43
45.9 <6.1 19/07/2016 12:44
46.7 <6.1
19/07/2016 12:45
46.8 <6.1 19/07/2016 12:46
45.9 <6.1
19/07/2016 12:47
45.7 <6.1 19/07/2016 12:48
47.5 <6.1
19/07/2016 12:49
46.4 <6.1 19/07/2016 12:50
45.2 <6.1
19/07/2016 12:51
45.0 <6.1 19/07/2016 12:52
45.0 <6.1
19/07/2016 12:53
45.6 <6.1 19/07/2016 12:54
45.3 <6.1
19/07/2016 12:55
45.2 <6.1 19/07/2016 12:56
45.2 <6.1
19/07/2016 12:57
44.5 <6.1 19/07/2016 12:58
44.7 <6.1
19/07/2016 12:59
45.6 <6.1 19/07/2016 13:00
44.5 <6.1
19/07/2016 13:01
44.9 <6.1 19/07/2016 13:02
44.4 <6.1
19/07/2016 13:03
44.9 <6.1 19/07/2016 13:04
44.6 <6.1
19/07/2016 13:05
44.6 <6.1 19/07/2016 13:06
44.6 <6.1
19/07/2016 13:07
43.0 <6.1 19/07/2016 13:08
44.4 <6.1
19/07/2016 13:09
45.5 <6.1 19/07/2016 13:10
44.9 <6.1
19/07/2016 13:11
45.0 <6.1 19/07/2016 13:12
44.8 <6.1
Average
45.2 <6.1 Uncertainty of Measurement
4.7 9.5
Uncertainty as % of ELV
6.33 27.03 Standard Requirement
<10% <10%
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EPA Export 07-02-2017:02:12:38