+ All Categories
Home > Documents > Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA...

Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA...

Date post: 05-Oct-2020
Category:
Upload: others
View: 7 times
Download: 0 times
Share this document with a friend
41
Challenges & opportunities for sustainable aviation Technical, economic and ecologic fuel evaluation from aviation point of view Sandra Adelung, Friedemann Albrecht, Ralph-Uwe Dietrich, Felix Habermeyer, Stefan Estelmann, Simon Maier, Moritz Raab (DLR e.V., www.DLR.de/tt) 13 th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’
Transcript
Page 1: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

Challenges & opportunities for sustainable aviation Technical, economic and ecologic fuel evaluation from aviation point of view

Sandra Adelung, Friedemann Albrecht, Ralph-Uwe Dietrich, Felix Habermeyer, Stefan Estelmann, Simon Maier, Moritz Raab (DLR e.V., www.DLR.de/tt)

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’

Page 2: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’

Outlook

Renewable jet fuel production routes

Techno-economic and ecological assessment at DLR

Technology development activities & need

Motivation

Agenda

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 2

Page 3: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Motivation

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 3

Source: https://www.co2.earth/daily-co2?noaa-mauna-loa-co2-data.html

Kyoto Protocol adopted on 1997

UNFCCC Paris Agreement adopted on 2015

Page 4: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Motivation

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 4

Brussels Paris

London Washington, DC

Sydney

Davos

Page 5: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’

1

2

3

Forecasted CO2 emissions without reduction measures

Improvement of technologies, operations and airport infrastructure

CO2-certificates and other economic measures (CORSIA[2] 2016)

Radical technology transitions and alternative fuels

CO

2 e

mis

sio

ns

Planned Measures:

No action

2010 2020 2030 2040 2050

3

Technology

1 2

Operations

Infrastructure

European aviation kerosene demand in 2010: ca. 56.5 Mt[3]

-50 % CO2

by 2050

Main goals:

Improvement of fuel

efficiency about

1.5 % p.a. until 2020

Carbon-neutral

growth from 2020

50 % CO2 emissions

reductions by 2050

Aviation Industry Response: IATA Technology Roadmap [1]

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 5

[1] iata.org, IATA Technology Roadmap 4. Edition, June 2013

[2] ICAO-Resolution A39-3: Carbon Offsetting and Reduction Scheme for International Aviation

[3] FuelsEurope “Statistical Report“ 2010

… equals renewable kerosene demand in 2050?

Page 6: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Certified alternative jet fuels (ASTM D7566 – 14c [1])

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 6

Feedstock Synthesis technology Fuel

Coal, natural gas, biomass, CO2 & H2 Fischer-Tropsch (FT) synthesis Synthetic paraffinic kerosene

Lipids from Biomass (e.g. algae, soya, jatropha) Hydroprocessed esters and fatty acids (HEFA) Synthetic paraffinic kerosene

Sugar from Biomass Direct Sugars to Hydrocarbons (DSHC) Synthetic iso-paraffins /

Farnesane

Bioethanol (-propanol, -butanol) dehydration+oligomerization+hydration

(Alcohol-to-Jet, AtJ)

AD-SPK

[1] ASTM International, „ASTM D7566 - 14C: Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons“, 2015

[2] Eurostat 2019, Crop production in EU standard humidity by NUTS 2 regions

[3] Fachagentur Nachwachsende Rohstoffe, „Steckbrief Ethanol-Kraftstoff”, 2016

[4] NREL, „Review of Biojet Fuel Conversion Technologies”, Golden, 2016

European AtJ? – feedstock example wheat:

Wheat cultivated area2017[2]: 25.9 mio. ha Ethanol per area: 2.2 t/ha[3]

Conversion to fuel [4]: 0.56 tKerosene/tEthanol

European kerosene production based on wheat: 31.9 Mt/a (≈ 56 % of demand)

Page 7: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Certified alternative jet fuels (ASTM D7566 – 14c [1])

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 7

Feedstock Synthesis technology Fuel

Coal, natural gas, biomass, CO2 & H2 Fischer-Tropsch (FT) synthesis Synthetic paraffinic kerosene

Lipids from Biomass (e.g. algae, soya, jatropha) Hydroprocessed esters and fatty acids (HEFA) Synthetic paraffinic kerosene

Sugar from Biomass Direct Sugars to Hydrocarbons (DSHC) Synthetic iso-paraffins /

Farnesane

Bioethanol (-propanol, -butanol) dehydration+oligomerization+hydration

(Alcohol-to-Jet, AtJ)

AD-SPK

[1] ASTM International, „ASTM D7566 - 14C: Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons“, 2015

[2] Eurostat 2019, Crop production in EU standard humidity by NUTS 2 regions

[3] Fachagentur Nachwachsende Rohstoffe, „Steckbrief Ethanol-Kraftstoff”, 2016

[4] NREL, „Review of Biojet Fuel Conversion Technologies”, Golden, 2016

European DSHC? – feedstock example sugar beet:

Sugar beet cultivated area2017[2]: 1.8 mio. ha Sugar per area: 11.6 t/ha[3]

Conversion to fuel [4]: 0. 168 tKerosene/tSugar

European kerosene production based on sugar: 3.4 Mt/a (≈ 6 % of demand)

Page 8: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Certified alternative jet fuels (ASTM D7566 – 14c [1])

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 8

Feedstock Synthesis technology Fuel

Coal, natural gas, biomass, CO2 & H2 Fischer-Tropsch (FT) synthesis Synthetic paraffinic kerosene

Lipids from Biomass (e.g. algae, soya, jatropha) Hydroprocessed esters and fatty acids (HEFA) Synthetic paraffinic kerosene

Sugar from Biomass Direct Sugars to Hydrocarbons (DSHC) Synthetic iso-paraffins /

Farnesane

Bioethanol (-propanol, -butanol) dehydration+oligomerization+hydration

(Alcohol-to-Jet, AtJ)

AD-SPK

[1] ASTM International, „ASTM D7566 - 14C: Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons“, 2015

[2] Eurostat 2019, Crop production in EU standard humidity by NUTS 2 regions

[3] Fachagentur Nachwachsende Rohstoffe, „Steckbrief Ethanol-Kraftstoff”, 2016

[4] NREL, „Review of Biojet Fuel Conversion Technologies”, Golden, 2016

European HEFA? – feedstock example rapeseed & soya:

Apeseed/Soya cultivated area2017[2]: 11.6 mio. ha Rapeoil/Soyaoil per area: 2.6 t/ha[3]

Conversion to fuel [4]: 0. 49 tKerosene/tBiooil

European kerosene production based on HEFA: 14.7 Mt/a (≈ 26 % of demand)

Page 9: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Certified alternative jet fuels (ASTM D7566 – 14c [1])

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 9

Feedstock Synthesis technology Fuel

Coal, natural gas, biomass, CO2 & H2 Fischer-Tropsch (FT) synthesis Synthetic paraffinic kerosene

Lipids from Biomass (e.g. algae, soya, jatropha) Hydroprocessed esters and fatty acids (HEFA) Synthetic paraffinic kerosene

Sugar from Biomass Direct Sugars to Hydrocarbons (DSHC) Synthetic iso-paraffins /

Farnesane

Bioethanol (-propanol, -butanol) dehydration+oligomerization+hydration

(Alcohol-to-Jet, AtJ)

AD-SPK

[1] ASTM International, „ASTM D7566 - 14C: Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons“, 2015

[2] Pablo Ruiz, „The JRC-EU-TIMES model. Bioenergy potentials for EU and neighbouring countries”, Table 38-43, 2015

[3] Albrecht, “A standardized methodology for the techno-economic evaluation of alternaitve fuels – a case study”, 2016

European BtL Fischer-Tropsch kerosene? – feedstock forestry and municipal waste:

Forest residues, municipal waste potential[2]: ≈ 8 EJLHV/a

Conversion to fuel[3]: 0.363 PLHV,Kerosene/PLHV,Biomass

European kerosene production based on BtL: 68.4 Mt/a (121 % of demand)

Page 10: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Certified alternative jet fuels (ASTM D7566 – 14c [1])

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 10

Feedstock Synthesis technology Fuel

Coal, natural gas, biomass, CO2 & H2 Fischer-Tropsch (FT) synthesis Synthetic paraffinic kerosene

Lipids from Biomass (e.g. algae, soya, jatropha) Hydroprocessed esters and fatty acids (HEFA) Synthetic paraffinic kerosene

Sugar from Biomass Direct Sugars to Hydrocarbons (DSHC) Synthetic iso-paraffins /

Farnesane

Bioethanol (-propanol, -butanol) dehydration+oligomerization+hydration

(Alcohol-to-Jet, AtJ)

AD-SPK

[1] ASTM International, „ASTM D7566 - 14C: Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons“, 2015

[2] European Environment Agency, “Europe's onshore and offshore wind energy potential,” 2009

[3] Komusanac et al, “Wind energy in Europe in 2018”, 2019

[4] Albrecht, “A standardized methodology for the techno-economic evaluation of alternaitve fuels – a case study”, 2016

European PtL Fischer-Tropsch kerosene? – feedstock renewable electricity:

European wind power potential[2]: 44 – 109 EJe/a (2018: 1.3 EJe/a[3])

Conversion to fuel[4]: 0.506 PLHV,Kerosene/Pe

European kerosene production based on PtL: 56.5 Mt/a (5 - 10 % of wind potential)

Page 11: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Certified alternative jet fuels (ASTM D7566 – 14c [1])

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 11

Feedstock Synthesis technology Fuel

Coal, natural gas, biomass, CO2 & H2 Fischer-Tropsch (FT) synthesis Synthetic paraffinic kerosene

Lipids from Biomass (e.g. algae, soya, jatropha) Hydroprocessed esters and fatty acids (HEFA) Synthetic paraffinic kerosene

Sugar from Biomass Direct Sugars to Hydrocarbons (DSHC) Synthetic iso-paraffins /

Farnesane

Bioethanol (-propanol, -butanol) dehydration+oligomerization+hydration

(Alcohol-to-Jet, AtJ)

AD-SPK

[1] ASTM International, „ASTM D7566 - 14C: Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons“, 2015

[2] European Environment Agency, “Europe's onshore and offshore wind energy potential,” 2009

[3] Komusanac et al, “Wind energy in Europe in 2018”, 2019

[4] Albrecht, “A standardized methodology for the techno-economic evaluation of alternaitve fuels – a case study”, 2016

European PtL Fischer-Tropsch kerosene? – feedstock renewable electricity:

European wind power potential[2]: 44 – 109 EJe/a (2018: 1.3 EJe/a[3])

Conversion to fuel[4]: 0.506 PLHV,Kerosene/Pe

European kerosene production based on PtL: 56.5 Mt/a (5 - 10 % of wind potential)

Wind capacity increase 17 GW/a required until 2050 !!! (wind2018: 11.7 GW[3])

Page 12: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’

Pyrolysis and gasification

(gasification options: fixed-bed, fluidized

bed, entrained-flow)

Fischer-Tropsch Synthesis

(Options: High-/low temperature, cobalt/

iron cat.)

Product separation & conditioning

(depending on the required fuel specifications)

Water-electrolysis(Options: Alkalic PEM,

High-temperature (SOEC))

CO2 purification(Options: SelexolTM

Rectisol, MEA …)

Reverse Water-Gas-Shift Reaction

(900°C)

Water-Gas Shift Reaction (230°C) + CO2 purification

CO2

H2

CO,H2,CO2

Fischer-Tropsch fuel

CO2

Internal recycle

External recycleIndustry

flue gases

Power

Biomass

Water

Steam

Steam

Oxy-fuel burner + steam cycle Tail gas

CO2-recycle

O2

O2

Syngas supply Syngas conditioning Fuel synthesis

Power-to-Liquid (PtL)

Power&Biomass-to-Liquid (PBtL)

Biomass-to-Liquid (BtL)

Heat

Steam

Overview: Fischer-Tropsch Kerosene Concepts [1]

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 12

1 F. G. Albrecht, D. H. König, N. Baucks und R. U. Dietrich, „A standardized methodology for the techno-economic evaluation of alternative fuels,“ Fuel, Bd. 194, pp. 511-526, 2017.

Page 13: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’

Alternative jet fuel

Technical evaluation

Ecological evaluation

Economic assessment

Techno-Economic and ecological assessment (TEEA)

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 13

DLR’s Techno economic

process evaluation tool

Page 14: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ TEEA approach @ DLR

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 14

Literature

survey

1. Step

Identification of best

suited process design

Energy and material

balance

3. Step 4. Step

Identifying

crucial

process

parameters

Feedback to

project

partners

5. Step

Exchange

with project

partners

2. Step

Detailed

process

simulation

Stationary flowsheet

model

Technical

optimization (Process

control,

Heat integration, …)

Techno-

economic

evaluation

TEPET-

ASPEN Link

Exchange of process

parameters

Automatic sequencing

and economic

optimization

Calculation of NPC

(CAPEX, OPEX, etc.)

Sensitivity analysis &

upscaling

Iteration

Aspen Plus®

Simulation

Page 15: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’

Alternative jet fuel

Technical evaluation

Ecological evaluation

Economic assessment

Techno-Economic and ecological assessment (TEEA)

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 15

DLR’s Techno economic

process evaluation tool

Efficiencies (X-to-Liquid, Overall)

Carbon conversion

Specific feedstock demand

Exergy analysis

Page 16: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Technical evaluation of renewable jet fuel options [1]

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 16

Comparison Biomass-to-Liquid Power/Biomass-to-Liquid Power-to-Liquid

X-to-Liquid efficiency 36.3 % 51.4 % 50.6 %

Energy efficiency 82.6 % 65.0 % 66.8 %

Carbon conversion 24.9 % 97.7 % 98 %

[1] Albrecht, “A standardized methodology for the techno-economic evaluation of alternaitve fuels – a case study”, 2016

η𝑋𝑡𝐿 =𝑄 𝑘𝑒𝑟𝑜𝑒𝑠𝑒𝑛𝑒−𝐿𝐻𝑉

𝑃𝑒 + 𝑄 𝐵𝑖𝑜𝑚𝑎𝑠𝑠−𝐿𝐻𝑉

η𝑒 =𝑄 𝑘𝑒𝑟𝑜𝑒𝑠𝑒𝑛𝑒−𝐿𝐻𝑉 + 𝑄 𝑠𝑡𝑒𝑎𝑚

𝑃𝑒 + 𝑄 𝐵𝑖𝑜𝑚𝑎𝑠𝑠−𝐿𝐻𝑉

η𝑐 =𝑛 𝐶−𝑘𝑒𝑟𝑜𝑒𝑠𝑒𝑛𝑒𝑛 𝐶−𝐹𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘

Page 17: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Techno-Economic and ecological assessment (TEEA)

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 17

Alternative jet fuel

Technical evaluation

Ecological evaluation

Economic assessment

DLR’s Techno economic

process evaluation tool

CAPEX, OPEX, NPC

Sensitivity analysis

Identification of most economic

feasible process design

Page 18: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ TEEA tool TEPET @ DLR

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 18

• adapted from best-practice chem. eng. methodology

• Meets AACE class 3-4, Accuracy: +/- 30 %

• Year specific using annual CEPCI Index

• Automated interface for seamless integration

• Easy sensitivity studies for every parameter

• Learning curves, economy of scale, …

Unit sizes Energy/

Material flows

Net production costs

(NPC) [€/kg]

Operational costs • Raw materials

• Utilities

• Maintenance

• Labor

Capital costs • Equipment costs

• Piping and installation

• Service facilities

• Engineering

Process simulation

results

Page 19: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’

Investment costs:

PEM-Electrolyzer (stack): 850 €/kW [1] (scale factor: 1)

PEM-Electrolyzer (system): 1,370 €/kW (TEPET, incl. supplementary factors)

Fischer-Tropsch reactor: 17.44 Mio.€/(kmolfeed/s) [2] (scale factor: 0.67)

Raw materials and utility costs

Electricity: 99.6 €/MWh [3]

Biomass: 80.1 €/t [4]

District heating 0.027 €/kWh [5,7] Byproduct

Steam (export): 19.8 €/t [6] Byproduct

General economic assumptions:

Year: 2017 Plant lifetime: 30 years

Full load hours: 8,260 h/a Interest rate: 5 %

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 19

[1] G. Saur, Wind-To-Hydrogen Project: Electrolyzer Capital Cost Study, Technical Report NREL, 2008

[2] I. Hannula and E. Kurkela, Liquid transportation fuels via large-scale fluidised-bed gasification of lignocellulosic biomass, VTT, Finland, 2013.

[3] Eurostat, Preise Elektrizität für Industrieabnehmer in Deutschland, 2016

[4] C.A.R.M.E.N. – Preisentwicklung bei Waldhackschnitzel (Energieholz-Index), 2017

[5] Energieeffizienzverband für Wärme, Kälte und KWK e.V., Heizkostenvergleich nach VDI 2067-Musterrechnung, 2014

[6] Own calculations based on natural gas price from Eurostat database 2017

[7] http://www.rogersrawmaterials.com/home.asp (accessed 02/2018)

Example: TEEA of sustainable Jet fuel production

Plant capacity: 550 kt/a (1 % of European jet fuel consumption)

Page 20: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’

-0,6

0,0

0,6

1,2

1,8

2,4

3,0

3,6

4,2

Pro

du

ctio

n c

ost

s in

€/k

g

Electrolyzer

Fischer-Tropsch synthesis

Gasifier

Rest (CAPEX)

Biomass

Electricity

Oxygen

Remaining (Raw materials & Utilities)

Revenue from by-products

Maintenance

Labor costs

Rest (OPEX)

51 % 65 %

Example: TEEA of sustainable Jet fuel production

Plant capacity: 550 kt/a (1 % of European jet fuel consumption) – Base year: 2017

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 20

BtL

1.80 €/kg

PBtL

2.91 €/kg

PtL

3.68 €/kg

• Investment costs: 5.03 billion €

• 2.27 GWth biomass feed required

very long transport distances

GHG-Footprint of

biomass increases

Page 21: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’

-0,6

0,0

0,6

1,2

1,8

2,4

3,0

3,6

4,2

Pro

du

ctio

n c

ost

s in

€/k

g

Electrolyzer

Fischer-Tropsch synthesis

Gasifier

Rest (CAPEX)

Biomass

Electricity

Oxygen

Remaining (Raw materials & Utilities)

Revenue from by-products

Maintenance

Labor costs

Rest (OPEX)

51 % 65 %

Example: TEEA of sustainable Jet fuel production

Plant capacity: 550 kt/a (1 % of European jet fuel consumption) – Base year: 2017

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 21

BtL

1.80 €/kg

PBtL

2.91 €/kg

PtL

3.68 €/kg

• Investment costs: 4.48 billion €

• 1.61 GW electrolyzer required

• Investment costs: 4.35 billion €

• 1.03 GW electrolyzer required

• 0.6 GWth biomass feed

Page 22: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’

Example: TEEA sensitivity of PBtL Plant capacity: 550 kt/a (1 % of European jet fuel consumption) – Base year: 2017

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 22

DLR.de • Folie 3 • TÖB der Erzeugung alternativer Kraftstoffe • R.-U. Dietrich • ProcessNet EVT 2017 • 03.04.2017

105

100

959085807570656055504540353025

20

1.3

1.4

1.5

1.6

1.7

1.8

1.9

2

2.1

2.2

2.3

2.4

2.5

2.6

25,000

77,941

130,882

183,824

236,765

2.5-2.6

2.4-2.5

2.3-2.4

2.2-2.3

2.1-2.2

2-2.1

1.9-2

1.8-1.9

1.7-1.8

1.6-1.7

1.5-1.6

1.4-1.5

1.3-1.4

BtL

PtL

PBtL

EEX

€/lPreferred technology depend on local conditions

Page 23: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’

Alternative jet fuel

Technical evaluation

Ecological evaluation

Economic assessment

DLR’s Techno economic

process evaluation tool

Techno-Economic and ecological assessment (TEEA)

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 23

GHG-footprint

GHG-abatement costs

Page 24: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Example: Fischer-Tropsch Jet fuel GHG-Footprint

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 24

Electricity footprint

CO2 footprint

GHG-footprint of

products

𝐆𝐇𝐆 𝐚𝐛𝐚𝐭𝐞𝐦𝐞𝐧𝐭 𝐜𝐨𝐬𝐭𝐬 €

𝐭𝐂𝐎𝟐𝐞𝐪. =

𝐃𝐢𝐟𝐟𝐞𝐫𝐞𝐧𝐜𝐞 𝐢𝐧 𝐩𝐫𝐨𝐝𝐮𝐜𝐭𝐢𝐨𝐧 𝐜𝐨𝐬𝐭𝐬

𝐆𝐇𝐆 𝐚𝐛𝐚𝐭𝐞𝐦𝐞𝐧𝐭

P&BtX - Concept

• Systemintegration

• Efficiency

• Plant emissions

• Crediting of by-products

(steam, electricity, …)

Biomass footprint

Application

efficiency

Page 25: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Example: Fischer-Tropsch Jet fuel GHG-Footprint

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 25

PtL PBtL BtL

3.68 €/kg 2.91 €/kg 1.80 €/kg

conv. Kerosene

0.63 €/kg 1)

• Calculation of production costs (550 kt/a):

1) U.S. energy information administration (05.09.2018) http://www.eia.gov/dnav/pet/pet_pri_spt_s1_d.htm 2) Eigene Berechnung: CO2-Ausstoß bei der Verbrennung von 1 kg Kerosin Jet-A1 3) Bouvart et al. (2013), „Well-To-Tank" carbon impact of fossil fuels

vs.

Electricity origin PtL PBtL BtL

Electricity mix (VEU-2015 scenario) 13.97 9.11 - 3.59

100 % wind energy - 1.61 - 0.37 - 0.89

vs.

• Calculation of GHG-emissions in kgCO2eq./kgfuel:

conv. Kerosene

3.11 kgCO2eq./kg 2)

+

0.64 kgCO2eq./kg 3) No CO2-reduction

possible

No CO2-reduction

with current German

electricity mix!

𝐆𝐇𝐆 𝐚𝐛𝐚𝐭𝐞𝐦𝐞𝐧𝐭 𝐜𝐨𝐬𝐭𝐬 €

𝐭𝐂𝐎𝟐𝐞𝐪. =

𝐃𝐢𝐟𝐟𝐞𝐫𝐞𝐧𝐜𝐞 𝐢𝐧 𝐩𝐫𝐨𝐝𝐮𝐜𝐭𝐢𝐨𝐧 𝐜𝐨𝐬𝐭𝐬

𝐆𝐇𝐆 𝐚𝐛𝐚𝐭𝐞𝐦𝐞𝐧𝐭

Page 26: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Example: Fischer-Tropsch Jet fuel GHG-Footprint

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 26

Production route: PtL PBtL BtL

Production costs [€/kgkerosene] 3.68 2.91 1.80

Electricity mix (VEU-2015 reg. change) x x 159

100 % wind energy 569 553 252

𝐆𝐇𝐆 𝐚𝐛𝐚𝐭𝐞𝐦𝐞𝐧𝐭 𝐜𝐨𝐬𝐭𝐬 €

𝐭𝐂𝐎𝟐𝐞𝐪. =

𝐃𝐢𝐟𝐟𝐞𝐫𝐞𝐧𝐜𝐞 𝐢𝐧 𝐩𝐫𝐨𝐝𝐮𝐜𝐭𝐢𝐨𝐧 𝐜𝐨𝐬𝐭𝐬

𝐆𝐇𝐆 𝐚𝐛𝐚𝐭𝐞𝐦𝐞𝐧𝐭

Electricity & biomass prices -70 %: 1.45 €/kg 1.29 €/kg 1.00 €/kg

Electricity mix (VEU-2015 reg. change) x x 50

100 % wind energy 152 160 80

• Future feedstock cost reduction?

Page 27: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ TEEA – long term goal

Merit order of GHG abatement

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 27

Option 4

Option 1

Option 3

Option 5

Option 6

CO

2-A

bat

emen

t co

sts

/ €/t

CO

2

CO2-Abatement Amount / tCO2/a

Option 8

Option 9

Option 10 Option 11

Option 2

Electro-Fuel 2

EU instrument to reduce GHG emissions: CO2-certificates

Electro-Fuel 1

Page 28: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ TEEA – long term goal

Merit order of GHG abatement

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 28

Option 4

Option 1

Option 3

Option 5

Option 6

CO

2-A

bat

emen

t co

sts

/ €/t

CO

2

CO2-Abatement Amount / tCO2/a

Option 8

Option 9

Option 10 Option 11

Option 2

Electro-Fuel 2

Goal: CO2 reduction @ minimized GHG-Abatement cost, either by reducing GHG footprint or costs!

Standardized and verified methodology for TEA required!

EU instrument to reduce GHG emissions: CO2-certificates

Electro-Fuel 1

Page 29: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Summary (part 1)

• Renewable fuels are required to achieve the aviation climate change mitigation goals

• “Silver bullet” technology not decided yet

• Large scale Fischer-Tropsch synthesis: highest feedstock flexibility (syngas) and highest technical maturity

Downscale towards renewable power and/or biomass supply?

• GHG abatement cost should be the key decision criterion for any climate change mitigation roadmap

• Transparent and standardized DLR methodology for cost estimation and GHG-footprint offers

a valid starting point for technology assessment and future global transport roadmap

• Renewable kerosene technology development, scale up and market introduction outlook

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 29

Page 30: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN1

www.comsynproject.eu – EU No. 727476

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 30

PRIMARY

CONVERSION

Decentralized FT wax

production at small-to-

medium scale units at

biomass sites

(50-150 MWth input)

+ locally utilized excess

heat for ηtotal > 80 %

PRODUCT

UPGRADING

Centralized FT

product refining to

high quality drop-in

liquid fuels at

existing oil refineries

New decentralized BTL production concept with biofuel production cost reduction up to 35 %

compared to alternative routes (< 1.10 €/kg production cost for diesel)

COMSYN project has received funding from the

European Union’s Horizon 2020 research and

innovation programme under grant agreement No

727476

[1] Special thanks to the contribution of: P. Simell, J. Kihlman, S. Tuomi, E. Kurkela, C. Frilund, V. Kivelä (VTT), T. Böltken, M. Selinsek (INERATEC), H. Balzer (GKN),

J. Hajek (UniCRE), V. Tota (Wood), V. Hankalin (ÅF Consult)

Page 31: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN

Project concept details

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 31

COMSYN project has received funding from the

European Union’s Horizon 2020 research and

innovation programme under grant agreement No

727476

5 m3/h

SLIP-STREAM TO

SYNTHESIS

DFB PILOT @ VTT MOBILE SYNTHESIS UNIT

FILTER DFB

GASIFIER

Product

Upgrading REFORMER ULTRACLEANING STEPS

FISCHER-TROPSCH

SYNTHESIS

Page 32: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN

Project concept details

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 32

COMSYN project has received funding from the

European Union’s Horizon 2020 research and

innovation programme under grant agreement No

727476

5 m3/h

SLIP-STREAM TO

SYNTHESIS

DFB PILOT @ VTT MOBILE SYNTHESIS UNIT

FILTER DFB

GASIFIER

Product

Upgrading REFORMER ULTRACLEANING STEPS

FISCHER-TROPSCH

SYNTHESIS

DFB Gasifier

• Finalized: 2015

• Biomass feed: ca. 50 kg/h

• Gasifier temperature: 750 – 820 °C

• Oxidizer temperature: ca. 900 °C

• Bed material: Dolomite/sand mixture

Page 33: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN

Project concept details

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 33

COMSYN project has received funding from the

European Union’s Horizon 2020 research and

innovation programme under grant agreement No

727476

5 m3/h

SLIP-STREAM TO

SYNTHESIS

DFB PILOT @ VTT MOBILE SYNTHESIS UNIT

FILTER DFB

GASIFIER

Product

Upgrading REFORMER ULTRACLEANING STEPS

FISCHER-TROPSCH

SYNTHESIS

Hot gas filtration

• Intermediate cooling/reheating steps eliminated

• Filtration at high temperature (ca. 800 °C) with

simultaneous decomposition of tars

• Development of catalytically activated filters

using ALD technology

Page 34: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN

Project concept details

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 34

COMSYN project has received funding from the

European Union’s Horizon 2020 research and

innovation programme under grant agreement No

727476

5 m3/h

SLIP-STREAM TO

SYNTHESIS

DFB PILOT @ VTT MOBILE SYNTHESIS UNIT

FILTER DFB

GASIFIER

Product

Upgrading REFORMER ULTRACLEANING STEPS

FISCHER-TROPSCH

SYNTHESIS

Catalytic reforming

• Development of an oxygen-permeable membrane

reactor to enable better control of reaction temperature

in the reformer (hot spots)

• Catalyst development: ALD coating to increase the

activity as well as sulphur and coke tolerance of the

catalyst

Page 35: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN

Project concept details

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 35

COMSYN project has received funding from the

European Union’s Horizon 2020 research and

innovation programme under grant agreement No

727476

5 m3/h

SLIP-STREAM TO

SYNTHESIS

DFB PILOT @ VTT MOBILE SYNTHESIS UNIT

FILTER DFB

GASIFIER

Product

Upgrading REFORMER ULTRACLEANING STEPS

FISCHER-TROPSCH

SYNTHESIS

Ultracleaning concept:

• Specifically for biomass-based gasification gas, thus considers:

• Low to medium sulphur content

• Residual hydrocarbons (tars)

• Wet scrubbing acid gas process (Rectisol, Selexol) replaced by:

• Simpler dry bed desulphurization

• No removal of CO2 or partial CO2 removal in simple

pressure water scrubbing to 5 vol-% content

Page 36: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN

Project concept details

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 36

COMSYN project has received funding from the

European Union’s Horizon 2020 research and

innovation programme under grant agreement No

727476

5 m3/h

SLIP-STREAM TO

SYNTHESIS

DFB PILOT @ VTT MOBILE SYNTHESIS UNIT

FILTER DFB

GASIFIER

Product

Upgrading REFORMER ULTRACLEANING STEPS

FISCHER-TROPSCH

SYNTHESIS

Fischer-Tropsch microreactor:

• Compact and modular design

• High efficiencies

• Load flexible

Page 37: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN

Project concept details

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 37

COMSYN project has received funding from the

European Union’s Horizon 2020 research and

innovation programme under grant agreement No

727476

5 m3/h

SLIP-STREAM TO

SYNTHESIS

DFB PILOT @ VTT MOBILE SYNTHESIS UNIT

FILTER DFB

GASIFIER

Product

Upgrading REFORMER ULTRACLEANING STEPS

FISCHER-TROPSCH

SYNTHESIS

Product upgrading

• Co-processesing of FT-waxes or

• Stand-alone treatment

(incl. a new hydroisomerisation unit)

Page 38: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Decentralized Approach: EU project COMSYN

Project concept details

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 38

COMSYN project has received funding from the

European Union’s Horizon 2020 research and

innovation programme under grant agreement No

727476

5 m3/h

SLIP-STREAM TO

SYNTHESIS

DFB PILOT @ VTT MOBILE SYNTHESIS UNIT

FILTER DFB

GASIFIER

Product

Upgrading REFORMER ULTRACLEANING STEPS

FISCHER-TROPSCH

SYNTHESIS

Hot gas filtration

• Intermediate cooling/reheating steps eliminated

• Filtration at high temperature (ca. 800 °C) with

simultaneous decomposition of tars

• Development of catalytically activated filters

using ALD technology

Catalytic reforming

• Development of an oxygen-permeable membrane

reactor to enable better control of reaction temperature

in the reformer (hot spots)

• Catalyst development: ALD coating to increase the

activity as well as sulphur and coke tolerance of the

catalyst

Ultracleaning concept:

• Specifically for biomass-based gasification gas, thus considers:

• Low to medium sulphur content

• Residual hydrocarbons (tars)

• Wet scrubbing acid gas process (Rectisol, Selexol) replaced by:

• Simpler dry bed desulphurization

• No removal of CO2 or partial CO2 removal in simple

pressure water scrubbing to 5 vol-% content

DFB Gasifier

• Finalized: 2015

• Biomass feed: ca. 50 kg/h

• Gasifier temperature: 750 – 820 °C

• Oxidizer temperature: ca. 900 °C

• Bed material: Dolomite/sand mixture

Fischer-Tropsch microreactor*:

• Compact and modular design

• High efficiencies

• Load flexible

Product upgrading

• Co-processesing of FT-waxes or

• Stand-alone treatment

(incl. a new hydroisomerisation unit)

Open Questions / Development Tasks

Within COMSYN: • Technical Validation • Fuel Flexibility • Techno-economic assessments • Ecological impact • Business cases for different

European regions

Beyond COMSYN: • No. of European sites for

decentralized fuels production • Logistic to interconnect

multiple decentralized sites • Mass manufacturing of

decentralized fuel plants

Validation of decentralized sustainable fuel production for large scale decarbonization of aviation!

Page 39: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ DLR contribution to renewable kerosene research

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 39

Fuel usage

Separation

CO2-Source

Reverse water - gas - shift reactor

Fischer - Tropsch s ynth e s is

Syncrude

Tail gas processing

External Recycle

Refinery

Tail gas

Gasoline Jet fuel Diesel

Intern al Recycle

H2

Electrolysis (Renewable)

Power

H2O

H2

Product separation

CO2

Industry delivery

Industry delivery

Comprehensive assessment (TEEA)

Gas Cleaning

Gas Cleaning

Biomass Gasification

Biomass-Source

Industry delivery

Power grid, feedstock supply

Refinery expertise required

Page 40: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’ Outlook

• Renewable aviation fuels development requires strong refinery commitment

• European GHG abatement will change global fossil energy market leading countries, other stakeholders?

• Upcoming CO2 regulation will need techno economic guidance GHG abatement costs

• DLR supports every promising technology towards renewable aviation HORIZON 2020 calls available

• Technology demonstration not sufficient for future renewable aviation market introduction

• Find a serious response to ensure next generations living conditions – now!

• Challenges & opportunities for sustainable aviation • Ralph-Uwe Dietrich et. al • 18 & 19 March 2019, Antwerp, Belgium DLR.de • Chart 40

Page 41: Challenges & opportunities for sustainable aviation ...€¦ · Aviation Industry Response: IATA Technology Roadmap [1] DLR.de • Chart 5 • Challenges & opportunities for sustainable

13th Concawe Symposium 2019, Antwerp Session 3: ’’Low-carbon pathways & Refining Technologies (I)’’

Ralph-Uwe Dietrich [email protected]

German Aerospace Center / Deutsches Zentrum für Luft- und Raumfahrt e.V. (DLR)

Institute of Engineering Thermodynamics

Research Area Manager Alternative Fuels

Thank you for your attention!


Recommended