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1 2.3 Measured Numbers and Significant Figures Chapter 2 Measurements Basic Chemistry Copyright © 2011 Pearson Education, Inc.
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2.3

Measured Numbers and Significant Figures

Chapter 2 Measurements

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Measured Numbers

A measuring tool • is used to determine a quantity such as the

length or the mass of an object• provides numbers for a measurement called

measured numbers

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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. l2. . . . l . . . . l3 . . . . l . . . . l4. . cm

• The markings on the meterstick at the end of the orange line are read as

The first digit 2 plus the second digit 2.7

• The last digit is obtained by estimating. • The end of the line might be estimated between

2.7–2.8 as half-way (0.05) or a little more (0.06), which gives a reported length of 2.75 cm or 2.76 cm.

Reading a Meterstick

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Known + Estimated Digits

In the length reported as 2.76 cm,

• the digits 2 and 7 are certain (known)

• the final digit 6 was estimated (uncertain)

• all three digits (2.76) are significant including the estimated digit

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Learning Check

. l8. . . . l . . . . l9. . . . l . . . . l10. . cm

What is the length of the red line?

1) 9.0 cm

2) 9.03 cm

3) 9.04 cm

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Solution

. l8. . . . l . . . . l9. . . . l . . . . l10. . cm

The length of the red line could be reported as

2) 9.03 cm

or 3) 9.04 cm

The estimated digit may be slightly different.

Both readings are acceptable.

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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. l3. . . . l . . . . l4. . . . l . . . . l5. . cm

• For this measurement, the first and second known digits are 4.5.

• Because the line ends on a mark, the estimated digit in the hundredths place is 0.

• This measurement is reported as 4.50 cm.

Zero as a Measured Number

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Significant Figuresin Measured Numbers• Significant figures obtained from a

measurement include all of the known digits plus the estimated digit.

• The number of significant figures reported in a measurement depends on the measuring tool.

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Significant Figures

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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All nonzero numbers in a measured number are significant.

Measurement Number of Significant Figures

38.15 cm 4

5.6 ft 2

65.6 lb 3

122.55 m 5

Counting Significant Figures

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Sandwiched zeros• occur between nonzero numbers• are significant

Measurement Number of Significant Figures

50.8 mm 32001 min 40.0702 lb 30.40505 m 5

Sandwiched Zeros

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Trailing zeros

• follow nonzero numbers in numbers without decimal points

• are placeholders

• are not significant

Measurement Number of Significant Figures

25 000 cm 2 200 kg 1 48 600 mL 3

25 005 000 g 5

Trailing Zeros

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Leading zeros • precede nonzero digits in a decimal number• are placeholders• are not significant

Measurement Number of Significant Figures

0.008 mm 10.0156 oz 30.0042 lb 20.000262 mL 3

Leading Zeros

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Significant Figures in Scientific Notation

In scientific notation• all digits including zeros in the coefficient are

significant

Scientific Notation Number of

Significant Figures

8 x 104 m 1

8.0 x 104 m 2

8.00 x 104 m 3

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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State the number of significant figures in each

of the following measurements:

A. 0.030 m

B. 4.050 L

C. 0.0008 g

D. 2.80 m

Learning Check

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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State the number of significant figures in each of the

following measurements:

A. 0.030 m 2

B. 4.050 L 4

C. 0.0008 g 1

D. 2.80 m 3

Solution

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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A. Which answer(s) contain three significant figures? 1) 0.4760 2) 0.00476 3) 4.76 x 103

B. All the zeros are significant in

1) 0.00307 2) 25.300 3) 2.050 x 103

C. The number of significant figures in 5.80 x 102 is

1) one 3) two 3) three

Learning Check

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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A. Which answer(s) contain three significant figures?

2) 0.00476 3) 4.76 x 103

B. All the zeros are significant in

2) 25.300 3) 2.050 x 103

C. The number of significant figures in 5.80 x 102

is

3) three

Solution

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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In which set(s) do both numbers contain the

same number of significant figures?

1) 22.0 and 22.00

2) 400.0 and 4.00 x 102

3) 0.000015 and 150 000

Learning Check

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Solution

In which set(s) do both numbers contain the

same number of significant figures?

3) 0.000015 and 150 000

Both numbers contain two (2) significant

figures.

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Exact Numbers

An exact number is obtained • when objects are counted

Example: counting objects2 baseballs4 pizzas

• from numbers in a defined relationshipExample: defined relationships

1 foot = 12 inches1 meter = 100 cm

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Examples of Exact Numbers

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Learning Check

A. Exact numbers are obtained by 1. using a measuring tool

2. counting 3. definition

B. Measured numbers are obtained by 1. using a measuring tool

2. counting 3. definition

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Solution

A. Exact numbers are obtained by

2. counting

3. definition

B. Measured numbers are obtained by

1. using a measuring tool

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Learning Check

Classify each of the following as exact (E) or measured numbers (M). Explain your answer.

A.__Gold melts at 1064 °C.

B.__1 yd = 3 ft

C.__The diameter of a red blood cell is 6 x 104 cm.

D.__There are 6 hats on the shelf.

E.__A can of soda contains 355 mL of soda.

Basic Chemistry Copyright © 2011 Pearson Education, Inc.

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Classify each of the following as exact (E) or

measured numbers (M).

A. M A measuring tool is required.

B. E This is a defined relationship.

C. M A measuring tool is used to determine

length.

D. E The number of hats is obtained by counting.

E. M The volume of soda is measured.

Solution

Basic Chemistry Copyright © 2011 Pearson Education, Inc.


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