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Page 1: Project B04: A PORE SCALE MICROLAB TO Fitted Function 10 · Project B04: A PORE SCALE MICROLAB TO PERFORM FUNDAMENTAL LABORATORY-BASED STUDIES OF CO 2 TRANSPORT AND REACTIVITY IN

Ehsan Behzadfar and Savvas G. Hatzikiriakos*

Chemical & Biological Engineering DepartmentUniversity of British Columbia, Vancouver, BC, Canada, V6T 1Z3*[email protected]

Methodology

Acknowledgement and References

• We gratefully acknowledge funding from CarbonManagement Canada for this project.

[1] IEA (2013), World Energy Outlook 2013, IEA. .

[2] USGCRP (2009), Global Climate Change Impacts in theUnited States.

[3] Optimization of CO2 storage in CO2 enhanced oilrecovery projects, prepared by Advanced resourcesInternational Inc, VA, & Melzer Consulting, TX, USA,November 2010.

Project B04: A PORE SCALE MICROLAB TO

PERFORM FUNDAMENTAL LABORATORY-BASED STUDIES OF CO2 TRANSPORT ANDREACTIVITY IN RESERVOIRS

David Sintont – U. TorontoAimy Bazylak – U. TorontoSavvas G. Hatzikiriakos – U. British Columbia Steve Larter – U. Calgary John Shaw – U. Alberta Zhenghe Xu – U. AlbertatLead PI

Introduction & Concepts

Temperature (°C)

0 50 100 150 200

Tem

pera

ture

sh

ift

fac

tor,

aT

10-9

10-8

10-7

10-6

10-5

10-4

10-3

10-2

10-1

100

101

Dynamic

Zero-shear

Double-log model

WLF model, TR=-41.7°C,

R=10

12Pa.s

Arrhenius model

Pressure, p (MPa)

0 5 10 15 20

Pre

ss

ure

sh

ift

fac

tor,

ap

0.9

2

3

1.0

30°C

45°C

60°C

90°C

Results & Discussion

With shearing CO2 starts to

diffuse into the oil (16ml).

, ,|T p C

T p C

R

a a a

Saturation pressure, psat

(MPa)

0 2 4 6 8 10

Ze

ro-s

he

ar

vis

co

sit

y,

0 (

Pa

.s)

0.01

0.1

1

10

100

1000

30°C

50°C

70°C

90°C

110°C

Fitted Function

30°C

50°C

70°C

90°C

110°C

P

Valve

Gas cylinder

Pressure gauge

Pressure regulator

Isothermal space

Sample cylinder

Pressure transducer

Measuring geometry

Magnetic coupling

Effect of Temperature on Viscosity

Effect of Pressure on Viscosity

Effect of Dissolved CO2 on Viscosity

Saturation pressure, psat

(MPa)

0 2 4 6 8 10

CO

2 C

on

cen

trati

on

sh

ift

fac

tor,

aC

0.001

0.01

0.1

1

110°C

90°C

70°C

50°C

30°C

Fitted Function

CO2 Phase Lines

Supercritical CO2

Gaseous CO2

Liquid CO2

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