National Atmospheric Deposition Program Wet Deposition Observations Along the Gulf Coast

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National Atmospheric Deposition Program Wet Deposition Observations Along the Gulf Coast Prepared by David Gay, Chris Lehmann, Bob Brunette July 28, 2010 217.244.0462, dgay@illinois.edu , http://nadp.isws.illinois.edu /. National Atmospheric Deposition Network Mercury Deposition Network. - PowerPoint PPT Presentation

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National Atmospheric Deposition Program

Wet Deposition Observations Along the Gulf Coast

Prepared by David Gay, Chris Lehmann, Bob Brunette

July 28, 2010217.244.0462, dgay@illinois.edu, http://nadp.isws.illinois.edu/

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National Atmospheric Deposition NetworkMercury Deposition Network

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Trajectories from the Blowout Location

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Forward Trajectories from the Blowout LocationEvery 12 hours, times in GMT

Approximate time of blowout and fire

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Mercury Deposition Network Data

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44 - 66 - 88 - 1010 - 1212 - 1414 - 1616 - 18> 18

Hg(ng/L)

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!!15

12.7

13.1

17.714.7

12.6

8

7

4

5

9

14

34

18

15

5.9

9.9

8.1

7.7

6.7

6.75.7

7.9

7.4

3.3

5.3

6.84.9

7.7

6.5

8.5

6.36.4

8.4

2.1

6.8 8.2

5.9

6.7

6.6

7.4

7.2

6.1

1.9

6.8

9.1

9.7

9.9

7.6

5.7

5.46.6

5.8

6.6

4.5

5.65.2

6.6

8.5

6.2

7.7

9.1

9.9

7.1

6.5

7.44.4

4.3

4.85.7

4.4

7.45.8

6.3

4.1 4.5

8.3

7.5

9.5

7.8

9.1

7.9

8.1

7.8

9.7

8.1

7.6

8.6

9.8

8.7

7.9

4.8

3.7

3.6

8.9

7.8

8.9

10.5

19.5

11.4

12.9

11.510.3

15.7

24.9

14.6

16.1 13.4

10.5

13.1

11.611.2

10.2

11.4 11.8

10.616.7

14.8

12.4

31.514.8

31.2

Slide 8

Mercury Deposition Network2009 Annual Average

2010 Mid-April through June

concentrations

Provisional Data:Do not cite

Slide 9

Site

2009 Concentration

ng/L

2010 Concentration

ng/L

Concentration Change2010-2009 Change %

FL98 12.6

LA05 12.8 14.7 1.9 15%

LA28 17.0 17.7 0.7 4%

FL05 11.8 13.1 1.3 11%

MS22 8.4 15.0 6.6 78%

MS12 12.7

Mercury Deposition Network2010 (mid April – June) vs. 2009

Provisional Data:Do not cite

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Provisional Data:Do not cite

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Provisional Data:Do not cite

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Blowout Week Deposition vs. All Observations

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Blowout Week Deposition vs. All Spring Observations

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Blowout Week Deposition vs. All Low-Precipitation

Spring Observations

<1inch, LA28 only

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National Trends Network Data

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0

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40

60

80

100

20

25

30

35

40

45

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Precipitatio

n Depth, m

m

oncentratio

n) / (3‐Year A

verage)

Ion Concentrations in PrecipitationIberia Research Station (LA12)

0

5

10

15

20

Ratio

: (Sample Co Ca

Mg

K

Na

NH4

NO3

Cl

SO4

SubPPt

National Trends Network: http://nadp.isws.illinois.edu

16Provisional Data: Do not cite

20

0

20

40

60

80

100

8

10

12

14

16

18

20

Precipitatio

n Depth, m

m

oncentratio

n) / (3‐Year A

verage)

Ion Concentrations in PrecipitationIberia Research Station (LA12)

0

2

4

6

8

Ratio

: (Sample Co

NH4

NO3

SO4

SubPPt

National Trends Network:  http://nadp.isws.illinois.edu

17Provisional Data: Do not cite

10050

Ion Concentrations in PrecipitationSoutheast Research Station (LA30)

60

80

40

45

epth, m

m

)

20

40

60

30

35

40

Precipita

tion D

e

(3‐Year A

verage)

0

20

25

30

oncentratio

n) / (

15

20

atio: (Sam

ple Co Ca

Mg

K

Na

5

10Ra NH4

NO3

Cl

SO4

0 SubPPt

National Trends

18

contamination

Provisional Data: Do not cite

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0

20

40

60

80

100

8

10

12

14

16

18

20

Precipitatio

n Depth, m

m

oncentratio

n) / (3‐Year A

verage)

Ion Concentrations in PrecipitationSoutheast Research Station (LA30)

0

2

4

6

8

Ratio

: (Sample Co

NH4

NO3

SO4

SubPPt

National Trends Network:  http://nadp.isws.illinois.edu

19Provisional Data: Do not cite

0

20

40

60

80

100

0 4

0.5

0.6

0.7

0.8

0.9

1

Precipitatio

n Depth, m

m

Wet Deposition

 (kg/ha)

Ion Wet DepositionSoutheast Research Station (LA30)

0

0.1

0.2

0.3

0.4

Total W

NH4Dep

NO3Dep

SO4Dep

SubPPt

National Trends Network:  http://nadp.isws.illinois.edu

20Provisional Data: Do not cite

21Provisional Data: Do not cite

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Blowout Week Sulfate Deposition vs. All Observations

Slide 23

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Blowout Week Sulfate Deposition vs. All Spring Observations

Slide 25

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Blowout Week Deposition vs. All Spring Observations

w/less than 1 inch rainfall

Slide 27

Change in sulfate ion concentration, 2009-2010 (microequivalents per liter)Six week period mid-April through May; all sites have a minimum of four data points within each 6 week period.

Six-Week Deposition Changes, 2010 vs. 2009

Slide 28

Provisional Data: Do not cite

Change in sulfate ion concentration, 2009-2010 (percent)Six week period mid-April through May; all sites have a minimum of four data points within each 6 week period.

Slide 29

Provisional Data: Do not cite

Change in nitrogen concentration, 2009-2010 (microequivalents per liter)Sum of nitrate plus ammonium ion. Six week period mid-April through May; all sites have a minimum of four data points within each 6 week period.

Slide 30

Provisional Data: Do not cite

Change in sulfate ion concentration, 2009-2010 (percent)Six week period mid-April through May; all sites have a minimum of four data points within the 6 week period.

Slide 31

Provisional Data: Do not cite