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EUROPEAN UNION PROFICIENCY TEST FOR PESTICIDES IN FRUIT AND VEGETABLES.
SCREENING METHODS 04 (EUPT-FV-SM-04)
2012
Pesticide Residues in Pear Homogenate
Final Report Organiser:
Dr. Amadeo R. Fernández-Alba Co-Head of EURL-FV
University of Almería, Edificio Químicas CITE I, Ctra. Sacramento s/n 04120 Almería, SPAIN
Phone: +34 950015034; Fax: +34 950015645 E-mail: amadeo@ual.es www.eurl-pesticides.eu
Organising team at the University of Almería:
Dr. Paula Medina, Chemist. University of Almería Mr. Octavio Malato, Chemist. University of Almería Ms. Carmen Ferrer, Chemist. University of Almería Ms. Noelia Belmonte, Chemist. University of Almería Ms. Ana Lozano, Chemist. University of Almería Ms. Mª del Mar Gómez, Chemist. University of Almería Ms. Samanta Uclés, Chemist. University of Almería Ms. Ana Uclés, Chemist. University of Almería
Quality Control Group
Dr. Antonio Valverde, Senior Chemist, University of Almería, Spain.
Mr. Stewart Reynolds, Senior Chemist, FERA, York, United Kingdom.
Statistical Group
Dr. Carmelo Rodriguez, Senior Mathematician, University of Almeria, Spain.
Advisory Group
Dr. André de Kok, Senior Chemist, NVWA, Wageningen, The Netherlands. Dr. Tuija Pihlström, Senior Chemist NFA, Uppsala, Sweden. Dr. Sonja Masselter, Senior Chemist, AGES, Innsbruck, Austria. Dr. Darinka Stajnbaher, Senior Chemist, IPH, Maribor, Slovenia. Dr. Magnus Jezussek, Senior Chemist, LGL, Erlangen, Germany. Dr. Miguel Gamón, Senior Chemist, Lab. Agroalimentario, Valencia, Spain. Dr. Mette Erecius Poulsen, Senior Chemist, DTU, Copenhagen, Denmark. Mr. Ralf Lippold, Senior Chemist, CVUA, Freiburg, Germany. Dr. Michelangelo Anastassiades, Senior Chemist, CVUA, Stuttgart, Germany.
CONTENTS
1. INTRODUCTION. 1
2. TEST MATERIALS. 2
2.1 Test material.
2.2 Analytical methods.
2.3 Prior analysis of the spiked pear test material.
2.4 Distribution of test material and protocol to participants.
3. STATISTICAL METHODS. 6
3.1 Type of Results Reported.
4. RESULTS. 7
4.1 Summary of reported results.
4.2 Concentration levels.
4.3 Assessment of laboratory performance.
5. CONCLUSIONS. 13
6. SUGGESTIONS FOR FUTURE WORK. 14
7. REFERENCES. 15
8. ACKNOWLEDGEMENTS. 16
APPENDIX 1. Results. 17
APPENDIX 2. Graphical Representations. 19
APPENDIX 3. Methods used by participants for detecting pesticides. 23 (available only as a pdf document uploaded to the EUPT-SM04 webpage, not in the printed version).
ANNEX 1. List of laboratories that participate in EUPT-FV-SM-04. 103
ANNEX 2. Specific Protocol. 105 (available only as a pdf document uploaded to the EUPT-SM04 webpage, not in the printed version).
EUROPEAN UNION PROFICIENCY TEST FOR PESTICIDES IN FRUITS AND VEGETABLES.
SCREENING METHODS 04 BACKGROUND
According to Article 28 of Regulation 396/2005/EC of the European Parliament and European
Council regarding maximum residue levels for pesticides in, or on, food and feed of plant and
animal origin1: all laboratories analysing samples for the official control of pesticide residues shall
participate in the European Union Proficiency Tests (EUPTs) for pesticide residues, facilitated by
the Commission. These proficiency tests are carried out on an annual basis in order to ensure the
quality, accuracy and comparability of the residue data reported by EU Member States to the
European Commission, as well as by other Member States within the framework of coordinated
national monitoring and surveillance programmes.
Regulation (EC) No 882/20042 lays down the general tasks, duties and requirements of European
Union Reference Laboratories (EURLs) for Food, Feed and Animal Health. Among these tasks is the
provision for independently-organised comparative tests. This is the fourth time that the EURL for
pesticides in fruit and vegetables at the University of Almería, Spain3 has organised a proficiency
test on qualitative screening methods for pesticides in fruit and vegetable commodities.
The aim of these tests is to evaluate laboratory capability when using wide-scope qualitative
and/or semi-quantitative screening methods during routine analysis, for detecting and identifying
unexpected pesticides at levels at, or above 0.01 mg/kg – included in and/or in addition to the
laboratories’ quantitative methods used for frequently-detected pesticides. A second aim is to
encourage official laboratories to extend the scope of their methods in a cost-effective way, by
using the different MS instruments/software and methods available (whether they be old or new).
Participation in this PT remains on a voluntary basis. Besides this, official laboratories have a
significant number of mandatory PTs annually given that the EURL-FV already organises the PT for
quantitative multi-residue pesticide analysis (EUPT-FV14), organised over the same time period.
Nevertheless, all FV-NRLs and FV-Official laboratories involved in the determination of pesticide
residues in fruit and vegetables for the EU-coordinated monitoring programme, or for their own
national programmes, were invited to take part.
This report will be presented to the European Commission Standing Committee for Animal Health
and the Food Chain. Furthermore, DG-SANCO has full access to all EUPT data including the
individual lab-codes/lab-name keys.
1 Regulation (EC) No 396/2005, published in the OJ of the EU L70 of 16.03.2005, as last amended by Regulation 839/2008 published in the OJ of the EU L234 of 30.08.2008. 2 Regulation (EC) No 882/2004 of the European Parliament and of the Council on official controls performed to ensure the verification of compliance with feed and food law, animal health and animal welfare rules. Published in the OJ of the EU L191 of 28.05.2004 3 Commission Regulation (EC) No 776/2006 of 23 May 2006 - amending Annex VII of Regulation (EC) No 882/2004 of the European Parliament and of the Council as regards Community Reference Laboratories.
Final Report - EURL-FV-SM-04, 2012 1
1. INTRODUCTION
In this fourth year, consolidation of inter-laboratory tests for pesticide screening methods among
laboratories seems to be assured; and are even requested by those laboratories not performing
routine analysis on fruit and vegetables. Responding to this demand, the EURL-FV has decided to
continue its operation. The support given by DG SANCO for these methods has greatly assisted
laboratory acceptance by allowing laboratories to conduct screening methods on the EU-
Coordinated Multiannual Programme samples.
Over recent years, it has been observed that many laboratories not only use a full-scan
approach to perform screening but that some also employ modern tandem-mass spectrometers,
even if their sensitivity has to be reduced.
Mass spectrometry plays an essential role in the everyday work carried out by laboratories.
Technological improvements in modern MS systems offer new possibilities for greatly increasing
the scope of MRM analysis. Whereas full-scan measurements are theoretically the best approach
for MS screening, developments in targeted measurements also offer the potential for a
substantially increased scope of analysis. Another reason for conducting this proficiency test on
screening methods is to gather information from laboratories as to the type of software they use
for processing data: whether laboratories are using commercial software and databases or
whether they are internally constructed and search manually. This type of test provides an
overview of such information as well as valuable insight into the possible need for further software
development in the near future.
The aim of the EURL-FV is for laboratories to be able to use mass-spectrometry-based screening
methods routinely, following validation. This is in line with Document N° SANCO/12495/2011 (which
supersedes Document No. SANCO/10684/2009)-Method validation and quality control
procedures for pesticide residues analysis in food and feed.
Only qualitative information was requested for those pesticides detected. It was decided, as in
previous PTs, not to provide the laboratories with a Target Pesticide List so that their capability in
detecting whatever pesticides were present was also evaluated.
Regulation (EC) No 882/2004 lays down the general tasks, duties and requirements for EURLs in
Food, Feed and Animal Health. Amongst these tasks is the provision for independently-organised
comparative tests. The EURL for pesticides in Fruit and Vegetables at the University of Almería,
Spain, has organised the proficiency test on qualitative screening methods for pesticides in fruit/
vegetable commodities. This EUPT-FV-SM04 is aimed at all National Reference Laboratories (NRLs)
and all Official Laboratories (OfLs) for fruit and vegetables in EU Member States. Laboratories
outside this EURL/NRL/OfL-Network were also able to participate on a case-by-case basis,
following consultation with DG SANCO.
2 Final Report - EURL-FV-SM-04, 2012
2. TEST MATERIALS
2.1 Test material
This proficiency test is based on the pesticide-residue analysis of pears. The pears were grown in
Aragón, Spain.
The pesticide treatments were carried out post-harvest using either commercial formulation in
micro-spray solutions or using standard solutions. The test material was frozen (using liquid
nitrogen), chopped, homogenised and sub-sampled into polyethylene bottles that had
previously been coded.
Ten of these bottles containing the test material were chosen randomly and analysed to check
for homogeneity.
The test material was stored frozen (–20ºC) prior to shipment to participants.
Two bottles, again chosen randomly, were analysed over a period of time to confirm the stability
of the pesticides in the test material (firstly, when the test materials were shipped, and then a few
days after the deadline for receipt of participants´ results). There was a further analysis during this
period reproducing the sample shipment i.e. maintaining the sample at room temperature for a
few days to see if there was any degradation of any of the pesticides present in the test material.
These results were not included in the statistical analysis of the proficiency test. The aim was solely
to check pesticide stability during the shipping process and for the duration of the proficiency
test.
Blank material without spiked pesticides was also prepared and shipped for confirmation
purposes.
The pesticides used to spike the pear test material were decided upon by the Quality Control
Group. It was decided that a target pesticide list would not be provided to participants. The
pesticides selected for treating the test material for this EUPT-FV-SM04 were mainly chosen taking
into account the following considerations:
that they were not included in the EU-Coordinated Multiannual Control Programme for
2011 (Regulation (EC) 915/2011).
that they had particularly acute toxicity and/or had low ARfD values.
Final Report - EURL-FV-SM-04, 2012 3
Table 2.1 shows the 26 pesticides used to spike the pear sample.
Table 2.1. The spiked pesticides used.
Spiked Pesticides
Bromacil Fenpropidin Napropamide
Bromoxinyl Flufenacet Prometryn
Cadusafos Flutolanil Propaquizafop
Diflubenzuron Imazapyr Pyrifenox
Diniconazole Ioxynil Terbacil
Ethoxiquin Isoproturon Terbumeton
Etrimfos Metazachlor Vamidothion
2.2 Analytical methods
The two analytical methods described briefly below were used by the Organiser for the
homogeneity and stability tests performed by the EURL-FV. These were:
- GC method: The sample is extracted with ethyl acetate along with sodium chloride and
magnesium sulphate anhydrous. The mixture is shaken and centrifuged. The final extract
is injected into GC-MS/MS.
- LC method: The sample is extracted with ethyl acetate and sodium hydroxide. The
mixture is shaken and centrifuged. The extract is evaporated and redissolved in methanol
and directly injected into LC-MS/MS.
2.3 Prior analysis of the spiked pear test material
The Organiser’s homogeneity and stability tests associated with ‘quantitative’ PTs were
conducted with a further acceptance criterion to those in the classical EUPT-FVs - the PT test
material was analysed in order to detect the presence of the spiked pesticides, which were
consistently confirmed to be above the Organiser’s LOD.
To confirm the homogeneity of the test material sent, ten spiked test samples were randomly
chosen from those stored in the freezer and analysed in duplicate so as to check for the
presence of the pesticides.
The injection sequence of the 10 analyses by GC and LC was determined from a table of
randomly-generated numbers. The relative standard deviation (RSD) of these 20 analyses
needed to be at 15%, or below, to consider the material homogeneous.
4 Final Report - EURL-FV-SM-04, 2012
Table 2.3.1 shows the results of these tests, together with the average concentration values for
each of the pesticides used to treat the sample along with the RSDs.
Table 2.3.1 Homogeneity tests
Test material No.
026 a
026 b
040a
040b
046a
046 b
054 a
054 b
074 a
074 b
078 a
078 b
081 a
081 b
114 a
114 b
132 a
132 b
141 a
141 b
A. Cc (µg/kg)
RSD (%)
Bromacil D D D D D D D D D D D D D D D D D D D D 437.7 8.4
Bromoxinyl D D D D D D D D D D D D D D D D D D D D 291.2 14.1
Cadusafos D D D D D D D D D D D D D D D D D D D D 209.4 10.6
Diflubenzuron D D D D D D D D D D D D D D D D D D D D 379.5 14.6
Diniconazole D D D D D D D D D D D D D D D D D D D D 209.2 8.2
Ethoxiquin D D D D D D D D D D D D D D D D D D D D 101.1 10.6
Etrimfos D D D D D D D D D D D D D D D D D D D D 56.5 1.1
Fenpropidin D D D D D D D D D D D D D D D D D D D D 59.5 12.5
Flufenacet D D D D D D D D D D D D D D D D D D D D 77.8 2.4
Flutolanil D D D D D D D D D D D D D D D D D D D D 79.8 2.3
Imazapyr D D D D D D D D D D D D D D D D D D D D 196.0 9.9
Ioxynil D D D D D D D D D D D D D D D D D D D D 148.1 10.6
Isoproturon D D D D D D D D D D D D D D D D D D D D 160.8 4.8
Metazachlor D D D D D D D D D D D D D D D D D D D D 80.2 2.7
Napropamide D D D D D D D D D D D D D D D D D D D D 51.6 1.5
Prometryn D D D D D D D D D D D D D D D D D D D D 62.7 1.6
Propaquizafop D D D D D D D D D D D D D D D D D D D D 16.5 4.5
Pyrifenox D D D D D D D D D D D D D D D D D D D D 37.5 4.2
Terbacil D D D D D D D D D D D D D D D D D D D D 204.6 8.3
Terbumeton D D D D D D D D D D D D D D D D D D D D 382.3 7.0
Vamidothion D D D D D D D D D D D D D D D D D D D D 95.4 10.9
D: Detected A. Cc: Average Concentration RSD: Relative Standard Deviation
Further analyses to test for stability were performed following varying time lapses. On each
occasion, a test material sample stored in the freezer at -20°C was randomly chosen and
analysed.
The three occasions were:
- Day 1: one week before the sample shipment on 10th February 2012.
- Day 2: on 20th February 2012 after reproducing the sample shipment conditions.
- Day 3: soon after the deadline for reporting results on 23rd February 2012.
For all the analyses, the two analytical methods described briefly above (in section 2.2) were
used.
All the pesticides used to spike the samples demonstrated sufficient stability even after
reproducing the 48h delivery conditions. All were detected on each occasion.
Final Report - EURL-FV-SM-04, 2012 5
Table 2.3.2 Stability tests performed.
Stability tests Test material Number
057 Day 1
057 Day 1
062 Day 2
062 Day 2
137 Day 3
137 Day 3
Bromacil D D D D D D
Bromoxinyl D D D D D D
Cadusafos D D D D D D
Diflubenzuron D D D D D D
Diniconazole D D D D D D
Ethoxiquin D D D D D D
Etrimfos D D D D D D
Fenpropidin D D D D D D
Flufenacet D D D D D D
Flutolanil D D D D D D
Imazapyr D D D D D D
Ioxynil D D D D D D
Isoproturon D D D D D D
Metazachlor D D D D D D
Napropamide D D D D D D
Prometryn D D D D D D
Propaquizafop D D D D D D
Pyrifenox D D D D D D
Terbacil D D D D D D
Terbumeton D D D D D D
Vamidothion D D D D D D
D: Detected
2.4 Distribution of test materials and protocol to participants
Approximately 300 g of treated pear homogenate together with another 300 g of ‘blank’ pear
homogenate were shipped to participants on 20th February 2012. The deadline for results
submission to the Organiser was 72 hours after receipt of the test material. Participants were
asked to report all the pesticides that they detected.
Laboratories were asked to screen the test materials using the wide-scope screening methods
they would normally apply, or anticipate applying, for official monitoring purposes. This typically
involves full-scan techniques like GC-MS (full-scan quadrupole, ion trap, ToF) and/or LC-TOF-MS
and Orbitrap. However, extended targeted methods using LC tandem MS (triple quadrupole, Q-
trap, Q-TOF) or GC-MS/MS could also be used.
Before shipment, the laboratories received full instructions for the receipt and analysis of the
spiked test material although they were encouraged to use their own screening methods. These
instructions, laid out as the General and Specific Protocols, were uploaded onto the EUPT-FV-
SM04 web page, designed especially for this Proficiency Test. This information was also sent by e-
mail to all participant laboratories. The Application Form was uploaded onto this same web site
together with Form 0 (Sample Receipt) and Form 1 (Results). These allowed the evaluation of the
mass-spectrometric screening methods that each of the participants used.
6 Final Report - EURL-FV-SM-04, 2012
3. STATISTICAL METHODS
3.1 Type of results reported
The results evaluation is concerned with the results themselves matching the pesticides that the
Organiser used to treat the sample; or otherwise stating a ‘not-reported pesticide’ or ‘other
reported pesticide’ from those used to treat the sample. After receiving the results, the Organiser
may consider further evaluation highlighted by important information received.
3.1.1 Other Reported Pesticides
These were considered as those results showing the apparent presence of pesticides which
were: (i) not used in the test material treatment, or (ii) not detected by the Organiser, even
after repeated analyses. However, if a number of participants detect the same additional
pesticide(s), then a decision as to whether, or not, this should be considered an ‘Other
Reported Pesticide’ result was made on a case-by-case basis.
Organiser’s Note:
Not all screening methods immediately provide sufficient information to
allow full identification. In such cases, when they detect a pesticide in
real life, laboratories normally do a follow-up confirmatory analysis:
using, for example, LC-MS/MS and based on two transitions. In future PTs
of this nature, there will be a need to distinguish between suspect or
tentative detection and full identification.
3.1.2 Not-Reported Pesticides
These were considered as any pesticides present in the sample but not reported by the lab
even though the Organiser had used it to spike the test material and it was detected by the
majority of participants.
Final Report - EURL-FV-SM-04, 2012 7
4. RESULTS
4.1 Summary of reported results
Fifty-three laboratories agreed to participate in this fourth proficiency test on screening methods.
Fifty-one laboratories submitted results. All results reported by the participants are given in
Appendix 1. Graphical representations of the results reported are shown in Appendix 2. Details of
the screening methods used are provided in Appendix 3 (available only as a pdf document
uploaded to the EUPT-SM04 webpage, not in the printed version). The laboratories that agreed to
participate are listed in Annex 1.
A summary of the results reported by pesticide and by laboratory can be seen in Table 4.1.
Table 4.1 Summary of Results Reported.
Pesticide No. of Reported % of Reported* No. of Not Reported % of Not Reported*
Bromacil 44 86 7 14
Bromoxinyl 37 73 14 27
Cadusafos 46 90 5 10
Diflubenzuron 42 82 9 18
Diniconazole 47 92 4 8
Ethoxyquin 37 73 14 27
Etrimfos 48 94 3 6
Fenpropidin 44 86 7 14
Flufenacet 39 76 12 24
Flutolanil 43 84 8 16
Imazapyr 18 35 33 65
Ioxynil 28 55 23 45
Isoproturon 46 90 5 10
Metazachlor 45 88 6 12
Napropamide 43 84 8 16
Prometryn 45 88 6 12
Propaquizafop 24 47 27 53
Pyrifenox 40 78 11 22
Terbacil 38 75 13 25
Terbumeton 38 75 13 25
Vamidothion 36 71 15 29
Spinosad** 43 84 8 16
* The % of laboratories is calculated based on the total number of laboratories submitting results (51). ** Reported but not spiked
8 Final Report - EURL-FV-SM-04, 2012
4.1.1 Other Reported Pesticides
Many laboratories reported additional pesticides to those used to spike the test material. These
reported pesticides are presented in Table 4.1.1.
Table 4.1.1. ‘Other reported pesticides’ in the test material given by laboratories.
LABORATORY CODE OTHER REPORTED PESTICIDES
Lab003* Secbumeton
Lab008 Atrazine-2-hydroxy, Atrazine-desethyl-2-hydroxy
Lab009* Ametryn, Carbaryl, Endosulfan alpha, Imibenconazol, Propiconazole, Terbutylazin
Lab010* 3-Chloroaniline, Prometon, Terbutryn, Secbumeton
Lab012* 3-Chloroaniline
Lab016 Formothion, Omethoate, Secbumeton
Lab017* Phenothrin, Photodieldrin, Tebufenocide, Thiodemeton
Lab019* 3-Chloroaniline
Lab020 3-Chloroaniline
Lab022 Terbutryn
Lab025 Cyproconazole, Diclobutrazol, Propiconazole
Lab028* Atrazine-desethyl-2-hydroxy
Lab029 Cymoxanil, Terbutryn
Lab030* Ametryn, Cyazofomid, Diclobutrazol, Molinate, Terbutryn
Lab040* 3-Chloroaniline, Atraton, Demeton O, Isobornyl Thiocyanoacetate
Lab044 Difenoconazole, Folpet, Procloraz
Lab045 Chlorbufam, o-Phenylphenol, Trichlorfon
Lab048 Atraton
Lab050 Bifenox
* National Reference Laboratories for Fruit and Vegetables from the EU participating in this test.
Those pesticides reported by more than two laboratories were analysed by the Organiser, but
none of these pesticides was detected after repeated analyses.
4.1.2 Not-Reported Pesticides
In Table 4.1, the number and percentage of laboratories not reporting each of the pesticides
used to spike the sample can be seen. The individual results for each laboratory are given in
Appendix 1. Graphical representations can be seen in Appendix 2.
4.2 Concentration levels.
Twenty-one pesticides were used to spike the pear test material at different levels, in the range
between 50 and 1000 µg/kg. Spinosad was present in the sample at around 5µg/kg. This EUPT was
focused only on detection capabilities; therefore no quantitative data were requested.
Final Report - EURL-FV-SM-04, 2012 9
4.3 Assessment of laboratory performance.
No z-score values were carried out for laboratories to assess their performance as no numerical
results were reported by the participants. However, classification was considered important,
based on the number of detected results each laboratory reported and also on which methods
they used.
Table 4.3.1 classifies the laboratories according to the number of spiked pesticides reported.
Table 4.3.1 Classification of laboratories according to the number of spiked pesticides reported.
Laboratory Code Reported
Other Reported Pesticides
Not Confirmed by the Organiser
Confirmed by the Organiser
Lab024 22 0
Lab034* 22 0 Lab028* 22 1 Lab048 22 1 Lab008 22 2 0
Lab040* 22 4 0 Lab001 21 0 Lab014 21 0 Lab023 21 0
Lab049 21 0 0 Lab010* 21 4 0 Lab004* 20 0 Lab015 20 0
Lab038 20 0 Lab047* 20 0 Lab003* 20 1 Lab025 20 3 0
Lab006 19 0 Lab018 19 0 Lab021 19 0 Lab041 19 0
Lab046 19 0 Lab030* 19 5 Lab002* 18 0 Lab011 18 0
Lab031 18 0 0 Lab039 18 0 0 Lab043* 18 0 0 Lab020 18 1 0
Lab036 17 0 Lab037 17 0 Lab042 17 0 Lab019* 17 1 0
Lab016 17 3 0 Lab045 17 3 0 Lab026 16 0 Lab050 16 1
10 Final Report - EURL-FV-SM-04, 2012
Laboratory Code Reported
Other Reported Pesticides
Not Confirmed by the Organiser
Confirmed by the Organiser
Lab029 16 2 0 Lab017* 16 4 0 Lab007* 15 0 Lab053 15 0
Lab009* 15 6 0 Lab027* 14 0
Lab012* 14 1 0
Lab033 13 0 0
Lab032 11 0
Lab051 11 0 0
Lab022 10 1
Lab035* 6 0
Lab013 1 0
Lab044 1 3 0
Lab005 No Results Reported
Lab052 No Results Reported * National Reference Laboratories for Fruit and Vegetables from the EU participating in this test.
The methods used by the laboratories, the chromatographic techniques, detectors,
instrumentation, etc… are detailed in Appendix 3 (available only as a pdf document uploaded
to the EUPT-SM04 webpage, not in the printed version). In Table 4.3.2, there is a summary of the
chromatographic techniques used for each pesticide, and a graphical representation is shown in
Appendix 2.
Table 4.3.2 Chromatographic techniques used to determine each pesticide in the test material
Pesticide Total no. of Reports GC Full-scan GC LC Full-scan LC
Bromacil 46 18 14 28 10
Bromoxinyl 39 11 11 28 6
Cadusafos 49 26 15 23 5
Diflubenzuron 44 3 2 41 10
Diniconazole 50 20 15 30 6
Ethoxyquin 39 24 17 15 4
Etrimfos 50 34 21 16 5
Fenpropidin 47 18 13 29 5
Flufenacet 41 14 12 27 7
Flutolanil 46 25 16 21 6
Imazapyr 18 0 0 18 4
Ioxynil 29 4 4 25 5
Isoproturon 46 2 2 44 10
Metazachlor 47 27 18 20 6
Final Report - EURL-FV-SM-04, 2012 11
Pesticide Total no. of Reports GC Full-scan GC LC Full-scan LC
Napropamide 45 18 12 27 8
Prometryn 48 26 18 22 6
Propaquizafop 25 0 0 25 5
Pyrifenox 44 20 14 24 6
Spinosad* 53 0 0 53 13
Terbacil 39 30 20 9 6
Terbumeton 41 23 18 18 7
Vamidothion 44 5 5 39 7
*Spinosad was present in the sample but not spiked. Note: The number of reports for each of the pesticides could be different to the reports shown in Table 4.1 because a particular laboratory might analize each of the pesticides with more than one technique.
In Appendix 2, graphical representations of the techniques used can be seen.
Table 4.3.3 shows the number and percentage of the pesticides used by the Organiser to spike
the sample which were reported by each laboratory. National Reference Laboratories are
marked with an asterisk.
Table 4.3.3. Number and Percentage of Present Pesticides Reported by Laboratory
Laboratory Code
Number of Present Pesticides Reported
% of Present Pesticides Reported
Lab001 21 95
Lab002* 18 82
Lab003* 20 91
Lab004* 20 91
Lab006 19 86
Lab007* 15 68
Lab008 22 100
Lab009* 15 68
Lab010* 21 95
Lab011 18 82
Lab012* 14 64
Lab013 1 5
Lab014 21 95
Lab015 20 91
Lab016 17 77
Lab017* 16 73
Lab018 19 86
Lab019* 17 77
Lab020 18 82
Lab021 19 86
Lab022 10 45
Lab023 21 95
12 Final Report - EURL-FV-SM-04, 2012
Laboratory Code
Number of Present Pesticides Reported
% of Present Pesticides Reported
Lab024 22 100
Lab025 20 91
Lab026 16 73
Lab027* 14 64
Lab028* 22 100
Lab029 16 73
Lab030* 19 86
Lab031 18 82
Lab032 11 50
Lab033 13 59
Lab034* 22 100
Lab035* 6 27
Lab036 17 77
Lab037 17 77
Lab038 20 91
Lab039 18 82
Lab040* 22 100
Lab041 19 86
Lab042 17 77
Lab043* 18 82
Lab044 1 5
Lab045 17 77
Lab046 19 86
Lab047* 20 91
Lab048 22 100
Lab049 21 95
Lab050 16 73
Lab051 11 50
Lab053 15 68
* National Reference Laboratories for Fruit and Vegetables from the EU participating in this test.
Final Report - EURL-FV-SM-04, 2012 13
5. CONCLUSIONS
Fifty-three laboratories applied to participate in this test and fifty-one laboratories submitted
results. Seventeen of the laboratories which applied were National Reference Laboratories for
Fruit and Vegetables (marked with an asterisk on the graphs and tables) representing nineteen
Member States. In addition to these, 2 EFTA countries (Norway and Switzerland) and three non-
EU/EFTA countries (Egypt, Serbia and Turkey) participated in this European Union Proficiency Test.
Most laboratories analysed the test material using methods based on both gas and liquid
chromatography, combined with mass spectrometric detection. In the case of GC-MS analysis,
full-scan acquisition, with associated target-library software (covering a large number of
pesticides) was used by the majority of the laboratories. In the case of LC-MS analysis, targeted
acquisition methods using triple quadrupole instruments were the most widely used. Of 930
detections, 395 were made using full-scan, meaning 43% of detections; 248 by LC techniques
and 147 by GC techniques.
Four of the 53 laboratories were able to detect all 22 pesticides in the spiked pear test material
(21 spiked plus spinosad, which was present in the blank). Only 4 laboratories failed to detect less
than 50% of the pesticides present.
Seventy-six percent of the laboratories (39 laboratories) that reported results were able to find
more than 70% of the pesticides used to spike the sample whereas last year (EUPT-FV-SM03) only
71% managed to do so.
Nineteen participants reported thirty-two different pesticides which were not used for spiking the
pears. Whether this should be judged as poor performance, or not, depends on how each
participant would act on these positive findings in routine analysis. If the detected pesticide were
reported as positive with no further identifying confirmation, then the result would be a false
positive and hence erroneous monitoring data would be reported. If the detected pesticide is
regarded simply as ‘suspect’ or ‘indicatively present’, leading to additional analysis to confirm
identity before reporting the result, then those pesticides indicated as ‘other reported pesticides’
in this report are not really an issue.
This fourth interlaboratory test on wide-scope screening methods showed that such an approach
can substantially expand the scope of pesticide residue analysis. This is especially useful for
pesticides not frequently found in food and feed, or not monitored by the laboratories because
they are not part of the EU-Coordinated Programme. The use of screening methods can greatly
increase the chance of detecting less commonly found pesticides. However, the test also
revealed that improvements in scope (both in number and the choice of pesticides included)
and verification of the screening methods performance (i.e. validation) are necessary to improve
the reliability of such methods.
14 Final Report - EURL-FV-SM-04, 2012
6. SUGGESTIONS FOR FUTURE WORK
The Organiser and the Scientific Committee consider that screening methods have provided
additional value to the current quantitative multiresidue methods routinely used for monitoring
purposes. The results of this fourth test are most encouraging, but also indicate the need for
continued evaluation of screening methods. Therefore, further proficiency tests will be organised
to provide support to those laboratories using screening methods in order to extend their use and
improve their reliability. These methods will be used more and more as screens/filters, to make
routine laboratory work easier and faster. The need for screening method validation has been
recognised and guidelines for such validation have been prepared and included in the updated
SANCO document: “Method validation and quality control procedures for pesticide residue
analysis in food and feed” (SANCO/12495/2011).
Next year, potato matrix test material will be used. If laboratories have a particular interest in
specific matrices, they should inform the EURL-FV and their suggestions will be evaluated. The
date of the test material delivery will be January 2013; and 72 hours will be allowed for results
submission (given that this should be enough time to carry out screening methods). There will be
no target list, as was the case in this test.
Final Report - EURL-FV-SM-04, 2012 15
7. REFERENCES
Malato O., Lozano, A., Mezcua M., Agüera, A., and Fernandez-Alba A. R. Benefits and
pitfalls of the application of screening methods for the analysis of pesticide residues in
fruits and vegetables. Journal of Chromatography A, 2011, 1218(42), 7615-7626.
Mezcua M., Malato O., Martinez-Uroz M. A., Lozano, A., Agüera, A., and Fernandez-Alba
A. R. Evaluation of Relevant Time-of-Flight-MS Parameters Used in HPLC/MS Full-Scan
Screening Methods for Pesticides Residues. Journal of AOAC Int., 2011, 94 (6), 1674-1684.
Mezcua M., Martinez-Uroz M. A., Wylie P. L. and Fernandez-Alba A.R. Simultaneous
screening and target analytical approach by GC-q-MS for pesticide residues in fruits and
vegetables. Journal of AOAC Int., 2009, 92 (6).
Mezcua M., Malato O., Garcia-Reyes J. F., Molina-Diaz A., and Fernandez-Alba A. R.
Accurate-Mass Databases for Comprehensive Screening of Pesticide Residues in Food by
Fast Liquid Chromatography Time-of-Flight Mass Spectrometry. Anal. Chem. 2009, 81,
913–929.
Method Validation and Quality Control Procedures for Pesticide Residues Analysis in Food
and Feed, European Commission, Document No. SANCO/10684/2009.
ISO/IEC 17043:2010 Conformity assessment - General requirements for proficiency testing.
16 Final Report - EURL-FV-SM-04, 2012
8. ACKNOWLEDGEMENTS
The Organiser is grateful to the European Commission for funding this 4th European Proficiency
Test for Screening Methods in Fruit and Vegetables.
The Organiser wishes to thank the members of the Scientific Committee for their invaluable and
knowledgeable advice.
The Organiser wishes to give a special thank-you to Almeria University for the use of their facilities.
APPENDIX 1. Results
Final Report - EURL-FV-SM-04, 2012 17
Labo
rato
ry C
ode
Tota
l No
of
Repo
rting
La
bora
torie
s = 5
1 Evaluated Pesticides (21 added + 1 present in the blank)
Repo
rted
Pes
ticid
es
by L
abor
ator
y
% o
f Rep
orte
d Pe
stic
ides
by
Labo
rato
ry
Brom
acil
Brom
oxin
yl
Cad
usaf
os
Difl
uben
zuro
n
Din
icon
azol
e
Etho
xyqu
in
Etrim
fos
Fenp
ropi
din
Fluf
ena
cet
Flut
olan
il
Imaz
apyr
Ioxy
nil
Isopr
otur
on
Met
aza
chlo
r
Nap
ropa
mid
e
Prom
etry
n
Prop
aqui
zafo
p
Pyrif
enox
Terb
acil
Terb
umet
on
Vam
idot
hion
Spin
osad
001 R R R R R R R R R R R R R R R R R R R R R 21 95 002* R R R R R R R R R R R R R R R R R R 18 82 003* R R R R R R R R R R R R R R R R R R R R 20 91 004* R R R R R R R R R R R R R R R R R R R R 20 91 005 No Results Reported 0 0 006 R R R R R R R R R R R R R R R R R R R 19 86 007* R R R R R R R R R R R R R R R 15 68 008 R R R R R R R R R R R R R R R R R R R R R R 22 100 009* R R R R R R R R R R R R R R R 15 68 010* R R R R R R R R R R R R R R R R R R R R R 21 95 011 R R R R R R R R R R R R R R R R R R 18 82 012* R R R R R R R R R R R R R R 14 64 013 R 1 5 014 R R R R R R R R R R R R R R R R R R R R R 21 95 015 R R R R R R R R R R R R R R R R R R R R 20 91 016 R R R R R R R R R R R R R R R R R 17 77 017* R R R R R R R R R R R R R R R R 16 73 018 R R R R R R R R R R R R R R R R R R R 19 86 019* R R R R R R R R R R R R R R R R R 17 77 020 R R R R R R R R R R R R R R R R R R 18 82 021 R R R R R R R R R R R R R R R R R R R 19 86 022 R R R R R R R R R R 10 45 023 R R R R R R R R R R R R R R R R R R R R R 21 95 024 R R R R R R R R R R R R R R R R R R R R R R 22 100 025 R R R R R R R R R R R R R R R R R R R R 20 91 026 R R R R R R R R R R R R R R R R 16 73 027* R R R R R R R R R R R R R R 14 64 028* R R R R R R R R R R R R R R R R R R R R R R 22 100 029 R R R R R R R R R R R R R R R R 16 73 030* R R R R R R R R R R R R R R R R R R R 19 86 031 R R R R R R R R R R R R R R R R R R 18 82 032 R R R R R R R R R R R 11 50 033 R R R R R R R R R R R R R 13 59 034* R R R R R R R R R R R R R R R R R R R R R R 22 100 035* R R R R R R 6 27 036 R R R R R R R R R R R R R R R R R 17 77 037 R R R R R R R R R R R R R R R R R 17 77 038 R R R R R R R R R R R R R R R R R R R R 20 91 039 R R R R R R R R R R R R R R R R R R 18 82 040* R R R R R R R R R R R R R R R R R R R R R R 22 100 041 R R R R R R R R R R R R R R R R R R R 19 86 042 R R R R R R R R R R R R R R R R R 17 77 043* R R R R R R R R R R R R R R R R R R 18 82 044 R 1 5 045 R R R R R R R R R R R R R R R R R 17 77 046 R R R R R R R R R R R R R R R R R R R 19 86 047* R R R R R R R R R R R R R R R R R R R R 20 91 048 R R R R R R R R R R R R R R R R R R R R R R 22 100 049 R R R R R R R R R R R R R R R R R R R R R 21 95 050 R R R R R R R R R R R R R R R R 16 73 051 R R R R R R R R R R R 11 50 052 No Results Reported 0 0 053 R R R R R R R R R R R R R R R 15 68
Reported Pesticides 44 37 46 42 47 37 48 44 39 43 18 28 46 45 43 45 24 40 38 38 36 43
% of Reported
Pesticides 86 73 90 82 92 73 94 86 76 84 35 55 90 88 84 88 47 78 75 75 71 84
R: Reported pesticide * NRLs from EU
APPENDIX 2. Graphical Representations
Final Report - EURL-FV-SM-04, 2012 19
1 16
10 1
11
11
3 14
14 1
51
51
5 16
16
16
16 1
71
71
71
71
71
7 18
18
18
18
18
18 1
91
91
91
91
91
9 20
20
20
20
20
20 2
12
12
12
12
1 22
22
22
22
22
22
0
2
4
6
8
10
12
14
16
18
20
22
24
Lab0
13
Lab0
44
Lab0
35
*Lab
02
2Lab
03
2Lab
05
1Lab
03
3Lab
01
2*
Lab0
27
*Lab
00
7*
Lab0
09
*Lab
05
3Lab
01
7*
Lab0
26
Lab0
29
Lab0
50
Lab0
16
Lab0
19
*Lab
03
6Lab
03
7Lab
04
2Lab
04
5Lab
00
2*
Lab0
11
Lab0
20
Lab0
31
Lab0
39
Lab0
43
*Lab
00
6Lab
01
8Lab
02
1Lab
03
0*
Lab0
41
Lab0
46
Lab0
03
*Lab
00
4*
Lab0
15
Lab0
25
Lab0
38
Lab0
47
*Lab
00
1Lab
01
0*
Lab0
14
Lab0
23
Lab0
49
Lab0
08
Lab0
24
Lab0
28
*Lab
03
4*
Lab0
40
*Lab
04
8N
o o
f R
ep
ort
ed
Pe
stic
ide
s
Number of Reported Data by Laboratory(*NRL) (22 Pesticides Included)
5 52
74
5 50
50
59 6
46
4 68
68
68 7
37
37
37
3 77
77
77
77
77
77 8
28
28
28
28
28
2 86
86
86
86
86
86 9
19
19
19
19
19
1 95
95
95
95
95 1
00
10
01
00
10
01
00
10
0
0
10
20
30
40
50
60
70
80
90
100
Lab0
13
Lab0
44
Lab0
35
*Lab
02
2Lab
03
2Lab
05
1Lab
03
3Lab
01
2*
Lab0
27
*Lab
00
7*
Lab0
09
*Lab
05
3Lab
01
7*
Lab0
26
Lab0
29
Lab0
50
Lab0
16
Lab0
19
*Lab
03
6Lab
03
7Lab
04
2Lab
04
5Lab
00
2*
Lab0
11
Lab0
20
Lab0
31
Lab0
39
Lab0
43
*Lab
00
6Lab
01
8Lab
02
1Lab
03
0*
Lab0
41
Lab0
46
Lab0
03
*Lab
00
4*
Lab0
15
Lab0
25
Lab0
38
Lab0
47
*Lab
00
1Lab
01
0*
Lab0
14
Lab0
23
Lab0
49
Lab0
08
Lab0
24
Lab0
28
*Lab
03
4*
Lab0
40
*Lab
04
8%
of
Re
po
rte
d P
est
icid
es
% of Reported Data by Laboratory(*NRL) (22 Pesticides Included)
APPENDIX 2. Graphical Representations
20 Final Report - EURL-FV-SM-04, 2012
0 0 0 0 0 01 1 1 1 1
2 2 2 2 2 23 3 3 3 3 3
4 4 4 4 4 45 5 5 5 5 5
6 6 6 67 7 7
8 89
11
11 1
21
62
12
1
0
2
4
6
8
10
12
14
16
18
20
22
24
26
Lab0
08
Lab0
24
Lab0
28
*Lab
03
4*
Lab0
40
*Lab
04
8Lab
00
1Lab
01
0*
Lab0
14
Lab0
23
Lab0
49
Lab0
03
*Lab
00
4*
Lab0
15
Lab0
25
Lab0
38
Lab0
47
*Lab
00
6Lab
01
8Lab
02
1Lab
03
0*
Lab0
41
Lab0
46
Lab0
02
*Lab
01
1Lab
02
0Lab
03
1Lab
03
9Lab
04
3*
Lab0
16
Lab0
19
*Lab
03
6Lab
03
7Lab
04
2Lab
04
5Lab
01
7*
Lab0
26
Lab0
29
Lab0
50
Lab0
07
*Lab
00
9*
Lab0
53
Lab0
12
*Lab
02
7*
Lab0
33
Lab0
32
Lab0
51
Lab0
22
Lab0
35
*Lab
01
3Lab
04
4N
o o
f N
ot
Re
po
rte
d P
est
icid
es
SM04 Not Reported Pesticides(*NRL)
0 0 0 0 0 05 5 5 5 5
9 9 9 9 9 91
41
41
41
41
41
4 18
18
18
18
18
18 2
32
32
32
32
32
3 27
27
27
27 3
23
23
2 36
36 4
15
05
0 55
73
95
95
0
10
20
30
40
50
60
70
80
90
100
Lab0
08
Lab0
24
Lab0
28
*Lab
03
4*
Lab0
40
*Lab
04
8Lab
00
1Lab
01
0*
Lab0
14
Lab0
23
Lab0
49
Lab0
03
*Lab
00
4*
Lab0
15
Lab0
25
Lab0
38
Lab0
47
*Lab
00
6Lab
01
8Lab
02
1Lab
03
0*
Lab0
41
Lab0
46
Lab0
02
*Lab
01
1Lab
02
0Lab
03
1Lab
03
9Lab
04
3*
Lab0
16
Lab0
19
*Lab
03
6Lab
03
7Lab
04
2Lab
04
5Lab
01
7*
Lab0
26
Lab0
29
Lab0
50
Lab0
07
*Lab
00
9*
Lab0
53
Lab0
12
*Lab
02
7*
Lab0
33
Lab0
32
Lab0
51
Lab0
22
Lab0
35
*Lab
01
3Lab
04
4%
of
No
t R
ep
ort
ed
Pe
stic
ide
s
SM04 % of Not Reported Pesticides(*NRL)
APPENDIX 2. Graphical Representations
Final Report - EURL-FV-SM-04, 2012 21
44
37
46
42
47
37
48
44
39
43
18
28
46
45
43
45
24
40
43
38
38
36
0
10
20
30
40
50
60
Bro
macil
Bro
mo
xinyl
Cad
usafo
s
Diflu
be
nzu
ron
Din
icon
azole
Etho
xyqu
in
Etrimfo
s
Fen
pro
pid
in
Flufe
nace
t
Fluto
lanil
Imazap
yr
Ioxyn
il
Isop
rotu
ron
Metazach
lor
Nap
rop
amid
e
Pro
metryn
Pro
paq
uizafo
p
Pyrifen
ox
Spin
osad
Terb
acil
Terb
um
eton
Vam
ido
thio
nN
o o
f D
ete
ctio
ns
SM04 Number of Reported Data by Pesticide(51 Laboratories Reported Data)
86 73 90 82 92 73 94 86 76 84 35 55 90 88 84 88 47 78 84 75 75 71
0
10
20
30
40
50
60
70
80
90
100
Bro
macil
Bro
mo
xinyl
Cad
usafo
s
Diflu
ben
zuro
n
Din
icon
azole
Etho
xyqu
in
Etrimfo
s
Fenp
rop
idin
Flufe
nace
t
Fluto
lanil
Imazap
yr
Ioxyn
il
Isop
rotu
ron
Metazach
lor
Nap
rop
amid
e
Pro
metryn
Pro
paq
uizafo
p
Pyrifen
ox
Spin
osad
Terb
acil
Terb
um
eto
n
Vam
ido
thio
n%
of
Det
ect
ion
s
SM04 % of Reported Data by Pesticide(51 Laboratories Reported Data)
APPENDIX 2. Graphical Representations
22 Final Report - EURL-FV-SM-04, 2012
Chromatographic Techniques used in Full Scan to determine each pesticide in the test material
46
39
49
44
50
39
50
47
41
46
18
29
46 47 45
48
25
44
53
39 41
44
14
11
15
2
15 17
21
13 12
16
0
4 2
18
12
18
0
14
0
20 18
5
10
6 5
10
6 4 5 5 7 6 4 5
10
6 8 6 5 6
13
6 7 7
0
10
20
30
40
50
60
Broma
cil
Bromoxinyl
Cadusafos
Diflubenzuron
Dinicona
zole
Ethoxyquin
Etrimfos
Fenprop
idin
Flufenacet
Flutolanil
Imaza
pyr
Ioxynil
Isoproturon
Metazachlor
Nap
ropam
ide
Prometryn
Propaquizafop
Pyrifenox
Spinosad
Terbacil
Terbum
eton
Va
midothion
No
of R
epor
ted
Dete
ctio
ns
SM4 Techniques (Full Scan)
Total Reported Full Scan GC Full Scan LC
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
23
BR
OM
AC
IL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
11.2
G
C
MSD
Q
EI
+
YES
YES
not
valid
ated
YE
S A
T 59
75
10
AC
N
SPE
HP5-
MS
10
Aut
o ap
rox
750
Alw
ays
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
+ YE
S N
O
NA
N
O
Agi
lent
646
0,
1290
HPLC
10
Et
OA
c N
one
Wa
ters
, HSS
T3,
15
0 x
2.1m
m
2 Bo
th
500
Each
Ba
tch
004
Con
firm
ed w
ith
seco
nd m
etho
d
-1.8
0.
6
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
006
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
<2
0 2
trans
ition
s LC
M
SD
Q
ESI
- YE
S YE
S >0
.010
m
g/kg
N
O
Wa
ters
qua
ttro
prem
ier
15
AC
N
Non
e BE
H C
18
3 Bo
th
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Agi
lent
68
90/5
973
10
AC
N
DSP
E HP
-5M
S 2
Man
ual
183
Each
Ba
tch
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch
Batc
h
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
6.3
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch
Batc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S 0.
01
NO
70
00B
10
AC
N
PSA
D
B-5M
S UI
2
Both
44
0
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.01
0 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
017
Tent
ativ
e d
etec
ted
GC
M
SD
TOF
EI
N
O
NO
YES
LEC
O P
EGA
SUS
15
Ace
tone
/PE/
DC
M
NO
D
B-5
1 Bo
th
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
24
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
BR
OM
AC
IL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
018
Tent
ativ
e d
etec
ted
5
5 ac
cura
te
mas
s LC
O
rbitr
ap
O
rbitr
ap
ES
I +
YES
YES
0.01
- 0.
05
mg/
kg
YES
Ther
mo
Exac
tive
10
AC
N
PSA
C
18
5 Bo
th
120
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
10
NO
A
gile
nt 6
490
15
AC
N
PSA
C
18
5 A
uto
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
bSci
ex
10
AC
N
DSP
E C
18
5 A
uto
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
022
Tent
ativ
e d
etec
ted
0.
5 0.
05
LC
M
SD
TOF
ESI
+ YE
S YE
S
YES
LCT
PREM
IER
XE
15
MIN
I LUK
E N
O
C-1
8 7
Aut
o 34
3 Ev
ery
Da
y
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
IT ES
I -
YES
YES
0.01
N
O
10
A
CN
Both
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
3
mas
ses
GC
M
SD
IT EI
+
YES
YES
0.01
YE
S V
aria
n Sa
turn
20
00
10
AC
N
PSA
V
acto
rFou
r 5 M
S 5
Aut
o 50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.1
2 1.
2 iso
tope
, 2 io
ns
< 5p
pm
LC
MSD
O
rbitr
ap
ES
I +
NO
N
O
0.01
-0.1
YE
S Ex
activ
e 10
A
CN
N
one
C18
Atla
ntis
T3
5 Bo
th
570
Each
Ba
tch
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
86
0 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 2.
5 %
2.
5 tra
nsiti
on 1
an
d 2
LC
M
SD
Q-T
RAP
ESI
+ YE
S YE
S 0.
01
YES
3200
Qtra
p
10
AC
N
DSP
E C
18
50
Aut
o 52
1 Ev
ery
Wee
k
028
Con
firm
ed w
ith
seco
nd m
etho
d
261.
0>20
5.0,
26
1.0>
187.
0 LC
M
SD
Q
ESI
+ N
O
NO
10-
100
ppb
N
O
LC: A
gile
nt 1
200,
M
S:
API
400
0 Q
TRA
P 10
A
CN
Q
uEC
hERS
w
ithou
t PSA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2.
1 m
m, 5
µm
2
Aut
o 59
1
029
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
NO
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch
Batc
h
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
25
BR
OM
AC
IL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
025-
0.4
µg/m
l N
O
UPLC
-MSM
S (W
ate
rs A
quity
UP
LC sy
stem
, A
PI 5
000
Trip
pel
quad
ropo
l, Sc
iex
10
EtO
Ac
Filte
r HS
S T3
2
Both
14
1 Ea
ch
Batc
h
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-5.5
20
%
min
3 io
ns
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01
YES
Agi
lent
GC
-MSD
78
90A
/597
5c
10
AC
N
PSA
, C18
HP
-5M
S 1
Aut
o 92
7
034
Con
firm
ed w
ith
seco
nd m
etho
d
full
scan
G
C
MSD
Q
EI
+
NO
N
O
YE
S A
gile
nt 5
973
MSD
10
A
CN
D
SPE
(PSA
/MgS
O4)
HP
-5M
S 10
Bo
th
950
035
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
NO
N
O
YE
S A
gile
nt 6
890N
10
A
CN
D
SPE
DB-
5 2
Aut
o
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
Non
e N
one
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
D
SPE
Wa
ters
-C18
2,
1x50
mm
x1,7
‚µm
5
Aut
o 60
0 Ev
ery
Wee
k
040
Con
firm
ed w
ith
seco
nd m
etho
d
3 1
LC
TOF
ESI
+ N
O
NO
YES
Agi
lent
623
0 10
A
CN
N
one
Eclip
se C
18
3 A
uto
apro
x 50
0
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5%
20
%
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 0.
005
mg/
kg
NO
V
ARI
AN
CP-
3800
M
S-32
0 10
A
CN
PS
A
VF-
5MS
1 A
uto
210
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
Q
uEC
hERS
C
18 A
qua
10
Bo
th
043
Tent
ativ
e d
etec
ted
0
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
YES
Api
320
0QT
10
AC
N
DSP
E Ph
enom
enex
fusio
n 10
A
uto
200
Dai
ly
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch
Batc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch
Batc
h
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
26
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
BR
OM
AC
IL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2.8
Spec
trum
m
atch
(re
vers
ed)
GC
M
SD
IT EI
+
YES
YES
20-1
0.00
0 µg
/kg
YES
Var
ian
Satu
rn
2000
15
A
ceto
ne/P
E/D
CM
N
O
VF-
5-m
s 5
Both
55
0 Q
uarte
rly
048
Con
firm
ed w
ith
seco
nd m
etho
d
8
G
C
MSD
TO
F EI
YES
YES
0.00
5 YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o m
icro
GC
10
A
CN
DB-
5MS
3 Bo
th
150
Dai
ly
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.0
18
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01-0
.05
YES
Agi
lent
120
0 LC
+646
0QQ
Q
10
AC
N
DSP
E YM
C T
riart
C18
2*
100
mm
3µm
5
Both
35
4 D
aily
051
Tent
ativ
e d
etec
ted
0.5
qual
ifier
s G
C
MSD
IT
EI
N
O
NO
YES
varia
n G
CM
S 40
00
10
AC
N
PSA
va
rian
fact
or fo
ur
5 Bo
th
053
Tent
ativ
e d
etec
ted
8
3
SIM
Ions
G
C
MSD
Q
EI
+
NO
N
O
>0.0
5 m
g/kg
YE
S Th
erm
o D
SQ
10
DC
M
Dia
tom
aceo
us
earth
1 Bo
th
400
Ever
y 6
Mon
ths
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
27
BR
OM
OX
INY
L
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2
tran
sitio
ns
LC
MSD
Q
ES
I -
YES
YES
0.01
N
O
Agi
lent
649
0 5
ACN
RP-
C18
10
Bot
h
Dai
ly
002
Con
firm
ed w
ith
seco
nd m
etho
d 9.
8
G
C
MSD
Q
EI
+
YE
S
YES
not
valid
ated
YE
S
AT
5975
10
ACN
SPE
H
P5-M
S
10
Aut
o ap
rox
750
Alw
ays
003
Con
firm
ed w
ith
seco
nd m
etho
d 0.
05
5 2
tran
sitio
ns
LC
Q
-TO
F ES
I +
N
O
NO
YES
Bru
ker
Max
is
10
ACN
PS
A
RSLC
C18
1
Bot
h ap
rox
400
004
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
N
A
NA
LC
M
SD
Q
ES
I -
YES
NO
N
A
NO
Agi
lent
646
0,
1290
HPL
C
10
EtO
Ac
Non
e W
ater
s, H
SS T
3,
150
x 2.
1mm
2
Bot
h 50
0 Ea
ch B
atch
006
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
<
2 0
2 tr
ansi
tions
LC
M
SD
Q
ES
I -
YES
YES
>0.
010
mg/
kg
NO
W
ater
s qu
attr
o pr
emie
r 15
ACN
N
one
BEH
C18
10
Bot
h
008
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
1
2
tran
sitio
ns
+ac
cura
te
mas
s LC
M
SD
Q
-TRAP
ESI
- YE
S
NO
0.
01
NO
Q
Trap
550
0 10
ACN
N
one
reve
rsed
pha
se
3 Aut
o 30
0 Ea
ch B
atch
009
Tent
ativ
e de
tect
ed
2 tr
ansi
tions
LC
Q
ESI
- N
O
NO
NO
API
4000
10
ACN
D
SPE
Syn
ergi
e Fu
sion
RP8
0A
8 M
anua
l 40
Sch
edul
ed
MRM
M
etho
d al
so u
sed
for
quan
tific
atio
n
010
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
2
tran
sitio
ns
LC
MSD
Q
ES
I +
N
O
YES
0.01
N
O
ABI4
000
10
ACN
N
O
C18
55
Bot
h ap
rox
580
Alw
ays
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
0.
2
2 tr
ansi
tions
G
C
MSD
Q
EI
+
YE
S
YES
0.01
YE
S
HP5
975C
10
ACN
D
SPE
H
P5M
S
10
Bot
h ap
rox
1000
Alw
ays
011
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
N
A
NA
NA
GC
MSD
Q
EI
+
N
O
NO
N
A
YES
5790
msd
10
ACN
PS
A
HP-
5MS
20
Aut
o 60
0 ap
rox
0-1
014
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
±
2.5%
2 tr
ansi
tions
LC
M
SD
Q
ES
I -
YES
YES
0.01
0 m
g/kg
YE
S
Wat
ers-
TQD
15
ACN
PS
A
UPL
C-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atch
015
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
N
A
NA
2 tr
ansi
tions
LC
Q
ESI
+
YES
YES
0.01
N
O
6460
10
ACN
PS
A
C18
-XB
2 Bot
h 44
0
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
28
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
BR
OM
OX
INY
L
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
017
Tent
ativ
e de
tect
ed
G
C
MSD
TO
F EI
NO
N
O
YE
S
LECO
PEG
ASU
S
15
Ace
tone
/PE/
DCM
N
O
DB-5
1
Bot
h
018
Tent
ativ
e de
tect
ed
RT
lock
ing
2
tran
sitio
ns
GC
MSD
Q
EI
+
YE
S
YES
0.01
-0.0
5 m
g/kg
YE
S
Agi
lent
MSD
59
75B
10
ACN
PS
A
HP5
10
Bot
h >
600
Alw
ays
019
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
3
2
tran
sitio
ns
LC
MSD
Q
ES
I -
YES
YES
10
NO
Agi
lent
649
0 15
ACN
PS
A
C18
5
Aut
o
021
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
15
2 tr
ansi
tions
LC
M
SD
Q
ES
I -
YES
YES
0.01
N
O
HPL
C A
gile
nt
1100
, M
S A
PI
3000
10
ACN
D
SPE
(PS
A,
MgS
O4)
C18
3µ
50x2
mm
10
Bot
h 55
0 Alw
ays
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
IT
ES
I -
YES
YES
0.01
N
O
10
ACN
Bot
h
Each
Bat
ch
024
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
0.
1
2 x
MRM
LC
M
SD
Q
ES
I -
YES
YES
0.01
N
O
AB S
ciex
API
40
00
10
ACN
PS
A
Phen
omen
ex C
18
10
Bot
h 50
0 D
aily
025
Con
firm
ed w
ith
seco
nd m
etho
d 0.
04
1.0
isot
ope
LC
MSD
O
rbitr
ap
ESI
- N
O
NO
0.
01-0
.1
YES
Exac
tive
10
ACN
N
one
C18
Atla
ntis
T3
5 Bot
h 57
0 Ea
ch B
atch
Con
firm
ed w
ith
seco
nd m
etho
d N
A
776
spec
trum
G
C
MSD
TO
F EI
+
YE
S
YES
0.01
-0.1
YE
S L
eco
Pega
sus
IV 1
0 ACN
D
SPE
(PS
A)
RTX
-CL
pest
10
Aut
o 55
7 Ea
ch B
atch
026
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
<
0.5%
2.
5
GC
MSD
io
n tr
ap
EI
YE
S
YES
0.01
YE
S
Trap
400
0 -
Var
ian
10
ACN
D
SPE
5%
1
µL
Aut
o 45
0 Ev
ery
Wee
k
028
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
27
3.7>
78.9
, 27
5.4>
81.0
LC
M
SD
Q
ES
I -
YES
YES L
OQ
:2 p
pb
NO
LC
: Agi
lent
12
00,
MS:
API
40
00 Q
TRAP
10
ACN
Q
uEChE
RS
with
out
PSA
Sup
elco
Dis
cove
ry
C18
, 15
0 m
m x
2.
1 m
m,
5 µm
2
Aut
o
030
Tent
ativ
e de
tect
ed
LC
Q
ESI
+
YES
YES
0.02
N
O
Var
ian
320
15
ACN
C18
10
Aut
o 15
0 Ea
ch B
atch
031
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
2
tran
sitio
ns
LC
MS/M
S
Q
ESI
- YE
S
YES
0.00
5-0.
04
µg/m
l N
O
UPL
C-M
SM
S
(Wat
ers
Aqu
ity
UPL
C s
yste
m,
API
500
0 Tr
ipel
quad
ropo
l, Sci
ex
5 Et
OAc
Filte
r H
SS T
3 2
Bot
h 25
0 Ea
ch B
atch
032
Tent
ativ
e de
tect
ed
0
2 tr
ansi
tions
LC
M
SD
Q
ES
I -
YES
YES
0.01
N
O
Wat
ers
Acq
uity
TQ
D
10
Met
hano
l Fi
lter
C18
6
Aut
o 15
0 Alw
ays
034
Con
firm
ed w
ith
seco
nd m
etho
d
fu
ll sc
an
GC
MSD
Q
EI
+
N
O
NO
YES
Agi
lent
597
3 M
SD
10
ACN
D
SPE
(P
SA/M
gSO
4)
HP-
5MS
10
Bot
h 95
0
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
29
BR
OM
OX
INY
L
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
037
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
2
tran
sitio
ns
LC
MS/M
S
Q
ESI
- YE
S
YES
0.01
0 N
O
4000
QTR
AP
10
ACN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
Alw
ays
038
Tent
ativ
e de
tect
ed
Non
e N
one
2 tr
ansi
tions
LC
M
SD
Q
ES
I -
NO
N
O
N
O
API
400
0 10
ACN
D
SPE
W
ater
s-C18
2,
1x50
mm
x1,7
‚µm
5
Aut
o 60
0 Ev
ery
Wee
k
039
Tent
ativ
e de
tect
ed
G
C
MSD
Q
EI
+
N
O
NO
YES
HP5
973
MSD
10
ACN
D
SPE
H
P-5M
SI
20
Bot
h 62
4 N
o st
anda
rd
used
040
Con
firm
ed w
ith
seco
nd m
etho
d 10
3
LC
TOF
ESI
- N
O
NO
YES
Agi
lent
623
0 10
ACN
N
one
Eclip
se C
18
3 Aut
o ap
rox
500
041
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
2.
5%
2
tran
sitio
ns
LC
MSD
Q
ES
I -
YES
YES
0.00
5 m
g/kg
N
O
AG
ILEN
T
G-6
410A
10
ACN
PS
A
ZO
RBAX-E
CLI
PSE
XD
B-C
8 80
Aut
o 14
3
042
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
2
tran
sitio
ns
LC
MSD
Q
ES
I -
YES
YES
N
O
API
400
0 10
ACN
Q
uEChE
RS
C18
Aqu
a 10
Bot
h
043
Tent
ativ
e de
tect
ed
0 0
2 tr
ansi
tions
LC
M
SD
Q
ES
I -
YES
YES
0.01
0 YE
S
Api
320
0QT
10
ACN
D
SPE
Ph
enom
enex
fus
ion
10
Aut
o 20
0 D
aily
045
Tent
ativ
e de
tect
ed
1 1
unit
G
C
MSD
Q
EI
YES
NO
0.
01 p
pm
YES
Agi
lent
597
3 10
ACN
PS
A
HP
5 M
S U
I 2
Aut
o 92
3 Ea
ch B
atch
047
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
2.
4
2 tr
ansi
tions
+
ion
ratio
LC
M
SD
Q
ES
I -
NO
N
O
5-10
00
µg/k
g N
O
Wat
ers
Qua
ttro
Pr
emie
r XE
15
Ace
tone
/PE/
DCM
N
O
Allt
ima
C18
(1
50x3
mm
i.d.
) 5
Bot
h 27
Ea
ch B
atch
048
Con
firm
ed w
ith
seco
nd m
etho
d 0.
9
LC
M
SD
Q
ES
I -
YES
YES
0.00
5 N
O
Agi
lent
641
0 10
ACN
D
SPE
(PSA)
Luna
C18
5
Bot
h 35
0 D
aily
049
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
0
2
tran
sitio
ns
LC
Q
ES
I +
YE
S
YES
N
O
Wat
ers
XEV
O
TQ M
S
10
ACN
BEH
C18
1,7
µm
3 Bot
h 60
D
aily
050
Fully
iden
tifie
d (S
AN
CO
/124
95/2
011
p.74
-80)
-0
.016
2 tr
ansi
tions
LC
M
SD
Q
ES
I -
YES
YES 0
.01-
0.05
YE
S
Agi
lent
120
0 LC
+64
60Q
10
ACN
D
SPE
YM
C T
riar
t C18
2*
100
mm
3µm
5
Bot
h 7
Dai
ly
051
Tent
ativ
e de
tect
ed
0.
5 qu
alifi
ers
GC
MSD
IT
EI
NO
N
O
YE
S
varian
GCM
S
4000
10
ACN
PS
A
varian
fac
tor
four
5
Bot
h
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
30
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
CA
DU
SA
FOS
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
6.8
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Ther
mo
TSQ
Q
uant
um X
LS
10
EtO
Ac
Non
e Th
erm
o TG
-5SI
LMS,
30
m*0
.25m
m*
0.25
um
2 A
uto
500
Each
Ba
tch
Con
firm
ed w
ith
seco
nd m
etho
d
1.2
0.4
LC
M
SD
TOF
ESI
+ N
O
NO
N
A
YES
Bruk
er M
axis
10
EtO
Ac
Non
e A
ccla
im R
SLC
120
C
18, 2
,1*1
00 m
m
1 Bo
th
1000
Ea
ch B
atc
h
006
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
<2
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.010
m
g/kg
N
O
Wa
ters
qua
ttro
prem
ier
15
AC
N
Non
e BE
H C
18
3 Bo
th
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Agi
lent
68
90/5
973
10
AC
N
DSP
E HP
-5M
S 2
Man
ual
183
Each
Ba
tch
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
009
Tent
ativ
e d
etec
ted
36
2 tra
nsiti
ons
LC
Q
ES
I +
NO
N
O
N
O
API
4000
10
A
CN
D
SPE
Syne
rgie
Fus
ion
RP80
A
8 M
anua
l 25
0
Sche
dul
ed
MRM
M
etho
d
also
use
d
for
qua
ntifi
catio
n
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
5.0
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
M
etha
nol
NO
C
18
5 Bo
th
211
Alw
ays
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
31
CA
DU
SA
FOS
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S 0.
01
NO
70
00B
10
AC
N
PSA
D
B-5M
S UI
2
Both
44
0
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
EI
+
NO
YE
S 0.
010
NO
G
C-M
S/M
S (A
gile
nt)
15
AC
N
QuE
ChE
RS
DB
5MS
1 Bo
th
130
Alw
ays
017
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
TO
F EI
YES
NO
YES
LEC
O P
EGA
SUS
15
Ace
tone
/PE/
DC
M
NO
D
B-5
1 Bo
th
018
Tent
ativ
e d
etec
ted
RT
lo
ckin
g
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01 -
0.05
m
g/kg
YE
S A
gile
nt M
SD
5975
B 10
A
CN
PS
A
HP5
10
Both
>
600
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 10
N
O
Agi
lent
689
0 15
A
ceto
ne/P
E/D
CM
N
one
95%
met
hyl 5
%
phen
yl si
loxa
ne
2 A
uto
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
YES
YES
0.01
N
O
agile
nt
10
AC
N
DSP
E HP
5MS
1
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, MS
API
30
00
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
022
Tent
ativ
e d
etec
ted
0.
5 0.
05
LC
M
SD
TOF
ESI
+ YE
S YE
S
YES
LCT
PREM
IER
XE
15
MIN
I LUK
E N
O
C-1
8 7
Aut
o 34
3 Ev
ery
Da
y
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
Q
ESI
+ YE
S YE
S 0.
01
NO
A
PI 5
500
10
AC
N
Pu
rsui
t XRs
Ultr
a
3 Bo
th
250
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
3
mas
ses
GC
M
SD
IT EI
+
YES
YES
0.01
YE
S V
aria
n Sa
turn
20
00
10
AC
N
PSA
V
acto
rFou
r 5 M
S 5
Aut
o 50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.2
2 -0
.05
isoto
pe, 2
ions
<
5ppm
LC
M
SD
Orb
itra
p
ESI
+ N
O
NO
0.
01-0
.1
YES
Exac
tive
10
AC
N
Non
e C
18 A
tlant
is T3
5
Both
57
0 Ea
ch B
atc
h
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
92
5 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 0.
5 %
2.
5
GC
M
SD
ion
trap
EI
YES
YES
0.01
YE
S Tr
ap 4
000
- V
aria
n 10
A
CN
D
SPE
5%
1 µL
A
uto
450
Ever
y W
eek
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
32
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
CA
DU
SA
FOS
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
4 0.
7 3
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Var
ian
3800
G
C +
320
-MS
10
AC
N
DSP
E w
ith P
SA
VF-
1ms
4 Bo
th
302
Each
Ba
tch
028
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
271.
1>21
5.0,
27
1.1>
159.
0 LC
M
SD
Q
ESI
+ YE
S YE
S LO
Q: 2
pp
b
NO
LC
: Agi
lent
120
0,
MS:
API
400
0 Q
TRA
P 10
A
CN
Q
uEC
hERS
w
ithou
t PSA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2
.1 m
m, 5
µm
2
Aut
o
029
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
GC
M
S/M
S Q
EI
+
YES
YES
0.00
5-0.
64
µg/m
l N
O
Wa
ters
Qua
ttro
Mic
ro G
C
10
EtO
Ac
Filte
r Rx
i-5sil
MS/
inte
gra-
guar
d R
este
k 10
Bo
th
373
Each
Ba
tch
032
Tent
ativ
e d
etec
ted
0
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
W
ate
rs A
cqui
ty
TQD
10
M
etha
nol
Filte
r C
18
6 A
uto
150
Alw
ays
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3.5
m
in 3
ions
G
C
MSD
Q
EI
+
YES
NO
0.
01
YES
Agi
lent
GC
-MSD
78
90A
/597
5c
10
AC
N
PSA
, C18
HP
-5M
S 1
Aut
o 92
7
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
Qua
ttro
Prem
ier
10
AC
N
DSP
E (P
SA/M
gSO
4)
RP-1
8 en
dca
pped
5
Both
18
6 Ea
ch B
atc
h
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S
10
A
CN
5
Aut
o 24
0
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
Non
e N
one
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
D
SPE
Wa
ters
-C18
2,
1x50
mm
x1,7
‚µm
5
Aut
o 60
0 Ev
ery
Wee
k
039
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
271.
1->1
59.0
, 27
1.1-
>130
.9
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
641
0B
10
AC
N
DSP
E C
18
2 Bo
th
187
Each
Ba
tch
040
Con
firm
ed w
ith
seco
nd m
etho
d
G
C
MSD
Q
EI
NO
N
O
YE
S A
gile
nt 5
973
30
EtO
Ac
HPG
PC
DB-
5MS
2 A
uto
apro
x 50
0
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5%
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 0.
005
mg/
kg
NO
V
ARI
AN
CP-
3800
M
S-32
0 10
A
CN
PS
A
VF-
5MS
1 A
uto
210
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
33
CA
DU
SA
FOS
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
Q
uEC
hERS
C
18 A
qua
10
Bo
th
043
Tent
ativ
e d
etec
ted
0
0 sc
an
GC
M
SD
IT EI
YES
YES
0.01
0 YE
S V
aria
n Sa
turn
40
00
10
AC
N
DSP
E V
aria
n V
F 1
Aut
o 26
0 D
aily
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
G
C
MSD
Q
EI
+
YES
YES
N
O
Ther
mo
TSQ
Q
uant
um G
C
10
Ace
tone
/PE/
DC
M
Na2
SO4
RXi-5
SIL
MS
1 Bo
th
199
Each
Ba
tch
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
Spec
trum
m
atch
(re
vers
ed)
GC
M
SD
IT EI
+
YES
YES
20-1
0.00
0 µg
/kg
YES
Var
ian
Satu
rn
2000
15
A
ceto
ne/P
E/D
CM
N
O
VF-
5-m
s 5
Both
55
0 Q
uarte
rly
048
Con
firm
ed w
ith
seco
nd m
etho
d
5
G
C
MSD
TO
F EI
YES
YES
0.00
5 YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o m
icro
GC
10
A
CN
DB-
5MS
3 Bo
th
150
Dai
ly
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.02
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
-0.0
5 YE
S A
gile
nt 1
200
LC+6
460Q
10
A
CN
D
SPE
YMC
Tria
rt C
18
2*10
0 m
m 3
µm
5 Bo
th
354
Dai
ly
053
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2
3 SI
M Io
ns
GC
M
SD
Q
EI
+ N
O
NO
>0
.05
mg/
kg
YES
Ther
mo
DSQ
10
D
CM
D
iato
mac
eous
ea
rth
1
Both
40
0 Ev
ery
6 M
onth
s
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2
2 M
RM
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.005
m
g/kg
N
O
API
4000
10
A
CN
PS
A
10
Bo
th
180
Ever
y M
onth
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
34
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
DIF
LUB
ENZ
UR
ON
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library (pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
- YE
S YE
S 0.
01
NO
A
gile
nt 6
460,
12
90HP
LC
10
EtO
Ac
Non
e W
ate
rs, H
SS T
3,
150
x 2.
1mm
2
Aut
o 50
0 Ea
ch B
atc
h
Con
firm
ed w
ith
seco
nd m
etho
d
-2.4
0
LC
M
SD
TOF
ESI
+ N
O
NO
N
A
YES
Bruk
er M
axis
10
EtO
Ac
Non
e A
ccla
im R
SLC
120
C
18, 2
,1*1
00 m
m
1 Bo
th
1000
Ea
ch B
atc
h
006
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
<2
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.010
m
g/kg
N
O
Wa
ters
qua
ttro
prem
ier
15
AC
N
Non
e BE
H C
18
3 Bo
th
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
LC
M
SD
Q
ESI
- YE
S YE
S 0.
01
NO
A
gile
nt 6
410
10
AC
N
DSP
E Ec
lipse
XD
B-C
18
4 M
anua
l 13
9 Ea
ch B
atc
h
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
009
Tent
ativ
e d
etec
ted
35
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
0.01
(=RL
) N
O
API
4000
10
A
CN
D
SPE
Syne
rgie
Fus
ion
RP80
A
8 M
anua
l 25
0
Sche
dul
ed
MRM
M
etho
d
also
use
d
for
qua
ntifi
catio
n
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
ABI
4000
10
A
CN
N
O
C18
55
Bo
th
apro
x 58
0 A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
LC
M
SD
Q-T
RAP
ESI
+ YE
S YE
S 0.
01
NO
32
00q
trap
10
A
CN
PS
A
T-3
5 M
anua
l 17
0 1
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
M
etha
nol
NO
C
18
5 Bo
th
211
Alw
ays
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
- YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
35
DIF
LUB
ENZ
UR
ON
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library (pesticides ONLY)
Standard Solution Frequency
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
0.01
N
O
6460
10
A
CN
PS
A
C18
-XB
2 Bo
th
440
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
017
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
TO
F EI
YES
YES
YE
S LE
CO
PEG
ASU
S 15
A
ceto
ne/P
E/D
CM
N
O
DB-
5 1
Both
018
Tent
ativ
e d
etec
ted
5
5 ac
cura
te
mas
s LC
O
rbitr
ap
O
rbitr
ap
ES
I +
YES
YES
0.01
- 0.
05
mg/
kg
YES
Ther
mo
Exac
tive
10
AC
N
PSA
C
18
5 Bo
th
120
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
LC
MSD
Q
ES
I -
YES
YES
10
NO
A
gile
nt 6
490
15
AC
N
PSA
C
18
5 A
uto
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
bSci
ex
10
AC
N
DSP
E C
18
5 A
uto
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E (P
SA, M
gSO
4)
C18
3µ
50x2
mm
10
Bo
th
550
Alw
ays
022
Tent
ativ
e d
etec
ted
0.
5 0.
05
LC
M
SD
TOF
ESI
+ YE
S YE
S
YES
LCT
PREM
IER
XE
15
MIN
I LUK
E N
O
C-1
8 7
Aut
o 34
3 Ev
ery
Da
y
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
IT ES
I -
YES
YES
0.01
N
O
10
A
CN
Both
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I -
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.1
9 -1
.0
isoto
pe, 2
ions
<
5ppm
LC
M
SD
Orb
itra
p
ESI
+ N
O
NO
0.
01-0
.1
YES
Exac
tive
10
AC
N
Non
e C
18 A
tlant
is T3
5
Both
57
0 Ea
ch B
atc
h
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 2.
5 %
2.
5 tra
nsiti
on 1
an
d 2
LC
M
SD
Q-T
RAP
ESI
+ YE
S YE
S 0.
01
YES
3200
Qtra
p
10
AC
N
DSP
E C
18
50
Aut
o 52
1 Ev
ery
Wee
k
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
4 0.
7 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
V
aria
n Pr
o St
ar +
32
0-M
S 10
A
CN
D
SPE
with
PSA
Re
stek
Ultr
a C
18
10
Both
30
2 Ea
ch B
atc
h
028
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
311.
1>15
8.2,
31
1.1>
141.
2 LC
M
SD
Q
ESI
- YE
S YE
S LO
Q: 2
pp
b
NO
LC
: Agi
lent
120
0,
MS:
API
400
0 Q
TRA
P 10
A
CN
Q
uEC
hERS
w
ithou
t PSA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2.
1 m
m, 5
µm
2
Aut
o
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
36
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
DIF
LUB
ENZ
UR
ON
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library (pesticides ONLY)
Standard Solution Frequency
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I -
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
- YE
S YE
S 0.
005-
0.4
µg/m
l N
O
Wa
ters
Aqu
ity
UPLC
syst
em,
API
500
0 Tr
ipel
quad
ropo
l, Sc
iex
10
EtO
Ac
Filte
r HS
S T3
2
Both
13
Ea
ch B
atc
h
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
Qua
ttro
Prem
ier
10
AC
N
DSP
E (P
SA/M
gSO
4)
RP-1
8 en
dca
pped
5
Both
18
6 Ea
ch B
atc
h
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
- YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
Non
e N
one
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
D
SPE
Wa
ters
-C18
2,
1x50
mm
x1,7
‚µm
5
Aut
o 60
0 Ev
ery
Wee
k
039
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
311.
0->1
58.0
, 31
1.0-
>141
.0
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
641
0B
10
AC
N
DSP
E C
18
2 Bo
th
187
Each
Ba
tch
040
Con
firm
ed w
ith
seco
nd m
etho
d
4 4
LC
TOF
ESI
+ N
O
NO
YES
Agi
lent
623
0 10
A
CN
N
one
Eclip
se C
18
3 A
uto
apro
x 50
0
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2.5%
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.00
5 m
g/kg
N
O
AG
ILEN
T G
-64
10A
10
A
CN
PS
A
ZORB
AX-
ECLI
PSE
XDB-
C8
80
Aut
o 14
3
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I -
YES
YES
N
O
API
400
0 10
A
CN
Q
uEC
hERS
C
18 A
qua
10
Bo
th
043
Tent
ativ
e d
etec
ted
0
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
YES
Api
320
0QT
10
AC
N
DSP
E Ph
enom
enex
fusio
n 10
A
uto
200
Dai
ly
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch B
atc
h
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2.4
2
trans
ition
s +
ion
ratio
LC
M
SD
Q
ESI
- N
O
NO
5-
1000
µg
/kg
NO
W
ate
rs Q
uattr
o Pr
emie
r XE
15
Ace
tone
/PE/
DC
M
NO
A
lltim
a C
18
(150
x3 m
m i.
d.)
5 Bo
th
27
Each
Ba
tch
048
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
005
NO
A
gile
nt 6
410
10
AC
N
DSP
E(PS
A)
Luna
C18
5
Both
35
0 D
aily
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
37
DIF
LUB
ENZ
UR
ON
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library (pesticides ONLY)
Standard Solution Frequency
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o m
icro
GC
10
A
CN
DB-
5MS
3 Bo
th
150
Dai
ly
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.01
9
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
-0.0
5 YE
S A
gile
nt 1
200
LC+6
460Q
10
A
CN
D
SPE
YMC
Tria
rt C
18
2*10
0 m
m 3
µm
5 Bo
th
354
Dai
ly
051
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.05
ABS
ciex
API
200
0 10
A
CN
PS
A
wat
ers A
tlant
is 5
Aut
o 11
7 Ea
ch B
atc
h
053
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
3 SI
M Io
ns
GC
M
SD
Q
EI
+ N
O
NO
>0
.05
mg/
kg
YES
Ther
mo
DSQ
10
D
CM
D
iato
mac
eous
ea
rth
1
Both
40
0 Ev
ery
6 M
onth
s
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 M
RM
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.005
m
g/kg
N
O
API
4000
10
A
CN
PS
A
10
Bo
th
180
Ever
y M
onth
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
38
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
DIN
ICO
NA
ZO
LE
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
5.3
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
+ YE
S N
O
NA
N
O
Agi
lent
646
0,
1290
HPLC
10
Et
OA
c N
one
Wa
ters
, HSS
T3,
150
x
2.1m
m
2 Bo
th
500
Each
Ba
tch
Con
firm
ed w
ith
seco
nd m
etho
d
-0.6
0.
3
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
006
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
<2
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.010
m
g/kg
N
O
Wa
ters
qua
ttro
prem
ier
15
AC
N
Non
e BE
H C
18
3 Bo
th
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons+
accu
rate
mas
s LC
M
SD
Q-T
RAP
ESI
+ YE
S N
O
0.01
N
O
QTr
ap 5
500
10
AC
N
Non
e re
vers
ed p
hase
2.
5 A
uto
300
Each
Ba
tch
009
Con
firm
ed w
ith
seco
nd m
etho
d
21
2
trans
ition
s LC
Q
ESI
+ YE
S YE
S 0.
01 (=
RL)
NO
A
PI55
00
10
AC
N
DSP
E Sy
nerg
ie F
usio
n RP
80A
8
Man
ual
35
Sche
dul
ed
MRM
M
etho
d
also
use
d
for
qua
ntifi
catio
n
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
ABI
4000
10
A
CN
N
O
C18
55
Bo
th
apro
x 58
0 A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
0 N
O
Var
ian
320
50
Ace
tone
L/
L D
B5 ty
pe
8 Bo
th
146
Alw
ays
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
39
DIN
ICO
NA
ZO
LE
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S 0.
01
NO
70
00B
10
AC
N
PSA
D
B-5M
S UI
2
Both
44
0
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
017
Tent
ativ
e d
etec
ted
GC
M
SD
TOF
EI
N
O
NO
YES
LEC
O P
EGA
SUS
15
Ace
tone
/PE/
DC
M
NO
D
B-5
1 Bo
th
018
Tent
ativ
e d
etec
ted
RT
lo
ckin
g
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01 -
0.05
m
g/kg
YE
S A
gile
nt M
SD
5975
B 10
A
CN
PS
A
HP5
10
Both
>
600
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
10
NO
A
gile
nt 6
490
15
AC
N
PSA
C
18
5 A
uto
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
bSci
ex
10
AC
N
DSP
E C
18
5 A
uto
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E (P
SA, M
gSO
4)
C18
3µ
50x2
mm
10
Bo
th
550
Alw
ays
022
Tent
ativ
e d
etec
ted
0.
5 0.
05
LC
M
SD
TOF
ESI
+ YE
S YE
S
YES
LCT
PREM
IER
XE
15
MIN
I LUK
E N
O
C-1
8 7
Aut
o 34
3 Ev
ery
Da
y
023
Con
firm
ed w
ith
seco
nd m
etho
d
G
C
MSD
TO
F
YE
S YE
S 0.
01
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E Ph
enom
enen
x
ZB-5
MS
3 Bo
th
750
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.2
0.
03
isoto
pe, 2
ions
<
5ppm
LC
M
SD
Orb
itra
p
ESI
+ N
O
NO
0.
01-0
.1
YES
Exac
tive
10
AC
N
Non
e C
18 A
tlant
is T3
5
Both
57
0 Ea
ch B
atc
h
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
92
3 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 0.
5 %
2.
5
GC
M
SD
ion
trap
EI
YES
YES
0.01
YE
S Tr
ap 4
000
Var
ian
10
AC
N
DSP
E 5%
1
µL
Aut
o 45
0 Ev
ery
Wee
k
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 0.
7 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
V
aria
n Pr
o St
ar
+320
-MS
10
AC
N
DSP
E w
ith P
SA
Rest
ek U
ltra
C18
10
Bo
th
302
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
40
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
DIN
ICO
NA
ZO
LE
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
028
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
326.
1>70
.1,
328.
1>70
.1
LC
MSD
Q
ES
I +
YES
YES
LOQ
: 8
ppb
N
O
LC: A
gile
nt 1
200,
M
S: A
PI 4
000
QTR
AP
10
AC
N
QuE
ChE
RS
with
out P
SA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2.
1 m
m, 5
µm
2
Aut
o
029
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
NO
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
025-
0.25
µg
/ml
NO
UPLC
-MSM
S (W
ate
rs A
quity
UP
LC sy
stem
, A
PI 5
000
Trip
elqu
adro
pol,
Scie
x
10
EtO
Ac
Filte
r HS
S T3
2
Both
14
1 Ea
ch B
atc
h
032
Tent
ativ
e d
etec
ted
0
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Ther
mo
TSQ
Q
uant
um X
LS
Ultra
10
A
CN
PS
A
Cap
illary
1
Both
15
0 A
lway
s
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.9
min
3 io
ns
GC
M
SD
Q
EI
+ YE
S N
O
0.01
YE
S A
gile
nt G
C-M
SD
7890
A/5
975c
10
A
CN
PS
A, C
18
HP-5
MS
1 A
uto
927
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
Qua
ttro
Prem
ier
10
AC
N
DSP
E (P
SA/M
gSO
4)
RP-1
8 en
dca
pped
5
Both
18
6 Ea
ch B
atc
h
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Tent
ativ
e d
etec
ted
N
one
Non
e 2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
PI 4
000
10
AC
N
DSP
E W
ate
rs-C
18
2,1x
50m
mx1
,7‚µ
m
5 A
uto
600
Ever
y W
eek
039
Tent
ativ
e d
etec
ted
GC
M
SD
Q
EI
+ N
O
NO
YES
HP59
73 M
SD
10
AC
N
DSP
E HP
-5M
SI
20
Both
62
4 N
o st
and
ard
us
ed
040
Tent
ativ
e d
etec
ted
5
4
LC
TO
F ES
I +
NO
N
O
YE
S A
gile
nt 6
230
10
AC
N
Non
e Ec
lipse
C18
3
Aut
o ap
rox
500
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5%
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 0.
005
mg/
kg
NO
V
ARI
AN
CP-
3800
M
S-32
0 10
A
CN
PS
A
VF-
5MS
1 A
uto
210
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
41
DIN
ICO
NA
ZO
LE
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
Q
uEC
hERS
C
18 A
qua
10
Bo
th
043
Tent
ativ
e d
etec
ted
0
0 sc
an
GC
M
SD
IT EI
YES
YES
0.01
0 YE
S V
aria
n Sa
turn
40
00
10
AC
N
DSP
E V
aria
n V
F 1
Aut
o 26
0 D
aily
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch B
atc
h
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons +
io
n ra
tio
LC
MSD
Q
ES
I +
YES
YES
5-10
00
µg/k
g N
O
Wa
ters
Qua
ttro
Prem
ier X
E 15
A
ceto
ne/P
E/D
CM
N
O
Acq
uity
BEH
(1
00x2
.1 m
m i.
d.)
5 Bo
th
230
Each
Ba
tch
048
Con
firm
ed w
ith
seco
nd m
etho
d
6
G
C
MSD
TO
F EI
YES
YES
0.00
5 YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o m
icro
GC
10
A
CN
DB-
5MS
3 Bo
th
150
Dai
ly
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.0
26
Q
ion
ratio
G
C
MSD
Q
EI
+
YES
YES
0.01
-0.0
5 YE
S A
gile
nt
6890
GC
+597
5MS
10
AC
N
DSP
E RE
STEK
-5M
S 50
Bo
th
168
Dai
ly
051
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
0.5
qual
ifier
s G
C
MSD
IT
EI
YE
S YE
S 0.
01
YES
Var
ian
GC
MS
4000
10
A
CN
PS
A
varia
n fa
ctor
four
5
Both
13
0 Ea
ch B
atc
h
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
120
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
05
A
BSci
ex A
PI 2
000
10
AC
N
PSA
w
ater
s Atla
ntis
5 A
uto
117
Each
Ba
tch
053
Tent
ativ
e d
etec
ted
8
3
SIM
Ions
G
C
MSD
Q
EI
+
NO
N
O
>0.0
5 m
g/kg
YE
S Th
erm
o D
SQ
10
DC
M
Dia
tom
aceo
us
earth
1 Bo
th
400
Ever
y 6
Mon
ths
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
42
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
ETH
OX
IQU
IN
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
3.0
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Con
firm
ed w
ith
seco
nd m
etho
d
-1.2
1.
9
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
+ YE
S N
O
NA
N
O
Agi
lent
646
0,
1290
HPLC
10
Et
OA
c N
one
Wa
ters
, HSS
T3,
15
0 x
2.1m
m
2 Bo
th
500
Each
Ba
tch
006
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
<2
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.010
m
g/kg
N
O
Wa
ters
qua
ttro
prem
ier
15
AC
N
Non
e BE
H C
18
10
Both
008
Tent
ativ
e d
etec
ted
2
trans
ition
s LC
M
SD
Q-T
RAP
ESI
+ N
O
NO
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 W
e d
o no
t ha
ve a
st
and
ard
009
Tent
ativ
e d
etec
ted
2
trans
ition
s G
C
MSD
Q
EI
+
NO
N
O
N
O
Ther
mo
TSQ
Q
uant
um
10
AC
N
DSP
E TG
-5M
S 30
m
2 M
anua
l 80
Ea
ch B
atc
h
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.3
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
M
etha
nol
NO
C
18
5 Bo
th
211
Alw
ays
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±0.5
%
GC
M
SD
Q
EI
+ YE
S YE
S 0.
010
mg/
kg
YES
Agi
lent
789
0-59
75C
15
A
CN
PS
A
HP-5
MS
10
Aut
o 21
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S 0.
01
NO
70
00B
10
AC
N
PSA
D
B-5M
S UI
2
Both
44
0
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
43
ETH
OX
IQU
IN
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
017
Tent
ativ
e d
etec
ted
GC
M
SD
TOF
EI
N
O
NO
YES
LEC
O P
EGA
SUS
15
Ace
tone
/PE/
DC
M
NO
D
B-5
1 Bo
th
018
Tent
ativ
e d
etec
ted
RT
lo
ckin
g
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01 -
0.05
m
g/kg
YE
S A
gile
nt M
SD
5975
B 10
A
CN
PS
A
HP5
10
Both
>
600
Alw
ays
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
YES
YES
0.01
N
O
agile
nt
10
AC
N
DSP
E HP
5MS
1
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, MS
API
30
00
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
025
Con
firm
ed w
ith
seco
nd m
etho
d
NA
<
5 iso
tope
, 2 io
ns
< 5p
pm
LC
MSD
O
rbitr
ap
ES
I +
NO
N
O
0.01
-0.1
YE
S Ex
activ
e 10
A
CN
N
one
C18
Atla
ntis
T3
5 Bo
th
570
Each
Ba
tch
Con
firm
ed w
ith
seco
nd m
etho
d
< 20
85
4 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 0.
5 %
2.
5
GC
M
SD
ion
trap
EI
YES
YES
0.01
YE
S Tr
ap 4
000
- V
aria
n 10
A
CN
D
SPE
5%
1 µL
A
uto
450
Ever
y W
eek
028
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
Mat
ch w
ith
anal
ytic
al
stan
dar
d
(Ma
tch
819,
ra
nge
0-10
00)
GC
M
SD
TOF
EI
YE
S YE
S LO
Q: 1
0 pp
b
YES
GC
xGC
-TO
F M
S Pe
gasu
s 4D
10
A
CN
Q
uEC
hERS
w
ithou
t PSA
DB5
-MS
(30
m x
0,2
5 m
m x
0,2
5 µm
) in
the
1st D
imen
sion,
BP
X-50
(2 m
x 0
,1
mm
x 0
,1 µ
m) i
n th
e 2n
d D
imen
sion
10
Aut
o
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
GC
M
S/M
S Q
EI
+
YES
YES
0.02
5-0.
25
µg/m
l N
O
Wa
ters
Qua
ttro
Mic
ro G
C
10
EtO
Ac
Filte
r Rx
i-5sil
MS/
inte
gra-
guar
d R
este
k 10
Bo
th
141
Each
Ba
tch
034
Tent
ativ
e d
etec
ted
fu
ll sc
an
GC
M
SD
Q
EI
+ N
O
NO
YES
Agi
lent
597
3 M
SD
10
AC
N
DSP
E (P
SA/M
gSO
4)
HP-5
MS
10
Both
95
0
035
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
NO
N
O
YE
S A
gile
nt 6
890N
10
A
CN
D
SPE
DB-
5 2
Aut
o
038
Tent
ativ
e d
etec
ted
N
one
Non
e 2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
PI 4
000
10
AC
N
DSP
E W
ate
rs-C
18
2,1x
50m
mx1
,7‚µ
m
5 A
uto
600
Ever
y W
eek
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
44
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
ETH
OX
IQU
IN
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
039
Tent
ativ
e d
etec
ted
GC
M
SD
Q
EI
+ N
O
NO
YES
HP59
73 M
SD
10
AC
N
DSP
E HP
-5M
SI
20
Both
62
4 N
o st
and
ard
us
ed
040
Con
firm
ed w
ith
seco
nd m
etho
d
1 4
LC
TOF
ESI
+ N
O
NO
YES
Agi
lent
623
0 10
A
CN
N
one
Eclip
se C
18
3 A
uto
apro
x 50
0
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5%
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 0.
005
mg/
kg
NO
V
ARI
AN
CP-
3800
M
S-32
0 10
A
CN
PS
A
VF-
5MS
1 A
uto
210
043
Tent
ativ
e d
etec
ted
0
0 sc
an
GC
M
SD
IT EI
YES
YES
0.01
0 YE
S V
aria
n Sa
turn
40
00
10
AC
N
DSP
E V
aria
n V
F 1
Aut
o 26
0 D
aily
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
G
C
MSD
Q
EI
+
YES
YES
N
O
Ther
mo
TSQ
Q
uant
um G
C
10
Ace
tone
/PE/
DC
M
Na2
SO4
RXi-5
SIL
MS
1 Bo
th
199
Each
Ba
tch
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.4
Sp
ectru
m
mat
ch
(reve
rsed
) G
C
MSD
IT
EI
+ YE
S YE
S 20
-10.
000
µg/k
g YE
S V
aria
n Sa
turn
20
00
15
Ace
tone
/PE/
DC
M
NO
V
F-5-
ms
5 Bo
th
550
Qua
rterly
048
Con
firm
ed w
ith
seco
nd m
etho
d
4
G
C
MSD
TO
F EI
YES
YES
0.01
YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o m
icro
GC
10
A
CN
DB-
5MS
3 Bo
th
150
Dai
ly
051
Tent
ativ
e d
etec
ted
0.5
qual
ifier
s G
C
MSD
IT
EI
N
O
NO
YES
varia
n G
CM
S 40
00
10
AC
N
PSA
va
rian
fact
or fo
ur
5 Bo
th
053
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2
2 M
RM
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.005
m
g/kg
N
O
API
4000
10
A
CN
PS
A
10
Bo
th
180
Ever
y M
onth
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
45
ETR
IMFO
S
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
1.6
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Con
firm
ed w
ith
seco
nd m
etho
d
0.6
0.8
LC
M
SD
TOF
ESI
+ N
O
NO
N
A
YES
Bruk
er M
axis
10
EtO
Ac
Non
e A
ccla
im R
SLC
120
C
18, 2
,1*1
00 m
m
1 Bo
th
1000
Ea
ch B
atc
h
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
460,
12
90HP
LC
10
EtO
Ac
Non
e W
ate
rs, H
SS T
3,
150
x 2.
1mm
2
Both
50
0 Ea
ch B
atc
h
006
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
<2
<1
3 d
iagn
ostic
io
ns
GC
M
SD
Q
EI
+ YE
S YE
S >0
.010
m
g/kg
YE
S Tr
ace
DSQ
15
A
CN
PS
A/C
18
DB5
MS
0.8
Both
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Agi
lent
68
90/5
973
10
AC
N
DSP
E HP
-5M
S 2
Man
ual
183
Each
Ba
tch
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
009
Tent
ativ
e d
etec
ted
2
trans
ition
s G
C
MSD
Q
EI
+
NO
N
O
N
O
Ther
mo
TSQ
Q
uant
um
10
AC
N
DSP
E TG
-5M
S 30
m
2 M
anua
l 18
0 Ea
ch B
atc
h
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1.3
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
0 N
O
Var
ian
320
50
Ace
tone
L/
L D
B5 ty
pe
8 Bo
th
146
Alw
ays
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±0.5
%
GC
M
SD
Q
EI
+ YE
S YE
S 0.
010
mg/
kg
YES
Agi
lent
78
90-5
975C
15
A
CN
PS
A
HP-5
MS
10
Aut
o 21
1 Ea
ch B
atc
h
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
46
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
ETR
IMFO
S
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S 0.
01
NO
70
00B
10
AC
N
PSA
D
B-5M
S UI
2
Both
44
0
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
EI
+
NO
YE
S 0.
010
NO
G
C-M
S/M
S (A
gile
nt)
15
AC
N
QuE
ChE
RS
DB
5MS
1 Bo
th
130
Alw
ays
017
Tent
ativ
e d
etec
ted
GC
M
SD
TOF
EI
N
O
NO
YES
LEC
O P
EGA
SUS
15
Ace
tone
/PE/
DC
M
NO
D
B-5
1 Bo
th
018
Tent
ativ
e d
etec
ted
RT
lo
ckin
g
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01 -
0.05
m
g/kg
YE
S A
gile
nt M
SD
5975
B 10
A
CN
PS
A
HP5
10
Both
>
600
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 10
N
O
Agi
lent
689
0 15
A
ceto
ne/P
E/D
CM
N
one
95%
met
hyl 5
%
phen
yl si
loxa
ne
2 A
uto
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
YES
YES
0.01
N
O
agile
nt
10
AC
N
DSP
E HP
5MS
1
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
022
Tent
ativ
e d
etec
ted
0.
5 0.
05
LC
M
SD
TOF
ESI
+ YE
S YE
S
YES
LCT
PREM
IER
XE
15
MIN
I LUK
E N
O
C-1
8 7
Aut
o 34
3 Ev
ery
Da
y
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
Q
ESI
+ YE
S YE
S 0.
01
NO
A
PI 5
500
10
AC
N
Pu
rsui
t XRs
Ultr
a
3 Bo
th
250
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
3
mas
ses
GC
M
SD
IT EI
+
YES
YES
0.01
YE
S V
aria
n Sa
turn
20
00
10
AC
N
PSA
V
acto
rFou
r 5 M
S 5
Aut
o 50
0 D
aily
025
Con
firm
ed w
ith
seco
nd m
etho
d
-0.2
3 -0
.04
isoto
pe
LC
MSD
O
rbitr
ap
ES
I +
NO
N
O
0.01
-0.1
YE
S Ex
activ
e 10
A
CN
N
one
C18
Atla
ntis
T3
5 Bo
th
570
Each
Ba
tch
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
94
3 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 0.
5 %
2.
5
GC
M
SD
ion
trap
EI
YES
YES
0.01
YE
S Tr
ap 4
000
- V
aria
n 10
A
CN
D
SPE
5%
1 µL
A
uto
450
Ever
y W
eek
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2
G
C
FPD
YES
YES
0.01
N
O
Var
ian
3800
GC
10
A
CN
D
SPE
with
PSA
Rt
x-O
PP
1 Bo
th
302
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
47
ETR
IMFO
S
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
028
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
Mat
ch w
ith
anal
ytic
al
stan
dar
d
(Ma
tch
927,
ra
nge
0-10
00)
GC
M
SD
TOF
EI
YE
S YE
S LO
Q: 2
pp
b
YES
GC
xGC
-TO
F M
S Pe
gasu
s 4D
10
A
CN
Q
uEC
hERS
w
ithou
t PSA
DB5
-MS
(30
m x
0,2
5 m
m x
0,2
5 µm
) in
the
1st D
imen
sion,
BP
X-50
(2 m
x 0
,1
mm
x 0
,1 µ
m) i
n th
e 2n
d D
imen
sion
10
Aut
o
029
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
IT
EI
+ YE
S YE
S 0.
01
YES
10
A
CN
N
O
DB-
5MS
5 Bo
th
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
005-
0.4
µg/m
l N
O
UPLC
-MSM
S (W
ate
rs A
quity
UP
LC sy
stem
, A
PI 5
000
Trip
elqu
adro
pol,
Scie
x
10
EtO
Ac
Filte
r HS
S T3
2
Both
37
3 Ea
ch B
atc
h
032
Tent
ativ
e d
etec
ted
0
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Ther
mo
TSQ
Q
uant
um X
LS
Ultra
10
A
CN
PS
A
Cap
illary
1
Both
15
0 A
lway
s
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.5
min
3 io
ns
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01
YES
Agi
lent
GC
-MSD
78
90A
/597
5c
10
AC
N
PSA
, C18
HP
-5M
S 1
Aut
o 92
7
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o M
icro
10
A
CN
D
SPE
(PSA
/MgS
O4)
HP
-5M
S 5
Both
11
0 Ea
ch B
atc
h
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Tent
ativ
e d
etec
ted
N
one
Non
e 2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
PI 4
000
10
AC
N
DSP
E W
ate
rs-C
18
2,1x
50m
mx1
,7‚µ
m
5 A
uto
600
Ever
y W
eek
039
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5973
MSD
10
A
CN
D
SPE
HP-5
MSI
20
Bo
th
113
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
48
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
ETR
IMFO
S
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
040
Con
firm
ed w
ith
seco
nd m
etho
d
G
C
MSD
Q
EI
NO
N
O
YE
S A
gile
nt 5
973
30
EtO
Ac
HPG
PC
DB-
5MS
2 A
uto
apro
x 50
0
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5%
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 0.
005
mg/
kg
NO
V
ARI
AN
CP-
3800
M
S-32
0 10
A
CN
PS
A
VF-
5MS
1 A
uto
210
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S
NO
TS
Q Q
uant
um
10
AC
N
QuE
ChE
RS
VF
5 M
S 3
Both
043
Tent
ativ
e d
etec
ted
0
0 sc
an
GC
M
SD
IT EI
YES
YES
0.01
0 YE
S V
aria
n Sa
turn
40
00
10
AC
N
DSP
E V
aria
n V
F 1
Aut
o 26
0 D
aily
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
G
C
MSD
Q
EI
+
YES
YES
N
O
Ther
mo
TSQ
Q
uant
um G
C
10
Ace
tone
/PE/
DC
M
Na2
SO4
RXi-5
SIL
MS
1 Bo
th
199
Each
Ba
tch
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.4
Sp
ectru
m
mat
ch
(reve
rsed
) G
C
MSD
IT
EI
+ YE
S YE
S 20
-10.
000
µg/k
g YE
S V
aria
n Sa
turn
20
00
15
Ace
tone
/PE/
DC
M
NO
V
F-5-
ms
5 Bo
th
550
Qua
rterly
048
Con
firm
ed w
ith
seco
nd m
etho
d
3
G
C
MSD
TO
F EI
YES
YES
0.00
5 YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o m
icro
GC
10
A
CN
DB-
5MS
3 Bo
th
150
Dai
ly
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.0
39
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01-0
.05
YES
Agi
lent
120
0 LC
+646
0QQ
Q
10
AC
N
DSP
E YM
C T
riart
C18
2*
100
mm
3µm
5
Both
35
4 D
aily
051
Tent
ativ
e d
etec
ted
0.5
qual
ifier
s G
C
MSD
IT
EI
N
O
NO
YES
varia
n G
CM
S 40
00
10
AC
N
PSA
va
rian
fact
or fo
ur
5 Bo
th
053
Tent
ativ
e d
etec
ted
5
3
SIM
Ions
G
C
MSD
Q
EI
+
NO
N
O
>0.0
5 m
g/kg
YE
S Th
erm
o D
SQ
10
DC
M
Dia
tom
aceo
us
earth
1 Bo
th
400
Ever
y 6
Mon
ths
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
49
FEN
PR
OP
IDIN
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
+
YES
NO
0.
01
YES
Agi
lent
597
3 in
ert
5 A
CN
HP-5
MSU
I 5
Both
Dai
ly
002
Con
firm
ed w
ith
seco
nd m
etho
d
0.2
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Con
firm
ed w
ith
seco
nd m
etho
d
1.2
1
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
+ YE
S N
O
NA
N
O
Agi
lent
646
0,
1290
HPLC
10
Et
OA
c N
one
Wa
ters
, HSS
T3,
15
0 x
2.1m
m
2 Bo
th
500
Each
Ba
tch
006
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
<2
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.010
m
g/kg
N
O
Wa
ters
qua
ttro
prem
ier
15
AC
N
Non
e BE
H C
18
3 Bo
th
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Agi
lent
68
90/5
973
10
AC
N
DSP
E HP
-5M
S 2
Man
ual
183
Each
Ba
tch
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
009
Tent
ativ
e d
etec
ted
2
trans
ition
s G
C
MSD
Q
EI
+
NO
N
O
N
O
Ther
mo
TSQ
Q
uant
um
10
AC
N
DSP
E TG
-5M
S 30
m
2 M
anua
l 80
Ea
ch B
atc
h
Con
firm
ed w
ith
seco
nd m
etho
d
13.8
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
0.01
(=RL
) N
O
API
5500
10
A
CN
D
SPE
Syne
rgie
Fus
ion
RP80
A
8 M
anua
l 35
Sche
dul
ed
MRM
M
etho
d
also
use
d
for
qua
ntifi
catio
n
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.8
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
50
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
FEN
PR
OP
IDIN
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
M
etha
nol
NO
C
18
5 Bo
th
211
Alw
ays
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±0.5
%
GC
M
SD
Q
EI
+ YE
S YE
S 0.
010
mg/
kg
YES
Agi
lent
78
90-5
975C
15
A
CN
PS
A
HP-5
MS
10
Aut
o 21
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S 0.
01
NO
70
00B
10
AC
N
PSA
D
B-5M
S UI
2
Both
44
0
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
017
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
TO
F EI
YES
NO
YES
LEC
O P
EGA
SUS
15
Ace
tone
/PE/
DC
M
NO
D
B-5
1 Bo
th
018
Tent
ativ
e d
etec
ted
RT
lo
ckin
g
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01 -
0.05
m
g/kg
YE
S A
gile
nt M
SD
5975
B 10
A
CN
PS
A
HP5
10
Both
>
600
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
10
NO
A
gile
nt 6
490
15
AC
N
PSA
C
18
5 A
uto
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
YES
YES
0.01
N
O
agile
nt
10
AC
N
DSP
E HP
5MS
1
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
Q
ESI
+ YE
S YE
S 0.
01
NO
A
PI 5
500
10
AC
N
Pu
rsui
t XRs
Ultr
a
3 Bo
th
250
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.15
0.
12
isoto
pe, 2
ions
<
5ppm
LC
M
SD
Orb
itra
p
ESI
+ N
O
NO
0.
01-0
.1
YES
Exac
tive
10
AC
N
Non
e C
18 A
tlant
is T3
5
Both
57
0 Ea
ch B
atc
h
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
91
8 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
51
FEN
PR
OP
IDIN
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 0.
5 %
2.
5
GC
M
SD
ion
trap
EI
YES
YES
0.01
YE
S Tr
ap 4
000
- V
aria
n 10
A
CN
D
SPE
5%
1 µL
A
uto
450
Ever
y W
eek
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 0.
7 3
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Var
ian
3800
GC
+
320-
MS
10
AC
N
DSP
E w
ith P
SA
VF-
1ms
4 Bo
th
302
Each
Ba
tch
028
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
274.
2>14
7.1,
27
4.2>
117.
0 LC
M
SD
Q
ESI
+ YE
S YE
S LO
Q: 2
pp
b
NO
LC
: Agi
lent
120
0,
MS:
API
400
0 Q
TRA
P 10
A
CN
Q
uEC
hERS
w
ithou
t PSA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2
.1 m
m, 5
µm
2
Aut
o
029
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
NO
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
025-
0.25
µg
/ml
NO
UPLC
-MSM
S (W
ate
rs A
quity
UP
LC sy
stem
, A
PI 5
000
Trip
elqu
adro
pol,
Scie
x
10
EtO
Ac
Filte
r HS
S T3
2
Both
14
1 Ea
ch B
atc
h
032
Tent
ativ
e d
etec
ted
0
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
W
ate
rs A
cqui
ty
TQD
10
M
etha
nol
Filte
r C
18
6 A
uto
150
Alw
ays
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-2.0
min
3 io
ns
GC
M
SD
Q
EI
+ YE
S N
O
0.05
YE
S A
gile
nt G
C-M
SD
7890
A/5
975c
10
A
CN
PS
A, C
18
HP-5
MS
1 A
uto
927
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
Qua
ttro
Prem
ier
10
AC
N
DSP
E (P
SA/M
gSO
4)
RP-1
8 en
dca
pped
5
Both
18
6 Ea
ch B
atc
h
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Tent
ativ
e d
etec
ted
N
one
Non
e 2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
PI 4
000
10
AC
N
DSP
E W
ate
rs-C
18
2,1x
50m
mx1
,7‚µ
m
5 A
uto
600
Ever
y W
eek
039
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
274.
3->1
47.1
, 27
4.3-
>86.
1 LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
410B
10
A
CN
D
SPE
C18
2
Both
18
7 Ea
ch B
atc
h
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
52
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
FEN
PR
OP
IDIN
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
040
Tent
ativ
e d
etec
ted
16
3
LC
TOF
ESI
+ N
O
NO
YES
Agi
lent
623
0 10
A
CN
N
one
Eclip
se C
18
3 A
uto
apro
x 50
0
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
Q
uEC
hERS
C
18 A
qua
10
Bo
th
043
Tent
ativ
e d
etec
ted
0
0 sc
an
GC
M
SD
IT EI
YES
YES
0.01
0 YE
S V
aria
n Sa
turn
40
00
10
AC
N
DSP
E V
aria
n V
F 1
Aut
o 26
0 D
aily
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch B
atc
h
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1.2
2
trans
ition
s +
ion
ratio
LC
M
SD
Q
ESI
+ YE
S YE
S 5-
1000
µg
/kg
NO
W
ate
rs Q
uattr
o Pr
emie
r XE
15
Ace
tone
/PE/
DC
M
NO
A
cqui
ty B
EH
(100
x2.1
mm
i.d
.) 5
Both
23
0 Ea
ch B
atc
h
048
Con
firm
ed w
ith
seco
nd m
etho
d
3
G
C
MSD
TO
F EI
YES
YES
0.00
5 YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
XEV
O T
Q
MS
10
AC
N
BE
H C
18 1
,7µm
3
Both
60
D
aily
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.0
38
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01-0
.05
YES
Agi
lent
120
0 LC
+646
0QQ
Q
10
AC
N
DSP
E YM
C T
riart
C18
2*
100
mm
3µm
5
Both
35
4 D
aily
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
53
FLU
FEN
AC
ET
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S A
gile
nt 5
973
iner
t 5
AC
N
HP
-5 M
SUI
5 Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
3.1
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Con
firm
ed w
ith
seco
nd m
etho
d
-1.2
2.
2
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
Tent
ativ
e d
etec
ted
N
A
NA
LC
MSD
Q
ES
I +
YES
NO
N
A
NO
A
gile
nt 6
460,
12
90HP
LC
10
EtO
Ac
Non
e W
ate
rs, H
SS T
3,
150
x 2.
1mm
2
Both
50
0 Ea
ch B
atc
h
006
Tent
ativ
e d
etec
ted
<1
3 d
iagn
ostic
io
ns
GC
M
SD
Q
EI
+ YE
S YE
S >0
.010
m
g/kg
YE
S Tr
ace
DSQ
15
A
CN
PS
A/C
18
DB5
MS
0.8
Both
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3.2
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
M
etha
nol
NO
C
18
5 Bo
th
211
Alw
ays
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
0.01
N
O
6460
10
A
CN
PS
A
C18
-XB
2 Bo
th
440
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
018
Tent
ativ
e d
etec
ted
RT
lo
ckin
g
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01 -
0.05
m
g/kg
YE
S A
gile
nt M
SD
5975
B 10
A
CN
PS
A
HP5
10
Both
>
600
Alw
ays
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
54
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
FLU
FEN
AC
ET
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
10
NO
A
gile
nt 6
490
15
AC
N
PSA
C
18
5 A
uto
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
YES
YES
0.01
N
O
agile
nt
10
AC
N
DSP
E HP
5MS
1
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, MS
API
30
00
10
AC
N
DSP
E (P
SA, M
gSO
4)
C18
3µ
50x2
mm
10
Bo
th
550
Alw
ays
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
Q
ESI
+ YE
S YE
S 0.
01
NO
A
PI 5
500
10
AC
N
Pu
rsui
t XRs
Ultr
a
3 Bo
th
250
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.2
1 -0
.35
isoto
pe, 2
ions
<
5ppm
LC
M
SD
Orb
itra
p
ESI
+ N
O
NO
0.
01-0
.1
YES
Exac
tive
10
AC
N
Non
e C
18 A
tlant
is T3
5
Both
57
0 Ea
ch B
atc
h
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
90
5 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 0.
7 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
V
aria
n Pr
o St
ar
+320
-MS
10
AC
N
DSP
E w
ith P
SA
Rest
ek U
ltra
C18
10
Bo
th
302
Each
Ba
tch
028
Tent
ativ
e d
etec
ted
36
4.1>
152.
2,
364.
1>19
4.2
LC
MSD
Q
ES
I +
NO
N
O 1
0-10
0 pp
b
NO
LC
: Agi
lent
120
0,
MS:
API
400
0 Q
TRA
P 10
A
CN
Q
uEC
hERS
w
ithou
t PSA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2
.1 m
m, 5
µm
2
Aut
o 59
1
029
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
NO
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
032
Tent
ativ
e d
etec
ted
0
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
W
ate
rs A
cqui
ty
TQD
10
M
etha
nol
Filte
r C
18
6 A
uto
150
Alw
ays
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-1.3
min
3 io
ns
GC
M
SD
Q
EI
+ YE
S N
O
0.05
YE
S A
gile
nt G
C-M
SD
7890
A/5
975c
10
A
CN
PS
A, C
18
HP-5
MS
1 A
uto
927
034
Con
firm
ed w
ith
seco
nd m
etho
d
full
scan
G
C
MSD
Q
EI
+
NO
N
O
YE
S A
gile
nt 5
973
MSD
10
A
CN
D
SPE
(PSA
/MgS
O4)
HP
-5M
S 10
Bo
th
950
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
55
FLU
FEN
AC
ET
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Tent
ativ
e d
etec
ted
N
one
Non
e 2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
PI 4
000
10
AC
N
DSP
E W
ate
rs-C
18
2,1x
50m
mx1
,7‚µ
m
5 A
uto
600
Ever
y W
eek
040
Con
firm
ed w
ith
seco
nd m
etho
d
0 4
LC
TOF
ESI
+ N
O
NO
YES
Agi
lent
623
0 10
A
CN
N
one
Eclip
se C
18
3 A
uto
apro
x 50
0
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
Q
uEC
hERS
C
18 A
qua
10
Bo
th
043
Tent
ativ
e d
etec
ted
0
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
YES
Api
320
0QT
10
AC
N
DSP
E Ph
enom
enex
fusio
n 10
A
uto
200
Dai
ly
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch B
atc
h
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s +
ion
ratio
LC
M
SD
Q
ESI
+ YE
S YE
S 5-
1000
µg
/kg
NO
W
ate
rs Q
uattr
o Pr
emie
r XE
15
Ace
tone
/PE/
DC
M
NO
A
cqui
ty B
EH
(100
x2.1
mm
i.d
.) 5
Both
23
0 Ea
ch B
atc
h
048
Con
firm
ed w
ith
seco
nd m
etho
d
4
G
C
MSD
TO
F EI
YES
YES
0.01
YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o m
icro
GC
10
A
CN
DB-
5MS
3 Bo
th
150
Dai
ly
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.0
58
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01-0
.05
YES
Agi
lent
120
0 LC
+646
0QQ
Q
10
AC
N
DSP
E YM
C T
riart
C18
2*
100
mm
3µm
5
Both
35
4 D
aily
053
Tent
ativ
e d
etec
ted
12
3 SI
M Io
ns
GC
M
SD
Q
EI
+ N
O
NO
>0
.05
mg/
kg
YES
Ther
mo
DSQ
10
D
CM
D
iato
mac
eous
ea
rth
1
Both
40
0 Ev
ery
6 M
onth
s
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
56
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
FLU
TOLA
NIL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
2.8
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Con
firm
ed w
ith
seco
nd m
etho
d
-1.2
1.
1
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
G
C
MSD
Q
EI
+
YES
NO
N
A
NO
Th
erm
o TS
Q
Qua
ntum
XLS
10
Et
OA
c N
one
Ther
mo
TG-5
SILM
S,
30m
*0.2
5mm
* 0.
25um
2
Aut
o 50
0 Ea
ch B
atc
h
006
Tent
ativ
e d
etec
ted
<1
3 d
iagn
ostic
io
ns
GC
M
SD
Q
EI
+ YE
S YE
S >0
.010
m
g/kg
YE
S Tr
ace
DSQ
15
A
CN
PS
A/C
18
DB5
MS
0.8
Both
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Agi
lent
68
90/5
973
10
AC
N
DSP
E HP
-5M
S 2
Man
ual
183
Each
Ba
tch
008
Tent
ativ
e d
etec
ted
1.3
LC
M
SD
Q-T
OF
ESI
+ N
O
NO
YES
5600
trip
le T
OF
10
AC
N
Non
e re
vers
ed p
hase
2
Aut
o 60
0 W
e d
o no
t ha
ve a
st
and
ard
009
Tent
ativ
e d
etec
ted
35
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
0.01
(=RL
) N
O
API
4000
10
A
CN
D
SPE
Syne
rgie
Fus
ion
RP80
A
8 M
anua
l 25
0
Sche
dul
ed
MRM
M
etho
d
also
use
d
for
qua
ntifi
catio
n
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2.5
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
57
FLU
TOLA
NIL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
M
etha
nol
NO
C
18
5 Bo
th
211
Alw
ays
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±0.5
%
GC
M
SD
Q
EI
+ YE
S YE
S 0.
010
mg/
kg
YES
Agi
lent
78
90-5
975C
15
A
CN
PS
A
HP-5
MS
10
Aut
o 21
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
0.01
N
O
6460
10
A
CN
PS
A
C18
-XB
2 Bo
th
440
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
018
Tent
ativ
e d
etec
ted
5
5 ac
cura
te
mas
s LC
O
rbitr
ap
O
rbitr
ap
ES
I +
YES
YES
0.01
- 0.
05
mg/
kg
YES
Ther
mo
Exac
tive
10
AC
N
PSA
C
18
5 Bo
th
120
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 10
N
O
Agi
lent
689
0 15
A
ceto
ne/P
E/D
CM
N
one
95%
met
hyl
5% p
heny
l silo
xane
2
Aut
o
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
bSci
ex
10
AC
N
DSP
E C
18
5 A
uto
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
023
Con
firm
ed w
ith
seco
nd m
etho
d
G
C
MSD
TO
F
YE
S YE
S 0.
01
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E Ph
enom
enen
x
ZB-5
MS
3 Bo
th
750
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I -
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.1
7 -0
.71
isoto
pe, 2
ions
<
5ppm
LC
M
SD
Orb
itra
p
ESI
+ N
O
NO
0.
01-0
.1
YES
Exac
tive
10
AC
N
Non
e C
18 A
tlant
is T3
5
Both
57
0 Ea
ch B
atc
h
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
93
3 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
58
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
FLU
TOLA
NIL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 0.
5 %
2.
5
GC
M
SD
ion
trap
EI
YES
YES
0.01
YE
S Tr
ap 4
000
- V
aria
n 10
A
CN
D
SPE
5%
1 µL
A
uto
450
Ever
y W
eek
028
Tent
ativ
e d
etec
ted
Mat
ch w
ith
NIS
T Lib
rary
(M
atc
h 82
8,
rang
e 0-
1000
)
GC
M
SD
TOF
EI
N
O
NO
10-
100
ppb
YE
S G
CxG
C-T
OF
MS
Pega
sus 4
D
10
AC
N
QuE
ChE
RS
with
out P
SA
DB5
-MS
(30
m x
0,2
5 m
m x
0,2
5 µm
) in
the
1st D
imen
sion,
BP
X-50
(2 m
x 0
,1
mm
x 0
,1 µ
m) i
n th
e 2n
d D
imen
sion
10
Aut
o 50
0
029
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
NO
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
GC
M
S/M
S Q
EI
+
YES
YES
0.02
5-0.
25
µg/m
l N
O
Wa
ters
Qua
ttro
Mic
ro G
C
10
EtO
Ac
Filte
r Rx
i-5sil
MS/
inte
gra-
guar
d R
este
k 10
Bo
th
141
Each
Ba
tch
032
Tent
ativ
e d
etec
ted
0
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Ther
mo
TSQ
Q
uant
um X
LS
Ultra
10
A
CN
PS
A
Cap
illary
1
Both
15
0 A
lway
s
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-1.9
min
3 io
ns
GC
M
SD
Q
EI
+ YE
S N
O
0.01
YE
S A
gile
nt G
C-M
SD
7890
A/5
975c
10
A
CN
PS
A, C
18
HP-5
MS
1 A
uto
927
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
Qua
ttro
Prem
ier
10
AC
N
DSP
E (P
SA/M
gSO
4)
RP-1
8 en
dca
pped
5
Both
18
6 Ea
ch B
atc
h
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Tent
ativ
e d
etec
ted
N
one
Non
e 2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
PI 4
000
10
AC
N
DSP
E W
ate
rs-C
18
2,1x
50m
mx1
,7‚µ
m
5 A
uto
600
Ever
y W
eek
039
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5973
MSD
10
A
CN
D
SPE
HP-5
MSI
20
Bo
th
113
Each
Ba
tch
040
Con
firm
ed w
ith
seco
nd m
etho
d
G
C
MSD
Q
EI
NO
N
O
YE
S A
gile
nt 5
973
30
EtO
Ac
HPG
PC
DB-
5MS
2 A
uto
apro
x 50
0
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
59
FLU
TOLA
NIL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5%
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 0.
005
mg/
kg
NO
V
ARI
AN
CP-
3800
M
S-32
0 10
A
CN
PS
A
VF-
5MS
1 A
uto
210
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S
NO
TS
Q Q
uant
um
10
AC
N
QuE
ChE
RS
VF
5 M
S 3
Both
043
Tent
ativ
e d
etec
ted
0
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
YES
Api
320
0QT
10
AC
N
DSP
E Ph
enom
enex
fusio
n 10
A
uto
200
Dai
ly
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch B
atc
h
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons +
io
n ra
tio
LC
MSD
Q
ES
I +
YES
YES
5-10
00
µg/k
g N
O
Wa
ters
Qua
ttro
Prem
ier X
E 15
A
ceto
ne/P
E/D
CM
N
O
Acq
uity
BEH
(1
00x2
.1 m
m i.
d.)
5 Bo
th
230
Each
Ba
tch
048
Con
firm
ed w
ith
seco
nd m
etho
d
6
G
C
MSD
TO
F EI
YES
YES
0.00
5 YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o m
icro
GC
10
A
CN
DB-
5MS
3 Bo
th
150
Dai
ly
051
Tent
ativ
e d
etec
ted
0.5
qual
ifier
s G
C
MSD
IT
EI
N
O
NO
YES
varia
n G
CM
S 40
00
10
AC
N
PSA
va
rian
fact
or fo
ur
5 Bo
th
053
Tent
ativ
e d
etec
ted
9
3
SIM
Ions
G
C
MSD
Q
EI
+
NO
N
O
>0.0
5 m
g/kg
YE
S Th
erm
o D
SQ
10
DC
M
Dia
tom
aceo
us
earth
1 Bo
th
400
Ever
y 6
Mon
ths
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
60
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
IMA
ZA
PY
R
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I -
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
410
10
AC
N
DSP
E Ec
lipse
XD
B-C
18
4 M
anua
l 13
9 Ea
ch B
atc
h
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
010
Tent
ativ
e d
etec
ted
2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
BI40
00
10
AC
N
NO
C
18
55
Both
ap
rox
580
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E (P
SA, M
gSO
4)
C18
3µ
50x2
mm
10
Bo
th
550
Alw
ays
022
Tent
ativ
e d
etec
ted
0.
5 0.
05
LC
M
SD
TOF
ESI
+ YE
S YE
S
YES
LCT
PREM
IER
XE
15
MIN
I LUK
E N
O
C-1
8 7
Aut
o 34
3 Ev
ery
Da
y
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
IT ES
I -
YES
YES
0.01
N
O
10
A
CN
Both
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
028
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
262.
2>21
7.0,
26
2.2>
149.
0 LC
M
SD
Q
ESI
+ YE
S YE
S LO
Q:
2 pp
b
NO
LC
: Agi
lent
120
0,
MS:
API
400
0 Q
TRA
P 10
A
CN
Q
uEC
hERS
w
ithou
t PSA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2.1
m
m, 5
µm
2
Aut
o
029
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
NO
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
034
Tent
ativ
e d
etec
ted
5
trans
ition
s LC
Q
ESI
+ N
O
NO
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
A
CN
D
SPE
(PSA
/MgS
O4)
RP
-18
end
capp
ed
5 Bo
th
500
038
Tent
ativ
e d
etec
ted
N
one
Non
e 2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
PI 4
000
10
AC
N
DSP
E W
ate
rs-C
18
2,1x
50m
mx1
,7‚µ
m
5 A
uto
600
Ever
y W
eek
040
Tent
ativ
e d
etec
ted
2
0
LC
TO
F ES
I +
NO
N
O
YE
S A
gile
nt 6
230
10
AC
N
Non
e Ec
lipse
C18
3
Aut
o ap
rox
500
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
61
IMA
ZA
PY
R
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2.5%
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.00
5 m
g/kg
N
O
AG
ILEN
T
G-6
410A
10
A
CN
PS
A
ZORB
AX-
ECLI
PSE
XDB-
C8
20
Aut
o 14
3
043
Tent
ativ
e d
etec
ted
0
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
YES
Api
320
0QT
10
AC
N
DSP
E Ph
enom
enex
fusio
n 10
A
uto
200
Dai
ly
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch B
atc
h
048
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1.1
LC
MSD
Q
ES
I +
YES
YES
0.00
5 N
O
Agi
lent
641
0 10
A
CN
D
SPE(
PSA
) Lu
na C
18
5 Bo
th
350
Dai
ly
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
62
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
IOX
YN
IL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I -
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
- YE
S N
O
NA
N
O
Agi
lent
646
0,
1290
HPLC
10
Et
OA
c N
one
Wa
ters
, HSS
T3,
150
x
2.1m
m
2 Bo
th
500
Each
Ba
tch
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I -
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
3 A
uto
300
Each
Ba
tch
009
Tent
ativ
e d
etec
ted
2
trans
ition
s LC
Q
ESI
- N
O
NO
NO
A
PI40
00
10
AC
N
DSP
E Sy
nerg
ie F
usio
n RP
80A
8
Man
ual
40
Sche
dul
ed
MRM
M
etho
d
also
use
d
for
qua
ntifi
catio
n
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I -
YES
YES
0.02
N
O
ABI
4000
10
A
CN
N
O
C18
55
Bo
th
apro
x 58
0 A
lway
s
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s LC
M
SD
Q
ESI
- YE
S YE
S 0.
010
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
M
etha
nol
NO
C
18
5 Bo
th
211
Alw
ays
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
- YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
017
Tent
ativ
e d
etec
ted
GC
M
SD
TOF
EI
N
O
NO
YES
LEC
O P
EGA
SUS
15
Ace
tone
/PE/
DC
M
NO
D
B-5
1 Bo
th
018
Tent
ativ
e d
etec
ted
RT
lo
ckin
g
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01 -
0.05
m
g/kg
YE
S A
gile
nt M
SD
5975
B 10
A
CN
PS
A
HP5
10
Both
>
600
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
LC
MSD
Q
ES
I -
YES
YES
10
NO
A
gile
nt 6
490
15
AC
N
PSA
C
18
5 A
uto
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
- YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, MS
A
PI 3
000
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
IT ES
I -
YES
YES
0.01
N
O
10
A
CN
Both
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
63
IOX
YN
IL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I -
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
025
Con
firm
ed w
ith
seco
nd m
etho
d
-0.0
2 0.
9 iso
tope
LC
M
SD
Orb
itra
p
ESI
- N
O
NO
0.
01-0
.1
YES
Exac
tive
10
AC
N
Non
e C
18 A
tlant
is T3
5
Both
57
0 Ea
ch B
atc
h
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
91
0 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
028
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
369.
6>12
6.9,
36
9.6>
214.
8 LC
M
SD
Q
ESI
- YE
S YE
S LO
Q: 2
pp
b
NO
LC
: Agi
lent
120
0,
MS:
API
400
0 Q
TRA
P 10
A
CN
Q
uEC
hERS
w
ithou
t PSA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2.
1 m
m, 5
µm
2
Aut
o
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
- YE
S YE
S 0.
005-
0.04
µg
/ml
NO
UPLC
-MSM
S (W
ate
rs A
quity
UP
LC sy
stem
, A
PI 5
000
Trip
elqu
adro
pol,
Scie
x
5 Et
OA
c Fil
ter
HSS
T3
2 Bo
th
250
Each
Ba
tch
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I -
YES
YES
N
O
Wa
ters
Qua
ttro
Prem
ier
10
AC
N
DSP
E (P
SA/M
gSO
4)
RP-1
8 en
dca
pped
5
Both
18
6 Ea
ch B
atc
h
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
- YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
040
Con
firm
ed w
ith
seco
nd m
etho
d
9 3
LC
TOF
ESI
- N
O
NO
YES
Agi
lent
623
0 10
A
CN
N
one
Eclip
se C
18
3 A
uto
apro
x 50
0
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2.5%
2 tra
nsiti
ons
LC
MSD
Q
ES
I -
YES
YES
0.00
5 m
g/kg
N
O
AG
ILEN
T G
-64
10A
10
A
CN
PS
A
ZORB
AX-
ECLI
PSE
XDB-
C8
80
Aut
o 14
3
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I -
YES
YES
N
O
API
400
0 10
A
CN
Q
uEC
hERS
C
18 A
qua
10
Bo
th
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3.6
2
trans
ition
s +
ion
ratio
LC
M
SD
Q
ESI
- N
O
NO
5-
1000
µg
/kg
NO
W
ate
rs Q
uattr
o Pr
emie
r XE
15
Ace
tone
/PE/
DC
M
NO
A
lltim
a C
18
(150
x3 m
m i.
d.)
5 Bo
th
27
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
64
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
IOX
YN
IL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
048
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.8
LC
MSD
Q
ES
I -
YES
YES
0.00
5 N
O
Agi
lent
641
0 10
A
CN
D
SPE(
PSA
) Lu
na C
18
5 Bo
th
350
Dai
ly
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
XEV
O T
Q
MS
10
AC
N
BE
H C
18 1
,7µm
3
Both
60
D
aily
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.01
7
2 tra
nsiti
ons
LC
MSD
Q
ES
I -
YES
YES
0.01
-0.0
5 YE
S A
gile
nt 1
200
LC+6
460Q
10
A
CN
D
SPE
YMC
Tria
rt C
18
2*10
0 m
m 3
µm
5 Bo
th
7 D
aily
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
65
ISO
PR
OTU
RO
N
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
002
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
API
4000
10
A
CN
N
one
C18
5
Man
ual
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
460,
12
90HP
LC
10
EtO
Ac
Non
e W
ate
rs, H
SS T
3,
150
x 2.
1mm
2
Both
50
0 Ea
ch B
atc
h
Con
firm
ed w
ith
seco
nd m
etho
d
-1.2
2.
2
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
006
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
<2
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.010
m
g/kg
N
O
Wa
ters
qua
ttro
prem
ier
15
AC
N
Non
e BE
H C
18
3 Bo
th
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
410
10
AC
N
DSP
E Ec
lipse
XD
B-C
18
4 M
anua
l 13
9 Ea
ch B
atc
h
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
009
Tent
ativ
e d
etec
ted
28
.8
2
trans
ition
s LC
Q
ESI
+ YE
S YE
S 0.
01 (=
RL)
NO
A
PI40
00
10
AC
N
DSP
E Sy
nerg
ie F
usio
n RP
80A
8
Man
ual
250
Sche
dul
ed
MRM
M
etho
d
also
use
d
for
qua
ntifi
catio
n
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
ABI
4000
10
A
CN
N
O
C18
55
Bo
th
apro
x 58
0 A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
LC
M
SD
Q-T
RAP
ESI
+ YE
S YE
S 0.
01
NO
32
00q
trap
10
A
CN
PS
A
T-3
5 M
anua
l 17
0 1
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
M
etha
nol
NO
C
18
5 Bo
th
211
Alw
ays
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
66
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
ISO
PR
OTU
RO
N
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
0.01
N
O
6460
10
A
CN
PS
A
C18
-XB
2 Bo
th
440
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
017
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
TO
F EI
YES
NO
YES
LEC
O P
EGA
SUS
15
Ace
tone
/PE/
DC
M
NO
D
B-5
1 Bo
th
018
Tent
ativ
e d
etec
ted
5
5 ac
cura
te
mas
s LC
O
rbitr
ap
O
rbitr
ap
ES
I +
YES
YES
0.01
- 0.
05
mg/
kg
YES
Ther
mo
Exac
tive
10
AC
N
PSA
C
18
5 Bo
th
120
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
LC
M
SD
Q
ESI
+ YE
S YE
S
NO
A
gile
nt 6
490
15
AC
N
PSA
5 A
uto
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
bSci
ex
10
AC
N
DSP
E C
18
5 A
uto
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
022
Tent
ativ
e d
etec
ted
0.
5 0.
05
LC
M
SD
TOF
ESI
+ YE
S YE
S
YES
LCT
PREM
IER
XE
15
MIN
I LUK
E N
O
C-1
8 7
Aut
o 34
3 Ev
ery
Da
y
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
Q
ESI
+ YE
S YE
S 0.
01
NO
A
PI 5
500
10
AC
N
Pu
rsui
t XRs
Ultr
a
3 Bo
th
250
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.2
0.
64
isoto
pe, 2
ions
<
5ppm
LC
M
SD
Orb
itra
p
ESI
+ N
O
NO
0.
01-0
.1
YES
Exac
tive
10
AC
N
Non
e C
18 A
tlant
is T3
5
Both
57
0 Ea
ch B
atc
h
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 2.
5 %
2.
5 tra
nsiti
on 1
an
d 2
LC
M
SD
Q-T
RAP
ESI
+ YE
S YE
S 0.
01
YES
3200
Qtra
p
10
AC
N
DSP
E C
18
50
Aut
o 52
1 Ev
ery
Wee
k
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
67
ISO
PR
OTU
RO
N
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 0.
7 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
V
aria
n Pr
o St
ar
+320
-MS
10
AC
N
DSP
E w
ith P
SA
Rest
ek U
ltra
C18
10
Bo
th
302
Each
Ba
tch
028
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
207.
2>72
.1,
207.
2>13
4.2
LC
MSD
Q
ES
I +
YES
YES
LOQ
: 2
ppb
N
O
LC: A
gile
nt 1
200,
M
S: A
PI 4
000
QTR
AP
10
AC
N
QuE
ChE
RS
with
out P
SA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2
.1 m
m, 5
µm
2
Aut
o
029
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
005-
0.12
5 µg
/ml
NO
UPLC
-MSM
S (W
ate
rs A
quity
UP
LC sy
stem
, A
PI 5
000
Trip
elqu
adro
pol,
Scie
x
10
EtO
Ac
Filte
r HS
S T3
2
Both
37
3 Ea
ch B
atc
h
032
Tent
ativ
e d
etec
ted
0
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
W
ate
rs A
cqui
ty
TQD
10
M
etha
nol
Filte
r C
18
6 A
uto
150
Alw
ays
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
Qua
ttro
Prem
ier
10
AC
N
DSP
E (P
SA/M
gSO
4)
RP-1
8 en
dca
pped
5
Both
18
6 Ea
ch B
atc
h
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
Non
e N
one
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
D
SPE
Wa
ters
-C18
2,
1x50
mm
x1,7
‚µm
5
Aut
o 60
0 Ev
ery
Wee
k
039
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
207.
1->7
2.0,
20
7.1-
>165
.1
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
641
0B
10
AC
N
DSP
E C
18
2 Bo
th
187
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
68
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
ISO
PR
OTU
RO
N
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
040
Con
firm
ed w
ith
seco
nd m
etho
d
3 2
LC
TOF
ESI
+ N
O
NO
YES
Agi
lent
623
0 10
A
CN
N
one
Eclip
se C
18
3 A
uto
apro
x 50
0
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2.5%
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.00
5 m
g/kg
N
O
AG
ILEN
T
G-6
410A
10
A
CN
PS
A
ZORB
AX-
ECLI
PSE
XDB-
C8
20
Aut
o 14
3
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
Q
uEC
hERS
C
18 A
qua
10
Bo
th
043
Tent
ativ
e d
etec
ted
0
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
YES
Api
320
0QT
10
AC
N
DSP
E Ph
enom
enex
fusio
n 10
A
uto
200
Dai
ly
044
Tent
ativ
e d
etec
ted
LC
Q
EI
+
YES
A
gile
nt 6
410
10
AC
N
Zo
rbax
SB
C-1
8 5
Aut
o
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch B
atc
h
047
Tent
ativ
e d
etec
ted
2
Sp
ectru
m
mat
ch
(reve
rsed
) G
C
MSD
IT
EI
+ YE
S YE
S 20
-10.
000
µg/k
g YE
S V
aria
n Sa
turn
20
00
15
Ace
tone
/PE/
DC
M
NO
V
F-5-
ms
5 Bo
th
550
Qua
rterly
048
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.9
LC
MSD
Q
ES
I +
YES
YES
0.00
5 N
O
Agi
lent
641
0 10
A
CN
D
SPE(
PSA
) Lu
na C
18
5 Bo
th
350
Dai
ly
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
XEV
O
TQ M
S 10
A
CN
BEH
C18
1,7
µm
3 Bo
th
60
Dai
ly
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.0
55
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01-0
.05
YES
Agi
lent
120
0 LC
+646
0QQ
Q
10
AC
N
DSP
E YM
C T
riart
C18
2*
100
mm
3µm
5
Both
35
4 D
aily
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
69
MET
AZ
AC
HLO
R
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S A
gile
nt 5
973
iner
t 5
AC
N
HP
-5 M
SUI
5 Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
3.1
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
004
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Ther
mo
TSQ
Q
uant
um X
LS
10
EtO
Ac
Non
e Th
erm
o TG
-5SI
LMS,
30
m*0
.25m
m*
0.25
um
2 A
uto
500
Each
Ba
tch
Con
firm
ed w
ith
seco
nd m
etho
d
-0.6
2.
4
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
006
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
<2
<1
3 d
iagn
ostic
io
ns
GC
M
SD
Q
EI
+ YE
S YE
S >0
.010
m
g/kg
YE
S Tr
ace
DSQ
15
A
CN
PS
A/C
18
DB5
MS
0.8
Both
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Agi
lent
68
90/5
973
10
AC
N
DSP
E HP
-5M
S 2
Man
ual
183
Each
Ba
tch
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
009
Tent
ativ
e d
etec
ted
36
.6
2
trans
ition
s LC
Q
ESI
+ YE
S YE
S 0.
01 (=
RL)
NO
A
PI40
00
10
AC
N
DSP
E Sy
nerg
ie F
usio
n RP
80A
8
Man
ual
250
Sche
dul
ed
MRM
M
etho
d
also
use
d
for
qua
ntifi
catio
n
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2.3
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
M
etha
nol
NO
C
18
5 Bo
th
211
Alw
ays
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
70
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
MET
AZ
AC
HLO
R
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±0.5
%
GC
M
SD
Q
EI
+ YE
S YE
S 0.
010
mg/
kg
YES
Agi
lent
78
90-5
975C
15
A
CN
PS
A
HP-5
MS
10
Aut
o 21
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S 0.
01
NO
70
00B
10
AC
N
PSA
D
B-5M
S UI
2
Both
44
0
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
017
Tent
ativ
e d
etec
ted
GC
M
SD
TOF
EI
N
O
NO
YES
LEC
O P
EGA
SUS
15
Ace
tone
/PE/
DC
M
NO
D
B-5
1 Bo
th
018
Tent
ativ
e d
etec
ted
RT
lo
ckin
g
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01 -
0.05
m
g/kg
YE
S A
gile
nt M
SD
5975
B 10
A
CN
PS
A
HP5
10
Both
>
600
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 10
N
O
Agi
lent
689
0 15
A
ceto
ne/P
E/D
CM
N
one
95%
met
hyl
5% p
heny
l silo
xane
2
Aut
o
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
YES
YES
0.01
N
O
agile
nt
10
AC
N
DSP
E HP
5MS
1
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
022
Tent
ativ
e d
etec
ted
0.
5 0.
05
LC
M
SD
TOF
ESI
+ YE
S YE
S
YES
LCT
PREM
IER
XE
15
MIN
I LUK
E N
O
C-1
8 7
Aut
o 34
3 Ev
ery
Da
y
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
Q
ESI
+ YE
S YE
S 0.
01
NO
A
PI 5
500
10
AC
N
Pu
rsui
t XRs
Ultr
a
3 Bo
th
250
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
3x
SIM
mas
ses
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01
YES
Agi
lent
597
5 10
A
CN
PS
A
GsB
P-5M
S 5
Both
50
0 D
aily
025
Con
firm
ed w
ith
seco
nd m
etho
d
-0.1
9 -0
.43
isoto
pe
LC
MSD
O
rbitr
ap
ES
I +
NO
N
O
0.01
-0.1
YE
S Ex
activ
e 10
A
CN
N
one
C18
Atla
ntis
T3
5 Bo
th
570
Each
Ba
tch
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
84
0 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 0.
5 %
2.
5
GC
M
SD
ion
trap
EI
YES
YES
0.01
YE
S Tr
ap 4
000
- V
aria
n 10
A
CN
D
SPE
5%
1 µL
A
uto
450
Ever
y W
eek
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
71
MET
AZ
AC
HLO
R
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 0.
7 4
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Var
ian
3800
G
C +
320
-MS
10
AC
N
DSP
E w
ith P
SA
VF-
1ms
4 Bo
th
302
Each
Ba
tch
028
Con
firm
ed w
ith
seco
nd m
etho
d
278.
2>14
3.2,
27
8.2>
210.
2 LC
M
SD
Q
ESI
+ N
O
NO
10-
100
ppb
N
O
LC: A
gile
nt 1
200,
M
S: A
PI 4
000
QTR
AP
10
AC
N
QuE
ChE
RS
with
out P
SA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2
.1 m
m, 5
µm
2
Aut
o 59
1
029
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
NO
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
YE
S V
aria
n 32
0 15
A
CN
C18
10
A
uto
150
Each
Ba
tch
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
GC
M
S/M
S Q
EI
+
YES
YES
0.00
5-0.
4 µg
/ml
NO
W
ate
rs Q
uattr
o M
icro
GC
10
Et
OA
c Fil
ter
Rxi-5
sil M
S/in
tegr
a-gu
ard
Res
tek
10
Both
37
3 Ea
ch B
atc
h
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-2.1
min
3 io
ns
GC
M
SD
Q
EI
+ YE
S N
O
0.05
YE
S A
gile
nt G
C-M
SD
7890
A/5
975c
10
A
CN
PS
A, C
18
HP-5
MS
1 A
uto
927
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
Qua
ttro
Prem
ier
10
AC
N
DSP
E (P
SA/M
gSO
4)
RP-1
8 en
dca
pped
5
Both
18
6 Ea
ch B
atc
h
035
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
NO
N
O
YE
S A
gile
nt 6
890N
10
A
CN
D
SPE
DB-
5 2
Aut
o
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
Non
e N
one
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
D
SPE
Wa
ters
-C18
2,
1x50
mm
x1,7
‚µm
5
Aut
o 60
0 Ev
ery
Wee
k
039
Tent
ativ
e d
etec
ted
GC
M
SD
Q
EI
+ N
O
NO
YES
HP59
73 M
SD
10
AC
N
DSP
E HP
-5M
SI
20
Both
62
4 N
o st
and
ard
us
ed
040
Con
firm
ed w
ith
seco
nd m
etho
d
7 3
LC
TOF
ESI
+ N
O
NO
YES
Agi
lent
623
0 10
A
CN
N
one
Eclip
se C
18
3 A
uto
apro
x 50
0
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
72
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
MET
AZ
AC
HLO
R
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2.5%
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.00
5 m
g/kg
N
O
AG
ILEN
T
G-6
410A
10
A
CN
PS
A
ZORB
AX-
ECLI
PSE
XDB-
C8
20
Aut
o 14
3
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S
NO
TS
Q Q
uant
um
10
AC
N
QuE
ChE
RS
VF
5 M
S 3
Both
043
Tent
ativ
e d
etec
ted
0
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
YES
Api
320
0QT
10
AC
N
DSP
E Ph
enom
enex
fusio
n 10
A
uto
200
Dai
ly
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch B
atc
h
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.2
Sp
ectru
m
mat
ch
(reve
rsed
) G
C
MSD
IT
EI
+ YE
S YE
S 20
-10.
000
µg/k
g YE
S V
aria
n Sa
turn
20
00
15
Ace
tone
/PE/
DC
M
NO
V
F-5-
ms
5 Bo
th
550
Qua
rterly
048
Con
firm
ed w
ith
seco
nd m
etho
d
4
G
C
MSD
TO
F EI
YES
YES
0.00
5 YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o m
icro
GC
10
A
CN
DB-
5MS
3 Bo
th
150
Dai
ly
053
Tent
ativ
e d
etec
ted
9
3
SIM
Ions
G
C
MSD
Q
EI
+
NO
N
O
>0.0
5 m
g/kg
YE
S Th
erm
o D
SQ
10
DC
M
Dia
tom
aceo
us
earth
1 Bo
th
400
Ever
y 6
Mon
ths
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
73
NA
PR
OP
AM
IDE
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S A
gile
nt 5
973
iner
t 5
AC
N
HP
-5 M
SUI
5 Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
4.2
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
460,
12
90HP
LC
10
EtO
Ac
Non
e W
ate
rs, H
SS T
3,
150
x 2.
1mm
2
Both
50
0 Ea
ch B
atc
h
Con
firm
ed w
ith
seco
nd m
etho
d
-0.6
0.
9
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
006
Tent
ativ
e d
etec
ted
<1
3 d
iagn
ostic
io
ns
GC
M
SD
Q
EI
+ YE
S YE
S >0
.010
m
g/kg
YE
S Tr
ace
DSQ
15
A
CN
PS
A/C
18
DB5
MS
0.8
Both
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Agi
lent
68
90/5
973
10
AC
N
DSP
E HP
-5M
S 2
Man
ual
183
Each
Ba
tch
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
009
Tent
ativ
e d
etec
ted
2
trans
ition
s G
C
MSD
Q
EI
+
NO
N
O
N
O
Ther
mo
TSQ
Q
uant
um
10
AC
N
DSP
E TG
-5M
S 30
m
2 M
anua
l 18
0 Ea
ch B
atc
h
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
5.4
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
M
etha
nol
NO
C
18
5 Bo
th
211
Alw
ays
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
74
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
NA
PR
OP
AM
IDE
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
0.01
N
O
6460
10
A
CN
PS
A
C18
-XB
2 Bo
th
440
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
018
Tent
ativ
e d
etec
ted
5
5 ac
cura
te
mas
s LC
O
rbitr
ap
O
rbitr
ap
ES
I +
YES
YES
0.01
- 0.
05
mg/
kg
YES
Ther
mo
Exac
tive
10
AC
N
PSA
C
18
5 Bo
th
120
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 10
N
O
Agi
lent
689
0 15
A
ceto
ne/P
E/D
CM
N
one
95%
met
hyl
5% p
heny
l silo
xane
2
Aut
o
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
bSci
ex
10
AC
N
DSP
E C
18
5 A
uto
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
Q
ESI
+ YE
S YE
S 0.
01
NO
A
PI 5
500
10
AC
N
Pu
rsui
t XRs
Ultr
a
3 Bo
th
250
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
96
4 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.2
8 1.
85
isoto
pe, 2
ions
<
5ppm
LC
M
SD
Orb
itra
p
ESI
+ N
O
NO
0.
01-0
.1
YES
Exac
tive
10
AC
N
Non
e C
18 A
tlant
is T3
5
Both
57
0 Ea
ch B
atc
h
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 2.
5 %
2.
5 tra
nsiti
on 1
an
d 2
LC
M
SD
Q-T
RAP
ESI
+ YE
S YE
S 0.
01
YES
3200
Qtra
p
10
AC
N
DSP
E C
18
50
Aut
o 52
1 Ev
ery
Wee
k
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 0.
7 3
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Var
ian
3800
GC
+
320-
MS
10
AC
N
DSP
E w
ith P
SA
VF-
1ms
4 Bo
th
302
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
75
NA
PR
OP
AM
IDE
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
028
Con
firm
ed w
ith
seco
nd m
etho
d
272.
1>12
9.3,
27
2.1>
171.
1 LC
M
SD
Q
ESI
+ N
O
NO
10-
100
ppb
N
O
LC: A
gile
nt 1
200,
M
S: A
PI 4
000
QTR
AP
10
AC
N
QuE
ChE
RS
with
out P
SA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2.
1 m
m, 5
µm
2
Aut
o 59
1
029
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
NO
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
030
Tent
ativ
e d
etec
ted
GC
Q
EI
+ YE
S YE
S 0.
02
NO
V
aria
n 45
0 15
A
ceto
ne
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
005-
0.12
5 µg
/ml
NO
UPLC
-MSM
S (W
ate
rs A
quity
UP
LC sy
stem
, A
PI 5
000
Trip
elqu
adro
pol,
Scie
x
10
EtO
Ac
Filte
r HS
S T3
2
Both
37
3 Ea
ch B
atc
h
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
m
in 3
ions
G
C
MSD
Q
EI
+
YES
NO
0.
01
YES
Agi
lent
GC
-MSD
78
90A
/597
5c
10
AC
N
PSA
, C18
HP
-5M
S 1
Aut
o 92
7
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
Qua
ttro
Prem
ier
10
AC
N
DSP
E (P
SA/M
gSO
4)
RP-1
8 en
dca
pped
5
Both
18
6 Ea
ch B
atc
h
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Tent
ativ
e d
etec
ted
N
one
Non
e 2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
PI 4
000
10
AC
N
DSP
E W
ate
rs-C
18
2,1x
50m
mx1
,7‚µ
m
5 A
uto
600
Ever
y W
eek
039
Tent
ativ
e d
etec
ted
GC
M
SD
Q
EI
+ N
O
NO
YES
HP59
73 M
SD
10
AC
N
DSP
E HP
-5M
SI
20
Both
62
4 N
o st
and
ard
us
ed
040
Con
firm
ed w
ith
seco
nd m
etho
d
11
3
LC
TO
F ES
I +
NO
N
O
YE
S A
gile
nt 6
230
10
AC
N
Non
e Ec
lipse
C18
3
Aut
o ap
rox
500
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5%
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 0.
005
mg/
kg
NO
V
ARI
AN
CP-
3800
M
S-32
0 10
A
CN
PS
A
VF-
5MS
1 A
uto
210
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
76
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
NA
PR
OP
AM
IDE
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
Q
uEC
hERS
C
18 A
qua
10
Bo
th
043
Tent
ativ
e d
etec
ted
0
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
YES
Api
320
0QT
10
AC
N
DSP
E Ph
enom
enex
fusio
n 10
A
uto
200
Dai
ly
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch B
atc
h
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5
Sp
ectru
m
mat
ch
(reve
rsed
) G
C
MSD
IT
EI
+ YE
S YE
S 20
-10.
000
µg/k
g YE
S V
aria
n Sa
turn
20
00
15
Ace
tone
/PE/
DC
M
NO
V
F-5-
ms
5 Bo
th
550
Qua
rterly
048
Con
firm
ed w
ith
seco
nd m
etho
d
3
G
C
MSD
TO
F EI
YES
YES
0.01
YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
XEV
O T
Q
MS
10
AC
N
BE
H C
18 1
,7µm
3
Both
60
D
aily
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.01
7
Qio
n ra
tio
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01-0
.05
YES
Agi
lent
68
90G
C+5
975M
S 10
A
CN
D
SPE
REST
EK-5
MS
50
Both
16
8 D
aily
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
77
PR
OM
ETR
YN
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S A
gile
nt 5
973
iner
t 5
AC
N
HP
-5 M
SUI
5 Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
5.3
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
460,
12
90HP
LC
10
EtO
Ac
Non
e W
ate
rs, H
SS T
3,
150
x 2.
1mm
2
Both
50
0 Ea
ch B
atc
h
Con
firm
ed w
ith
seco
nd m
etho
d
3 0.
9
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
006
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
<2
<1
3 d
iagn
ostic
io
ns
GC
M
SD
Q
EI
+ YE
S YE
S >0
.010
m
g/kg
YE
S Tr
ace
DSQ
15
A
CN
PS
A/C
18
DB5
MS
0.8
Both
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Agi
lent
68
90/5
973
10
AC
N
DSP
E HP
-5M
S 2
Man
ual
183
Each
Ba
tch
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
009
Tent
ativ
e d
etec
ted
2
trans
ition
s G
C
MSD
Q
EI
+
NO
N
O
N
O
Ther
mo
TSQ
Q
uant
um
10
AC
N
DSP
E TG
-5M
S 30
m
2 M
anua
l 18
0 Ea
ch B
atc
h
010
Tent
ativ
e d
etec
ted
2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
BI40
00
10
AC
N
NO
C
18
55
Both
ap
rox
580
Alw
ays
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
4.7
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
78
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
PR
OM
ETR
YN
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S 0.
01
NO
70
00B
10
AC
N
PSA
D
B-5M
S UI
2
Both
44
0
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
017
Tent
ativ
e d
etec
ted
GC
M
SD
TOF
EI
N
O
NO
YES
LEC
O P
EGA
SUS
15
Ace
tone
/PE/
DC
M
NO
D
B-5
1 Bo
th
018
Tent
ativ
e d
etec
ted
RT
lo
ckin
g
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01 -
0.05
m
g/kg
YE
S A
gile
nt M
SD
5975
B 10
A
CN
PS
A
HP5
10
Both
>
600
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
10
NO
A
gile
nt 6
490
15
AC
N
PSA
C
18
5 A
uto
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
YES
YES
0.01
N
O
agile
nt
10
AC
N
DSP
E HP
5MS
1
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
Q
ESI
+ YE
S YE
S 0.
01
NO
A
PI 5
500
10
AC
N
Pu
rsui
t XRs
Ultr
a
3 Bo
th
250
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
3
mas
ses
GC
M
SD
IT EI
+
YES
YES
0.01
YE
S V
aria
n Sa
turn
20
00
10
AC
N
PSA
V
acto
rFou
r 5 M
S 5
Aut
o 50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
91
7 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
Con
firm
ed w
ith
seco
nd m
etho
d
0.28
1.
2 iso
tope
, 2 io
ns
< 5p
pm
LC
MSD
O
rbitr
ap
ES
I +
NO
N
O
0.01
-0.1
YE
S Ex
activ
e 10
A
CN
N
one
C18
Atla
ntis
T3
5 Bo
th
570
Each
Ba
tch
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3 0.
7 3
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Var
ian
3800
GC
+
320-
MS
10
AC
N
DSP
E w
ith P
SA
VF-
1ms
4 Bo
th
302
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
79
PR
OM
ETR
YN
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
028
Con
firm
ed w
ith
seco
nd m
etho
d
242.
2>20
0.1,
24
2.2>
158.
1 LC
M
SD
Q
ESI
+ N
O
NO
10-
100
ppb
N
O
LC: A
gile
nt 1
200,
M
S: A
PI 4
000
QTR
AP
10
AC
N
QuE
ChE
RS
with
out P
SA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2.
1 m
m, 5
µm
2
Aut
o 59
1
029
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
005-
0.12
5 µg
/ml
NO
UPLC
-MSM
S (W
ate
rs A
quity
UP
LC sy
stem
, A
PI 5
000
Trip
elqu
adro
pol,
Scie
x
10
EtO
Ac
Filte
r HS
S T3
2
Both
37
3 Ea
ch B
atc
h
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5
m
in 3
ions
G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S A
gile
nt G
C-M
SD
7890
A/5
975c
10
A
CN
PS
A, C
18
HP-5
MS
1 A
uto
927
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o M
icro
10
A
CN
D
SPE
(PSA
/MgS
O4)
HP
-5M
S 5
Both
11
0 Ea
ch B
atc
h
035
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
NO
N
O
YE
S A
gile
nt 6
890N
10
A
CN
D
SPE
DB-
5 2
Aut
o
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
Non
e N
one
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
D
SPE
Wa
ters
-C18
2,
1x50
mm
x1,7
‚µm
5
Aut
o 60
0 Ev
ery
Wee
k
039
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5973
MSD
10
A
CN
D
SPE
HP-5
MSI
20
Bo
th
113
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
80
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
PR
OM
ETR
YN
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
040
Con
firm
ed w
ith
seco
nd m
etho
d
30
3
LC
TO
F ES
I +
NO
N
O
YE
S A
gile
nt 6
230
10
AC
N
Non
e Ec
lipse
C18
3
Aut
o ap
rox
500
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5%
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 0.
005
mg/
kg
NO
V
ARI
AN
CP-
3800
M
S-32
0 10
A
CN
PS
A
VF-
5MS
1 A
uto
210
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
Q
uEC
hERS
C
18 A
qua
10
Bo
th
043
Tent
ativ
e d
etec
ted
0
0 sc
an
GC
M
SD
IT EI
YES
YES
0.01
0 YE
S V
aria
n Sa
turn
40
00
10
AC
N
DSP
E V
aria
n V
F 1
Aut
o 26
0 D
aily
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
G
C
MSD
Q
EI
+
YES
YES
N
O
Ther
mo
TSQ
Q
uant
um G
C
10
Ace
tone
/PE/
DC
M
Na2
SO4
RXi-5
SIL
MS
1 Bo
th
199
Each
Ba
tch
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
Sp
ectru
m
mat
ch
(reve
rsed
) G
C
MSD
IT
EI
+ YE
S YE
S 20
-10.
000
µg/k
g YE
S V
aria
n Sa
turn
20
00
15
Ace
tone
/PE/
DC
M
NO
V
F-5-
ms
5 Bo
th
550
Each
Ba
tch
048
Con
firm
ed w
ith
seco
nd m
etho
d
4
G
C
MSD
TO
F EI
YES
YES
0.00
5 YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
XEV
O T
Q
MS
10
AC
N
BE
H C
18 1
,7µm
3
Both
60
D
aily
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.05
4
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
-0.0
5 YE
S A
gile
nt 1
200
LC+6
460Q
10
A
CN
D
SPE
YMC
Tria
rt C
18
2*10
0 m
m 3
µm
5 Bo
th
354
Dai
ly
051
Tent
ativ
e d
etec
ted
0.5
qual
ifier
s G
C
MSD
IT
EI
N
O
NO
YES
varia
n G
CM
S 40
00
10
AC
N
PSA
va
rian
fact
or fo
ur
5 Bo
th
053
Tent
ativ
e d
etec
ted
2
3
SIM
Ions
G
C
MSD
Q
EI
+
NO
N
O
>0.0
5 m
g/kg
YE
S Th
erm
o D
SQ
10
DC
M
Dia
tom
aceo
us
earth
1 Bo
th
400
Ever
y 6
Mon
ths
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
81
PR
OP
AQ
UIZ
AFO
P
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
460,
12
90HP
LC
10
EtO
Ac
Non
e W
ate
rs, H
SS T
3,
150
x 2.
1mm
2
Both
50
0 Ea
ch B
atc
h
Con
firm
ed w
ith
seco
nd m
etho
d
1.2
3.7
LC
M
SD
TOF
ESI
+ N
O
NO
N
A
YES
Bruk
er M
axis
10
EtO
Ac
Non
e A
ccla
im R
SLC
120
C
18, 2
,1*1
00 m
m
1 Bo
th
1000
Ea
ch B
atc
h
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
410
10
AC
N
DSP
E Ec
lipse
XD
B-C
18
4 M
anua
l 13
9 Ea
ch B
atc
h
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
0.01
N
O
6460
10
A
CN
PS
A
C18
-XB
2 Bo
th
440
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
Q-T
OF
ESI
+ N
O
NO
0.
01
Br
uker
Max
is 10
A
CN
Both
70
0 Ea
ch B
atc
h
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
028
Tent
ativ
e d
etec
ted
44
4.1>
299.
1,
444.
1>10
0.0
LC
MSD
Q
ES
I +
NO
N
O 1
0-10
0 pp
b
NO
LC
: Agi
lent
120
0,
MS:
API
400
0 Q
TRA
P 10
A
CN
Q
uEC
hERS
w
ithou
t PSA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2
.1 m
m, 5
µm
2
Aut
o 59
1
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
YE
S V
aria
n 32
0 15
A
CN
C18
10
A
uto
150
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
82
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
PR
OP
AQ
UIZ
AFO
P
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
005-
0.4
µg/m
l N
O
UPLC
-MSM
S (W
ate
rs A
quity
UP
LC sy
stem
, A
PI 5
000
Trip
elqu
adro
pol,
Scie
x
10
EtO
Ac
Filte
r HS
S T3
2
Both
37
3 Ea
ch B
atc
h
032
Tent
ativ
e d
etec
ted
0
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
W
ate
rs A
cqui
ty
TQD
10
M
etha
nol
Filte
r C
18
6 A
uto
150
Alw
ays
034
Tent
ativ
e d
etec
ted
3
trans
ition
s LC
Q
ESI
+ N
O
NO
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
A
CN
D
SPE
(PSA
/MgS
O4)
RP
-18
end
capp
ed
5 Bo
th
500
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Tent
ativ
e d
etec
ted
N
one
Non
e 2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
PI 4
000
10
AC
N
DSP
E W
ate
rs-C
18
2,1x
50m
mx1
,7‚µ
m
5 A
uto
600
Ever
y W
eek
039
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
444.
1->1
00.1
, 44
4.1-
>299
.1
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
641
0B
10
AC
N
DSP
E C
18
2 Bo
th
187
Each
Ba
tch
040
Con
firm
ed w
ith
seco
nd m
etho
d
4 5
LC
TOF
ESI
+ N
O
NO
YES
Agi
lent
623
0 10
A
CN
N
one
Eclip
se C
18
3 A
uto
apro
x 50
0
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch B
atc
h
048
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2.3
LC
MSD
Q
ES
I +
YES
YES
0.00
5 N
O
Agi
lent
641
0 10
A
CN
D
SPE(
PSA
) Lu
na C
18
5 Bo
th
350
Dai
ly
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
XEV
O
TQ
MS
10
AC
N
BE
H C
18 1
,7µm
3
Both
60
D
aily
053
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 M
RM
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.005
m
g/kg
N
O
API
4000
10
A
CN
PS
A
10
Bo
th
180
Ever
y M
onth
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
83
PY
RIF
ENO
X
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
3.0
and
3.
9
G
C
MSD
Q
EI
+
YES
YES
not
valid
ated
YE
S A
T 59
75
10
AC
N
SPE
HP5-
MS
10
Aut
o ap
rox
750
Alw
ays
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Con
firm
ed w
ith
seco
nd m
etho
d
3 0.
6
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
460,
12
90HP
LC
10
EtO
Ac
Non
e W
ate
rs, H
SS T
3,
150
x 2.
1mm
2
Both
50
0 Ea
ch B
atc
h
006
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
<2
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.010
m
g/kg
N
O
Wa
ters
qua
ttro
prem
ier
15
AC
N
Non
e BE
H C
18
3 Bo
th
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
009
Tent
ativ
e d
etec
ted
2
trans
ition
s G
C
MSD
Q
EI
+
NO
N
O
N
O
Ther
mo
TSQ
Q
uant
um
10
AC
N
DSP
E TG
-5M
S 30
m
2 M
anua
l 18
0 Ea
ch B
atc
h
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S 0.
01
NO
70
00B
10
AC
N
PSA
D
B-5M
S UI
2
Both
44
0
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
84
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
PY
RIF
ENO
X
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
018
Tent
ativ
e d
etec
ted
RT
lo
ckin
g
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01 -
0.05
m
g/kg
YE
S A
gile
nt M
SD
5975
B 10
A
CN
PS
A
HP5
10
Both
>
600
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 10
N
O
Agi
lent
689
0 15
A
ceto
ne/P
E/D
CM
N
one
95%
met
hyl
5% p
heny
l silo
xane
2
Aut
o
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
YES
YES
0.01
N
O
agile
nt
10
AC
N
DSP
E HP
5MS
1
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, M
S A
PI 3
000
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
023
Con
firm
ed w
ith
seco
nd m
etho
d
G
C
MSD
TO
F
YE
S YE
S 0.
01
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E Ph
enom
enen
x
ZB-5
MS
3 Bo
th
750
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
3
mas
ses
GC
M
SD
IT EI
+
YES
YES
0.01
YE
S V
aria
n Sa
turn
20
00
10
AC
N
PSA
V
acto
rFou
r 5 M
S 5
Aut
o 50
0 D
aily
025
Con
firm
ed w
ith
seco
nd m
etho
d
-0.1
6 0.
22
isoto
pe, t
wo
isom
er p
eaks
LC
M
SD
Orb
itra
p
ESI
+ N
O
NO
0.
01-0
.1
YES
Exac
tive
10
AC
N
Non
e C
18 A
tlant
is T3
5
Both
57
0 Ea
ch B
atc
h
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
91
6 sp
ectru
m, t
wo
isom
er p
eaks
G
C
MSD
TO
F EI
+
YES
YES
0.01
-0.1
YE
S Le
co P
egas
us IV
10
A
CN
D
SPE
(PSA
) RT
X-C
L pe
st
10
Aut
o 55
7 Ea
ch B
atc
h
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 2.
5 %
2.
5 tra
nsiti
on 1
an
d 2
LC
M
SD
Q-T
RAP
ESI
+ YE
S YE
S 0.
01
YES
3200
Qtra
p
10
AC
N
DSP
E C
18
50
Aut
o 52
1 Ev
ery
Wee
k
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 0.
7 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
V
aria
n Pr
o St
ar
+320
-MS
10
AC
N
DSP
E w
ith P
SA
Rest
ek U
ltra
C18
10
Bo
th
302
Each
Ba
tch
028
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
297.
1>93
.1,
295.
1>92
.9
LC
MSD
Q
ES
I +
YES
YES
LOQ
: 8
ppb
N
O
LC: A
gile
nt 1
200,
M
S: A
PI 4
000
QTR
AP
10
AC
N
QuE
ChE
RS
with
out P
SA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2.
1 m
m, 5
µm
2
Aut
o
029
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
NO
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
85
PY
RIF
ENO
X
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
005-
0.4
µg/m
l N
O
UPLC
-MSM
S (W
ate
rs A
quity
UP
LC sy
stem
, A
PI 5
000
Trip
elqu
adro
pol,
Scie
x
10
EtO
Ac
Filte
r HS
S T3
2
Both
37
3 Ea
ch B
atc
h
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.8
min
3 io
ns
GC
M
SD
Q
EI
+ YE
S N
O
0.01
YE
S A
gile
nt G
C-M
SD
7890
A/5
975c
10
A
CN
PS
A, C
18
HP-5
MS
1 A
uto
927
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
Qua
ttro
Prem
ier
10
AC
N
DSP
E (P
SA/M
gSO
4)
RP-1
8 en
dca
pped
5
Both
18
6 Ea
ch B
atc
h
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
038
Tent
ativ
e d
etec
ted
N
one
Non
e 2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
PI 4
000
10
AC
N
DSP
E W
ate
rs-C
18
2,1x
50m
mx1
,7‚µ
m
5 A
uto
600
Ever
y W
eek
039
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
+
YES
YES
0.02
YE
S HP
5973
MSD
10
A
CN
D
SPE
HP-5
MSI
20
Bo
th
113
Each
Ba
tch
040
Con
firm
ed w
ith
seco
nd m
etho
d
2 4
LC
TOF
ESI
+ N
O
NO
YES
Agi
lent
623
0 10
A
CN
N
one
Eclip
se C
18
3 A
uto
apro
x 50
0
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5%
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 0.
005
mg/
kg
NO
V
ARI
AN
CP-
3800
M
S-32
0 10
A
CN
PS
A
VF-
5MS
1 A
uto
210
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
Q
uEC
hERS
C
18 A
qua
10
Bo
th
043
Tent
ativ
e d
etec
ted
0
0 sc
an
GC
M
SD
IT EI
YES
YES
0.01
0 YE
S V
aria
n Sa
turn
40
00
10
AC
N
DSP
E V
aria
n V
F 1
Aut
o 26
0 D
aily
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch B
atc
h
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
86
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
PY
RIF
ENO
X
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
12
2
trans
ition
s +
ion
ratio
LC
M
SD
Q
ESI
+ YE
S YE
S 5-
1000
µg
/kg
NO
W
ate
rs Q
uattr
o Pr
emie
r XE
15
Ace
tone
/PE/
DC
M
NO
A
cqui
ty B
EH
(100
x2.1
mm
i.d
.) 5
Both
23
0 Ea
ch B
atc
h
048
Con
firm
ed w
ith
seco
nd m
etho
d
4
G
C
MSD
TO
F EI
YES
YES
0.00
5 YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o m
icro
GC
10
A
CN
DB-
5MS
3 Bo
th
150
Dai
ly
053
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 M
RM
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.005
m
g/kg
N
O
API
4000
10
A
CN
PS
A
10
Bo
th
180
Ever
y M
onth
Con
firm
ed w
ith
seco
nd m
etho
d
0
3 SI
M Io
ns
GC
M
SD
Q
EI
+ N
O
NO
>0
.05
mg/
kg
YES
Ther
mo
DSQ
10
D
CM
D
iato
mac
eous
ea
rth
1
Both
40
0 Ev
ery
6 M
onth
s
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
87
SP
INO
SA
D
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library (pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
002
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
API
4000
10
A
CN
N
one
C18
5
Man
ual
004
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
460,
12
90HP
LC
10
EtO
Ac
Non
e W
ate
rs, H
SS T
3,
150
x 2.
1mm
2
Both
50
0 Ea
ch B
atc
h
006
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
<2
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.010
m
g/kg
N
O
Wa
ters
qua
ttro
prem
ier
15
AC
N
Non
e BE
H C
18
10
Both
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
410
10
AC
N
DSP
E Ec
lipse
XD
B-C
18
4 M
anua
l 13
9 Ea
ch B
atc
h
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
ABI
4000
10
A
CN
N
O
C18
55
Bo
th
apro
x 58
0 A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
LC
M
SD
Q-T
RAP
ESI
+ YE
S YE
S 0.
01
NO
32
00q
trap
10
A
CN
PS
A
T-3
5 M
anua
l 17
0 1
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
M
etha
nol
NO
C
18
5 Bo
th
211
Alw
ays
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
0.01
N
O
6460
10
A
CN
PS
A
C18
-XB
2 Bo
th
440
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
88
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
SP
INO
SA
D
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library (pesticides ONLY)
Standard Solution Frequency
017
Tent
ativ
e d
etec
ted
LC
MSD
Q
ES
I
NO
N
O
Agi
lent
641
0 15
A
ceto
ne/P
E/D
CM
N
O
C-1
8 3
Both
018
Tent
ativ
e d
etec
ted
5
5 ac
cura
te
mas
s LC
O
rbitr
ap
O
rbitr
ap
ES
I +
YES
YES
0.01
- 0.
05
mg/
kg
YES
Ther
mo
Exac
tive
10
AC
N
PSA
C
18
5 Bo
th
120
Alw
ays
019
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
10
NO
A
gile
nt 6
490
15
AC
N
PSA
C
18
5 A
uto
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
bSci
ex
10
AC
N
DSP
E C
18
5 A
uto
200
Alw
ays
021
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
15
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
HP
LC A
gile
nt
1100
, MS
A
PI 3
000
10
AC
N
DSP
E
(PSA
, MgS
O4)
C
18 3
µ 50
x2m
m
10
Both
55
0 A
lway
s
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
Q
ESI
+ YE
S YE
S 0.
01
NO
A
PI 5
500
10
AC
N
Pu
rsui
t XRs
Ultr
a
3 Bo
th
250
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.2
7 1.
3 iso
tope
, 2 io
ns
< 5p
pm
LC
MSD
O
rbitr
ap
ES
I +
NO
N
O
0.01
-0.1
YE
S Ex
activ
e 10
A
CN
N
one
C18
Atla
ntis
T3
5 Bo
th
570
Each
Ba
tch
Tent
ativ
e d
etec
ted
0.
22
1.4
othe
r sp
inos
yns
LC
MSD
O
rbitr
ap
ES
I +
NO
N
O
0.01
-0.1
YE
S Ex
activ
e 10
A
CN
N
one
C18
Atla
ntis
T3
5 Bo
th
570
Each
Ba
tch
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 2.
5 %
2.
5 tra
nsiti
on 1
an
d 2
LC
M
SD
Q-T
RAP
ESI
+ YE
S YE
S 0.
01
YES
3200
Qtra
p
10
AC
N
DSP
E C
18
50
Aut
o 52
1 Ev
ery
Wee
k
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3 0.
7 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
V
aria
n Pr
o St
ar
+320
-MS
10
AC
N
DSP
E w
ith P
SA
Rest
ek U
ltra
C18
10
Bo
th
302
Each
Ba
tch
028
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
732.
6>14
2.2,
73
2.6>
98.2
LC
M
SD
Q
ESI
+ YE
S YE
S LO
Q: 8
pp
b
NO
LC
: Agi
lent
120
0,
MS:
API
400
0 Q
TRA
P 10
A
CN
Q
uEC
hERS
w
ithou
t PSA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2
.1 m
m, 5
µm
2
Aut
o
029
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
89
SP
INO
SA
D
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library (pesticides ONLY)
Standard Solution Frequency
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
005-
0.4
µg/m
l N
O
UPLC
-MSM
S (W
ate
rs A
quity
UP
LC sy
stem
, A
PI 5
000
Trip
elqu
adro
pol,
Scie
x
10
EtO
Ac
Filte
r HS
S T3
2
Both
37
3 Ea
ch B
atc
h
032
Tent
ativ
e d
etec
ted
0
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
W
ate
rs A
cqui
ty
TQD
10
M
etha
nol
Filte
r C
18
6 A
uto
150
Alw
ays
034
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
Qua
ttro
Prem
ier
10
AC
N
DSP
E (P
SA/M
gSO
4)
RP-1
8 en
dca
pped
5
Both
18
6 Ea
ch B
atc
h
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
037
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MS/
MS
Q
ESI
+ YE
S YE
S 0.
010
NO
40
00 Q
TRA
P 10
A
CN
D
SPE
C18
hyd
ro
Phen
omen
ex
40
Man
ual
A
lway
s
038
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
Non
e N
one
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
D
SPE
Wa
ters
-C18
2,
1x50
mm
x1,7
‚µm
5
Aut
o 60
0 Ev
ery
Wee
k
039
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
732.
4->1
42.0
, 73
2.4-
>98.
1,
746.
5->1
42.1
, 74
6.5-
>98.
1
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
641
0B
10
AC
N
DSP
E C
18
2 Bo
th
187
Each
Ba
tch
040
Con
firm
ed w
ith
seco
nd m
etho
d
1 7
LC
TOF
ESI
+ N
O
NO
YES
Agi
lent
623
0 10
A
CN
N
one
Eclip
se C
18
3 A
uto
apro
x 50
0
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2.5%
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.00
5 m
g/kg
N
O
AG
ILEN
T
G-6
410A
10
A
CN
PS
A
ZORB
AX-
ECLI
PSE
XDB-
C8
20
Aut
o 14
3
042
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
N
O
API
400
0 10
A
CN
Q
uEC
hERS
C
18 A
qua
10
Bo
th
043
Tent
ativ
e d
etec
ted
0
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
YES
Api
320
0QT
10
AC
N
DSP
E Ph
enom
enex
fusio
n 10
A
uto
200
Dai
ly
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
LC
M
SD
Q
ESI
+ N
O
NO
W
ate
rs X
evo
10
Ace
tone
/PE/
DC
M
Na2
SO4
C18
2
Both
28
6 Ea
ch B
atc
h
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
90
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
SP
INO
SA
D
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library (pesticides ONLY)
Standard Solution Frequency
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s +
ion
ratio
LC
M
SD
Q
ESI
+ YE
S YE
S 5-
1000
µg
/kg
NO
W
ate
rs Q
uattr
o Pr
emie
r XE
15
Ace
tone
/PE/
DC
M
NO
A
cqui
ty B
EH
(100
x2.1
mm
i.d
.) 5
Both
23
0 Ea
ch B
atc
h
048
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1.2
LC
MSD
Q
ES
I +
YES
YES
0.00
5 N
O
Agi
lent
641
0 10
A
CN
D
SPE(
PSA
) Lu
na C
18
5 Bo
th
350
Dai
ly
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
XEV
O
TQ M
S 10
A
CN
BEH
C18
1,7
µm
3 Bo
th
60
Dai
ly
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.07
8
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
-0.0
5 YE
S A
gile
nt 1
200
LC+6
460Q
10
A
CN
D
SPE
YMC
Tria
rt C
18
2*10
0 m
m 3
µm
5 Bo
th
354
Dai
ly
051
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.05
ABS
ciex
API
200
0 10
A
CN
PS
A
wat
ers A
tlant
is 5
Aut
o 11
7 Ea
ch B
atc
h
053
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3
2 M
RM
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S >0
.005
m
g/kg
N
O
API
4000
10
A
CN
PS
A
10
Bo
th
180
Ever
y M
onth
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
91
TER
BA
CIL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S A
gile
nt 5
973
iner
t 5
AC
N
HP
-5 M
SUI
5 Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
8.0
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I -
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
006
Tent
ativ
e d
etec
ted
<1
3 d
iagn
ostic
io
ns
GC
M
SD
Q
EI
+ YE
S YE
S >0
.010
m
g/kg
YE
S Tr
ace
DSQ
15
A
CN
PS
A/C
18
DB5
MS
0.8
Both
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Agi
lent
68
90/5
973
10
AC
N
DSP
E HP
-5M
S 2
Man
ual
183
Each
Ba
tch
008
Tent
ativ
e d
etec
ted
5
GC
M
SD
TOF
EI
N
O
NO
YES
GC
T M
icro
mas
s 12
.5
EtO
Ac
GPC
ca
pilla
ry
1 A
uto
NIS
T lib
rary
W
e d
o no
t ha
ve a
st
and
ard
009
Tent
ativ
e d
etec
ted
2
trans
ition
s G
C
MSD
Q
EI
+
NO
N
O
N
O
Ther
mo
TSQ
Q
uant
um
10
AC
N
DSP
E TG
-5M
S 30
m
2 M
anua
l 18
0 Ea
ch B
atc
h
010
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.7
2
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
- YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S 0.
01
NO
70
00B
10
AC
N
PSA
D
B-5M
S UI
2
Both
44
0
017
Tent
ativ
e d
etec
ted
GC
M
SD
TOF
EI
N
O
NO
YES
LEC
O P
EGA
SUS
15
Ace
tone
/PE/
DC
M
NO
D
B-5
1 Bo
th
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
92
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
TER
BA
CIL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
018
Tent
ativ
e d
etec
ted
RT
lo
ckin
g
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01 -
0.05
m
g/kg
YE
S A
gile
nt M
SD
5975
B 10
A
CN
PS
A
HP5
10
Both
>
600
Alw
ays
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
YES
YES
0.01
N
O
agile
nt
10
AC
N
DSP
E HP
5MS
1
200
Alw
ays
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
IT ES
I -
YES
YES
0.01
N
O
10
A
CN
Both
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
2
x M
RM
LC
MSD
Q
ES
I -
YES
YES
0.01
N
O
AB
Scie
x A
PI
4000
10
A
CN
PS
A
Phen
omen
ex C
18
10
Both
50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.3
1.
7 iso
tope
, 2 io
ns
< 5p
pm
LC
MSD
O
rbitr
ap
ES
I +
NO
N
O
0.01
-0.1
YE
S Ex
activ
e 10
A
CN
N
one
C18
Atla
ntis
T3
5 Bo
th
570
Each
Ba
tch
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
93
9 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
026
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 0.
5 %
2.
5
GC
M
SD
ion
trap
EI
YES
YES
0.01
YE
S Tr
ap 4
000
- V
aria
n 10
A
CN
D
SPE
5%
1 µL
A
uto
450
Ever
y W
eek
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
4 0.
7 3
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Var
ian
3800
GC
+
320-
MS
10
AC
N
DSP
E w
ith P
SA
VF-
1ms
4 Bo
th
302
Each
Ba
tch
028
Tent
ativ
e d
etec
ted
Mat
ch w
ith
NIS
T Lib
rary
(M
atc
h 92
5,
rang
e 0-
1000
)
GC
M
SD
TOF
EI
N
O
NO
10-
100
ppb
YE
S G
CxG
C-T
OF
MS
Pega
sus 4
D
10
AC
N
QuE
ChE
RS
with
out P
SA
DB5
-MS
(30
m x
0,2
5 m
m x
0,2
5 µm
) in
the
1st D
imen
sion,
BP
X-50
(2 m
x 0
,1
mm
x 0
,1 µ
m) i
n th
e 2n
d D
imen
sion
10
Aut
o 50
0
029
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
NO
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
030
Tent
ativ
e d
etec
ted
GC
Q
EI
+ N
O
NO
0.
02
NO
V
aria
n 45
0 15
A
ceto
ne
V
5MS
1 A
uto
150
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
93
TER
BA
CIL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-4.1
min
3 io
ns
GC
M
SD
Q
EI
+ YE
S N
O
0.01
YE
S A
gile
nt G
C-M
SD
7890
A/5
975c
10
A
CN
PS
A, C
18
HP-5
MS
1 A
uto
927
034
Con
firm
ed w
ith
seco
nd m
etho
d
full
scan
G
C
MSD
Q
EI
+
NO
N
O
YE
S A
gile
nt 5
973
MSD
10
A
CN
D
SPE
(PSA
/MgS
O4)
HP
-5M
S 10
Bo
th
950
035
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
NO
N
O
YE
S A
gile
nt 6
890N
10
A
CN
D
SPE
DB-
5 2
Aut
o
036
Tent
ativ
e d
etec
ted
GC
M
SD
Q
EI
10
AC
N
5 A
uto
039
Tent
ativ
e d
etec
ted
GC
M
SD
Q
EI
+ N
O
NO
YES
HP59
73 M
SD
10
AC
N
DSP
E HP
-5M
SI
20
Both
62
4 N
o st
and
ard
us
ed
040
Con
firm
ed w
ith
seco
nd m
etho
d
17
8
LC
TO
F ES
I -
NO
N
O
YE
S A
gile
nt 6
230
10
AC
N
Non
e Ec
lipse
C18
3
Aut
o ap
rox
500
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5%
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 0.
005
mg/
kg
NO
V
ARI
AN
CP-
3800
M
S-32
0 10
A
CN
PS
A
VF-
5MS
1 A
uto
210
043
Tent
ativ
e d
etec
ted
0
0 2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
YES
Api
320
0QT
10
AC
N
DSP
E Ph
enom
enex
fusio
n 10
A
uto
200
Dai
ly
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
046
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
G
C
MSD
Q
EI
+
YES
YES
N
O
Ther
mo
TSQ
Q
uant
um G
C
10
Ace
tone
/PE/
DC
M
Na2
SO4
RXi-5
SIL
MS
1 Bo
th
199
Each
Ba
tch
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.7
Sp
ectru
m
mat
ch
(reve
rsed
) G
C
MSD
IT
EI
+ YE
S YE
S 20
-10.
000
µg/k
g YE
S V
aria
n Sa
turn
20
00
15
Ace
tone
/PE/
DC
M
NO
V
F-5-
ms
5 Bo
th
550
Qua
rterly
048
Con
firm
ed w
ith
seco
nd m
etho
d
6
G
C
MSD
TO
F EI
YES
YES
0.00
5 YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
94
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
TER
BA
CIL
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S
NO
W
ate
rs Q
uattr
o m
icro
GC
10
A
CN
DB-
5MS
3 Bo
th
150
Dai
ly
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.03
6
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
-0.0
5 YE
S A
gile
nt 1
200
LC+6
460Q
10
A
CN
D
SPE
YMC
Tria
rt C
18
2*10
0 m
m 3
µm
5 Bo
th
354
Dai
ly
051
Tent
ativ
e d
etec
ted
0.5
qual
ifier
s G
C
MSD
IT
EI
N
O
NO
YES
varia
n G
CM
S 40
00
10
AC
N
PSA
va
rian
fact
or fo
ur
5 Bo
th
053
Tent
ativ
e d
etec
ted
12
3 SI
M Io
ns
GC
M
SD
Q
EI
+ N
O
NO
>0
.05
mg/
kg
YES
Ther
mo
DSQ
10
D
CM
D
iato
mac
eous
ea
rth
1
Both
40
0 Ev
ery
6 M
onth
s
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
95
TER
BU
MET
ON
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library (pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
5.0
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
004
Tent
ativ
e d
etec
ted
N
A
NA
LC
MSD
Q
ES
I +
YES
NO
N
A
NO
A
gile
nt 6
460,
12
90HP
LC
10
EtO
Ac
Non
e W
ate
rs, H
SS T
3,
150
x 2.
1mm
2
Both
50
0 Ea
ch B
atc
h
Con
firm
ed w
ith
seco
nd m
etho
d
-1.2
0.
6
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
006
Tent
ativ
e d
etec
ted
<1
3 d
iagn
ostic
io
ns
GC
M
SD
Q
EI
+ YE
S YE
S >0
.010
m
g/kg
YE
S Tr
ace
DSQ
15
A
CN
PS
A/C
18
DB5
MS
0.8
Both
007
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1 N
one
G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Agi
lent
68
90/5
973
10
AC
N
DSP
E HP
-5M
S 2
Man
ual
183
Each
Ba
tch
008
Tent
ativ
e d
etec
ted
0.1
LC
M
SD
Q-T
OF
ESI
+ N
O
NO
YES
5600
trip
le T
OF
10
AC
N
Non
e re
vers
ed p
hase
2
Aut
o 60
0 W
e d
o no
t ha
ve a
st
and
ard
010
Tent
ativ
e d
etec
ted
3.
8
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S N
O
0.01
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
011
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
NA
G
C
MSD
Q
EI
+
NO
N
O
NA
YE
S 57
90 m
sd
10
AC
N
PSA
HP
-5M
S 20
A
uto
600
apro
x 0-
1
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
GC
Q
EI
+ YE
S YE
S 0.
01
NO
70
00B
10
AC
N
PSA
D
B-5M
S UI
2
Both
44
0
016
Con
firm
ed w
ith
seco
nd m
etho
d
MSD
Q
C
I +
YES
YES
0.00
5 N
O
LC-M
S/M
S (W
ate
rs)
15
AC
N
QuE
ChE
RS
C18
10
Bo
th
370
Alw
ays
017
Tent
ativ
e d
etec
ted
GC
M
SD
TOF
EI
N
O
NO
YES
LEC
O P
EGA
SUS
15
Ace
tone
/PE/
DC
M
NO
D
B-5
1 Bo
th
018
Tent
ativ
e d
etec
ted
RT
lo
ckin
g
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01 -
0.05
m
g/kg
YE
S A
gile
nt M
SD
5975
B 10
A
CN
PS
A
HP5
10
Both
>
600
Alw
ays
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
96
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
TER
BU
MET
ON
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library (pesticides ONLY)
Standard Solution Frequency
020
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
bSci
ex
10
AC
N
DSP
E C
18
5 A
uto
200
Alw
ays
022
Tent
ativ
e d
etec
ted
0.
5 0.
05
LC
M
SD
TOF
ESI
+ YE
S YE
S
YES
LCT
PREM
IER
XE
15
MIN
I LUK
E N
O
C-1
8 7
Aut
o 34
3 Ev
ery
Da
y
023
Con
firm
ed w
ith
seco
nd m
etho
d
LC
Q
ESI
+ YE
S YE
S 0.
01
NO
A
PI 5
500
10
AC
N
Pu
rsui
t XRs
Ultr
a
3 Bo
th
250
Each
Ba
tch
024
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.1
3
mas
ses
GC
M
SD
IT EI
+
YES
YES
0.05
YE
S V
aria
n Sa
turn
20
00
10
AC
N
PSA
V
acto
rFou
r 5 M
S 5
Aut
o 50
0 D
aily
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
-0.1
6 -1
.5
isoto
pe, 2
ions
<
5ppm
LC
M
SD
Orb
itra
p
ESI
+ N
O
NO
0.
01-0
.1
YES
Exac
tive
10
AC
N
Non
e C
18 A
tlant
is T3
5
Both
57
0 Ea
ch B
atc
h
025
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 20
75
5 sp
ectru
m
GC
M
SD
TOF
EI
+ YE
S YE
S 0.
01-0
.1
YES
Leco
Peg
asus
IV
10
AC
N
DSP
E (P
SA)
RTX-
CL
pest
10
A
uto
557
Each
Ba
tch
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
< 0.
5 %
2.
5
GC
M
SD
ion
trap
EI
YES
YES
0.01
YE
S Tr
ap 4
000
- V
aria
n 10
A
CN
D
SPE
5%
1 µL
A
uto
450
Ever
y W
eek
027
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
3 0.
7 3
trans
ition
s G
C
MSD
Q
EI
+
YES
YES
0.01
N
O
Var
ian
3800
GC
+
320-
MS
10
AC
N
DSP
E w
ith P
SA
VF-
1ms
4 Bo
th
302
Each
Ba
tch
028
Tent
ativ
e d
etec
ted
22
6.0>
170.
0,
226.
0>11
4.0
LC
MSD
Q
ES
I +
NO
N
O 1
0-10
0 pp
b
NO
LC
: Agi
lent
120
0,
MS:
API
400
0 Q
TRA
P 10
A
CN
Q
uEC
hERS
w
ithou
t PSA
Supe
lco
Disc
over
y C
18, 1
50 m
m x
2.
1 m
m, 5
µm
2
Aut
o 59
1
029
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
NO
N
O
10
A
CN
N
O
Xter
ra C
18
20
Both
030
Tent
ativ
e d
etec
ted
LC
Q
ES
I +
YES
YES
0.02
N
O
Var
ian
320
15
AC
N
C
18
10
Aut
o 15
0 Ea
ch B
atc
h
033
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.3
m
in 3
ions
G
C
MSD
Q
EI
+
YES
NO
0.
01
YES
Agi
lent
GC
-MSD
78
90A
/597
5c
10
AC
N
PSA
, C18
HP
-5M
S 1
Aut
o 92
7
034
Con
firm
ed w
ith
seco
nd m
etho
d
full
scan
G
C
MSD
Q
EI
+
NO
N
O
YE
S A
gile
nt 5
973
MSD
10
A
CN
D
SPE
(PSA
/MgS
O4)
HP
-5M
S 10
Bo
th
950
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
97
TER
BU
MET
ON
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library (pesticides ONLY)
Standard Solution Frequency
035
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
G
C
MSD
Q
EI
NO
N
O
YE
S A
gile
nt 6
890N
10
A
CN
D
SPE
DB-
5 2
Aut
o
036
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
10
AC
N
5 A
uto
350
038
Tent
ativ
e d
etec
ted
N
one
Non
e 2
trans
ition
s LC
M
SD
Q
ESI
+ N
O
NO
NO
A
PI 4
000
10
AC
N
DSP
E W
ate
rs-C
18
2,1x
50m
mx1
,7‚µ
m
5 A
uto
600
Ever
y W
eek
039
Tent
ativ
e d
etec
ted
GC
M
SD
Q
EI
+ N
O
NO
YES
HP59
73 M
SD
10
AC
N
DSP
E HP
-5M
SI
20
Both
62
4 N
o st
and
ard
us
ed
040
Con
firm
ed w
ith
seco
nd m
etho
d
17
3
LC
TO
F ES
I +
NO
N
O
YE
S A
gile
nt 6
230
10
AC
N
Non
e Ec
lipse
C18
3
Aut
o ap
rox
500
Tent
ativ
e d
etec
ted
3
LC
TO
F ES
I +
NO
N
O
YE
S A
gile
nt 6
230
10
AC
N
Non
e Ec
lipse
C18
3
Aut
o ap
rox
500
041
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.5%
2 tra
nsiti
ons
GC
M
SD
Q
EI
YE
S YE
S 0.
005
mg/
kg
NO
V
ARI
AN
CP-
3800
M
S-32
0 10
A
CN
PS
A
VF-
5MS
1 A
uto
210
045
Tent
ativ
e d
etec
ted
1
1 un
it
GC
M
SD
Q
EI
YE
S N
O
0.01
ppm
YE
S A
gile
nt 5
973
10
AC
N
PSA
HP
5 M
S UI
2
Aut
o 92
3 Ea
ch B
atc
h
047
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.2
Sp
ectru
m
mat
ch
(reve
rsed
) G
C
MSD
IT
EI
+ YE
S YE
S 20
-10.
000
µg/k
g YE
S V
aria
n Sa
turn
20
00
15
Ace
tone
/PE/
DC
M
NO
V
F-5-
ms
5 Bo
th
550
Qua
rterly
048
Con
firm
ed w
ith
seco
nd m
etho
d
4
G
C
MSD
TO
F EI
YES
YES
0.00
5 YE
S Pe
gasu
s IV
10
A
CN
D
SPE(
PSA
) HP
-5M
S 5
Both
65
0 W
eekl
y
049
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
XEV
O
TQ M
S 10
A
CN
BEH
C18
1,7
µm
3 Bo
th
60
Dai
ly
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.03
2
Qio
n ra
tio
GC
M
SD
Q
EI
+ YE
S YE
S 0.
01-0
.05
YES
Agi
lent
68
90G
C+5
975M
S 10
A
CN
D
SPE
REST
EK-5
MS
50
Both
16
8 D
aily
051
Tent
ativ
e d
etec
ted
0.5
qual
ifier
s G
C
MSD
IT
EI
N
O
NO
YES
varia
n G
CM
S 40
00
10
AC
N
PSA
va
rian
fact
or fo
ur
5 Bo
th
053
Tent
ativ
e d
etec
ted
10
3 SI
M Io
ns
GC
M
SD
Q
EI
+ N
O
NO
>0
.05
mg/
kg
YES
Ther
mo
DSQ
10
D
CM
D
iato
mac
eous
ea
rth
1
Both
40
0 Ev
ery
6 M
onth
s
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
98
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
VA
MID
OTH
ION
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
001
Con
firm
ed w
ith
seco
nd m
etho
d
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
N
O
Agi
lent
649
0 5
AC
N
RP
-C18
10
Bo
th
D
aily
002
Con
firm
ed w
ith
seco
nd m
etho
d
8.4
GC
M
SD
Q
EI
+ YE
S YE
S no
t va
lidat
ed
YES
AT
5975
10
A
CN
SP
E HP
5-M
S 10
A
uto
apro
x 75
0 A
lway
s
002
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
API
4000
10
A
CN
N
one
C18
5
Man
ual
003
Con
firm
ed w
ith
seco
nd m
etho
d
0.05
5
2 tra
nsiti
ons
LC
Q
-TO
F ES
I +
NO
N
O
YE
S Br
uker
Max
is 10
A
CN
PS
A
RSLC
C18
1
Both
ap
rox
400
004
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
LC
M
SD
Q
ESI
+ YE
S YE
S 0.
01
NO
A
gile
nt 6
460,
12
90HP
LC
10
EtO
Ac
Non
e W
ate
rs, H
SS T
3,
150
x 2.
1mm
2
Both
50
0 Ea
ch B
atc
h
Con
firm
ed w
ith
seco
nd m
etho
d
-0.6
2.
4
LC
MSD
TO
F ES
I +
NO
N
O
NA
YE
S Br
uker
Max
is 10
Et
OA
c N
one
Acc
laim
RSL
C 1
20
C18
, 2,1
*100
mm
1
Both
10
00
Each
Ba
tch
006
Tent
ativ
e d
etec
ted
<1
3 d
iagn
ostic
io
ns
GC
M
SD
Q
EI
+ YE
S YE
S >0
.010
m
g/kg
YE
S Tr
ace
DSQ
15
A
CN
PS
A/C
18
DB5
MS
0.8
Both
008
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
1
2 tra
nsiti
ons
+acc
urat
e m
ass
LC
MSD
Q
-TRA
P ES
I +
YES
NO
0.
01
NO
Q
Trap
550
0 10
A
CN
N
one
reve
rsed
pha
se
2.5
Aut
o 30
0 Ea
ch B
atc
h
010
Tent
ativ
e d
etec
ted
6.
5
2 tra
nsiti
ons
GC
M
SD
Q
EI
+ YE
S N
O
YE
S HP
5975
C
10
AC
N
DSP
E HP
5MS
10
Both
ap
rox
1000
A
lway
s
012
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.6
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
NO
W
ate
rs Q
uattr
o Pr
emie
r 10
M
etha
nol
NO
C
18
5 Bo
th
211
Alw
ays
013
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
4 N
A
ion
ratio
- qu
antif
ier
288/
146
qual
ifier
28
8/11
8
LC
MSD
Q
ES
I +
YES
YES
0.01
0 m
g/Kg
N
O
API
320
0 Q
TRA
P 10
.0
AC
N
d-S
PE
C18
20
M
anua
l 12
0 Ea
ch B
atc
h
014
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
±2.5
%
2
trans
ition
s LC
M
SD
Q
ESI
+ YE
S YE
S 0.
010
mg/
kg
YES
Wa
ters
-TQ
D
15
AC
N
PSA
UP
LC-B
EH C
18
10
Aut
o 33
1 Ea
ch B
atc
h
015
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
NA
N
A
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
0.01
N
O
6460
10
A
CN
PS
A
C18
-XB
2 Bo
th
440
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
99
VA
MID
OTH
ION
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
016
Con
firm
ed w
ith
seco
nd m
etho
d
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Tent
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APP
ENDI
X 3.
Met
hods
use
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par
ticip
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for d
etec
ting
pest
icid
es.
100
Fi
nal R
epor
t - E
URL-
FV-S
M-0
4, 2
012
VA
MID
OTH
ION
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
031
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
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MS
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+ YE
S YE
S 0.
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0.4
µg/m
l N
O
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S (W
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stem
, A
PI 5
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Trip
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3 Ea
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Tent
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010
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00 Q
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P 10
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CN
D
SPE
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ro
Phen
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8.1-
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7 Ea
ch B
atc
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Con
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NC
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2495
/201
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M
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nsiti
ons +
io
n ra
tio
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I +
YES
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5-10
00
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O
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ters
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ttro
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E 15
A
ceto
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E/D
CM
N
O
Acq
uity
BEH
(1
00x2
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5 Bo
th
230
Each
Ba
tch
APP
ENDI
X 3.
Met
hods
use
d by
par
ticip
ants
for d
etec
ting
pest
icid
es.
Fina
l Rep
ort -
EUR
L-FV
-SM
-04,
201
2
10
1
VA
MID
OTH
ION
Laboratory Code
How was the identification done?
RT Deviation (in seconds)
MS Tolerance (ppm)
Other Identification Details
Chromatographic Techique
Detector
Analyzer
IonizationMode
Polarity
Routine Method?
Routine Scope?
Screening Reporting Level (SRL) Range?
Full Scan
Instrument Model
Sample Weight (g)
Extraction Solvent
Clean up Step
Column Type
Injecton Volume (µL)
Software
Compounds in method or library
(pesticides ONLY)
Standard Solution Frequency
048
Con
firm
ed w
ith
seco
nd m
etho
d
2.7
LC
MSD
Q
ES
I +
YES
YES
0.00
5 N
O
Agi
lent
641
0 10
A
CN
D
SPE(
PSA
) Lu
na C
18
5 Bo
th
350
Dai
ly
049
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tifie
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(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0
2 tra
nsiti
ons
LC
Q
ES
I +
YES
YES
N
O
Wa
ters
XEV
O T
Q
MS
10
AC
N
BE
H C
18 1
,7µm
3
Both
60
D
aily
050
Fully
iden
tifie
d
(SA
NC
O/1
2495
/201
1 p.
74-8
0)
0.03
9
2 tra
nsiti
ons
LC
MSD
Q
ES
I +
YES
YES
0.01
-0.0
5 YE
S A
gile
nt 1
200
LC+6
460Q
10
A
CN
D
SPE
YMC
Tria
rt C
18
2*10
0 m
m 3
µm
5 Bo
th
354
Dai
ly
ANNEX 1. List of Laboratories that participate in EUPT-FV-SM04.
Final Report - EURL-FV-SM-04, 2012 103
COUNTRY LABORATORY NAME CITY REPORTED RESULTS
AUSTRIA AUSTRIAN AGENCY FOR HEALTH AND FOOD
SAFETY, COMPETENCE CENTER FOR RESIDUES OF PLANT PROTECTION PRODUCTS
INNSBRUCK YES
BELGIUM FYTOLAB ZWIJNAARDE YES
BELGIUM LOVAP GEEL YES
BELGIUM SCIENTIFIC INSTITUTE OF PUBLIC HEALTH BRUXELLES YES
CZECH REPUBLIC CZECH AGRICULTURE AND FOOD INSPECTION AUTHORITY PRAHA YES
CZECH REPUBLIC INSTITUTE OF CHEMICAL TECHNOLOGY PRAGUE, DEPT. OF FOOD CHEMISTRY AND ANALYSIS PRAGUE YES
DENMARK DANISH VETERINARY AND FOOD ADMINISTRATION REGION EAST RINGSTED YES
DENMARK NATIONAL FOOD INSTITUTE, TECHNICAL UNIVERSITY OF DENMARK SOEBORG YES
EGYPT CENTRAL LAB OF RESIDUE ANALYSIS OF PESTICIDES AND HEAVY METALS IN FOODS DOKKI, GIZA YES
ESTONIA LABORATORY FOR RESIDUES AND CONTAMINANTS, AGRICULTURAL RESEARCH CENTRE SAKU YES
FINLAND FINNISH CUSTOMS LABORATORY ESPOO YES
FRANCE CERECO SUD GARONS YES
FRANCE GIRPA BEAUCOUZE YES
FRANCE LABORATOIRE DU SCL DE MONTPELLIER MONTPELLIER YES
FRANCE LABORATORY SCL-RENNES RENNES YES
FRANCE SERVICE COMMUN DES LABORATOIRES - LABORATOIRE SCL D'ILE DE FRANCE MASSY CEDEX YES
GERMANY BAYERISCHES LANDESAMT FÜR GESUNDHEIT UND LEBENSMITTELSICHERHEIT ERLANGEN YES
GERMANY CHEMICAL AND VETERINARY ANALYTICAL INSTITUTE MUENSTERLAND-EMSCHER LIPPE MUENSTER YES
GERMANY EUROFINS DR. SPECHT LABORATORIEN GMBH HAMBURG YES
GERMANY FEDERAL OFFICE OF CONSUMER PROTECTION AND FOOD SAFETY (BVL) BERLIN YES
GERMANY GALAB LABORATORIES GMBH GEESTHACHT YES
GERMANY INSTITUTE FOR HYGIENE AND ENVIRONMENT HAMBURG YES
GERMANY LABOR FRIEDLE GMBH REGENSBURG YES
GERMANY LUA SACHSEN, DEUTSCHLAND DRESDEN YES
GERMANY NIEDERSAECHSISCHES LANDESAMT FUER
VERBRAUCHERSCHUTZ UND LEBENSMITTELSICHERHEIT, LVI OLDENBURG
OLDENBURG YES
GREECE PESTICIDE RESIDUES LABORATORY, D CHEMICAL
DIVISION, GENERAL CHEMICAL STATE LABORATORY
ATHENS YES
HUNGARY AGRICULTURAL OFFICE, DPPSCA PESTICIDE RESIDUE ANALYTICAL LABORATORY, MISKOLC MISKOLC YES
HUNGARY WESSLING HUNGARY LTD. FOOD TESTING LABORATORY BUDAPEST YES
IRELAND THE PESTICIDE CONTROL LABORATORY CELBRIDGE YES
ANNEX 1. List of Laboratories that participate in EUPT-FV-SM04.
104 Final Report - EURL-FV-SM-04, 2012
COUNTRY LABORATORY NAME CITY REPORTED RESULTS
ITALY AGENZIA REGIONALE PROTEZIONE AMBIENTALE-LABORATORIO DI PORDENONE PORDENONE YES
ITALY ARPA PUGLIA DIPARTIMENTO DI BRINDISI BRINDISI NO
ITALY ARPA VENETO, S.L. VERONA VERONA YES
ITALY LABORATORIO CONTAMINANTI AMBIENTALI - ISTITUTO ZOOPROFILATTICO SPERIMENTALE
UMBRIA MARCHE PERUGIA YES
ITALY LANDESAGENTUR FÜR UMWELT - LABOR FÜR CHROMATOGRAPHIE BOZEN YES
ITALY SERVIZIO LABORATORIO CHIMICO - TOSSICOLOGICO ARPACAL COSENZA YES
LATVIA INSTITUTE OF FOOD SAFETY, ANIMAL HEALTH AND ENVIRONMENT "BIOR" RIGA YES
NORWAY
BIOFORSK - NORWEGIAN INSTITUTE FOR AGRICULTURAL AND ENVIRONMENTAL RESEARCH, PLANT HEALTH AND PLANT PROTECTION DIVISION,
PESTICIDE CHEMISTRY SECTION
AAS YES
ROMANIA LABORATORY FOR PESTICIDES RESIDUES CONTROL IN PLANTS AND VEGETABLE PRODUCTS BUCHAREST YES
ROMANIA SANITARY VETERINARY AND FOOD SAFETY DIRECTORATE BUCHAREST YES
SERBIA CENTER FOR FOOD ANALYSIS BELGRADE YES
SLOVENIA INSTITUTE OF PUBLIC HEALTH MARIBOR, ENVIRONMENTAL PROTECTION INSTITUTE MARIBOR YES
SPAIN LABORATORIO AGROALIMENTARIO DE GRANADA (ATARFE)
ATARFE (GRANADA) YES
SPAIN LABORATORIO AGROALIMENTARIO DE LA GENERALITAT VALENCIANA BURJASSOT YES
SPAIN LABORATORIO AGROALIMENTARIO Y DE SANIDAD ANIMAL
EL PALMAR (MURCIA) YES
SPAIN LABORATORIO DE SANIDAD VEGETAL OVIEDO NO
SWEDEN EUROFINS FOOD & AGRO SWEDEN AB LIDKÖPING YES
SWEDEN NATIONAL FOOD AGENCY (NFA), CHEMICAL UNIT 1 UPPSALA YES
SWITZERLAND SERVICE DE LA CONSOMMATION ET DES AFFAIRES VETERINAIRES (SCAV) GENEVE YES
THE NETHERLANDS NVWA - NETHERLANDS FOOD AND CONSUMER PRODUCT SAFETY AUTHORITY WAGENINGEN YES
THE NETHERLANDS RIKILT WAGENINGEN YES
TURKEY MSM FOOD CONTROL LABORATORY MERSIN YES
UNITED KINGDOM EUROFINS LABORATORIES LTD WOLVERHAMPTON YES
UNITED KINGDOM THE FOOD AND ENVIRONMENT RESEARCH AGENCY (FERA) YORK YES
ANNEX 2. Specific Protocol.
Final Report - EURL-FV-SM-04, 2012 105
EUPT-FV-SM04 SPECIFIC PROTOCOL European Union Proficiency Test for
Pesticide Residues in Fruits and Vegetables
Screening Multiresidue Methods
(2012) Introduction
This protocol is complementary to the General Protocol for EU Proficiency Tests (EUPT) dealing with Pesticide Residues in Food and Feed. This
Proficiency Test is organised by the EURL for Pesticide Residues in Fruits and Vegetables and covers the screening of pesticides using multiresidue
methods of analysis.
The aim of this test is to evaluate laboratory capability when using large-scope quantitative and/or screening methods during routine analysis, for
detecting and identifying unexpected pesticides at levels at, or above 0.01 mg/kg – included in and/or in addition to the laboratories’ quantitative
methods used for frequently-detected pesticides. A second aim is to encourage official laboratories to extend the scope of their methods in a cost-
effective way, by using the different MS instruments/software and methods available (whether old or new).
Test material
This proficiency test is based on the pesticide-residue analysis of pears. The pears were grown in Aragón, Spain.
The pesticide treatments will be carried out post-harvest using either commercial formulation in micro-spray solutions or using standard solutions. The
test material will be frozen (using liquid nitrogen), chopped, homogenised and sub-sampled into polyethylene bottles that have previously been
coded.
Ten of these bottles containing the test material will be chosen randomly and analysed to check for homogeneity.
The test material will be stored frozen (–20ºC) prior to shipment to participants.
Two bottles, again chosen randomly, will be analysed over a period of time to confirm the stability of the pesticides in the test material (firstly, when
the test materials are shipped, and then a few days after the deadline for receipt of participants´ results). There will be a further analysis during this
period reproducing the sample shipment i.e. maintaining the sample at room temperature for a few days to see if there is any degradation of any
of the pesticides present in the test material.
These results will not be included in the statistical analysis of the proficiency test. The aim is solely to check pesticide stability during the shipping
process and for the duration of the proficiency test.
Steps to follow
This Proficiency Test will be made up of the following 6 essential steps:
1. To participate, each laboratory must complete the Application Form online, available on the EURL-FV Web page, before the deadline
stipulated on the Calendar.
2. Laboratories will then receive an e-mail confirming their participation in this exercise, and assigning them a unique Laboratory Code. With
this code, laboratories will be able to access the restricted area containing the reply forms using their login information - consisting of their
USER NAME, which is the Laboratory Code expressed as Labxxx (three digits with no spaces between them) and their PASSWORD, as chosen
on the application form.
3. The sample delivery will be free of charge to those laboratories already participating in EUPT-FV14. For those who are not EUPT-FV14
participants, please see Cost for shipment of the test material for further details. The payment procedure must have started before 20th
February. An e-mail showing the bank transfer confirmation, or similar, must have been sent beforehand, or may be requested by the
Organiser at any time. Payments without a Laboratory Code or Invoice Number to identify them will not be considered paid.
4. When the participant laboratories receive the test material (and not before), they must enter the restricted area and submit Form 0 - Test
Material Receipt to inform the Organiser that they have accepted the test material. If no test material has been received by 23rd February,
please contact the Organiser by e-mail (cferrer@ual.es and omalato@ual.es).
5. The participating laboratories must respect the deadline for submitting the results. Results must be reported using Form 1 - Results within 72
hours after the arrival of the test item.
6. The Organiser will evaluate the results at the end of the proficiency test, once the deadline for the receipt of results has passed. The
Organiser will prepare a Preliminary Report that will be sent to the participants and uploaded to the website to show the pesticides reported,
ANNEX 2. Protocols.
106 Final Report - EURL-FV-SM-04, 2012
after the revision of all the data by the Scientific Panel a Final Report will be done and the organiser will upload an electronic version on the
EURL-FV website and, afterwards, send a hard copy to each participant laboratory. This report will include information regarding the design
of the test, the homogeneity and stability test results, an evaluation of the participant’s results as well as graphical displays of the results and
any conclusions. Any other relevant information considered of value may also be included.
Amount of Test Material
Participants will receive:
• Approximately 300 g of pear test material treated with pesticides.
• Approximately 300 g of ‘blank’ pear test material.
Shipment of Test Materials
All test materials will be frozen and packed in polystyrene boxes surrounded by dry ice and packed into cardboard boxes.
The shipment of the test materials will start on 20th February 2012. An information message will be sent out by e-mail before shipment. Laboratories
must make their own arrangements for the receipt of the package. They must inform the Organiser of any public holidays in their country/city during
the delivery period given in the calendar as well as making the necessary arrangements to receive the shipment, even if the laboratory is closed.
Advice on Test Material Handling
Once received, the test material should be stored deeply frozen (-18°C or less) prior to analysis to avoid any possible deterioration/spoilage. The test
material should be mixed thoroughly before taking the analytical portion(s).
All participants should use their own routine standard operating procedures for extraction, clean-up and analytical measurement and their own
reference standards for identification.
Form 0 - Test Material Receipt
Once the laboratory has received the test material, the Organiser must be notified using Form 0 in the restricted area; filling in the date of receipt,
the condition of the test material, and acknowledging its acceptance. If the laboratory does not inform the Organiser by 23rd February 2012 (at the
latest) via email (to cferrer@ual.es and omalato@ual.es), stating that no sample has been received, the Organiser will assume that the test material
has been received and accepted.
Form 1 - Results
Laboratories must enter their results in Form 1 by accessing the restricted area on the EURL-FV web site: http://www.eurl-pesticides.eu
On this form, the laboratory should report the name of each of the pesticides detected.
Each pesticide may be reported more than once if it has been detected by more than one method or identification criteria, as long as details of
each method used are also provided.
Information on the parameters and/or criteria used for detecting and reporting the pesticides found will be requested, such as deviation from
expected retention time, and MS identification details.
The idea is to ascertain if the methods are used in routinely or just specifically for this test and if the identification is undertaken manually or
automatically. Moreover, the range over which your method operates will be required. This is the concentration range - the minimum and
maximum level of your screening method that is used to detect pesticides.
Information in this form will be saved and may be changed or updated up to 72 hours after sample arrival in the laboratory. After the deadline,
results submission and/or changes to the results form will no longer be possible.
Calendar
ACTIVITY DATE
Publishing the Calendar and Matrix on the EURL-FV Web page. 30th November 2011
Submission of Application Form by invited laboratories. 15th Dec. 2011-18th Jan 2012
Sample distribution. 20th February 2012
Submission of sample receipt and acceptance - Form 0. As soon as sample is received
Deadline for receiving results - Form1 72 hours after receiving the sample
Preliminary Report. March 2012
Final Report distributed to the Laboratories. December 2012
ANNEX 2. Specific Protocol.
Final Report - EURL-FV-SM-04, 2012 107
Cost for shipment of the test material
Only those laboratories not participating in EUPT-FV 14 will have to pay the following fee for sample shipment: EU and EFTA laboratories will be
charged 175€ and other laboratories will be charged 200 €. For the payment procedures, each laboratory can specify their details and requests for
invoices when applying for the test. Payment details are as follows:
BANK NAME: CAJAMAR - Caja Rural Sociedad Corporativa de Crédito
BANK ACCOUNT OWNER: Universidad de Almeria
BANK ADDRESS: Office Number 990. Universidad de Almeria. Spain
ACCOUNT NUMBER: 30580130172731005000
IBAN: ES0730580130172731005000
SWIFT: CCRIES2A
CONCEPT: Invoice No. or Lab Code
Contact information
The official organising group details are as follows:
Universidad de Almería. Edificio Químicas CITE I
Ctra. Sacramento s/n
04120 Almería - Spain
Fax No.: +34 950015483
Organising team (e-mail and phone no.):
Dr. Amadeo R. Fernández-Alba EURL-FV amadeo@ual.es +34 950015034
Dr. Paula Medina Pastor EURL-FV pmedina@ual.es +34 950015531
Ms. Carmen Ferrer Amate EURL-FV cferrer@ual.es +34 950015645
Mr. Octavio Malato Rodriguez EURL-FV omalato@ual.es +34 950214423
Quality Control Group
Dr. Antonio Valverde, Senior Chemist, University of Almería, Spain.
Mr. Stewart Reynolds, Senior Chemist, FERA, York, United Kingdom.
Statistical Group
Dr. Carmelo Rodriguez, Senior Mathematician, University of Almeria, Spain.
Advisory Group
Dr. André de Kok, Senior Chemist, NVWA, Wageningen, The Netherlands.
Dr. Tuija Pihlström, Senior Chemist NFA, Uppsala, Sweden.
Dr. Sonja Masselter, Senior Chemist, AGES, Innsbruck, Austria.
Dr. Darinka Stajnbaher, Senior Chemist, IPH, Maribor, Slovenia.
Dr. Magnus Jezussek, Senior Chemist, LGL, Erlangen, Germany.
Dr. Miguel Gamón, Senior Chemist, Laboratorio Agroalimentario, Valencia, Spain.
Dr. Mette Erecius Poulsen, Senior Chemist, DTU, Copenhagen, Denmark.
Mr. Ralf Lippold, Senior Chemist, CVUA, Freiburg, Germany.
Dr. Michelangelo Anastassiades, Senior Chemist, CVUA, Stuttgart, Germany.