Post on 18-Feb-2018
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Gas Turbine Fuel Flexibility for IGCCGas Turbine Fuel Flexibility for IGCCGas Turbine Fuel Flexibility for IGCCGas Turbine Fuel Flexibility for IGCC
GE EnergyGE EnergyGE EnergyGE Energy
S4FE Sustainable EnergyRome, Italy
July 07, 2009
Marcus H. ScholzKlaus Payrhuber
© Copyright General Electric Company, 2009
OutlineOutlineOutlineOutline
• Gasification Gasification Gasification Gasification –––– a prea prea prea pre----combustion Ccombustion Ccombustion Ccombustion C----separation historyseparation historyseparation historyseparation history
• Fuel flexibility… a changing fuel spaceFuel flexibility… a changing fuel spaceFuel flexibility… a changing fuel spaceFuel flexibility… a changing fuel space
• High Hydrogen Fuel High Hydrogen Fuel High Hydrogen Fuel High Hydrogen Fuel ---- IGCC IGCC IGCC IGCC
© Copyright General Electric Company, 2009
• High Hydrogen Fuel High Hydrogen Fuel High Hydrogen Fuel High Hydrogen Fuel ---- IGCC IGCC IGCC IGCC
• Advanced technology developmentAdvanced technology developmentAdvanced technology developmentAdvanced technology development
• SummarySummarySummarySummary
• Petroleum Coke• Asphalt• Heavy Oil• Vacuum Residue• Natural Gas
Gasification SolutionsGasification SolutionsGasification SolutionsGasification Solutions
Substitute Natural Gas• SNG
…since > 50 years !
© Copyright General Electric Company, 2009
1950 1970 1960 1980 1990 2000 2010
Gas Liquid Solid
Current Operating Gasification Plants: 65Under Construction: 12
Montebello Test Facility Operations
Plants in Progress 120MW IGCCTechnical Demo
Cool Water
250MW IGCCCommercial DemoTECO/Polk Power
1946 2004
Gasification Gasification Gasification Gasification ---- Decades of ExperienceDecades of ExperienceDecades of ExperienceDecades of Experience
Over 3 GW Commercial Feedstock Experience
© Copyright General Electric Company, 2009
1,132
760
1,120
Syngas Power Syngas & Power
Over 3 GW GE IGCC
Experience
(MWs)> Natural GasNatural GasNatural GasNatural Gas> Refinery Off GasRefinery Off GasRefinery Off GasRefinery Off Gas
> Crude OilCrude OilCrude OilCrude Oil> Fuel Oil/Heavy Fuel OilFuel Oil/Heavy Fuel OilFuel Oil/Heavy Fuel OilFuel Oil/Heavy Fuel Oil> NaphthaNaphthaNaphthaNaphtha> Vacuum ResidueVacuum ResidueVacuum ResidueVacuum Residue> Asphalt/Deasphalter Asphalt/Deasphalter Asphalt/Deasphalter Asphalt/Deasphalter
ResidueResidueResidueResidue> Visbreaker TarVisbreaker TarVisbreaker TarVisbreaker Tar> Steam Cracked TarSteam Cracked TarSteam Cracked TarSteam Cracked Tar
Liquids
> Range of coalsRange of coalsRange of coalsRange of coals> Petroleum CokePetroleum CokePetroleum CokePetroleum Coke> Coal/Coke BlendsCoal/Coke BlendsCoal/Coke BlendsCoal/Coke Blends
Gas
Solids
Commercial Feedstock Experience
Integrated Gasification Combined CycleIntegrated Gasification Combined CycleIntegrated Gasification Combined CycleIntegrated Gasification Combined Cycle
GasificationGasificationGasificationGasification Syngas Syngas Syngas Syngas cooling & cooling & cooling & cooling & shiftingshiftingshiftingshifting
Syngas Syngas Syngas Syngas CleanCleanCleanClean----
upupupup
CoalCoalCoalCoal
SlagSlagSlagSlag
COCOCOCO2222
SulfurSulfurSulfurSulfur
HgHgHgHg
Cleaned Syngas / H2Cleaned Syngas / H2Cleaned Syngas / H2Cleaned Syngas / H2HeatHeatHeatHeatOOOO2222
IGCCIGCCIGCCIGCC
© Copyright General Electric Company, 2009
AirAirAirAirSeparationSeparationSeparationSeparationSystemSystemSystemSystem
Combined Cycle Combined Cycle Combined Cycle Combined Cycle SystemSystemSystemSystem
SlagSlagSlagSlag
AirAirAirAir Air/NAir/NAir/NAir/N2222
Cleaned Syngas / H2Cleaned Syngas / H2Cleaned Syngas / H2Cleaned Syngas / H2HeatHeatHeatHeat
ElectricityElectricityElectricityElectricity
OOOO2222
Five Basic Process Steps Five Basic Process Steps Five Basic Process Steps Five Basic Process Steps –––– all commercial provenall commercial provenall commercial provenall commercial proven
IGCC + COIGCC + COIGCC + COIGCC + CO2222 Separation “Capture” Separation “Capture” Separation “Capture” Separation “Capture”
© Copyright General Electric Company, 2009
Produce Produce Produce Produce SyngasSyngasSyngasSyngasGasifierGasifierGasifierGasifier
H2 & COH2 & COH2 & COH2 & CO
Shift SyngasShift SyngasShift SyngasShift SyngasWater gas shift reactorWater gas shift reactorWater gas shift reactorWater gas shift reactor
•Copper or Zinc Oxide Based
CO + H2O > CO2 + H2CO + H2O > CO2 + H2CO + H2O > CO2 + H2CO + H2O > CO2 + H2
Separate CarbonSeparate CarbonSeparate CarbonSeparate CarbonAGR & CO2 AGR & CO2 AGR & CO2 AGR & CO2 CompressionCompressionCompressionCompression
Selexol Refrigeration: >90% Removal
H2 & CO2H2 & CO2H2 & CO2H2 & CO2
Produce PowerProduce PowerProduce PowerProduce PowerDiffusion flame for HDiffusion flame for HDiffusion flame for HDiffusion flame for H2222+ Diluent(N+ Diluent(N+ Diluent(N+ Diluent(N2222, Steam), Steam), Steam), Steam)
H2H2H2H2
Syngas shift & extract carbon photos courtesy of Air Products, Baytown, TX facility.
Owner: Owner: Owner: Owner: Sarlux S.r.lLocation:Location:Location:Location: Cagliari, Sardinia, ItalyStartup: Startup: Startup: Startup: 2001Feedstock: Feedstock: Feedstock: Feedstock: Visbreaker tarDesign Capacity: Design Capacity: Design Capacity: Design Capacity: 1,200 mTPD Operation Pressure:Operation Pressure:Operation Pressure:Operation Pressure: 38 barGasifier Size:Gasifier Size:Gasifier Size:Gasifier Size: 3 x 900 ft³Power: Power: Power: Power: 3 x GE 9E GT’s, 3 x GE STEPC ContractorEPC ContractorEPC ContractorEPC Contractor : Snamprogetti S.p.A.
IGCC IGCC IGCC IGCC – Polygeneration, SarluxPolygeneration, SarluxPolygeneration, SarluxPolygeneration, Sarlux
© Copyright General Electric Company, 2009
EPC ContractorEPC ContractorEPC ContractorEPC Contractor : Snamprogetti S.p.A.
GE GE GE GE Gasification Gasification Gasification Gasification & Carbon & Carbon & Carbon & Carbon ExtractionExtractionExtractionExtraction
Gas Gas Gas Gas Cooling &Cooling &Cooling &Cooling &
COS COS COS COS HydrolysisHydrolysisHydrolysisHydrolysis
OxygenOxygenOxygenOxygen
Visbreaker Visbreaker Visbreaker Visbreaker TarTarTarTar
SulfurSulfurSulfurSulfur
Sulphur Sulphur Sulphur Sulphur Removal & Removal & Removal & Removal & RecoveryRecoveryRecoveryRecovery
Steam to RefinerySteam to RefinerySteam to RefinerySteam to Refinery
Power to GridPower to GridPower to GridPower to GridGE GE GE GE
Combined Combined Combined Combined CycleCycleCycleCycle
Hydrogen Hydrogen Hydrogen Hydrogen ProductionProductionProductionProduction
H2 to RefineryH2 to RefineryH2 to RefineryH2 to Refinery
3,600 t/day3,600 t/day3,600 t/day3,600 t/day
551 MW551 MW551 MW551 MW
40,000 Nm3/h40,000 Nm3/h40,000 Nm3/h40,000 Nm3/h
MP = 100 t/h; LP =85 t/hMP = 100 t/h; LP =85 t/hMP = 100 t/h; LP =85 t/hMP = 100 t/h; LP =85 t/h
WastewaterWastewaterWastewaterWastewaterPretreatmentPretreatmentPretreatmentPretreatment
Filter CakeFilter CakeFilter CakeFilter Cake
to metals to metals to metals to metals reclaimerreclaimerreclaimerreclaimer
Steam to exportSteam to exportSteam to exportSteam to export
90+% availability (no 90+% availability (no 90+% availability (no 90+% availability (no spare)spare)spare)spare)
Sulfur RemovalSulfur RemovalSulfur RemovalSulfur Removal
Gasifier & SGCGasifier & SGCGasifier & SGCGasifier & SGC
IGCC IGCC IGCC IGCC –––– Power Generation, TECPower Generation, TECPower Generation, TECPower Generation, TEC–––– S107FAS107FAS107FAS107FATampa, FL (Coal + Petcoke)Tampa, FL (Coal + Petcoke)Tampa, FL (Coal + Petcoke)Tampa, FL (Coal + Petcoke)IGCC IGCC IGCC IGCC –––– Power Generation, TECPower Generation, TECPower Generation, TECPower Generation, TEC–––– S107FAS107FAS107FAS107FATampa, FL (Coal + Petcoke)Tampa, FL (Coal + Petcoke)Tampa, FL (Coal + Petcoke)Tampa, FL (Coal + Petcoke)
© Copyright General Electric Company, 2009
Combined CycleCombined CycleCombined CycleCombined Cycle
ASU/Oxygen PlantASU/Oxygen PlantASU/Oxygen PlantASU/Oxygen Plant
© Copyright General Electric Company, 2009
Tampa Electric Polk, 1996Tampa Electric Polk, 1996Tampa Electric Polk, 1996Tampa Electric Polk, 1996----PresentPresentPresentPresent• 250 MW net IGCC• GE gasifier/RSC• GE 7FA turbine• GE steam turbine• 12 years of operation
© Copyright General Electric Company, 2009
• 12 years of operation�High availability > 85%� Low emissions < 50ppm SO2/SO3
� Low cost electricity – Petcoke/coal blend
Courtesy: Tampa Electric Company
IGCC Reference Plant IGCC Reference Plant IGCC Reference Plant IGCC Reference Plant –––– 207F207F207F207F• Nominal 630MW net plant outputNominal 630MW net plant outputNominal 630MW net plant outputNominal 630MW net plant output• 207F gas turbine combined cycle207F gas turbine combined cycle207F gas turbine combined cycle207F gas turbine combined cycle• Base load/load following operationBase load/load following operationBase load/load following operationBase load/load following operation• Turndown to ~50% loadTurndown to ~50% loadTurndown to ~50% loadTurndown to ~50% load• Fuel flexibilityFuel flexibilityFuel flexibilityFuel flexibility
> Wide range of bituminous Wide range of bituminous Wide range of bituminous Wide range of bituminous coalscoalscoalscoals
> Coal/pet coke blendsCoal/pet coke blendsCoal/pet coke blendsCoal/pet coke blends
• 15 ppm NOx Gas Turbine 15 ppm NOx Gas Turbine 15 ppm NOx Gas Turbine 15 ppm NOx Gas Turbine • Natural gas or distillate backup Natural gas or distillate backup Natural gas or distillate backup Natural gas or distillate backup
fuelfuelfuelfuel• Full plant performance guaranteesFull plant performance guaranteesFull plant performance guaranteesFull plant performance guarantees• Configuration optimized forConfiguration optimized forConfiguration optimized forConfiguration optimized for
– COE, RAM, Perf, & Capex COE, RAM, Perf, & Capex COE, RAM, Perf, & Capex COE, RAM, Perf, & Capex • Allows for future COAllows for future COAllows for future COAllows for future CO2222 capture capture capture capture
blockblockblockblock
© Copyright General Electric Company, 2009
> Coal/pet coke blendsCoal/pet coke blendsCoal/pet coke blendsCoal/pet coke blends blockblockblockblock
GE IGCC plant under ConstructionGE IGCC plant under ConstructionGE IGCC plant under ConstructionGE IGCC plant under Construction630MWnet IGCC Plant 630MWnet IGCC Plant 630MWnet IGCC Plant 630MWnet IGCC Plant ---- Duke Energy Duke Energy Duke Energy Duke Energy • Indiana 5 coal - Edwardsport• NTP in 2008, COD in 2012• Detailed engineering completed 2009• Construction on-track • RSC arrived on site in June 2009• 7F Syngas turbines ship in 2010
© Copyright General Electric Company, 2009
• 7F Syngas turbines ship in 2010• Successful siting & permittingSuccessful siting & permittingSuccessful siting & permittingSuccessful siting & permitting 2008200820082008
“ We have an opportunity to make history with the Edwardsport plant. The facility could very well be one of the cleanest coal-fired power plants in the
world. It will produce nearly 10 times as much energy as the existing Edwardsport plant with much less environmental impact.” - Jim Turner,
President & COO, U.S. Franchised Electric and Gas-Duke Energy Duke Energy press release, Jan. 25, 2008
Duke Energy Duke Energy Duke Energy Duke Energy Edwardsport site construction, January 2009Edwardsport site construction, January 2009Edwardsport site construction, January 2009Edwardsport site construction, January 2009
IGCC MilestonesIGCC MilestonesIGCC MilestonesIGCC MilestonesPilotPilotPilotPilot
(1984-89)
CommercialCommercialCommercialCommercial(1996 – Present)
LargeLargeLargeLargeCommercialCommercialCommercialCommercial(2012 - tomorrow)
© Copyright General Electric Company, 2009
Coolwater• 120 MW IGCC
• 7E Gas Turbine
• N/A time to maturity
TEC• 250 MW IGCC
• 7FA Gas Turbine
• 5 yr time to maturity
Duke Edwardsport• 630 MW IGCC
• 7FB Gas Turbine
• 1 yr time to maturity
Increasing demand for fuel flexibilityIncreasing demand for fuel flexibilityIncreasing demand for fuel flexibilityIncreasing demand for fuel flexibility
Segment conditionsSegment conditionsSegment conditionsSegment conditions• Nat Gas Fuel diversification
• Price volatility
• Emission regulations / constraints
• Carbon Capture provisions50
60
70
80
90
100
110
Mod
Wob
be In
dex@
70F
C5H12
C4H10
H2CH4
C3H8
C2H6
NG50
60
70
80
90
100
110
Mod
Wob
be In
dex@
70F
C5H12
C4H10
H2CH4
C3H8
C2H6
NG
LNG Field LNG Field LNG Field LNG Field (High C(High C(High C(High C2222))))
RefineryRefineryRefineryRefineryLNG FieldLNG FieldLNG FieldLNG Field
NG/LNG Wide NG/LNG Wide NG/LNG Wide NG/LNG Wide WobbeWobbeWobbeWobbe
Wob
be In
dex,
MJ/
Nm
Wob
be In
dex,
MJ/
Nm
Wob
be In
dex,
MJ/
Nm
Wob
be In
dex,
MJ/
Nm
33 33
© Copyright General Electric Company, 2009
Source: GE
• Carbon Capture provisions
GE responseGE responseGE responseGE response• 50+ years of experience in
non-traditional fuels• Extending low emissions
technology• Investing in technology for fuel
flexibility
0
10
20
30
40
50
0 5 10 15 20 25 30 35 40 45 50 55
Fuel Lower Heating Value, BTU/lb/1000
Mod
Wob
be In
dex@
70F
CO
NG
0
10
20
30
40
50
0 5 10 15 20 25 30 35 40 45 50 55
Fuel Lower Heating Value, BTU/lb/1000
Mod
Wob
be In
dex@
70F
CO
NGHigh H2High H2High H2High H2
RefineryRefineryRefineryRefineryOffgasOffgasOffgasOffgasLNG FieldLNG FieldLNG FieldLNG Field
(High Inert)(High Inert)(High Inert)(High Inert)
BFG/COGBFG/COGBFG/COGBFG/COG
O2 Blown SyngasO2 Blown SyngasO2 Blown SyngasO2 Blown Syngas
Air Blown SyngasAir Blown SyngasAir Blown SyngasAir Blown Syngas
0 10 20 30 40 50 60 70 80 90 100 110 0 10 20 30 40 50 60 70 80 90 100 110 0 10 20 30 40 50 60 70 80 90 100 110 0 10 20 30 40 50 60 70 80 90 100 110
Fuel Lower Heating Value, MJ/kgFuel Lower Heating Value, MJ/kgFuel Lower Heating Value, MJ/kgFuel Lower Heating Value, MJ/kg
Wob
be In
dex,
MJ/
Nm
Wob
be In
dex,
MJ/
Nm
Wob
be In
dex,
MJ/
Nm
Wob
be In
dex,
MJ/
Nm
GE fuel flexibility experienceGE fuel flexibility experienceGE fuel flexibility experienceGE fuel flexibility experience
Natural Gas
NGL
Marine
Propane
LPG
LNG
Kerosene
Naphtha
Perc
ent H
ydro
gen,
(by
mas
s)Pe
rcen
t Hyd
roge
n, (b
y m
ass)
Perc
ent H
ydro
gen,
(by
mas
s)Pe
rcen
t Hyd
roge
n, (b
y m
ass)
Hydrogen (to 95%)
© Copyright General Electric Company, 2009
Residual
RefineryGas
Butane
Ethanol
Marine Fuels
Heavy Gas Oil
Kerosene
Crude
Distillate
Specific Energy, (Btu/lb)Specific Energy, (Btu/lb)Specific Energy, (Btu/lb)Specific Energy, (Btu/lb)
Perc
ent H
ydro
gen,
(by
mas
s)Pe
rcen
t Hyd
roge
n, (b
y m
ass)
Perc
ent H
ydro
gen,
(by
mas
s)Pe
rcen
t Hyd
roge
n, (b
y m
ass)
Methanol
Weak Natural
Gas
Coke Oven gas
IGCC
GE Syngas Gas Turbine ApplicationsGE Syngas Gas Turbine ApplicationsGE Syngas Gas Turbine ApplicationsGE Syngas Gas Turbine ApplicationsPlant Type COD MW
Power
Block Application Integration Gasifier Fuel
Coal IGCC ExperienceCoolwater IGCC 1984 120 107E Power Steam GE Coal
SUV Vresova IGCC 1996 350 209E Cogen Steam ZVU Coal
SVZ IGCC 1996 70 6B Cogen/ MeOH Steam GSP Coal
Wabash IGCC 1996 250 107FA Power Steam E-Gas Coal/Pet Coke
Tampa Polk IGCC 1996 250 107FA Power Steam/N2 GE Coal
Refinery IGCC ExperienceFrontier Refinery 1996 40 6B Cogen Steam/Air/N2 GE Pet Coke
Shell Pernis Refinery 1997 120 206B Cogen/H2 Steam Shell Oil
Sarlux Refinery 2000 550 3x109E Cogen Steam GE vis breaker tar
© Copyright General Electric Company, 2009
Sarlux Refinery 2000 550 3x109E Cogen Steam GE vis breaker tar
Motiva Refinery 2000 180 2- 6FA Cogen Steam/N2 GE Pet Coke
Exxon Singapore Refinery 2000 173 2- 6FA Cogen Steam GE Oil
Nexen/Opti Refinery 2008 160 2- 7EA Cogen Steam Shell Asphaltene
Fujian JV Refinery 2009 253 2- 9E Cogen N2 Shell Oil
Steel ExperienceILVA ISE Steel 1996 520 3x109E Cogen None Steel Mill BFG/COG/LDG
Piombino Edison Steel 2001 180 1x109E Cogen None Steel Mill BFG/COG/LDG
Tonghua Steel 2003 50 6B Cogen None Steel Mill BFG/COG
Jinan Steel 2004 100 6B Power None Steel Mill BFG/COG
Baosteel Luojing Steel 2008 174 1x109E Cogen None Steel Mill COREX
Enhanced Enhanced Enhanced Enhanced Increased Area Increased Area Increased Area Increased Area
S1NS1NS1NS1N
9F Syngas Features9F Syngas Features9F Syngas Features9F Syngas Features
Mark VIe Mark VIe Mark VIe Mark VIe Control Control Control Control SystemSystemSystemSystem
Combustion System: Combustion System: Combustion System: Combustion System: Proven IGCC MNQCProven IGCC MNQCProven IGCC MNQCProven IGCC MNQC
Axial
Exhaust
9FA+e HGP9FA+e HGP9FA+e HGP9FA+e HGP
© Copyright General Electric Company, 2009
Cold
End
Drive
FA+e Aero compressor bladingFA+e Aero compressor bladingFA+e Aero compressor bladingFA+e Aero compressor bladingFB Wheels for Compressor & FB Wheels for Compressor & FB Wheels for Compressor & FB Wheels for Compressor &
TurbineTurbineTurbineTurbine
Leveraging “F” Product Line Experience & Technology Advancements of H
Cleaner Energy
Objective Approach Capability
IGCCwithCarbon Capture
• High-H2 GT fleet• Successful
operation• Diffusion flame• Diluent for NOx
TodayTodayTodayToday
IGCC & CCS Combustion LandscapeIGCC & CCS Combustion LandscapeIGCC & CCS Combustion LandscapeIGCC & CCS Combustion Landscape
© Copyright General Electric Company, 2009
Energy fromCoal
Capture
AdvancedSeparation
& GasificationTechnology
• Diluent for NOx
• Advanced pre-mix combustion
• Membranes --O2, CO2, H2
• DOE program
Future
Conceptual FutureGen plant courtesy US DOE Conceptual FutureGen plant courtesy US DOE Conceptual FutureGen plant courtesy US DOE Conceptual FutureGen plant courtesy US DOE
Syngas turbines Syngas turbines Syngas turbines Syngas turbines –––– MNQC CombustorMNQC CombustorMNQC CombustorMNQC Combustor
N2/Steam
Syngas
Air Extraction
Air from Compressor
Fuel Nozzle
• Same combustor architecture Same combustor architecture Same combustor architecture Same combustor architecture for 6FA, 7EA, 9E, 7/9F Syngas for 6FA, 7EA, 9E, 7/9F Syngas for 6FA, 7EA, 9E, 7/9F Syngas for 6FA, 7EA, 9E, 7/9F Syngas turbinesturbinesturbinesturbines
• End cover/fuel nozzle End cover/fuel nozzle End cover/fuel nozzle End cover/fuel nozzle assembly identical, assembly identical, assembly identical, assembly identical,
© Copyright General Electric Company, 2009
Natural Gas/ Syngas To
Turbine Nozzles
Compressor
Liner
Flow Sleeve Transition Piece
assembly identical, assembly identical, assembly identical, assembly identical, except for minor scalingexcept for minor scalingexcept for minor scalingexcept for minor scaling
• Combustor liner and cap Combustor liner and cap Combustor liner and cap Combustor liner and cap designs similar, scaled to designs similar, scaled to designs similar, scaled to designs similar, scaled to different operating conditionsdifferent operating conditionsdifferent operating conditionsdifferent operating conditions
300
400
500
600
700
800
BT
U/s
cf
of
Fu
el
Process
Gases
IGCC
Gases300
400
500
600
700
800
BT
U/s
cf
of
Fu
el
Process
Gases
IGCC
Gases
Hydrogen Fuel ExperienceHydrogen Fuel ExperienceHydrogen Fuel ExperienceHydrogen Fuel Experience
Video capture of flame Video capture of flame Video capture of flame Video capture of flame structure structure structure structure ---- 85858585----90% H90% H90% H90% H2222
© Copyright General Electric Company, 2009
0
100
200
300
0 10 20 30 40 50 60 70 80 90 100
Percent Hydrogen
BT
U/ Gases
MNQC H2
Testing0
100
200
300
0 10 20 30 40 50 60 70 80 90 100
Percent Hydrogen
BT
U/ Gases
MNQC H2
Testing
GE High HGE High HGE High HGE High H2222 GT Commercial ExperienceGT Commercial ExperienceGT Commercial ExperienceGT Commercial Experience
• 6B 95% H2 (Daeson)• 6FA 44.5% H2 (Exxon,
Motiva)• 7FA 37.2% H2 (Tampa, PSI)
Customer/ Site GT Model No. Gas Features1 ExxonMobil Singapore MS6241FA 2 IGCC 44.5% H2
2 Georgia Gulf MS7001EA 3 Blend Methane+50% H2
3 SUV Vresova MS9001E 2 IGCC 46.8% H2
4 BASF/ Geismer MS6001B 1 PG Up to 80% H2
5 Koch Refinery MS6001B 1 RFG 12% to 50% H2
6 Daeson Korea MS6001B 1 PG up to 95% H2
7 Shell Int'l MS5001P 1 RFG 60% H2, propane
8 Reutgerswerke MS3002J 1 PG 60% H2
9 Tenerife MS6001B 1 RFG ~70% H2
10 Cartagena MS6000B 1 RFG 66% H2
11 San Roque MS6000B 2 RFG 70% H2
12 Antwerpen MS6000B 1 RFG 78% H2
© Copyright General Electric Company, 2009
12 Antwerpen MS6000B 1 RFG 78% H2
13 Puertollano MS6000B 2 RFG Up to 60% H2
14 La Coruna MS6000B 1 RFG Up to 52% H2
15 Rotterdam MS6000B 1 RFG 59% H2
16 AGIP/ Milazzo MS5001P 1 RFG 30% to 50% H2
17 Cochin Refineries MS5001P 1 RFG 50% H2
18 Mobil/ Paulsboro MS5001P 2 RFG 20% to 60% H2
19 Uhde NUP MS3002J 1 TG ~60% H2
20 Donges GE10 1 RFG 76% H221 Zarqa Refinery PGT10 1 RFG 82% H2
IGCC=Syngas; RFG=Refinery Gas; PG=Process Gas; TG=Tail GasF-class H2 Combustion Validation … Video Capture of Flame Structure 85-90% H2
FFFF----Class Hydrogen ExperienceClass Hydrogen ExperienceClass Hydrogen ExperienceClass Hydrogen Experience
© Copyright General Electric Company, 2009
IGCC + Carbon Capture…available today!IGCC + Carbon Capture…available today!IGCC + Carbon Capture…available today!IGCC + Carbon Capture…available today!
COCOCOCO2222SSSSHgHgHgHg
Water Gas ShiftWater Gas ShiftWater Gas ShiftWater Gas ShiftCO+HCO+HCO+HCO+H2222O O O O ----> CO> CO> CO> CO2222+H+H+H+H2222
Power
Oxygen,Oxygen,Oxygen,Oxygen,FeedstockFeedstockFeedstockFeedstock
Process Gas OnlyProcess Gas OnlyProcess Gas OnlyProcess Gas OnlyHigh P, Low VolumeHigh P, Low VolumeHigh P, Low VolumeHigh P, Low VolumeHigh Driving ForceHigh Driving ForceHigh Driving ForceHigh Driving Force
SlagSlagSlagSlag
AGR / SRU
Diffusion Diffusion Diffusion Diffusion CombustorCombustorCombustorCombustorDiluent NOx Diluent NOx Diluent NOx Diluent NOx
ControlControlControlControl
Proven Turbine Proven Turbine Proven Turbine Proven Turbine Proven Proven Proven Proven
HHHH2222Gasification CO Shift
Proven Process Proven Process Proven Process Proven Process TechnologyTechnologyTechnologyTechnology
Proven Turbine Proven Turbine Proven Turbine Proven Turbine HHHH2222 CapabilityCapabilityCapabilityCapability
Proven Proven Proven Proven GasificationGasificationGasificationGasification
• 25 GE gas turbines 25 GE gas turbines 25 GE gas turbines 25 GE gas turbines operating at 50%+ Hoperating at 50%+ Hoperating at 50%+ Hoperating at 50%+ H2222
• FFFF----class combustion class combustion class combustion class combustion validation up to validation up to validation up to validation up to 90% H90% H90% H90% H2222
• 65 GE gasifier 65 GE gasifier 65 GE gasifier 65 GE gasifier commercially commercially commercially commercially operating operating operating operating worldwideworldwideworldwideworldwide
• 26 GE gasifier 26 GE gasifier 26 GE gasifier 26 GE gasifier commercially commercially commercially commercially operating using operating using operating using operating using shift reaction to shift reaction to shift reaction to shift reaction to produce Hproduce Hproduce Hproduce H2222
• 33 GE gasifier 33 GE gasifier 33 GE gasifier 33 GE gasifier plants commerplants commerplants commerplants commer----cially operating cially operating cially operating cially operating using AGR techusing AGR techusing AGR techusing AGR tech----nology to remove nology to remove nology to remove nology to remove COCOCOCO2 2 2 2 from shifted from shifted from shifted from shifted syngassyngassyngassyngas
Technology development for future high H2 turbines
Source: US Department of Energy
Objective
GE PG7321FBGE PG7321FBGE PG7321FBGE PG7321FB----H2H2H2H2
Cleaner energy
Approach Capability
IGCCwithCarbon capture
• High-H2 GT fleet• Successful
operation• Diffusion flame• Diluent for NOx
Today
IGCC & CCS combustion landscapeIGCC & CCS combustion landscapeIGCC & CCS combustion landscapeIGCC & CCS combustion landscape
© Copyright General Electric Company, 2009
energy fromcoal Advanced
Separation & Gasification
Technology
• Advanced pre-mix combustion
• Membranes --O2, CO2, H2
• DOE program
FuturePrePrePrePre----mix combustionmix combustionmix combustionmix combustion
GE’s DOE HGE’s DOE HGE’s DOE HGE’s DOE H2222/IGCC turbines program/IGCC turbines program/IGCC turbines program/IGCC turbines program
• Advanced combustion development� Flame imaging� Alternate nozzle concepts
• Full scale, multi-nozzle testing
• Technology advancement for future gas turbines:IGCC - syngas fuelIGCC with carbon capture - H2 fuel
• Objectives:Lower NOxHigher efficiencyLower capital cost
© Copyright General Electric Company, 2009
• Full scale, multi-nozzle testing
Oxygen
• Switch from Nat Gas Switch from Nat Gas Switch from Nat Gas Switch from Nat Gas to Coals & Petcoketo Coals & Petcoketo Coals & Petcoketo Coals & Petcoke
• Reduce Industry Reduce Industry Reduce Industry Reduce Industry dependency from dependency from dependency from dependency from Nat GasNat GasNat GasNat Gas
Future CO2 CaptureCombined Cycle Power Block – 209FB
Create integrated Create integrated Create integrated Create integrated Refinery solutionsRefinery solutionsRefinery solutionsRefinery solutions- Hydrogen- Fischer Tropsch Liquids- Methanol- Carbon Monoxide- Higher Alcohols
Phased NGCC IGCC CCS implementationPhased NGCC IGCC CCS implementationPhased NGCC IGCC CCS implementationPhased NGCC IGCC CCS implementation
© Copyright General Electric Company, 2009
Sulfur
SulfurRemoval
SyngasSyngasSyngasSyngas
Slag
GasifierGasifierGasifierGasifier
MarketableByproducts
Mercury & Sulfur Removal
Build Nat Gas fired Combined Cycle as Build Nat Gas fired Combined Cycle as Build Nat Gas fired Combined Cycle as Build Nat Gas fired Combined Cycle as –––– ‘IGCC ready’‘IGCC ready’‘IGCC ready’‘IGCC ready’
• Fuel flexibility Fuel flexibility Fuel flexibility Fuel flexibility – lower cost fuels than lower cost fuels than lower cost fuels than lower cost fuels than natural gas natural gas natural gas natural gas – will gain importance will gain importance will gain importance will gain importance
• Syngas and Hydrogen fuels will support Syngas and Hydrogen fuels will support Syngas and Hydrogen fuels will support Syngas and Hydrogen fuels will support a low Carbon economya low Carbon economya low Carbon economya low Carbon economy
• Low cost feed stocks (coals, refinery Low cost feed stocks (coals, refinery Low cost feed stocks (coals, refinery Low cost feed stocks (coals, refinery residue) will continue to challenge low residue) will continue to challenge low residue) will continue to challenge low residue) will continue to challenge low
Fuel space of the futureFuel space of the futureFuel space of the futureFuel space of the future
residue) will continue to challenge low residue) will continue to challenge low residue) will continue to challenge low residue) will continue to challenge low emission conversion emission conversion emission conversion emission conversion
• IGCC can leverage lower overall IGCC can leverage lower overall IGCC can leverage lower overall IGCC can leverage lower overall emission footprint than conventional emission footprint than conventional emission footprint than conventional emission footprint than conventional combustion (PM, Hg, S, COcombustion (PM, Hg, S, COcombustion (PM, Hg, S, COcombustion (PM, Hg, S, CO2222, ash/slag), ash/slag), ash/slag), ash/slag)
• Technology is commercially proven at Technology is commercially proven at Technology is commercially proven at Technology is commercially proven at scalescalescalescale…including COincluding COincluding COincluding CO2222 capturecapturecapturecapture