Date of issue: 24/06/2015 Revision date: 24/06/2015 Version: 1.0
24/06/2015 EN (English) 1/8
SECTION 1: Identification of the substance/mixture and of the company/undertaking1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified usesUse of the substance/mixture : Coating
1.2.2. Uses advised againstNo additional information available
1.3. Details of the supplier of the safety data sheet
1.4. Emergency telephone numberEmergency number : ORFILA - 0033 1 45 42 59 59
SECTION 2: Hazards identification2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture: SDS < 2015 : Show CLP information + DPD classification in section 2.1Flam. Liq. 3 H226 Acute Tox. 4 (Inhalation:dust,mist) H332 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Repr. 2 H361 STOT RE 1 H372
Full text of H-statements: see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]Xn; R20Xi; R36/37/38R10Xn; R48/20Full text of R-phrases: see section 16
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Hazard pictograms (CLP) :
GHS02 GHS07 GHS08
Signal word (CLP) : DangerHazardous ingredients : StyreneHazard statements (CLP) : H226 - Flammable liquid and vapour
H315 - Causes skin irritationH319 - Causes serious eye irritationH332 - Harmful if inhaled
Uni-Mould Tooling Gel-CoatSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
Product formProduct name
: Mixture: Uni-Mould Tooling Gel-Coat : ResinType of product
Easy Composites LtdUnit 39, Park Hall Business Village, Stoke on Trent,Staffordshire, ST3 5XA. United Kingdom.T +44 (0) 1782 454499 (08:00 - 17:30hrs, Mon-Fri) - F +44 (0)1782 [email protected] - www.easycomposites.co.uk
24/06/2015 EN (English) 2/8
H361 - Suspected of damaging fertility or the unborn childH372 - Causes damage to organs through prolonged or repeated exposure
Precautionary statements (CLP) : P280 - Wear protective gloves, protective clothing, eye protectionP241 - Use explosion-proof electrical equipmentP271 - Use only outdoors or in a well-ventilated areaP370+P378 - In case of fire: Use Water fog, foam, extinguishing powder, carbon dioxide (CO2) for extinctionP264 - Wash hands thoroughly after handlingP210 - Keep away from heat, hot surfaces, sparks, open flames. - No smoking
2.3. Other hazardsAdverse physicochemical, human health and environmental effects
: Flammable liquid and vapour. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.
SECTION 3: Composition/information on ingredients3.1. SubstanceNot applicable
3.2. Mixture
Name Product identifier % Classification according to Directive 67/548/EEC
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Styrene (CAS No) 100-42-5(EC no) 202-851-5(EC index no) 601-026-00-0(REACH-no) 01-2119457861-32
30 - 40 Repr.Cat.3; R63Xn; R20Xn; R48/20Xi; R36/38R10
Flam. Liq. 3, H226Repr. 2, H361dAcute Tox. 4 (Inhalation), H332STOT RE 1, H372Skin Irrit. 2, H315Eye Irrit. 2, H319
(CAS No) 64742-95-6(EC no) 265-199-0(EC index no) 649-356-00-4(REACH-no) 01-2119455851-35
< 1 Xn; R65N; R51/53R10R67R66Xi; R37
Flam. Liq. 3, H226STOT SE 3, H335Asp. Tox. 1, H304Aquatic Chronic 2, H411
ethanediol, ethylene glycolsubstance with a Community workplace exposure limit
(CAS No) 107-21-1(EC no) 203-473-3(EC index no) 603-027-00-1(REACH-no) 01-2119472426-35
< 1 Xn; R22 Acute Tox. 4 (Oral), H302
xylenesubstance with a Community workplace exposure limit
(CAS No) 1330-20-7(EC no) 215-535-7(EC index no) 601-022-00-9(REACH-no) 01-2119488216-32
< 1 R10Xn; R20/21Xi; R38
Flam. Liq. 3, H226Acute Tox. 4 (Inhalation), H332Acute Tox. 4 (Dermal), H312Skin Irrit. 2, H315
ethylbenzenesubstance with a Community workplace exposure limit
(CAS No) 100-41-4(EC no) 202-849-4(EC index no) 601-023-00-4
< 1 F; R11Xn; R20Xn; R65Xn; R48/20
Flam. Liq. 2, H225Acute Tox. 4 (Inhalation), H332STOT RE 2, H373Asp. Tox. 1, H304
(CAS No) 95-71-6(EC no) 202-443-7
< 1 Xn; R22Xi; R36/38N; R50
Acute Tox. 4 (Oral), H302Skin Irrit. 2, H315Eye Irrit. 2, H319Aquatic Acute 1, H400 (M=10)
Specific concentration limits:Name Product identifier Specific concentration limits:
DSD/DPDSpecific concentration limits: CLP
Styrene (CAS No) 100-42-5(EC no) 202-851-5(EC index no) 601-026-00-0(REACH-no) 01-2119457861-32
(C >= 12,5) Xn;R20(C >= 12,5) Xi;R36/38
xylene (CAS No) 1330-20-7(EC no) 215-535-7(EC index no) 601-022-00-9(REACH-no) 01-2119488216-32
(C >= 12,5) Xn;R20/21
Full text of R- and H-statements: see section 16
SECTION 4: First aid measures4.1. Description of first aid measuresFirst-aid measures general : IF exposed or concerned: Get medical advice/attention. Call a poison center or a doctor if you
feel unwell.
Uni-Mould Tooling Gel-CoatSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
24/06/2015 EN (English) 3/8
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison center or a doctor if you feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayedSymptoms/injuries after skin contact : Irritation.Symptoms/injuries after eye contact : Eye irritation.
4.3. Indication of any immediate medical attention and special treatment neededTreat symptomatically.
SECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.
5.2. Special hazards arising from the substance or mixtureFire hazard : Flammable liquid and vapour.Hazardous decomposition products in case of fire
: Toxic fumes may be released.
5.3. Advice for firefightersProtection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing. Use water spray or fog for cooling exposed containers. Prevent entry to sewers and public waters.
SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnelEmergency procedures : Ventilate spillage area. No open flames, no sparks, and no smoking. Avoid contact with skin
and eyes. Do not breathe vapours. fume.
6.1.2. For emergency respondersProtective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautionsAvoid release to the environment.
6.3. Methods and material for containment and cleaning upMethods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public
waters.Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sectionsFor further information refer to section 13.
SECTION 7: Handling and storage7.1. Precautions for safe handlingPrecautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapours may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe fume. Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes.
Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilitiesTechnical measures : Ground/bond container and receiving equipment.Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed.
7.3. Specific end use(s)No additional information available
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
24/06/2015 EN (English) 4/8
SECTION 8: Exposure controls/personal protection8.1. Control parameters
Styrene (100-42-5)United Kingdom WEL STEL (mg/m³) 1080 mg/m³United Kingdom WEL STEL (ppm) 250 ppm
ethanediol, ethylene glycol (107-21-1)EU IOELV TWA (mg/m³) 246 mg/m³EU IOELV TWA (ppm) 50 ppmEU IOELV STEL (mg/m³) 492 mg/m³EU IOELV STEL (ppm) 100 ppm
ethylbenzene (100-41-4)EU Local name EthylbenzeneEU IOELV TWA (mg/m³) 442 mg/m³EU IOELV TWA (ppm) 100 ppmEU IOELV STEL (mg/m³) 884 mg/m³EU IOELV STEL (ppm) 200 ppmEU Notes Skin
xylene (1330-20-7)EU Local name Xylene, mixed isomers, pureEU IOELV TWA (mg/m³) 221 mg/m³EU IOELV TWA (ppm) 50 ppmEU IOELV STEL (mg/m³) 442 mg/m³EU IOELV STEL (ppm) 100 ppmEU Notes Skin
8.2. Exposure controls
Appropriate engineering controls : Ensure good ventilation of the work station.
Hand protection : Protective gloves
Eye protection : Safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask
Environmental exposure controls : Avoid release to the environment.
SECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesPhysical stateColour
: Liquid: Black.
Odour : characteristic.Odour threshold : No data availablepH : No data availableRelative evaporation rate (butylacetate=1) : No data availableMelting point : Not applicableFreezing point : No data availableBoiling point : No data availableFlash point : No data availableAuto-ignition temperature : No data availableDecomposition temperature : No data availableFlammability (solid, gas) : Not applicableVapour pressure : No data availableRelative vapour density at 20 °C : No data availableRelative density : 1 - 1,1Solubility : No data available
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
24/06/2015 EN (English) 5/8
9.2. Other informationNo additional information available
SECTION 10: Stability and reactivity10.1. ReactivityFlammable liquid and vapour.
10.2. Chemical stabilityStable under normal conditions.
10.3. Possibility of hazardous reactionsNo dangerous reactions known under normal conditions of use.
10.4. Conditions to avoidAvoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.
10.5. Incompatible materialsNo additional information available
10.6. Hazardous decomposition productsUnder normal conditions of storage and use, hazardous decomposition products should not be produced.
SECTION 11: Toxicological information11.1. Information on toxicological effectsAcute toxicity : Inhalation:dust,mist: Harmful if inhaled.
ATE CLP (dust,mist) 4,028 mg/l/4h
Styrene (100-42-5)LD50 oral > 5000 mg/kgLD50 dermal > 5000 mg/kgethanediol, ethylene glycol (107-21-1)LD50 oral rat 7712 mg/kgLD50 dermal > 3500 mg/kg mouseLC50 inhalation rat (mg/l) > 2,5 mg/l
Skin corrosion/irritation : Causes skin irritation.Serious eye damage/irritation : Causes serious eye irritation.Respiratory or skin sensitisation : Not classifiedGerm cell mutagenicity : Not classifiedCarcinogenicity : Not classified
Reproductive toxicity : Suspected of damaging fertility or the unborn child.Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure)
: Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
SECTION 12: Ecological information12.1. ToxicityEcology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Styrene (100-42-5)LC50 fish 1 4,02 mg/lEC50 Daphnia 1 4,7 mg/lethanediol, ethylene glycol (107-21-1)LC50 fish 1 72860 mg/lEC50 Daphnia 1 > 100 mg/lNOEC chronic fish 15380 mg/l
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
ethanediol, ethylene glycol (107-21-1)NOEC chronic crustacea 8590 mg/l (95-71-6)LC50 fish 1 0,09 mg/l (Pimephales promelas; 96h)
12.2. Persistence and degradability
ethanediol, ethylene glycol (107-21-1)Biodegradation 90 - 100 %
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12.3. Bioaccumulative potentialNo additional information available
12.4. Mobility in soilNo additional information available
12.5. Results of PBT and vPvB assessmentNo additional information available
12.6. Other adverse effectsNo additional information available
SECTION 13: Disposal considerations13.1. Waste treatment methodsWaste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.Additional information : Flammable vapours may accumulate in the container.
SECTION 14: Transport informationIn accordance with ADR / RID / IMDG / IATA / ADN
ADR IMDG IATA14.1. UN number1866 1866 186614.2. UN proper shipping nameRESIN SOLUTION RESIN SOLUTION Resin solutionTransport document descriptionUN 1866 RESIN SOLUTION, 3, III, (D/E)
UN 1866 RESIN SOLUTION, 3, III
14.3. Transport hazard class(es)3 3 3
14.4. Packing groupIII III III14.5. Environmental hazardsDangerous for the environment : No
Dangerous for the environment : NoMarine pollutant : No
Dangerous for the environment : No
No supplementary information available
14.6. Special precautions for user- Overland transportSpecial provisions (ADR) : 640ETransport category (ADR) : 3Hazard identification number (Kemler No.) : 30Orange plates :
Tunnel restriction code (ADR) : D/EEAC code : •3YE
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
- Transport by seaEmS-No. (Fire)EmS-No. (Spillage)Stowage category (IMDG)Properties and observations (IMDG)
- Air transportPCA packing instructions (IATA)CAO packing instructions (IATA)ERG code (IATA)
: F-E: S-E: A: Miscibility with water depends upon the composition.
: 355: 366: 3L
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SECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no substances with Annex XVII restrictionsContains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulationsNo additional information available
15.2. Chemical safety assessmentNo chemical safety assessment has been carried out
SECTION 16: Other information
Full text of R-, H- and EUH-statements:Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2Asp. Tox. 1 Aspiration hazard, Category 1Eye Irrit. 2 Serious eye damage/eye irritation, Category 2Flam. Liq. 2 Flammable liquids, Category 2Flam. Liq. 3 Flammable liquids, Category 3Repr. 2 Reproductive toxicity, Category 2Repr. 2 Reproductive toxicity, Category 2Skin Irrit. 2 Skin corrosion/irritation, Category 2STOT RE 1 Specific target organ toxicity — Repeated exposure, Category 1STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritationH225 Highly flammable liquid and vapourH226 Flammable liquid and vapourH302 Harmful if swallowedH304 May be fatal if swallowed and enters airwaysH312 Harmful in contact with skinH315 Causes skin irritationH319 Causes serious eye irritationH332 Harmful if inhaledH335 May cause respiratory irritationH361 Suspected of damaging fertility or the unborn childH361d Suspected of damaging the unborn childH372 Causes damage to organs through prolonged or repeated exposureH373 May cause damage to organs through prolonged or repeated exposureH400 Very toxic to aquatic life
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable
Data sources
Other information
: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
: Information in this safety data sheet is based on actual knowledge in our possession and our experience. This does not in any way excuse the user from knowing and applying all the regulations governing his activity. It is the sole responsibility of the user to take all precautions required in handling the product. It is the user's responsibility to take the mentioned precautionary measures and to ensure that this information is complete and sufficient for the use of this product.
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H411 Toxic to aquatic life with long lasting effectsR10 FlammableR11 Highly flammableR20 Harmful by inhalationR20/21 Harmful by inhalation and in contact with skinR22 Harmful if swallowedR36/37/38 Irritating to eyes, respiratory system and skinR36/38 Irritating to eyes and skinR37 Irritating to respiratory systemR38 Irritating to skinR48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalationR50 Very toxic to aquatic organismsR51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environmentR63 Possible risk of harm to the unborn childR65 Harmful: may cause lung damage if swallowedR66 Repeated exposure may cause skin dryness or crackingR67 Vapours may cause drowsiness and dizzinessF Highly flammableN Dangerous for the environmentXi IrritantXn Harmful
SDS EU (REACH Annex II)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
Date of issue: 19/06/2015 Revision date: 19/06/2015 Version: 1.0
19/06/2015 EN (English) 1/8
SECTION 1: Identification of the substance/mixture and of the company/undertaking1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified usesUse of the substance/mixture : Resin
1.2.2. Uses advised againstNo additional information available
1.3. Details of the supplier of the safety data sheet
1.4. Emergency telephone numberEmergency number : ORFILA - 0033 1 45 42 59 59
SECTION 2: Hazards identification2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture: SDS < 2015 : Show CLP information onlyFlam. Liq. 3 H226 Acute Tox. 4 (Inhalation:dust,mist) H332 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Repr. 2 H361 STOT RE 1 H372
Full text of H-statements: see section 16
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Hazard pictograms (CLP) :
GHS02 GHS07 GHS08
Signal word (CLP) : DangerHazardous ingredients : StyreneHazard statements (CLP) : H226 - Flammable liquid and vapour
H315 - Causes skin irritationH319 - Causes serious eye irritationH332 - Harmful if inhaledH361 - Suspected of damaging fertility or the unborn childH372 - Causes damage to organs through prolonged or repeated exposure
Precautionary statements (CLP) : P280 - Wear protective gloves, protective clothing, eye protectionP241 - Use explosion-proof electrical equipmentP271 - Use only outdoors or in a well-ventilated areaP370+P378 - In case of fire: Use Water fog, foam, extinguishing powder, carbon dioxide (CO2) for extinctionP264 - Wash hands thoroughly after handlingP210 - Keep away from heat, hot surfaces, sparks, open flames. - No smoking
EUH-statements : EUH208 - Contains CAS 136-52-7. May produce an allergic reaction
Uni-Mould Coupling CoatSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
: Mixture: Uni-Mould Coupling Coat : Resin
Product formProduct name
Type of product
Easy Composites LtdUnit 39, Park Hall Business Village, Stoke on Trent,Staffordshire, ST3 5XA. United Kingdom.T +44 (0) 1782 454499 (08:00 - 17:30hrs, Mon-Fri) - F +44 (0)1782 [email protected] - www.easycomposites.co.uk
19/06/2015 EN (English) 2/8
2.3. Other hazardsAdverse physicochemical, human health and environmental effects
: Flammable liquid and vapour. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.
SECTION 3: Composition/information on ingredients3.1. SubstanceNot applicable
3.2. Mixture
Name Product identifier % Classification according to Directive 67/548/EEC
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Styrene (CAS No) 100-42-5(EC no) 202-851-5(EC index no) 601-026-00-0(REACH-no) 01-2119457861-32
40 - 50 Repr.Cat.3; R63Xn; R20Xn; R48/20Xi; R36/38R10
Flam. Liq. 3, H226Repr. 2, H361dAcute Tox. 4 (Inhalation), H332STOT RE 1, H372Skin Irrit. 2, H315Eye Irrit. 2, H319
(CAS No) 64742-82-1(EC no) 265-185-4(EC index no) 649-330-00-2
< 1 R10N; R51/53Xn; R65R66R67
Flam. Liq. 3, H226STOT SE 3, H336Asp. Tox. 1, H304Aquatic Chronic 2, H411
Cobalt bis(2-ethylhexanoate) (CAS No) 136-52-7(EC no) 205-250-6(REACH-no) 01-2119524678-29
< 1 Repr.Cat.3; R62R43N; R50/53
Eye Irrit. 2, H319Skin Sens. 1, H317Repr. 2, H361fAquatic Acute 1, H400Aquatic Chronic 1, H410
(CAS No) 64742-95-6(EC no) 265-199-0(EC index no) 649-356-00-4(REACH-no) 01-2119455851-35
< 1 Xn; R65N; R51/53R10R67R66Xi; R37
Flam. Liq. 3, H226STOT SE 3, H335Asp. Tox. 1, H304Aquatic Chronic 2, H411
ethanediol, ethylene glycolsubstance with a Community workplace exposure limit
(CAS No) 107-21-1(EC no) 203-473-3(EC index no) 603-027-00-1(REACH-no) 01-2119472426-35
< 1 Xn; R22 Acute Tox. 4 (Oral), H302
Specific concentration limits:Name Product identifier Specific concentration limits:
DSD/DPDSpecific concentration limits: CLP
Styrene (CAS No) 100-42-5(EC no) 202-851-5(EC index no) 601-026-00-0(REACH-no) 01-2119457861-32
(C >= 12,5) Xn;R20(C >= 12,5) Xi;R36/38
Full text of R- and H-statements: see section 16
SECTION 4: First aid measures4.1. Description of first aid measuresFirst-aid measures general : IF exposed or concerned: Get medical advice/attention. Call a poison center or a doctor if you
feel unwell.First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison center or a
doctor if you feel unwell.First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. If skin
irritation occurs: Get medical advice/attention.First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayedSymptoms/injuries after skin contact : Irritation.Symptoms/injuries after eye contact : Eye irritation.
4.3. Indication of any immediate medical attention and special treatment neededTreat symptomatically.
Uni-Mould Coupling CoatSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
19/06/2015 EN (English) 3/8
SECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.
5.2. Special hazards arising from the substance or mixtureFire hazard : Flammable liquid and vapour.Hazardous decomposition products in case of fire
: Toxic fumes may be released.
5.3. Advice for firefightersProtection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing. Use water spray or fog for cooling exposed containers. Prevent entry to sewers and public waters.
SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnelEmergency procedures : Ventilate spillage area. No open flames, no sparks, and no smoking. Avoid contact with skin
and eyes. Do not breathe vapours. fume.
6.1.2. For emergency respondersProtective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautionsAvoid release to the environment.
6.3. Methods and material for containment and cleaning upMethods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public
waters.Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sectionsFor further information refer to section 13.
SECTION 7: Handling and storage7.1. Precautions for safe handlingPrecautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapours may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe fume. Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes.
Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilitiesTechnical measures : Ground/bond container and receiving equipment.Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed.
7.3. Specific end use(s)No additional information available
SECTION 8: Exposure controls/personal protection8.1. Control parameters
Styrene (100-42-5)United Kingdom WEL STEL (mg/m³) 1080 mg/m³United Kingdom WEL STEL (ppm) 250 ppmethanediol, ethylene glycol (107-21-1)EU IOELV TWA (mg/m³) 246 mg/m³EU IOELV TWA (ppm) 50 ppmEU IOELV STEL (mg/m³) 492 mg/m³EU IOELV STEL (ppm) 100 ppm
8.2. Exposure controls
Appropriate engineering controls : Ensure good ventilation of the work station.
Uni-Mould Coupling CoatSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
19/06/2015 EN (English) 4/8
Hand protection : Protective gloves
Eye protection : Safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask
Environmental exposure controls : Avoid release to the environment.
SECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesPhysical state : LiquidColour : orange.Odour : characteristic.Odour threshold : No data availablepH : No data availableRelative evaporation rate (butylacetate=1) : No data availableMelting point : Not applicableFreezing point : No data availableBoiling point : No data availableFlash point : No data availableAuto-ignition temperature : No data availableDecomposition temperature : No data availableFlammability (solid, gas) : Not applicableVapour pressure : No data availableRelative vapour density at 20 °C : No data availableRelative density : 1,08 - 1,1Solubility : No data availableLog Pow : No data availableViscosity, kinematic : No data availableViscosity, dynamic : No data availableExplosive properties : No data availableOxidising properties : No data availableExplosive limits : No data available
9.2. Other informationNo additional information available
SECTION 10: Stability and reactivity10.1. ReactivityFlammable liquid and vapour.
10.2. Chemical stabilityStable under normal conditions.
10.3. Possibility of hazardous reactionsNo dangerous reactions known under normal conditions of use.
10.4. Conditions to avoidAvoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.
10.5. Incompatible materialsNo additional information available
10.6. Hazardous decomposition productsUnder normal conditions of storage and use, hazardous decomposition products should not be produced.
Uni-Mould Coupling CoatSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
19/06/2015 EN (English) 5/8
SECTION 11: Toxicological information11.1. Information on toxicological effectsAcute toxicity : Inhalation:dust,mist: Harmful if inhaled.
ATE CLP (dust,mist) 3,471 mg/l/4h
Styrene (100-42-5)LD50 oral > 5000 mg/kgLD50 dermal > 5000 mg/kgethanediol, ethylene glycol (107-21-1)LD50 oral rat 7712 mg/kgLD50 dermal > 3500 mg/kg mouseLC50 inhalation rat (mg/l) > 2,5 mg/l
Skin corrosion/irritation : Causes skin irritation.Serious eye damage/irritation : Causes serious eye irritation.Respiratory or skin sensitisation : Not classifiedGerm cell mutagenicity : Not classifiedCarcinogenicity : Not classifiedReproductive toxicity : Suspected of damaging fertility or the unborn child.Specific target organ toxicity (single exposure) : Not classifiedSpecific target organ toxicity (repeated exposure)
: Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
SECTION 12: Ecological information12.1. ToxicityEcology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Styrene (100-42-5)LC50 fish 1 4,02 mg/lEC50 Daphnia 1 4,7 mg/lethanediol, ethylene glycol (107-21-1)LC50 fish 1 72860 mg/lEC50 Daphnia 1 > 100 mg/lNOEC chronic fish 15380 mg/lNOEC chronic crustacea 8590 mg/l
12.2. Persistence and degradability
ethanediol, ethylene glycol (107-21-1)Biodegradation 90 - 100 %
12.3. Bioaccumulative potentialNo additional information available
12.4. Mobility in soilNo additional information available
12.5. Results of PBT and vPvB assessmentNo additional information available
12.6. Other adverse effectsNo additional information available
SECTION 13: Disposal considerations13.1. Waste treatment methodsWaste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.Additional information : Flammable vapours may accumulate in the container.
SECTION 14: Transport informationIn accordance with ADR / RID / IMDG / IATA / ADN
Uni-Mould Coupling CoatSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
19/06/2015 EN (English) 6/8
ADR IMDG IATA14.1. UN number1866 1866 186614.2. UN proper shipping nameRESIN SOLUTION RESIN SOLUTION Resin solutionTransport document descriptionUN 1866 RESIN SOLUTION, 3, III, (D/E)
UN 1866 RESIN SOLUTION, 3, III
14.3. Transport hazard class(es)3 3 3
14.4. Packing groupIII III III14.5. Environmental hazardsDangerous for the environment : No
Dangerous for the environment : NoMarine pollutant : No
Dangerous for the environment : No
No supplementary information available
14.6. Special precautions for user
- Overland transportSpecial provisions (ADR) : 640ETransport category (ADR) : 3Hazard identification number (Kemler No.) : 30Orange plates :
Tunnel restriction code (ADR) : D/EEAC code : •3YE
- Transport by seaEmS-No. (Fire) : F-EEmS-No. (Spillage) : S-EStowage category (IMDG) : AProperties and observations (IMDG) : Miscibility with water depends upon the composition.
- Air transportPCA packing instructions (IATA) : 355CAO packing instructions (IATA) : 366ERG code (IATA) : 3L
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable
SECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no substances with Annex XVII restrictionsContains no substance on the REACH candidate listContains no REACH Annex XIV substances
15.1.2. National regulationsNo additional information available
15.2. Chemical safety assessmentNo chemical safety assessment has been carried out
Uni-Mould Coupling CoatSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
19/06/2015 EN (English) 7/8
SECTION 16: Other information
Full text of R-, H- and EUH-statements:
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2Asp. Tox. 1 Aspiration hazard, Category 1Eye Irrit. 2 Serious eye damage/eye irritation, Category 2Flam. Liq. 3 Flammable liquids, Category 3Repr. 2 Reproductive toxicity, Category 2Repr. 2 Reproductive toxicity, Category 2Repr. 2 Reproductive toxicity, Category 2Skin Irrit. 2 Skin corrosion/irritation, Category 2Skin Sens. 1 Sensitisation — Skin, category 1STOT RE 1 Specific target organ toxicity — Repeated exposure, Category 1STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritationSTOT SE 3 Specific target organ toxicity — Single exposure, Category 3, NarcosisH226 Flammable liquid and vapourH302 Harmful if swallowedH304 May be fatal if swallowed and enters airwaysH315 Causes skin irritationH317 May cause an allergic skin reactionH319 Causes serious eye irritation
Uni-Mould Coupling CoatSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
Data sources
Other information
: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
: Information in this safety data sheet is based on actual knowledge in our possession and our experience. This does not in any way excuse the user from knowing and applying all the regulations governing his activity. It is the sole responsibility of the user to take all precautions required in handling the product. It is the user's responsibility to take the mentioned precautionary measures and to ensure that this information is complete and sufficient for the use of this product.
H332 Harmful if inhaledH335 May cause respiratory irritationH336 May cause drowsiness or dizzinessH361 Suspected of damaging fertility or the unborn childH361d Suspected of damaging the unborn childH361f Suspected of damaging fertilityH372 Causes damage to organs through prolonged or repeated exposureH400 Very toxic to aquatic lifeH410 Very toxic to aquatic life with long lasting effectsH411 Toxic to aquatic life with long lasting effectsEUH208 Contains . May produce an allergic reactionR10 FlammableR20 Harmful by inhalationR22 Harmful if swallowedR36/38 Irritating to eyes and skinR37 Irritating to respiratory systemR43 May cause sensitisation by skin contactR48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalationR50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
19/06/2015 EN (English) 8/8
Uni-Mould Coupling CoatSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
SDS EU (REACH Annex II)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 Possible risk of impaired fertilityR63 Possible risk of harm to the unborn childR65 Harmful: may cause lung damage if swallowedR66 Repeated exposure may cause skin dryness or crackingR67 Vapours may cause drowsiness and dizzinessN Dangerous for the environmentXi IrritantXn Harmful
Date of issue: 22/05/2015 Revision date: 22/05/2015 Supersedes: 06/05/2015 Version: 2.1
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SECTION 1: Identification of the substance/mixture and of the company/undertaking1.1. Product identifierProduct formProduct name
: Mixture: Uni-Mould Tooling Resin : Resin
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
1.2.2. Uses advised againstNo additional information available
1.3. Details of the supplier of the safety data sheet
1.4. Emergency telephone numberEmergency number
SECTION 2: Hazards identification2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture: SDS < 2015 : Show CLP information onlyFlam. Liq. 3 H226 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Skin Sens. 1 H317 Repr. 2 H361 STOT RE 1 H372
Full text of H-phrases: see section 16
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Hazard pictograms (CLP) :
GHS02 GHS07 GHS08
Signal word (CLP) : DangerHazardous ingredients : Styrene, Cobalt bis(2-ethylhexanoate), methyl methacrylate, methyl 2-methylprop-2-enoate,
methyl 2-methylpropenoateHazard statements (CLP) : H226 - Flammable liquid and vapour
H315 - Causes skin irritationH317 - May cause an allergic skin reactionH319 - Causes serious eye irritationH361 - Suspected of damaging fertility or the unborn childH372 - Causes damage to organs through prolonged or repeated exposure
Precautionary statements (CLP) : P280 - Wear protective gloves, protective clothing, eye protectionP241 - Use explosion-proof electrical equipmentP271 - Use only outdoors or in a well-ventilated areaP370+P378 - In case of fire: Use Water fog, foam, extinguishing powder, carbon dioxide (CO2) for extinctionP264 - Wash hands thoroughly after handlingP210 - Keep away from heat, hot surfaces, sparks, open flames. - No smoking
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
Type of product
Main use categoryIndustrial/Professional use spec
Use of the substance/mixture
: Industrial use: Intended for general public
Industrial: Industrial laminating resin, casting, injection, winding, infusion, gluing, foaming, coatings and
sealants.
Easy Composites LtdUnit 39, Park Hall Business Village, Stoke on Trent,Staffordshire, ST3 5XA. United Kingdom.T +44 (0) 1782 454499 (08:00 - 17:30hrs, Mon-Fri) - F +44 (0)1782 [email protected] - www.easycomposites.co.uk
: ORFILA (FRANCE) : +33 (0)1 45 42 59 59 (24h/24, 7j/7)
27/05/2015 EN (English) 2/7
2.3. Other hazardsAdverse physicochemical, human health and environmental effects
: Flammable liquid and vapour. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.
SECTION 3: Composition/information on ingredients3.1. SubstanceNot applicable
3.2. Mixture
Name Product identifier % Classification according to Directive 67/548/EEC
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Styrene (CAS No) 100-42-5(EC no) 202-851-5(EC index no) 601-026-00-0(REACH-no) 01-2119457861-32
20 - 30 Repr.Cat.3; R63Xn; R20Xn; R48/20Xi; R36/38R10
Flam. Liq. 3, H226Repr. 2, H361dAcute Tox. 4 (Inhalation), H332STOT RE 1, H372Skin Irrit. 2, H315Eye Irrit. 2, H319
methyl methacrylate, methyl 2-methylprop-2-enoate, methyl 2-methylpropenoate
(CAS No) 80-62-6(EC no) 201-297-1(EC index no) 607-035-00-6(REACH-no) 01-2119452498-28
1 - 5 F; R11Xi; R37/38R43
Flam. Liq. 2, H225Skin Irrit. 2, H315Skin Sens. 1, H317STOT SE 3, H335
ethanediol, ethylene glycolsubstance with a Community workplace exposure limit
(CAS No) 107-21-1(EC no) 203-473-3(EC index no) 603-027-00-1(REACH-no) 01-2119472426-35
< 1 Xn; R22 Acute Tox. 4 (Oral), H302
Cobalt bis(2-ethylhexanoate) (CAS No) 136-52-7(EC no) 205-250-6(REACH-no) 01-2119524678-29
< 1 Repr.Cat.3; R62R43N; R50/53
Eye Irrit. 2, H319Skin Sens. 1, H317Repr. 2, H361fAquatic Acute 1, H400Aquatic Chronic 1, H410
(CAS No) 95-71-6(EC no) 202-443-7
< 1 Xn; R22Xi; R36/38N; R50
Acute Tox. 4 (Oral), H302Skin Irrit. 2, H315Eye Irrit. 2, H319Aquatic Acute 1, H400 (M=10)
Specific concentration limits:Name Product identifier Specific concentration limits:
DSD/DPDSpecific concentration limits: CLP
Styrene (CAS No) 100-42-5(EC no) 202-851-5(EC index no) 601-026-00-0(REACH-no) 01-2119457861-32
(C >= 12,5) Xn;R20(C >= 12,5) Xi;R36/38
Full text of R- and H-phrases: see section 16
SECTION 4: First aid measures4.1. Description of first aid measuresFirst-aid measures general : IF exposed or concerned: Get medical advice/attention. Call a poison center or a doctor if you
feel unwell.First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison center or a
doctor if you feel unwell.First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. If skin
irritation occurs: Get medical advice/attention.First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayedSymptoms/injuries after skin contact : Irritation.Symptoms/injuries after eye contact : Eye irritation.
4.3. Indication of any immediate medical attention and special treatment neededTreat symptomatically.
SECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
27/05/2015 EN (English) 3/7
5.2. Special hazards arising from the substance or mixtureFire hazard : Flammable liquid and vapour.Hazardous decomposition products in case of fire
: Toxic fumes may be released.
5.3. Advice for firefightersProtection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing. Use water spray or fog for cooling exposed containers. Prevent entry to sewers and public waters.
SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnelEmergency procedures : Ventilate spillage area. No open flames, no sparks, and no smoking. Avoid contact with skin
and eyes. Do not breathe vapours. fume.
6.1.2. For emergency respondersProtective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautionsAvoid release to the environment.
6.3. Methods and material for containment and cleaning upMethods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public
waters.Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sectionsFor further information refer to section 13.
SECTION 7: Handling and storage7.1. Precautions for safe handlingPrecautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapours may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe fume. Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes.
Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilitiesTechnical measures : Ground/bond container and receiving equipment.Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed.
7.3. Specific end use(s)No additional information available
SECTION 8: Exposure controls/personal protection8.1. Control parameters
Styrene (100-42-5)United Kingdom WEL STEL (mg/m³) 1080 mg/m³United Kingdom WEL STEL (ppm) 250 ppm
methyl methacrylate, methyl 2-methylprop-2-enoate, methyl 2-methylpropenoate (80-62-6)EU Local name Methyl methacrylateEU IOELV TWA (ppm) 50 ppmEU IOELV STEL (ppm) 100 ppm
ethanediol, ethylene glycol (107-21-1)EU IOELV TWA (mg/m³) 246 mg/m³EU IOELV TWA (ppm) 50 ppmEU IOELV STEL (mg/m³) 492 mg/m³EU IOELV STEL (ppm) 100 ppm
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
27/05/2015 EN (English) 4/7
8.2. Exposure controls
Appropriate engineering controls : Ensure good ventilation of the work station.
Hand protection : Protective gloves
Eye protection : Safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask
Environmental exposure controls : Avoid release to the environment.
SECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesPhysical state : LiquidColour : No data availableOdour : characteristic.Odour threshold : No data availablepH : No data availableRelative evaporation rate (butylacetate=1) : No data availableMelting point : Not applicableFreezing point : No data availableBoiling point : No data availableFlash point : No data availableAuto-ignition temperature : No data availableDecomposition temperature : No data availableFlammability (solid, gas) : Not applicableVapour pressure : No data availableRelative vapour density at 20 °C : No data availableRelative density : 1,41 - 1,45Solubility : No data availableLog Pow : No data availableViscosity, kinematic : No data availableViscosity, dynamic : No data availableExplosive properties : No data availableOxidising properties : No data availableExplosive limits : No data available
9.2. Other informationNo additional information available
SECTION 10: Stability and reactivity10.1. ReactivityFlammable liquid and vapour.
10.2. Chemical stabilityStable under normal conditions.
10.3. Possibility of hazardous reactionsNo dangerous reactions known under normal conditions of use.
10.4. Conditions to avoidAvoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.
10.5. Incompatible materialsNo additional information available
10.6. Hazardous decomposition productsUnder normal conditions of storage and use, hazardous decomposition products should not be produced.
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
27/05/2015 EN (English) 5/7
SECTION 11: Toxicological information11.1. Information on toxicological effectsAcute toxicity : Not classified
Styrene (100-42-5)LD50 oral > 5000 mg/kgLD50 dermal > 5000 mg/kg
methyl methacrylate, methyl 2-methylprop-2-enoate, methyl 2-methylpropenoate (80-62-6)LD50 oral rat 7872 mg/kgLD50 dermal rabbit > 5000 mg/kgLC50 inhalation rat (mg/l) 29,8 mg/l/4h
ethanediol, ethylene glycol (107-21-1)LD50 oral rat 7712 mg/kgLD50 dermal > 3500 mg/kg mouseLC50 inhalation rat (mg/l) > 2,5 mg/l
Skin corrosion/irritation : Causes skin irritation.Serious eye damage/irritation : Causes serious eye irritation.Respiratory or skin sensitisation : May cause an allergic skin reaction.Germ cell mutagenicity : Not classifiedCarcinogenicity : Not classified
Reproductive toxicity : Suspected of damaging fertility or the unborn child.Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure)
: Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
SECTION 12: Ecological information12.1. ToxicityEcology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Styrene (100-42-5)LC50 fish 1 4,02 mg/lEC50 Daphnia 1 4,7 mg/l
methyl methacrylate, methyl 2-methylprop-2-enoate, methyl 2-methylpropenoate (80-62-6)LC50 fish 1 130 mg/l (Pimephales promelas)EC50 Daphnia 1 69 mg/l (daphnia magna; 48h)
ethanediol, ethylene glycol (107-21-1)LC50 fish 1 72860 mg/lEC50 Daphnia 1 > 100 mg/lNOEC chronic fish 15380 mg/lNOEC chronic crustacea 8590 mg/l
(95-71-6)LC50 fish 1 0,09 mg/l (Pimephales promelas; 96h)
12.2. Persistence and degradability
ethanediol, ethylene glycol (107-21-1)Biodegradation 90 - 100 %
12.3. Bioaccumulative potentialNo additional information available
12.4. Mobility in soilNo additional information available
12.5. Results of PBT and vPvB assessmentNo additional information available
12.6. Other adverse effectsNo additional information available
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
27/05/2015 EN (English) 6/7
SECTION 13: Disposal considerations13.1. Waste treatment methodsWaste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.Additional information : Flammable vapours may accumulate in the container.
SECTION 14: Transport informationIn accordance with ADR / RID / IMDG / IATA / ADN
ADR IMDG IATA14.1. UN number1866 1866 186614.2. UN proper shipping nameRESIN SOLUTION RESIN SOLUTION Resin solutionTransport document descriptionUN 1866 RESIN SOLUTION, 3, III, (D/E)
UN 1866 RESIN SOLUTION, 3, III
14.3. Transport hazard class(es)3 3 3
14.4. Packing groupIII III III14.5. Environmental hazardsDangerous for the environment : No
Dangerous for the environment : NoMarine pollutant : No
Dangerous for the environment : No
No supplementary information available
14.6. Special precautions for user
: 640E: 3: 30:
- Overland transportSpecial provisions (ADR)Transport category (ADR)Hazard identification number (Kemler No.) Orange plates
Tunnel restriction code (ADR)EAC code- Transport by seaEmS-No. (Fire)EmS-No. (Spillage)Stowage category (IMDG) Properties and observations (IMDG)
- Air transportPCA packing instructions (IATA) CAO packing instructions (IATA) ERG code (IATA)
: D/E: •3YE
: F-E: S-E: A: Miscibility with water depends upon the composition.
:355:366: 3L
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable
SECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no substances with Annex XVII restrictionsContains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
15.1.2. National regulationsNo additional information available
15.2. Chemical safety assessmentNo chemical safety assessment has been carried out
27/05/2015 EN (English) 7/7
SECTION 16: Other information
Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1Eye Irrit. 2 Serious eye damage/eye irritation, Category 2Flam. Liq. 2 Flammable liquids, Category 2Flam. Liq. 3 Flammable liquids, Category 3Repr. 2 Reproductive toxicity, Category 2Repr. 2 Reproductive toxicity, Category 2Repr. 2 Reproductive toxicity, Category 2Skin Irrit. 2 Skin corrosion/irritation, Category 2Skin Sens. 1 Sensitisation — Skin, category 1STOT RE 1 Specific target organ toxicity — Repeated exposure, Category 1STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritationH225 Highly flammable liquid and vapourH226 Flammable liquid and vapourH302 Harmful if swallowedH315 Causes skin irritationH317 May cause an allergic skin reactionH319 Causes serious eye irritationH332 Harmful if inhaledH335 May cause respiratory irritationH361 Suspected of damaging fertility or the unborn childH361d Suspected of damaging the unborn childH361f Suspected of damaging fertilityH372 Causes damage to organs through prolonged or repeated exposureH400 Very toxic to aquatic lifeH410 Very toxic to aquatic life with long lasting effectsR10 FlammableR11 Highly flammableR20 Harmful by inhalationR22 Harmful if swallowedR36/38 Irritating to eyes and skinR37/38 Irritating to respiratory system and skinR43 May cause sensitisation by skin contactR48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalationR50 Very toxic to aquatic organismsR50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R62 Possible risk of impaired fertilityR63 Possible risk of harm to the unborn childF Highly flammableN Dangerous for the environmentXi IrritantXn Harmful
SDS EU (REACH Annex II)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product
Uni-Mould Tooling ResinSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
Data sources
Other information
: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
: Information in this safety data sheet is based on actual knowledge in our possession and our experience. This does not in any way excuse the user from knowing and applying all the regulations governing his activity. It is the sole responsibility of the user to take all precautions required in handling the product. It is the user's responsibility to take the mentioned precautionary measures and to ensure that this information is complete and sufficient for the use of this product.
Revision date: 11/09/2014 Supersedes date: 25/07/2014Revision: 3
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
MEKPProduct name
MEKPProduct number
1.2. Relevant identified uses of the substance or mixture and uses advised against
Activator.Identified uses
No specific uses advised against are identified.Uses advised against
1.3. Details of the supplier of the safety data sheet
Easy Composites Ltd Unit 39, Park Hall Business Village Longton, Stoke‐on‐Trent ST3 5XA United Kingdom [email protected]
Supplier
1.4. Emergency telephone number
+44 (0)1782 454499Emergency telephone
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification
Physical hazards
Org. Perox. D - H242
Health hazards
Acute Tox. 4 - H302 Skin Corr. 1B - H314 Eye Dam. 1 - H318
Environmental hazards
Not Classified
Classification (67/548/EEC or 1999/45/EC)
O; R7. Xn; R22. C; R34
2.2. Label elements
Pictogram
DangerSignal word
Hazard statements
1/14
SAFETY DATA SHEET MEKP
Supersedes date: 25/07/2014Revision date: 11/09/2014 Revision: 3
Precautionary statements
H242 Heating may cause a fire.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P220 Keep away from acids, alkalis, heavy metal compounds, oxidising material, combustible materials.
P234 Keep only in original container.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P411+235 Store at temperatures not exceeding 30°C. Keep cool.
P501 Dispose of contents/container in accordance with national regulations.
methyl ethyl ketone peroxideContains
Supplementary precautionary statements
P260 Do not breathe vapour/spray.
P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P321 Specific treatment (see medical advice on this label).
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P410 Protect from sunlight.
P420 Store away from other materials.
2.3. Other hazards
This product does not contain any substances classified as PBT or vPvB.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
dimethyl phthalate 50 - 100%
CAS number: 131-11-3 EC number: 205-011-6
Classification Classification (67/548/EEC or 1999/45/EC)
Not Classified
methyl ethyl ketone peroxide 25 - <50%
CAS number: 1338-23-4 EC number: 215-661-2
Classification Classification (67/548/EEC or 1999/45/EC)
O; R7. Xn; R22. C; R34Org. Perox. D - H242
Acute Tox. 4 - H302
Skin Corr. 1B - H314
Eye Dam. 1 - H318
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butanone 2.5 - <5%
CAS number: 78-93-3 EC number: 201-159-0
Classification Classification (67/548/EEC or 1999/45/EC)
F; R11. Xi; R36. R67Flam. Liq. 2 - H225
Eye Irrit. 2 - H319
STOT SE 3 - H336
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
General information
Remove affected person from source of contamination. Promptly remove any clothing that becomes contaminated.
Inhalation
Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Get medical attention if
symptoms are severe or persist.
Ingestion
Do not induce vomiting. Get medical attention.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention. Wash contaminated
clothing before reuse.
Eye contact
Remove any contact lenses and open eyelids wide apart. Rinse immediately with plenty of water. Continue to rinse for at least
15 minutes and get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependent on the concentration and the length of exposure.
Inhalation
Vapours may cause drowsiness and dizziness. May cause respiratory system irritation.
Ingestion
Harmful if swallowed. May cause chemical burns in mouth, oesophagus and stomach.
Skin contact
Severe skin irritation. Blistering may occur.
Eye contact
May cause blurred vision and serious eye damage. Symptoms following overexposure may include the following: Blindness.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Water spray, fog or mist. Carbon dioxide (CO2).
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire. Dry chemical fire extinguishing agent may catalyse the
decomposition.
5.2. Special hazards arising from the substance or mixture
Specific hazards
The heat of decomposition of the peroxides adds to the heat of the fire. Dry chemical fire extinguishing agent may catalyse the
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The heat of decomposition of the peroxides adds to the Dry chemical fire extinguishing agent may catalyse the
decomposition.
Hazardous combustion products
Acetic acid. Carbon dioxide (CO2). Carbon monoxide (CO). Formic acid Propanoic acid.
5.3. Advice for firefighters
Protective actions during firefighting
Avoid breathing fire gases or vapours. Cool containers exposed to heat with water spray and remove them from the fire area if
it can be done without risk. Control run-off water by containing and keeping it out of sewers and watercourses. If dry chemical is
used to extinguish a methyl ethyl ketone peroxide fire, the extinguished area must be thoroughly wetted down with water to
prevent re-ignition.
Special protective equipment for firefighters
Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions
Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of vapours and contact with skin
and eyes.
6.2. Environmental precautions
Environmental precautions
Do not discharge into drains or watercourses or onto the ground.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up
Wear protective clothing as described in Section 8 of this safety data sheet. Eliminate all sources of ignition. Do not touch or
walk into spilled material. Absorb in vermiculite, dry sand or earth and place into containers. Containers with collected spillage
must be properly labelled with correct contents and hazard symbol. Dispose of contents/container in accordance with national
regulations.
6.4. Reference to other sections
Reference to other sections
For personal protection, see Section 8. See Section 11 for additional information on health hazards. See Section 12 for
additional information on ecological hazards. For waste disposal, see Section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Usage precautions
Read and follow manufacturer's recommendations. Avoid inhalation of vapours and contact with skin and eyes. Do not handle
broken packages without protective equipment.
Advice on general occupational hygiene
Do not smoke in work area. Eye wash facilities and emergency shower must be available when handling this product. Wash
hands thoroughly after handling. Do not eat, drink or smoke when using this product.
7.2. Conditions for safe storage, including any incompatibilities
Storage precautions
Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep away from food, drink and animal feeding
stuffs. Keep at temperature not exceeding 25°C. Keep away from oxidising materials, heat and flames.
7.3. Specific end use(s)
Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure Controls/personal protection
8.1. Control parameters
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Occupational exposure limits
dimethyl phthalate
Long-term exposure limit (8-hour TWA): WEL 5 mg/m3
Short-term exposure limit (15-minute): WEL 10 mg/m3
methyl ethyl ketone peroxide
Short-term exposure limit (15-minute): WEL 0.2 ppm 1.5 mg/m3
butanone
Long-term exposure limit (8-hour TWA): WEL 200 ppm 600 mg/m3
Short-term exposure limit (15-minute): WEL 300 ppm 899 mg/m3
Sk
WEL = Workplace Exposure Limit
Sk = Can be absorbed through the skin.
dimethyl phthalate (CAS: 131-11-3)
Workers - Dermal; Long term systemic effects: 100 mg/kg/day
Workers - Inhalation; Long term systemic effects: 293.86 mg/m³
Consumer - Dermal; Long term systemic effects: 60 mg/kg/day
Consumer - Inhalation; Long term systemic effects: 86.96 mg/m³
Consumer - Oral; Long term systemic effects: 25 mg/kg/day
DNEL
- Fresh water; 0.192 mg/l
- Marine water; 0.0192 mg/l
- Intermittent release; 0.39 mg/l
- STP; 4 mg/l
- Sediment (Freshwater); 1.403 mg/kg
- Soil; 3.16 mg/kg
PNEC
methyl ethyl ketone peroxide (CAS: 1338-23-4)
Workers - Dermal; Long term systemic effects: 1.08 mg/kg/day
Workers - Inhalation; Long term systemic effects: 1.9 mg/m³
Consumer - Dermal; Long term systemic effects: 0.54 mg/kg/day
Consumer - Inhalation; Long term systemic effects: 0.41 mg/m³
Consumer - Oral; Long term systemic effects: 0.27 mg/kg/day
DNEL
- Fresh water; 5.6 µg/l
- Marine water; 0.56 µg/l
- Intermittent release; 56 µg/l
- STP; 1.2 mg/l
- Sediment (Freshwater); 19 µg/kg
- Sediment (Marinewater); 1.9 µg/kg
- Soil; 2.31 µg/kg
PNEC
butanone (CAS: 78-93-3)
Workers - Dermal; Long term systemic effects: 1161 mg/kg/day
Workers - Inhalation; Long term systemic effects: 600 mg/m³
Consumer - Dermal; Long term systemic effects: 412 mg/kg/day
Consumer - Inhalation; Long term systemic effects: 106 mg/m³
Consumer - Oral; Long term systemic effects: 31 mg/kg/day
DNEL
- Fresh water; 55.8 mg/l
- Marine water; 55.8 mg/l
- Intermittent release; 55.8 mg/l
- STP; 709 mg/l
- Sediment (Freshwater); 284.7 mg/kg
- Sediment (Marinewater); 284.7 mg/kg
- Soil; 22.5 mg/kg
PNEC
8.2. Exposure controls
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Vapour pressure
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Protective equipment
Appropriate engineering controls
Provide adequate ventilation. Observe any occupational exposure limits for the product or ingredients. Use explosion-proof
general and local exhaust ventilation.
Eye/face protection
Wear tight-fitting, chemical splash goggles or face shield.
Hand protection
Wear protective gloves made of the following material: Neoprene. Nitrile rubber. Butyl rubber. Considering the data specified
by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon
as any deterioration is detected.
Other skin and body protection
Wear suitable coveralls to prevent exposure to the skin.
Hygiene measures
Do not smoke in work area. Provide eyewash station and safety shower. Wash promptly with soap and water if skin becomes
contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.
Respiratory protection
If ventilation is inadequate, suitable respiratory protection must be worn. Wear a respirator fitted with the following cartridge:
Organic vapour filter.
Environmental exposure controls
Keep container tightly sealed when not in use.
SECTION 9: Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Appearance
Liquid.
Colour
Colourless.
Odour
Characteristic.
Odour threshold
Not available.
pH
Not available.
Melting point
Not available.
Initial boiling point and range
Not available.
Flash point
93°C CC (Closed cup).
Evaporation rate
Not available.
Evaporation factor
Not available.
Upper/lower flammability or explosive limits
Not available.
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Vapour pressure
Not available.
Vapour density
> 1
Relative density
1.18 @ 20°C
Bulk density
Not available.
Solubility(ies)
Slightly soluble in water.
Partition coefficient
Not available.
Auto-ignition temperature
Not available.
Decomposition Temperature
60°C
Viscosity
24 mPa s @ 20°C
Explosive properties
Not considered to be explosive.
Oxidising properties
Not available.
9.2. Other information
8.8-9.0Active Oxygen
SECTION 10: Stability and reactivity
10.1. Reactivity
See the other subsections of this section for further details.
10.2. Chemical stability
Stability
Stable at normal ambient temperatures and when used as recommended.
10.3. Possibility of hazardous reactions
Reactions with the following materials may generate heat: Alkalis. Amines. Reducing agents. Strong acids.
10.4. Conditions to avoid
Avoid heat, flames and other sources of ignition. Avoid exposure to high temperatures or direct sunlight.
10.5. Incompatible materials
Materials to avoid
Reducing agents. Dimethylaniline. Cobalt naphthenate and other promoters. Strong acids. Strong alkalis. Promoted resins.
Amines. Accelerators. Sulphur compounds. Hot material. 7. Heavy metals and their salts
10.6. Hazardous decomposition products
Does not decompose when used and stored as recommended.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity - oral
Notes (oral LD50)
Harmful if swallowed.
ATE oral (mg/kg)
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500.0
Acute toxicity - dermal
Notes (dermal LD50)
Based on available data the classification criteria are not met.
Acute toxicity - inhalation
Notes (inhalation LC50)
Based on available data the classification criteria are not met.
Skin corrosion/irritation
Animal data
Corrosive to skin.
Serious eye damage/irritation
Corrosivity to eyes is assumed.
Respiratory sensitisation
Based on available data the classification criteria are not met.
Skin sensitisation
Based on available data the classification criteria are not met.
Germ cell mutagenicity
Genotoxicity - in vitro
Based on available data the classification criteria are not met.
Carcinogenicity
Based on available data the classification criteria are not met.
Reproductive toxicity
Reproductive toxicity - fertility
Based on available data the classification criteria are not met.
Reproductive toxicity - development
Based on available data the classification criteria are not met.
Specific target organ toxicity - single exposure
STOT - single exposure
Based on available data the classification criteria are not met.
Specific target organ toxicity - repeated exposure
STOT - repeated exposure
Based on available data the classification criteria are not met.
Aspiration hazard
Based on available data the classification criteria are not met.
Toxicological information on ingredients.
methyl ethyl ketone peroxide
Acute toxicity - oral
Acute toxicity oral (LD50 mg/kg)
1,017.0
Species
Rat
Notes (oral LD50)
REACH dossier information. Based on available data the classification criteria are not met.
ATE oral (mg/kg)
1,017.0
Acute toxicity - dermal
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Acute toxicity dermal (LD50 mg/kg)
4000.0
Species
Rabbit
Notes (dermal LD50)
REACH dossier information. Based on available data the classification criteria are not met.
ATE dermal (mg/kg)
4000.0
Acute toxicity - inhalation
Notes (inhalation LC50)
Based on available data the classification criteria are not met.
Skin corrosion/irritation
Animal data
Dose: 0.5 mL, 24 hours, Rabbit Erythema/eschar score: Severe erythema (beef redness) to eschar formation preventing
grading of erythema (4). Oedema score: Slight oedema - edges of area well defined by definite raising (2). REACH
dossier information. Corrosive.
Serious eye damage/irritation
Corrosive to skin. Corrosivity to eyes is assumed.
Respiratory sensitisation
Based on available data the classification criteria are not met.
Skin sensitisation
Guinea pig maximization test (GPMT) - Guinea pig: Not sensitising. REACH dossier information. Based on available data
the classification criteria are not met.
Germ cell mutagenicity
Genotoxicity - in vitro
Chromosome aberration: Negative. REACH dossier information. Based on available data the classification criteria are not
met.
Carcinogenicity
Based on available data the classification criteria are not met.
Reproductive toxicity
Reproductive toxicity - fertility
Screening - NOAEL 75 mg/kg/day, Oral, Rat P REACH dossier information. Based on available data the classification
criteria are not met.
Reproductive toxicity - development
Neonatal toxicity - NOAEL: 50 mg/kg/day, Oral, Rat REACH dossier information. Based on available data the classification
criteria are not met.
Specific target organ toxicity - single exposure
STOT - single exposure
Based on available data the classification criteria are not met.
Specific target organ toxicity - repeated exposure
STOT - repeated exposure
NOAEL 200 mg/kg/day, Oral, Rat REACH dossier information. Based on available data the classification criteria are not
met.
Aspiration hazard
Based on available data the classification criteria are not met.
butanone
Acute toxicity - oral
Acute toxicity oral (LD50 mg/kg)
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2,054.0
Species
Rat
Notes (oral LD50)
REACH dossier information. Based on available data the classification criteria are not met.
ATE oral (mg/kg)
2,054.0
Acute toxicity - dermal
Notes (dermal LD50)
Based on available data the classification criteria are not met.
Acute toxicity - inhalation
Notes (inhalation LC50)
Based on available data the classification criteria are not met.
Skin corrosion/irritation
Animal data
Dose: 0.5 ml, 4 hours, Rabbit Erythema/eschar score: No erythema (0). Oedema score: No oedema (0). REACH dossier
information. Based on available data the classification criteria are not met.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory sensitisation
Based on available data the classification criteria are not met.
Skin sensitisation
Buehler test - Guinea pig: Not sensitising. REACH dossier information. Based on available data the classification criteria
are not met.
Germ cell mutagenicity
Genotoxicity - in vitro
Gene mutation: Negative. REACH dossier information. Based on available data the classification criteria are not met.
Genotoxicity - in vivo
Chromosome aberration: Negative. REACH dossier information. Based on available data the classification criteria are not
met.
Carcinogenicity
Based on available data the classification criteria are not met.
Reproductive toxicity
Reproductive toxicity - fertility
Two-generation study - NOAEL 10000 mg/l, Oral, Rat F1 REACH dossier information. Based on available data the
classification criteria are not met.
Reproductive toxicity - development
Maternal toxicity: - NOAEC: 1002 ppm, Inhalation, Rat REACH dossier information. Based on available data the
classification criteria are not met.
Specific target organ toxicity - single exposure
STOT - single exposure
STOT SE 3 - H336 May cause drowsiness or dizziness.
Specific target organ toxicity - repeated exposure
STOT - repeated exposure
NOAEC 5041 ppm, Inhalation, Rat REACH dossier information. Based on available data the classification criteria are not
met.
Aspiration hazard
Based on available data the classification criteria are not met.
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SECTION 12: Ecological Information
12.1. Toxicity
The product is not expected to be toxic to aquatic organisms. However, large or frequent spills may have hazardous effects on
the environment.
Ecological information on ingredients.
methyl ethyl ketone peroxide
Acute toxicity - fish
LC₅₀, 96 hours: 44.2 mg/l, Poecilia reticulata (Guppy)
Acute toxicity - aquatic invertebrates
EC₅₀, 48 hours: 26.7 mg/l, Daphnia magna
Acute toxicity - aquatic plants
EC₅₀, 72 hours: 3.2 mg/l, Pseudokirchneriella subcapitata
butanone
Acute toxicity - fish
LC₅₀, 96 hours: 2993 mg/l, Pimephales promelas (Fat-head Minnow)
Acute toxicity - aquatic invertebrates
EC₅₀, 48 hours: 308 mg/l, Daphnia magna
Acute toxicity - aquatic plants
EC₅₀, 96 hours: 2029 mg/l, Selenastrum capricornutum
12.2. Persistence and degradability
Persistence and degradability
The product is biodegradable.
Ecological information on ingredients.
methyl ethyl ketone peroxide
Persistence and degradability
The product is readily biodegradable.
Biodegradation
Water - Degradation 87%: 28 days
butanone
Persistence and degradability
The product is readily biodegradable.
Biodegradation
Water - Degradation 98%: 28 days
12.3. Bioaccumulative potential
No data available on bioaccumulation.
Partition coefficient
Not available.
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Ecological information on ingredients.
methyl ethyl ketone peroxide
No data available on bioaccumulation.
Partition coefficient
log Pow: < 0.3
butanone
No data available on bioaccumulation.
Partition coefficient
log Pow: 0.3
12.4. Mobility in soil
Mobility
The product is partly miscible with water and may spread in the aquatic environment.
Ecological information on ingredients.
methyl ethyl ketone peroxide
Mobility
The product is soluble in water.
butanone
Mobility
The product is soluble in water.
12.5. Results of PBT and vPvB assessment
This product does not contain any substances classified as PBT or vPvB.
Ecological information on ingredients.
methyl ethyl ketone peroxide
This substance is not classified as PBT or vPvB according to current EU criteria.
butanone
This substance is not classified as PBT or vPvB according to current EU criteria.
12.6. Other adverse effects
None known.
Ecological information on ingredients.
methyl ethyl ketone peroxide
None known.
butanone
None known.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Disposal methods
Do not empty into drains. Containers should be thoroughly emptied before disposal because of the risk of an explosion.
Dispose of contents/container in accordance with national regulations.
SECTION 14: Transport information
14.1. UN number
3105UN No. (ADR/RID)
3105UN No. (IMDG)
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3105UN No. (ICAO)
3105UN No. (ADN)
14.2. UN proper shipping name
ORGANIC PEROXIDE TYPE D, LIQUID (METHYL ETHYL KETONE PEROXIDE(S))Proper shipping name
(ADR/RID)
ORGANIC PEROXIDE TYPE D, LIQUID (METHYL ETHYL KETONE PEROXIDE(S))Proper shipping name (IMDG)
ORGANIC PEROXIDE TYPE D, LIQUID (METHYL ETHYL KETONE PEROXIDE(S))Proper shipping name (ICAO)
ORGANIC PEROXIDE TYPE D, LIQUID (METHYL ETHYL KETONE PEROXIDE(S))Proper shipping name (ADN)
14.3. Transport hazard class(es)
5.2ADR/RID class
5.2ADR/RID label
5.2IMDG class
5.2ICAO class/division
5.2ADN class
Transport labels
14.4. Packing group
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant
No.
14.6. Special precautions for user
F-J, S-REmS
2ADR transport category
(D)Tunnel restriction code
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not relevant.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
EH40/2005 Workplace exposure limits. The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI
2009 No. 716).
EU legislation
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling
and packaging of substances and mixtures (as amended). Regulation (EC) No 1907/2006 of the European Parliament and of
the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)
(as amended).
15.2. Chemical safety assessment
No chemical safety assessment has been carried out.
SECTION 16: Other information
Revision comments
Revised Classification.
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Revision date
Revision
Supersedes date
Risk phrases in full
Hazard statements in full
25/07/2014
R7 May cause fire.
R11 Highly flammable.
R22 Harmful if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R67 Vapours may cause drowsiness and
dizziness.
H225 Highly flammable liquid and vapour.
H242 Heating may cause a fire.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
This information relates only to the specific material designated and may not be valid for such material used in combination with
any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and
reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
Disclaimer
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