Challenges & opportunities for sustainable aviation Technical, economic and ecologic fuel evaluation from aviation point of view
Sandra Adelung, Friedemann Albrecht, Ralph-Uwe Dietrich, Felix Habermeyer, Stefan Estelmann, Simon Maier, Moritz Raab (DLR e.V., www.DLR.de/tt)
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
Outlook
Renewable jet fuel production routes
Techno-economic and ecological assessment at DLR
Technology development activities & need
Motivation
Agenda
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 2
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Motivation
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 3
Source: https://www.co2.earth/daily-co2?noaa-mauna-loa-co2-data.html
Kyoto Protocol adopted on 1997
UNFCCC Paris Agreement adopted on 2015
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Motivation
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 4
Brussels Paris
London Washington, DC
Sydney
Davos
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
1
2
3
Forecasted CO2 emissions without reduction measures
Improvement of technologies, operations and airport infrastructure
CO2-certificates and other economic measures (CORSIA[2] 2016)
Radical technology transitions and alternative fuels
CO
2 e
mis
sio
ns
Planned Measures:
No action
2010 2020 2030 2040 2050
3
Technology
1 2
Operations
Infrastructure
European aviation kerosene demand in 2010: ca. 56.5 Mt[3]
-50 % CO2
by 2050
Main goals:
Improvement of fuel
efficiency about
1.5 % p.a. until 2020
Carbon-neutral
growth from 2020
50 % CO2 emissions
reductions by 2050
Aviation Industry Response: IATA Technology Roadmap [1]
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 5
[1] iata.org, IATA Technology Roadmap 4. Edition, June 2013
[2] ICAO-Resolution A39-3: Carbon Offsetting and Reduction Scheme for International Aviation
[3] FuelsEurope “Statistical Report“ 2010
… equals renewable kerosene demand in 2050?
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Certified alternative jet fuels (ASTM D7566 – 14c [1])
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 6
Feedstock Synthesis technology Fuel
Coal, natural gas, biomass, CO2 & H2 Fischer-Tropsch (FT) synthesis Synthetic paraffinic kerosene
Lipids from Biomass (e.g. algae, soya, jatropha) Hydroprocessed esters and fatty acids (HEFA) Synthetic paraffinic kerosene
Sugar from Biomass Direct Sugars to Hydrocarbons (DSHC) Synthetic iso-paraffins /
Farnesane
Bioethanol (-propanol, -butanol) dehydration+oligomerization+hydration
(Alcohol-to-Jet, AtJ)
AD-SPK
[1] ASTM International, „ASTM D7566 - 14C: Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons“, 2015
[2] Eurostat 2019, Crop production in EU standard humidity by NUTS 2 regions
[3] Fachagentur Nachwachsende Rohstoffe, „Steckbrief Ethanol-Kraftstoff”, 2016
[4] NREL, „Review of Biojet Fuel Conversion Technologies”, Golden, 2016
European AtJ? – feedstock example wheat:
Wheat cultivated area2017[2]: 25.9 mio. ha Ethanol per area: 2.2 t/ha[3]
Conversion to fuel [4]: 0.56 tKerosene/tEthanol
European kerosene production based on wheat: 31.9 Mt/a (≈ 56 % of demand)
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Certified alternative jet fuels (ASTM D7566 – 14c [1])
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 7
Feedstock Synthesis technology Fuel
Coal, natural gas, biomass, CO2 & H2 Fischer-Tropsch (FT) synthesis Synthetic paraffinic kerosene
Lipids from Biomass (e.g. algae, soya, jatropha) Hydroprocessed esters and fatty acids (HEFA) Synthetic paraffinic kerosene
Sugar from Biomass Direct Sugars to Hydrocarbons (DSHC) Synthetic iso-paraffins /
Farnesane
Bioethanol (-propanol, -butanol) dehydration+oligomerization+hydration
(Alcohol-to-Jet, AtJ)
AD-SPK
[1] ASTM International, „ASTM D7566 - 14C: Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons“, 2015
[2] Eurostat 2019, Crop production in EU standard humidity by NUTS 2 regions
[3] Fachagentur Nachwachsende Rohstoffe, „Steckbrief Ethanol-Kraftstoff”, 2016
[4] NREL, „Review of Biojet Fuel Conversion Technologies”, Golden, 2016
European DSHC? – feedstock example sugar beet:
Sugar beet cultivated area2017[2]: 1.8 mio. ha Sugar per area: 11.6 t/ha[3]
Conversion to fuel [4]: 0. 168 tKerosene/tSugar
European kerosene production based on sugar: 3.4 Mt/a (≈ 6 % of demand)
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Certified alternative jet fuels (ASTM D7566 – 14c [1])
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 8
Feedstock Synthesis technology Fuel
Coal, natural gas, biomass, CO2 & H2 Fischer-Tropsch (FT) synthesis Synthetic paraffinic kerosene
Lipids from Biomass (e.g. algae, soya, jatropha) Hydroprocessed esters and fatty acids (HEFA) Synthetic paraffinic kerosene
Sugar from Biomass Direct Sugars to Hydrocarbons (DSHC) Synthetic iso-paraffins /
Farnesane
Bioethanol (-propanol, -butanol) dehydration+oligomerization+hydration
(Alcohol-to-Jet, AtJ)
AD-SPK
[1] ASTM International, „ASTM D7566 - 14C: Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons“, 2015
[2] Eurostat 2019, Crop production in EU standard humidity by NUTS 2 regions
[3] Fachagentur Nachwachsende Rohstoffe, „Steckbrief Ethanol-Kraftstoff”, 2016
[4] NREL, „Review of Biojet Fuel Conversion Technologies”, Golden, 2016
European HEFA? – feedstock example rapeseed & soya:
Apeseed/Soya cultivated area2017[2]: 11.6 mio. ha Rapeoil/Soyaoil per area: 2.6 t/ha[3]
Conversion to fuel [4]: 0. 49 tKerosene/tBiooil
European kerosene production based on HEFA: 14.7 Mt/a (≈ 26 % of demand)
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Certified alternative jet fuels (ASTM D7566 – 14c [1])
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 9
Feedstock Synthesis technology Fuel
Coal, natural gas, biomass, CO2 & H2 Fischer-Tropsch (FT) synthesis Synthetic paraffinic kerosene
Lipids from Biomass (e.g. algae, soya, jatropha) Hydroprocessed esters and fatty acids (HEFA) Synthetic paraffinic kerosene
Sugar from Biomass Direct Sugars to Hydrocarbons (DSHC) Synthetic iso-paraffins /
Farnesane
Bioethanol (-propanol, -butanol) dehydration+oligomerization+hydration
(Alcohol-to-Jet, AtJ)
AD-SPK
[1] ASTM International, „ASTM D7566 - 14C: Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons“, 2015
[2] Pablo Ruiz, „The JRC-EU-TIMES model. Bioenergy potentials for EU and neighbouring countries”, Table 38-43, 2015
[3] Albrecht, “A standardized methodology for the techno-economic evaluation of alternaitve fuels – a case study”, 2016
European BtL Fischer-Tropsch kerosene? – feedstock forestry and municipal waste:
Forest residues, municipal waste potential[2]: ≈ 8 EJLHV/a
Conversion to fuel[3]: 0.363 PLHV,Kerosene/PLHV,Biomass
European kerosene production based on BtL: 68.4 Mt/a (121 % of demand)
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Certified alternative jet fuels (ASTM D7566 – 14c [1])
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 10
Feedstock Synthesis technology Fuel
Coal, natural gas, biomass, CO2 & H2 Fischer-Tropsch (FT) synthesis Synthetic paraffinic kerosene
Lipids from Biomass (e.g. algae, soya, jatropha) Hydroprocessed esters and fatty acids (HEFA) Synthetic paraffinic kerosene
Sugar from Biomass Direct Sugars to Hydrocarbons (DSHC) Synthetic iso-paraffins /
Farnesane
Bioethanol (-propanol, -butanol) dehydration+oligomerization+hydration
(Alcohol-to-Jet, AtJ)
AD-SPK
[1] ASTM International, „ASTM D7566 - 14C: Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons“, 2015
[2] European Environment Agency, “Europe's onshore and offshore wind energy potential,” 2009
[3] Komusanac et al, “Wind energy in Europe in 2018”, 2019
[4] Albrecht, “A standardized methodology for the techno-economic evaluation of alternaitve fuels – a case study”, 2016
European PtL Fischer-Tropsch kerosene? – feedstock renewable electricity:
European wind power potential[2]: 44 – 109 EJe/a (2018: 1.3 EJe/a[3])
Conversion to fuel[4]: 0.506 PLHV,Kerosene/Pe
European kerosene production based on PtL: 56.5 Mt/a (5 - 10 % of wind potential)
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Certified alternative jet fuels (ASTM D7566 – 14c [1])
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 11
Feedstock Synthesis technology Fuel
Coal, natural gas, biomass, CO2 & H2 Fischer-Tropsch (FT) synthesis Synthetic paraffinic kerosene
Lipids from Biomass (e.g. algae, soya, jatropha) Hydroprocessed esters and fatty acids (HEFA) Synthetic paraffinic kerosene
Sugar from Biomass Direct Sugars to Hydrocarbons (DSHC) Synthetic iso-paraffins /
Farnesane
Bioethanol (-propanol, -butanol) dehydration+oligomerization+hydration
(Alcohol-to-Jet, AtJ)
AD-SPK
[1] ASTM International, „ASTM D7566 - 14C: Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons“, 2015
[2] European Environment Agency, “Europe's onshore and offshore wind energy potential,” 2009
[3] Komusanac et al, “Wind energy in Europe in 2018”, 2019
[4] Albrecht, “A standardized methodology for the techno-economic evaluation of alternaitve fuels – a case study”, 2016
European PtL Fischer-Tropsch kerosene? – feedstock renewable electricity:
European wind power potential[2]: 44 – 109 EJe/a (2018: 1.3 EJe/a[3])
Conversion to fuel[4]: 0.506 PLHV,Kerosene/Pe
European kerosene production based on PtL: 56.5 Mt/a (5 - 10 % of wind potential)
Wind capacity increase 17 GW/a required until 2050 !!! (wind2018: 11.7 GW[3])
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
Pyrolysis and gasification
(gasification options: fixed-bed, fluidized
bed, entrained-flow)
Fischer-Tropsch Synthesis
(Options: High-/low temperature, cobalt/
iron cat.)
Product separation & conditioning
(depending on the required fuel specifications)
Water-electrolysis(Options: Alkalic PEM,
High-temperature (SOEC))
CO2 purification(Options: SelexolTM
Rectisol, MEA …)
Reverse Water-Gas-Shift Reaction
(900°C)
Water-Gas Shift Reaction (230°C) + CO2 purification
CO2
H2
CO,H2,CO2
Fischer-Tropsch fuel
CO2
Internal recycle
External recycleIndustry
flue gases
Power
Biomass
Water
Steam
Steam
Oxy-fuel burner + steam cycle Tail gas
CO2-recycle
O2
O2
Syngas supply Syngas conditioning Fuel synthesis
Power-to-Liquid (PtL)
Power&Biomass-to-Liquid (PBtL)
Biomass-to-Liquid (BtL)
Heat
Steam
Overview: Fischer-Tropsch Kerosene Concepts [1]
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 12
1 F. G. Albrecht, D. H. König, N. Baucks und R. U. Dietrich, „A standardized methodology for the techno-economic evaluation of alternative fuels,“ Fuel, Bd. 194, pp. 511-526, 2017.
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
Alternative jet fuel
Technical evaluation
Ecological evaluation
Economic assessment
Techno-Economic and ecological assessment (TEEA)
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 13
DLR’s Techno economic
process evaluation tool
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ TEEA approach @ DLR
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 14
Literature
survey
1. Step
Identification of best
suited process design
Energy and material
balance
3. Step 4. Step
Identifying
crucial
process
parameters
Feedback to
project
partners
5. Step
Exchange
with project
partners
2. Step
Detailed
process
simulation
Stationary flowsheet
model
Technical
optimization (Process
control,
Heat integration, …)
Techno-
economic
evaluation
TEPET-
ASPEN Link
Exchange of process
parameters
Automatic sequencing
and economic
optimization
Calculation of NPC
(CAPEX, OPEX, etc.)
Sensitivity analysis &
upscaling
Iteration
Aspen Plus®
Simulation
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
Alternative jet fuel
Technical evaluation
Ecological evaluation
Economic assessment
Techno-Economic and ecological assessment (TEEA)
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 15
DLR’s Techno economic
process evaluation tool
Efficiencies (X-to-Liquid, Overall)
Carbon conversion
Specific feedstock demand
Exergy analysis
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Technical evaluation of renewable jet fuel options [1]
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 16
Comparison Biomass-to-Liquid Power/Biomass-to-Liquid Power-to-Liquid
X-to-Liquid efficiency 36.3 % 51.4 % 50.6 %
Energy efficiency 82.6 % 65.0 % 66.8 %
Carbon conversion 24.9 % 97.7 % 98 %
[1] Albrecht, “A standardized methodology for the techno-economic evaluation of alternaitve fuels – a case study”, 2016
η𝑋𝑡𝐿 =𝑄 𝑘𝑒𝑟𝑜𝑒𝑠𝑒𝑛𝑒−𝐿𝐻𝑉
𝑃𝑒 + 𝑄 𝐵𝑖𝑜𝑚𝑎𝑠𝑠−𝐿𝐻𝑉
η𝑒 =𝑄 𝑘𝑒𝑟𝑜𝑒𝑠𝑒𝑛𝑒−𝐿𝐻𝑉 + 𝑄 𝑠𝑡𝑒𝑎𝑚
𝑃𝑒 + 𝑄 𝐵𝑖𝑜𝑚𝑎𝑠𝑠−𝐿𝐻𝑉
η𝑐 =𝑛 𝐶−𝑘𝑒𝑟𝑜𝑒𝑠𝑒𝑛𝑒𝑛 𝐶−𝐹𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Techno-Economic and ecological assessment (TEEA)
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 17
Alternative jet fuel
Technical evaluation
Ecological evaluation
Economic assessment
DLR’s Techno economic
process evaluation tool
CAPEX, OPEX, NPC
Sensitivity analysis
Identification of most economic
feasible process design
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ TEEA tool TEPET @ DLR
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 18
• adapted from best-practice chem. eng. methodology
• Meets AACE class 3-4, Accuracy: +/- 30 %
• Year specific using annual CEPCI Index
• Automated interface for seamless integration
• Easy sensitivity studies for every parameter
• Learning curves, economy of scale, …
Unit sizes Energy/
Material flows
Net production costs
(NPC) [€/kg]
Operational costs • Raw materials
• Utilities
• Maintenance
• Labor
Capital costs • Equipment costs
• Piping and installation
• Service facilities
• Engineering
Process simulation
results
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
Investment costs:
PEM-Electrolyzer (stack): 850 €/kW [1] (scale factor: 1)
PEM-Electrolyzer (system): 1,370 €/kW (TEPET, incl. supplementary factors)
Fischer-Tropsch reactor: 17.44 Mio.€/(kmolfeed/s) [2] (scale factor: 0.67)
Raw materials and utility costs
Electricity: 99.6 €/MWh [3]
Biomass: 80.1 €/t [4]
District heating 0.027 €/kWh [5,7] Byproduct
Steam (export): 19.8 €/t [6] Byproduct
General economic assumptions:
Year: 2017 Plant lifetime: 30 years
Full load hours: 8,260 h/a Interest rate: 5 %
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 19
[1] G. Saur, Wind-To-Hydrogen Project: Electrolyzer Capital Cost Study, Technical Report NREL, 2008
[2] I. Hannula and E. Kurkela, Liquid transportation fuels via large-scale fluidised-bed gasification of lignocellulosic biomass, VTT, Finland, 2013.
[3] Eurostat, Preise Elektrizität für Industrieabnehmer in Deutschland, 2016
[4] C.A.R.M.E.N. – Preisentwicklung bei Waldhackschnitzel (Energieholz-Index), 2017
[5] Energieeffizienzverband für Wärme, Kälte und KWK e.V., Heizkostenvergleich nach VDI 2067-Musterrechnung, 2014
[6] Own calculations based on natural gas price from Eurostat database 2017
[7] http://www.rogersrawmaterials.com/home.asp (accessed 02/2018)
Example: TEEA of sustainable Jet fuel production
Plant capacity: 550 kt/a (1 % of European jet fuel consumption)
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
-0,6
0,0
0,6
1,2
1,8
2,4
3,0
3,6
4,2
Pro
du
ctio
n c
ost
s in
€/k
g
Electrolyzer
Fischer-Tropsch synthesis
Gasifier
Rest (CAPEX)
Biomass
Electricity
Oxygen
Remaining (Raw materials & Utilities)
Revenue from by-products
Maintenance
Labor costs
Rest (OPEX)
51 % 65 %
Example: TEEA of sustainable Jet fuel production
Plant capacity: 550 kt/a (1 % of European jet fuel consumption) – Base year: 2017
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 20
BtL
1.80 €/kg
PBtL
2.91 €/kg
PtL
3.68 €/kg
• Investment costs: 5.03 billion €
• 2.27 GWth biomass feed required
very long transport distances
GHG-Footprint of
biomass increases
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
-0,6
0,0
0,6
1,2
1,8
2,4
3,0
3,6
4,2
Pro
du
ctio
n c
ost
s in
€/k
g
Electrolyzer
Fischer-Tropsch synthesis
Gasifier
Rest (CAPEX)
Biomass
Electricity
Oxygen
Remaining (Raw materials & Utilities)
Revenue from by-products
Maintenance
Labor costs
Rest (OPEX)
51 % 65 %
Example: TEEA of sustainable Jet fuel production
Plant capacity: 550 kt/a (1 % of European jet fuel consumption) – Base year: 2017
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 21
BtL
1.80 €/kg
PBtL
2.91 €/kg
PtL
3.68 €/kg
• Investment costs: 4.48 billion €
• 1.61 GW electrolyzer required
• Investment costs: 4.35 billion €
• 1.03 GW electrolyzer required
• 0.6 GWth biomass feed
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
Example: TEEA sensitivity of PBtL Plant capacity: 550 kt/a (1 % of European jet fuel consumption) – Base year: 2017
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 22
DLR.de • Folie 3 • TÖB der Erzeugung alternativer Kraftstoffe • R.-U. Dietrich • ProcessNet EVT 2017 • 03.04.2017
105
100
959085807570656055504540353025
20
1.3
1.4
1.5
1.6
1.7
1.8
1.9
2
2.1
2.2
2.3
2.4
2.5
2.6
25,000
77,941
130,882
183,824
236,765
2.5-2.6
2.4-2.5
2.3-2.4
2.2-2.3
2.1-2.2
2-2.1
1.9-2
1.8-1.9
1.7-1.8
1.6-1.7
1.5-1.6
1.4-1.5
1.3-1.4
BtL
PtL
PBtL
EEX
€/lPreferred technology depend on local conditions
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
Alternative jet fuel
Technical evaluation
Ecological evaluation
Economic assessment
DLR’s Techno economic
process evaluation tool
Techno-Economic and ecological assessment (TEEA)
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 23
GHG-footprint
GHG-abatement costs
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Example: Fischer-Tropsch Jet fuel GHG-Footprint
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 24
Electricity footprint
CO2 footprint
GHG-footprint of
products
𝐆𝐇𝐆 𝐚𝐛𝐚𝐭𝐞𝐦𝐞𝐧𝐭 𝐜𝐨𝐬𝐭𝐬 €
𝐭𝐂𝐎𝟐𝐞𝐪. =
𝐃𝐢𝐟𝐟𝐞𝐫𝐞𝐧𝐜𝐞 𝐢𝐧 𝐩𝐫𝐨𝐝𝐮𝐜𝐭𝐢𝐨𝐧 𝐜𝐨𝐬𝐭𝐬
𝐆𝐇𝐆 𝐚𝐛𝐚𝐭𝐞𝐦𝐞𝐧𝐭
P&BtX - Concept
• Systemintegration
• Efficiency
• Plant emissions
• Crediting of by-products
(steam, electricity, …)
Biomass footprint
Application
efficiency
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Example: Fischer-Tropsch Jet fuel GHG-Footprint
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 25
PtL PBtL BtL
3.68 €/kg 2.91 €/kg 1.80 €/kg
conv. Kerosene
0.63 €/kg 1)
• Calculation of production costs (550 kt/a):
1) U.S. energy information administration (05.09.2018) http://www.eia.gov/dnav/pet/pet_pri_spt_s1_d.htm 2) Eigene Berechnung: CO2-Ausstoß bei der Verbrennung von 1 kg Kerosin Jet-A1 3) Bouvart et al. (2013), „Well-To-Tank" carbon impact of fossil fuels
vs.
Electricity origin PtL PBtL BtL
Electricity mix (VEU-2015 scenario) 13.97 9.11 - 3.59
100 % wind energy - 1.61 - 0.37 - 0.89
vs.
• Calculation of GHG-emissions in kgCO2eq./kgfuel:
conv. Kerosene
3.11 kgCO2eq./kg 2)
+
0.64 kgCO2eq./kg 3) No CO2-reduction
possible
No CO2-reduction
with current German
electricity mix!
𝐆𝐇𝐆 𝐚𝐛𝐚𝐭𝐞𝐦𝐞𝐧𝐭 𝐜𝐨𝐬𝐭𝐬 €
𝐭𝐂𝐎𝟐𝐞𝐪. =
𝐃𝐢𝐟𝐟𝐞𝐫𝐞𝐧𝐜𝐞 𝐢𝐧 𝐩𝐫𝐨𝐝𝐮𝐜𝐭𝐢𝐨𝐧 𝐜𝐨𝐬𝐭𝐬
𝐆𝐇𝐆 𝐚𝐛𝐚𝐭𝐞𝐦𝐞𝐧𝐭
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Example: Fischer-Tropsch Jet fuel GHG-Footprint
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 26
Production route: PtL PBtL BtL
Production costs [€/kgkerosene] 3.68 2.91 1.80
Electricity mix (VEU-2015 reg. change) x x 159
100 % wind energy 569 553 252
𝐆𝐇𝐆 𝐚𝐛𝐚𝐭𝐞𝐦𝐞𝐧𝐭 𝐜𝐨𝐬𝐭𝐬 €
𝐭𝐂𝐎𝟐𝐞𝐪. =
𝐃𝐢𝐟𝐟𝐞𝐫𝐞𝐧𝐜𝐞 𝐢𝐧 𝐩𝐫𝐨𝐝𝐮𝐜𝐭𝐢𝐨𝐧 𝐜𝐨𝐬𝐭𝐬
𝐆𝐇𝐆 𝐚𝐛𝐚𝐭𝐞𝐦𝐞𝐧𝐭
Electricity & biomass prices -70 %: 1.45 €/kg 1.29 €/kg 1.00 €/kg
Electricity mix (VEU-2015 reg. change) x x 50
100 % wind energy 152 160 80
• Future feedstock cost reduction?
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ TEEA – long term goal
Merit order of GHG abatement
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 27
Option 4
Option 1
Option 3
Option 5
Option 6
CO
2-A
bat
emen
t co
sts
/ €/t
CO
2
CO2-Abatement Amount / tCO2/a
Option 8
Option 9
Option 10 Option 11
Option 2
Electro-Fuel 2
EU instrument to reduce GHG emissions: CO2-certificates
Electro-Fuel 1
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ TEEA – long term goal
Merit order of GHG abatement
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 28
Option 4
Option 1
Option 3
Option 5
Option 6
CO
2-A
bat
emen
t co
sts
/ €/t
CO
2
CO2-Abatement Amount / tCO2/a
Option 8
Option 9
Option 10 Option 11
Option 2
Electro-Fuel 2
Goal: CO2 reduction @ minimized GHG-Abatement cost, either by reducing GHG footprint or costs!
Standardized and verified methodology for TEA required!
EU instrument to reduce GHG emissions: CO2-certificates
Electro-Fuel 1
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Summary (part 1)
• Renewable fuels are required to achieve the aviation climate change mitigation goals
• “Silver bullet” technology not decided yet
• Large scale Fischer-Tropsch synthesis: highest feedstock flexibility (syngas) and highest technical maturity
Downscale towards renewable power and/or biomass supply?
• GHG abatement cost should be the key decision criterion for any climate change mitigation roadmap
• Transparent and standardized DLR methodology for cost estimation and GHG-footprint offers
a valid starting point for technology assessment and future global transport roadmap
• Renewable kerosene technology development, scale up and market introduction outlook
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 29
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN1
www.comsynproject.eu – EU No. 727476
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 30
PRIMARY
CONVERSION
Decentralized FT wax
production at small-to-
medium scale units at
biomass sites
(50-150 MWth input)
+ locally utilized excess
heat for ηtotal > 80 %
PRODUCT
UPGRADING
Centralized FT
product refining to
high quality drop-in
liquid fuels at
existing oil refineries
New decentralized BTL production concept with biofuel production cost reduction up to 35 %
compared to alternative routes (< 1.10 €/kg production cost for diesel)
COMSYN project has received funding from the
European Union’s Horizon 2020 research and
innovation programme under grant agreement No
727476
[1] Special thanks to the contribution of: P. Simell, J. Kihlman, S. Tuomi, E. Kurkela, C. Frilund, V. Kivelä (VTT), T. Böltken, M. Selinsek (INERATEC), H. Balzer (GKN),
J. Hajek (UniCRE), V. Tota (Wood), V. Hankalin (ÅF Consult)
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN
Project concept details
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 31
COMSYN project has received funding from the
European Union’s Horizon 2020 research and
innovation programme under grant agreement No
727476
5 m3/h
SLIP-STREAM TO
SYNTHESIS
DFB PILOT @ VTT MOBILE SYNTHESIS UNIT
FILTER DFB
GASIFIER
Product
Upgrading REFORMER ULTRACLEANING STEPS
FISCHER-TROPSCH
SYNTHESIS
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN
Project concept details
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 32
COMSYN project has received funding from the
European Union’s Horizon 2020 research and
innovation programme under grant agreement No
727476
5 m3/h
SLIP-STREAM TO
SYNTHESIS
DFB PILOT @ VTT MOBILE SYNTHESIS UNIT
FILTER DFB
GASIFIER
Product
Upgrading REFORMER ULTRACLEANING STEPS
FISCHER-TROPSCH
SYNTHESIS
DFB Gasifier
• Finalized: 2015
• Biomass feed: ca. 50 kg/h
• Gasifier temperature: 750 – 820 °C
• Oxidizer temperature: ca. 900 °C
• Bed material: Dolomite/sand mixture
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN
Project concept details
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 33
COMSYN project has received funding from the
European Union’s Horizon 2020 research and
innovation programme under grant agreement No
727476
5 m3/h
SLIP-STREAM TO
SYNTHESIS
DFB PILOT @ VTT MOBILE SYNTHESIS UNIT
FILTER DFB
GASIFIER
Product
Upgrading REFORMER ULTRACLEANING STEPS
FISCHER-TROPSCH
SYNTHESIS
Hot gas filtration
• Intermediate cooling/reheating steps eliminated
• Filtration at high temperature (ca. 800 °C) with
simultaneous decomposition of tars
• Development of catalytically activated filters
using ALD technology
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN
Project concept details
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 34
COMSYN project has received funding from the
European Union’s Horizon 2020 research and
innovation programme under grant agreement No
727476
5 m3/h
SLIP-STREAM TO
SYNTHESIS
DFB PILOT @ VTT MOBILE SYNTHESIS UNIT
FILTER DFB
GASIFIER
Product
Upgrading REFORMER ULTRACLEANING STEPS
FISCHER-TROPSCH
SYNTHESIS
Catalytic reforming
• Development of an oxygen-permeable membrane
reactor to enable better control of reaction temperature
in the reformer (hot spots)
• Catalyst development: ALD coating to increase the
activity as well as sulphur and coke tolerance of the
catalyst
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN
Project concept details
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 35
COMSYN project has received funding from the
European Union’s Horizon 2020 research and
innovation programme under grant agreement No
727476
5 m3/h
SLIP-STREAM TO
SYNTHESIS
DFB PILOT @ VTT MOBILE SYNTHESIS UNIT
FILTER DFB
GASIFIER
Product
Upgrading REFORMER ULTRACLEANING STEPS
FISCHER-TROPSCH
SYNTHESIS
Ultracleaning concept:
• Specifically for biomass-based gasification gas, thus considers:
• Low to medium sulphur content
• Residual hydrocarbons (tars)
• Wet scrubbing acid gas process (Rectisol, Selexol) replaced by:
• Simpler dry bed desulphurization
• No removal of CO2 or partial CO2 removal in simple
pressure water scrubbing to 5 vol-% content
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN
Project concept details
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 36
COMSYN project has received funding from the
European Union’s Horizon 2020 research and
innovation programme under grant agreement No
727476
5 m3/h
SLIP-STREAM TO
SYNTHESIS
DFB PILOT @ VTT MOBILE SYNTHESIS UNIT
FILTER DFB
GASIFIER
Product
Upgrading REFORMER ULTRACLEANING STEPS
FISCHER-TROPSCH
SYNTHESIS
Fischer-Tropsch microreactor:
• Compact and modular design
• High efficiencies
• Load flexible
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN
Project concept details
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 37
COMSYN project has received funding from the
European Union’s Horizon 2020 research and
innovation programme under grant agreement No
727476
5 m3/h
SLIP-STREAM TO
SYNTHESIS
DFB PILOT @ VTT MOBILE SYNTHESIS UNIT
FILTER DFB
GASIFIER
Product
Upgrading REFORMER ULTRACLEANING STEPS
FISCHER-TROPSCH
SYNTHESIS
Product upgrading
• Co-processesing of FT-waxes or
• Stand-alone treatment
(incl. a new hydroisomerisation unit)
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN
Project concept details
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 38
COMSYN project has received funding from the
European Union’s Horizon 2020 research and
innovation programme under grant agreement No
727476
5 m3/h
SLIP-STREAM TO
SYNTHESIS
DFB PILOT @ VTT MOBILE SYNTHESIS UNIT
FILTER DFB
GASIFIER
Product
Upgrading REFORMER ULTRACLEANING STEPS
FISCHER-TROPSCH
SYNTHESIS
Hot gas filtration
• Intermediate cooling/reheating steps eliminated
• Filtration at high temperature (ca. 800 °C) with
simultaneous decomposition of tars
• Development of catalytically activated filters
using ALD technology
Catalytic reforming
• Development of an oxygen-permeable membrane
reactor to enable better control of reaction temperature
in the reformer (hot spots)
• Catalyst development: ALD coating to increase the
activity as well as sulphur and coke tolerance of the
catalyst
Ultracleaning concept:
• Specifically for biomass-based gasification gas, thus considers:
• Low to medium sulphur content
• Residual hydrocarbons (tars)
• Wet scrubbing acid gas process (Rectisol, Selexol) replaced by:
• Simpler dry bed desulphurization
• No removal of CO2 or partial CO2 removal in simple
pressure water scrubbing to 5 vol-% content
DFB Gasifier
• Finalized: 2015
• Biomass feed: ca. 50 kg/h
• Gasifier temperature: 750 – 820 °C
• Oxidizer temperature: ca. 900 °C
• Bed material: Dolomite/sand mixture
Fischer-Tropsch microreactor*:
• Compact and modular design
• High efficiencies
• Load flexible
Product upgrading
• Co-processesing of FT-waxes or
• Stand-alone treatment
(incl. a new hydroisomerisation unit)
Open Questions / Development Tasks
Within COMSYN: • Technical Validation • Fuel Flexibility • Techno-economic assessments • Ecological impact • Business cases for different
European regions
Beyond COMSYN: • No. of European sites for
decentralized fuels production • Logistic to interconnect
multiple decentralized sites • Mass manufacturing of
decentralized fuel plants
Validation of decentralized sustainable fuel production for large scale decarbonization of aviation!
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ DLR contribution to renewable kerosene research
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 39
Fuel usage
Separation
CO2-Source
Reverse water - gas - shift reactor
Fischer - Tropsch s ynth e s is
Syncrude
Tail gas processing
External Recycle
Refinery
Tail gas
Gasoline Jet fuel Diesel
Intern al Recycle
H2
Electrolysis (Renewable)
Power
H2O
H2
Product separation
CO2
Industry delivery
Industry delivery
Comprehensive assessment (TEEA)
Gas Cleaning
Gas Cleaning
Biomass Gasification
Biomass-Source
Industry delivery
Power grid, feedstock supply
Refinery expertise required
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Outlook
• Renewable aviation fuels development requires strong refinery commitment
• European GHG abatement will change global fossil energy market leading countries, other stakeholders?
• Upcoming CO2 regulation will need techno economic guidance GHG abatement costs
• DLR supports every promising technology towards renewable aviation HORIZON 2020 calls available
• Technology demonstration not sufficient for future renewable aviation market introduction
• Find a serious response to ensure next generations living conditions – now!
• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 40
13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
Ralph-Uwe Dietrich [email protected]
German Aerospace Center / Deutsches Zentrum für Luft- und Raumfahrt e.V. (DLR)
Institute of Engineering Thermodynamics
Research Area Manager Alternative Fuels
Thank you for your attention!