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  • Research ArticleEnhanced Device and Circuit-Level PerformanceBenchmarking of Graphene Nanoribbon Field-Effect Transistoragainst a Nano-MOSFET with Interconnects

    Huei Chaeng Chin,1 Cheng Siong Lim,1 Weng Soon Wong,1

    Kumeresan A. Danapalasingam,1 Vijay K. Arora,1,2 and Michael Loong Peng Tan1

    1 Faculty of Electrical Engineering, Universiti Teknologi Malaysia (UTM), 81310 Skudai, Johor, Malaysia2 Division of Engineering and Physics, Wilkes University, Wilkes-Barre, PA 18766, USA

    Correspondence should be addressed to Michael Loong Peng Tan; [email protected]

    Received 10 December 2013; Revised 11 February 2014; Accepted 12 February 2014; Published 26 March 2014

    Academic Editor: Tianxi Liu

    Copyright ยฉ 2014 Huei Chaeng Chin et al. This is an open access article distributed under the Creative Commons AttributionLicense, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properlycited.

    Comparative benchmarking of a graphene nanoribbon field-effect transistor (GNRFET) and a nanoscale metal-oxide-semiconductor field-effect transistor (nano-MOSFET) for applications in ultralarge-scale integration (ULSI) is reported. GNRFETis found to be distinctly superior in the circuit-level architecture. The remarkable transport properties of GNR propel it into analternative technology to circumvent the limitations imposed by the silicon-based electronics. Budding GNRFET, using the circuit-level modeling software SPICE, exhibits enriched performance for digital logic gates in 16 nmprocess technology.The assessment ofthese performance metrics includes energy-delay product (EDP) and power-delay product (PDP) of inverter and NOR and NANDgates, forming the building blocks for ULSI.The evaluation of EDP and PDP is carried out for an interconnect length that ranges upto 100 ๐œ‡m. An analysis, based on the drain and gate current-voltage (๐ผ๐‘‘-๐‘‰๐‘‘ and ๐ผ๐‘‘-๐‘‰๐‘”), for subthreshold swing (SS), drain-inducedbarrier lowering (DIBL), and current on/off ratio for circuit implementation is given. GNRFET can overcome the short-channeleffects that are prevalent in sub-100 nm Si MOSFET. GNRFET provides reduced EDP and PDP one order of magnitude that islower than that of a MOSFET. Even though the GNRFET is energy efficient, the circuit performance of the device is limited by theinterconnect capacitances.

    1. Introduction

    The number of transistors on a typical 1 ร— 1 cm chip hasgrown exponentially with twofold increase every 18 monthskeeping Mooreโ€™s Law [1] on track. Serious hindrances arein sight as transistor scaling enters the nanometer domain.Short-channel effects are significant as devices are scaledbelow sub-100 nm, providing challenges and opportunitiesfor device and process engineers. Researchers across theglobe are exploring new nanomaterials with transformedarchitecture to circumvent the roadblocks of silicon-basednanotechnology for enhanced circuit performance. Inter-connects also play a key role as channels reach nanometerscale and resistance surge takes on an increasing impor-tance [2]. Carbon-based allotropes offer a distinct advantage

    in a variety of applications [3โ€“8]. Graphene nanoribbons(GNRs) are one-dimensional (1D) nanostructures restrictingcarrier motion in only one direction, reducing scattering forenhanced mobility [6, 9]. The transistor current is quite highas electrons are injected from the source and transit to thedrain terminal [6, 10โ€“12]. A narrow width semiconductingGNR is utilized as a channel in a top-gated transistor [13โ€“15]. This pushes the limits of complementary metal-oxide-semiconductor (CMOS) type of technology beyond its limitsin a GNR. This paper focuses on modeling, simulation,and benchmarking of top-gated graphene nanoribbon field-effect transistors (GNRFETs) against MOSFET. In addition,the evaluation of logic performance is carried out for bothdevices. It is observed that there is a good agreement betweenGNRFET and MOSFET based on the drain current-voltage

    Hindawi Publishing CorporationJournal of NanomaterialsVolume 2014, Article ID 879813, 14 pageshttp://dx.doi.org/10.1155/2014/879813

  • 2 Journal of Nanomaterials

    Table 1: Design specifications C and S for various channel lengths.

    Channel length (nm) C (nm) S (nm) W (nm)16 30 8 4632 50 16 8245 60 20 10065 90 40 17090 120 50 220180 220 100 420

    (๐ผ-๐‘‰) characteristics. The energy-delay product (EDP) andpower-delay product (PDP) are the performancemetrics thatrepresent the energy efficiencies of GNRFET and MOSFETlogic gates. The simulations in this work are carried outfor the 16 nm manufacturing processes. In the following,device model framework of our previous work [7, 16โ€“19] isextended for the simulation and analysis of GNRFET andMOSFET at 16 nm node. Circuit-level models of GNRFETare benchmarked against MOSFET. Logic performances ofcarbon and silicon-based inverter andNAND andNOR gatesare assessed. For a fair assessment, the same channel length,๐ฟ = 16 nm, is adopted for GNRFET, PMOS, and NMOS.The device modeling is carried out in MATLAB and circuitdevelopment and simulation is performed usingHSPICE andCosmoscope.

    2. Device Modeling

    The simulated silicon MOSFET is based on Berkeley short-channel IGFETmodel (BSIM) which was the standardmodelfor deep submicron CMOS circuit design in the early 2000s[20]. IC companies including Intel, IBM, AMD, NationalSemiconductor, and Samsung widely use the charge-basedmodel as an electronic computer-aided design (ECAD) tool.BSIM4 version 4.7 MOSFET model is utilized in the simu-lation of NMOS and PMOS [21] in the present assessment.The top view of GNRFET with source and drain contacts isdepicted in Figure 1. Various values of ๐ถ and ๐‘† (see Figure 2)are given in Table 1.

    3. Proposed Layout and Design

    The interpolated contact size ๐ถ and spacer size ๐‘† of16 nm node process technology are illustrated in Figures2(a) and 2(b), respectively.

    The channel width,๐‘Š, is a function of ๐ถ and S as givenby

    ๐‘Š = ๐ถ + 2๐‘†. (1)

    Table 1 gives design specifications for channel lengthsfrom 16 to 180 nm range.

    4. Analytical Modeling of GNRFET

    In this section, the analytical model of GNRFET is derived.The channel surface potential ๐‘‰SC, or self-consistent voltageas is commonly known, is solved numerically in MATLAB

    using Newton-Raphson algorithm to obtain the voltagepotential at the top barrier along the channel [23]. The ๐‘‰SCis given by

    ๐‘‰SC = ๐‘‰๐ฟ + ๐‘‰๐‘ =โˆ’๐‘„๐‘ก + ฮ”๐‘„

    ๐ถฮฃ

    , (2)

    where ๐ถฮฃ is the total sum of capacitance at all the fourterminals and ๐‘„๐‘ก is the total charge. ฮ”๐‘„ is the additionalcharge due to the increase of๐‘‰SC.๐‘‰๐ฟ is the potential appearingacross the channel region and ๐‘‰๐‘ƒ is existing across theparasitic regions.The other symbols in (2) are given as followswhere ๐‘๐‘  is the density of positive velocity states, ๐‘๐‘‘ is thedensity of negative velocity states and ๐‘0 is the electrondensity at equilibrium:

    ๐‘„๐‘ก = ๐ถ๐‘ ๐‘‰๐‘  + ๐ถ๐‘”๐‘‰๐‘” + ๐ถ๐‘‘๐‘‰๐‘‘ + ๐ถsub๐‘‰sub,

    ๐ถฮฃ = ๐ถ๐‘  + ๐ถ๐‘” + ๐ถ๐‘‘ + ๐ถsub,

    ฮ”๐‘„ = ๐‘ž (๐‘๐‘  + ๐‘๐‘‘ + ๐‘0) .

    (3)

    The carriers obey the Fermi-Dirac probability distribution asfollows:

    ๐‘๐‘  =1

    2โˆซ

    +โˆž

    โˆ’โˆž

    ๐ท (๐ธ)๐‘“ (๐ธ โˆ’ ๐‘ˆSF) ๐‘‘๐ธ,

    ๐‘๐‘‘ =1

    2โˆซ

    +โˆž

    โˆ’โˆž

    ๐ท (๐ธ)๐‘“ (๐ธ โˆ’ ๐‘ˆDF) ๐‘‘๐ธ,

    ๐‘0 = โˆซ

    +โˆž

    โˆ’โˆž

    ๐ท (๐ธ)๐‘“ (๐ธ โˆ’ ๐ธ๐น) ๐‘‘๐ธ,

    (4)

    where ๐‘ˆSF and ๐‘ˆDF are defined as

    ๐‘ˆSF = ๐ธ๐น โˆ’ ๐‘ž๐‘‰SC,

    ๐‘ˆDF = ๐ธ๐น โˆ’ ๐‘ž๐‘‰SC โˆ’ ๐‘ž๐‘‰๐‘‘.(5)

    The one-dimensional (1D) density of state (DOS) function in(4) is defined as

    ๐ท (๐ธ) =2๐‘”V๐‘”๐‘ 

    3๐œ‹๐‘Žcc๐‘กโˆ‘

    ๐‘–

    ๐ธ

    โˆš๐ธ2 โˆ’ (๐ธ๐บ/2)2

    , (6)

    where ๐‘Žcc = 0.142 nm is the Cโ€“C bond length and ๐‘ก = 3 eVis the Cโ€“C bonding energy. In (6), ๐ธ๐บ is the bandgap energy,๐‘”๐‘  is the spin degeneracy, and ๐‘”V is the valley degeneracy. Inan armchair GNR (aGNR), ๐‘”V = 1. A nonlinear regressionmodel of ๐‘‰SC is obtained through the use of the polynomialfit [24, 25].The nonlinear approximation for๐‘‰SC dependenceon๐‘‰๐‘‘ and๐‘‰๐‘” in the form of fifth-order polynomial is given toreplace theNewton-Raphson algorithm in (2).The regressionmodel is given as

    ๐‘‰SC (๐‘‰๐‘”, ๐‘‰๐‘‘) = ๐ด๐‘‰๐‘‘ + ๐ต๐‘‰๐‘”5+ ๐ถ๐‘‰๐‘”

    4

    + ๐ท๐‘‰๐‘”3+ ๐ธ๐‘‰๐‘”

    2+ ๐น๐‘‰๐‘” + ๐บ,

    (7)

    where ๐ด, ๐ต, ๐ถ, ๐ท, ๐ธ, ๐น, and ๐บ are the coefficients extractedfromMATLAB curve fitting tool.

  • Journal of Nanomaterials 3

    Contact

    Contact length, L c

    Wid

    th (W

    )

    ChannelContactGraphene nanoribbon

    C

    S

    S

    Channel length, L

    Figure 1: Top view of GNRFET device structure with contact and channel design layout architecture.

    0 50 100 150 2000

    50

    100

    150

    200

    250

    Technology process (nm)

    Con

    tact

    size

    , C (n

    m)

    Contact size

    Process design kitLinear regression

    (a)

    0 50 100 150 2000

    20

    40

    60

    80

    100

    120

    140

    160

    180

    200

    Technology process (nm)

    Spac

    er si

    ze, S

    (nm

    )

    Spacer size

    Process design kitLinear regression

    (b)

    Figure 2: Interpolation of (a) contact and (b) spacer sizes.

    Table 2: Values for the coefficients A to G.

    Coefficient ValueA โˆ’3.5000 ร— 10โˆ’2

    B 1.0737 ร— 10โˆ’3

    C โˆ’2.7542 ร— 10โˆ’3

    D 2.3754 ร— 10โˆ’3

    E โˆ’6.3691 ร— 10โˆ’4

    F โˆ’8.8009 ร— 10โˆ’1

    G โˆ’3.5738 ร— 10โˆ’4

    The coefficients ๐ด to ๐บ in Table 2 are empirical parame-ters used for curve fitting (2).

    HSPICE utilizes (8) to simulate the drain and gate ๐ผ-๐‘‰characteristic of GNRFET and MOSFET. The noniterativemodel allows cross-platform simulation, shorter executiontime, and reduced computational cost [26]. In GNRFET,when gate and drain voltages are applied, ๐‘‰SC is reduced by๐‘‰๐ฟ. This would result in a flow of electron in the channel

    that increases๐‘‰SC by๐‘‰๐‘ƒ due to introduction of the additionalcharges [27]. In the ๐ผ๐‘‘-๐‘‰๐‘‘ simulation of GNRFET, the ๐ผ๐‘‘-๐‘‰๐‘‘equation can be written in ๐‘‰๐‘‘, ๐‘‰๐‘  and ๐‘‰๐‘” coefficients as givenby

    ๐ผ๐‘‘ (๐‘‰๐‘”, ๐‘‰๐‘‘, ๐‘‰๐‘ )

    = ๐บON๐‘˜๐ต๐‘‡

    ๐‘ž[log(1+exp(

    ๐‘ž (๐ธ๐น โˆ’ ๐‘‰SC (๐‘‰๐‘”, ๐‘‰๐‘‘, ๐‘‰๐‘ ))

    ๐‘˜๐ต๐‘‡))] . . .

    โˆ’ ๐บON๐‘˜๐ต๐‘‡

    ๐‘ž

    ร— [log(1+exp(๐‘ž (๐ธ๐นโˆ’๐‘‰SC (๐‘‰๐‘”, ๐‘‰๐‘‘, ๐‘‰๐‘ )โˆ’ ๐‘‰๐‘‘ โˆ’ ๐‘‰๐‘ )

    ๐‘˜๐ต๐‘‡))] ,

    (8)

    where ๐บON is the on-conductance.

  • 4 Journal of Nanomaterials

    0 0.2 0.4 0.6 0.8 10

    5

    10

    15

    20

    25

    30

    GNRFETn-type MOSFETp-type MOSFET

    Vd (V)

    I d(๐œ‡

    A)

    Figure 3: ๐ผ๐‘‘-๐‘‰๐‘‘ characteristics n-type GNRFET, p-type, and n-typeMOSFET for various gate voltages starting from ๐‘‰๐‘” = 1V at the topin 0.1 V decrement.

    5. Device Simulation

    The device performance of GNRFET and MOSFET arecompared by evaluating their respective ๐ผ๐‘‘-๐‘‰๐‘‘ characteristicas shown in Figure 3. The output response of p-type and n-type MOSFETs is superimposed for comparison purposes.Also, the ๐ผ๐‘‘-๐‘‰๐‘‘ characteristics of p-type and n-typeGNRFETsare symmetrical as in a CMOS and thus coincide with eachother. Figure 4 illustrated the ๐ผ๐‘‘-๐‘‰๐‘” transfer characteristic ofn-type and p-type MOSFET and GNRFET. DIBL and SS arecalculated from the ๐ผ๐‘‘-๐‘‰๐‘” curve and are given as

    DIBL = ๐œ•๐‘‰๐‘‡๐œ•๐‘‰๐‘‘

    ,

    SS =๐œ•๐‘‰๐‘”

    ๐œ• (log10๐ผ๐‘‘).

    (9)

    The range of the DIBL measurement is taken between |๐‘‰๐‘‘| =0.1V and |๐‘‰๐‘‘| = 1V and the SS measurement is for the draincurrent curve at |๐‘‰๐‘‘| = 0.1V. As deduced from Figure 3,GNRFET has a lower linear on-conductance compared toMOSFET. In addition, GNRFET achieves higher saturationcurrent values than those of MOSFET for most gate voltages.

    As listed in Table 3, the DIBL of MOSFET is betterthan GNRFET. The subthreshold swing (SS) of both devicesis comparable. The ๐ผon/๐ผoff ratio of GNRFET is two-ordermagnitude lower than that of MOSFET.This is due to a lowerlinear on-conductance limit of a ballistic GNRFET. The on-conductance limit, ๐บON, with zero contact resistance is givenby

    ๐บON =2๐‘ž2

    โ„Ž, (10)

    Table 3: Device parameters and performance metrics of GNRFET,n-type, and p-type MOSFET.

    Parameter GNRFET n-typeMOSFETp-type

    MOSFETElectrical gate oxidethickness (nm) 2.0 1.0 1.6

    Gate dielectric constantrelative to vacuum 25 25 25

    Subthreshold swing(mV/decade) 70.1704 61.7527 70.7253

    Drain-induced barrierlowering (mV/V) 40.7448 35.2515 36.6697

    On/off ratio, (๐ผon/๐ผoff ) 3.42 ร— 104 1.25 ร— 106 6.9868 ร— 105

    where ๐‘ž is the electronic charge and โ„Ž is Planckโ€™s constant.The simulation is carried out using a high gate dielectricconstant (high-๐‘˜) with high thermal stability. In a practicalmicrofabrication, zirconium dioxide which has high-๐‘˜ valuesbetween 20 and 25 is considered [28].

    Note that different values of oxide thickness are beingused to obtain almost symmetrical ๐ผ-๐‘‰ characteristics forboth p-type and n-type MOSFET, namely, in the linearregion. It is found that when all the transistors adopt equaloxide thickness, the maximum current at ๐‘‰๐‘‘ = 1V and ๐‘‰๐‘” =1V differs from one another. The output waveform will nothave uniform square wave anymore. The propagation delay,rise time, and fall time will be significantly affected. Thus,they are no longer suitable for logic application due to themismatch of the p-type and n-type ๐ผ๐‘‘-๐‘‰๐‘‘ curves at the voltagetransfer characteristics.

    6. Circuit Design

    In this Section, circuit simulation is considered. As partof the circuit design process, parasitic capacitance, namely,load capacitance ๐ถ๐ฟ is determined for an accurate circuitrepresentation. The top diagram in Figure 5 shows a typicalarrangement of two inverters in series with ๐ถ๐ฟ. The compo-nents of ๐ถ๐ฟ are gate-drain capacitance ๐ถgd1, ๐ถgd2, drain-bulkcapacitance ๐ถdb1, ๐ถdb2, and wire capacitance ๐ถ๐‘Š as depictedin the bottom diagram of Figure 5. Note that the termwire capacitance is used interchangeably with interconnectcapacitance. Table 4 lists the local, intermediate, and globalcopper and GNRFET interconnect capacitances for 32 nm,22 nm, and 14 nm technology process. The finite elementmethod (FEM) charts the pathways in obtaining capacitancesas in [29]. The interconnects used in the simulation areconsidered to be in the intermediate layer [30] and vary from1 ๐œ‡m to 100 ๐œ‡m in length [31]. It is found that for 0.18 ๐œ‡mtechnology, average interconnect lengths are considered to be7 ๐œ‡mper fan-out [31].These interconnect specifications fromITRS 2005 are shown in Table 4.

    Table 5 shows the extrapolated interconnect capacitancesfor the 90 nm, 65 nm, 45 nm, and 16 nm process technologies.The capacitance values of copper and metallic GNR areextrapolated from Figure 6 using a linear function based onthe intermediate capacitance in Table 4.

  • Journal of Nanomaterials 5

    โˆ’1 โˆ’0.5 0 0.5 110โˆ’11

    10โˆ’10

    10โˆ’9

    10โˆ’8

    10โˆ’7

    10โˆ’6

    10โˆ’5

    10โˆ’4

    MOSFET

    p-type n-type

    Vd

    = +/โˆ’ 0.1 VVd

    = +/โˆ’ 1 V

    Vg (V)

    I d(๐œ‡

    A)

    (a)

    10โˆ’11

    10โˆ’10

    10โˆ’9

    10โˆ’8

    10โˆ’7

    10โˆ’6

    10โˆ’5

    10โˆ’4

    Vd

    = +/โˆ’ 0.1 VVd

    = +/โˆ’ 1 V

    โˆ’1 โˆ’0.5 0 0.5 1

    GNRFET

    p-type n-type

    Vg (V)I d

    (๐œ‡A

    )

    (b)

    Figure 4: ๐ผ๐‘‘-๐‘‰๐‘” transfer characteristic of n-type and p-type (a) MOSFET and symmetrical n-type and p-type (b) GNRFET FET for |๐‘‰๐‘‘| =0.1V and |๐‘‰๐‘‘| = 1V.

    VCC

    M1M1

    M2

    M3

    M4

    Cgd12

    VCC

    Cdb2

    Cdb1

    CW

    Cgs3

    Cgs4

    CG3

    CG4

    CL

    Vout

    Vout

    Vout2

    Vout2

    Vin

    Vin

    Figure 5: Two-cascaded inverter gate with parasitic capacitance.

    Table 6 contains the relevant equations for the load andoutput capacitance for the logic gates.

    7. Performance Analysis of Digital Circuit

    HSPICE is used to simulate the logic operations of GNR-FET and MOSFET. The schematic diagram and input-output waveforms of GNRFET and MOSFET NOT, two-input NAND (NAND2), two-input NOR (NOR2), three-input NAND (NAND3), and three-input NOR (NOR3) gates

    are delineated in Figures 7, 8, 9, 10, and 11, respectively. Allthe logic gates consist of 1 ๐œ‡m copper interconnects at theoutput terminals. In the simulation, the maximum fan-infor a gate is limited to 3. Correct logical operations areconfirmed from the simulation results as shown in theinput-output waveforms. Voltage spikes observed are foundto be negligible in the output waveform of MOSFET inFigures 7(b)โ€“11(b). The circuit inductance possibly causesspikes that are possible to be compensated by incorporatingan on-chip decoupling capacitor at the output in parallel.Note that Figures 7โ€“Figure 11 are important to calculate thepropagation delay which is computed between 50% of theinput rising to the 50% of the output rising. Together withthe average power consumption, the metric performance oflogic gates in termof EDP andPDP is obtained. PDP andEDPparameters are the figure of merit for logic devices. PDP andEDP are given by

    PDP = ๐‘ƒav ร— ๐‘ก๐‘,

    EDP = PDP ร— ๐‘ก๐‘,(11)

    where๐‘ƒav is the average power and ๐‘ก๐‘ is the propagation delay.Table 7 lists the ๐‘ƒav and ๐‘ก๐‘ for various logic gates as obtainedfrom the simulation. The PDP and EDP for GNRFET arean order of lower magnitude compared to MOSFET dueto smaller ๐‘ก๐‘ and its ultralow ๐‘ƒav during logic operation asrevealed in Table 7. GNRFET power consumption is by atleast 1 order of magnitude lower than that of a MOSFET.

  • 6 Journal of Nanomaterials

    0 20 40 60 800

    50

    100

    150

    200

    250

    Technology process (nm)

    Cop

    per c

    apac

    itanc

    e (p

    F/m

    )

    Copper interconnect capacitance

    ITRS 2005Interpolation

    (a)

    0 20 40 60 800

    50

    100

    150

    200

    250

    Technology process (nm)G

    NRF

    ET c

    apac

    itanc

    e (p

    F/m

    )

    GNRFET interconnect capacitance

    ITRS 2005Interpolation

    (b)

    Figure 6: Extrapolation of interconnect capacitance for copper and GNR.

    In Out

    VDD

    (a)

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    VA

    Inverter gate for GNRFET with 1๐œ‡m interconnect

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    Time (s)

    Time (s)0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6

    00.5

    1

    VA

    Inverter gate for MOSFET with 1๐œ‡m interconnect

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    Time (s)

    Time (s)

    Vou

    t

    Vou

    t

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    (b)

    Figure 7: (a) Schematic of NOT gate. (b) Input and output waveforms for GNRFET and MOSFET with 1 ๐œ‡m interconnect.

  • Journal of Nanomaterials 7

    A B

    A

    B

    Out

    VDD

    (a)

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    Time (s)

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    Time (s)

    Time (s) Time (s)

    Time (s) Time (s)

    VA

    VB

    Vou

    t

    VA

    VB

    Vou

    t

    NAND2 gate for GNRFET with 1๐œ‡m interconnect NAND2 gate for MOSFET with 1๐œ‡m interconnect

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    (b)

    Figure 8: (a) Schematic of NAND2 gate. (b) Input and output waveforms for GNRFET and (b) MOSFET with 1 ๐œ‡m interconnect.

    Table 4: ITRS 2005 based simulation parameters (adapted from[22]).

    Technology process (nm) 32 22 14Local and intermediate

    WidthW (nm) 32 22 14ILD thickness ๐‘กox (nm) 54.40 39.60 25.20๐ถcu (pF/m) 144.93 131.01 111.83๐ถgnrfet (pF/m) 130.15 117.70 100.51

    GlobalWidthW (nm) 48 32 21ILD thickness ๐‘กox (nm) 110.40 76.80 52.50๐ถcu (pF/m) 179.78 163.30 139.30๐ถgnrfet (pF/m) 163.81 148.90 126.78

    Figure 12 depicts the layout for GNRFET NOR2schematic shown in Figure 9(a). In the top-gated design, the

    Table 5: Interconnect capacitances for 16, 45, 65, and 90 nm nodes.

    Capacitance Technology process (nm)90 65 45 16

    ๐ถcu (pF/m) 252.32 206.60 170.03 116.99๐ถgnr (pF/m) 226.87 185.70 152.76 105.01

    GNR is placed under the metal gate and thus hidden fromthe view. The ๐‘‰๐‘” is supplied to the device through terminalsA and B. The vertical-interconnect-access (via) as labeled inFigure 12 allows a conductive connection between differentlayers. To realize the number of p-type and n-type transistorsas given in Figure 9(a), three and four electrode contacts,respectively, are implemented in the layout. While the seriesconfiguration of the p-type transistors requires only threeelectrode contacts, and four electrode contacts are neededfor the n-type transistors connected in parallel.

  • 8 Journal of Nanomaterials

    A

    B

    A B

    Out

    VDD

    (a)

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    Time (s)

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    Time (s)

    Time (s) Time (s)

    Time (s) Time (s)

    VA

    VB

    Vou

    t

    VA

    VB

    Vou

    t

    NOR2 gate for GNRFET with 1๐œ‡m interconnect NOR2 gate for MOSFET with 1๐œ‡m interconnect

    ร—10โˆ’7

    ร—10โˆ’7 ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    (b)

    Figure 9: (a) Schematic of NOR2 gate. (b) Input and output waveforms for GNRFET and (b) MOSFET with 1 ๐œ‡m interconnect.

    Table 6: Load and output capacitance for logic gates NOT, two-input NAND, two-input NOR, three-input NAND, and three-input NOR.

    Gate logic CapacitanceNOT ๐ถ๐ฟ = ๐ถgd1 + ๐ถgd2 + ๐ถdb1 + ๐ถdb2 + ๐ถ๐‘ŠTwo-input NAND ๐ถ1 = ๐ถdb1 + ๐ถsb2 + ๐ถgd1 + ๐ถgs2Two-input NOR ๐ถ๐ฟ = ๐ถdb2 + ๐ถdb3 + ๐ถdb4 + ๐ถgd2 + ๐ถgd3 + ๐ถgd4 + ๐ถ๐‘ŠThree-input NAND ๐ถ1 = ๐ถdb1 + ๐ถsb2 + ๐ถgd1 + ๐ถgs2Three-input NOR ๐ถ

    2= ๐ถdb2 + ๐ถsb3 + ๐ถgd2 + ๐ถgs3

    ๐ถ๐ฟ = ๐ถdb3 + ๐ถdb4 + ๐ถdb5 + ๐ถdb6 + ๐ถgd3 + ๐ถgd4 + ๐ถgd5 + ๐ถgd6 + ๐ถ๐‘Š

    The Fermi velocity in a GNRFET is distinctly higherthan that in a heavily dopedMOSFET. Obviously, degeneratestatistics is applicable in heavily doped channels.The intrinsicvelocity for a nondegenerate low-doping level is limited tothe thermal velocity which is lower than the Fermi velocityin heavily doped semiconductors. The device modeling ofGNR adopts similar modeling framework in [17] where we

    havemodified the density of states and quantum conductancelimit of a ballistic SWCNT to GNR. The maximum draincurrent for a monolayer GNRFET is found to be at 19 ๐œ‡A. ForCNTFET, the maximum drain current is at 46 ๐œ‡A. Neverthe-less, both low dimensional carbon devices outperform siliconMOSFET in term of power-delay-product (PDP) and energy-delay-product (EDP) by at least one order of magnitude.

  • Journal of Nanomaterials 9

    A B

    A

    B

    Out

    C

    C

    VDD

    (a)

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    Time (s)

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    Time (s)

    Time (s) Time (s)

    Time (s) Time (s)

    Time (s) Time (s)

    VA

    VB

    VC

    Vou

    t

    VA

    VB

    VC

    Vou

    t

    NAND3 gate for GNRFET with 1๐œ‡m interconnect NAND3 gate for MOSFET with 1๐œ‡m interconnect

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    (b)

    Figure 10: (a) Schematic of NAND3 gate. (b) Input and output waveforms for GNRFET and (b) MOSFET with 1 ๐œ‡m interconnect.

    Table 7: Propagation delay and average power consumption of GNRFET and MOSFET with L = 16 nm and 1 ๐œ‡m interconnect for variouslogic gates.

    Logic gates Propagation delay, ๐‘ก๐‘ (ps) Average power, ๐‘ƒav (nJ/s)GNRFET MOSFET GNRFET MOSFET

    Inverter 4.825 14.02 2.90 96.11Two-input NAND 7.059 44.90 3.13 124.04Three-input NAND 9.555 58.82 3.24 270.18Two-input NOR 7.059 44.95 3.07 122.12Three-input NOR 9.589 58.19 3.24 286.58

  • 10 Journal of Nanomaterials

    A

    B

    A B

    Out

    C

    C

    VDD

    (a)

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    Time (s)

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.60

    0.51

    Time (s)

    Time (s) Time (s)

    Time (s) Time (s)

    Time (s) Time (s)

    NOR3 gate for GNRFET with 1๐œ‡m interconnect NOR3 gate for MOSFET with 1๐œ‡m interconnectV

    AV

    BV

    CV

    out

    VA

    VB

    VC

    Vou

    t

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    ร—10โˆ’7

    (b)

    Figure 11: (a) Schematic of NOR3 gate. (b) Input and output waveforms for GNRFET and (b) MOSFET with 1 ๐œ‡m interconnect.

    Figure 13 depicts the GNRFET PDP and EDP, respec-tively, for 0โ€“100 ๐œ‡m copper interconnects in length for var-ious logic gates. Figure 14 shows the MOSFET PDP and EDP,respectively, for 0โ€“100๐œ‡m copper interconnect in length forvarious logic gates. The logic gates with high fan-in exhibitincreased EDP andPDP as exhibited by these plots.The cutofffrequency at which the current gain is 1 is used to describethe high-frequency performance of a transistor. The currentunity gain cutoff frequency of the intrinsic transistor [32, 33]with interconnect capacitance is given by

    ๐‘“๐‘‡ =1

    2๐œ‹

    ๐‘”๐‘š

    ๐ถ๐‘” + C๐ฟ + ๐ถsub, (12)

    where ๐ถ๐‘” is the gate capacitance, ๐ถ๐ฟ is the load capacitance,and ๐ถsub is the substrate capacitance. Devices with thickersubstrate insulator (for instances, 500 nm) and smaller con-tact area have higher unity cutoff frequency.Theunity currentgain cutoff frequency for GNRFET circuit model is depictedin Figure 15. The model uses a copper interconnect of the16 nm, 45 nm, 65 nm, 9 and 0 nm nodes technology. Thesimulation shows that a 16 nm GNRFET can deliver a unitycutoff frequency of 400GHz. The interconnect length variesfrom 0.01๐œ‡m to 100๐œ‡m. It is found that cutoff frequencyis inversely proportional to interconnect length. When theinterconnects are longer than 10 ๐œ‡m, the frequency remainsthe same regardless of the technology nodes. Therefore, it

  • Journal of Nanomaterials 11

    Metal

    Gate contact

    Electrode contact

    Output

    Via

    p-type FET

    n-type FET

    Figure 12: Proposed layout of GNRFET NOR2 gate with metalcontacts and interconnects.

    is essential to utilize interconnects as short as possible totap the high-frequency capability of the CNTFETs [17] andGNRFETs. Our finding is consistent with the state-of-the-artgraphene transistors that have been shown to reach operatingfrequencies up to 300GHz experimentally [34].

    8. Conclusions

    Complementary CMOS based on ๐‘›-type and ๐‘-type MOS-FETs has been at the center stage in industrial environmentsbecause of low power consumption. A CMOS circuit drawspower from the source only when an inverter is switchingfrom low to high or vice versa. A CMOS inverter is abuilding block for other gates to build a complete ultralarge-scale-integrated (ULSI) ensemble. After the 2010 Nobel Prizeawarded to graphene, graphene allotropes have overwhelmedthe center stage to capture the advantage ofMore thanMooreโ€™sEra. In fact, Arora and Bhattacharyya [35] show that CNTband structure can be drawn from that of graphene nanolayerwith rollover in various chirality directions. GNR [36] offerssimilar endless opportunities. Considering these noteworthydevelopments, we believe that graphene allotropes offerdistinct advantage over and above the CMOS architecturefor a variety of applications in creating sensors, actuators,and transistors for implementation in the ULSI. As grapheneallotropes bring to focus the advanced applications, weconsider GNR as an example to demonstrate its superiorityover the CMOS. Primary reason why graphene is superiorto silicon is its intrinsic velocity. The drift in graphene islimited to the Fermi velocity V๐น โ‰ˆ 10

    6m/s that is 10 times thanthat of a silicon (V๐‘– โ‰ˆ 10

    5m/s). Saturation velocity limited tothe intrinsic velocity V๐‘– determines the high-frequency cutoffof a ULSI circuit. That is the reason that graphene-basedelectronics will offer unique advantage in high-frequencycircuit design. As current saturates, the power in a ULSIcircuit is governed by ๐‘ƒ = ๐‘‰๐ผsat and hence becomes a linearfunction of voltage, in direct contrast to square law dictatedby Ohmโ€™s law. The power consumption will be much lowerin a graphene circuit affording the opportunity to lower thescale of the voltage source. Power-frequency product is a

    figure of merit in ULSI applications.The paper shows distinctadvantages of graphene-based integration in ULSI circuitsin designing various Boolean gates. The comparative studystretches the landscape ofMore than Moore era as traditionalscaling reaches its limit. As demonstrated by Greenberg anddel Alamo [37], interconnect degrades the device behavior.That iswhy it is important to include interconnects in the totalpackage of these studies. The rise in the resistance in scaled-down channels also affects the voltage divider and currentdivider principles, normally based on Ohmโ€™s law. Wheninterconnects are considered in series with the channel, theresistance surges for a smaller length resistor, creating theimportance of comprehensive study [38]. Similarly, whenparasitic channels are considered in parallel with the con-ducting channel, the resistance can be higher than what ispredicted fromOhmโ€™s law.This rise in resistance can increasethe RC time constants as demonstrated in [38, 39]. GNRFETwith proper architecture can extend the domain ofMore thanMoore era in meeting the requirements of the future. Short-channel effects that restrict the silicon technology to reachits full potential are controllable in GNRFET architecture.GNRFET has shown comparable device performance against16 nm CMOS node. In terms of circuit performance inlogic design, the PDP and EPD of GNRFET are distinctlybetter. The modern adage is โ€œsilicon comes from geology,but carbon comes from biology.โ€ This transformation fromsilicon to carbon-based graphene will usher new era forcircuit design based on carbon electronics that is expected tobe compatible with bioelements. ULSI designers will greatlybenefit from this comparative study as they change theirmode of thinking from CMOS to new graphene-based ULSI.We are also expecting that parasitic elements that inhibit thespeed of ULSI circuits will pose less of a problem in futurearchitectures based on our findings. The all-encompassinglandscape covered in this paper will find broader applicationsbenefitting not only the research labs in their characterizationandperformance evaluation, but also in giving newdirectionsto the industry in product development that will benefitglobal community.

    Conflict of Interests

    The authors declare that there is no conflict of interestsregarding the publication of this paper.

    Acknowledgments

    The authors would like to acknowledge the financialsupport from UTM GUP Research Grant (Vote nos.:Q.J130000.2523.04H32 and Q.J130000.2623.09J21) andFundamental Research Grant Scheme (FRGS) (Votenos.: R.J130000.7823.4F247, R.J130000.7823.4F273, andR.J130000.7823.4F314) of the Ministry of Higher Education(MOHE), Malaysia. Weng Soon Wong thanks YayasanSime Darby (YSD) for the scholarship given for his study atthe Universiti Teknologi Malaysia (UTM). Vijay K. Aroraappreciates the Distinguished Visiting Professorship of theUTM. UTM Research Management Centre (RMC) provided

  • 12 Journal of Nanomaterials

    CMOS NAND2

    NAND3NOR2 NOR3

    0

    50

    1000

    0.5

    1

    1.5

    Logic gates

    PDP of GNRFETPo

    wer

    -del

    ay p

    rodu

    ct (J

    )

    Interconnect length (๐œ‡m)

    ร—10โˆ’16

    (a)

    CMOS NAND2

    NAND3NOR2 NOR3

    0

    50

    1000

    0.5

    1

    Logic gates

    EDP of GNRFET

    Ener

    gy-d

    elay

    pro

    duct

    (J.s)

    Interconnect length (๐œ‡m)

    ร—10โˆ’25

    (b)

    Figure 13: (a) PDP and (b) EDP of GNRFET logic gates for copper interconnect length from 0 to 100 ๐œ‡m.

    CMOS NAND2NAND3

    NOR2 NOR3

    0

    50

    1000

    0.5

    1

    1.5

    Logic gat

    es

    PDP of MOSFET

    Pow

    er-d

    elay

    pro

    duct

    (J)

    Interconnect length (๐œ‡m)

    ร—10โˆ’15

    (a)

    CMOS NAND2

    NAND3NOR2

    NOR3

    0

    50

    1000

    0.5

    1

    1.5

    2

    2.5

    Logic gates

    EDP of MOSFET

    Ener

    gy-d

    elay

    pro

    duct

    (J.s)

    Interconnect length (๐œ‡m)

    ร—10โˆ’24

    (b)

    Figure 14: (a) PDP and (b) EDP of MOSFET logic gates for copper interconnect length from 0 to 100 ๐œ‡m.

    10โˆ’2 10โˆ’1 100 101 1020

    50

    100

    150

    200

    250

    300

    350

    400

    Cut

    off fr

    eque

    ncy

    (GH

    z)

    16 nm node45 nm node

    65 nm node90 nm node

    Length of interconnect (๐œ‡m)

    Figure 15: Unity cutoff frequency for GNRFET based on 16 nm,45 nm, 65 nm, and 90 nm process technology.

    excellent support conduciveness to the research environmentneeded to complete project of this magnitude with personnelof far-reaching background.

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