10 Edition SUNJIN Catalog1 SUN CARE - in-cosmetics

SUNJIN Catalog1 SUN CARE SINCE 1978

2 SUNJIN Members in 2012

3 Company overview

4 In vivo & in vitro test capabilities @SUNJIN

5 New Nano Definition of EU Commission

6 Product Guideline Table

APRIL 2012

10 THE TH

Edition

(2) TiO2 Dispersion

16 SFT85-AB:

Non Nano

EU UVA protection

No Alumina, Alkylbenzoate Dispersion

19 SFT85-CCTG & CC :

ECOCERT TiO2 Dispersion

Non Nano

EU UVA protection

22 TPD40-AB

Nano Alkylbenzoate Dispersion

26 SUNCLEAR T40AQ

Aqueous TiO2 Dispersion

(5) Zinc Oxide

54 Zinc Oxide Powder

59 Zinc Oxide Dispersion

(6) Guideline Formula

65 ECOCERT Sun care

66 W/O Mineral Sun Care

67 W/O ZnO Only Sun Care

68 W/Si Shaking Sun Milk Lotion

69 O/W Light Texture Sun Cream

70 Sun Protect Gel

71 BB Cream

72 Powdery Sun Block

73 Non Nano Pressed Powder

(1) Non Nano TiO2

7 T-80 Series

Non Nano TiO2 Powder

EU UVA protection Guideline

- Critical wavelength ≥ 370nm

- UVA / UVB ≤ 1/3

13 T-80 JJ & T-80 LL

Non Nano & EU UVA Protection

ECOCERT Jojoba ester or Lauroyl Lysine coated TiO2 Powder

(4) Hybrid Chemical UV Filters

35 Avobenzone encapsulated

Hybrid PMMA

46 Hybrid Talc (DM)

MBBT coated talc

51 FP-OMC

OMC containing porous PMMA

(3) TiO2 encapsulated Silica Bead

31 SUNSIL Tin50

TiO2 Encapsulated Silica Bead

SUNJIN MEMBERS in 2012

Copyright © 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 3

INTRODUCTION

Micro bead synthesis

Nano powder synthesis

Encapsulation & Composition

Surface treatment

TECHNOLOGY OVERVIEW

Dispersion

Organic synthesis

porous

nano & micro encapsulation

hollow

Triple composition

solid

nano & micro

Founded in 1978

Headquartered in Korea

Product Category:

Cosmetic Raw Materials,

Surfactants,

Paint & Coating Raw Materials,

Plastic,

Optical Materials

ISO 9001 certified

COMPANY OVERVIEW

Plastic

Flat Panel Display: LCD, PDP

SUNJIN brings new concepts & new technologies From other industries TO COSMETICS

Paint & coating


All Formulas from SUNJIN,

With in vivo test results

SUNJIN owns in vivo & in vitro SPF & PA test capabilities

In vitro SPF & PA test @ SUNJIN Chemical Co. In vivo SPF & PA test @ SUNJIN Chemical Co.

Optometrics 290

Installed at SUNJIN in 2001

SPF Testing 601-300W Multiport UV Solar Simulator


Sample Report from SUNJIN


New Nano Definition of the EU Commission(October 2011)

New Definition of the EU commission about Nano (October 18th 2011) A natural, incidental or manufactured material containing particles, in an unbound state or as an aggregate or as agglomerate and where, for 50% or more of the particles in the number size distribution, one or more external dimension is in the size range 1nm – 100 nm

If the product contains Nano Material, it must be labeled on container and package. New recommendation will be fully effective on 11 July 2013 when all provisions of the Regulation become enforceable. All ingredients present in the form of nano materials shall be clearly indicated in the list of ingredients. The names of such ingredients shall be followed by the word “nano” in brackets. ex: Titanium Dioxide Titanium Dioxide(Nano)

Quiz: Nano or Non nano?

10nm

(1)

150nm

(2)

150nm

120nm

10nm

(3)

120nm

(4)

10nm


in vivo in vivo Sun Care Skin Care Make-up Remarks

SPF/% PFA/% O/W W/O O/W W/O Powder

Hybrid ABOC 0.75 +++ +++ +++ Premium skin care & sun care

Hybrid EHT +++ +++ +++ SPF

FP-OMC 0.8 ++ +++

Hybrid TALC(DM) 0.4 0.2 +++ +++ +++ +++ Hybrid for make up

T-80AS 2.6 0.5 +++ +++ +++ +++

Non nano TiO2

T-80JJ 2.5 0.5 +++ +++ +++ +++

T-80LL 2.5 0.5 +++ +++ +++ +++

SUNSIL Tin50 0.3 +++ ++ +++ +++ +++

SUNSIL Tin50AS 0.3 +++ +++ +++

SUNZNO-NCO 1.5 0.3 +++ +++ ++

SUNZNO-NAS 1.5 0.3 +++ +++ ++

SUNZNO 0.9 0.3 ++ + + ++ Ecocert sun care

SUNZNO-SA 0.9 0.3 +++ +++ +++ Ecocert sun care

SFT85-AB 1.26 0.25 +++ +++ +++ +++

Oil Dispersion for sun care

SFT85-CCTG 1.25 0.25 +++ +++ +++ +++

SFT85-CC 1.25 0.25 +++ +++ +++ +++

TPD40-AB 1.5 +++ +++ +++ +++

TD50-AB 1.2 ++ +++ + +++

Z60CO 0.8 0.2 +++ +++

ZD60-AB 0.8 0.2 ++ +++ + +++

ZD60-BOS 1 0.2 + +++ + +++

T40AQ ECOCLEAR Z50

1 +++ Aqueous Dispersion for sun care

Benchmarks

OMC 1.5

Tinsorb S 1

15nm TiO2 2.5

Product Guideline Table

ECOCERT

T-80 Series: TiO2 Powder

Non Nano EU UVA Guideline

SPF / UVA PF Ratio ≤ 3 Critical Wavelength ≥ 370nm

No Alumina


T-80 series: NON NANO TiO2

TiO2

Silica Thin layer Coating

Primary TiO2 Aggregation Granulation Nano TiO2 bound By inorganic silica binder to from Micro size granule

Surface treatment

T-80AS

20nm

TiO2

Silica

Alkyl Silane

T-80JJ or T-80LL

Jojoba Ester or Lauroyl Lysine T-80AS TiO2 80% SiO2 15% Alkyl Silane 5%

T-80JJ or T-80LL TiO2 80% SiO2 12% Jojoba Ester 8% Lauroyl Lysine 8%

T-80

Copyright © 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED.

T-80 series are Broad Spectrum UV Filter

15nm Nano TiO2

Product “M“

T-80JJ

(1)

(2)

Primary TiO2 particle for

UVB protection

Secondary semi spherical TiO2 granule for

UVA protection and

Better spread and feel

20nm

9

Much better UVA protection

UVB

Same level of UVB protection

UVA

In vivo SPF/%

In vivo PA/%

15nm TiO2 Product ”M”

2.5

2.6 2.5 2.5

T-80AS T-80JJ T-80LL

0.5 0.5 0.5


NON NANO T-80JJ

T-80 series are NON NANO

T-80JJ TiO2 80% SiO2 12% Jojoba Ester 8% Particle Size 300nm ~ 1um D10 : 309nm D50 : 458nm D90 : 918nm Specific Surface Area 48m2/g

10


T-80JJ, NON-NANO & Not Breakable

T-80JJ

20nm TiO2

35nm ZnO

NANO Particle detection test results from RAW Material

T-80JJ 10% containing

W/O formula

35nm ZnO 10% containing

W/O formula

20nm TiO2

10% containing W/O formula

NANO Particle detection test results from finished formula

Test Equipment used

Light Scattering size analyzer

Malvern Mastersizer 2000


11


T-80 series are Alumina Free

T-80AS T-80JJ or T-80LL

T-80AS TiO2 80% SiO2 15% Alkyl Silane 5%

T-80JJ or T-80LL TiO2 80% SiO2 12% Jojoba Ester 8% Lauroyl Lysine 8%

12


T-80JJ vs T-80LL are ECOCERT

T-80JJ Better Hydrophobicity Ideal for Sun Care

T-80LL Better Skin Feel Good for Make-up

T-80JJ or T-80LL

13

TiO2 SiO2 Jojoba Ester Lauroyl Lysine

80% 12% 8% 8%

TiO2 Dispersion Overview

1. Non Nano Alkyl Benzoate Dispersion

2. ECOCERT Dispersion

3. Nano Alkyl Benzoate Dispersion

4. Aqueous Disersion


Overview: TiO2 dispersion

SFT85-AB SFT85-CCTG SFT85-CC TPD40-AB T40AQ

Carrier Alkyl Benzoate Caprylic Capric Triglyceride

Dicaprylyl Carbonate

Alkyl Benzoate H2O

Solid % 60% 60% 60% 45% 40%

Net TiO2 % 48% 48% 48% 35% 32%

TiO2 coating Silica / Triethoxy caprylyl silane

Silica / Jojoba Ester


Alumina Hydrated Silica

Dispersing agent Polyhydroxy stearic acid

Polyhydroxy stearic acid



Disodium stearyl Sulfosuccinamate

Non-Nano - -

EU UVA Protection - -

ECOCERT - - -

Alumina Free -

SFT85-AB: TiO2 Alkyl Benzoate Dispersion

Non nano EU UVA Guideline

SPF / UVA PF Ratio ≤ 3 Critical Wavelength ≥ 370nm

No Alumina


SFT85-AB is NON Nano TiO2 dispersion

T-80AS TiO2 80% SiO2 15% Alkyl Silane 5%

SFT85-AB

Carrier Alkyl Benzoate

Solid % 60%

Net TiO2 % 48%

TiO2 coating Silica / Triethoxy

caprylyl silane

Dispersing agent


As NON NANO T-80AS USED,

D10 : 377nm D50 : 578nm D90 : 1.155um

PSD of SFT-85AB shows no nano particle


SFT85-AB meets EU UVA Protection Guideline

Trade Name %

A

D.I-Water 50.15

P.G 4.0

Carbopol 940 2% 8.0

B

Arlacel 60 0.5

Tween 60 2.7

Kalcohol 6870 1.0

TCG-M 8.0

Myristic Acid 2.5

Arlacel 165 2.0

C TEA 0.2

D SFT85-AB 20.0

E Phenoxyethanol 0.8

Fragrance 0.15

20% of SFT-85AB @ O/W sun cream

Test Result SFT85-AB

in vivo SPF 25

in vitro SPF 33.29

in vitro UVA PF 15.47

SPF/ UVA PF =25/15.47

=1.62

C.W 377 ≥ 370nm

≤ 3.0

In vivo SPF 25 @ 20% of SFT-85AB = 25/20 = 1.25 SPF/1% dispersion SFT-85AB = 48% Net TiO2 In vivo SPF25 @ 20% of SFT-85AB = 25/20/48% = 2.6 SPF/1% Net TiO2

EU UVA Protection Guideline

In vitro

EU Collipa Regulation(PMMA-Plate)

Optometrics 290 at SUNJIN

In vivo

EU Collipa Regulation

SPF Testing 601-300W Multiport UV Solar Simulator Installed at SUNJIN in 2009

TEST METHOD

SFT85-CCTG & CC: ECOCERT TiO2 Dispersion

Non nano EU UVA Guideline

ECOCERT No Alumina


SFT85-CCTG & CC, Non Nano & ECOCERT & UVA Protection

T80-JJ TiO2 80% SiO2 12% Jojoba Ester 8%

SFT85-CCTG SFT85-CC

Carrier Caprylic Capric Triglyceride


Solid % 60% 60%

Net TiO2 % 48% 48%

TiO2 coating Silica / Jojoba Ester


Dispersing Agent



D10 : 254nm D50 : 341nm D90 : 635nm

As NON NANO T-80JJ USED for both CCTG & CC dispersions

PSD of SFT-85CCTG & CC show no nano particle


SFT85-CCTG meets EU UVA Protection Guideline

Trade Name %

A

D.I-Water 50.15

P.G 4.0

Carbopol 940 2% 8.0

B

Arlacel 60 0.5

Tween 60 2.7

Kalcohol 6870 1.0

TCG-M 8.0

Myristic Acid 2.5

Arlacel 165 2.0

C TEA 0.2

D SFT85-CCTG 20.0


Fragrance 0.15

20% of SFT85-CCTG @ O/W sun cream

In vitro

EU Collipa Regulation(PMMA-Plate)

Optometrics 290 at SUNJIN

In vivo

EU Collipa Regulation

SPF Testing 601-300W Multiport UV Solar Simulator Installed at SUNJIN in 2009

TEST METHOD

In vivo SPF 24 @ 20% of SFT85-CCTG = 24/20 = 1.2 SPF/1% dispersion SFT85-CCTG = 48% Net TiO2 In vivo SPF25 @20% of SFT85-CCTG = 24/20/48% = 2.5 SPF/1% TiO2

Test Result SFT85-CCTG

in vivo SPF 24

in vitro SPF 33.3

in vitro UVA PF 15.2

SPF/ UVA PF =24/15.2

=1.58

C.W 377 ≥ 370nm

≤ 3.0

EU UVA Protection Guideline

TPD40-AB: Nano TiO2 Alkyl Benzoate Dispersion

NO ODOR Transparent

Highest 1.5 SPF/% Can be used O/W or W/O


W: White Index Higher White index means less transparency

TPD40-AB

W = 18.17 W = 19.16

TPD40-AB


Solid % 45%

Net TiO2 % 35%

TiO2 coating Alumina

Dispersing agent


1) Odor No odor

2) Transparency

TPD40-AB C12-15 AB dispersion

TiO2(35%)

Benchmark “C” C12-15 AB dispersion TiO2(35%)

odor

3) Absorption curve TPD40-AB

“C”


TPD40-AB

4) In vivo SPF

TPD40-AB C12-15 AB dispersion

TiO2(35%)

Benchmark “C” C12-15 AB dispersion TiO2 (35%)

Formula O/W Sun Cream

TPD40-AB(%) Net TiO2 35%

20 -

Benchmark “C” (%) Net TiO2 35%

- 20

In vivo SPF 30 28

Unit SPF/(%) 1.5 1.4

In vivo tested @ SUNJIN

Test Formula TPD40-AB 20% @ O/W sun cream

Part Trade Name % %

A

D.I-Water 49.7 49.7

P.G 4.0 4.0

Carbopol 940 2% 8.0 8.0

B

Arlacel 60 0.5 0.5

Tween 60 2.7 2.7

Kalcohol 6870 1.0 1.0

TCG-M 8.0 8.0

Myristic Acid 2.5 2.5

Arlacel 165 2.0 2.0

C TEA 0.2 0.2

Sepiplus 400 0.5 0.5

D TPD40-AB 20.0 -

Benchmark “C” - 20.0

E Phenoxyethanol 0.8 0.8

Fragrance 0.15 0.15


TPD40-AB can be used both W/O & O/W formula

Trade Name %

A

Dehymuls LE 2.0

Arlamol HD 10.0

TCG-M 4.0

B

D.I. Water 57.0

Magnesium Sulfate 1.0

1,3-BG 5.0

C TPD40-AB 20.0

D Phenoxyethanol 0.8

Fragrance 0.2

Trade Name %

A

D.I-Water 49.65

P.G 4.0

Carbopol 940 2% 8.0

B

Arlacel 60 0.5

Tween 60 2.7

Kalcohol 6870 1.0

TCG-M 8.0

Myristic Acid 2.5

Arlacel 165 2.0

C TPD40-AB 20.0

D TEA 0.2

Sepi Plus 400 0.5


Fragrance 0.15

SPF30,

In vivo tested

@SUNJIN

TPD40-AB


Solid % 45%

Net TiO2 % 35%

TiO2 coating Alumina

Dispersing agent


O/W sun cream

In internal oil phase

W/O sun cream

In external oil phase

No need to have 2 different kinds of dispersions to make O/W and W/O

simple inventory management

SUNCLEAR T40AQ: Aqueous Nano TiO2

NO ODOR Low Viscosity

Good Compatibility with thickeners


T40AQ, Aqueous TiO2 dispersion

(1) NO odor You can’t smell anything from T40AQ

Pourable Sprayable

(2) Low viscosity

Preservative used

Optiphen, composed of

Phenoxyethanol, Caprylyl Glycol.

(3) T40AQ, good compatibility with thickeners

T40AQ

Carrier H2O

Solid % 40%

Net TiO2 % 32%

TiO2 coating Hydrated Silica

Dispersing agent

Disodium stearyl Sulfosuccinamate

Copyright © 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 28 28

T40AQ has good compatibility with popular thickeners

Tested thickeners T40AQX T40AQ

VEEGUM:

Magnesium aluminum silicate

OK OK

CARBOPOL 940:

Carbomer

0.1% OK 0.3% OK

SEPIGEL 305:

Polyacrylamide/ C13-14 Isoparaffin/ Laureth-7

0.3% OK OK

FLOCARE ET76:

Sodium Polyacrylate & Hydrogenated Polydecene & Trideceth-6

0.3% OK 1% OK

More Thickener compatible

Test condition

Tested formula: O/W,

Emulsifier used :

AR165 2% & TWEEN60 1%

T40AQ or T40AQX used 15%

0.3% 0.5%

T4

0A

Q

SUNCLEAR T40AQ

T4

0A

QX

T4

0A

Q

T4

0A

QX


Why Aqueous Dispersion?

TiO2

Chemical UV filters in internal oil phase

Why do I need Aqueous dispersion? When to use?

1. Better product stability because of separation between chemical UV filters and

physical UV filters

2. Synergistic SPF boost comes from Improved skin coverage: incorporation of one

active the oil phase and one in the water phase of an emulsion results in

improved overall coverage of the skin

Chemical filter in oil phase

Physical filter in Water phase

Chemical filter in oil phase

Physical filter in Oil phase

When you make O/W sun care, it’s always better to put Chemical UV filters inside internal oil phase,

while putting Physical filters such as TiO2 in external water phase because

Better UV protection efficiency Better formula stability


Split UV filters for SPF efficiency

Phase Ingredients %

Water Phase

D.I. Water 30.3

SUNCLEAR-T40AQ 15.0

SUNSIL-Tin50 3.0

1.3 BG 5.0

Phenoxy Ethanol 0.5

Allantoin 0.2

Oil Phase

Cetiol CC 10.0

ZD60-BOS 30.0

KSG 16 2.0

ABIL EM90 2.0

KF-6017 2.0

Phase Ingredients %

Water phase

D.I. Water 34.3

NaCl 1.0

1.3 BG 5.0

Phenoxy Ethanol 0.5

Allantoin 0.2

Oil Phase

Cetiol CC 10.0

ZD60-BOS 30.0

TPD40-AB 13.0

SUNSIL-Tin50 3.0

KSG 16 2.0

ABIL EM90 2.0

KF-6017 2.0

ZnO used = 30%*55%* = 16.5 % TiO2 used = 13%*37% + 3.0%*40% = 4.8% + 1.2% = 6.0 % Total mineral UV filter = 16.5%+6.0% = 22.5%

ZnO used = 30.0%*55% = 16.5 % TiO2 used = 15.0%*32% + 3.0%*40% = 4.8% + 1.2% = 6.0 % Total Mineral UV filter used = 16.5% + 6.0% = 22.5%

Split for Better Efficiency!

O/W O/W

UV Filters No Split only in oil phase @O/W UV Filters Split in oil & water phase @O/W

Non Nano TiO2

Great Sensorial Feeling Truly Transparent

ECOCERT


SUNSIL Tin50 is TiO2 Encapsulated Silica Bead

Silica Bead: SUNSIL 130 SH 219 SUNSIL Tin50

TiO2 SUNSIL Tin NaturalWhite

Grade Descriptions Crystal size of TiO2

Size of silica bead (㎛)

SUNSIL-Tin50 TiO2 42% & Silica 58% 12 nm 2~7

SUNSIL-Tin50AS TiO2 41% & Silica 57% Alkyl Silane 2%

12 nm 2~7

5um Silica Bead With 12nm TiO2

No nano particle visible

Extremely Transparent as

compared to TiO2


Tin50 is alone not a good UVB filter but a UVB booster

I tested SUNSIL Tin50.

But I could not get enough SPF. What should I do?

4.2 1.2

6.6

5.0

10.0

15.0

20.0

NAS 3%

Tin50 4%

1.2 5.0

10.0

15.0

20.0

Tin50 4%

8.5

15.4

TiO2 3%

SPF boost = 5.7

4.2 1.2 5.0

10.0

15.0

20.0

25.0

30.0

NAS 3%

Tin50 4%

SPF

8.5

TiO2 3%

25.3

SPF boost = 11.4

SPF boost = 0.2

O.K. SPF boost Between Tin50 and TiO2

Good

SPF

synergy

Unit SPF of 1% of Tin50: 0.3

Tin50 is low SPF by itself But

when used together with TiO2

& ZnO has great synergistic

SPF boost.

Tin50 is a good UV booster

Tin50 4%

NAS 3% +

Tin50 4%

TiO2

3% +

Tin50 4%

TiO2 7% +

NAS 3% +

Almost no SPF boost

Between Tin50 and ZnO


In vivo test result of Tin50

In vivo SPF

tested @SUNJIN 35

Trade Name

Micronized TiO2

Micronized ZnO

Octyl Methoxy Cinnamate

SUNSIL-Tin50

#1

2.3

12

3

-

#2

2.3

12

3

3

41

Synergistic SPF boost of 3% Tin50 = 41-35 = 6

1% Tin50 boosted 2 SPF Tin50 is very useful UVB booster especially

when you make SPF50/PA+++ sun care

products as Tin50 does not hurt transparency and sensorial feel of high SPF formula

O/W sun cream

Oil soluble UV filter into water phase Great Sensory

Minimized skin irritancy Improved photostability


The amount of BMDBM decreases

weakening of the UVA protection

(3) Poor Compatibility

(2) Poor Photo-stablility

Aluminum oxide is one of the most

common coating material for TiO2.

BMDBM forms a complex with Al3+

salts from TiO2 coatings

Avobenzone degrades quickly in the sun.

Researchers have reported a 36% reduction

in UVA absorption by avobenzone after only

15 minutes of exposure. In vitro studies have

shown a 50% loss in UVA blockage for

different sunscreen formulations, confirming

the photodegradation of avobenzone.

(4) Crystallization

BMDBM is susceptible to

crystallization that results in loss of

product aesthetics, sun protection,

appearance, stability

Dimethicone 0 3

Cyclomethicone 0 50

Mineral oil 1 50

Isostearyl Isosterate 3 50

Octylpalmitate 3 50

Capric/Caprylic Triglyceride 7 50

Isopropyl Myristate 9 50

PG/Dicaprate/Dicaprylate 5 50

C12-C15 Alkyl Benzoate 11 50

Octyldodecanol 13 50

Ethyl Butylacetylaminopropionate 26 50

(1) Poor Solubility

Globally Approved: USA, EU,

Japan, Australia

Approved % by FDA is 3%

Very Affordable Price

Very Efficient UVA Filter

Avobenzone has exceptionally

high molar extinction

coefficient(>30,000) and גmax

of 357nm…

BMDBM(=Avobenzone) is a great UVA filter but has Problems too

INCI Name Trade Name USA Japan EU Australia

BEMT Tinosorb S - - 10 -

BMDBM Parsol 1789 3 10 5 5

However, BMDBM is globally approved

BMDBM Problems


EHT most powerful UVB filter

Globally Approved: EU(5%), Japan(3%), Australia(5%), Korea(5%)

Extremely low skin penetration

Excellent photostability

EHT, oil soluble UVB filter is the most powerful of its kind and has the

highest UV absorption

Etheylhexyl Triazone

(1) Poor Solubility

Problems

(2) Crystallization

EHT is susceptible to crystallization

that results in loss of product

aesthetics, sun protection,

appearance, stability

PPG-3 myristyl ether 13.0

Polyol-fatty acid ester 10.0

Triethyl citrate 9.0

Caprylic/capric acid triglycerides 4.0

C12C15-alcohol benzoate 4.0

Isopropyl myristate 3.5

Isopropyl palmitate 2.0

Oleic acid decyl ester 1.5

2-Ethylhexanoic acid cetylstearyl ester 1.0

Olive oil 1.0

Peanut oil 1.0

Jojoba oil < 1.0

Propylene glycol < 1.0

Liquid paraffin < 1.0

EHT is one of the strongest UVB filters.


Grade Composition Particle size(um) Remark

Hybrid ABOC BMDBM(Avo Benzone) 28~32%

Octocrylene 5~8%

PMMA 62~67%

2~7

UVA

Hybrid ABOS BMDBM(Avo Benzone) 28~32%

Ethyl Hexyl Salicylate 5~8%

PMMA 62~67%

2~7

UVA

Hybrid AB BMDBM(Avo Benzone) 28~32%

PMMA 68~72%

2~7 UVA

Hybrid EHT Ethyl Hexyl Triazone 28~32%

PMMA 68~72%

2~7 UVB

HYBRID PMMA is PMMA bead containing UV filters inside

Korean Patent Registered No. 10-2007-0083469 US Patent Application No. 11/872,456 “POLYMER COMPOSITE PARTICLES CONTAINING SUNSCREEN AGENT AND MANUFACTURING METHOD THEREOF” Japanese Patent Application 特願 2007-272539

Global patent pending By SUNJIN

Core: Chemical UV Filter Inside For UV protection

Shell: PMMA Bead 1) For Sensorial Modification 2) Oil soluble UV filters can be used into water phase

Benefits of Hybrid PMMA 1) Oil soluble UV filters into water

phase 2) Silicone insoluble UV filters into

silicone gel phase 3) Diminished skin irritancy 4) Improved photo-stability


Benefit 1: Oil soluble UV filters into water phase

Solution from SUNJIN: Putting Hybrid PMMA into water phase Challenges in sun care

formulation

Most chemical UV filters are oils and

need more oily emollients to be

dissolved in.

This makes an unpleasant and

sometimes sticky feel on the skin. To

make High SPF & PA sun care

formulation, oil soluble UV filters

should be used a lot which ends with

highly loaded oil phases which lead

to the most common limitations in

sun care formulations:

- Sticky and oily sensory

- Suboptimal UV protection

performance due to putting oil

soluble UV filters mainly in oil

phase

Benefits

As spherical PMMA bead which is frequently used as a sensory modifier, Hybrid

PMMA greatly improves sensorial feeling of sun care cosmetics

Minimize usage of oily emollients only to solubilize oil soluble chemical UV filters

Splitting UV filters in oil and water phase to distribute UV filters on skin more

homogeneously which often provides a SPF & PA boosting effect

Better formulation flexibility

No negative influence on water resistance

No whitening effect

Hybrid PMMA Bead

Chemical UV filters in internal oil phase


Phase Ingredients %

A: Water Phase

D.I. Water 40.20

1,3–BG 5.00

Glycerin 3.00

Phenoxy ethanol 0.50

Allantoin 0.10

1% carbopol 940 20.00

Arlatone 2121 1.00

1% hyalluroic acid 1.00

B: Oil

Phase

Salacos 99 2.00

Rheodol TW S-120 1.50

Rheodol MS 165 1.50

Parsol MCX 6.50

Parsol EHS 4.00

TSF 405 4.50

Kalcohol 6870 0.50

DC 200F-10cs 1.00

Vege Wax 1.50

C T.E.A 0.20

D: into water phase

Hybrid ABOC 6.00

Phase Ingredients %

A D.I.Water 41.27

ARISTOFLEX AVC 0.30

B

1,3-BG 8.00

EDTA-2NA 0.10

SUNCLEAR Z-50AQX 7.00

SUNSIL TIN50 5.00

PHENOXY ETHANOL 1.00

OLIVEM 1000 0.80

C

ARLACEL 165 2.00

OMC 6.30

PARSOL EHS 4.50

ESCALOL 507 5.00

DC 345 3.00

SENSOFT 4.20

BEESWAX 0.70

STEARIC ACID 1.50

VIT E ACETATE 0.20

D: into water phase

HYBRID ABOC 7.00

COCO170 2.00

E Fragrance 0.13

SJF-1101-DAILY SUN Lotion-O/W-ver1.0

In vivo SPF 20,

PA 4.5 (++)

Hybrid PMMA provides

Extremely light texture

Minimized skin irritancy

PA++ can be achieved

easily by incorporating 6%

inside formula

SJF-1102-SUN Cream-O/W-ver1.1

In vivo SPF 40,

PA 5.7 (++)

Benefit 1: Oil soluble UV filters into water phase


No. Trade Name INCI %

A

1 SUNTITAN-AS Titanium dioxide/ Triethoxy caprylyl silane

7.00

2 SUNSERI-AS Sericite/ Triethoxy caprylyl silane 5.00

3 SUNMICA-AS Mica/ Triethoxy caprylyl silane 2.00

4 SUNSIL-130HSC Silica / Methicone 5.00

5 SUNSIL Tin50 Silica/ Titanium dioxide 3.50

6 Hybrid Talc(DM) Talc/ MBBT /Dimethicone 5.00

7 Hybrid ABOC PMMA/Avobenzone/Octocrylene 5.00

8 SUNIOR-AS Iron oxide Red/ Triethoxy caprylyl silane 0.42

9 SUNIOY-AS Iron oxide Yellow/ Triethoxy caprylyl silane

0.84

10 SUNIOB-AS Iron oxide Black/ Triethoxy caprylyl silane 0.05

B

11 SALACOS 99 Isononyl isononanoate 10.00

12 DC200-10CS Dimethicone 5.00

13 SQUALANE Squalane 3.00

14 IPP Isopropyl Palmitate 2.00

15 L.P Liquid Paraffin 6.00

16 NOMKORT HKG Glyceryl Behenate / Elcosadioate 4.00

17 JOJOBA OIL Jojoba oil 1.00

18 VIT.E ACETATE Tocopheryl Acetate 0.20

19 PARSOL MCX Ethylhexyl Methxycinnamate 2.00

20 GRAPE SEED OIL Grape Seed Oil 3.00

C 21 KSG 16 Dimethicone/ Vinyl Dimethicone Cross Polymer

30.00

D 22 FRAGRANCE FRAGRANCE 0.08

SJF-0806-Mousse Foundation-ver2.0

Have you ever seen any mousse

foundation with UV protection property? Difficult to see in the market, right?

SPF 25, PA ++ (5.0)

In vivo tested

@SUNJIN

Most chemical UV filters are not very silicone-

compatible. How to incorporate silicone-

incompatible UV filters into silicone phase?

You can incorporate Hybrid PMMA into silicone gel phase very easily by simple mixing

Benefit 2: Silicone incompatible UV filters into silicone gel phase


Benefit 3: Diminished skin irritancy

#1 #2 #3 #4 #5 #6 #7 #8 #9

Distilled Water 10.0 - - - - - - - -

Isohexadecane - 10.0 9.00 9.00 9.00 9.00 9.00 9.00 9.00

SUNPMMA-S - - 1.00 - - - 0.62 0.62 0.62

OMC - - - 1.00 - - 0.38 - 0.31

AvoBenzone - - - - 1.00 - - 0.38 0.07

Hybrid ABOMC - - - - - 1.00 - - -

Irritation Score 0 1 2 5 3 1 3 2 3

#11 #12 #13 #14 #15 #16 #7 #8 #9

Distilled Water 10.0

-

-

-

-

-

-

-

-

Alkyl Benzoate -

10.0

9.00

9.00

9.00

9.00

9.00

9.00

9.00

SUNPMMA-S -

-

1.00

-

-

-

0.62

0.62

0.62

OMC -

-

-

1.00

-

-

0.38

-

0.31

AvoBenzone -

-

-

-

1.00

-

-

0.38

0.07

Hybrid ABOMC -

-

-

-

-

1.00

-

-

-

Irritation Score 0 0 0 3 0 0 0 3 4

Sample size: 5 subjects(Korean) Study Design: Patch test Application time: 72hr Dosage: 25㎕

Dermal response: 0 = No evidence of irritation 1 = Minimal erythema, 2 = Readily visible erythema, 3 = Erythema and papules 4 = Definite edema 5 = Erythema, edema, and papules 6 = Vesicular eruption 7 = strong reaction spreading

“The 500-Da rule for skin penetration is:

1)virtually all common contact allergens are under 500-Da,

larger molecules are not known as contact sensitizers…they

can not penetrate and thus cannot act as allergens in man” Avobenzone Mw: 310.4

OMC Mw: 290

Octocrylene Mw: 361

Minimized Skin Irritation

Test Condition:

Test Results

The encapsulation of UV filters

inside PMMA bead reduces dermal

uptake, thereby reducing the

potential for irritation


Benefit 4: Photo-stability Test results & Theory

Blocked Blocked

Photodegradation of Avobenzone can be

blocked because nano sized Avobenzone

crystals are immobilized in solid PMMA

matrix

OMC/avobenzone combination is well known to

be not amenable to photostabilization unless

segregated by some means such as

encapsulation.

Vs.

Prisoner, not allowed to move

Avobenzone in Hybrid PMMA

Free man, free to move

Avobenzone in liquid formula

Test Results

Theoretical Explanation


No Ingredients # 1 # 2 # 3 # 4 # 5 # 6

Actives

PARSOL 1789 Internal oil phase

0.9 - 1.8 - 2.7 -

Hybrid AB External water phase

- 3 - 6 - 9

BMDBM NET (%) 0.9 3%*30%

= 0.9 1.8

6%*30% =1.8

2.7 9%*30%

2.7

PA Ratio 4.5

(++) 3.6 (+)

5.6 (++)

4.5 (++)

7.0 (++)

5.6 (++)

O/W sun cream formula

Only BMDBM & Hybrid AB incorporated

In vivo PA measured at SUNJIN

Hybrid PMMA has 80% efficacy of BMDBM

*1. To achieve PA++(PA4.5), PARSOL1789 0.9% was needed

*2. To achieve PA++(PA4.5), Hybrid AB 6% was needed

*3. in vivo Efficiency ratio between Hybrid AB and BMDBM was about 80%

3.6 / 4.5 = 80.0%

4.5 / 5.6 = 80.3%

5.6 / 7.0 = 80.0%

If I use Hybrid PMMA, how much PA do I get?

Questions Test Condition

Test Result

Efficiency Hybrid AB / BMDBM

*1 *2

*3

I know how BMDBM

works in my formula. Do

you have any

comparison data

between BMDBM &

Hybrid PMMA?

3.6

4.5

5.6

3% 6% 9%

3.6/3% =1.2

4.5/6% =0.75

5.6/9% =0.62

PA index

Hybrid AB

In vivo tested @SUNJIN


How to reach PA +++(8.0) by using Hybrid PMMA?

PA

2.0

4.0

6.0

8.0

Hybrid PMMA with ZnO-NAS From SUNJIN

Hybrid AB 6%

SUNZNO-NAS 12%

Hybrid AB 6% +

SUNZNO-NAS 12%

PA

2.0

4.0

6.0

8.0

Hybrid PMMA with Chemical UV Filters & ZnO

Hybrid AB 6%

BEMT 1%

Hybrid AB 6% +

BEMT 1% +

SUNZNO-NAS 6%

SUNZNO-NAS 6%

PA+++(>PA8.0) can be achieved by

using 6% Hybrid AB & 12%

SUNZNO-NAS together

Remember Hybrid PMMA could be

easily incorporated into water phase,

which is very useful when you make

O/W sun care(i.e. few water soluble

chemical filter available)

* BEMT : Bis-Ethylhexyloxyphenol

Methoxyphenyl Triazine 4.5

3.6

8.1

UV-A

Pro

tect

ion

UV-A

Pro

tect

ion

PA

2.0

4.0

6.0

8.0

Hybrid PMMA with Chemical UV Filters

Hybrid AB 6%

BEMT * 2%

Hybrid AB 6% +

BEMT * 2%

UV-A

Pro

tect

ion

4.5

3.6

8.1

4.5

1.8

1.8

8.1

I need PA+++

… How can I?

Questions

Net PA efficacy

• Hybrid AB = 0.75

• Zinc Oxide = 0.3

• BEMT = 1.8

PA+++ PA+++

PA+++

UVA protection Without ZnO


Hybrid Talc(DM) is MBBT coated Talc

Composition

MBBT 20 %

DIMETHICONE 10 %

TALC 70 %

Particle Size 11um

INCI : Talc / MBBT1) / Dimethicone

11um

(2) Because of Bulky chemical structure, MBBT is neither oil soluble nor water soluble Hybrid

Talc(DM) can make very stable O/W or W/O emulsion

50% of MBBT

(1) MBBT is a great UVA Filter

1) MBBT : Methylene Bis-benzotrizolyl Tetramethylbutylphenol

Hybrid Talc(DM)


No. Trade Name #1 #2

A

1 Hybrid Talc (DM) 15.0 25.0

2 SUNTITAN-LL 5.0 5.0

3 SH219-AS 2.0 2.0

4 Iron Oxides 1.3 1.3

B 7 Parsol MCX 6.0 6.0

8 Emollients 21.2 21.2

C 16 D.I-Water 34.5 39.5

In vivo SPF 30 35

In vivo PA 7.0(++) 8.0(+++)

Hybrid TALC(DM) for PA++ & PA+++

Without ZnO, 25% Hybrid Talc(DM) provides PA+++ 15% Hybrid Talc(DM) provides PA++

W/S Foundation In vivo tested @ SUNJIN

@15% of Talc(DM) In vivo PA7.0 = 7.0/15% = 0.46 PA/1%

@25% of Talc(DM) In vivo PA8.0 = 8.0/25% = 0.32 PA/1%


How to use Hybrid Talc(DM): PA+++ Pressed Powder

1) High SPF & PA Make-up

SJF-1118 ZnO Free Transparent Powdery Sun Pact-ver2.0

Phase Trade Name % INCI Name

A

SUNTALC-LL 26.25 Talc / Lauroyl Lysine

SUNMICA-LL 15.00 Mica / Lauroyl Lysine

SUNPMMA-X 3.00 Methyl Methacrylate Cross Polymer

Hybrid Talc(DM) 25.00 Talc / MBBT / Dimethicone

T-80LL 8.00 TiO2 / Silica / Lauroyl Lysine

SUNTITAN-LL 5.00 TiO2 / Lauroyl Lysine

FP-OMC 5.00 Methyl methacrylate Crosspolymer & Ethylhexyl Methoxy cinnamate

SUNSIL-TIN50 5.00 Silica / Titanium dioxide

SUNIOR-AS 0.04 Alkyl Silane coated Iron Oxide Red

SUNIOY-AS 0.09 Alkyl Silane coated Iron Oxide Yellow

SUNIOB-AS 0.02 Alkyl Silane coated Iron Oxide Black

B

Parsol MCX 5.00 Ethylhexyl Methoxy cinnamate

DC 200F/100cs 2.00 Dimethicone

Phenoxyethanol 0.50 Phenoxyethanol

Fragrance 0.10 Fragrance

In-vivo SPF 50

PA +++


2) Blemish Balm Cream

SJF-1117 ZnO Free BB Cream-ver1.0

Phase Trade Name % INCI Name

A

Hybrid Talc(DM) 25.0 Talc / MBBT / Dimethicone

SUNTITAN-LL 5.0 Titanium Dioxide / Lauroyl Lysine

SUNSIL-Tin50AS 2.0 Titanium Dioxide / Silica / Alkyl Silane

SUNIOY-AS 0.9 Alkyl Silane coated Iron Oxide Yellow

SUNIOR-AS 0.3 Alkyl Silane coated Iron Oxide Red

SUNIOB-AS 0.1 Alkyl Silane coated Iron Oxide Block

B

TEGOSOFT DEC 3.0 DiethylhexylCarbonate

Bentone 38 VCG 0.2 Quaternium-18 Hectorite

DC 345 5.0 Cyclomethicone

Parsol MCX 6.0 Ethylhexyl Methoxy cinnamate

ABIL EM 90 2.0 Cetyl PEG/PPG-10/1 Dimethicone

KSG 16 4.0 Dimethicone (and) Dimethicone / Vinyl Dimethicone Crosspolymer

CETIOL CC 2.0 Dicaprylyl Carbonate

SALACOS 99 2.0 Isononyl Isononanoate

KF 6017 3.0 PEG-10 Dimethicone

C

D.I-Water 31.0 Water

1,3-BG 7.0 Butylene Glycol

NaCl 1.0 Sodium Chloride

D Phenoxy Ethanol 0.3 Phenoxy Ethanol

Fragrance 0.2 Fragrance

In-vivo SPF 35

PA +++

How to use Hybrid Talc(DM): PA+++ BB Cream

Challenges in BB cream Normally BB cream formulation is made up of high portion of powders for coverage and silicone oils for light feel Often there may be not be enough polar emollients to solubilize BEMT or BMDBM So it would be difficult to achieve PA+++ without ZnO

=Porous PMMA + OMC


FP OMC is Porous PMMA containing OMC inside

Grade INCI Name & composition Avg. Particle

size(㎛) EFFECT & APPLICATION

FP - OMC Methyl methacrylate crosspolymer 60% Ethyl hexyl methoxycinnamate 40%

8 UV protecting High SPF sun care products

(1) Make-up with UV protection

Best recommend for

OMC is normally used as a binder when to make

UV protecting make-up.

But OMC is skin irritant, of no good sensorial feel

So rather than using OMC as a binder, better to

use FP-OMC FP-OMC = Porous PMMA + OMC

SJF-1008-Transparent Powdery

Sun Block-ver2.0

Phase Ingredients %

A

Magnesium Myristate 3.0

SUNMICA-LL 13.0

SUNSERI-LL 5.0

SUNTALC-LL 44.1

T-80LL 10.0

FP-OMC 4.0

SUNZnO-NCO 5.0

SNOWTITAN-LL 5.0

B

Parsol MCX 5.0

DC200f 100cs 5.5

Phenoxyl Ethanol 0.2

Fragrance 0.2

In vivo

SPF 50

PA +++

(2) Sun Protect GEL


SUN PROTECT GEL, by using FP-OMC

SJF-0905-SUN PROTECT GEL-ver1.0

No emulsifier

No emulsion Process used

So translucent

Applicable to

Skin care formula

Trade Name INCI Name %

A PARSOL EHS Ethylhexyl Salicylate 3.0

PARSOL MCX Ethylhexyl Methoxy cinnamate 3.6

B

FP-OMC (SUNJIN)

Methylmethacrylate Crosspolymer & Ethylhexyl Methoxy cinnamate

6.0

HYBRID ABOC (SUNJIN)

Polymethyl Methacrylate / Avo Benzone / Octocrylene 3.0

1,3-B.G. 1,3-Butylene Glycol 10.0

C

D.I. WATER Water 73.85

ARISTIFLEX AVC Ammonium Acryloyldimethyltaurate / VP Copolymer 0.4

D FRAGRANCE Fragrance 0.15

In vivo SPF 21.8, PA 5.0 (++) Sun Protect Gel

Super light,

Very translucent

Aristoflex AVC used to thicken water

phase

No shine,

No white casts,

No oiliness,

No stickiness, nothing!

Liquid Chemical Filter=

3.0%

+3.6%

+2.4%(6.0%*40%)

=9.0%

3% Hybrid

ABOC

provides

PA++


Surface treatment

Crystal size

(nm)

Surface area

(m2/g)

Remarks

Nano

SUNZNO-NAS

Alkyl Silane 40 19~23 AS coated ZnO, Counter type of product “Z”

SUNZNO-NCO

Hydrogen Dimethicone

35 21~28 The most compatible with Silicone Oils The lowest viscosity of ZnO dispersion

SUNZNO-AS

Alkyl Silane 80 10~15 Standard

Non

Nano

SUNZNO

none 150 n.a. Non-Nano, ECOCERT for O/W sun care

SUNZNO-SA

Stearic Acid 150 n.a. Non-Nano, ECOCERT for W/O sun care

Nano & Non-Nano Zinc Oxides, for UVA protection

Zinc Oxide meet so called

“1/3 rule” of EU

recommendation: Level of

UVA protection (measured by

in vivo or in vitro methods) at

least 1/3 of labelled SPF

Chemical Filter Free

Non Nano Sun Care

Mineral Sun Care

UVA Sun Care

Sensitive Skin Sun Care

X 100,000 SUNZNO-SA


Zinc Oxide is Safe & Transparent UVA filter

Zinc oxide is the closest thing to a

total "broad-spectrum" sunblock on

the market today.

It uniformly covers from 290 to 380 nm,

thus protecting against UVB and most of

the UVA spectrum.

No other sunscreen ingredient

provides broader protection.

(1) UVA protection (2) Minimized skin irritation

“Zinc oxide is a physical block that is not

absorbed, so it does not cause any allergic

reactions. This is especially important to

look for if you have sensitive skin or are

using sunscreens on a daily basis.”

And unlike many chemical sunscreen

agents, zinc oxide is never irritating. In fact,

it is recognized by the Food and Drug

Administration as a Category I skin

protectant, meaning that it is safe for

compromised or environmentally

challenged skin.

Zinc oxide has over a 300-year history of

safety, with no known adverse reactions

(which is why it is often used to treat

babies). Now, in its micro-fine form, it is

ideal for use in sunscreens and daily

moisturizers.

(3) Transparent formula

ZnO Only

Very Transparent

TiO2

Not Transparent

Benefits


FAQ about Zinc Oxide

Although ZnO would have lower SPF than TiO2

by themselves, ZnO shows greater SPF boost

when used together with OMC compared to TiO2

with OMC.

Zinc Oxide has higher SPF boost when used

together with OMC as compared to TiO2

SPF

5.0

10.0

15.0

20.0

25.0

30.0

SUNZNO -NAS 3%

OMC 5%

ZnO with OMC

6.5

SPF

6.5

22.5

5.0

10.0

15.0

20.0

25.0

30.0

OMC 5%

TiO2 with OMC

6.5

7.5

8.5

TiO2 3%

8.5 4.2

6.5

24.3

4.2

13.6 SPF Boost

6.5

NAS 3%

OMC 5%

+ OMC 5%

TiO2 3% +

A common caution in formulating a ZnO-containing product is to avoid or to minimize the use of anionic emulsifier or thickener such as

carbomers At pH values < 6, the solubility of zinc oxide increase and migration from the oil phase to water phase observed

For this reason, ZnO is usually incorporated into the oil phase of the formulation. Moreover these problems can be minimized or eliminated by

various means. Use of an optimized predispersion maintains the ZnO in a finely dispersed form in the oil phase. In W/O emulsions, such

dispersion techniques are sufficient to eliminate migration and efficacy of ZnO. ZnO can also be coated with hydrophobic materials in order to

reduce migration

A. Generally ZnO is considered

not stable in O/W formulation.

However, if zinc oxide is well

surface treated, almost there is

no problem.

Q1. SPF is the half of TiO2

Q2. Not stable in O/W formula

As SUNJIN chemical applies one step coating process for surface treated Zinc

Oxide, zinc oxides from SUNJIN are very price competitive. SUNJIN tries to match

the price level of Zinc Oxide comparable to the price of micro-fine TiO2

Q3. Price too expensive as compared to TiO2

Questions

A. Yes it is. But ZnO has great

synergy with OMC. Thus the SPF

of 3% ZnO and 5% OMC would

be comparable to the SPF of 3%

TiO2 and 5% OMC.


In vivo SPF & PA study of Zinc Oxide

SJF-1005-ZnO Only Sunscreen-

W/O-ver1.0

Ingredients %

A

D.I. Water 38.0

NaCl 0.5

1.3-BG 2.0

Glycerin 98% 3.0

Phenoxy ethanol 0.5

B

Salacos 99 6.0

Abil EM-90 3.0

KSG-16 3.0

C

KF-995 20.0

ISOLAN GI 34 1.0

Bentone 38 VCG 1.0

SUNZnO-NCO 20.0

SUNPMMA-COCO170 2.0

SPF30, PA6.0(++)

In vivo tested

@SUNJIN

SUNZNO-NCO 20% provides SPF 30

Unit SPF = 30/20% = 1.5 SPF/%

SUNZNO-NCO 20% provides PA 6.0

Unit SPF = 6.0/20% = 0.3 PA/%

Australian Formula - ZnO Only sun care


Overview

ZD60-AB SUNCLEAR -Z60CO

ZD60-BOS ECOCLEAR -Z50

Carrier Alkyl Benzoate D5 Butyl Octyl Salicylate


Net ZnO % 57% 57% 57% 47%

ZnO coating Hydrogen Dimethicone



Stearic Acid

Dispersing agent Polyhydroxy Stearic Acid

PEG-9 polydimethyl siloxyethyl

dimethicone

Polyhydroxy Stearic Acid

Polyglyceryl-2 Dipolyhydroxyst

earate & Polyglyceryl-3 Diisostearate

Non-Nano - - -

ECOCERT - - -


ECOCLEAR-Z50

Carrier Dicaprylyl Carbonate

Net ZnO % 47%

ZnO coating Stearic Acid

Dispersing agent

Polyglyceryl-2 Dipolyhydroxyst

earate & Polyglyceryl-3 Diisostearate

X 100,000

D10 : 426nm D50 : 775nm D90 : 1.728um

PSD of ECOCLEAR- Z50 shows no nano particle

SUNZnO-SA ZnO 95% Stearic Acid 5%

As NON NANO SUNZnO-SA USED,

ECOCLEAR-Z50 is ECOCERT approved ZnO dispersion


AB & BOS Dispersion

ZD60-AB ZD60-BOS

Carrier Alkyl Benzoate Butyl Octyl Salicylate

Net ZnO % 57% 57%

ZnO coating Hydrogen Dimethicone


Dispersing agent Polyhydroxy Stearic Acid

Polyhydroxy Stearic Acid

Ingredient

W/O tested

formula (%)

A

D.I. Water 55.0

NaCl 1.0

1.3-BG 5.0

B

ININ 10.0

KF-6017 4.0

ZD60-AB or

ZD60-BOS 25.0

Formula W/O Cream

ZD60-AB (%) 25 -

ZD60-BOS (%) - 25

In vivo SPF 21.7 25

Unit SPF/(%) = 21.7/25%

= 0.9 = 25/25%

= 1.0

In vivo PA 5.8 5.9

Unit PA/(%) = 5.8/25%

= 0.23 = 5.9/25%

= 0.23

Tested formula

Test Results


BUTYL OCTYL SALICYLATE Dispersion

BOS

OMC

Butyloctyl Salicylate is classified as Emollient from ICID(INCI) But, it UV protection efficacy like chemical UV Filter.

1) Transmittance

2) Transparency

BUTYLOCTYL SALICYLATE

Emollient

Guideline Formula


ECOCERT Sun Care

No Ingredients % INCI Name Supplier Origin

A

D.I. Water 44.0 Aqua - -

NaCl 1.0 Sodium chloride - -

Natural Extract

5.0 ECOCERT approved organic extract - Organic

B

Cetiol CC 8.0 Dicaprylyl Carbonate

COGNIS

Natural

Lameform TGI

2.0 Polyglyceryl-3 Diisostearate

Dehymuls PGPH

2.0 Polyglyceryl-2 Dipolyhydroxystearate

SFT85-CC 30.0 Titainum Dioxide, Silica, Jojoba Ester, Dicaprylyl Carbonate. Polyhydroxystearic Acid

SUNJIN

C SUNSIL-Tin50 5.0 Silica & Titanium dioxide

SUNZnO-SA 3.0 Zinc Oxide & Stearic Acid

In vivo SPF40, PA+++ SJF-0906-ECOCERT Sun Cream_SPF40-ver2.0


Phase Ingredients %

A

D.I. Water 29.0

NaCl 1.0

1.3 BG 5.0

B

Dehymuls PGPH 2.0

Lameform TGI 2.0

DC 200F-10cs 1.0

TD50-AB 25.0

C

Cetiol Sensoft 15.0

SUNSIL-Tin50 3.0

T-80JJ 5.0

SUNZnO-SA 10.0

SUNPMMA-COCO170 2.0

In vivo

SPF 50 PA ++

SJF-1002-Mineral Sunscreen-W/O-ver2.0

Mineral Sun Care: W/O Type

1. Chemical Filter Free

2. Nano TiO2 Allowed

3. Nano ZnO is not allowed but Non

nano ZnO OK

4. Silicone oil should be used less than

1%

5. No D5

6. Emulsifier with EO or PO not allowed


SJF-1005-ZnO Only Sunscreen-

W/O-ver1.0

Ingredients %

A

D.I. Water 38.0

NaCl 0.5

1.3-BG 2.0

Glycerin 98% 3.0

Phenoxy ethanol 0.5

B

Salacos 99 6.0

Abil EM-90 3.0

KSG-16 3.0

C

KF-995 20.0

ISOLAN GI 34 1.0

Bentone 38 VCG 1.0

SUNZnO-NCO 20.0

SUNPMMA-COCO170 2.0

SPF30, PA6.0(++)

In vivo tested

@SUNJIN

SUNZNO-NCO 20% provides SPF 30

Unit SPF = 30/20% = 1.5 SPF/%

SUNZNO-NCO 20% provides PA 6.0

Unit SPF = 6.0/20% = 0.3 PA/%

Australian Formula - ZnO Only sun care

ZnO Only Sun Care: W/O Type


SPF50, PA+++ W/S Type

In vivo SPF50, PA+++

SJF-1004-D5 Transparent

Shaking Sun Milk Lotion-W/S-ver1.3

Phase Ingredients %

A

D.I. Water 21.0

NaCl 0.4

1.3 BG 2.0

Phenoxy Ethanol 0.5

B

KF 995 20.6

Tegosoft DEC 2.0

PARSOL MCX 6.5

PARSOL EHS 4.0

PARSOL 340 1.0

KF-6028 2.0

Uvinul A PLUS 2.5

SilForm Flexible resin 4.5

C

TD50-AB 5.0

SUNCLEAR-Z60CO 19.0

SUNSIL-Tin50AS 2.0

SUNPMMA-COCO170 1.0

D Ethanol (98%) 6.0

1. Transparent & Light Texture

2. UVA protection by ZnO(12%) &

Chemical Filters

3. Cooling effect by using Ethanol

4. Low viscosity

5. Good water resistance

Formulation Tip 1. Too much strong film forming? Hard to remove by soap? Reduce SiliForm Flexible resin

2. You don’t want “shaking type’? Remove Ethanol

3. You want “Sun Cream” not Sun Lotion? Add Bentone 0.2 ~ 0.5%


SPF50 PA+++ O/W Type

Phase Ingredients %

A

D.I. Water 33.6

1% Carbomer 20.0

1.3 BG 3.0

Glycerin 1.5

DC2501 WAX 1.0

Phenoxy Ethanol 0.8

EDTA 2Na 0.2

B

D5 4.5

PARSOL MCX 6.5

PARSOL EHS 4.5

Tinosorb S 4.0

UVINUL T150 1.5

VEGE WAX 70 1.0

KALCOHL 6870 1.0

ARACEL 165 2.0

Tween 60 0.7

Tocopheryl acetate 0.3

C TEA 0.2

SEPIPLUS 400 0.5

D

SUNSIL-Tin50 5.0

Hybrid AB 3.0

Fragrance 0.2

E Ethanol (98%) 5.0

SJF-1112-D5 Extra Light texture Sun

Cream Homme-ver1.0

In vivo SPF 50,

PA +++

1. No micronized TiO2

2. No micronized ZnO

But SUNSIL-Tin50 used instead

Ultra Light Texture

Super Transparency

SUNSIL Tin50

Chemical UV Filters = 6.5%

+ 4.5% + 4.0% + 1.5%

+ 0.9%(3.0%*30%) = 18.4%

Mineral UV Filters = 5.0%*42% = 2.0%

W=19.9

SJF-1112-Extra Light texture Sun Cream Homme-O/W-ver1.0 -D5


SUN PROTECT GEL, by using FP-OMC

No emulsifier

No emulsion Process used

So translucent

Applicable to

Skin care formula

Trade Name INCI Name %

A PARSOL EHS Ethylhexyl Salicylate 3.0

PARSOL MCX Ethylhexyl Methoxy cinnamate 3.6

B

FP-OMC (SUNJIN)

Methylmethacrylate Crosspolymer & Ethylhexyl Methoxy cinnamate

6.0

HYBRID ABOC (SUNJIN)

Polymethyl Methacrylate / Avo Benzone / Octocrylene 3.0

1,3-B.G. 1,3-Butylene Glycol 10.0

C

D.I. WATER Water 73.85

ARISTIFLEX AVC Ammonium Acryloyldimethyltaurate / VP Copolymer 0.4

D FRAGRANCE Fragrance 0.15

In vivo SPF 21.8, PA 5.0 (++) Sun Protect Gel

Super light,

Very translucent

Aristoflex AVC used to thicken water

phase

No shine,

No white casts,

No oiliness,

No stickiness, nothing!

Liquid Chemical Filter=

3.0%

+3.6%

+2.4%(6.0%*40%)

=9.0%

3% Hybrid

ABOC

provides

PA++

SJF-0905-SUN PROTECT GEL-ver1.0


Phase Ingredients %

A

T-80AS 10.0

SUNTITAN-LL 3.0

SUNPMMA COCO170 2.0

SUNIOY-SA 0.9

SUNIOR-SA 0.35

SUNIOB-SA 0.1

B

TEGOSOFT DEC 3.0

Bentone 38 V CG 0.2

DC 345 5.0

Parsol MCX 6.0

Abil EM 90 2.0

KSG 16 4.0

CETIOL CC 2.0

SALACOS 99 2.0

KF6017 3.0

C

D.I. Water 47.95

1,3-BG 7.0

NaCl 1.0

D Phenoxy Ethanol 0.3

Fragrance 0.2

SJF-1117-ZnO Free BB Cream-ver2.0

In vivo SPF35, PA++

BB Cream, Non Nano & Zinc Oxide Free formula

What is BB Cream?

BB Cream is pretty

much the end all of

foundation,

concealer,

moisturizer, etc...

Korean formula -BB Cream

Phase Ingredients %

A

Hybrid Talc(DM) 25.0

SUNTITAN-LL 5.0

SUNSIL-Tin50AS 2.0

SUNIOY-AS 0.9

SUNIOR-AS 0.3

SUNIOB-AS 0.1

B

TESGSOFT DEC 3.0

Bentone 38 VCG 0.2

DC 345 5.0

Parsol MCX 6.0

ABIL EM 90 2.0

KSG 16 4.0

Cetiol CC 2.0

SALACOS 99 2.0

KF 6017 3.0

C

D.I-Water 31.0

1,3-BG 7.0

NaCl 1.0

D Phenoxy Ethanol 0.3

Fragrance 0.2

SJF-1104-Non nano BB Cream-ver2.0

In vivo SPF35, PA++


SJF-1008-Transparent Powdery Sun Block-ver2.0

Phase Ingredients %

A


SUNMICA-LL 13.0

SUNSERI-LL(P) 5.0

SUNTALC-LL 44.1

T-80LL 10.0

FP-OMC 4.0

SUNZnO-NCO 5.0

SNOWTITAN-LL 5.0

B

Parsol MCX 5.0

DC200 F100 5.5


Fragrance 0.2

In vivo

SPF 50 PA +++

Pressed Powder

Benefits of “powdery sun block”

1. Extremely transparent, you can put

sun protection without re-doing

make up

2. Powdery sun pact type

3. Powdery spread

4. Transparent


SJF-1105-Non nano Pressed powder-ver2.0

In vivo

SPF50, PA+++

Pressed Powder

Phase Ingredients %

A


SUNMICA-LL 13.0

SUNSERI-LL(p) 5.0

SUNTALC-LL 40.15

SUNSIL-Tin50 5.0

T-80AS 18.0

SUNTITAN-LL 5.0

SUNIOR-AS 0.6

SUNIOY-AS 1.2

SUNIOB-AS 0.05

B

Parsol MCX 6.0

DC200 F100 2.6


Perfume 0.2

1. Non Nano

2. High SPF & PA

3. Meet PA +++ without Zinc Oxide

Phase Trade Name %

A

SUNTALC-LL 26.25

SUNMICA-LL 15.00

SUNPMMA-X 3.00

Hybrid Talc(DM) 25.00

T-80LL 8.00

SUNTITAN-LL 5.00

FP-OMC 5.00

SUNSIL-TIN50 5.00

SUNIOR-AS 0.04

SUNIOY-AS 0.09

SUNIOB-AS 0.02

B

Parsol MCX 5.00

DC 200F/100cs 2.00

Phenoxyethanol 0.50

Fragrance 0.10

SJF-1118-ZnO Free Transparent Powdery Sun Pact-ver2.0

In vivo

SPF50, PA+++


Memo

The information given in this publication is based on our current knowledge and experience, and may be used at your discretion and risk. We do not assume any liability in connection with your product or its use

ASIA & Pacific China

TIANJIN XIANGUANG CHEMICAL

Jinyu Road, Xiditou Beichen District,

Tianjin

Tel : +86-22-8684-5637

E-mail : [email protected]

Mobile: +86-1370-213-6240

Contact : Sheng-Fan Piao

Japan/ LINDEN CO.,LTD.

A202, 3-6-3Watado, Fujimi-Shi, Saitama

TEL : (+81)049-255-5670


Contact : Kazuyuki Miyadera

Australia / New Zealand

RPL Trading.

159-161 Allingham Street, Golden Square,

VIC 3555, Australia

Tel : +61-3-9375-4100


Contact : Russell McNab

Thailand/ GOWELL CO. LTD

8/9 Moo 7, Bangna - Trad Road KM.9,

Bangkaew, Bangplee, Samutprakarn

10540, Thailand

TEL : +66-2-315-9189


Contact : Nutthamol Rattanachaiyaphong

Taiwan/ WWRC

5F-A, No. 30, Chung Cheng 2nd Road,

Kaohsiung 802, Taiwan, R.O.C.

Tel : +886-7-223-9188

Email : [email protected]

Contact : Tommy Hu

EUROPE France / IMPAG France SAS

6, Boulevard du 21eme Regiment

d'Aviation 54000 NANCY France

Tel : +33 (0)3 83 48 98 05


Contact : Dominique Cormary

Germany/ IMPAG GmbH

Fritz-Remy-str.25,63071 offenbach

Tel: +49-69-8500-0830

Fax: +49-69-8500-0880

E-mail: [email protected]

Contact : Karin Flach-Zierer

Switzerland/ IMPAG AG

Feldeggstrasse 26, Postfach, CH-8008

Zü rich

TEL: +41 43 499 25 20


Contact: Peter Alder

AMERICA USA & Canada

KOBO PRODUCTS, INC.

690 Montrose Ave. - South Plainfield,

NJ 07080

Tel : +1-908-757-0033(Ext.6152)

[email protected]

Contact : Barbara Scott

SUNJIN AMERICA INC.

2125 Center Ave. (Suite 502) Fort Lee,

NJ 07024

Tel : +1-201-585-2801

Mobile : 201-936-3860


Contact : Phil Lee

Malaysia/ DCM Personal Care

Address : No. 5, Jalan U1/21 Seksyen

U1, Hicom-Glenmarie Industrial park ,

40150 . Shah Alam, SelangorDarul

Ehsan. Malaysia .

Tel : +603-7804 9606

[email protected]

Contact : Kok Leong, KHOO

Indonesia/ PT. MEGASETIA AGUNG

KIMIA

JI. Paradise Timur Raya F21/58,

Sunter Agung Podomoro, Jakarta

14350

Tel : +62-21-645-1037

[email protected]

Contact : Abagail

Global Distributors’ List

Italy/ Caldic Italia Srl

Via Saronnino, 5 21040 Origgio (VARESE)

Italy

Tel : +39 (02) 96390216


Contact : Marcello Baggi

UK/ ASTON CHEMICALS

1 Aylesbury Industrial Center

Bicester Road, Aylesbury, HP19 8AL

Tel: +44 (0) 1296 678224


Contact: Louis Moulin

Poland/ ASTON CHEMICALS

Oddział w Polsce, ul. Mińska 63 03-

828 Warszawa

Tel. +48 22 33-08-450


Contact: Mariusz Siwiński

Spain & Portugal / C.E.S.T.I.S.A.

Bailen 43 pral, 08010 Barcelona

Tel : +34-93-265-2264


Contact : Laura Mas

Turkey/ HD ULUSLARARASI TIC. VE

AMBALAJ SAN. LTD.STI.

Dilovasi Organize Sanayi Bolgesi 5.Kisim

D-5007 Sokak No:2 Ofis No: 11 (Jokey

Plastik Fabrikasi ici) TR-41455 Dilovasi-

Kocaeli Turkey

Tel : +90 262 754 01 62


Contact : Oktay OZTURK

MIDDLE EAST Jordan & Syria

RIMA AL.SHURAFA & PARTENERS

149 Amman 11118 Jordan

8th Circle, Al.Bayader, Randa Complex

Building, 2nd Floor, Office, 206

Tel: 009625829876

Mobile: 00962796559025


Contact : Firas Shurafa

mailto:[email protected]












http://www.sunjinchem.com/mailto@[email protected]








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10 Edition SUNJIN Catalog1 SUN CARE - in-cosmetics

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