ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279
Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland
Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL
Exova Catalyst Ireland, Unit D8 North City Business Park, North Road, Finglas, Dublin 11E: [email protected]
Your Exova Catalyst Ireland Contact: Patrick O'Brien (+353 86 416 1434)
Co MonaghanCastleblayney
Kingspan Insulation Ltd
Kingspan Insulation Ltd
A2-14 RTO Outlet
MM 13 1259
Stack Reference
Irish EPA IE Licence: P0057-03
Signature of Report Approver
Version 1
Team Leader
MCERTS Level 2
Donal O Faogain
Report Approved by
Deputy Regional Manager
TE1 TE2 TE3 TE4
MM 10 1074MCERTS Level 2
13th June 2018Report Date
TE1 TE2 TE3 TE4
Report Written by
John Glennon
Stack Emissions Testing Report Commissioned by
15th - 16th May 2018
Job Reference Number
CDU-1018
Installation Name & Address
Dates of the Monitoring Campaign
Version
CAT-RT (Version BV)
CDU-1018-Kingspan A2-14 Report
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EPA Export 18-08-2018:04:04:18
TITLE PAGE
CONTENTS
Summary of Sampling Deviations
EXECUTIVE SUMMARY
Monitoring Objectives
Monitoring Results
Monitoring Dates & Times
Process Details
Monitoring & Analytical Methods
Sampling Location
Plant Photos / Sample Points
APPENDIX 1 - Monitoring Personnel & List of Equipment
APPENDIX 2 - Raw Data, Sampling Equations & Charts
The testing performed fully meets the technical requirements in Irish EPA
Guidance Note, AG2.
Opinions and interpretations expressed herein are outside the scope of
Exova Catalyst Ireland's ISO 17025 accreditation.
This test report shall not be reproduced, except in full, without the
written approval of Exova Catalyst Ireland.
9
3
5
6
8
4
2
7
CONTENTS
CAT-RT (Version BV)
Page 2 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:18
Overall Aim of the Monitoring Campaign
Special Requirements
Target Parameters
Exova Catalyst Ireland were commissioned by Kingspan Insulation Ltd to carry out stack emissions testing on the A2-14 RTO Outlet
at Castleblayney.
The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values (ELVs) as specified in the
Site's Permit.
There were no special requirements.
Dioxins & Furans, Hydrogen Chloride, Hydrogen Fluoride, Organics Class I , Organics Class II , Formaldehyde , Total VOCs (as
Carbon), Oxides of Nitrogen (as NO₂), Sulphur Dioxide, Carbon Monoxide
MONITORING OBJECTIVES
Executive Summary
A2-14 RTO Outlet
15th - 16th May 2018
Kingspan Insulation Ltd, Castleblayney
(Page 1 of 7)
CAT-RT (Version BV)
Page 3 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:18
where MU = Measurement Uncertainty associated with the Result
Parameter
Dioxins & Furans (NATO I-TEQ) Dioxins & Furans ¹
Dioxins & Furans (WHO TEQ Humans / Mammals) ¹
Dioxins & Furans (WHO TEQ Fish) ¹
Dioxins & Furans (WHO TEQ Birds) ¹
Dioxins & Furans (NATO I-TEQ) ¹
Dioxins & Furans (WHO TEQ Humans / Mammals) ¹
Dioxins & Furans (WHO TEQ Fish) ¹
Dioxins & Furans (WHO TEQ Birds) ¹
Hydrogen Chloride ¹ - -
Hydrogen Fluoride ¹ < <
Organics Class I ¹ < <
Organics Class II ¹ < <
Formaldehyde ¹ < <
Total VOCs (as Carbon) ¹ - -
Oxides of Nitrogen (as NO₂) ¹ - -
Sulphur Dioxide ¹ - -
Carbon Monoxide ¹ - -
Carbon Dioxide Dry
Oxygen Dry
Water Vapour
Stack Gas Temperature
Stack Gas Velocity
¹
- -
NOTE: VOLUMETRIC FLOW RATE & VELOCITY DATA TAKEN FROM AN AVERAGE OF ALL OF THE ISOKINETIC RUNS.
¹ Reference Conditions (REF) are: 273K, 101.3kPa, dry gas.
mg/m³ 0.04 -
-
8000
8.60 16.8
6.436
0.24
1.17
6.305.28mg/m³ 1001.20
100 g/hr 167.7 34.9 500
mg/m³
-
g/hr
µg/hr
Kingspan Insulation Ltd, Castleblayney
15th - 16th May 2018
+/-
0.0005
0.0021
Units Result
0.0004
Concentration
-
0.01 0.002
0.0005
-
MU
0.010.0021
0.022
MU
ng/m³
ng/m³
ng/m³
0.0004
0.01
0.0022 0.1
Units
µg/hr
-
ng/m³
0.0022ng/m³
0.0009
0.0026 -
0.002
-
Dioxins & Furans Upper Limit (worst case where <LOD = LOD)
Dioxins & Furans Lower Limit (best case where <LOD = 0)
0.032
-
0.0005
µg/hr
0.0043
mg/m³
12.02
-
Executive Summary
-
0.012 0.002
Mass Emission
- µg/hr
MONITORING RESULTS
µg/hr
A2-14 RTO Outlet
µg/hr
0.0004
Result Limit
-µg/hr
-
0.0026
ng/m³ 0.003
µg/hr
Limit
+/-
30
0.005
0.02 0.005
ng/m³
0.012 0.002 -
0.014 0.003
-
-
63.00.78 g/hr
0.4g/hr
5.21
0.0040.07
-
mg/m³ 65.9 10012.57 2.51 13.620
mg/m³ 32.00 6.46
0.01 4 0.043
m³/hr
20.46
268
g/hr
(Page 2 of 7)
1.23 300
4.60
g/hr
-
0.46
Volumetric Flow Rate (REF)
3.21 200
% v/v
mg/m³ 1.64
24.1
g/hr
% v/v
Volumetric Flow Rate (ACTUAL)
3.86
27.7
mg/m³
m³/hr
0.24
5240
0.55
10.3m/s
0.35
36.8
% v/v
7.428
6450
°C
-
329
-
-
-
0.0042 0.0009ng/m³
0.2
mg/m³ 2.69650 g/hr
6.11
g/hr
CAT-RT (Version BV)
Page 4 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:18
Parameter
(NATO) R1 - -
R1 - -
R1 < <
R1 < <
R1 < <
R1 < <
R1 - -
R1 - -
R1 - -
R1 - -
R1 -
R1 -
R1
All results are expressed at the respective reference conditions.
mg/m³
13:10 - 13:40
Date(s)
Mass Emission
12.0
Dioxins & Furans
167.7
Formaldehyde g/hr 15/05/2018 300.040
Velocity Traverse 15/05/2018 10:45 - 10:50
Sampling
Times
Units
Kingspan Insulation Ltd, Castleblayney
Duration
0.012ng/m³ µg/hr
mg/m³ g/hr
A2-14 RTO Outlet
15th - 16th May 2018
Executive Summary
g/hr
11:18 - 11:48
09:10 - 09:40
g/hr
MONITORING DATE(S) & TIMES
0.002
mins
15/05/2018
(Page 3 of 7)
32.00
mg/m³ 15/05/201865.9
Total VOCs (as Carbon)
30
Organics Class II
g/hr
SamplingConcentration
30
10:57 - 16:57
Units
0.36
30
360
Hydrogen Chloride 16/05/201863.0
mg/m³ 15/05/2018Hydrogen Fluoride
mg/m³
0.069
g/hr12.57Organics Class I 12:30 - 13:00 30
15/05/2018 30
0.21 13:55 - 14:25
15/05/2018
20.46
24.1
g/hr
mg/m³ g/hr
4.60
1.64
30
8.60
15/05/2018
15/05/2018Oxides of Nitrogen (as NO₂) 30
30
15/05/2018Sulphur Dioxide
% v/v
301.20
15/05/2018mg/m³Carbon Monoxide 6.11
g/hr
Carbon Dioxide
6.30mg/m³
16:20 - 16:50
16:20 - 16:50
16:20 - 16:50mg/m³
1.17
16:20 - 16:50
% v/v
Oxygen
16:20 - 16:50
3.86
15/05/2018
3016:20 - 16:50
CAT-RT (Version BV)
Page 5 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:18
Standard Operating Conditions
Parameter
Extracted Air and LPG
White - Visible
Full Production
Value
Process Status
A2-14 RTO Outlet
15th - 16th May 2018
Fuel
Feedstock (if applicable)
PROCESS DETAILS
Kingspan Insulation Ltd, Castleblayney
(Page 4 of 7)
Running
Continuous
Regenerative Thermal Oxidising Unit
Abatement System
Abatement System Running Status
Plume Appearance
Thermal Oxidiser
Executive Summary
Capacity (of 100%) and Tonnes / Hour
Continuous or Batch Process
N/A
CAT-RT (Version BV)
Page 6 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:18
0.0003 ng/m³
CAT-TP-10 Yes YesYes CAT
GC/MS
GC/MSOrganics Class II CEN/TS 13649
HPLC Yes
CAT
CAT-TP-16
NDIR by Horiba PG-250
Yes
Yes
0.62 mg/m³
CAT-TP-41
CAT
NDIR by Horiba PG-250
NDIR by Horiba PG-250Sulphur Dioxide
Carbon Monoxide
ISO 12039
CAT-TP-21
0.14 %CAT-TP-21 Yes
EN 12619:2013
CAT 1.64 mg/m³
CAT-TP-21
Yes
Yes
0.1 %
RPS Laboratories Ltd (RPS)
Marchwood Scientific Services Ltd (MAR)
CAT-TP-20
CAT Yes
1.11 mg/m³
Oxygen
ISO 17025 Accreditation Number: 4279
ISO 17025 Accreditation Number: 0605
SUMMARY OF SAMPLING DEVIATIONS
(with short name reference as appears in the table above)
Exova Catalyst (CAT)
CAT-TP-05
Yes
CAT-TP-21
Velocity & Vol. Flow Rate
Yes
Yes
Deviation
Oxides of Nitrogen (as NO₂)
Parameter
1One out of two sampling lines was used due to sampling location restrictions, however the number of sample points used
on the available line were increased to the minimum required by the Standard
Pitot Tube and Thermocouple
ANALYSIS LABORATORIES
CAT
TGN M21
CAT-TP-05
Yes
0.1 % v/vYesEN 14790
Chemiluminescence by Horiba PG-250
Yes
EN 14792
EN 16911-1 (MID)
Yes
EN 14789
Carbon Dioxide
Yes
Dry Zirconia Cell by Horiba PG-250CAT
Total VOCs (as Carbon)
Yes
0.04 mg/m³
Yes CAT
Yes 1.2 m/s
ISO 17025 Accreditation Number: 1668
CAT
CEN/TS 13649 CAT A40
GravimetricWater Vapour
EN 15058
Flame Ionisation Detection by Sick 3006 FID
Yes
CAT 0.32 mg/m³
RPS
Yes
Yes
Yes
Formaldehyde Yes
CEN/TS 13649
CAT-TP-16 Yes CAT
12.57 mg/m³Yes
0.052 mg/m³
CAT-TP-16 Yes
RPS
Hydrogen Fluoride
GC/MS
0.069 mg/m³IC
32.004 mg/m³
CAT CLSOrganics Class I
Yes
Dioxins & Furans
GC/MS
GC-HRMSYes
CAT Yes
ISO
Executive Summary
A2-14 RTO Outlet
ISO
Hydrogen Chloride EN 1911 CAT-TP-11
ISO 15713
Analysis
17025 Analysis
Technical LOD
Monitoring
Lab
CAT-TP-07 Yes MAR
CAT
Testing
Yes
IC
CAT
CAT
Lab
Yes CAT-AP-01
CAT-AP-01
EN 1948 WI 1122
Analysis
MONITORING & ANALYTICAL METHODS
(Average)
Analytical
15th - 16th May 2018
Parameter
Procedure
MCERTS
17025
Testing
Standard Analytical
TechniqueProcedure
Kingspan Insulation Ltd, Castleblayney
(Page 5 of 7)
Testing
Dioxins & Furans
CAT-TP-21
Run
CAT-RT (Version BV)
Page 7 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:18
Duct Characteristics Location of Sampling Platform
Platform Details
Sampling Location / Platform Improvement Recommendations
EN 15259 Homogeneity Test Requirements
Sampling Plane Validation Criteria (from EN 15259)
Number of Ports -
Yes
Pa
Yes
--
0
10.16 -
Value
No Local Negative Flow
0.17
Orientation of Duct
Compliant
-
Yes
SUITABILITY OF SAMPLING LOCATION
Outside
cm
-
Port Depth
0.00
Permanent / Temporary Platform
Width
Platform has vertical base boards (approx. 0.25m high)
Vertical
Type
Yes
-
Units
-
Sufficient working area to manipulate probe and operate the measuring instruments
-
Permanent
0.00
-
-
0.00
-
-
Maximum Angle of Swirl
-Yes
Yes
-
-
All platforms should be designed in accordance with the requirements in EPA Guidance Note AG1 and EN 15259.
Criteria in EN 15259
-10.40
-
Mean Velocity
-
Safe Access Available
There are no obstructions present which hamper insertion of sampling equipment
-
Parameter
(Page 6 of 7)
5" Flange
Easy Access Available
Units
m
Irish EPA Technical Guidance Note AG1 / EN 15259 Platform Requirements
-
Yes
Traverse 1
Inside / Outside0.47
-
Sample Port Size
There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.
81.0
Circular
Value
-
-
Highest Gas Velocity
Area
Yes
4
-
Lowest Gas Velocity
m/s
Yes
9.96
-
-
Required
-
Platform has chains / self closing gates at top of ladders
-
m/s
-
-
m²
m
-
-
-
-
-
Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)
-m/s
Executive Summary
General Platform Information
> 5 Pa Yes
-
Lowest Differential Pressure
Depth
Value
Ratio of Above < 3 : 1
- Yes-
-
: 1 Yes
< 15°
0.001.04
° 8
CAT-RT (Version BV)
Page 8 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:18
Executive Summary
Photo 2
PLANT PHOTOS
(Page 7 of 7)
SAMPLE POINTS
Photo 1
where = isokinetic point sampled at
= isokinetic point not sampled at
= combustion gases sample point
Line A
A1
A4
A3
A2
= non-isokinetic sample point
CAT-RT (Version BV)
Page 9 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:18
APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDIX CONTENTS
APPENDICES
CAT-RT (Version BV)
Page 10 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:18
Bioaerosols Temperature Logger -
Electronic Refrigerator -
ABB AO2020-URAS26
Stack Thermocouple (2)
Servomex 4900
-
Stopwatch
CAT 7.23
Position
CAT 9.19
Equipment Type
APPENDIX 1
CAT 3.168-
-
CAT 21P.14
MM16 1413 TE1
CAT 25.12
CEN/TS 13649
Miscellaneous Items
-
MM 10 1074 TE1 TE2 TE3 TE4
Technician Brian Walsh MCERTS Level 1
Oven Box (2)
Eco Physics CLD 822Mh
CAT 3.59
5m Heated Line (1) -
Barometer
Digital Manometer (2)
MCERTS Number
CAT-TP-16Organics Class II
Technical Endorsements
S-Pitot (1)
L-Pitot
SELECT FTIR
SELECT Horiba Model (2)
CEN/TS 13649
CAT 6.21
Stack Thermocouple (3)
ISO 12039
TGN M21
CAT-TP-21
CAT-TP-21
Velocity & Vol. Flow Rate
Organics Class I
Hydrogen Fluoride
Water Vapour
Sulphur Dioxide
EN 15058
CAT-TP-21
Total VOCs (as Carbon)
Oxides of Nitrogen (as NO₂)
Oxygen
EN 14790
Formaldehyde
EN 16911-1 (MID) CAT-TP-41
EN 14789
Carbon Monoxide
Carbon Dioxide
EN 14792
CAT-TP-16
CAT-TP-21
CAT-TP-16
CAT-TP-21
CAT 12.83
-
Mass Flow Controller (2)
Name
Site Balance
M&C PSS
Control Box DGM (2)
-
John Glennon MCERTS Level 2
Extractive Sampling
CAT 23.26
STACK EMISSIONS MONITORING PERSONNEL
CAT 4.491
-
Umbilical (2) Servomex 5200MP
LIST OF EQUIPMENT
MCERTS Accreditation
-
Equipment I.D.
CAT 6.1
CAT 3.168
- 20m Heated Line (1)
20m Heated Line (2)
-
Stack Thermocouple (1)
Gasmet Sampling System
Instrumental Analysers
CAT 25.11
-
JCT JCC P1 Cooler
CAT 13.27
Mass Flow Controller (1)
Umbilical (1)
Box Thermocouples (2)
Box Thermocouples (1)
SELECT Logger 2 -
Dual Channel Heater Controller -500g / 1Kg Check Weights
METHODS & TECHNICAL PROCEDURES USED
Single Channel Heater Controller
Tubes Kit Thermocouple CAT 4.0005
CAT 11.58
EN 1911
Mass View (1)
Hioki 5043 (V)
CAT 20.71
Equipment Type
CAT 4.605
-
CAT 14.65
-
Bernath 3006 FID CAT 8.16
15m Heated Line (1)
CAT 17.24
-
- 1m Heated Line (2)Heated Probe (2)
Team Leader
S-Pitot (2) CAT 21S.42
CAT 17.24
Last Impinger Arm CAT 4.405
Callipers
Mass View (2)
Dioxins & Furans
1m Heated Line (1)
Technical ProcedureStandard
Heated Probe (1)
Control Box DGM (1)
CAT 3.59
-
-
Parameter
1m Heated Line (3)
-
Oven Box (1)
CAT 20.71
Laboratory Balance
Equipment I.D.
Digital Manometer (1)Horiba PG-250
CAT 5.3
EN 1948
CEN/TS 13649
Hydrogen Chloride
Equipment I.D.Equipment Type
CAT-TP-10
CAT-TP-11
CAT-TP-07
CAT-TP-20
CAT-TP-05
Digital Temperature Meter
Heated Probe (3) -
EN 12619:2013
CAT 16.35Tape Measure
-
CAT 12.115
-
CAT 4.568
ISO 15713
CAT-RT (Version BV)
Page 11 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:18
General Stack Details
Stack Gas Composition & Molecular Weights
CO₂
O₂
Moisture (H₂O)
Where: p = M / 22.41
pi = r x p
Calculation of Stack Gas Densities
Where: P STD = sum of component concentrations, kg/m³ (not including water vapour)
P STW = sum of all wet concentrations / 100 x density, kg/m³ (including water vapour)
P Actual = P STD x (TSTP / (PSTP)) x ((Pstatic + Pb) / Ta)
P ActualW (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)
Calculation of Stack Gas Volumetric Flowrate, Q
Gas Volumetric Flowrate (from Traverse)
m²
Stack Diameter / Depth, D
PRELIMINARY STACK SURVEY: CALCULATIONS
Average Barometric Pressure, Pb
Dry Density (STP), P STD
0.0386
5204
Value
34.5
Units
0.47
Dry
0.05970
20.46 32.00
Conc
Gas Volumetric Flowrate (Actual)
kg/m³
ConcMolar Conc
-
0.2046
m³/hr
REF ¹
1.130
Dry Density (Actual), P Actual
APPENDIX 2
kg/m³
m³/hr
7.43
m³/hr
°C
84.0
m³/hr
Gas Volumetric Flowrate (STP, Dry)
18.02
Determinand
kg/m³
0.17
Result
-
mStack Width, W
Stack Details (from Traverse)
Moisture
Stack Area, A
3.86
Units
Average Pitot Tube Calibration Coefficient, Cp
ppm
Average Stack Gas Pressure
Conc
kg/m³
0.7568
Average Stack Gas Temperature, Ta
-0.0
5204
0.085Average Stack Static Pressure, Pstatic
-
28.01
Pa
Result
1.9635
-
Volume
kPa
kPa
0.84
-
-
1.2498
44.01
0.94587
1.314
70.06
34.5
101.1
Gas Volumetric Flowrate REF ¹
1.4277 0.29217
Mass
Component
N₂
101.0
7.43
M
Wet
r% v/v
kg/m³
-
Units
Fraction
Density
Total Pressure
Average Wet Density (Actual), P ActualW
°C
Gas Volumetric Flowrate (STP, Wet)
101.3
Temperature
Duct gas flow conditions
75.68
p pi
3.57 0.07573
kPa
0.0743
5622
18.94
6345
1.164
Wet Density (STP), P STW
% v/v
Units
0.00
kg/m³ 1.276
0.8037
m
Actual
%
CAT-RT (Version BV)
Page 12 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:18
Parameter Parameter
Date of Survey Initial Pitot Leak Check
Time of Survey Final Pitot Leak Check
Atmospheric Pressure Orientation of Duct
Average Stack Static Pressure Pitot Tube, Cp
Result of Pitot Stagnation Test Number of Lines Available
Are Water Droplets Present? Number of Lines Used
Device Used
15/05/2018
Value
S-Type Pitot with KIMO MP 200 (500Pa)
101.0
Velocity
Units
Pa
Depth
-
∆P -
-
-
Temp
APPENDIX 2
1-
-Swirl
No
Pass
PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID)
Pass
-
-
(1 of 1)
1
Wet Density
5.085.0
4
2.088.0
Units
kPa
-
-
-
1.134
0.35
Point
35.0
Mean
0.12
3
34.5
10.05
10.40
1.128
1.128
--° -°C
85.0
0.03
kg/m³ -m/sPa
1.130
m
Value
-
--
-
-
Traverse
0.84
2
0.44
10.23
34.6
33.481.0
35.0
- -
Sampling Line A
4.0
-
-
-
-
-
-
- --
- -
-
-
-
-
-
-
-
-
-- - --
1.130
STATIC (Units: Pa)
85 -
-
1
82.0
84.0 -
-
-
-
-
-
-
8.09.96
-
-
--
-
--
-
-
- -
--
10:45 - 10:50
-
-
-
10.16
-
-
-
-
--
-
-
- -
-
- -
-
-
-
-
-
-
-
-
-
-
-
-
-
Vertical
Pass
-
-
CAT-RT (Version BV)
Page 13 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:18
- u²(qV,w)/q²V,w
1.569
-
1.534
u(φO₂,d) 0.626
u(φCO₂,w) 0.110
- u²(a)/a²
u(Tc)
APPENDIX 2
- 27352
- 165.4
Uc,rel(qV,w) 5.11
%
- Static Pressure
Standard uncertainty associated with the density in the duct
Standard uncertainty associated with the volume flow rate (95% Confidence)
m/s
u(φCO₂,d) 0.118
Standard uncertainty associated with the local velocities
- φCO₂,w
- Oxygen, dry
- Carbon Dioxide, dry
Standard uncertainty associated with the mean velocity
175.692
1.534
u(ρ) 0.00609
u(fit) 0.535
Standard Uncertainty associated with the mean local dynamic pressures
Standard uncertainty associated with the mean velocity (95% Confidence), relative
0.005
Uc,rel(v) 2.37
Standard uncertainty associated with the absolute pressure in the duct
- Atmospheric Pressure
u(drift) 0.083- Drift
- Lack of Fit
- Water Vapour
- Oxygen, wet
- Carbon Dioxide, wet
-
Pa
u(res) 0.00087
u(vi)
K
u(pc)
0.241
1.354
u(∆pi)
324.2 m³/hr
- u²(qV,w)
Performance characteristics (Uncertainty Components) UnitsValueUncertainty
PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID) - MEASUREMENT UNCERTAINTY(1 of 1)
Standard uncertainty associated with the mean velocity (95% Confidence)
- Overall corrections to dynamic measurements
Standard uncertainty associated with the molar mass of the gas
- φO₂,w
- Resolution
- Calibration
0.00068
%
- u(qV,w)
18.944
- 3.570
u(M) 0.00005
0.147
u(v) 0.123
Standard Uncertainty on the coefficient of the Pitot Tube -
0.00053
-
Uc(qV,w)
Standard uncertainty associated with the stack temperature
Uc(v)
-
-
Pa
m/s
u(Cf)
u(φH₂O) 0.379
u(pstat)
u(k)
u(cal) 0.735
u(φO₂,w) 0.585
Standard uncertainty associated with the volume flow rate (95% Confidence), relative
175.699 Pa
u(patm)
CAT-RT (Version BV)
Page 14 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sample Runs (UPPER NATO I-TEQ)
- -
- -
- -
- -
- -
Sample Runs (UPPER WHO TEQ Humans / Mammals)
- -
- -
- -
- -
- -
Sample Runs (UPPER WHO TEQ Fish)
- -
- -
- -
- -
- -
Sample Runs (UPPER WHO TEQ Birds)
- -
- -
- -
- -
- -
0.0224
0.0009
Mass Emission
0.0043
±ng/m³
Mass Emission µg/hr
0.0026
ng/m³
0.012
TEQ1 - UPPER LIMITS (worst case where <LOD = LOD)
Uncertainty
Uncertainty
0.0047
0.0005
±ng/m³ 0.0004
0.0005
Mass Emission µg/hr
Uncertainty
0.0043
Mean
APPENDIX 2
0.002
Parameter
0.0009
µg/hr 0.0138
0.0224
Mean
Parameter Units
Units Run 1
0.0029
0.0022Concentration ng/m³
DIOXINS & FURANS: RESULTS SUMMARY
Mass Emission
±ng/m³
Parameter Units
0.002
Parameter Units
Uncertainty
0.012
Uncertainty ±µg/hr 0.002
ng/m³ 0.0022 0.0022
±µg/hr
Concentration
A2-14 RTO Outlet
0.002
0.012
0.0026
Uncertainty ±µg/hr
Concentration
0.0138
Uncertainty ±µg/hr 0.0029
Concentration ng/m³
Run 1
(PAGE 1 OF 4)
Uncertainty ±ng/m³ 0.0005
Kingspan Insulation Ltd, Castleblayney
0.0022
0.0005
Mean
Run 1 Mean
µg/hr 0.012
Run 1
0.0047
0.0004
CAT-RT (Version BV)
Page 15 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Sample Runs (LOWER NATO I-TEQ)
- -
- -
- -
- -
- -
Sample Runs (LOWER WHO TEQ Humans / Mammals)
- -
- -
- -
- -
- -
Sample Runs (LOWER WHO TEQ Fish)
- -
- -
- -
- -
- -
Sample Runs (LOWER WHO TEQ Birds)
- -
- -
- -
- -
- -
Concentration
Uncertainty
0.0026
Concentration ng/m³ 0.0021
0.0021
0.0111
0.0021
APPENDIX 2
µg/hr 0.0220
±ng/m³
µg/hr
±µg/hrUncertainty
ng/m³
±µg/hr
MeanRun 1
±µg/hr 0.0024
Mean
ng/m³
Concentration ng/m³
0.0111
Mass Emission
±ng/m³
Mass Emission
0.0023
0.0028
0.0005Uncertainty
0.0028
0.0009
0.0004
Mass Emission
0.0009
Parameter Units
±ng/m³
µg/hr 0.0134
0.0004
µg/hr
Parameter
0.00420.0042
Mean
0.0026
0.0112
Kingspan Insulation Ltd, Castleblayney
A2-14 RTO Outlet
TEQ2 - LOWER LIMITS (best case where <LOD = 0)
Parameter
0.0112
Parameter
(PAGE 2 OF 4)
Mass Emission
Units Run 1
Uncertainty
Uncertainty 0.0004
Concentration
Uncertainty
±ng/m³
0.0220
Uncertainty
0.0021
0.0024
Units
0.0023
±µg/hr 0.0046
Run 1Units Mean
Run 1
0.0004
Uncertainty
0.0005
0.0134
DIOXINS & FURANS: RESULTS SUMMARY
0.0046
CAT-RT (Version BV)
Page 16 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Blank Runs (UPPER NATO I-TEQ)
- -
- -
Blank Runs (UPPER WHO TEQ Humans / Mammals)
- -
- -
Blank Runs (UPPER WHO TEQ Fish)
- -
- -
Blank Runs (UPPER WHO TEQ Birds)
- -
- -
Blank Runs (LOWER NATO I-TEQ)
- -
- -
Blank Runs (LOWER WHO TEQ Humans / Mammals)
- -
- -
Blank Runs (LOWER WHO TEQ Fish)
- -
- -
Blank Runs (LOWER WHO TEQ Birds)
- -
- -
Concentration ng/m³
0.00002
0.0002
Parameter
Blank 1
ng/m³
0.0003
Concentration
0.0002
ng/m³
ng/m³
0.0002
TEQ2 - LOWER LIMITS (best case where <LOD = 0)
0.00002
APPENDIX 2
Units
Units Blank 1
Blank 1
A2-14 RTO Outlet
Maximum
TEQ1 - UPPER LIMITS (worst case where <LOD = LOD)
Parameter Units Blank 1
0.0002
Maximum
Blank 1
0.0002
Parameter
Kingspan Insulation Ltd, Castleblayney
Blank 1
Concentration
0.00002
Parameter Units
Maximum
0.0003
Concentration ng/m³ 0.00002
Concentration
Maximum
0.00002
Units
Parameter
Maximum
ng/m³
Concentration
0.00002
Maximum
0.00002
DIOXINS & FURANS: RESULTS SUMMARY(PAGE 3 OF 4)
Units
Maximum
Concentration
Blank 1
ng/m³
Units
Parameter
Parameter Units Blank 1
0.00002
Concentration ng/m³ 0.0002
Maximum
Parameter
CAT-RT (Version BV)
Page 17 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
- -
- -
- -
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, dry gas.
Name of Analytical Laboratory
Value
(PAGE 4 OF 4)
Kingspan Insulation Ltd, Castleblayney
MAR
Titanium
Borosilicate Glass
Uncertainty ±% v/v 0.41
Yes
Positioning of Filter
Probe Material
Parameter
Technical Procedure
A2-14 RTO Outlet
Water Vapour % v/v
4 / 4
CAT-TP-07
Out Stack
90mm Quartz Fibre
Number of Sampling Lines Used 1 / 1
XAD-2
Glassware Material
Absorption Material
7.41
APPENDIX 2
Analytical Laboratory's Procedure
07/06/2018
DIOXINS & FURANS: RESULTS SUMMARY
7.41
Mean
Date of Sample Analysis
Filter Size and Material
Parameter Units
ISO 17025 Accredited Analysis?
Number of Sampling Points Used
WI 1122
Run 1
EN 1948
0.41
Filter Housing Material Borosilicate Glass
Standard
Sample Point I.D.'s A1 - A4
CAT-RT (Version BV)
Page 18 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
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EPA Export 18-08-2018:04:04:19
Absolute pressure of stack gas, Ps
Volume of water vapour collected, Vwstd
Volume of gas metered dry, Vmstd
Moisture content, Bwo & Rwv
Bwo as a percentage
Reported Water Vapour, checked with Tables in EN 14790, Rwv
Volume of gas metered wet, Vmstw
Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂
Molecular weight of dry gas stream, Md
CO₂
O₂
Molecular weight of stack gas (wet), Ms
Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)
Percent isokinetic, %I
Average square root of velocity heads, √∆P
8.47
107.5
0.17
30.3
756.8
-9.2
Vmstw = (Vmstd)(100/(100 - Rwv))
% v/v
m³
757.5
N/A
Barometric pressure, Pb mmHg
Units Run 1
mmHg
Gas meter correction factor, Yd - 0.9220
Vmstd@X%oxygen = (Vmstd) / (O₂REFd)
Test
N/A
m³
Bwo = Vwstd / (Vmstd + Vwstd)
-
N/A
m³/min
m³
297.0
gTotal mass collected in impingers (silica trap)
0.4283
0.84
5.7831
Ps = (Pb + (Pstatic / 13.6)
g
% v/v 0.36
N/A
27.62
% v/v 20.36
N/A
mmH₂OAverage of velocity heads, ∆Pavg
- 34.97
Total mass of liquid collected, Vlc g
O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)
Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol
Pitot tube velocity constant, Kp
79.64
N/A
% v/v
Qa = (60)(As)(Vs)
√mmH₂O
343.7
N/A
28.05
Velocity pressure coefficient, Cp -
87.3
-
36.8
%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))
20.4
No
Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol
5.3548
mmH₂O
Total mass collected in impingers (liquid trap)
m³ 6.2450
% v/v
mmH₂O
DIOXINS & FURANS: ISOKINETIC SAMPLING CALCULATIONS
7.41
46.7
Stack static pressure, Pstatic
APPENDIX 2
% dry oxygen measured in gas stream, ACT%O₂d % v/v
°CAverage dry gas meter temperature, Tm
Volume of gas sample through gas meter, Vm
% v/v
% wet oxygen measured in gas stream, ACT%O₂w
Average pressure drop across orifice, ∆H
% oxygen reference condition, REF%O₂ % v/v N/A
Vwstd = (0.001246)(Vlc)
Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³
7.41
Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min
% 107.0
Area of stack, As m²
Average stack gas temperature, Ts °C
N₂ % v/v
28.86
Velocity of stack gas, Vs
Conversion factor (K/mm.Hg), Cf
10.33
m³/min
Vmstw@X%oxygen = (Vmstw) / (O₂REFw)
Total sampling time, q min
m³ 0.0741
Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273) m³/min 94.3
2.91
Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s
20.00
-
Nozzle area, An
IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)
m³ N/A
Total
-
QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min
360
O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)
QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)
0.3592
mm²
Nozzle diameter, Dn mm 5.93
CAT-RT (Version BV)
Page 19 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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Where: ISO stands for Manual Isokinetic Sampling Train
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HPeCDD
OCDD
Total Dioxins
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HPeCDF
1234789-HPeCDF
OCDF
Total Furans
Totals
Total Concentration
Limit of Detection
Where: ND stands for Non Detected
DL stands for Analytical Detection Limit
TEQ1 refers to Non Detected Congeners at the Detection Limit
TEQ2 refers to Non Detected Congeners at Zero
% Rec stands for the Recovery Percentage of the Sample
- - -
0.0007
102
0.00350.0035
0.0004
0.0009
0.0035
0.0000
0.0001
0.0002
0.0000
ND
1010.0002
0.0185
0.0017
ng
960.0004
0.0003
0.0003
0.0035
0.0009
0.0037
-
0.0000
0.0082 0.0064
0.0000
-
ng/m³ -
-
- 0.0003
-
0.0185
0.00000.0000
0.0026
0.0776
0.0022
0.0119
- 0.0003
0.0142
0.0026
0.0118
0.00020.0023
0.0000
0.0007
-
0.0000
0.0007
0.0003
0.0004
0.0007
0.0000
0.0035
0.0043
0.0000
0.0007
0.0000
0.0000
121
0.0005
0.0010 0.0006
0.0003
92
84
0.0000
0.0003
0.0043
0.0000
0.0002
0.0026
0.0000
128
TEQ1 TEQ2 TEQ1
0.0010
0.0026
ng 0.0007
0.0002
0.0001
0.0002
0.0017
0.0202
0.00000.0026
0.0006
0.0021
0.0086
0.00000.0036
-
0.0000
0.0002
0.0007
0.0001
ng
0.0000
0.0000
140
0.0003
ng
-
0.0004
0.0000
0.0002
0.0000
0.0003
Sampling Dates
Sampling Device
ng
0.0007
82
0.00030.0063ng
91
85
0.0001
0.0002
Units
0.0023
0.0000
0.0063
0.0023
0.0062ng
0.0007
0.0000
0.0006
0.0000
0.0000
0.0082
0.0001
0.0000
0.0079
0.0002
0.0005
-
0.0079
0.0005
0.0000
0.0063
m³
Value
ISO
ng
- -
ng 0.1374 0.0229
0.0043
0.0000
0.0000
10:57 - 16:57
0.0033
Sampling Times
0.0050
0.0006
0.0035
WHO
Birds
-
0.0010
0.0002
0.0005
0.00440.0597
0.0002 0.0002
0.0021
DL
93
0.0063
0.0010
0.0001
0.0086
0.0002
0.0007
ng 0.0005
WHO Humans /
Mammals
WHO
Fish
ng
0.0086
0.0007
0.0010
0.0009 0.0009
0.0054
0.0002ng
0.0072
0.0228
0.0000
0.0000
0.0009
ng
0.0000
0.0002
0.0000
0.0005
0.0002
0.0004
0.0004
0.0006
0.0137
0.0007
ng/m³
Volume Sampled (REF)
TEQ2
0.0006
0.0007
0.0010
ng
0.0006
0.0010
0.0063
0.0043
0.0094
TEQ2
76
0.0010
0.0009
-
114
139
81
Parameter Units Result
RUN 1
0.0035
0.0002
0.0100 0.0005
0.0005 0.0009
0.0002
0.0009
ng
0.0006
0.0002
0.0001
0.0002
0.0000
0.0003
0.0043
TEQ1 TEQ2 TEQ1
Parameter
0.0022
0.0115 0.0225
0.0042
0.0113
0.0045
0.0003
0.00010.0065
15/05/2018
5.3548
NATO
I-TEQ
ND
0.0010ng
APPENDIX 2
DIOXINS & FURANS: SAMPLING DETAILS
0.0004
0.0002
0.0000ng
ng
0.0058
0.0237
0.0007
0.0007
0.0000
-
0.0004
% Rec
0.0002
0.0040
-
ng
ng
0.0000
CAT-RT (Version BV)
Page 20 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Where: ISO stands for Manual Isokinetic Sampling Train
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HPeCDD
OCDD
Total Dioxins
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HPeCDF
1234789-HPeCDF
OCDF
Total Furans
Totals
Total Concentration
Where: ND stands for Non Detected
DL stands for Analytical Detection Limit
TEQ1 refers to Non Detected Congeners at the Detection Limit
TEQ2 refers to Non Detected Congeners at Zero
% Rec stands for the Recovery Percentage of the Sample
0.0000
Parameter
TEQ1
0.0000 0.0000
132
TEQ2 TEQ1
0.0000
ng
Units
85
0.0000ND
0.0000
TEQ2
Sampling Device -
0.0000
0.0000
TEQ2
0.0000
0.00000.0003
0.0000
0.0000
0.0000
0.0000
-
0.0000
0.0000
0.0004 0.0000
0.00000.0000
107
TEQ2 TEQ1
WHO Humans /
Mammals
0.0001
NATO
I-TEQ
(Continued)
0.0000
104
-
-
0.00000.0003
0.0000
0.0000 0.0004 0.0000
0.0000
BLANK 1
% Rec
0.0002
0.0037
0.00000.0000
Sampling Dates
930.0000
ND
82
-
0.0000
90
150
ng 0.0003
0.0000
0.0013
0.0012
0.0000
0.0002 0.00000.0002ng/m³
0.0000
0.0000
0.0000
0.0003
0.0000
0.0003
0.0000
ND
0.0002
0.0000
0.0002
0.0000
0.0000 0.0000 0.0000
ng
0.0004
0.0000
0.0002
0.0000 0.0000 0.0000
0.0001
0.0010 0.0001
0.0000 0.0000
0.0001 0.0015
0.0003
0.0000
0.0005
0.0000
0.0000
0.0001ng
0.0000
0.0000
0.0000
0.0000 0.0000 0.0000 0.0000ng
0.0000 0.0000 0.0000
0.0000
0.0000 0.0000
0.0000
0.0000 0.0000 0.0000
0.0000
ND
0.0169
87
0.0003
0.0011 0.0001ng
- - 0.0003
0.0011
0.0008
ng
0.0003 0.0000
75
0.0000
95
0.0000
0.0000
0.00000.0000
0.0000
ND
0.0000
ng ND
0.0000ng
ng
0.0000
0.0000
0.0000
0.0000 0.0000
0.0000
0.0000 0.0000 0.0000
0.0003
154
0.0000 0.0000
0.0000
0.0003
0.0008
0.0000
ng
ng 0.0000 0.0000
TEQ1
0.0002
0.0003
ISO
WHO
Fish
DLResult
-
0.0000
0.0000
ND
0.0000
0.0002
0.0007
0.0000
0.0002
0.0000
ng ND 0.0002 0.0000 81
0.0000
0.0000
0.0137
0.0000
0.0001
0.0000
0.0100
-
0.0003
5.3548
0.0003 0.0000
0.0000 0.0000
ng ND
0.0006 0.0000 0.0008
Average Volume Sampled (REF)
APPENDIX 2
DIOXINS & FURANS: SAMPLING DETAILS
0.0000
0.0006
0.0000
0.0000
0.0000 0.0000
0.0000
0.0000
0.0000
0.0004
ND
0.0000
ng
Parameter Units
-
0.0000
0.0000
15/05/2018
m³
Value
0.0000
0.0000
WHO
Birds
0.0003
0.0000
0.0000
ng
0.0000
120
ng 0.0032 - 0.0003 0.0001
126
0.0000
-
0.0000
ng 0.0002
0.0000
0.0004
0.0000
0.0003 0.0001 0.0001
0.0000
ND
0.0003
0.0000
ng
96
0.0003
0.0000
ng
0.0002
CAT-RT (Version BV)
Page 21 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sample Runs
(PAGE 1 OF 2)
Run 1
MU (Concurrent Water Vapour) Run 1
Maximum Allowable Temperature
Pre-Sampling Leak Rate
APPENDIX 2
DIOXINS & FURANS: QUALITY ASSURANCE
Units
Allowable Isokinetic Range
Units Run 1
19
Units
Units
Water Droplets
Measurement Uncertainty (MU)
%
% Yes
Allowable MU
Isokinetic Variation
°C
l/min 0.24
Mean Sampling Rate
107.0
-
Test Conditions Units
YesAmbient Temperature Recorded?
- Yes
-
%
No
Isokinetic Criterion Compliance
Post-Sampling Leak Rate
Leak Test Acceptable
Units
%
Are Water Droplets Present
Maximum Temperature Recorded
Condenser Exit Temperature
Run 1
Isokineticity Acceptable -
Temperature Acceptable - Yes
Yes
Leak Test Results
Units
5.6
Yes
°C
l/min
°C 120Maximum Filter Temperature
Maximum Allowable Temperature
Units
125
%
Allowable Leak Rate l/min 0.80
20
Run 1
Less than 50% Faded
MU Acceptable -
0.21
95 - 115
Yes
Filter Temperatures
Run 1
15.99
Run 1
l/min
Silica Gel (Concurrent Water Vapour)
-
Exit Temperature Acceptable
Run 1
°C
20
CAT-RT (Version BV)
Page 22 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Blank Runs
Method Deviations
1
wx
- - - - -
- - - - -
- - - - -
- - - - -
- - - - -
(PAGE 2 OF 2)
Nature of Deviation
Leak Test Acceptable
Yes
One out of two sampling lines was used due to sampling location restrictions, however the number of sample points used on the available
line were increased to the minimum required by the Standard
l/min 0.15
Units Blank 1
Yes
-
l/min
Blank Acceptable
Validity of NATO I-TEQ Blank vs ELV
-
l/min 15.00
Units
DIOXINS & FURANS: QUALITY ASSURANCE
Blank 1
Expected Sampling Rate
0.0100
Allowable Leak Rate
Allowable Blank
0.75
ng/m³
Sampling Leak Rate
Leak Test Results
APPENDIX 2
Run Number
(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)
CAT-RT (Version BV)
Page 23 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
% N/A
ng/m³
0.0005
20.4
0.68
1.00
Parameter
ng/m³ 0.0002
Measured Quantities
%
- N/A
%
N/A
%
0.0002
ng/m³
Symbol
Units Run 1
10.00 No Requirement
ng/m³
m³ 5.3548
ng/m³
Vm 0.00
Run 1
0.0000
%
- N/A
%
uTm
N/A
≤5%
Oxygen Correction Part of MU Budget
uLr
Run 1
K
Measured Quantities
1.00
1.00
% v/v N/A
Uncertainty in Result
Measured Quantities
20.4
%
0.0000
≤1%
0.5
Units
ng/m³
20.4
Requirement of Standard
uL
% v/v 1.0
L
ng/m³
ng/m³
kPa
0.0
0.0002
0.0005
Units
Units Run 1
0.0005
Symbol
%
ρm
≤1%
Uncertainty in Measurement Units
2.00
L
%
uρm
Units
Lr
uHm
Run 1
Run 1
%
ng/m³ 0.0001
Sensitivity Coefficient
%
Standard uncertainty
Vm
Measured Quantities
0.50
%
Uncertainty as a Percentage
1.50
≤1%
Symbol Run 1
Tm
%
m³6.2450
Lr 10.00
-
Hm
Measured Quantities
APPENDIX 2
UnitsRun 1
uVm 0.1249
100.9
2.0293.4
ng/m³
-
1.50
DIOXINS & FURANS (NATO I-TEQ): MEASUREMENT UNCERTAINTY CALCULATIONS
Value
≤2%
Overall MU For O₂ Measurement
CAT-RT (Version BV)
Page 24 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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Sample Runs
- -
- -
- -
- -
- -
- -
- -
- -
Blank Runs
- -
< <
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, dry gas.
MeanRun 1
0.06
5.2
Units
Blank 1
Uncertainty
Parameter Units
Uncertainty
0.06
12.02
5.56
63.0
Date of Sample Analysis
Concentration
ISO 17025 Accredited Analysis?
A2-14 RTO Outlet
APPENDIX 2
0.25
Maximum
Stainless Steel
Filter Housing Material Titanium
CAT
Number of Sampling Points Used
0.1μm Glass Fibre
HPLC Grade Water
mg/m³ 12.02
Impinger Material Polyethylene
Absorption Solution
1 / 1
Out Stack Heated Head
Filter Size and Material
Run 1
5.56Water Vapour % v/v
0.78
0.25
24/05/2018
Units
Positioning of Filter
5.2
63.0
±% v/v
Mass Emission
Sample Point I.D.'s
Probe Material
CAT-TP-11
Concentration mg/m³
0.78
Number of Sampling Lines Used
A1
1 / 4
±g/hr
Standard EN 1911
Technical Procedure
Parameter
Parameter
±mg/m³
Yes
Name of Analytical Laboratory
CAT-AP-01
Value
Uncertainty
Mean
HYDROGEN CHLORIDE: RESULTS SUMMARY
Analytical Laboratory's Procedure
Parameter
Kingspan Insulation Ltd, Castleblayney
g/hr
CAT-RT (Version BV)
Page 25 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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Sample Runs
-
-
-
-
-
-
-
-
Where: MFC stands for Mass Flow Controller, MV stands for Mass View Flowmeter
Blank Runs
<
-
<
<
0.05
ml
Laboratory Result for Impingers µg/ml
Total Mass Of Water Vapour g
Calculated Concentration mg/m³
Parameter
Duration
Volume in Impingers
Units Blank 1
Total Mass Collected µg 15.5
Blank Dates - 16/05/2018
Average Volume Sampled (REF) m³ 0.2813
Sample Flow Rate l/min
HYDROGEN CHLORIDE: SAMPLING DETAILS
- 16/05/2018
Sampling Device - MFC / MV
1.62
240.8
µg
54.1
Sampling Times - 11:18 - 11:48
mins 30
Sampling Dates
2113.2Liquid Trap End Mass
Volume Sampled (STP, Wet) m³
Mass in Back Impinger µg 87.6
Total Mass Collected µg 3381.8
Mass in Front Impingers
g
0.06
Laboratory Result for Front Impingers
Silica Trap Start Mass
13.68
Laboratory Result for Back Impinger
Volume Sampled (STP, Dry) m³ 0.2813
g 2101.3
µg/ml
12.02Calculated Concentration mg/m³
Liquid Trap Start Mass
13.3
Calculated Water Vapour % v/v 5.56
APPENDIX 2
3294.1
0.2978
310.1
Parameter Units Run 1
Volume in Front Impingers
Volume in Back Impinger
µg/ml
g 899.5
9.36
ml
ml
g 898.1
Volume Sampled (REF) m³ 0.2813
Silica Trap End Mass
CAT-RT (Version BV)
Page 26 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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Sample Runs
¹ The concentration in the last absorber was less than 5 times the analytical detection limit. 1 0 11 12
Blank Runs
Method Deviations
1
wx
- - - - -
- - - - -
- - - - -
Pre-Sampling Leak Rate l/min 0.04
APPENDIX 2
HYDROGEN CHLORIDE: QUALITY ASSURANCE
Leak Test Results Units
Pre-Sampling Leak Rate
Yes
Measurement Uncertainty (MU) % 4.5
Allowable MU % 20
MU (Concurrent Water Vapour) Units Run 1
Test Conditions Units Run 1
Expected Sampling Rate l/min 9.50
Are Water Droplets Present
Mean Sampling Rate
0.14
Absorption Efficiency Units Run 1
Absorption Efficiency % 97.4
l/min
Run 1
Water Droplets Units
Yes
Run 1
Allowable Absorption Efficiency % N/A ¹
Leak Test Results Units
Silica Gel (Concurrent Water Vapour)
Blank 1
Leak Test Acceptable -
Yes-
Yes ¹
Allowable Leak Rate l/min 0.19
Ambient Temperature Recorded? -
-
- No
Units Run 1
l/min
Nature of Deviation Run Number
(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)
There are no deviations associated with the sampling employed.
Allowable Blank
Absorption Efficiency Acceptable -
mg/m³ 3.0
Blank 1
Blank Acceptable
Allowable Leak Rate l/min 0.19
Units
Leak Test Acceptable
Validity of Blank vs ELV
Less than 50% Faded % Yes
Post-Sampling Leak Rate
Yes
MU Acceptable % Yes
9.36
l/min 0.11
Post-Sampling Leak Rate l/min 0.01
CAT-RT (Version BV)
Page 27 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
mg/m³ 0.78
% v/v
Measured Quantities Run 1
Uncertainty in Measurement Units
1.00
L
HYDROGEN CHLORIDE: MEASUREMENT UNCERTAINTY CALCULATIONS
Requirement of Standard
%
Symbol
mg/m³
mg/m³
Standard uncertainty
mg/m³
N/A
%
2.00
0.104
%
Oxygen Correction Part of MU Budget
≤2%
%
Lr
0.2813
mg/m³
0.1038
uL
Lr
Vm
1.50
uLr
%
Symbol
APPENDIX 2
m³
Run 1Units
42.75
% 6.5
0.2813 uVm
L 1.50
Run 1
Value
≤2%
0.2405
Vm
Measured Quantities
Run 1
1.00
mg/m³
N/A
UnitsParameter
Measured Quantities Units Run 1
mg/m³
6.5
-
- N/A
0.40
6.5
mg/m³
Measured Quantities
-
Overall MU For O₂ Measurement
% N/A
0.78
mg/m³ 0.78
Units Run 1
0.301
mg/m³ 0.3006
No Requirement
Measured Quantities Symbol
Uncertainty in Result
2.50
Run 1
% -
0.0056
Units Run 1
2.50
m³
Uncertainty as a Percentage
N/A
%
% N/A
Units
Sensitivity Coefficient
CAT-RT (Version BV)
Page 28 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sample Runs
- -
< <
- -
< <
- -
- -
- -
- -
Blank Runs
- -
< <
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, dry gas.
Parameter
APPENDIX 2
Units
Kingspan Insulation Ltd, Castleblayney
A2-14 RTO Outlet
0.030 0.030
CAT-TP-10
Name of Analytical Laboratory CAT
0.38 0.38
1 / 4
ISO 15713
Technical Procedure
Sample Point I.D.'s A1
Value
Probe Material Monel
29/05/2018
0.07
MeanRun 1
Water Vapour % v/v
Concentration mg/m³ 0.07
HYDROGEN FLUORIDE: RESULTS SUMMARY
0.004
MeanUnits
Uncertainty ±mg/m³
±g/hr
0.004
Mass Emission g/hr 0.4
9.32 9.32
Parameter Run 1
Uncertainty ±% v/v
0.4
Uncertainty
Parameter Units Blank 1 Maximum
Concentration mg/m³ 0.05
Parameter
1 / 1
Number of Sampling Points Used
0.05
Filter Housing Material Monel
Impinger Material Polyethylene
Absorption Solution 0.1 mol/l Sodium Hydroxide
Positioning of Filter Out Stack Heated Head
Filter Size and Material 0.1μm Glass Fibre
CAT-AP-01
ISO 17025 Accredited Analysis? Yes
Standard
Date of Sample Analysis
Number of Sampling Lines Used
Analytical Laboratory's Procedure
CAT-RT (Version BV)
Page 29 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sample Runs
<
<
-
-
<
<
<
<
Where: MFC stands for Mass Flow Controller, MV stands for Mass View Flowmeter
Blank Runs
<
-
<
<
Volume in Impingers
Laboratory Result for Impingers µg/ml
ml
1270.2
µg 20.2
MFC / MV
- 15/05/2018
Calculated Water Vapour % v/v
g 1255.9
Sampling Device
Duration 30
Volume Sampled (REF) m³
Sample Flow Rate l/min 9.81
mins
Volume Sampled (STP, Dry)
APPENDIX 2
HYDROGEN FLUORIDE: SAMPLING DETAILS
Parameter
m³ 0.2948
-
Sampling Times
Sampling Dates
- 09:10 - 09:40
Units Run 1
Blank Dates -
Volume Sampled (STP, Wet) m³ 0.3250
0.2948
9.32
Silica Trap End Mass g 884.9
mg/m³ 0.07
µg/ml 0.05
305.8
Total Mass Collected
Liquid Trap End Mass
Calculated Concentration
g
0.05
g
Laboratory Result for Front Impingers µg/ml 0.05
Laboratory Result for Back Impinger
Volume in Back Impinger ml 122.7
Mass in Front Impingers µg 14.1
Mass in Back Impinger µg 6.1
Total Mass Of Water Vapour 24.3
Total Mass Collected µg
Silica Trap Start Mass g 874.9
15.3
0.05
Liquid Trap Start Mass
15/05/2018
Parameter Units Blank 1
Volume in Front Impingers ml 281.9
Calculated Concentration mg/m³
Average Volume Sampled (REF) m³ 0.2948
CAT-RT (Version BV)
Page 30 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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Sample Runs
² The concentration is less than 30% of the ELV, therefore no assessment against an allowable efficiency is required. 1 7 0 8
Blank Runs
Method Deviations
1
wx
- - - - -
- - - - -
- - - - -
MU (Concurrent Water Vapour) Units Run 1
%
9.81
Leak Test Acceptable - Yes
Water Droplets
Mean Sampling Rate l/min
Units Run 1
APPENDIX 2
HYDROGEN FLUORIDE: QUALITY ASSURANCE
Allowable Absorption Efficiency
Expected Sampling Rate
Are Water Droplets Present - No
Absorption Efficiency % 100.0
N/A ²
Silica Gel (Concurrent Water Vapour)
-
Units
Units
Pre-Sampling Leak Rate l/min 0.14
Measurement Uncertainty (MU) % 4.1
Less than 50% Faded
Allowable MU
%
Run 1
Run 1
Post-Sampling Leak Rate l/min 0.04
Nature of Deviation
Blank 1
l/min 0.08
l/min 0.08
Blank Acceptable -
Leak Test Results
Leak Test Acceptable - Yes
Allowable Leak Rate l/min 0.20
Absorption Efficiency Units Run 1
Allowable Leak Rate
Absorption Efficiency Acceptable - Yes ²
l/min 0.20
Yes
Pre-Sampling Leak Rate
% Yes
Leak Test Results
Units Run 1
mg/m³ 0.2
Yes
Post-Sampling Leak Rate
MU Acceptable
% 20
Test Conditions
l/min 10.00
Units Blank 1
Yes
Ambient Temperature Recorded?
Validity of Blank vs ELV Units
Run Number
(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)
There are no deviations associated with the sampling employed.
Allowable Blank
CAT-RT (Version BV)
Page 31 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
-
≤2%
% 0.41
Requirement of Standard
Units Run 1
L 0.41
Measured Quantities Symbol Run 1
2.00
0.00
0.00
0.0014
Run 1
% 6.5
UnitsParameter
6.5
uVm m³
Symbol
% N/A
%
mg/m³ 0.00
%
Lr 2.65
m³
mg/m³
Run 1
HYDROGEN FLUORIDE: MEASUREMENT UNCERTAINTY CALCULATIONS
uL % -
Measured Quantities
mg/m³
Units
Oxygen Correction Part of MU Budget
Measured Quantities Units
1.00
Lr mg/m³
0.0059
0.002
Vm
0.0018
Uncertainty in Measurement Units Sensitivity Coefficient
- N/A
L
0.00
%
N/A
%
-
Overall MU For O₂ Measurement N/A
Vm
mg/m³
1.00
0.2948
Uncertainty in Result
mg/m³
%
≤2%
mg/m³
N/A
mg/m³
2.65
mg/m³
0.000
Value Standard uncertainty
APPENDIX 2
uLr
Units
Symbol
% v/v
Units Run 1
%
Measured Quantities
0.2948
mg/m³ 0.0002
0.23
Run 1
Measured Quantities
Run 1
6.5
Run 1
N/A
No Requirement
Uncertainty as a Percentage
CAT-RT (Version BV)
Page 32 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Sample Runs
- -
< <
< <
< <
< <
< <
< <
< <
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, dry gas.
Total mg/m³ 12.57
CEN/TS 13649
Probe Material Stainless Steel
2.03Trichloroethylene
Carbon Tetrachloride
4.05
2.03
4.05
mg/m³
mg/m³
Benzene
2.03
2.03
2.03
2.03
Parameter
Chloroform
2.03
A2-14 RTO Outlet
mg/m³
mg/m³
mg/m³ 2.03
mg/m³
Yes
Number of Sampling Lines Used 1 / 1
12.57
Technical Procedure CAT-TP-16
Name of Analytical Laboratory CLS
Standard
Dichloromethane
Tetrachloroethylene
Kingspan Insulation Ltd, Castleblayney
Sample Point I.D.'s A1
1 / 4
ORGANICS CLASS I : RESULTS SUMMARY
Mean
Value
Coconut Shell Charcoal
Date of Sample Analysis 31/05/2018
Sample Tube Type
Units Run 1
Parameter
APPENDIX 2
Analytical Laboratory's Procedure GC/MS
ISO 17025 Accredited Analysis? See Executive Summary
0.41 0.41
Dynamic Dilution Employed
Number of Sampling Points Used
CAT-RT (Version BV)
Page 33 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Where: MV stands for Mass View (Mass Flow Controller Technology)
< < - < <
< < - < <
< < - < <
< < - < <
< < - < <
< < - < <
- < <
Reference Conditions are: 273K, 101.3kPa, dry gas.
Tube Lot Number and Unique ID: 739340-1
100.0
Dichloromethane
5.0
Trichloroethylene 5.0
2.027 2.027
Concentration
mg/m³
2.027 2.027 2.027
Sampling Times
Duration
1.0
10.0
ORGANICS CLASS I : SAMPLING DETAILS
-
5.0 10.0
5.0
10.0 20.0
Value
Sampling Dates
Lab Result
(Back)
µg
Lab Result
(Total)
µg
-
12.57062.0 12.570
mins
62.0
Tetrachloroethylene
5.0 5.0 10.0
Total 12.570
30
Benzene
1.5
Chloroform
10.0
APPENDIX 2
-
-
AG2 Reporting Format ELV (mg/m³)
Organics Class I 20 > 0 and < 12.57 > (sum of ) and < (sum of 1+2+3+4+5+6)
10.0
10.0 2.027 2.027 2.027 100.0
Sampling Device
LOD
(Total)
µg
Parameter
20.0 4.055
MV
Volume Sampled (REF) m³ 0.0049
RUN 1
Parameter
5.0 10.0
2.0 1.0 0.405
4.055 4.055 100.0
LOD
(Back)
µg
Reported
Concentration
(Blank Reviewed)
mg/m³
2.0 0.405
2.0275.0
- 15/05/2018
1.0 1.0
12:30 - 13:00
10.0
LOD
(Front)
µg
0.405 100.0
Carbon Tetrachloride 5.0
Reported
LOD
mg/m³
Adsorption
Efficiency
%
2.027 2.027 2.027 100.0
: 1N₂ to Stack Gas Dilution Ratio
Results (mg/m³) Breakdown of Results Exceedance?
100.0
5.0
10.0 10.0
5.0 5.0 10.0 5.05.0
5.0
5.0
Lab Result
(Front)
µg
Units
CAT-RT (Version BV)
Page 34 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Where: MV stands for Mass View (Mass Flow Controller Technology)
< < - <
< < - <
< < - <
< < - <
< < - <
< < - <
Reference Conditions are: 273K, 101.3kPa, dry gas.
Tube Lot Number and Unique ID: 739340-1
APPENDIX 2
Benzene
Dichloromethane
2.027
2.027
20.0 4.055
Tetrachloroethylene 5.0 5.0
Trichloroethylene 5.0 5.0 10.0
10.0
Units
Sampling Device - MV
Average Volume Sampled (REF) m³ 0.0049
Parameter Lab Result
(Front)
µg
Lab Result
(Back)
µg
5.0
15/05/2018
ORGANICS CLASS I : SAMPLING DETAILS
BLANK 1
Parameter
10.0
5.0 10.0 2.027
10.0 2.027
Chloroform
Lab Result
(Total)
µg
Concentration
mg/m³
1.0 2.0 0.405
Carbon Tetrachloride 5.0 5.0
10.0
1.0
Sampling Dates -
Value
CAT-RT (Version BV)
Page 35 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Sample Runs
Allowable Leak Rate
0.000
Yes
°C 11
%
-
%
%
APPENDIX 2
l/min
0.000
ORGANICS CLASS I : QUALITY ASSURANCE
Leak Test Results Units
Run 1
Trichloroethylene
Adsorption Efficiency Units
l/min
%
Benzene %
-Leak Test Acceptable
100.0
Dichloromethane
%
Pre-Sampling Leak Rate
Carbon Tetrachloride
l/min
95
0.400
l/min
0.020
100.0Chloroform
% 100.0
100.0
Run 1
Mean Sampling Rate
Tetrachloroethylene
Yes
100.0
Post-Sampling Leak Rate
100.0
(PAGE 1 OF 2)
Yes
Run 1
Allowable Temperature
-
Adsorption Efficiency Acceptable
°C
-Ambient Temperature Recorded?
Allowable Adsorption Efficiency
Temperature
40
Test Conditions Units
Yes
Run 1
Temperature Acceptable
Temperature at Sample Tubes Units
CAT-RT (Version BV)
Page 36 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Blank Runs
Method Deviations
1
x
- - - - -
- - - - -
- - - - -
12.6 2.0
0.400
0.020
Validity of Blank vs ELV Units
Allowable Leak Rate
Allowable for Chloroform
2.0
mg/m³
There are no deviations associated with the sampling employed.
Allowable for TOTAL
(x = deviation applies to the associated run)
Nature of Deviation
Allowable for Benzene
UnitsLeak Test Results
Sampling Leak Rate
Expected Sampling Rate
2.0 N/A
l/min
Allowed
mg/m³ N/A
mg/m³
mg/m³
0.000
(PAGE 2 OF 2)
Leak Test Acceptable
N/A
l/min
2.0
Allowable for Carbon Tetrachloride
Blank 1
N/A
Allowable for Dichloromethane
Allowable for Tetrachloroethylene
Allowable for Trichloroethylene
0.4
N/A
mg/m³
mg/m³
mg/m³
l/min
- Yes
4.1
Run Number
Blank 1
APPENDIX 2
ORGANICS CLASS I : QUALITY ASSURANCE
2.0
N/A
CAT-RT (Version BV)
Page 37 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
NOTE: Uncertainties reported in mg/m ³ are based upon the summation of all Speciated VOCs Measured.
mg/m³
Run 1
Run 1
Run 1
mg/m³
Measured Quantities
2548.52Vm
mg/m³ 1.282
20.0
m³
1.2570
0.00
Run 1
-
Symbol
L
0.0
1.00
Run 1
1.257
% ≤5%
uLr
Uncertainty in Result
0.2514
mg/m³ 0.0000
2.00
Run 1
APPENDIX 2
10.00
m³
Measured Quantities
% ≤2%
0.000 uL %
Vm uVm
ORGANICS CLASS I : MEASUREMENT UNCERTAINTY CALCULATIONS
Run 1Units
0.0049
mg/m³
L mg/m³
Lr -
mg/m³
Uncertainty as a Percentage
No Requirement
N/A
0.000
Oxygen Correction Part of MU Budget
0.0049
% 10.00
Uncertainty in Measurement Units
2.513
%
Lr
- N/A
N/A
Units
N/A
2.513
20.0
mg/m³ N/A
%
Parameter
Overall MU For O₂ Measurement
2.513
Sensitivity Coefficient
Symbol Units
Measured Quantities Symbol
Value
Requirement of StandardUnits
Measured Quantities
1.00
Units
Standard uncertainty
Run 1
mg/m³
mg/m³
%
% N/A
% v/v
Measured Quantities
%
20.0
%
-
Units
CAT-RT (Version BV)
Page 38 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
For
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EPA Export 18-08-2018:04:04:19
Sample Runs
- -
< <
< <
< <
< <
< <
< <
< <
< <
< <
< <
< <
< <
< <
< <
< <
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, dry gas.
Number of Sampling Lines Used
Coconut Shell Charcoal
Methyl-iso-butyl
1.95
Cyclohexane mg/m³ 1.95
0.39
Total mg/m³ 32.00
Name of Analytical Laboratory RPS
Analytical Laboratory's Procedure
1.95
mg/m³
Tetrahydrofuran mg/m³
Probe Material
GC/MS
ISO 17025 Accredited Analysis? See Executive Summary
1 / 1
Yes
1.95
1.95
mg/m³
1.95
mg/m³ 0.39
o-Xylene mg/m³
3.90
ORGANICS CLASS II : RESULTS SUMMARY
Kingspan Insulation Ltd, Castleblayney
0.39
3.90
3.90
Heptane mg/m³ 1.95
1 / 4
31/05/2018
Number of Sampling Points Used
Units Run 1
CAT-TP-16
Dynamic Dilution Employed
Value
A1
Date of Sample Analysis
3.90
mg/m³ 3.90
1.95
32.00
Standard CEN/TS 13649
Technical Procedure
A2-14 RTO Outlet
Parameter
1.95
3.90
Ethyl Acetate
3.90 3.90
m + p-Xylene
1.95
Stainless Steel
Cyclohexanone
Acetone
Parameter
1.95
Mean
mg/m³ 1.95
1.95
Hexane
Sample Point I.D.'s
APPENDIX 2
mg/m³
Toluene
Sample Tube Type
Ethanol mg/m³
Methyl Ethyl Ketone mg/m³ 1.95
0.39
1.95
2-Propanol mg/m³
1.95
mg/m³
CAT-RT (Version BV)
Page 39 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
For
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EPA Export 18-08-2018:04:04:19
Where: MV stands for Mass View (Mass Flow Controller Technology)
< < - < <
< < - < <
< < - < <
< < - < <
< < - < <
< < - < <
< < - < <
< < - < <
< < - < <
< < - < <
< < - < <
< < - < <
< < - < <
< < - < <
- < <
Reference Conditions are: 273K, 101.3kPa, dry gas.
Tube Lot Number and Unique ID: 739340-1
Units Value
Reported
Concentration
(Blank Reviewed)
mg/m³
100.0
Duration
m + p-Xylene 1.0
Lab Result
(Total)
µg
LOD
(Front)
µg
LOD
(Back)
µg
LOD
(Total)
µg
Concentration
mg/m³
5.0 5.0
5.0 10.0
Methyl-iso-butyl Ketone 5.0 5.0 10.0 5.0 5.0 100.0
1.951 1.951
100.0
Heptane 5.0 10.0 1.951
5.0 10.0 5.0
10.0 1.951 1.951
20.0 3.903
1.951 1.951 100.0
Hexane 10.0
1.951
20.0 3.903
Parameter Lab Result
(Front)
µg
100.0
Reported
LOD
mg/m³
Adsorption
Efficiency
%
2-Propanol 5.0 10.0 5.0
10.0 20.0
10.0
10.0 5.0 5.0 10.0
-
: 1 1.5
Lab Result
(Back)
µg
5.0
5.0
Acetone 10.0
5.0 5.0 10.0 5.0
1.951 1.951 1.951
10.0 1.951 1.951 1.951
10.0 10.0
20.0 10.0 10.0
0.390
164.0
5.0
10.0 5.0 5.0
3.903
3.903 3.903Ethyl Acetate 10.0
1.0 2.0
20.0 3.903 3.903
Cyclohexane
Ethanol 10.0
10.0
1.951 1.951 1.951 100.0
100.0
5.0
1.0 1.0 2.02.0 1.0 100.0
1.0 2.0 1.0
10.0 10.0 3.903 100.010.0 20.0
100.0
3.903 100.0
1.0 0.390
5.0 10.0
0.390
10.0 10.0 20.0 3.903
3.903 3.903
5.0
5.0
1.951 1.951 1.951
5.0 5.010.0
10.0 20.0
0.390 0.390
1.95110.0 1.951
Tetrahydrofuran 5.0
> 0 and < 32> (sum of ) and < (sum of
1+2+3+4+5+6+7+8+9+10+11+12+13+14)-
164.0 32.004 32.004 -
1.951 100.0
Total
-
1.951
ORGANICS CLASS II : SAMPLING DETAILS
RUN 1
Parameter
Cyclohexanone 5.0 5.0 10.0
100.0
Methyl Ethyl Ketone
100.0
Toluene 5.0
MV
N₂ to Stack Gas Dilution Ratio
mins 30
32.004
-
Sampling Times
APPENDIX 2
Volume Sampled (REF) m³ 0.0051
13:10 - 13:40
Sampling Dates
o-Xylene 0.390
15/05/2018
Sampling Device
AG2 Reporting Format ELV (mg/m³) Results (mg/m³) Breakdown of Results Exceedance?
Organics Class II 100
CAT-RT (Version BV)
Page 40 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
For
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EPA Export 18-08-2018:04:04:19
Where: MV stands for Mass View (Mass Flow Controller Technology)
< < - <
< < - <
< < - <
< < - <
< < - <
< < - <
< < - <
< < - <
< < - <
< < - <
< < - <
< < - <
< < - <
< < - <
Reference Conditions are: 273K, 101.3kPa, dry gas.
Tube Lot Number and Unique ID: 739340-1
Hexane 10.0 10.0 20.0 3.903
m + p-Xylene 1.0 1.0 2.0 0.390
Methyl Ethyl Ketone 5.0 5.0 10.0 1.951
Methyl-iso-butyl Ketone 5.0 5.0 10.0 1.951
o-Xylene 1.0 1.0 2.0 0.390
Tetrahydrofuran 5.0 5.0 10.0 1.951
Toluene 5.0 5.0 10.0 1.951
5.0 10.0 1.951
Acetone 10.0 10.0 20.0 3.903
Cyclohexane 5.0 5.0 10.0 1.951
Cyclohexanone 5.0 5.0 10.0 1.951
Ethanol 10.0 10.0 20.0 3.903
Ethyl Acetate 10.0 10.0 20.0 3.903
Heptane 5.0 5.0 10.0 1.951
APPENDIX 2
ORGANICS CLASS II : SAMPLING DETAILS
BLANK 1
Parameter Units Value
Sampling Dates - 15/05/2018
Sampling Device - MV
Average Volume Sampled (REF) m³ 0.0051
Parameter Lab Result
(Front)
µg
Lab Result
(Back)
µg
Lab Result
(Total)
µg
Concentration
mg/m³
2-Propanol 5.0
CAT-RT (Version BV)
Page 41 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Sample Runs
Adsorption Efficiency Acceptable - Yes
Temperature at Sample Tubes Units Run 1
Test Conditions
Ambient Temperature Recorded? - Yes
Units Run 1
Temperature °C 12
Allowable Temperature °C 40
Temperature Acceptable - Yes
Allowable Adsorption Efficiency % 95
o-Xylene % 100.0
Tetrahydrofuran % 100.0
Toluene % 100.0
Heptane % 100.0
Hexane % 100.0
m + p-Xylene % 100.0
Methyl Ethyl Ketone % 100.0
Methyl-iso-butyl Ketone % 100.0
Acetone % 100.0
Cyclohexane % 100.0
Cyclohexanone % 100.0
Ethanol % 100.0
Ethyl Acetate % 100.0
Post-Sampling Leak Rate l/min 0.010
Allowable Leak Rate l/min 0.020
Leak Test Acceptable - Yes
Adsorption Efficiency Units Run 1
2-Propanol % 100.0
APPENDIX 2
ORGANICS CLASS II : QUALITY ASSURANCE(PAGE 1 OF 2)
Leak Test Results Units Run 1
Mean Sampling Rate l/min 0.400
Pre-Sampling Leak Rate l/min 0.010
CAT-RT (Version BV)
Page 42 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Blank Runs
Method Deviations
1
x
- - - - -
- - - - -
- - - - -
Nature of Deviation
N/A
Allowable for Ethanol mg/m³ 3.9 N/A
Run Number
(x = deviation applies to the associated run)
APPENDIX 2
ORGANICS CLASS II : QUALITY ASSURANCE(PAGE 2 OF 2)
Leak Test Results Units Blank 1
0.400
Allowable for Acetone mg/m³
Allowable for Cyclohexane mg/m³
Allowable for Cyclohexanone mg/m³
2.0 N/A
3.9
Allowable for TOTAL mg/m³
There are no deviations associated with the sampling employed.
3.9 N/A
32.0 10.0
Allowable for o-Xylene mg/m³
Allowable for Tetrahydrofuran mg/m³
Allowable for Toluene mg/m³ 2.0 N/A
0.4 N/A
2.0 N/A
mg/m³
Allowable for Hexane mg/m³
Allowable for m + p-Xylene mg/m³
Allowable for Methyl Ethyl Ketone mg/m³
Allowable for Methyl-iso-butyl Ketone mg/m³
2.0 N/A
3.9 N/A
0.4 N/A
2.0 N/A
2.0 N/A
Allowable for Heptane
Allowable for Ethyl Acetate mg/m³
Sampling Leak Rate l/min 0.000
Allowable Leak Rate l/min 0.020
Leak Test Acceptable - Yes
Validity of Blank vs ELV Units
Allowable for 2-Propanol mg/m³
Blank 1 Allowed
2.0 N/A
2.0 N/A
Expected Sampling Rate l/min
CAT-RT (Version BV)
Page 43 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
NOTE: Uncertainties reported in mg/m ³ are based upon the summation of all Speciated VOCs Measured.
% -
% 20.2
uLr
Units Run 1
Vm 0.0051
1.00
Lr mg/m³ 3.200 1.00
Vm m³
uL % -
Measured Quantities Symbol Run 1 Symbol Units
APPENDIX 2
L
≤2%
% 2.50
Parameter Units Run 1
mg/m³
Units
3.296
Run 1
mg/m³ 6.461
2.500
0.0051
% 20.2
≤5%
% 10.00 No Requirement
Measured Quantities
ORGANICS CLASS II : MEASUREMENT UNCERTAINTY CALCULATIONS
mg/m³ 0.462
Uncertainty as a Percentage
uVm m³ 0.0
Sensitivity Coefficient
L
% 2.00
Uncertainty in Measurement Units
Uncertainty in Result
Lr 10.00
6245.34
Measured Quantities Symbol Units Run 1
Requirement of Standard
Value Standard uncertainty
mg/m³
N/A
mg/m³ 0.6401
mg/m³ 0.4619
mg/m³
% 20.2
6.461
mg/m³
Run 1
%
Measured Quantities
Measured Quantities Units Run 1
mg/m³ 3.2004
6.461
% v/v N/A
Oxygen Correction Part of MU Budget
- N/A
Run 1
N/A
N/AOverall MU For O₂ Measurement %
- N/A
CAT-RT (Version BV)
Page 44 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sample Runs
- -
< <
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, dry gas.
APPENDIX 2
FORMALEHYDE : RESULTS SUMMARY
Kingspan Insulation Ltd, Castleblayney
Number of Sampling Lines Used 1 / 1
A2-14 RTO Outlet
Parameter Units Run 1 Mean
Formaldehyde mg/m³ 0.04 0.04
Value
Sample Tube Type
Date of Sample Analysis 29/05/2018
Technical Procedure CAT-TP-16
Number of Sampling Points Used 1 / 4
Sample Point I.D.'s A1
Name of Analytical Laboratory RPS
ISO 17025 Accredited Analysis?
DNPH Coated Silica Gel
Dynamic Dilution Employed Yes
CEN/TS 13649
Analytical Laboratory's Procedure A40
Probe Material Stainless Steel
Parameter
Standard
See Executive Summary
CAT-RT (Version BV)
Page 45 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Where: MV stands for Mass View (Mass Flow Controller Technology)
< < - < <
Reference Conditions are: 273K, 101.3kPa, dry gas.
Tube Lot Number and Unique ID: WK18-3398
LOD
(Back)
µg
LOD
(Total)
µg
100.0
Reported
Concentration
(Blank Reviewed)
mg/m³
Reported
LOD
mg/m³
0.040
- 13:55 - 14:25
N₂ to Stack Gas Dilution Ratio
Duration mins 30
m³
Sampling Device - MV
0.0050
Parameter Lab Result
(Front)
µg
Lab Result
(Back)
µg
Sampling Dates
0.040 0.040
Adsorption
Efficiency
%
Parameter Value
Sampling Times
0.2 0.1
- 15/05/2018
APPENDIX 2
FORMALEHYDE : SAMPLING DETAILS
RUN 1
0.2Formaldehyde 0.1 0.1
Units
: 1 1.5
0.1
Volume Sampled (REF)
Lab Result
(Total)
µg
LOD
(Front)
µg
Concentration
mg/m³
CAT-RT (Version BV)
Page 46 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Where: MV stands for Mass View (Mass Flow Controller Technology)
< < - <
Reference Conditions are: 273K, 101.3kPa, dry gas.
Tube Lot Number and Unique ID: WK18-3398
APPENDIX 2
FORMALEHYDE : SAMPLING DETAILS
BLANK 1
Parameter Units Value
Sampling Dates - 15/05/2018
Sampling Device - MV
Average Volume Sampled (REF) m³ 0.0050
Parameter Lab Result
(Front)
µg
Lab Result
(Back)
µg
Lab Result
(Total)
µg
Concentration
mg/m³
Formaldehyde 0.1 0.1 0.2 0.040
CAT-RT (Version BV)
Page 47 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sample Runs
APPENDIX 2
FORMALEHYDE : QUALITY ASSURANCE(PAGE 1 OF 2)
Leak Test Results Units Run 1
Mean Sampling Rate l/min 0.400
Pre-Sampling Leak Rate l/min 0.010
Post-Sampling Leak Rate l/min 0.010
Allowable Leak Rate l/min 0.020
- Yes
Adsorption Efficiency Units Run 1
Formaldehyde % 100.0
Leak Test Acceptable
13
Temperature at Sample Tubes Units Run 1
Adsorption Efficiency Acceptable -
Allowable Temperature °C 40
Units
Temperature Acceptable - Yes
Run 1
Yes
Temperature °C
Allowable Adsorption Efficiency % 95
Test Conditions
Ambient Temperature Recorded? -
Yes
CAT-RT (Version BV)
Page 48 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Blank Runs
Method Deviations
1
x
- - - - -
- - - - -
- - - - -
0.0
Allowed
Allowable for TOTAL mg/m³
Leak Test Acceptable
l/min 0.020
Yes
Validity of Blank vs ELV Units
Allowable for Formaldehyde
Leak Test Results Units Blank 1
0.400
Sampling Leak Rate l/min 0.010
Allowable Leak Rate
Blank 1
Expected Sampling Rate l/min
0.4
0.0 N/A
Nature of Deviation Run Number
(x = deviation applies to the associated run)
There are no deviations associated with the sampling employed.
FORMALEHYDE : QUALITY ASSURANCE(PAGE 2 OF 2)
-
mg/m³
APPENDIX 2
CAT-RT (Version BV)
Page 49 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
NOTE: Uncertainties reported in mg/m ³ are based upon the summation of all Speciated VOCs Measured.
Run 1
Oxygen Correction Part of MU Budget
mg/m³ 0.008
Overall MU For O₂ Measurement
1.00
mg/m³
10.00
Lr mg/m³ 0.004 1.00
2.500
uVm m³ 0.0
Units Run 1 Run 1
%
L
2.00
Uncertainty as a Percentage
Requirement of Standard
%
APPENDIX 2
Run 1
10.00 uLr % -
FORMALEHYDE : MEASUREMENT UNCERTAINTY CALCULATIONS
Value Standard uncertainty
Measured Quantities Symbol Run 1 Symbol Run 1
Measured Quantities
Vm 0.0050
uL
20.2
% -
Lr
Uncertainty in Measurement Units Sensitivity Coefficient
Units
≤2%
% 2.50
No Requirement
Measured Quantities
Measured Quantities Units
Vm m³ 0.0050
Units
% 20.2
7.93
% N/A
0.0040
%
0.0008
N/A
0.008
Measured Quantities
mg/m³
mg/m³
mg/m³
0.004
N/A
-
0.0006
N/A
0.001
Symbol
Uncertainty in Result
L mg/m³
Parameter Units Run 1
mg/m³
N/A
% 20.2
mg/m³
mg/m³ 0.008
% v/v
%
Units Run 1
- N/A
≤5%
CAT-RT (Version BV)
Page 50 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sample Runs
- -
- -
- -
- -
- -
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, dry gas.
Span Gas Type Propane In Synthetic Air (5 Grade)
Probe Material Stainless Steel
Heated Head Filter Used
Span Gas Set Point (ppm)
Span Gas Expiry Date
4.60
N/A
Yes
24.1
2.7
Concentration
g/hr
86.1
Number of Sampling Points Used 1 / 4
Uncertainty
Value
Run 1
APPENDIX 2
Mass Emission
Synthetic Air (5 Grade)
180°C
Standard
Number of Sampling Lines Used
A1
Mean
0.46
A2-14 RTO Outlet
TOTAL VOCs (as CARBON): RESULTS SUMMARY
Sample Point I.D.'s
Technical Procedure
1 / 1
INPUT
Uncertainty
Kingspan Insulation Ltd, Castleblayney
Gas Cylinder Concentration (ppm)
Span Gas Start Pressure (bar)
Span Gas Reference Number
100
Span Gas Uncertainty (%)
Parameter Units
±mg/m³
4.60
CAT-TP-20
2.7
Parameter
Heated Line Temperature
INPUT
mg/m³
0.46
EN 12619:2013
86.10
0.1µm Glass Fibre
24.1
Filtration Type / Size
±g/hr
Zero Gas Type
CAT-RT (Version BV)
Page 51 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Graphical Trend of Data
TOTAL VOCs (as CARBON): DATA TREND
APPENDIX 2
COVER ME WITH CHART/S
0.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0 1
6:2
0
16
:21
16
:22
16
:23
16
:24
16
:25
16
:26
16
:27
16
:28
16
:29
16
:30
16
:31
16
:32
16
:33
16
:34
16
:35
16
:36
16
:37
16
:38
16
:39
16
:40
16
:41
16
:42
16
:43
16
:44
16
:45
16
:46
16
:47
16
:48
16
:49
16
:50
Co
nce
ntr
atio
n (
mg/
m³)
Total VOCs At Reference Conditions
- Run 1
CAT-RT (Version BV)
Page 52 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sampling Details
Quality Assurance
Zero Drift 0 0 0
Span Drift 0 0 0
Method Deviations
1
x
- - -
- - -
- - -
- - -
- - -
- 15/05/2018
- Yes
Units
0.20
Instrument Range ppm 100
0.20
Sampling Dates
Units
Zero Drift Acceptable
Span Drift
Zero Down Sampling Line (Post) ppm
Span Down Sampling Line (Post)
Zero Down Sampling Line (Pre)
Run Ambient Temperature Range 11
CA
L 1
ppm 82.00
Span Gas Value
Run 1
Run 1
Sampling Times -
ppm
ppm
4.31
Zero Drift
0.00ppm
4.31
Units
86.1
Span Down Sampling Line (Pre)
Run 1
Parameter
Yes
CA
L 1
ppm -2.40
16:20 - 16:50
APPENDIX 2
Span Drift Acceptable
Allowable Span Drift ± ppm
TOTAL VOCs (as CARBON): SAMPLING DETAILS & QUALITY ASSURANCE
Nature of Deviation
(x = deviation applies to the associated run)
Allowable Zero Drift ± ppm
Run 1
There are no deviations associated with the sampling employed.
Units
ppm
84.40
°C
Run Number
Test Conditions
-
CAT-RT (Version BV)
Page 53 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
k =
mg/m³
-
N/A
RUN 1 Units
Result of Compliance with Uncertainty Requirement in M2 COMPLIANT
0.23
RUN 1
Losses in the line (leak) 1.97 % of value
Uncertainty of calibration gas 2.00 % of value
Units
mg/m³
Uncertainty of calibration gas 0.05
Atmospheric pressure dependence 0.01 mg/m³
Lack of fit 0.04
Lower of [A] or [B]
mg/m³
Measurement uncertainty
0.00
mg/m³ (REF)
Dependence on voltage
4.60 mg/m³
Combined uncertainty
Result
mg/m³
Losses in the line (leak) 0.05
0.20
2.00
15.0 mg/m³
Cal gas conc. 138.3
% of value/kPa
Combined interference
mg/m³
0.06
seconds
Number of readings in measurement
Atmospheric pressure dependence 0.30
% full scale
Conversion 1.61
Dependence on voltage
Standard deviation of repeatability at span level
% full scale
Deviation from linearity 0.46
Volume or pressure flow dependence
Standard deviation of repeatability at zero mg/m³
ppm to mg/m³
MCERTS Range [B]
use rep at span
0.45
Performance characteristic
Performance characteristics
% full scale
Span drift 0.00
% of full scale
mg/m³
Drift 0.00
1.40
mg/m³
mg/m³
0.00
-
ppm
15.0
% range
0.50 % full scale/10V
mg/m³
Cal gas conc. 86.1 ppm
Range Used [A]
mg/m³
% of value
Zero drift
Measured concentration
TGN M2 Allowable MU
Limit value
%
4.60 mg/m³ (STP, dry)
mg/m³
1.60
15.0
50.0
RUN 1 Units
Response time 45
Performance characteristics RUN 1 Units
% full scale/10K
% full scale
Volume or pressure flow dependence
Repeatability at zero
TOTAL VOCs (as CARBON): MEASUREMENT UNCERTAINTY CALCULATIONS
Units
% of Value
RUN 1
% at ELVN/A
Expanded uncertainty (with O₂) - at 95% Confidence
N/A
% at ELVExpanded uncertainty (with O₂) - at 95% Confidence N/A
Overall Allowable uncertainty (with O₂) - at 95% Confidence
Requirement for SRM is that Uncertainty should be <15% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 15% + the
uncertainty associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.
Result of Compliance with Uncertainty Requirement in M2 -
0.92 % at ELV
Units
mg/m³ (REF)
% of Value
RUN 1
Expanded uncertainty (no O₂) - at 95% Confidence
0.46
Expanded uncertainty (no O₂) - at 95% Confidence 9.95
Overall Allowable uncertainty (no O₂) - at 95% Confidence 15.0
mg/m³
Combined interference (from MCERTS Certificate) 0.04
mg/m³
% at ELV
Ambient temperature dependence
Expanded uncertainty 1.96 0.46 mg/m³
Uncertainty corrected to std conds. (O₂)
0.00
30
0.00
Repeatability at span level
Ambient temperature dependence
Range Used 100.0
160.6
APPENDIX 2
CAT-RT (Version BV)
Page 54 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Sample Runs
- -
- -
- -
- -
- -
General Sampling Information
NOTE: Dilution performed to achieve correct span value
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, dry gas.
Span Gas Type Nitrogen Monoxide
Technical Procedure
A2-14 RTO Outlet
Parameter Units Mean
Number of Sampling Points Used
Mass Emission
APPENDIX 2
OXIDES OF NITROGEN (as NO₂): RESULTS SUMMARY
1 / 4
8.6
Span Gas Expiry Date
1.64
Stainless Steel
Concentration mg/m³
415.9
Yes
16.8
CYL 12.0146
3.21
22/03/2020
Number of Sampling Lines Used 1 / 1
Kingspan Insulation Ltd, Castleblayney
2
A1
Span Gas Reference Number
Filtration Type / Size
CAT-TP-21
g/hr
Probe Material
Span Gas Start Pressure (bar) 100
Gas Cylinder Concentration (ppm)
16.8
1.64
Uncertainty ±mg/m³
Date & Result of Last Converter Check
Zero Gas Type Nitrogen (5 Grade)
Span Gas Uncertainty (%)
Sample Point I.D.'s
Run 1
EN 14792
0.1µm Glass Fibre
Uncertainty
8.6
Value
18/04/2018 - 96.1%
Heated Head Filter Used
Parameter
Heated Line Temperature
Standard
180°C
3.21
±g/hr
CAT-RT (Version BV)
Page 55 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Graphical Trend of Data
COVER ME WITH CHART/S
APPENDIX 2
OXIDES OF NITROGEN (as NO₂): DATA TREND
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0 1
6:2
0
16
:21
16
:22
16
:23
16
:24
16
:25
16
:26
16
:27
16
:28
16
:29
16
:30
16
:31
16
:32
16
:33
16
:34
16
:35
16
:36
16
:37
16
:38
16
:39
16
:40
16
:41
16
:42
16
:43
16
:44
16
:45
16
:46
16
:47
16
:48
16
:49
16
:50
Co
nce
ntr
atio
n (
mg/
m³)
Oxides of Nitrogen (as NO₂) At Reference Conditions
- Run 1
CAT-RT (Version BV)
Page 56 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:19
Sampling Details
Quality Assurance
Zero Drift 0 0 0
Span Drift 0 0 0
Method Deviations
1
x
- - -
- - -
- - -
± ppm 4.87
< °C
ppm -1.20
97.5
There are no deviations associated with the sampling employed.
Units
-
Run 1
Zero at Analyser (Post) ppm -1.20
Sampling Dates
Temperature Acceptable
APPENDIX 2
0.00
Units
OXIDES OF NITROGEN (as NO₂): SAMPLING DETAILS & QUALITY ASSURANCE
Zero Drift
Zero at Analyser (Pre)
- Yes
Units
Instrument Range
4.0
15/05/2018
ParameterC
AL
1
Sampling Times - 16:20 - 16:50
Span at Analyser (Pre) ppm 97.50
Average Temperature °C 1.2
250
Span Gas Value ppm
Run 1
Allowable Temperature
ppm
± ppm
Span Drift Acceptable
Run Ambient Temperature Range 11
4.87
Test Conditions
°C
(x = deviation applies to the associated run)
Yes
ppm -2.50
Span Drift
-
- Yes
Units Run 1
CA
L 1
Nature of Deviation
Run 1
Run Number
Conditioning Unit Temperature
Span at Analyser (Post) ppm 95.00
Allowable Zero Drift
Allowable Span Drift
Run 1
Units
Zero Drift Acceptable
ppm
CAT-RT (Version BV)
Page 57 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
k =
use rep at span
0.40
% of full scale
0.52 mg/m³
Drift
513.1
200.0
OXIDES OF NITROGEN (as NO₂): MEASUREMENT UNCERTAINTY CALCULATIONS
% full scale/10K
Performance characteristics RUN 1
Repeatability at span level
Ambient temperature dependence
Units
-
Repeatability at zero 0.40
125.0 mg/m³
Cal gas conc.
mg/m³
250.0
Response time 60
mg/m³
125.0
ppm
Range Used [A]
0.07
N/A
N/A % at ELV
Overall Allowable uncertainty (with O₂) - at 95% Confidence N/A % at ELV
1.64
ppm
Conversion 2.05 ppm to mg/m³
MCERTS Range [B]
Units
% of Value195.62
% full scale
% full scale
seconds
Units
mg/m³
Dependence on voltage
% full scale/10V
96.1
Ration NO / NO₂
Measured concentration
TGN M2 Allowable MU
Limit value
mg/m³
% range
% of value
mg/m³ (REF)
Converter efficiency
Number of readings in measurement
mg/m³
Result
-
RUN 1
mg/m³
0.00Converter efficiency
Losses in the line (leak) 0.00
Units
Expanded uncertainty (with O₂) - at 95% Confidence
Result of Compliance with Uncertainty Requirement in M2
-1.42
0.05
mg/m³
Atmospheric pressure dependence 0.30 % of value/kPa
0.72
Span drift 0.00 % full scale
Volume or pressure flow dependence 0.40
%
Range Used
%
Lower of [A] or [B]
30
mg/m³
% full scale
Deviation from linearity
Standard deviation of repeatability at zero
1.61 % at ELV
Performance characteristics RUN 1
mg/m³ (REF)
mg/m³ (STP, dry)
5
0.18
mg/m³
0.60
%
% at ELV
Result of Compliance with Uncertainty Requirement in M2 COMPLIANT
Expanded uncertainty (no O₂) - at 95% Confidence
10.0
0.02
Lack of fit
Uncertainty of calibration gas
97.5
1.64
mg/m³
RUN 1
RUN 1
3.21
mg/m³
Atmospheric pressure dependence 0.11 mg/m³
Overall Allowable uncertainty (no O₂) - at 95% Confidence 10.0
% of Value
Dependence on voltage
Units
mg/m³
Uncertainty corrected to std conds. (O₂) 3.21
Measurement uncertainty
mg/m³
Standard deviation of repeatability at span level
Volume or pressure flow dependence 0.00
Zero drift -1.23
Requirement for SRM is that Uncertainty should be <10% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 10% + the
uncertainty associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.
-
Expanded uncertainty 1.96
Uncertainty of calibration gas blending 0.01
Uncertainty of calibration gas
0.03
% of value
% of value
0.21
Expanded uncertainty (with O₂) - at 95% Confidence N/A
Cal gas conc. 200.0
RUN 1
Combined interference (from MCERTS Certificate) 0.43
2.00
Losses in the line (leak)
Expanded uncertainty (no O₂) - at 95% Confidence
Ambient temperature dependence
mg/m³
Combined uncertainty 1.64
APPENDIX 2
Units
% of value
mg/m³
mg/m³
mg/m³
Combined interference
Uncertainty of calibration gas blending 1.40
Performance characteristic
0.40
CAT-RT (Version BV)
Page 58 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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Sample Runs
- -
- -
- -
- -
- -
General Sampling Information
NOTE: Dilution performed to achieve correct span value
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, dry gas.
Span Gas Type Sulphur Dioxide
Filtration Type / Size
Probe Material Stainless Steel
SULPHUR DIOXIDE: RESULTS SUMMARY
Mass Emission
CAT-TP-21
Zero Gas Type
Mean
Kingspan Insulation Ltd, Castleblayney
105.9
1.20
±mg/m³
Heated Line Temperature
g/hr 6.3
Span Gas Expiry Date 22/03/2020
180°C
100
APPENDIX 2
Uncertainty
Parameter
Number of Sampling Points Used
Sample Point I.D.'s A1
Nitrogen (5 Grade)
Yes
Span Gas Start Pressure (bar)
Standard TGN M21
Uncertainty
2
Concentration mg/m³
Number of Sampling Lines Used
27.7
5.28
6.3
0.1µm Glass Fibre
Heated Head Filter Used
5.28
Span Gas Reference Number
A2-14 RTO Outlet
Gas Cylinder Concentration (ppm)
Run 1
Parameter Value
Units
Technical Procedure
CYL 12.0146
1 / 4
±g/hr 27.7
1.20
1 / 1
Span Gas Uncertainty (%)
CAT-RT (Version BV)
Page 59 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Graphical Trend of Data
COVER ME WITH CHART/S
APPENDIX 2
SULPHUR DIOXIDE: DATA TREND
0.0
5.0
10.0
15.0
20.0
25.0 1
6:2
0
16
:21
16
:22
16
:23
16
:24
16
:25
16
:26
16
:27
16
:28
16
:29
16
:30
16
:31
16
:32
16
:33
16
:34
16
:35
16
:36
16
:37
16
:38
16
:39
16
:40
16
:41
16
:42
16
:43
16
:44
16
:45
16
:46
16
:47
16
:48
16
:49
16
:50
Co
nce
ntr
atio
n (
mg/
m³)
Sulphur Dioxide At Reference Conditions
- Run 1
CAT-RT (Version BV)
Page 60 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Sampling Details
Quality Assurance
Zero Drift 0 0 0
Span Drift 0 0 0
Method Deviations
1
x
- - -
- - -
- - -
Sampling Dates
Run Ambient Temperature Range
35.0
Span Down Sampling Line (Post)
15/05/2018
Allowable Zero Drift
< °C 4.0
CA
L 1
± ppm
Conditioning Unit Temperature
Zero Drift Acceptable
Yes
Units Run 1
-
ppm
Units
1.75
Run Number
(x = deviation applies to the associated run)
°C 11
Average Temperature
ppm
Span Drift
Zero Drift
-
SULPHUR DIOXIDE: SAMPLING DETAILS & QUALITY ASSURANCE
Temperature Acceptable
Yes
Allowable Span Drift
1.75
Parameter
Nature of Deviation
Span Drift Acceptable -
APPENDIX 2
Units Run 1
°C
34.60
0.20
± ppm
Allowable Temperature
Zero Down Sampling Line (Pre)
Run 1Units
Span Down Sampling Line (Pre)
Yes
Zero Down Sampling Line (Post) ppm
ppm -0.20
Run 1
0.00
Units Run 1
-
CA
L 1
200
ppm
1.2
-
ppm -0.60
ppm
There are no deviations associated with the sampling employed.
Instrument Range
Span Gas Value
Test Conditions
34.00
ppm
16:20 - 16:50Sampling Times
CAT-RT (Version BV)
Page 61 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
k =
mg/m³
1.40
mg/m³ (REF)
5.28
% at ELV
Overall Allowable uncertainty (no O₂) - at 95% Confidence 10.0 % at ELV
seconds
ppm
Zero drift
35.0
Measured concentration
Expanded uncertainty (with O₂) - at 95% Confidence N/A % at ELV
% of Value
mg/m³
Uncertainty of calibration gas blending 0.01 mg/m³
Uncertainty of calibration gas 0.01 mg/m³
RUN 1 Units
Measurement uncertainty Result 1.20 mg/m³
Combined uncertainty 2.69
Result of Compliance with Uncertainty Requirement in M2 COMPLIANT -
RUN 1 Units
Units
Expanded uncertainty (no O₂) - at 95% Confidence 439.14
Range Used [A] 571.1
Combined interference
% full scale
Span drift -1.73
mg/m³
160
Expanded uncertainty 1.96 5.28
mg/m³
Atmospheric pressure dependence
% of Value
Expanded uncertainty (no O₂) - at 95% Confidence 5.28
% of value
Uncertainty of calibration gas
Conversion 2.86
% of value
Cal gas conc. 100.0
10.0
Repeatability at span level 0.40
30
Expanded uncertainty (with O₂) - at 95% Confidence N/A
Number of readings in measurement
Response time
2.00
mg/m³
Losses in the line (leak)
mg/m³
% full scale
Deviation from linearity 0.84
TGN M2 Allowable MU
Performance characteristics RUN 1 Units
SULPHUR DIOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS
-0.58
Overall Allowable uncertainty (with O₂) - at 95% Confidence N/A % at ELV
% full scale
Result of Compliance with Uncertainty Requirement in M2 N/A -
mg/m³ (REF)
mg/m³
0.01
Dependence on voltage 0.05
Ambient temperature dependence 0.02
Requirement for SRM is that Uncertainty should be <10% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 10% + the
uncertainty associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.
RUN 1
Atmospheric pressure dependence 0.30
mg/m³
% full scale
Cal gas conc.
1.00
Dependence on voltage 0.40
1.20
mg/m³
Volume or pressure flow dependence
mg/m³
100.0
Range Used 200.0
Repeatability at zero 0.40
ppm to mg/m³
Uncertainty of calibration gas blending
Limit value
APPENDIX 2
mg/m³ (STP, dry)
% range
Units
%
mg/m³
Volume or pressure flow dependence 0.01 mg/m³
% full scale/10V
Losses in the line (leak) 1.14
0.40
Drift
% of value/kPa
Ambient temperature dependence 0.15
0.40
Standard deviation of repeatability at span level 0.07
Performance characteristic RUN 1 Units
Standard deviation of repeatability at zero use rep at span mg/m³
2.23 mg/m³
RUN 1
Lower of [A] or [B] 460.0
mg/m³
Uncertainty corrected to std conds. (O₂)
0.38
-
% full scale/10K
Performance characteristics
Combined interference (from MCERTS Certificate)
% of value
ppm
-0.35
MCERTS Range [B] 460.0
mg/m³
Lack of fit
% of value
% of full scale
CAT-RT (Version BV)
Page 62 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Sample Runs
- -
- -
- -
- -
- -
General Sampling Information
NOTE: Dilution performed to achieve correct span value
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, dry gas.
Span Gas Type Carbon Monoxide
Uncertainty
Gas Cylinder Concentration (ppm) 100.9
Technical Procedure
Parameter
Sample Point I.D.'s
Mean
CARBON MONOXIDE: RESULTS SUMMARY
6.1
Number of Sampling Lines Used
Run 1
1.23
1 / 4
Uncertainty
Value
6.1
Heated Head Filter Used
APPENDIX 2
Concentration mg/m³ 1.17
Mass Emission
Yes
Heated Line Temperature
Span Gas Uncertainty (%) 2
EN 15058
1 / 1
1.23
CAT-TP-21
Zero Gas Type
6.4
Standard
Span Gas Reference Number
Parameter
g/hr
A2-14 RTO Outlet
Probe Material Stainless Steel
Filtration Type / Size
Number of Sampling Points Used
Span Gas Start Pressure (bar) 100
1.17
22/03/2020Span Gas Expiry Date
Units
Kingspan Insulation Ltd, Castleblayney
6.4
±mg/m³
180°C
A1
CYL 12.0146
0.1µm Glass Fibre
Nitrogen (5 Grade)
±g/hr
CAT-RT (Version BV)
Page 63 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:19
Graphical Trend of Data
APPENDIX 2
COVER ME WITH CHART/S
CARBON MONOXIDE: DATA TREND
0.0
5.0
10.0
15.0
20.0
25.0
16
:20
16
:21
16
:22
16
:23
16
:24
16
:25
16
:26
16
:27
16
:28
16
:29
16
:30
16
:31
16
:32
16
:33
16
:34
16
:35
16
:36
16
:37
16
:38
16
:39
16
:40
16
:41
16
:42
16
:43
16
:44
16
:45
16
:46
16
:47
16
:48
16
:49
16
:50
Co
nce
ntr
atio
n (
mg/
m³)
Carbon Monoxide At Reference Conditions
- Run 1
CAT-RT (Version BV)
Page 64 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:20
Sampling Details
Quality Assurance
Zero Drift 0 0 0
Span Drift 0 0 0
Method Deviations
1
x
- - -
- - -
- - -
Zero Drift Acceptable -
ppm
Span Gas Value
CA
L 1
Units
Units
34.80
- 15/05/2018
Instrument Range
Sampling Dates
CARBON MONOXIDE: SAMPLING DETAILS & QUALITY ASSURANCE
Run 1
Zero Drift
Units
16:20 - 16:50
APPENDIX 2
Span Drift
ppm
Parameter
ppm
Run 1
Zero at Analyser (Post)
Conditioning Unit Temperature Run 1
°C 1.2
ppm
Run 1
Run Number
Zero at Analyser (Pre)
Average Temperature
Allowable Temperature < °C 4.0
0.20
Yes
Run 1
Test Conditions
1.75
1.75
Units
35.0
Nature of Deviation
Span at Analyser (Pre)
Units
ppm -0.20
-Temperature Acceptable
Allowable Zero Drift
ppm
0.20
-
Yes
± ppm
Allowable Span Drift ± ppm
(x = deviation applies to the associated run)
There are no deviations associated with the sampling employed.
Run Ambient Temperature Range
200
CA
L 1
ppm 0.00
°C 11
Span at Analyser (Post)
35.00
- YesSpan Drift Acceptable
Sampling Times
ppm
CAT-RT (Version BV)
Page 65 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:20
k =
Measurement uncertainty Result
mg/m³
Uncertainty corrected to std conds. (O₂) 1.23
RUN 1 Units
mg/m³
Uncertainty of calibration gas blending 0.01
-
RUN 1
mg/m³
mg/m³
mg/m³
Combined uncertainty
Uncertainty of calibration gas 0.01 mg/m³
RUN 1 Units
mg/m³ (REF)
Ambient temperature dependence 0.01 mg/m³
Combined interference (from MCERTS Certificate) 0.40
Units
0.63 mg/m³
Expanded uncertainty 1.96 1.23
Result of Compliance with Uncertainty Requirement in M2 N/A -
Expanded uncertainty (with O₂) - at 95% Confidence N/A % of Value
Requirement for SRM is that Uncertainty should be <6% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 6% + the uncertainty
associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.
Expanded uncertainty (no O₂) - at 95% Confidence 105.13
Expanded uncertainty (with O₂) - at 95% Confidence N/A % at ELV
Overall Allowable uncertainty (with O₂) - at 95% Confidence N/A
% full scale/10V
Losses in the line (leak) 0.29 % of value
Uncertainty of calibration gas blending 1.40 % of value
Volume or pressure flow dependence 0.40
Number of readings in measurement
Zero drift 0.57
mg/m³
Range Used
95.0
mg/m³
Cal gas conc. 43.7
Response time
Repeatability at span level 0.40 % full scale
Deviation from linearity 0.37
% range
-
Repeatability at zero
Performance characteristics
0.40
Units
ppm
Conversion 1.25
mg/m³
Lower of [A] or [B] 95.0
Dependence on voltage 0.40
% of full scale
Atmospheric pressure dependence 0.30 % of value/kPa
Ambient temperature dependence
Limit value
Measured concentration
1.17
% of Value
0.05
% at ELV
Overall Allowable uncertainty (no O₂) - at 95% Confidence 6.0 % at ELV
Result of Compliance with Uncertainty Requirement in M2 COMPLIANT
0.00Volume or pressure flow dependence
60
% full scale
2.00 % of valueUncertainty of calibration gas
0.41
Performance characteristics RUN 1 Units
300.0 mg/m³ (REF)
6.0
mg/m³
Losses in the line (leak) 0.00 mg/m³
mg/m³
Expanded uncertainty (no O₂) - at 95% Confidence
ppm to mg/m³
MCERTS Range [B]
0.14 mg/m³
Units
Standard deviation of repeatability at zero use rep at span mg/m³
Standard deviation of repeatability at span level 0.07
Drift
mg/m³
Dependence on voltage 0.05
% at ELV
mg/m³
Atmospheric pressure dependence 0.08
Lack of fit 0.20
200.0 ppm
Range Used [A] 249.8 mg/m³
Cal gas conc. 35.0
% full scale/10K
Combined interference 0.73
% of value
Performance characteristic RUN 1
APPENDIX 2
CARBON MONOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS
%
1.17 mg/m³ (STP, dry)
TGN M2 Allowable MU
RUN 1
seconds
30
% full scale
Span drift -0.57 % full scale
CAT-RT (Version BV)
Page 66 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:20
Sample Runs
- -
- -
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
- -
Span Gas Type Carbon Dioxide
3.86
0.24
Filtration Type / Size
Stainless Steel
Span Gas Reference Number
1 / 1
Number of Sampling Points Used
Number of Sampling Lines Used
0.24
Technical Procedure
Yes
Span Gas Expiry Date 26/04/2023
Span Gas Start Pressure (bar) 180
Gas Cylinder Concentration (% v/v)
Sample Point I.D.'s A1
Value
16.02
A2-14 RTO Outlet
Parameter
CAT-TP-21
180°C
Concentration % v/v 3.86
Nitrogen (5 Grade)
Kingspan Insulation Ltd, Castleblayney
0.1µm Glass Fibre
Heated Head Filter Used
Heated Line Temperature
Standard ISO 12039
1 / 4
Zero Gas Type
CYL 6.0042
Probe Material
Units
±% v/vUncertainty
Parameter
Span Gas Uncertainty (%) 2.00
APPENDIX 2
CARBON DIOXIDE: RESULTS SUMMARY
CAT-RT (Version BV)
Page 67 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:20
Graphical Trend of Data
APPENDIX 2
CARBON DIOXIDE: DATA TREND
COVER ME WITH CHART/S
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0 1
6:2
0
16
:21
16
:22
16
:23
16
:24
16
:25
16
:26
16
:27
16
:28
16
:29
16
:30
16
:31
16
:32
16
:33
16
:34
16
:35
16
:36
16
:37
16
:38
16
:39
16
:40
16
:41
16
:42
16
:43
16
:44
16
:45
16
:46
16
:47
16
:48
16
:49
16
:50
Co
nce
ntr
atio
n (
% v
/v)
Carbon Dioxide Carbon Dioxide
- Run 1
CAT-RT (Version BV)
Page 68 of 74
Kingspan Insulation Ltd
Castleblayney
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Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
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EPA Export 18-08-2018:04:04:20
Sampling Details
Quality Assurance
Zero Drift 0 0 0
Span Drift 0 0 0
Method Deviations
1
x
- - -
- - -
- - -
0.80
Span Drift Acceptable
Nature of Deviation Run Number
-
Run 1
Yes
Yes
°C
Span Gas Value % v/v 16.02
°C 1.2
Temperature Acceptable
Conditioning Unit Temperature Units
Average Temperature
Parameter Units
11
Zero Down Sampling Line (Post) % v/v 0.00
% v/v 0.00
± % v/v
Units
± % v/v
APPENDIX 2
Units
0.00
CA
L 1
Zero Down Sampling Line (Pre)
Allowable Temperature < °C 4.0
- Yes
Zero Drift
- 16:20 - 16:50
Instrument Range % v/v 30
Run 1
Sampling Dates -
% v/v 15.94
Span Down Sampling Line (Post)
(x = deviation applies to the associated run)
There are no deviations associated with the sampling employed.
Allowable Span Drift
% v/v
Run 1
Run 1
CARBON DIOXIDE: SAMPLING DETAILS & QUALITY ASSURANCE
CA
L 1
15/05/2018
15.90
Test Conditions Units
Allowable Zero Drift
Sampling Times
-
0.80
-0.04
Span Drift
Run Ambient Temperature Range
Span Down Sampling Line (Pre)
Zero Drift Acceptable
Run 1
% v/v
% v/v
CAT-RT (Version BV)
Page 69 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
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EPA Export 18-08-2018:04:04:20
k =
Measured concentration
TGN M2 Allowable MU
Limit value
Drift
%vol
Losses in the line (leak) 0.01
N/A
%
3.86 %vol
%vol
APPENDIX 2
Zero drift 0.00
%vol
Uncertainty of calibration gas 0.04
Units
Measurement uncertainty Result 3.86 %vol
Units
Standard deviation of repeatability at span level %vol
-0.01
% full scale
Expanded uncertainty 1.96 0.24
RUN 1
Expanded uncertainty (no O₂) - at 95% Confidence 6.19
%volCombined uncertainty 0.12
%vol
RUN 1
%vol
Units
% of Value
%vol
% of value/kPa
Cal gas conc. 16.0
%vol
Dependence on voltage 0.05 %vol
%vol
Deviation from linearity 0.39
0.40 % full scale
Repeatability at span level 0.40
Performance characteristic Units
Repeatability at zero
seconds
Number of readings in measurement 30 -
Performance characteristics RUN 1
%vol
25.0
% of value
%vol
CARBON DIOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS
% of value
Lack of fit 0.07
0.30
RUN 1
Range Used 30.0
2.00
% full scale
RUN 1
Combined interference (from MCERTS Certificate) 0.00
Dependence on voltage 0.40 % full scale/10V
Losses in the line (leak) 0.50 % of value
Ambient temperature dependence 0.01
%vol
%vol
% full scale/10K
Combined interference 0.00 % range
Uncertainty of calibration gas
Volume or pressure flow dependence 0.00
Atmospheric pressure dependence 0.03
% full scale
0.00
0.40 % of full scale
0.07
%vol
Ambient temperature dependence
Span drift -0.25
Volume or pressure flow dependence
use rep at span
Units
Response time 160
Atmospheric pressure dependence
Standard deviation of repeatability at zero
Performance characteristics
CAT-RT (Version BV)
Page 70 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
For
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ectio
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EPA Export 18-08-2018:04:04:20
Sample Runs
- -
- -
- -
General Sampling Information
NOTE: Dilution performed to achieve correct span value
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
20.46
Kingspan Insulation Ltd, Castleblayney
Probe Material Stainless Steel
Filtration Type / Size
Span Gas Type Synthetic Air (5 Grade)
CAT-TP-21
Parameter
Number of Sampling Points Used 1 / 4
Sample Point I.D.'s A1
EN 14789
Technical Procedure
Mean
0.1µm Glass Fibre
20.46
Span Gas Reference Number
Units Run 1
Span Gas Expiry Date 14/04/2023
Span Gas Start Pressure (bar) 180
Gas Cylinder Concentration (% v/v) 21.02
Number of Sampling Lines Used 1 / 1
Value
Standard
Parameter
180°C
0.55
Span Gas Uncertainty (%) 2
Zero Gas Type Nitrogen (5 Grade)
A2-14 RTO Outlet
0.55
CYL 11.0345
Uncertainty ±% v/v
Heated Head Filter Used Yes
Heated Line Temperature
Concentration % v/v
APPENDIX 2
OXYGEN: RESULTS SUMMARY
CAT-RT (Version BV)
Page 71 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
For
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EPA Export 18-08-2018:04:04:20
Graphical Trend of Data
OXYGEN: DATA TREND
APPENDIX 2
COVER ME WITH CHART/S
0.0
5.0
10.0
15.0
20.0
25.0 1
6:2
0
16
:21
16
:22
16
:23
16
:24
16
:25
16
:26
16
:27
16
:28
16
:29
16
:30
16
:31
16
:32
16
:33
16
:34
16
:35
16
:36
16
:37
16
:38
16
:39
16
:40
16
:41
16
:42
16
:43
16
:44
16
:45
16
:46
16
:47
16
:48
16
:49
16
:50
Co
nce
ntr
atio
n (
% v
/v)
Oxygen Oxygen
- Run 1
CAT-RT (Version BV)
Page 72 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
For
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EPA Export 18-08-2018:04:04:20
Sampling Details
Quality Assurance
Zero Drift 0 0 0
Span Drift 0 0 0
Method Deviations
1
x
- - -
- - -
- - -
Average Temperature
Conditioning Unit Temperature Units
Span Gas Value
- 15/05/2018
Allowable Temperature < °C
0.00
Zero at Analyser (Post) % v/v 0.14
1.2
Allowable Zero Drift ± % v/v
Parameter Units Run 1
Instrument Range
°C
% v/v 21.02
16:20 - 16:50
Sampling Dates
4.0
0.14
CA
L 1
Zero at Analyser (Pre) % v/v
Sampling Times -
APPENDIX 2
% v/v
OXYGEN: SAMPLING DETAILS & QUALITY ASSURANCE
Temperature Acceptable
Allowable Span Drift
(x = deviation applies to the associated run)
There are no deviations associated with the sampling employed.
Zero Drift Acceptable
Run 1
0.03
11
Span Drift Acceptable - Yes
Span at Analyser (Post) % v/v
Run 1
% v/v
21.05
Span at Analyser (Pre)
Test Conditions Units
± % v/v 1.05
% v/v
Run Number
Run 1
Run Ambient Temperature Range °C
-
- Yes
Span Drift Units
21.02
25
Yes
Units Run 1
Nature of Deviation
1.05
CA
L 1
% v/v
Zero Drift
CAT-RT (Version BV)
Page 73 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
For
insp
ectio
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EPA Export 18-08-2018:04:04:20
k =
-0.07 % full scale/10K
Atmospheric pressure dependence 0.30 % of value/kPa
Ambient temperature dependence
Volume or pressure flow dependence 0.20 % of full scale
N/A %vol
6.0 %
Expanded uncertainty (no O₂) - at 95% Confidence 2.70 % of Value
Expanded uncertainty 1.96 0.55 %vol
RUN 1 Units
%vol
Uncertainty of calibration gas 2.00
% range
Performance characteristic
% full scale
20.46
RUN 1
% of value
% full scale/10V
% of value
%vol
RUN 1
Deviation from linearity
% full scale
Span drift
Losses in the line (leak)
0.14
Measured concentration
Range Used
Dependence on voltage 0.02
-
Repeatability at zero 0.04
0.16
%vol
% of value
Zero drift
0.02
seconds
0.00
Standard deviation of repeatability at zero use rep at span %vol
Standard deviation of repeatability at span level 0.01 %vol
Lack of fit 0.02
Atmospheric pressure dependence
Result 20.46
RUN 1 Units
Limit value
TGN M2 Allowable MU
%volVolume or pressure flow dependence 0.00
Units
Drift 0.10
Units
Response time 60
0.67
Repeatability at span level 0.04 % full scale
%vol
Performance characteristics
%vol
Performance characteristics
Requirement for SRM is that Uncertainty should be 0.5%vol absolute or 6% relative whichever is the lower, on a dry gas basis. Ref EA TGN M2.
%vol
Measurement uncertainty
25.0
% full scale
%vol
Cal gas conc. 21.0
Combined interference 0.56
RUN 1
-0.01 %vol
Combined uncertainty 0.28 %vol
Result of Compliance with Uncertainty Requirement in M2 COMPLIANT -
Combined interference (from MCERTS Certificate) 0.08 %vol
Dependence on voltage 0.00 %vol
Losses in the line (leak) 0.00 %vol
Uncertainty of calibration gas 0.24 %vol
APPENDIX 2
OXYGEN: MEASUREMENT UNCERTAINTY CALCULATIONS
Number of readings in measurement 30
Ambient temperature dependence
Units
CAT-RT (Version BV)
Page 74 of 74
Kingspan Insulation Ltd
Castleblayney
A2-14 RTO Outlet
Job Number: CDU-1018, Version 1
Sample Date/s: 15th - 16th May 2018
Irish EPA IE Licence: P0057-03
For
insp
ectio
n pur
pose
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Conse
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EPA Export 18-08-2018:04:04:20