TestAmericaTHE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number: 680-42572-1
Job Description: Hercules Hattiesburg 4Q08
For:Hercules Inc.
Research Center- Bldg 8139/15500 Hercules Road
Wilmington, DE 19808-1599
Attention: Mr. Timothy Hassett
L Approved for releaseLolyc GuIiz,aProject Menager I1211512008 504 PM
cc: Mr. Charles Coney
Lidya GuliziaProject Manager I
[email protected]/15/2008
The test results in this report meet NELAP requirements for parameters for which accreditation is required or available.Any exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This reportmay not be reproduced, except in full, without the written approval of the laboratory. Questions should be directed to theperson who signed this report.
Savannah Certifications and ID #s: A2LA: 0399.01; AL: 41450; ARDEQ: 88-0692; ARDOH; CA: 03217CA; Cc; CT:PHOI61; DE; FL: E87052; GA: 803; Guam; HI; IL: 200022; IN; IA: 353; KS: F-i 0322; KY EPPC: 90084; KY UST; LA
L DEQ: 30690; LA DHH: LA080008; ME: 2008022; MD: 250; MA: M-GAOO6; MI: 9925; MS; NFESC: 249; NV: GA00006;NJ: GA769; NM; NY: 10842; NC DWQ: 269; NC DHHS: 13701; PA: 68-00474; PR: GA00006; RI: LA000244; SC:98001001; TN: TN0296; TX: Ti 04704185; USEPA: GA00006; VT: VT-87052; VA: 00302; WA; WV DEP: 094; WVDHHR: 9950 C; WI DNR: 999819810; WY/EPAR8: 8TMS-Q
TestAmerica Laboratories, Inc.
TestAmerica Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel (912) 354-7858 Fax (912) 352-0165 www.testamericpinc.com
8 ACC0,
(ePage 1 of 119
Job Narrative680-J42572-1
OReceiptL Method(s) 8260B: The following sample(s) was received with headspace in the sample vial: HER-MWO5-1 11908 (680-42572-15),
HER-MW14-112008(680-42572-25). Three of three vials contain headspace for both IDs,
All other samples were received in good condition within temperature requirements.
GCIMSVOANo analytical or quality issues were noted
CommentsNo additional comments.
Page 2 of 119
LIL
METHOD SUMMARY
0 Client Hercules Inc. Job Number 680-42572-1
LI Description Lab Location Method Preparation Method
Matrix Water
[j Volatile Organic Compounds (GC/MS) TAL SAV SW846 82608Purge and Trap TAL SAV SW846 5030B
U Lab References:
TAL SAV = TestAmerica Savannah
El Method References:
SW846 = Test Methods For Evaluating Solid Waste, Physical/Chemical Methods, Third Edition, November 1986 And ItsUpdates.
0UEl[0
Lici
LiLI
TestAmerica Savannah
Page 3 of 119
I
UCi
cD METHOD I ANALYST SUMMARY
U Client: Hercules Inc Job Number: 680-42572-1
[ Method Analyst
SW846 8260B Bearden, Robert RBSW846 8260B Lui, Chung CL
[] SW846 826DB Sokolin, Eleina ES
UCiU[0
UF::!UUEl
TestAmerica Savannah
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Ii
SAMPLE SUMMARY
Client: Hercules Inc. Job Number: 680-42572-1
Lab Sample ID Client Sample ID Client MatrixDate/Time
SampledDate/TimeReceived
680-42572-1 RB
680-42572-2
680-42572-3
680-42572-4
680-42572-5
680-42572-6
680-42572-7
680-42572-8
680-42572-9
680-42572-9MS
flU 680-42572-1 ORB
680-42572-11
ci680-42572-12
680-42572-13
680-42572-1 4FD680-42572-15
rO 680-42572-16
[j,680-42572-18
680-42572-19
680-42572-2OFD
680-42572-21
680-42572-22
U680-42572-22MS
680-42572-22MSD
680-42572-23
680-42572-24
fl 680-42572-25
Li 680-42572-26
680-42572-27
680-42572-28
[1 680-42572-29
680-42572-3OTB
HER-RS1-1 11808
HER-CMO5-1 11808HER-CMO4-1 11808HER-CMO3-1 11808
HER-CMO2-1 11808HER-CMO1-1 11808
HER-CMOO-1 11808
HER-MWO3-1 11908HER-MWO2-1 11908
HER-MWO2-1 11908
HER-MWO2-1 11908HER-RS2-1 11908
HER-MW1 0-111908
HER-MW1 1-111908
HER-MWO4-1 11908HER-FDO1 -111908
HER-MWO5-1 11908
HER-MW1 2-112008
HER-RSO3-1 12008HER-MWO6-1 12008
HER-MW1 8-112008
HER-FDO2-1 12008
HER-MW1 9-112008
HER-MWO7-1 12008HER-MWO7-1 12008
HER-MWO7-1 12008
HER-MW1 6-112008
HER-MW1 5-112008
HER-MW14-112008
HER-MW1 3-112008HER-MWO9-1 12108
HER-MWO8-1 12108
HER-MW17-112108
TRIP BLANK
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
WaterWater
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
11/19/2008 1034
11/19/2008 1034
11/19/2008 1057
11/19/2008 1221
11/19/2008 1428
11/19/2008 1515
11/19/2008 1515
11/19/2008 1639
11/20/2008 090611/20/2008 0925
11/20/2008 0953
11/20/2008 1037
11/20/2008 0000
11/20/2008 1129
11/20(2008 1323
11/20/2008 1323
11/20/2008 132311/20/2008 1415
11/20/2008 1455
11/20/2008 1529
11/20/2008 1629
11/21/2008 0908
11/21/2008 0957
11/21/2008 1040
11/21/2008 0000
11/22/2008 0950
11/22/2008 095011/22/2008 0950
11/22/2008 095011/22)2008 095011/22/2008 0950
11/22/2008 095011/22/2008 0950
11/22/2008 0950
11/22/2008 0950
11/22/2008 095011/22/2008 0950
11(22/2008 0950
11/22/2008 095011/22/2008 095011/22/2008 0950
11/22/2008 0950
11/22/2008 095011/22/2008 095011/22/2008 095011/22/2008 0950
11/22/2008 095011/22/2008 095011/22/2008 0950
11/22/2008 095011/22/2008 095011/22/2008 095011/22/2008 0950
11/22/2008 095011/22/2008 0950
11/22/2008 095011/22/2008 095011/22)2008 095011/22)2008 0950
TestAmerica Savannah
ciiEl
11/18/2008
11/18/2008
11/18/2008
11/18/2008
11/18/2008
11/18/2008
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11/19/2008
11/19/2008
1325
1330
1350
1410
1425
1437
1455
0927
1034
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-RSI-111808
Lab Sample ID: 680-42572-1 RB Date Sampled: 11/18/2008 1325Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)[ Method: 82608 Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a384.dDilution: 1.0 Initial Weight/Volume: 5 mLDate Analyzed: 11/25/2008 1237 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1237
UAnalyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein . <20 20
O Acrytonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0[ Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0
U Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.0ri 2-Chloro-1,3-butadiene <1.0 1.0
I 3-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0
U1 2-Dibrorno-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i 4-Dichloro-2-butene <2.0 2.0
UDichlorodifluoromethane <1.0 1.0i,1-Dichloroethane <1.0 1.0i,2-Dichloroethane <1.0 1.0li-Dichloroethene <1.0 1.0cis-i ,2-Dichloroethene <1.0 1.0trans-i 2-Dichloroethene <1.0 1.0i ,2-Dichloropropane <1.0 1.0cis-i,3-Dichloropropene <1.0 1.0[ trans-i 3-Dichloropropene <1.0 i .0Ethylbenzene <1.0 i.0Ethyl melhacrylate <1.0 1.02-Hexanone <10 iO
U lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0
fl Methyl methacrylate <1.0 1.0
__
4-Methyl-2-pentanone (MIBK) <10 10
( Pentachtoroethane <5.0 5.0‘-.) Propionitrile <20 20
1 Styrene <1.0 1.0
J ii, 1 2-Tetrachloroethane <1.0 1.0
TestAmerica Savannah Page 7 of 119
Analytical Data
Client: Hercules inc. Job Number: 680-42572-1
Client Sample ID: HER-RSI-111808
Lab Sample ID: 680-42572-1 RB Date Sampled: 11/18/2008 1325Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a384.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11125/2008 1237 Final WeightNolume: 5 mLDate Prepared. 11125)2008 1237
Analyte Result (ugIL) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.01,1,1-Trichloroethane <1.0 1.01,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0
L 1,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 100 75- 120Dibromofluoromethane 102 75- 121Toluene-d8 (Surr) 96 75-120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-CMO5-111808
Lab Sample ID: 680-42572-2 Date Sampled: 11/18/2008 1330Client Matrix: Water Date Received: 11/22/2008 0950
826DB Volatile Organic Compounds (GCIMS)
Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 503DB Lab File ID: a386.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1307 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1307
OAnalyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0
Q Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 3-butadiene <1 .0 1.03-Chloro-i-propene <1.0 1.0Chlorodibromomethane <1.0 1.0
U1,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <20 2.0
UDichlorodifluoromethane <1.0 1.0ii-Dichloroethane <1.0 1.012-Dichloroethane <1.0 1.0li-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0
H trans-i,2-Dichloroethene <1.0 1.01 ,2-Dichloropropane <1.0 1.0cis-1 ,3-Dichloropropene <1.0 1.0trans-1,3-Dichloropropene <1.0 1.0
J Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5 0
J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.0J 4-Methyl-2-pentanone (MIBK) <10 10
O Pentachloroethane <5 0 5 0Propionitrile <20 20Styrene <1.0 1.01,1,1 2-Tetrachloroethane <1.0 1.0
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-CMO5-1 11808
Lab Sample ID: 680-42572-2 Date Sampled: 11/18/2008 1330Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC/MS)
U Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a386.dDilution: 1.0 Initial WeightfVolume: 5 mLDate Analyzed: 11/25/2008 1307 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1307
Analyte Result (ugIL) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0
O 1,11-Trichloroethane <1.0 1.01,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0
U 1,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 98 75- 120Dibromofluoromethane 104 75 - 121Toluene-d8 (Surr) 98 75- 120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-CM041 11808
Lab Sample ID: 680-42572-3 Date Sampled: 11/18/2008 1350Client Matrix: Water Date Received: 11/2212008 0950
8260B Volatile Organic Compounds (GCIMS)
U Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles -A C2Preparation: 5030B Lab File ID: a388.dDilution: 1.0 Initial WeightNolume. 5 mLDate Analyzed: 11/25/2008 1336 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1336
fl Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20fl Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0
fl Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 3-butadiene <1.0 1.0r 3-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.01 ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0
UDichlorodifluoromethane <1.0 1.011-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0cis-1 2-Dichloroethene <1.0 1.0trans-i,2-Dichloroethene <1.0 1.01 2-Dichloropropane <1.0 1.0cis-i,3-Dichloropropene <1.0 1.0trans-1,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0
J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.07 Methyl methacrylate <1 0 1.0J
Q4-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5 0 5.0Propionitrile <20 20Styrene <1.0 1.01,1 1 2-Tetrachloroethane <1.0 1.0
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-CMO4-111808
Lab Sample ID: 680-42572-3 Date Sampled: 11/1812008 1350Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
L Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GCIMS Volatiles - A C2Preparation: 5030B Lab File ID: a388.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1336 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1336
Analyte Result (ugIL) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.01,1,1-Trichloroethane <1.0 1.01,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.01 ,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 95 75- 120Dibromofluoromethane 104 75- 121Toluene-d8 (Surr) 97 75- 120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-CMO3-111808
Lab Sample ID: 680-42572-4 Date Sampled: 11/18/2008 1410
Client Matrix: Water Date Received: 11)22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
O Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2
Preparation: 5030B Lab File ID: a390.dDilution: 1.0 Initial Weight/Volume: 5 mLDate Analyzed: 11/25/2008 1405 Final Weight/Volume: 5 mLDate Prepared: 11/25/2008 1405
fl Analyte Result (ug/L) Qualifier RL
U Acetone <25 25Acetonitrile <40 40Acrolein <20 20Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 ,3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.01,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i 4-Dichloro-2-butene <2.0 2.0
UDichlorodifluoromethane <1.0 1.0li-Dichloroethane <1.0 1.01 2-Dichloroethane <1.0 1.01 ,i-Dichloroethene <1.0 1.0cis-i2-Dichloroethene <1.0 1.0
[j trans-12-Dichloroethene <1.0 1.0i,2-Dichloropropane <1.0 1.0cis-i,3-Dichloropropene <1.0 1.0
Utrans-i 3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5 0 5.0
U Methyl methacrylate <1.0 1.04-Methyl-2-pentanone (MIBK) <10 10
Q Pentachloroethane <5 0 5,0Propionitrile <20 20
L Styrene <1.0 1.01,1 1 ,2-Tetrachloroethane <1.0 1.0
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-CMO3-111808
Lab Sample ID: 680-42572-4 Date Sampled: 11/18/2008 1410Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a390.dDilution: 1.0 Initial Weight/Volume: 5 mLDate Analyzed: 11/25/2008 1405 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1405
Analyte Result (ug/L) Qualifier RL
LI 1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.01,1,1-Trichloroethane <1.0 1.01,1 ,2-Trichloroetharie <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 . 1.0
O 1,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 99 75- 120Dibromotluoromethane 102 75- 121Toluene-d8 (Sun) 98 75- 120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-CMO2-111808
Lab Sample ID: 680-42572-5 Date Sampled: 11118/2008 1425Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC/MS)
U Method: 826DB Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles -A C2Preparation: 503DB Lab File ID: a392.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1435 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1435
J Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20
fl Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0
U Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0
U Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1,3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0
U1 2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0
ODichlorodifluoromethane <1.0 1.0i,i-Dichloroethane <1.0 1.01 2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0
Li trans-1,2-Dichloroethene <1.0 1.0i,2-Dichloropropane <1.0 1.0cis-1,3-Dichloropropene <1.0 1.0trans-i 3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.07 Methyl methacrylate <1.0 1.0J 4-Methyl-2-pentanone (MIBK) <10 10Q Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1.0 1.01,112-Tetrachloroethane <1.0 1.0
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Analytical Data
Chent: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-CMO2-111808
Lab Sample ID: 680-42572-5 Date Sampled: 11/18/2008 1425Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a392.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1435 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1435
Analyte Result (ug/L) Qualifier RL1,1 ,2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0
fl 11,1-Trichloroethane <1.0 1.01,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.01,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xy)enes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 97 75 - 120Dibromofluoromethane 100 75- 121Toluene-dS (Surr) 97 75- 120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-CMOI.111808
Lab Sample ID: 680-42572-6 Date Sampled: 11118/2008 1437Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a394.dDilution; 1.0 Initial Weight/Volume: 5 mLDale Analyzed: 11/25/2008 1504 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1504
O Analyle Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20
O Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0[ Bromomelhane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0
Q Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.01 2-Dibromo-3-Chloropropane <1 .0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0
JDichlorodilluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.0i,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0cis-i ,2-Dichloroelhene <1.0 1.0
[j trans-12-Dichloroethene <1.0 1.0i,2-Dichloropropane <1.0 1.0cis-1 .3-Dichloropropene <1.0 1.0trans-i,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 101 lodomethane <5.0 5.0J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.0J 4-Methyl-2-pentanone (MIBK) <10 10Q Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1.0 1.01,1,1,2-Tetrachloroethane <1.0 1.0
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-CMOI-111808
Lab Sample ID: 680-42572-6 Date Sampled: 11/18/2008 1437Client Matrix: Water Date Received: 11/22/2008 0950
826DB Volatile Organic Compounds (GCIMS)
fl Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a394.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 1112512008 1504 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1504
Analyte Result (ug/L) Qualifier RL1,1 ,2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.01,1,1-Trichloroethane <1.0 1.01,1 2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0
U 1,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 95 75- 120Dibromofluoromethane 101 75 121Toluene-d8 (Surr) 97 75- 120
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Analytical DataClient: Hercules Inc.
Job Number: 680-42572-1
Client Sample ID: HER-CMQD-111808
Lab Sample ID: 680-42572-7 Date Sampled: 11/18/2008 1455Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)[ Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GCIMS Volatiles - A C2Preparation: 50308 Lab File ID: a396.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1534 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1534
fl Analyte Result (ug/L) QualifierAcetone <25 25Acetonitrile <40 40Acrolein <20 20fl Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0[ Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1,3-butadiene <1,0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0
U1 2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0
UDichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0[ cis-1,2-Dichloroethene <1.0 1.0trans-i ,2-Dichloroethene <1.0 1.01,2-Dichloropropane <1.0 1.0cis-1,3-Dichloropropene <1.0 1.0fl trans-i ,3-Dichloropropene <1.0 1.0J Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 101 lodomethane <5.0 5.0J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.01 Methyl methacrylate <1.0 1.0J 4-Methyl-2-pentanone (MIBK) <10 10Q Pentachloroethane <5.0 5.0Propionitrile <20 201 Styrene <1.0 1.0J i,i,1,2-Tetrachloroethane <1 0 1.0
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Analytical Data
Client: Hercules Inc. Job Number 680-42572-1
Client Sample ID: HER-CMOO-111808
Lab Sample ID: 680-42572-7 Date Sampled: 11/18/2008 1455Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a396.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11125/2008 1534 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1534
Analyte Result (ugIL) Qualifier RL1,1 ,22-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0fl 1,1,1-Thchloroethane <1.0 1.0
U 1,1,2-Tiichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0
O 1 ,23-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 94 75- 120Dibromofluoromethane 100 75- 121Toluene-d8 (Surr) 99 75 - 120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWO3-111908
Lab Sample ID: 680-42572-8 Date Sampled: 11/19/2008 0927Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC/MS)
U Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a398.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1603 Final Weight/Volume: 5 mLDate Prepared: 11/25/2008 1603
Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20
O Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disultide <2.0 2.0Carbon teirachloride <1.0 1.0Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1,3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0
U1 ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0Dichlorodifluoromethane <1.0 1.0i,1-Dichloroethane <1.0 1.0i,2-Dichloroethane <1.0 1.0i,i-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0trans-12-Dichloroethene <1.0 1.01,2-Dichloropropane <1.0 1.0cis-i,3-Dichloropropene <1.0 1.0trans-i ,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.0
J 4-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5.0Propionilrile <20 20Styrene <1,0 1.01,1,1 ,2-Tetrachloroethane <1.0 1.0
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Analytical DataClient: Hercules Inc. Job Number: 680-42572-1
Client Sample ID; I-IER-MWO3-111908
Lab Sample ID: 680-42572-8 Date Sampled: 11/19/2008 0927Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)[ Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a398.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1603 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1603
Analyte Result (ug/L) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0
fl 1,1,1-Trichloroethane <1.0 1.0U 1,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0
U 1,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 97 75- 120Dibromofluoromethane 101 75- 121Toluene-d8 (Surr) 98 75 - 120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWO2-111908
Lab Sample ID: 680-42572-9 Date Sampled: 11/19/2008 1034Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC/MS)
fl Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles -A C2LI Preparation: 5030B Lab File ID: a400.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25)2008 1632 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1632
Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0
D Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 3-butadiene <1.0 1.03-Chloro-i-propene <1.0 1.0Chlorodibromomethane <1.0 1,0
U1 2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0
UDichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.0i,1-Dichloroethene <1.0 1 0
fjcis-1,2-Dichloroethene <1.0 1 0trans-i ,2-Dichloroethene <1.0 1.0i,2-Dichloropropane <1.0 1.0cis-i ,3-Dichloropropene <1.0 1.0trans-i .3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.0J 4-Methyl-2-pentanone (MIBK) <10 10Q Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1.0 1 01,1,1 ,2-Tetrachloroethane <1.0 1 0
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Analytical DataClient: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWO2-111908
Lab Sample ID: 680-42572-9 Date Sampled: 11/19/2008 1034Client Matrix: Water Date Received: 11/2212008 0950
8260B Volatile Organic Compounds (GC/MS)
Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a400.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/2512008 1632 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1632
UAnalyte Result (ug/L) Qualifier RL1,1 ,2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0fl ill-Trichloroethane <1,0 1.01,12-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0
E l ,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 97 75- 120Dibromofluoromethane 101 75- 121Toluene-d8 (Surr) 96 75- 120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-RS2-111908
Lab Sample ID: 680-42572-1 ORB Date Sampled: 1111912008 1057Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC/MS)
Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GO/MS Volatiles - A 02Preparation: 5030B Lab File ID: a402.dDilution: 1.0 Initial WeightfVolume: 5 mLDate Analyzed: 1112512008 1702 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1702
fl Analyte Result (ug/L) Qualifier RL
U Acetone <25 25Acetonitrile <40 40Acrolein <20 20
O Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1,3-butadiene <1.0 1.03-Chtoro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0
Ui ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0Dichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0cis-1,2-Dichloroethene <1.0 1.0trans-i ,2-Dichloroethene <1.0 1.01,2-Dichloropropane <1.0 1.0cis-i ,3-Dichloropropene <1.0 1.0r trans-i ,3-Dichloropropene <1.0 1.0
U Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5 0J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.04-Methyl-2-pentanone (MIBK) <10 10Q Pentachloroethane <5.0 5,0Propionitrile <20 20Styrene <1.0 1.01.1,1 ,2-Tetrachloroethane <1.0 1.0
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-RS2.111908
Lab Sample ID: 680-42572-1 ORB Date Sampled: 11/19)2008 1057Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)[ Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a402.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1702 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1702
fl Analyte Result (ugIL) Qualifier RL11 ,2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0111-Trichloroethane <1.0 1.0
U 1,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0[ 1 ,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 98 75- 120Dibromofluoromethane 102 75 - 121Toluene-d8 (Surr) 98 75- 120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWIO-111908
Lab Sample ID: 680-42572-11 Date Sampled: 11/19/2008 1221Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC/MS)
D Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a404.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1731 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1731
Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0
U Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-i ,3-butadiene <1.0 1.03-Chloro-i-propene <1.0 1.0Chlorodibromomethane <1.0 1.0i,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0
UDichlorodifluoromethane <1.0 1.0i,i-Dichloroethane <1.0 1.01 ,2-Dichloroethane <1.0 1.0i,i-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0
[I trans-i 2-Dichloroethene <1.0 1.0i,2-Dichloropropane <1.0 1.0cis-i ,3-Dichloropropene <1.0 1.0trans-i 3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.04-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1.0 1.01,1.1 2-Tetrachloroethane <1.0 1.0
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWIO-111908
Lab Sample ID: 680-42572-11 Date Sampled: 11/19/2008 1221Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC/MS)
U Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles -A C2Preparation: 5030B Lab File ID: a404,dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1731 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1731
Analyte Result (ug/L) Qualifier RL1,1 ,2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0fl 1,1,1-Trichloroethane <1.0 1.0
LI 1,1 ,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.01 ,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 97 75- 120Dibromofluoromethane 102 75- 121Toluene-d8 (Surr) . 97 75- 120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MW1I-111908
Lab Sample ID: 680-42572-12 Date Sampled: 1111912008 1428Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC/MS)
Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a406.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1800 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1800
fl Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20fl Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0
U Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0
U Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0
IJ1 ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2,0
UDichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.0i,1-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0
U trans-i ,2-Dichloroethene <1.0 1.01,2-Dichloropropane <1.0 1.0cis- 1 ,3-Dichloropropene <1.0 1.0
Dtrans-i,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0
] Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.0
2 4-Methyl-2-pentanone (MIBK) <10 10
Q Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1.0 1.01,1,1 ,2-Tetrachloroethane <1.0 1.0
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Analytical DataClient: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWII-111908
Lab Sample ID: 680-42572-12 Date Sampled: 11/19/2008 1428Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC/MS)
Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles -A C2Preparation: 5030B Lab File ID: a406.dDilution: 1.0 Initial Weight/Volume: 5 mLDate Analyzed: 11/25/2008 1800 Final Weight/Volume: 5 mLDate Prepared: 11/25/2008 1800
UAnalyte Result (ug/L) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0
fl 1,1,1-Trichloroethane <1.0 1 01,1 ,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.01 ,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 95 75- 120Dibromofluoromethane 105 75- 121Toluene-d8 (Surr) 97 75- 120
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Analytical DataClient: Hercules Inc.
Job Number: 680-42572-1
Client Sample ID: HER-MWO4-111908
Lab Sample ID: 680-42572-13 Date Sampled: 11/19/2008 1515Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
O Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC!MS Volatiles - A C2Preparation: 50308 Lab File ID: a408.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1830 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1830
UAnalyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20
fl Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobrornomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0
O Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 3-butadiene <1.0 1.03-Chloro-i-propene <1.0 1.0Chlorodibromomethane <1.0 1.01 ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0
UDichlorodifluoromethane <1.0 1.0li-Dichloroethane <1.0 1.0i,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0
Dcis-i,2-Dichloroethene <1.0 1.0trans-i 2-Dichloroethene <1.0 1.01 2-Dichloropropane <1.0 1.0cis-i ,3-Dichloropropene <1.0 1.0trans-i 3-Dichloropropene <1.0 1.0Ethylbenzene <i.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 iDlodornethane <5.0 5.0J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl melhacrylate <1.0 1.0
j 4-Methyl-2-pentanone (MIBK) <10 10Q Pentachloroethane <5.0 50Propionitrile <20 20Styrene <1.0 1.01,i,i,2-Tetrachloroethane <1.0 1 0
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWO4-111908
Lab Sample ID: 680-42572-13 Date Sampled: 11/19/2008 1515Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC/MS)
U Method: 826GB Analysis Batch: 680-1 23846 Instrument ID: DC/MS Volatiles - A C2Preparation: 503DB Lab File ID: a408.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1830 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1830
Analyte Result (ug)L) Qualifier RL1,1 ,2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0
1,1,1-Trichloroethane
<1.0 1.011,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0
U 1,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 107 75- 120Dibromofluoromethane 102 75- 121Toluene-d8 (Surr) 98 75- 120
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Analytical DataClient: Hercules Inc.
Job Number: 680-42572-1
Client Sample ID: HER-FDOI-111908
Lab Sample ID: 680-42572-14FD Date Sampled: 11/19/2008 1515Client Matrix: Water Date Received: 11122/2008 0950
8260B Volatile Organic Compounds (GCIIVIS)
U Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a410.dDilution: 1.0 Initial Weight/Volume: 5 mLDateAnalyzed: 11/25/2008 1859 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1859
Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20
U Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbontetrachloride <1.0 1.0Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-13-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.01 2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0Dichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0cis-1,2-Dichloroethene <1.0 1.0lrans-1 ,2-Dichloioethene <1.0 1.01 ,2Dichloropropane <1.0 1.0cis-1,3-Dichloropropene <1.0 1.0trans-i ,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0
Methylmethacrylate <1 0 1.0
4-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1 0 1.01,1,1 ,2-Tetrachloroethane <1.0 1.0
TestAmerica Savannah Page 33 of 119
Analytical DataClient: Hercules Inc.
Job Number: 680-42572-1
Client Sample ID:
Lab Sample ID:Client Matrix.
HER-FDOI -111908
580-42572-1 4FDWater
Date Sampled:Date Received:
11/19/2008 151511/22/2008 0950
8260B Volatile Organic Compounds (GC1MS)
826DB
503DB
1.011/25/2008 185911/25/2008 1859
U Analyte
1,1 ,2,2-TetrachloroethaneTetrachloroetheneToluene
fl 1,1 1-Trichloroethane
Lj 1,1,2-TrichloroethaneTrichloroetheneTrichiorofluoromethane1 ,2,3-TrichloropropaneVinyl acetateVinyl chlorideXylenes, Total
Result (ug/L) Qualifier<1.0<1.0<1.0<1.0<1.0<1.0<1.0<1.0<2.0<1.0<2.0
Instrument ID: GC/MS Volatiles - A C2Lab File ID: a410.dInitial WeightNolume: 5 mLFinal WeightNolume: 5 mL
RL
1.01.01.01.01.01.01.01.02.01.02.0
Surrogate4-BromofluorobenzeneDibromofluoromethaneToluene-d8 (Surr)
%Rec
10010399
Acceptance Limits75- 12075- 12175-120
U Method:Preparation:Dilution:
Date Analyzed:Date Prepared:
Analysis Batch: 680-1 23846
TestAmerica Savannah Page 34 of 119
Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWO5-111908
Lab Sample ID: 680-42572-15 Date Sampled: 11(19/2008 1639Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
U Method: 8260B Analysis Batch: 680-124082 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a425.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/26/2008 1523 Final WeightNolume: 5 mLDate Prepared: 11/26/2008 1523
Analyte Result (ugIL) Qualifier RLAcetone 85 25Acetonitrile <40 40Acrolein <20 20Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0
U Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0
OCarbon tetrachlonde <1.0 1.0
O Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-i 3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0
Ui 2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0Dichlorodifluoromethane <1.0 1.0ii-Dichloroethane <1.0 1.0i,2-Dichloroethane <1.0 1.0i,i-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0
fl trans-i ,2-Dichloroethene <1.0 1.0I—I i,2-Dichloropropane <1.0 1.0
cis-1 ,3-Dichloropropene <1.0 1.0trans-i ,3-Dichloropropene <1.0 1.0Lthylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.0
JO4-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5.0Propionitrile <20 20nStyrene <1.0 1.0
J i,1i,2-Tetrachloroethane <1 0 1.0
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWO5-111908
Lab Sample ID: 680-42572-15 Date Sampled: 11/19/2008 1639Client Matrix: Water Date Received: 11/22/2008 0950
826DB Volatile Organic Compounds (GC/MS)
O Method: 826DB Analysis Batch: 680-1 24082 Instrument ID: GC/MS Volatiles - A C2Preparation: 503DB Lab File ID: a425.dDilution: 1.0 Initial WeighlNolume: 5 mLDate Analyzed: 11/26/2008 1523 Final WeightNolume: 5 mLDate Prepared: 11/26/2008 1523
Analyte Result (ugiL) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0ill-Trichloroethane <1,0 1.01,1 2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.01 23-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 98 75- 120Dibromofluoromethane 102 75- 121Toluene-d8 (Surr) 97 75- 120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWI2-1 12008
Lab Sample ID: 680-42572-16 Date Sampled: 11120/2008 0906
Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
fl Method: 82608 Analysis Batch: 680-1 241 64 Instrumenl ID: GCIMS Volatiles - APreparation: 50308 Lab File ID: a485.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 12/01/2008 1716 Final WeightNolume: 5 mLDate Prepared: 12/01/2008 1716
Analyte Result (ug/L) Qualifier RLAcetone 32 25Acetonitrile <40 40Acrolein <20 20
h Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <10 1.0Bromoform <1.0 1.0
J Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0
I Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1,3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.01 ,2-Dibromo-3-Chloropropane <1.0 1.0
Ethylene Dibromide <1.0 1.0jijJ Dibromomethane <1.0 1.0
trans-i ,4-Dichloro-2-butene <2.0 2.0
U. Dichlorodifluoromethane <1.0 1.0
1,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.011-Dichloroethene <1.0 1.0cis-1,2-Dichloroethene <1.0 1.0trans-1,2-Dichloroethene <1.0 1.01,2-Dichloropropane <1.0 1.0cis-13-Dichloropropene <1.0 1.0
Otrans-1,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10
U lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.04-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5.0Propionitrile <20 20
D Styrene <1.0 1.0111,2-Tetrachloroethane <1 0 1.0
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWI2-112008
Lab Sample ID: 680-42572-16 Date Sampled: 11/20/2008 0906Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
Method: 8260B Analysis Batch: 680-1 24164 Instrument ID: GC/MS Volatiles - APreparation: 50308 Lab File ID: a485.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 12/01/2008 1716 Final WeightNolume: 5 mLDate Prepared: 12101/2008 1716
fl Analyte Result (ugIL) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.01,1,1-Trichloroethane <1.0 1.01,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0[ 1,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 100 75- 120Dibromofluoromethane 96 75- 121Toluene-d8 (Surr) 95 75-120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-RSO3-112008
Lab Sample ID: 680-42572-17RB Date Sampled: 11/20/2008 0925
Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
U Method: 8260B Analysis Batch: 680-124164 Instrument ID: GC/MS Volatiles -APreparation: 5030B Lab File ID: a487.d
Dilution: 1.0 Initial WeightlVolume: 5 mL
Date Analyzed: 12/01/2008 1746 Final WeightNolume: 5 mLDate Prepared: 12/01/2008 1746
Analyte Result (ugIL) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20
E] Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0
QCarbon tetrachloride <1.0 1.0
fl Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 ,3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0
Ui ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0Dichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.0
LJ 1,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0
IJ trans-i,2-Dichloroethene <1.0 1.01 ,2-Dichloropropane <1.0 1.0cis-i ,3-Dichloropropene <1.0 1.0
Utrans-i 3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10
U lodomethane <5.0 5.0lsobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0
U Methyl methacrylate <1.0 1.0
O4-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5 0Propionitrile <20 20Styrene <1.0 1.01,1.1 ,2-Tetrachloroethane <1.0 1.0
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-RSO3-1 12008
Lab Sample ID: 680-42572-17RB Date Sampled: 11/20/2008 0925
Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
Method: 8260B Analysis Batch: 680-124164 Instrument ID: GC/MS Volatiles -A
Preparation: 503DB Lab File ID: a487.d
Dilution: 1.0 Initial Weight/Volume: 5 mL
Date Analyzed: 12/01/2008 1746 Final WeightNolume: 5 mL
Date Prepared: 12/01/2008 1746
Analyte Result (ugIL) Qualifier RL
1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1,0 1.01,1,1-Trichloroethane <1.0 1.01,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0
fl 1,2,3-Trichloropropane <1.0 1.0
U Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits
4-Bromofluorobenzene 99 75- 120Dibromofluoromethane 98 75- 121Toluene-d8 (Surr) 96 75 - 120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWO6-112008
Lab Sample ID: 680-42572-18 Date Sampled: 11/20/2008 0953
Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
O Method: 8260B Analysis Batch: 680-1 241 64 Instrument ID: GC/MS Volatiles - A
Preparation: 5030B Lab File ID: a493.d
Dilution: 2.0 Initial WeightNolume: 5 mL
Date Analyzed: 12/01/2008 1914 Final WeightNolume: 5 mL
Date Prepared: 12/01/2008 1914
Analyte Result (ug/L) Qualifier RL
Acetone 490 50Acetonitrile <80 80Acrolein <40 40Acrylonitrile <40 40Benzene <2.0 2.0Dichlorobromomethane <2.0 2.0Bromoform <2.0 2.0
fl Bromomethane <2.0 2.02-Butanone (MEK) <20 20Carbon disulfide <4.0 4.0
OCarbon tetrachloride <2.0 2.0
O Chlorobenzene <2.0 2.0Chloroethane <2.0 2.0Chloroform <2.0 2.0Chloromethane <2.0 2.02-Chloro-13-butadiene <2.0 2.03-Chloro-1-propene <2.0 2.0Chlorodibromomethane <2.0 2.0
U1,2-Dibromo-3-Chloropropane <2.0 2.0Ethylene Dibromide <2.0 2.0Dibromomethane <2.0 2,0trans-i ,4-Dichloro-2-butene <4.0 4.0Dichlorodifluoromethane <2.0 2.0
U 1,1-Dichloroethane <2.0 2.01 ,2-Dichloroethane <2.0 2.01,1-Dichloroethene <2.0 2.0cis-1,2-Dichloroethene <2.0 2.0
U trans-i 2-Dichloroethene <2.0 2.01 ,2-Dichloropropane <2.0 2.0cis-1,3-Dichloropropene <2.0 2.0trans-i 3-Dichloropropene <2.0 2.0Ethylbenzene <2.0 2.0Ethyl methacrylate <2.0 2.02-Hexanone <20 20lodomethane <10 10Isobutyl alcohol <80 80Methacrylonitrile <40 40Methylene Chloride <10 10
D Methyl methacrylate <2.0 2.0
Q4-Methyl-2-pentanone (MIBK) <20 20Pentachloroethane <10 10Propionitrile <40 40Styrene <2.0 2.01,1,1 2-Tetrachloroethane <2.0 2.0
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HERMWO6-1120O8
Lab Sample ID: 680-42572-18 Date Sampled 11/20/2008 0953
Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC/MS)
O Method: 82608 Analysis Batch: 680-124164 lnstwment ID: GC/MS Volatiles -A
Preparation: 5030B Lab File ID: a493.d
Dilution: 2.0 Initial WeighliVolume: 5 mL
Date Analyzed: 12/01/2008 1914 Final Weight/Volume: 5 mL
Date Prepared: 12/01/2008 1914
Analyte Result (ug/L) Qualifier RL
U 11,2,2-Tetrachloroethane <2.0 2.0
Tetrachloroethene <2.0 2.0
Toluene <2.0 2.0
fl 11,1-Trichloroethane <2.0 2.0
LI 1,1,2-Trichloroethane <2.0 2.0
Trichloroethene <2.0 2.0
Trichlorofluoromethane <2.0 2.0[ 12,3-Trichloropropane <2.0 2.0
Vinyl acetate <4.0 4 0
Vinyl chloiide <2.0 2.0
Xylenes, Total <4.0 4.0
Surrogate %Rec Acceptance Limits
4-Bromofluorobenzene 99 75- 120
Dibromofluoromethane 97 75- 121
Toluene-d8 (Surr) 95 75- 120
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWI8-112008
Lab Sample ID: 680-42572-19 Date Sampled; 11/20/2008 1037
Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC1MS)
O Method: 826DB Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2
Preparation: 503DB Lab File ID: a412 d
Dilution: 1.0 Initial WeightNolume: 5 mL
Date Analyzed: 11/25/2008 1929 Final WeightNolume. 5 mL
Date Prepared: 11/25/2008 1929
fl Analyte Result (ug/L) Qualifier RL
U Acetone <25 25
Acetonitrile <40 40
Acrolein <20 20
O Acrylonitrile <20 20
Benzene <1.0 1.0
Dichlorobromomethane <1.0 1.0
Bromoform <1.0 1.0
L Bromomethane <1.0 1.0
2-Butanone (MEK) <10 10
Carbon disulfide <2.0 2.0
OCarbon tetrachloride <1.0 1.0
L Chlorobenzene 23 1.0
Chloroethane <1.0 1.0
Chloroform <1.0 1.0
Chloromethane <1.0 1.0
2-Chloro-13-butadiene <1.0 1.0
3-Chloro-1-propene <1.0 1.0
Chlorodibromomethane <1.0 1.0
Ui ,2-Dibrorno-3-Chloropropane <1.0 1.0
Ethylene Dibromide <1.0 1.0
Dibromomethane <1.0 1.0
trans-i 4-Dichloro-2-butene <2.0 2.0
UDichlorodifluoromethane <1.0 1.0
ii-Dichloroethane <1.0 1.0
i2-Dichloroethane <1.0 1.0
1,1-Dichloroethene 1.0 1.0
cis-i,2-Dichloroethene <1.0 1.0trans-i ,2-Dichloroethene <1.0 1.0
1,2-Dichloropropane <1.0 1.0
cis-i ,3-Dichloropropene <1.0 1.0
Utrans-i ,3-Dichloropropene <1.0 1.0
Ethylbenzene <1.0 1.0
Ethyl methacrylate <1.0 1.0
2-Hexanone <10 10
r lodomethane <5.0 5.0
[j Isobutyl alcohol <40 40
Methacrylonitrile <20 20
Methylene Chloride <5.0 5.0
fl Methyl methacrylate <1.0 1.0
jQ4-Methyl-2-pentanone (MIBK) <10 10
Pentachloroethane <5.0 5.0Propionitrile <20 20
Styrene <1.0 1.0
1 1 1 2-Tetrachloroethane <1.0 1.0
TestAmerica Savannah Page 43 of 119
Analytical Data
Client: Hercules Inc. Job Number 680-42572-1
8260B Volatile Organic Compounds (GCIMS)
Method:
Li Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.011/25/2008 1929
11/25/2008 1929
Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2
Lab File ID: a412.d
Initial WeightNolume: 5 mL
Final WeightNolume: 5 mL
OAnalyte
1,1 ,22-TetrachloroethaneTetrachloroetheneToluene1,1,1-Trichloroethane1,1 2-TrichloroethaneTrichloroetheneTrichiorofluoromethane
[J 1 2,3-TrichloropropaneVinyl acetateVinyl chlorideXylenes, Total
Result (ug/L)
<1.0<1.0<1.0<1.0<1.0<1.0<1.0<1.0<2.0<1.0<2.0
Surrogate
4-BromofluorobenzeneDibromofluoromethaneToluene-d8 (Surr)
%Rec
101105101
Acceptance Limits
75- 12075- 12175- 120
Client Sample ID:
Lab Sample ID:
Client Matrix:
HER-MWI 8-1 12008
680-42572-19
Water
Date Sampled:
Date Received:
11/20/2008 1037
11/22/2008 0950
Qualifier RL
1.01.01.01.01.01.01.01.02.01.02.0
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Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-FDO2-112008
Lab Sample ID: 680-42572-2OFD Date Sampled: 11/20/2008 0000
Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GC/MS)
O Method: 8260B Analysis Batch: 680-124115 Instrument ID: GC/MS Volatiles -0 C2
Preparation: 5030B Lab File ID: o6496.d
Dilution: 1.0 Initial Weight/Volume: 5 mL
Date Analyzed: 11/28/2008 1244 Final Weight/Volume: 5 mL
Date Prepared: 11/28/2008 1244
Analyte Result (ug/L) Qualifier RL
U Acetone <25 25
Acetonitrile <40 40
Acrolein <20 20
fl Acrylonitrile <20 20
U Benzene 1.1 1.0
Dichlorobromomethane <1 0 1.0
Bromoform <1.0 1.0
Bromomethane <1.0 1.0
2-Butanone (MEK) <10 10
Carbon disulfide <2.0 2.0
OCarbon tetrachloride <1.0 1.0
fl Chlorobenzene 28 1.0
U Chloroethane <1.0 1.0
Chloroform <1.0 1.0
Chloromethane <1.0 1.0
2-Chloro-1,3-butadiene <1.0 1.0
3-Chloro-1-propene <1.0 1.0
Chlorodibromomethane <1.0 1.0
1 ,2-Dibromo-3-Chloropropane <1.0 1.0
Ethylene Dibromide <1.0 1.0
U Dibromomethane <1.0 1.0
trans-i ,4-Dichloro-2-butene <2.0 2.0
Dichlorodifluoromethane <1.0 1.0
i,i-Dichloroethane <1.0 1.0
i,2-Dichloroethane <1.0 1.0
1,i-Dichloroethene 1.2 1.0
cis-i,2-Dichloroethene <1.0 1.0
U trans-i2-Dichloroethene <1.0 1.0
i,2-Dichloropropane 1.1 1.0
cis-13-Dichloropropene <1.0 1.0
Ltrans-1,3-Dichloropropene <1.0 1.0
Ethylbenzene <1.0 1.0
Ethyl methacrylate <1.0 1.0
2-Hexanone <10 10
L lodomethane <5.0 5.0
Isobutyl alcohol <40 40
Methacrylonitrile <20 20
Methylene Chloride <5.0 5.0
fl Methyl methacrylate <1 0 1 0
O4-Methyl-2-pentanone (MIBK) <10 10
Pentachloroethane <5.0 5.0
Propionitrile <20 20
Styrene <1 0 1.0
L 1,1,1 .2-Tetrachloroethane <1.0 1.0
TestAmerica Savannah Page 45 of 119
Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-FDO2-112008
Lab Sample ID: 680-42572-2OFD Date Sampled: 11/20/2008 0000
Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
Method: 8260B Analysis Batch: 680-124115 Instrument ID. GC/MS Volatiles -0 C2
Preparation: 5030B Lab File ID: o6496.d
Dilution: 1.0 Initial WeightfVolume: 5 mL
Date Analyzed: 11/28/2008 1244 Final WeightNolume: 5 mL
Date Prepared: 11/28/2008 1244
Analyte Result (ug/L) Qualifier RL
U 112,2-Tetrachloroethane <1.0 1.0
Tetrachloroethene <1.0 1.0
Toluene <1.0 1.0
O1,1,1-Trichloroethane <1.0 1.0
1,1,2-Trichloroethane <1.0 1.0
Trichloroethene <1.0 1.0
Trichlorofluoromethane <1.0 1.0
O 1,2,3-Trichloropropane <1.0 1.0
Vinyl acetate <2.0 2.0
Vinyl chloride <1.0 1.0
Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits
4-Bromofluorobenzene 103 75- 120
Dibromofluoromethane 95 75 121
Toluene-d8 (Surr) 104 75- 120
TestAmerica Savannah Page 46 of 119
Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID; HER-MWI9-112008
Lab Sample ID: 680-42572-21 Date Sampled: 11/20/2008 1129
Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIMS)
Method: 8260B Analysis Batch: 680-124115 Instrument ID: GC/MS Volatiles -0 C2
Preparation: 5030B Lab File ID: o6498.d
Dilution: 1.0 Initial WeightNolume: 5 mL
Date Analyzed: 11/28/2008 1313 Final WeightNolume: 5 mL
Date Prepared: 11/28/2008 1313
Analyte Result (ug/L) Qualifier RL
LI Acetone <25 25
Acetonitrile <40 40
Acrolein <20 20
fl Acrylonitrile <20 20
U Benzene 58 1.0
Dichlorobromomethane <1.0 1.0
Bromoform <1.0 1.0
L Bromomethane <1.0 1.0
2-Butanone (MEK) <10 10
Carbon disulfide <2.0 2.0
OCarbon tetrachloride <1 0 1.0
L Chlorobenzene 9.7 1.0
Chloroethane <1.0 1.0
Chloroform 1.1 1.0
Chloromethane <1.0 1.02-Chloro-i,3-butadiene <1.0 1.0
3-Chloro-1-propene <1.0 1.0
Chlorodibromomethane <1.0 1.0
U12-Dibromo-3-Chloropropane <1.0 1.0
Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0
trans-i ,4-Dichloro-2-butene <2.0 2.0
UDichlorodifluoromethane <1.0 1.0
ii-Dichloroethane <1.0 1.012-Dichloroethane <1.0 1.0
li-Dichloroethene <1.0 1.0
cis-i,2-Dichloroethene <1.0 1.0
U trans-i 2-Dichloroethene <1.0 1.0
12-Dichloropropane <1.0 1.0
cis-i,3-Dichloropropene <1.0 1.0[ trans-1,3-Dichloropropene <1.0 1.0
Ethylbenzene 2.4 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10
U lodomelhane <5.0 5.0
Isobutyl alcohol <40 40
Methacrylonitrile <20 20Melhylene Chloride <5.0 5.0
Methyl methacrylate <1.0 1.0
Li 4-Methyl-2-pentanone (MIBK) <10 10
Pentachloroelhane <5.0 5.0Propionitrile <20 20
Styrene <1.0 1.0
11,1 2-Tetrachloroethane <1.0 1.0
TestAmerica Savannah Page 47 of 119
Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MW07-1 12008
Lab Sample ID: 680-42572-22 Date Sampled: 11/20/2008 1323
Client Matrix: Water Date Received: 11/22/2008 0950
8260B Volatile Organic Compounds (GCIrV1S)
r Method: 8260B Analysis Batch: 680-124115 Instrument ID: GC/MS Volatiles - 0 C2
[j Preparation: 5030B Lab File ID: o6500.dDilution: 1.0 Initial WeightNolume: 5 mL
Date Analyzed: 11/28/2008 1342 Final WeightNolume: 5 mL
Date Prepared: 11/28/2008 1342
Analyte Result (ug/L) Qualifier RL
Acetone <25 25Acetonitrile <40 40Acrolein <20 20
Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0
OCarbon tetrachloride <1.0 1.0[ Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 ,3-butadiene <1.0 1.03-Chloro-i-propene <1.0 1.0Chlorodibromomethane <1.0 1.0
Ui ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i 4-Dichloro-2-butene <2.0 2.0Dichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.0i,i-Dichloroethene <1,0 1.0cis-i,2-Dichloroethene <1.0 1.0
U trans-1,2-Dichloroethene <1.0 1.01,2-Dichloropropane <1.0 1.0cis-i,3-Dichloropropene <1.0 1.0trans-i ,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.04-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1.0 10i,1,1,2-Tetrachloroethane <1.0 1 0
TestAmerica Savannah Page 49 of 119
Analytical Data
Client: Hercules Inc. Job Number: 680-42572-1
Client Sample ID: HER-MWO7-1 12008
Lab Sample ID: 680-42572-22 Date Sampled: 11/20/2008 1323
Client Matiix: Water Date Received: 11/22/2008 0950
826DB Volatile Organic Compounds (GC/MS)
Method: 8260B Analysis Batch: 680-124115 Instrument ID: GC/MS Volatiles -0 C2
Preparation: 5030B Lab File ID: o6500.d
Dilution: 1.0 Initial WeightNolume: 5 mL
Date Analyzed: 11/28/2008 1342 Final WeightNolume: 5 mL
Date Prepared: 11/28/2008 1342
Analyte Result (ug/L) Qualifier RL
1,1 ,22-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.01,1 1 -Trichloroethane <1.0 1.01,1 2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0
fl 12,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0
Surrogate %Rec Acceptance Limits
4-Bromofluorobenzene 102 75- 120Dibromofluoromethane 96 75- 121Toluene-d8 (Surr) 104 75- 120
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