Classification of selected substances http://echa.europa.eu/web/guest/information-on-chemicals/cl-inventory-database

www.kemi.se

Substance CAS No Name Classification Pictogram(s) Hazard statement(s)

EU Harmonized C&L?

1 143-33-9

2 117-81-7

3 67-56-1

4 57-27-2

5 7439-97-6

6 50-29-3

7 52645-53-1

8 7440-02-0

9 103-90-2

Codification of Hazard Pictograms

GHS01 GHS05 GHS03 GHS04

GHS06 GHS07 GHS08

GHS02

GHS09

Substance 1

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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)

EU Harmonized C&L?

1 143-33-9 Sodium cyanide Acute Tox. 2 Acute Tox. 1 Eye Dam. 1 Acute Tox. 2 Aquatic Acute 1 Aquatic Chronic 1

GHS05 GHS06 GHS09

H300 H310 H318 H330 H400 H410

No

Substance 2

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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)

EU Harmonized C&L?

2 117-81-7 DEHP Repr. 1B GHS08 H360FD Yes

Substance 3

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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)

EU Harmonized C&L?

3 67-56-1 Methanol Flam. Liq. 2 Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 STOT SE 1

GHS02 GHS06 GHS08

H225 H301 H311 H331 H370

Yes

Substance 4

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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)

EU Harmonized C&L?

4 57-27-2 Morphine Acute Tox. 4 GHS07 H302 No

Substance 5

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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)

EU Harmonized C&L?

5 7439-97-6 Mercury Acute Tox. 2 Repr. 1B STOT RE 1 Aquatic Acute 1 Aquatic Chronic 1

GHS06 GHS08 GHS09

H330 H360D H372 H400 H410

Yes

Substance 6

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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)

EU Harmonized C&L?

6 50-29-3 DDT Acute Tox. 3 Carc. 2 STOT RE 1 Aquatic Acute 1 Aquatic Chronic 1

GHS06 GHS08 GHS09

H301 H351 H372 H400 H410

Yes

Substance 7

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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)

EU Harmonized C&L?

7 52645-53-1 Permethrin Acute Tox. 4 Skin Sens. 1 Acute Tox. 4 Aquatic Acute 1 Aquatic Chronic 1

GHS07 GHS09

H302 H317 H332 H400 H410

Yes

Substance 8

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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)

EU Harmonized C&L?

8 7440-02-0 Nickel powder Skin Sens. 1 Carc. 2 STOT RE 1 Aquatic Chronic 3

GHS07 GHS08

H317 H351 H372 H412

Yes

Substance 9

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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)

EU Harmonized C&L?

9 103-90-2 Paracetamol Acute Tox. 4 Aquatic Chronic 3

GHS07 H302 H412

No

Hazard communication Exercises

• Pretend that you are an inspector visiting a manufacturer/importer of chemical products

• You are there to find out if the company is in compliance with GHS when it comes to hazard information given in labels and SDS

• Check for incompliances for these 3 products, Aldicarb, Sodium Fluoroacetate, Phosphine

Exercise 1-is this label correct? Use criteria given in SDS

• SDS information

• 11. Toxicological information Acute toxicity Oral 40 mg/kg bw Dermal 500 mg/kg bw Inhalation (mist) 0,25 mg/L

• 12. Ecological information Acute LC50 (fish) 150 mg/L EC 50 (algea) 0,5 mg/L Chronic NOEC (fish) 0,03 mg/L Non rapidly degradable

• ALDICARB (CAS nr: 116-06-3)

• Fatal if swallowed

• Very toxic to aquatic life with long lasting effects

Exercise 2-is this label correct? Use criteria given in SDS

• SDB information

• 11. Toxicological information Acute toxicity Oral 8 mg/kg bw Dermal 30 mg/kg bw Inhalation (gas) 400 ppmV

• 12. Ecological information Acute LC50 (fish) 150 mg/L EC 50 (algea) 0,5 mg/L Chronic NOEC (fish) 1,35 mg/L Non rapidly degradable

•

• Sodium fluoroacetate (CAS nr: 62-74-8)

• Harmful if swallowed

WARNING

Exercise 3 – is this label correct, use EU Inventory

•

• Phosphine (CAS nr: 7803-51-2)

• Extremely flammable gas

Danger