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PHARIO – A Full Scale/Pilot Scale

Practical Evaluation of

Regional Biopolymer Value Chains

Built on Residuals Management Services

Tomas Alexandersson, Simon Anterrieu, Monica Arcos, Simon Bengtsson, Giulia Degrazia, Markus Hjort, Peter Johansson, Anton Karlsson, Lamija

Karabegovic, Per Magnusson, Fernando Morgan, Luca Quadri, Eric Train, Jacob Bruus, Alan Werker… (VWT)

Leon Korving, Etteke Wipkema, Levien van Dixhoorn, Jack Eversdijk, Lennert de Graaf, Martijn Gebraad… (WBD)

Jarno de Jonge, Victor Claessen, Alexandra Deeke, Doy Schellekens, Peter van Horne… (WDD)

Yede van der Kooij… (WF), Martin Tietema, Peter Dijkstra, Cindy Visser, Yme Flapper (KNN), Luc Sijstermans (SNB),

Cora Uijterlinde (STOWA),…

Looking Back and Ahead from 2002 – Cella™ Technologies

2002 2015

Fundamental R&D

Integration Strategies for Business Developments

First Circular Economies

Pilot Prototyping

Demo/1st Full Scale

2

Food and Dairy WW

Municipal WW and Sludge

Municipal WW and Agro-Industry Residues

A Party for the Biomass Produced From Water Treatment

RWZI Bath ≈ 500,000 p.e. Waste Activated Sludge Produced ≈ 2500 tVSS/yr

PHA (Biopolymer) Production Potential ≈ 2000-2500 t/yr

The Sludge is ”Wasted” – Let’s Make this active biomass a Harvested Functional Resource

Functional

Biomass

Bioplastic From Bacteria Produced During WWT

WAS or Harvested Functional Activated Sludge?

Polyhydroxyalkanoate (”Biopolymer”) Production from Services of Wastewater Treatment 7

PHA PHA

Granules of Polyhydroxyalkanoates (PHA)

”Photoshop’d for illustration”

CellaPol™ Production – 2 Regional Input Raw Materials

BIOMASS (Activated

Sludge)

PHA

(Residual) REGIONAL ORGANIC

FEEDSTOCK +

= 10

PHA

PHARIO - Making a Move Up The Renewables Value Pyramid

11

Source: IMA Fungus. 2012 Jun; 3(1): 87–92. Figure by Peter Westermann, Aalborg University

PHA

Focus – Raw Materials Supply and Product Quality

(Residual) ORGANIC

FEEDSTOCK +

= 12

(Residual) ORGANIC

FEEDSTOCK

(Residual) ORGANIC

FEEDSTOCK

(Residual) ORGANIC

FEEDSTOCK

(Residual) REGIONAL ORGANIC

FEEDSTOCKS

Harvested Activated

Sludge

PHA

PHA

Products and Product Quality as a function of Material Source and/or Time

Process Elements PE1-PE4

Contaminated Waste Water

Municipal/Industry Wastewater Treatment

Functional Biomass

Treated Water

Process Elements Integrated Within Existing Municipal/Industrial Infrastructures 13

Municipal/Industry Wastewater Treatment

Process Elements PE1-PE4

Contaminated Waste Water

Functional Biomass

Treated Water

Process Elements Integrated Within Existing Municipal/Industrial Infrastructures

Not Waste, Not Sludge! Resource for making 1000s tPHA/yr

14

Process Elements PE1-PE4

Contaminated Waste Water

Municipal/Industry Wastewater Treatment

Functional Biomass

Treated Water

Regional VFA Rich Feedstock

Process Elements Integrated Within Existing Municipal/Industrial Infrastructures

VFA = Volatile Fatty Acids

15

VFA Rich Feedstock

Process Elements PE1-PE4

Contaminated Municipal Water

Municipal/Industry Wastewater Treatment

Functional Biomass

Treated Water

Treated Water

Process Elements Integrated Within Existing Municipal/Industrial Infrastructures

PHA

16

VFA Rich Feedstock

Process Elements PE1-PE4

Contaminated Waste Water

Municipal/Industry Wastewater Treatment

Functional Biomass

Treated Water

Treated Water

PHA

PHA

Process Elements Integrated Within Existing Municipal/Industrial Infrastructures 17

Municipal/Industry Wastewater Treatment

VFA Rich Feedstock

Green Chemistry – Side Products and Services

Contaminated Waste Water

Functional Biomass

Treated Water

Treated Water

PHA

PHA

Process Elements Integrated Within Existing Municipal/Industrial Infrastructures

No Water No Waste

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Municipal/Industry Wastewater Treatment

VFA Rich Feedstock

Cella™ Technologies – Stimulating Value Chains

Contaminated Waste Water

Functional Biomass

Treated Water

Treated Water

PHA

PHA

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Municipal/Industry Wastewater Treatment

VFA Rich Feedstock

PHARIO Case Study – One Biomass – Many Products

Municipal Wastewater

Functional Biomass

Treated Water

Treated Water

PHA

PHA

VFA Rich Feedstock

VFA Rich Feedstock

VFA Rich Feedstock

PHA PHA PHA 20 Polymer Product Quality

RWZI Bath ≈ 500,000 p.e. Waste Activated Sludge Produced ≈ 2500 tVSS/yr

PHA Production Potential ≈ 2000-2500 t/yr

The Sludge is ”Wasted” – Why not Make it a Harvested Functional Resource

Pilot Scale PE1 and PE3 Located at RWZI Bath

Mobile PHA Recovery Unit – Lund Sweden

23

CellaPol™ Pilot Production (10 L Batch Process)

From Municipal or

Industrial WWT Facilities

PHA

24

PHA

A Pressed Cake of CellaPol™ - PHARIO Production Routine

25

PHA

Value Chains From Environmental Engineering Services

PHA rich Biomass

Biomass Residual

Recovered PHA

Bioplastics

Environmental Protection/Residuals Management Biobased Society

Value Chains And Material Product Market Combinations

VFA

Supply

PHA-rich biomass

PHA Recovery Bioplastics Bioplastic

compounders & converters

Products &

Services

Forward & Backward Feedback

28

Bridging to the Biobased Value Chain Market Gap

VFA

Supply

PHA-rich biomass

PHA Recovery Bioplastics Bioplastic

compounders & converters

Products &

Services

Waterboards, Industries and

Regional Raw Materials

Regional Entrepreneurial

Biobased Products and Services

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V1.0

PHARIO: a stepping stone to regional economic development

PHARIO 50

kg/yr

Demonstration Value Chain

100 ton/yr

1st commercial Value Chains

2000-5000 ton/yr

Further biobased growth

10000 + ton/yr

2015 - 2016

2017-2018

2019-2021 2021 and beyond

Earlier Cella™ Pilot Projects (2008-2015): Lund, Eslöv, Groningen, Leeuwarden, Brussel, Brande

Thank You!

PHARIO is financially supported by a subsidy from the Topsector Energy program of the Dutch ministry of

Economic Affairs and contributions by the PHARIO project partners: Veolia Water Technologies, the Dutch water

authorities Brabantse Delta, De Dommel and Fryslan, STOWA, KNN and Slibverwerking Noord-Brabant