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Ashland, Technical Data Sheet - addresins.com · during process upsets or during shipping and...

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DERAKANE 411-350 WSR Series epoxy vinyl ester resins are based on bisphenol-A epoxy resin. DERAKANE 411 Series epoxy vinyl ester resins have become the "industry standard" due to their wide range of end-use applications and ability to be used in a wide range of fabrication techniques. The raw materials used in the manufacture of these resins are listed as acceptable in FDA regulation Title 21 CFR 177.2420 for repeated use in contact with food, subject to user's compliance with the prescribed limitations of that regulation. DERAKANE 411-350 WSR and WSR-20 resins are recognized registered components in a coating system Certified by NSF (1) to ANSI/NSF Standard 61, Drinking Water System Components. DERAKANE 411-350 WSR resin may be cured using cobalt/MEKP or BPO/DMA where cobalt free systems are required - e.g. bleach service within the limits prescribed by Ashland's technical service team. Equipment fabricated with DERAKANE 411-350 WSR Series resins exhibit superior elongation, toughness and impact resistance. This physical resilience offers greater resistance to cracking due to thermal cycling, pressure fluctuations and mechanical shocks providing a safety factor against damage during process upsets or during shipping and installation. Composites fabricated with DERAKANE 411-350 WSR Series resins provide resistance to a wide range of acids, alkalis, bleaches and solvents. These resins hold up well in corrosive environments, postponing the need for replacements. Equipment fabricated with DERAKANE 411-350 WSR Series resins tolerate heavy design loads without causing failure due to resin damage. This facilitates working with large weight-bearing equipment with confidence. (1)National Sanitation Foundation, NSF International (nsf.org) APPLICATIONS AND USE -DERAKANE 411-350 WSR Series resins are designed for use in fabricating FRP storage tanks, vessels, pipes, ducts and on-site maintenance projects, paticularly in chemical processing and pulp and paper operations. - The resins are designed for ease of fabrication using hand lay-up, spray-up, filament winding, compression molding and resin transfer molding techniques, pultrusion and molded grating applications. - Recommendations for specific services and environments can be provided by contacting us at [email protected]. DERAKANE 411-350 WSR RESIN COATING SYSTEM FOR POTABLE WATER Requirements for use of DERAKANE 411-350 WSR or WSR-20 resins in a coating system Certified by NSF to ANSI/NSF Standard 61, Drinking Water System Components DERAKANE 411-350 WSR and WSR-20 resins are recommended as coating systems in potable water tanks >/= 150 gallons and piping >/= 16" diameter at ambient temperature. In potable water applications, the following are required of the coating system. Additional, non-specified Technical Datasheet Ashland Performance Materials Ashland is committed to the continuous evolution of technology and service solutions that promote health, safety and environmental protection around the world. * Registered service mark of the American Chemistry Council. ® Registered trademark and ™ trademark of Ashland Inc. Document 6849 V3 F2, Language EN V1, Approved 2016-9-20, © 2016 Ashland Inc. Page 1 (6) DERAKANE™ 411-350 WSR Series Epoxy Vinyl Ester Resins
Transcript
Page 1: Ashland, Technical Data Sheet - addresins.com · during process upsets or during shipping and installation. Composites fabricated with DERAKANE ... compression molding and resin transfer

DERAKANE 411-350 WSR Series epoxy vinyl ester resins are based on bisphenol-A epoxy resin.DERAKANE 411 Series epoxy vinyl ester resins have become the "industry standard" due to their widerange of end-use applications and ability to be used in a wide range of fabrication techniques. The rawmaterials used in the manufacture of these resins are listed as acceptable in FDA regulation Title 21 CFR177.2420 for repeated use in contact with food, subject to user's compliance with the prescribedlimitations of that regulation. DERAKANE 411-350 WSR and WSR-20 resins are recognized registeredcomponents in a coating system Certified by NSF(1) to ANSI/NSF Standard 61, Drinking Water SystemComponents. DERAKANE 411-350 WSR resin may be cured using cobalt/MEKP or BPO/DMA wherecobalt free systems are required - e.g. bleach service within the limits prescribed by Ashland's technicalservice team.

Equipment fabricated with DERAKANE 411-350 WSR Series resins exhibit superior elongation,toughness and impact resistance. This physical resilience offers greater resistance to cracking due tothermal cycling, pressure fluctuations and mechanical shocks providing a safety factor against damageduring process upsets or during shipping and installation. Composites fabricated with DERAKANE411-350 WSR Series resins provide resistance to a wide range of acids, alkalis, bleaches and solvents.These resins hold up well in corrosive environments, postponing the need for replacements. Equipmentfabricated with DERAKANE 411-350 WSR Series resins tolerate heavy design loads without causingfailure due to resin damage. This facilitates working with large weight-bearing equipment with confidence.

(1)National Sanitation Foundation, NSF International (nsf.org)

APPLICATIONS ANDUSE

-DERAKANE 411-350 WSR Series resins are designed for use in fabricating FRP storage tanks, vessels,pipes, ducts and on-site maintenance projects, paticularly in chemical processing and pulp and paperoperations.

- The resins are designed for ease of fabrication using hand lay-up, spray-up, filament winding,compression molding and resin transfer molding techniques, pultrusion and molded grating applications.

- Recommendations for specific services and environments can be provided by contacting us [email protected].

DERAKANE 411-350WSR RESIN COATINGSYSTEM FORPOTABLE WATER

Requirements for use of DERAKANE 411-350 WSR or WSR-20 resins in a coating system Certified byNSF to ANSI/NSF Standard 61, Drinking Water System Components

DERAKANE 411-350 WSR and WSR-20 resins are recommended as coating systems in potable watertanks >/= 150 gallons and piping >/= 16" diameter at ambient temperature.

In potable water applications, the following are required of the coating system. Additional, non-specified

Technical DatasheetAshland Performance Materials

Ashland is committed to the continuous evolution of technology and service solutions that promote health, safety and environmental protection around the world.* Registered service mark of the American Chemistry Council. ® Registered trademark and ™ trademark of Ashland Inc.

Document 6849 V3 F2, Language EN V1, Approved 2016-9-20, © 2016 Ashland Inc. Page 1 (6)

DERAKANE™ 411-350 WSR Series Epoxy Vinyl Ester Resins

Page 2: Ashland, Technical Data Sheet - addresins.com · during process upsets or during shipping and installation. Composites fabricated with DERAKANE ... compression molding and resin transfer

chemical components or designated components that are utilized outside the percentage limitationsspecified below constitute non-compliance with the NSF certified DERAKANE 411-350 WSR or WSR-20resin coating systems. Strict adherence to components and percentages is required.

NSF Registered Recipe Components Supplier/Manufacturer DERAKANE411-350 WSRResin MEKP

CureFormulation

DERAKANE411-350

WSR-20 ResinMEKP CureFormulation

DERAKANE411-350 WSRResin BPOCureFormulation

DERAKANE 411-350 WSR Resin Ashland Inc. 96.5-98.9% 0% 93.0 - 98.9%DERAKANE 411-350 WSR-20 Resin Ashland Inc. 0% 96.5-98.9% 0%6% Cobalt Naphthenate OMG Americas Inc.,

LV Lomas Limited,Dura ChemicalsInc., GMZ, Walsh &Associates orBrenntag

0.1-0.5% 0% 0%

Dimethylaniline (DMA) Aceto Corp., NexeoSolutions, Univar,Cellmark ShanghaiCo., Lted., PuritanProducts, KesslerChemical or Charkit

0.01-0.04% 0% 0.05-0.5%

tertiary butyl catechol (tBC-85) Puritan, Rhodia Inc.,Nexeo Solutions,DIC International,ChemPoint.com,Charkit ChemicalCorp., ECEM,Bonderalia MontoilSA, Akzo Nobel

0% 0% 0.0 - 0.1%

Methyl ethyl ketone peroxide MEKP 925(4) 1-3% 1-3% 0%

Technical DatasheetAshland Performance Materials

Ashland is committed to the continuous evolution of technology and service solutions that promote health, safety and environmental protection around the world.* Registered service mark of the American Chemistry Council. ® Registered trademark and ™ trademark of Ashland Inc.

Document 6849 V3 F2, Language EN V1, Approved 2016-9-20, © 2016 Ashland Inc. Page 2 (6)

DERAKANE™ 411-350 WSR Series Epoxy Vinyl Ester Resins

Page 3: Ashland, Technical Data Sheet - addresins.com · during process upsets or during shipping and installation. Composites fabricated with DERAKANE ... compression molding and resin transfer

Benzoyl Peroxide Paste 38 - 62%Active (BPO)

Luperox AFR40(5),Benox L40LV(4) orCadox 40E(6)

0% 0% 2.5 - 6.0%

Fiberglass C-veil or NEXUS(2) veil Owens Corning(C-veil), PrecisionFiberglass (NEXUS)

1-2 plies(minimum

veil thickness= 10 mils)

same same

OptionalComponents

Supplier/Manufacturer Percentage Percentage Percentage

5-50% Paraffinwax / styrenesolution, for topcoating of airinhibited areas

Wax: Ashland ENGWS-0010; Styrene:Shell Chemical Co.,Nexeo Solutions,PolyOne, M HollandCo., LyondellChemical Co.,Univar, Brenntag,Ineos Styrolution

0-0.4% wax +styrene

0-0.4% wax +styrene

0-0.4% wax +styrene

Amorphousfumed silica fortop coating(3)

Cab-O-Sil(7) TS-720 0-2% 0-2% 0-2%

(2) Registered trademark of Precision Fiberglass(3) Fumed silica is frequently unacceptable for corrosion service. Consult Ashland([email protected]) to confirm if fumed silica is acceptable for your service.(4) Registered trademark of United Initiators. NOROX (ME)KP-925,(ME) used in NA name, but notelsewhere. NOROX (ME)KP-925 or equivalent low hydrogen peroxide content MEKP. Use of other MEKPcatalysts or additives may result in different geltimes.(5) Registered trademark of Arkema(6) Registered trademark of Akzo Nobel(7) Registered trademark of Cabot Corporation

Technical DatasheetAshland Performance Materials

Ashland is committed to the continuous evolution of technology and service solutions that promote health, safety and environmental protection around the world.* Registered service mark of the American Chemistry Council. ® Registered trademark and ™ trademark of Ashland Inc.

Document 6849 V3 F2, Language EN V1, Approved 2016-9-20, © 2016 Ashland Inc. Page 3 (6)

DERAKANE™ 411-350 WSR Series Epoxy Vinyl Ester Resins

Page 4: Ashland, Technical Data Sheet - addresins.com · during process upsets or during shipping and installation. Composites fabricated with DERAKANE ... compression molding and resin transfer

ProcessCureTime

2-100 hours at ambient temperature

Postcure

4 hours at 180°F

Wash /Rinse

Following post cure, the equipment must be washed thoroughly with a non-ionic detergentsolution and rinsed thoroughly with potable water.

The DERAKANE 411-350 WSR resin Coating System is Certified by NSF International to therequirements of NSF/ANSI Standard 61: Drinking Water System Components-Health Effects. Thiscertification is non-transferable. Certain jurisdictions may require certain end products to be coated withan NSF Certified coating system, while other jurisdictions may require certain end products to be Certifiedto NSF 61. If you would like information regarding NSF Certification, please contact NSF International [email protected]; www.nsf.org; or at 1-800-NSF-MARK.

TYPICAL LIQUIDRESIN PROPERTIES

Property(8) at 25°C (77°F) Value UnitDynamic Viscosity 340 mPas (cps)Kinematic Viscosity 330 cStStyrene Content 45 %Density 1.03 g/ml

(8) Properties are typical values, based on material tested in our laboratories, but varies from sample tosample. Typical values should not be construed as a guaranteed analysis of any specific lot or asspecification items.

MEKP Cure System Typical geltimes(9) using NOROX(ME)KP-925(4) catalyst (MEKP) and Cobalt Naphthenate-6%(10)

(Co-nap6%)and Dimethylaniline (DMA)

Target Gel Times 20 minutes 20 Minutes 40 minutesDERAKANE 411-350 WSR-20 RESIN 100DERAKANE 411-350 WSR RESIN 100 1006% Cobalt Naphthenate 0.25 0.13Dimethyl analine 0.015 0.01MEKP-925 1.25 1.25 1.0

Technical DatasheetAshland Performance Materials

Ashland is committed to the continuous evolution of technology and service solutions that promote health, safety and environmental protection around the world.* Registered service mark of the American Chemistry Council. ® Registered trademark and ™ trademark of Ashland Inc.

Document 6849 V3 F2, Language EN V1, Approved 2016-9-20, © 2016 Ashland Inc. Page 4 (6)

DERAKANE™ 411-350 WSR Series Epoxy Vinyl Ester Resins

Page 5: Ashland, Technical Data Sheet - addresins.com · during process upsets or during shipping and installation. Composites fabricated with DERAKANE ... compression molding and resin transfer

(9) Thoroughly test any other materials in your applications before full-scale use. Geltimes may vary dueto the reactive nature of these materials. Always test a small quantity before formulating large quantities.(4) Registered trademark of United Initiators. NOROX (ME)KP-925,(ME) used in NA name, but notelsewhere. NOROX (ME)KP-925 or equivalent low hydrogen peroxide content MEKP. Use of other MEKPcatalysts or additives may result in different geltimes.(10) Use of cobalt octoate, especially in combination with 2,4-Pentanedione can result in 20-30% slowergeltimes.

BPO Cure System Target Gel Times 20 minutes 40 minutes 60 minutesDERAKANE 411-350 WSR RESIN 100 100 100Dimethyl analine 0.16 0.10 0.06BPO - 40% Active 2.5 2.5 2.5

Typical(8) MechanicalProperties

The properties in the table below are measured from a postcured(11) clear resin casting.

Property Value (SI) Value (US) MethodTensile Strength 83 MPa 12000 psi ASTM D638Tensile Modulus 3000 MPa 440 kpsi ASTM D638Tensile Elongation 5% 5% ASTM D638Flexural Strength 140 MPa 20100 psi ASTM D790Flexural Modulus 3300 MPa 480 kpsi ASTM D790Heat Distortion Temperature(12) 100 °C 212 °F ASTM D648

(11) Cure schedule: 24 hours at room temperature and 2 hours at 120°C (250 °F).(12) Maximum stress: 1.8 MPa (264 psi)

CERTIFICATES ANDAPPROVALS

The manufacturing, quality control and distribution of products, by Ashland Performance Materials,comply with one or more of the following programs or standards: Responsible Care, ISO 9001, ISO 14001and OHSAS 18001.

HANDLING ANDSTORAGE

Standard Package: 55-Gallon (208 liter) Drum, Non-Returnable, Net Wt. 205 kgs (452 Lbs.)Dot Label Required: Flammable Liquid

Technical DatasheetAshland Performance Materials

Ashland is committed to the continuous evolution of technology and service solutions that promote health, safety and environmental protection around the world.* Registered service mark of the American Chemistry Council. ® Registered trademark and ™ trademark of Ashland Inc.

Document 6849 V3 F2, Language EN V1, Approved 2016-9-20, © 2016 Ashland Inc. Page 5 (6)

DERAKANE™ 411-350 WSR Series Epoxy Vinyl Ester Resins

Page 6: Ashland, Technical Data Sheet - addresins.com · during process upsets or during shipping and installation. Composites fabricated with DERAKANE ... compression molding and resin transfer

Drums - It is highly recommended that all material is stored at stable temperatures below 25°C (77 °F).Avoid exposure to heat sources such as direct sunlight or steam pipes. To avoid contamination of productwith water, do not store outdoors. Keep sealed to prevent moisture pick-up and monomer loss. Rotatestock.

Bulk - See Ashland's Bulk Storage and Handling Manual for Polyesters and Vinyl Esters. A copy of thismay be obtained from Ashland at +1.614.790.3333 or 800.523.6963.

When stored in accordance with the above conditions, Ashland warrants the unpromoted version of thisproduct to remain within specifications for six (6) months from date of manufacture and the pre-promoted(WSR-20) version of this product to remain within specifications for three (3) months from the date ofmanufacture. All things being equal, higher storage temperature will reduce product stability and lowerstorage temperature will extend product stability.

Notice All information presented herein is believed to be accurate and reliable, and is solely for the user'sconsideration, investigation and verification. The information is not to be taken as an express or impliedrepresentation or warranty for which Ashland assumes legal responsibility. Any warranties, includingwarranties of merchantability, fitness for use or non-infringement of intellectual property rights of thirdparties, are herewith expressly excluded.

Since the user's product formulations, specific use applications and conditions of use are beyond thecontrol of Ashland, Ashland makes no warranty or representation regarding the results which may beobtained by the user. It shall be the sole responsibility of the user to determine the suitability of any of theproducts mentioned for the user's specific application.

Ashland requests that the user reads, understands and complies with the information contained hereinand the current Material Safety Data Sheet.

More information Ashland Performance MaterialsAmericas Headquarters5200 Blazer ParkwayDublin, OH 43017 OhioUSAPhone: +1 800 523 [email protected]

Technical DatasheetAshland Performance Materials

Ashland is committed to the continuous evolution of technology and service solutions that promote health, safety and environmental protection around the world.* Registered service mark of the American Chemistry Council. ® Registered trademark and ™ trademark of Ashland Inc.

Document 6849 V3 F2, Language EN V1, Approved 2016-9-20, © 2016 Ashland Inc. Page 6 (6)

DERAKANE™ 411-350 WSR Series Epoxy Vinyl Ester Resins


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