Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-1
Chapter 7 – Additional Studies
7.1 Public Hearing
Public Consultation refers to the process by which the concerns of locals likely to be
affected/all the stakeholders who have plausible stake in the environmental impacts due to the
project activity are ascertained with a view to taking into account all the material concerns in
the proposed project or activity design as appropriate. M/s. Pest Control India Pvt. Ltd. will
execute the proposed project activity at their existing premises located at plot 38 & 39, Taloja
MIDC, Raigad, Maharashtra, India. Now since the unit has been located in Notified MIDC
area, as per the OM No. J-11013/36/2014-IA-I dated 10th December 2014 public hearing is
exempted for the industries which are located in industrial estate or parks notified prior to
14.09.2006 i.e. the EIA Notification 2006 coming into force.
7.2 Risk Assessment
Risk assessment is an essential part of the risk management process and is the overall term
covering the risk identification, analysis and risk evaluation part of the risk management
process. The Risk management process involves the following steps,
1. System Definition
2. Risk Identification
3. Risk Estimation
4. Risk Evaluation
5. Risk Control
6. Risk Monitoring
7. Risk Communication
As indicated in the earlier chapter the company proposed to manufacture Bromodilone
Technical & formulation of Ethylene oxide. The manufacturing activity poses various types
of hazards due to storage, handling and manipulation of different chemicals.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-2
In order to study the risks envisaged by the proposed activities, the following methodology
was adopted.
Detailed study of all manufacturing activities
7.2.1 M.S.D.S.s
Brief M.S.D.S.s of all the chemicals and other raw materials which would be used in the
manufacturing processes of products are used as reference for preparation of HAZOP study.
7.3 HAZOP Study
Introduction
The HAZOP Study for has been prepared considering all the unit operations and processes
involved in the manufacturing of products.
Methodology
The site visit was conducted at the factory in the month of September 2016. The laboratory
scale R&D set up was seen at the site. The documents pertaining to the processes such as
rough process flow diagram and process description of stage wise manufacturing process
made available by the client, MSDS of the substances involved, etc. were made available.
Detailed discussions were held with the concerned officials of the factory regarding the
process.
Based on the above HAZOP worksheets were prepared by applying standard procedures of
using guide words to generate deviations in the process parameters. Corrective actions
wherever necessary were indicated. Based on the above, HAZOP worksheets were prepared
by applying standard procedures of using guide words to generate deviations in the process
parameters. Corrective actions wherever necessary were indicated and presented below as
HAZOP recommendations. The complete HAZOP report is attached as annexure 7.1.
Table No.7.1: HAZOP Study Recommendations
Sr. No. Recommendation
01 Spill control kit to be provided and spill control procedure to be developed
02 Regular calibration of the temperature indicator to be ensued
03 Temperature controller to be provided on the bromine addition line so that if
the temperature goes beyond 20 deg. c., the addition should stop
04 Orifice plate (calibrated) to be provided in the bromine addition line.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-3
05 Provide two valves in the bromine addition line.
06 Procedure to be developed for periodic checking of the integrity of the glass
lining.
07 To provide protective paint on the glass flask so as to ensure that splinters of
glass flask do not take place in case of breakage of the same.
08 Glass flask to be provided with wire mesh protection
09 To obtain a certificate from the suppler of the glass flask to confirm that it
can withstand full vacuum.
10 Scrubber working to be ensured before starting the batch.
11 The reactor is adequately inertised by nitrogen purging to prevent fire and
explosion.
12 The inertisation procedure to be defined and validated
13 Ensure slow addition of dry powder with the help of an earthed SS scoop.
14 The addition of borohydride should be done through glove box
7.4 Aerial Location of Hazardous Atmosphere (ALOHA):
A Quantitative Risk Assessment based on the software ALOHA – Aerial Locations of
Hazardous Atmospheres was carried out. The criteria failure scenarios considered for
ALOHA depend on the type of storage whether above ground tank, drums in storage area or
pressurized cylinders as well as physical state of the chemical stored and chemical properties
of the chemical.
ALOHA (Arial Locations of Hazards Atmosphere) is an atmospheric dispersion
model used for evaluating releases of hazardous chemical vapors. ALOHA is a part of
software called CAMEO (Computer Aided Management of Emergency Operation). CAMEO
is one of the tools developed by EPA‘s Chemical Emergency Preparedness and Prevention
Office (CEPPO) and the National Oceanic and Atmospheric Administration Office of
Response and Restoration (NOAA), to assist front-line chemical emergency planners and
responders. For the present calculation version 5.4.4 is used.
CAMEO suite consists of three parts viz.
1. CAMEO: It is basically a chemical data base provided for calculations.
2. ALOHA: ALOHA allows the user to estimate the downwind dispersion of a chemical
cloud based on the toxicological/physical characteristics of the released chemical,
atmospheric conditions, and specific circumstances of the release.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-4
3. MARPLOT (Mapping Applications for Response, Planning, and Local Operational
Tasks): Graphical outputs include a "cloud footprint" that can be plotted on maps with
MARPLOT to display the location of other facilities storing hazardous materials and
vulnerable locations, such as hospitals and schools. Specific information about these
locations can be extracted from CAMEO information modules to help make decisions
about the degree of hazard posed.
Acute Exposure Guideline Levels (AEGL):
Figure No. 7.1: Description of AEGL levels
THERMAL RADITION EFFECTS:
A Thermal Radiation Level of Concern (LOC) is a threshold level of thermal radiation,
usually the level above which a hazard may exist.
10 kW/(sq m) -- potentially lethal within 60 sec;
5 kW/(sq m) -- second-degree burns within 60 sec; and
2 kW/(sq m) -- pain within 60 sec.
Below are some effects at specific thermal radiation levels for which software was run.
37.5 kw / m2 (100% lethality),
12.5 kw/m2 (1% lethality),
1.6 kw/m2 (no discomfort)
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-5
The thermal radiation effects that people experience depend upon the length of time they are
exposed to a specific thermal radiation level. Longer exposure durations, even at a lower
thermal radiation level, can produce serious physiological effects.
OVERPRESSURE EFFECTS:
A major hazard associated with any explosion is overpressure. Overpressure, also called a
blast wave, refers to the sudden onset of a pressure wave after an explosion. This pressure
wave is caused by the energy released in the initial explosion—the bigger the initial
explosion, the more damaging the pressure wave. Blast waves can damage buildings or even
knock them flat—often injuring or killing the people inside them. The sudden change in
pressure can also affect pressure-sensitive organs like the ears and lungs. The damaging
effects of the overpressure will be greatest near the source of the explosion and lessen as you
move farther from the source.
An Overpressure Level of Concern (LOC) is a threshold level of pressure from a blast wave,
usually the pressure above which a hazard may exist. In vapour cloud explosion scenario,
ALOHA will suggest three default LOC values. ALOHA uses three threshold values to create
the default threat zones:
• Red: 8.0 psi (destruction of buildings);
• Orange: 3.5 psi (serious injury likely); and
• Yellow: 1.0 psi (shatters glass).
ALOHA software is used to estimate the risk associated with release of pressurized gases.
Following table represent the list of chemicals with their storage quantity for which aloha is
performed.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-6
Table No 7.2: Chemical Storage Details for which ALOHA is performed
Sr.
No
Name of Chemicals Maximum Storage
Quantity at any given
time
Dyke Details
1 Methanol 200 kg X 10 Drums Yes
1.5m X 1.5m X 1.0m = 2.25 M3
2 Iso Propyl Alcohol 200 kg X 9 Drums Yes
1.5m X 1.5m X 1.0m = 2.25 M3
3 Acetone 200 Kg X 2 Drums --
4 Acetyl Chloride 30 Lit X 1 Carboy --
5 Acetic Acid 30 Lit X 1 Carboy --
6 Toulene 200 kg X 4 Drums --
7 Bromine 3 kg X 4 Bottle --
8 1,4-Dioxane 200 kg X 8 Drums Yes
1.5m X 1.5m X 1.0m = 2.25 M3
9 Ethylene Dichloride 200 kg X 15 Drums Yes
1.9m X 1.8m X 1.0m = 3.42 M3
10 Ethylene Oxide 35 Kg X 5 Cylinders --
The summary of ALOHA for different scenarios for above chemicals attached in Annexure
7.2. ALOHA footprints for different hazard scenarios are presented in table 7.3
Substance Scenario. Effects
considered
LOC Distance,
m
Methanol Evaporating
Puddle of
Flammable
Chemical
Toxic area of
vapor cloud
AEGL-3 7200 ppm Less than 10
meters
AEGL -2 2100 ppm Less than 10
meters
AEGL -1 530 ppm 18
Flammable area
of vapour cloud
43080 ppm =
60% LEL
Less than 10
meters
7180ppm =
10% LEL
Less than 10
meters
Blast area of
vapour cloud
explosion
- - No
Explosion
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-7
Burning Puddle
of Flammable
Chemical
Thermal
Radiation from
Pool Fire
10.0
kW/(sq m)
potentially
lethal within
60 sec
Less than 10
meters
5.0 kW/(sq
m)
2nd degree
burns within
60 sec
Less than 10
meters
2.0 kW/(sq
m)
pain within
60 sec
Less than 10
meters
Iso Propyl
Alcohol
Evaporating
Puddle of
Flammable
Chemical
Toxic area of
vapor cloud
PAC-3 12000 ppm Less than 10
meters
PAC -2 400 ppm Less than 10
meters
PAC -1 400 ppm Less than 10
meters
Flammable area
of vapor cloud
60% LEL 12000 ppm Less than 10
meters
10% LEL 2000 ppm Less than 10
meters
Blast area of
vapour cloud
explosion
- - No
Explosion
Burning Puddle
of Flammable
Chemical
Thermal
Radiation from
pool fire
10.0
kW/(sq m)
potentially
lethal within
60 sec
Less than 10
meters
5.0 kW/(sq
m)
2nd degree
burns within
60 sec
Less than 10
meters
2.0 kW/(sq
m)
pain within
60 sec
Less than 10
meters
Acetone Spill of entire
chemical
present in single
drum
Toxic area of
vapor cloud
AEGL-3 5700 ppm 94
AEGL-2 3200 ppm 132
AEGL-1 200 ppm 544
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-8
Flammable area
of vapor cloud
60% LEL 15600 ppm 52
10% LEL 2600 ppm 148
Blast area of
vapour cloud
explosion
Destructio
n of
building
8.0 psi LOC never
exceeded
Serious
injury
likely
3.5 psi LOC never
exceeded
Shatter
glass
1.0 psi LOC never
exceeded
Acetyl
Chloride
Spill of entire
chemical
present in single
carboy
Toxic area of
vapor cloud
PAC-3 56 ppm 434
PAC-2 9.4 ppm 1.0 km
PAC-1 0.85 ppm 2.9 km
Flammable area
of vapor cloud
60% LEL 43800 ppm 11
10% LEL 7300 ppm 28
Blast area of
vapour cloud
explosion
Destructio
n of
building
8.0 psi LOC never
exceeded
Serious
injury
likely
3.5 psi LOC never
exceeded
Shatter
glass
1.0 psi LOC never
exceeded
Acetic Acid Spill of entire
chemical
present in single
carboy
Toxic area of
vapor cloud
ERPG-3 250 ppm 230
ERPG-2 35 ppm 640
ERPG-1 5 ppm 1.6 km
Flammable area 60% LEL 24000 ppm 15
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-9
of vapor cloud
10% LEL 4000 ppm 45
Blast area of
vapour cloud
explosion
Destructio
n of
building
8.0 psi LOC never
exceeded
Serious
injury
likely
3.5 psi LOC never
exceeded
Shatter
glass
1.0 psi LOC never
exceeded
Toluene Spill of entire
chemical
present in single
Drum
Toxic area of
vapor cloud
AEGL-3 3700 ppm 93
AEGL-2 560 ppm 253
AEGL-1 67 ppm 673
Flammable area
of vapor cloud
60% LEL 6600 ppm 67
10% LEL 1100 ppm 180
Blast area of
vapour cloud
explosion
Destructio
n of
building
8.0 psi LOC never
exceeded
Serious
injury
likely
3.5 psi LOC never
exceeded
Shatter
glass
1.0 psi LOC never
exceeded
Bromine Spill of entire
chemical
present in single
bottle
Heavy Gas AEGL-3 8.5 ppm 312
AEGL-2 0.24 ppm 1.5 km
AEGL-1 0.033 ppm 3.2 km
1,4 Dioxane Evaporating
Puddle of
Flammable
Toxic area of
vapor cloud
- 215000 ppm Less than 10
meters
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-10
Chemical
- 21000 ppm Less than 10
meters
Flammable area
of vapour cloud
12600 ppm =
60% LEL
Less than 10
meters
2100 ppm =
10% LEL
Less than 10
meters
Blast area of
vapour cloud
explosion
- - No
Explosion
Burning Puddle
of Flammable
Chemical
Thermal
Radiation from
Pool Fire
10.0
kW/(sq m)
potentially
lethal within
60 sec
Less than 10
meters
5.0 kW/(sq
m)
2nd degree
burns within
60 sec
Less than 10
meters
2.0 kW/(sq
m)
pain within
60 sec
Less than 10
meters
Ethylene
Dichloride
Evaporating
Puddle of
Flammable
Chemical
Toxic area of
vapor cloud
EPRG-3 300 ppm 20
EPRG-2 200 ppm 27
EPRG-1 50 ppm 58
Flammable area
of vapour cloud
27000 ppm =
60% LEL
Less than 10
meters
4500 ppm =
10% LEL
Less than 10
meters
Blast area of
vapour cloud
explosion
- - No
Explosion
Burning Puddle
of Flammable
Thermal
Radiation from
10.0
kW/(sq m)
potentially
lethal within
Less than 10
meters
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-11
Chemical Pool Fire 60 sec
5.0 kW/(sq
m)
2nd degree
burns within
60 sec
Less than 10
meters
2.0 kW/(sq
m)
pain within
60 sec
Less than 10
meters
Ethylene
Oxide
Direct –
Leakage in
storage cylinder
Heavy Gas AEGL-3 200 ppm 350
AEGL-1 45 ppm 744
AEGL-1 Not
recommende
d
-
Flammable area
of vapor cloud
18000 ppm =
60% LEL
22
3000 ppm =
10% LEL
68
Blast area of
vapour cloud
explosion
Destructio
n of
building
8.0 psi LOC never
exceeded
Serious
injury
likely
3.5 psi LOC never
exceeded
Shatter
glass
1.0 psi 20
Leaking Tank,
Chemical is not
Burning as it
escape into
atmosphere
Heavy Gas AEGL-3 200 ppm 255
AEGL-1 45 ppm 514
AEGL-1 Not
recommende
d
-
Flammable area
of vapor cloud
18000 ppm =
60% LEL
23
3000 ppm =
10% LEL
59
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-12
Blast area of
vapour cloud
explosion
Destructio
n of
building
8.0 psi LOC never
exceeded
Serious
injury
likely
3.5 psi LOC never
exceeded
Shatter
glass
1.0 psi 29
Leaking Tank,
Chemical is not
Burning as it
escape into
atmosphere
Thermal
radiation from
jet fire
10.0
kW/(sq m)
potentially
lethal within
60 sec
10
5.0 kW/(sq
m)
2nd degree
burns within
60 sec
10
2.0 kW/(sq
m)
pain within
60 sec
20
BLEVE of
flammable
liquid in vertical
cylinder tank
Thermal
radiation from
fireball
10.0
kW/(sq m)
potentially
lethal within
60 sec
36
5.0 kW/(sq
m)
2nd degree
burns within
60 sec
51
2.0 kW/(sq
m)
pain within
60 sec
80
General Recommendations for Solvents (Flammable Liquids) Storage:
i) Dedicated storage area to be provided.
ii) Keep containers tightly closed/sealed until ready for use.
iii) Keep containers in cooled and ventilated area.
iv) Avoid all possible source of ignition.
v) Keep away from heat and their sources.
vi) Use suitable PPE during handling of chemicals.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-13
vii) Storage area should be away from incompatibilities such as oxidizing agents,
metals & acid.
viii) Avoid direct contact with body.
ix) Chemical spill kit to be maintained to avoid possible effects from spillage.
x) Chemical transfer line should be periodically inspected and well maintained to
avoid possibility for leakage of chemical.
xi) Periodic inspection of dykes to be done.
General Recommendations for Bromine (Corrosive/Poisonous Liquid) Storage:
i) Dedicated storage area to be provided.
ii) Store away from the combustible materials.
iii) Appropriate PPEs to be used during handling of solutions / chemicals.
iv) Keep containers in tightly closed and in cool, dry and well ventilated area.
v) Keep in proper storage cabinets and shelving. Use lowest shelve possibly.
vi) Assure all bottles are properly labeled.
vii) Bromine gas detector should be installed.
viii) Proper precautions to be taken during chemical preparation.
ix) Wearing PPEs, Laboratory work surface should be cleaned at the end of each
working day.
x) Dispose of contaminated material in accordance with hazardous waste
disposal guidelines.
xi) Decontaminate all the equipments before removing from designated area.
xii) Never work alone with bromine, make sure there is another worker present
who is trained for bromine handling.
7.5 DOW Fire and Explosion Index
The DOW index is performed for all flammable chemicals which is to be stored in raw
material storage building for proposed activity. Details of DOW index is given in table
below,
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-14
Table No. 7.4: List of hazardous chemicals and its respective DOW F& E Index
Sr.
No
Name of
Chemical
Qty. at any
given time in
MT
Nh Nf Nr Material
Factor
Fire &
Explosion
Index
Degree
of
Hazards
1 Acetone 0.4 1 3 0 16 54.89 Light
2 Acetyl
Chloride
0.03 3 3 2 24 90.24 Moderate
3 Acetic Acid 0.03 3 2 0 14 41.65 Light
4 Benzaldehyde 0.06 2 2 0 10 26.25 Light
5 Toulene 0.8 2 3 0 16 56.4 Light
6 1,4-Dioxane 1.6 2 3 1 16 56.4 Light
7 Ethylene di
Chloride
3.0 2 3 0 16 56.4 Light
8 Iso Propyl
Alcohol
1.8 1 3 0 16 48.8 Light
9 Methanol 2.0 1 3 0 16 48.8 Light
10 Petroleum
Ether
0.8 1 4 0 21 64.15 Moderate
The DOW Index work sheet and the respective storages and recommendations for all storages
are attached as Annexure - 7.3.
7.6 Toxicity (Monds) Index
Introduction
The principle and general approach used in the DOW method of hazard evaluation have been
further developed by ICI Mond Division, the revised Mond Fire, Explosive and Toxicity
index is a series of papers by Lewis (1979). The main developments made to the DOW Index
in the Mond Index are:
1. It covers a wider range of process and storage installation
2. It covers the processing of chemicals with explosive properties
3. A calculation procedure is included to allow for the off-setting effects of good design and
control and safety instrumentation
4. The procedure has been extended to cover plant layout
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-15
5. Separate indices are calculated to access the hazards of fire, internal explosion and aerial
explosion.
To estimate the Monds Index for raw materials in storage area following,
All the raw materials stored in the industry premises are tabulated and data for their N (H)
levels and TLV levels are obtained. Based on their highest toxicity factor and lowest TLV
level Mond‘s Index was calculated for Acetic Acid, Bromine, Biphenyl, Hydrochloric Acid,
Piperidine, Sodium methoxide for drum/bag storages. Detailed methodology of Toxicity
Index and the toxicity index calculations are given in Annexure - 7.4.
Table 7.6 explains the toxicity index and degree of hazard associated with respective raw
material.
Table No. 7.5: Monds Toxicity index of toxic chemicals
Sr.
No
Raw Materials Qty. at any
given time in
MT
Flash
Point
in 0C
UN Classification Health
Hazard
TLV in
ppm
1 Acetic Acid 0.03 39 CLASS 3: Flammable
liquid. Class 8:
Corrosive material
3 10
2 Benzaldehyde 0.06 64.4 CLASS 3:
Combustible liquid
2 --
3 Bromine 0.10 - Class 8: Corrosive
material CLASS 6.1:
Poisonous material.
3 0.1
4 Biphenyl 0.15 112.8 - 2 1.3
5 Hydrochloric
Acid
1.5 - Class 8: Corrosive
material
2 5
6 Peperidine 0.01 16.1 Class 3: Flammable
liquid
3 1
7 Sodium
Thiosulfate
0.01 - - 2 --
8 Sodium
Methoxide
0.05 33 CLASS 4.2:
Spontaneously
combustible substance.
Class 8: Corrosive
material
3 10
9 Sodium
Borohydride
0.02 - CLASS 4.3: Material
that emits flammable
gases on contact with
3 --
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-16
water.
Table no. 7.6: Calculated Mond’s Index and degree of Hazard for Hazardous chemicals.
Sr.
No.
Raw Materials Th (Toxicity
factor)
Ts (
Correction
factor)
Mond’s
Index
Degree of
hazard
1. Acetic Acid 250 75 5.83 Moderate
2. Bromine 250 125 7.75 Moderate
3. Biphenyl 125 125 6.56 Moderate
4. Hydrochloric
Acid
250 125 7.75 Moderate
5. Peperidine 250 125 8.81 Moderate
6. Sodium
Methoxide
250 75 5.83 Moderate
Toxicity (Mond) Index recommendations:
1. Toxic material should be stored in cool place. It should be away from heat and
temperature.
2. Toxic material can cause breathing difficulty therefore storage area should be well
ventilated.
3. Spill kit should be provided for storage to limit the spill of materials. Suitable Absorbent
like sodium bi carbonate should be used to absorb the spill.
4. The storage area should not be congested and good housekeeping practice should be
implemented.
5. The chemicals should be stored considering their compatibility with each other.
6. PPE‘s should be used wherever necessary.
7.7 DISASTER MANAGEMENT PLAN
Objectives of Disaster Management Plan [DMP]
The Disaster Management Plan (DMP) is aimed to ensure safety of life, protection of
environment, protection of installation, restoration of production and salvage operations in
the same order of priorities. For effective implementation of the DMP, it should be widely
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-17
circulated and personnel training through rehearsals/drills should be organized. Further, the
management should be able to demonstrate that its assessment of the consequences as good
supporting evidence. To tackle the consequences of a major emergency inside the factory or
immediate vicinity of the factory, a DMP has to be formulated and this planned emergency
document is called "Disaster Management Plan". The objective of the Industrial Disaster
Management Plan is to make use of the combined resources of the plant and the outside
services to achieve the following:
Effect the rescue and medical treatment of causalities
Safeguard other people
Minimize damage to property and the environment
Initially control and ultimately bring the incident under control
Identify any casualties
Provide authoritative information to the news media
Secure the safe rehabilitation of affected area
Preserve relevant records and equipment for the subsequent inquiry into the cause and
circumstances of the emergency. In effect, it is to optimize operational efficiency to
rescue rehabilitation and render medical help and to restore normalcy.
7.8. Onsite Emergency Plan
The Onsite emergency plan is prepared based on the guidelines mentioned under schedule 6
of the rule 12 (1) of the Maharashtra factories (Control of industrial Major Accidents
Hazards) Rules 2003.
On-Site emergency preparedness plan has the following objectives:
1. Safeguard lives and property at site and in its vicinity area.
2. Contain the incident and bring it under control;
3. Minimize damage to lives, property and environment;
4. Rescue and treat casualties;
5. To train the people to act efficiently and with confidence in an emergency.
6. Evacuate people to safe areas;
7. To minimize its occurrence.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-18
7.8.1. Name & Address of the person furnishing the Information.
Name: Mr. Vilas Andhere
Designation: Factory Manager
Address: Plot No. 38 & 39, MIDC Taloja, District - Raigad, Maharashtra
7.8.1. Key personnel of the organization and responsibility assigned to them in case of
an emergency.
Key Persons in the
Emergency Plan
Mr. Vilas Andhere
Designation - ( Site Main Controller)
Mr. Raghu Kothary
Designation- (Site Incident Controller)
Mr. Mandar Shedge
Designation-( EHS Team Head)
Mr. G. Rao
Designation-( Production Manager)
7.8.1.1. Site Main Controller
During the onsite emergency situation the Site Main Controller shall,
Activate the Emergency Control Centre & personnel
Relieve the Site Incident Controller of overall responsibility during off shift hours
Take stock of situation with SIC & direct operations to control the emergency.
Ensure that all the key persons are called on site. Delegate any extra duty to any
person depending upon the situation and his judgment.
Verify the head count & arrange for search / rescue
Instruct for shutting & evacuation if required.
Seek assistance from external agencies & Mutual aid
Withdraw the staff in case of the human life is in peril.
Liaison with statutory authorities
Arrange to call the experts/ the supplier.
Give All Clear siren when everything becomes normal.
Works as liaison officer between outside fire brigade & police advice on specialized
technical aspects of the materials involved and internal details of the factory.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-19
Report the event to the nearest district police station, fire brigade, civil defense force,
district emergency officer, factory Inspectorate and other voluntary body to assist to
the task.
M/s Pest Control India Pvt. Ltd. will establish an Emergency Control Centre at the cabin of
the Site Main Controller (Factory Manager). It will have external telephone, telefax and telex
facility & contact number of the Incident Controller Officer, Senior Personnel etc.
7.8.1.2. Site Incident Controller
Assume the responsibility of the Site Main Controller till the arrival of the site main
controller.
Brief the Site Main Controller on arrival - during off shift hours.
Be over all in charge of the emergency situation and head of fire fighting team.
Arrive immediately to the site of emergency and issue instructions for speedy combat.
On arrival immediately assess the scale of emergency and decide if a major
emergency exists or is likely.
Report head count to Site Main Controller.
Activate the security head to report the emergency to Site Main Controller.
Activate the Onsite action plan depending on the type of emergency.
Direct all operations and call the external help from emergency control center.
Search for the injured and / or casualties.
Direct the shutdown and evacuation of the plant. Identify the areas likely to be
affected by the emergency.
Provide information to emergency services about the chemicals / incident
7.8.1.3. EHS Team.
In addition to his general duties of maintaining order of administration he shall discharge
following duties:
Execute all directions and instruction of site main controller regarding.
Calling mutual aid members.
Specialist from the supplying company.
Lead the fire fighting & rescue operations
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-20
For efficient and successful operation of the plan statutory agencies listed below should be
actively involved for guidance and help: -
o Fire Brigade
o Police Authorities
o Collectorate / revenue officials
o Directorate of Industrial Safety and Health
o Maharashtra Pollution Control Board.
o District Health Authorities
o Non Government organization
o Local News Media.
o Local Leaders
Supervise the duties of Security Personnel.
Supervise rescue & medical operations
If injuries and casualties does occur then he shall obtain names and addresses of the
injured and dead.
Arrange for the medical aid. Talk to the hospital and doctors. Report about the type of
injury / burn injuries and or toxic effects.
Report to the hospital and make arrangement for likely more cases of injuries.
In consultation with the site main controller he shall identify the antidote or any
special medical procedure and report the same to hospitals.
7.8.1.4. Production Manager & Team
A. (In affected Plant Area)
Inform EHS Manager / Factory Manager / Plant / Dept Manager or his nominee / Site
Main Controller on the telephone immediately.
Assume the role of Site Incident Controller till his arrival.
Direct employees / contractor's workers / visitors at the assembly point.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-21
Take head count of employees.
Deploy trained Emergency Response Team & direct.
Hold personnel at the Assembly point till ‗All Clear‘ signal is obtained.
Act as per instructions from Site Incident Controller / Site Main Controller.
Open plant drain valves to FWRB
Provide information to external agency about the chemical involved to control
emergency/ treating injured employees.
B. (Non –affected Plant Area)
Ensure that all employees including contractor‘s workers / visitors assemble at the
Assembly Point and take roll call of employees.
Take Head Count & report to SMC at ECC
Switch off all critical operations.
Be Alert for evacuation & evacuate on instructions from SMC
Keep ready - Emergency Response Team members
Provide necessary information and support to affected dept/plant to control
emergency.
Hold personnel at Assembly Point till ‗All Clear‖ siren is raised
7.8.1.5. Security Personnel
In addition to the normal duties of maintaining security at the place of work they shall
discharge following duties:
On hearing the fire alarm, proceed to the incident immediately.
Be in charge of Fire Fighting and rescue operations with the assistance of essential
workers and key personnel till the arrival of Fire Brigade and Police. (These
operations shall be under the direct supervision of Site Incident Controller)
Ask the ambulance to proceed to the scene of the incident in case of serious injury.
Remove obstruction from the road to help Fire brigade to proceed to the scene of fire.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-22
Restrict entry of unauthorized and untrained persons from the scene of incident. Also
don't allow unauthorized persons / vehicles to enter the premises. Control traffic
movement for smooth & normal flow.
Initiate rescue operation if required.
Call for fire brigade & ambulance during off hours
Depending on seriousness arrange to inform police personnel if instructed by Factory
Manager.
7.8.1.6. General Instructions and Response during the Onsite Emergency Situation
1. Major Fire/ Explosion
Operate the nearest fire alarm or alert the personnel by raising an audible alarm or by
shouting Fire!, Fire!!‖
Inform the Manager Production / Shift Supervisor available who is in charge of the
factory at that time about the
Place of Fire / Explosion
Extent of Fire fighting Action taken by him
The material involved
No. of persons affected.
Try to extinguish the fire with the help of fire extinguishers, if without risk. If he is
unable to extinguish the fire, he should see that the fire does not spread to nearby area.
2. Collapse of structure/ Serious Injury
Inform the Manager Production / Supervisor etc.
Remove the injured person to a safe place. Take help of trained first-aiders.
3. Release of toxic and hazardous material
Inform the Manager Production / Supervisor or person available who is in-charge of the
factory at that time about the
Place of Gas leak
Extent of leakage
Action taken by him
The material involved
No. of persons affected.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-23
EMERGENCY DO ‘S DON 'TS DO ‘S
ANY ONE NOTICING AN
EMERGENCY : Actuate nearest fire alarm button and /or
inform the supervisor. Get back to your
normal workstation (if safe) or else report to
the assembly point.
DO NOT panic and avoid running all over
the place prevent others from doing so.
DO NOT enter the site unless instructed if
you are out side and emergency alarm is
heard.
CONTRACTOR PERSONNEL : Stop work on hearing alarm and assemble at
the ASSEMBLY POINT and be ready to
evacuate.
DO NOT enter the site until it is cleared for
the normal work by Incident Controller.
SECURITY : Keep the gate manned.
Keep the road clear for movement of fire
tenders.
Control traffic at gates.
DO NOT allow unauthorized visitors to
enter.
VISITORS : Leave the place and assemble at assembly
point.
DO NOT enter the site if emergency alarm is
heard.
ALL OTHER EMPLOYEES ON SITE : On hearing Emergency alarm
Get back to work place (if safe) for head
count and get instructions from supervisor.
Be alert.
DO NOT panic/run
DO NOT go to the scene of emergency
unless specifically instructed by Incident
Controller.
7.8.2. Establishment of the Safety Committee
M/s Pest Control India Pvt. Ltd would be having around 50 Nos. of employees during the
proposed activity. Since the company deals with the dangerous operations as mentioned in
the section 87 of the Factories Act 1948, it is mandatory for the company to establish an
safety committee. The safety committee shall include a senior official, safety officer and
representatives of workers & each department. The tenure of the safety committee would be
for 2 years. The Roles and responsibility of the safety committee is listed below,
(a) Assisting and co-operating with the management in achieving the aims and objectives
outlined in the 'Health and Safety Policy' of the occupier;
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-24
(b) Dealing with all matters concerning health, safety and environment and to arrive at
practicable solutions to problems encountered;
(c) Creating safety awareness amongst all workers;
(d) Undertaking educational, training and promotional activities;
(e) Deliberating on reports of safety, environmental and occupational health surveys,
emergency plans safety audits, risk assessment and implementation of the recommendations
made in the reports;
(f) Carrying out health and safety surveys and identify causes of accidents;
(g) Looking into any complaint made on the likelihood of an imminent danger to the safety
and health of the workers and suggest corrective measures; and
(h) Reviewing the implementation of the recommendations made by it.
7.8.3. Outside Organization Involvement in assisting during the On-site emergency.
The Outside organization that would be involved during the On-site emergency would be fire,
hospital and Police authority. These authorities would be contacted when the resources
provided within the factory will not fulfill the requirement.
7.8.4. Information on the preliminary hazard analysis.
A detailed HAZOP Study for process operations & Risk Assessment have been prepared
considering all possible and rare events regarding handling, storage of Raw Materials. Based
on the study the maximum credible scenario has been identified for the particular scenario
and recommendation to reduce the effect and its occurrence has been
suggested/recommended.
7.8.5. Details about Safety related features in Plant
a) Location of the Dangerous Substances
The dangerous substances are stored in a demarcated area in the plant premises. The raw
materials are stored based on their compatibility with other raw materials. The raw materials
whose quantity is large will be stored in drums with appropriate safety measures. The plot
layout is marked with the locations of such raw materials.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-25
b) Details of Key Personal
Name Designation Contact No.
Mr. Anil Rao Managing Director 9820045009
Mr. Vilas Andhere Site Controller 9324801572
Mr. G. Rao Production Manager 9869348832
Mr Mandar R Shedge EHS Officer 9820578866
Dr R.B.Kudachi Medical Officer 9004239792
Mr. Raghu Kotary Site Incident Controller 9967391203
c) Emergency Control Room
EMERGENCY CONTROL ROOM as marked on site plan will be focal point in case of an
emergency, from where the operations to handle the emergency are directed and co-ordinate
by Site Main Controller. The following information and equipment is provided at the
Emergency Control Centre (ECC):
Intercom, telephone
P and T telephone
Safe contained breathing apparatus
Fire suit/gas tight goggles/gloves/helmets
Hand tools, wind direction/velocities indicators
Public address megaphone, hand bell, telephone directories
(Internal, P and T) factory layout, site plan
Emergency lamps/torch lights/batteries
Plan indicating locations of hazard inventories, plant control room, sources of safety
equipment, work road plan, assembly points, rescue location, vulnerable zones, and
escape routes
Hazard chart
Emergency shut-down procedures
Nominal roll of employees
List of key personnel, list of essential employees, list of Emergency Co-ordinators
Duties of key personnel
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-26
Addresses with telephone numbers of key personnel, emergency coordinator, and
essential employees.
Important addresses and telephone numbers including Government agencies,
neighboring industries and sources of help, outside experts, chemical fact sheets,
population details around the factory.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-27
7.8.6. Description of Hazardous chemicals at plant site.
Sr. No
Common Name
of Raw
Material
IUPAC CAS
Number
Chemical
Formula
Molecular
Weight in
g/mol
Physical
State Odor
Flash
Point
(°C)
Boiling
Point (°C)
Melting
Point (°C) Stability Density LEL UEL
1 Acetone
propan-2-
one 67-64-1 (CH3)2CO 58.08 g/mol Liquid. Ethereal 20°C 56.2 -95.35 Stable
0.7845 g/cu
cm at 15o C 2.60% 12.80%
2 Acetyl chloride
Acetyl
chloride 75-36-5 CH3COCl 78.495 g/mol
Liquid.
(Fuming
liquid.)
Strong. 4.4°C 52 -112 Stable 1.1051 at
15o C/ 4o C 7.30% NA
3 Acetic Acid
Acetic
Acid 64-19-7 CH3COOH 60.052 g/mol Liquid. Pungent, 39°C. 118.1 16.6 Stable 1.0446 4% 19.90%
4
Aluminum
chloride
trichloroal
umane
7446-
70-0 AlCl3 133.332 g/mol
Solid.
(Crystals
solid.)
NA NA NA Sublimes Stable 2.48 NA NA
5 Benzaldehyde
Benzeneca
rbaldehyde
100-52-
7 C6H5CHO 106.124 g/mol Liquid NA
CLOSE
D CUP:
64.4°C
OPEN
CUP:
73.9°C
179 -26 Stable 1.050 at 15o
C/ 4o C 1.40% NA
6 Toluene Toluene
108-88-
3 C6H5CH3 92.141 g/mol Liquid.
Sweet,
pungent,
Benzene
-like.
CLOSE
D CUP:
4.4444°
C OPEN
CUP:
16°C
110.6 -95 Stable 0.8623 g/cu
cm at 20o C 1.10% 7.1%
7 Bromine
Molecular
bromine
7726-
95-6 Br2 159.808 g/mol Liquid.
Pungent.
Suffocat
ing.
NA 58.78 -7.25 Stable 3.1023 NA NA
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-28
(Strong.)
8 Biphenyl
1,1'-
biphenyl 92-52-4 C12H10 154.212 g/mol
Solid.
(Crystals
solid.)
Characte
ristic.
(Slight.)
CLOSE
D CUP:
112.8°C
254.5 68.9 Stable 1.041 at 15o
C 0.60% 5.80%
9 1,4- Dioxane
1,4-
dioxane-
2,3-diol
123-91-
1 C4H8O2 88.11 g/mol Liquid.
Ethereal.
Pleasant.
(Slight.)
CLOSE
D CUP:
12°C
OPEN
CUP:
18.3°C
101.1 11.8 Stable 2% 22%
10
Ethylene
Dichloride
1,2-
dichloroeth
ane
107-06-
2 C2H4Cl2 98.954 g/mol Liquid. NA
CLOSE
D CUP:
13°C
OPEN
CUP:
18°C
83.5 -35.3 Stable 1.2351 at
15o C 6.20% 15.60%
11 Ferric Chloride
trichloroiro
n-59
7705-
08-0 FeCl3 165.285 g/mol Solid. NA NA 316 306 Stable - - -
12
4-Hydroxy
Coumarine
4-
hydroxychr
omen-2-
one
1076-
38-6 C9H6O3 162.144 g/mol Solid
Not
Avialabl
e
Not
Avialabl
e
Not
Avialable
Not
Avialable
Not
Avialable
Not
Avialable
Not
Avialab
le
Not
Avialab
le
13
Hydrochloric
Acid 30% chlorane
7732-
18-5
&
7647-
01-0
Not
applicable Not applicable Liquid.
Not
available
.
Not
applicabl
e.
The lowest
known
value is
100°C
(212°F)
(Water)
Not
available
Stability:
The product
is stable.
Instability
Temperature
: Not
available.
Conditions
of
Instability:
The highest
known
value is
0.62 (Air =
1) (Water).
- -
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-29
Incompatible
materials
14 Iodine
molecular
iodine
7553-
56-2 I2 253.809 g/mol Solid.
Sharp
Characte
ristic.
(Strong.)
NA 184.4 113.7 Stable 4.93 NA NA
15
Iso Amyl
Alcohol
3-
methylbuta
n-1-ol
123-51-
3 C5H12O 88.15 g/mol Liquid
Disagree
able and
choking
42.78°C. 132 117.2 Stable
0.813 at 15o
C 1.20% 9%
16 Methanol Methanol 67-56-1 CH3OH 32.042 g/mol Liquid.
Alcohol
like.
Pungent
when
crude.
CLOSE
D CUP:
12°C
OPEN
CUP:
16°C
64.5 -97.8 Stable 0.7866 6% 36.50%
17 Petroleum Ether -
8032-
32-4 NA NA Liquid. Slight.
CLOSE
D CUP:
Lower
than -
18°C
60 NA Stable 0.7 1.10% 5.9%
18 Peperidine
110-89-
4 C5H11N 85.15 g/mol Liquid. NA
CLOSE
D CUP:
16.1°C
106 -9 Stable 0.86 NA NA
19
Polyethylene
glycol 400
25322-
68-3
H(OCH2CH2
)nOH
400 (380 - 420)
g/mol
Liquid. (
viscous)
Odorless
.
CLOSE
D CUP:
226.67°
C OPEN
CUP:
231.11°
C
NA 4°C - 6 °C Stable 1.1254 NA NA
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-30
20
Sodium
thiosulfate
disodium;d
ioxido-
oxo-
sulfanylide
ne-$l^{6}-
sulfane
7772-
98-7 Na2S2O3 248.19 g/mol Solid. NA NA NA
Decompose
s. Stable. 1.73 NA NA
21
Sodium
Methoxide 30%
sodium;me
thanolate
124-41-
4 CH3ONa 54.03 g/mol
Solid. (Solid
powder.
Amorphous
solid powder
or lumps. )
NA
CLOSE
D CUP:
33°C
NA
Decomposit
ion
temperature
: >126°C
Stable. 1.1 7.30% 36%
22
Sodium
Borohydride
sodium;bor
on(1-)
16940-
66-2 NaBH4 37.84 g/mol Solid. NA NA NA
Decompose
s. Stable. 1.074 NA NA
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-31
7.8.7. Likely Dangers To The Plant
Sr.
No. Accident Scenario Causes
Consequence
Zone
2. Spill
Pipe line /pump gland leakage, Gasket
failure
Spill of
Flammable solvents : Methanol
- Toluene, Acetyl Chloride etc.
Toxic chemicals - Bromine
Local
3. Large spill Rupture of drum Local
4. Pressure development Pressure development ,
Uncontrolled reaction exothermic Local
5. Fire
Any spill of flammable chemical,
e.g. solvent spill finding source
catching fire on finding of ignition
source.
Local
6. Electric fire At transformer area Local
7.
Release of
Toxic / flammable
Vapors
Distillation column, failure of cooling
water supply, etc. at Condenser.
Lead to an off-
site consequences
8. Fall of structure Earthquake , poor maintenance Local
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-32
7.8.8. Details of Safety Systems in the Plant Premises
The below section will explain about the safety features & measures to be adopted by M/s
Pest Control India Pvt. Ltd. for dealing with the onsite emergency situation.
A) Alarm / Siren
There will be totally 10 nos. of hooters located in the plant premises. Once in week by giving
an ―All Clear‖ siren will be sounded for testing purpose. Emergency Alarm annountiator
panel will be located at gate office building.
On hearing alarm the incident controller will activate the action on Disaster control plan by
giving proper instructions or predetermined signals. The alarm code used in the company is
explained below,
ALARM CODE
Sr. No Situation Type of Siren/Alarm
1. Emergency at Site One Minute waxing and wailing siren
2. All Clear One Minute continuous siren
3. Evacuation Three minutes waxing and wailing siren
B) Assembly Points
Numbers of assemblies in the plant location are identified wherein employees who are not
directly connected with the disaster management would be assembled for safety and rescue.
Emergency breathing apparatus, minimum facilities like water etc. would be organized. In
view of the size of plant, different locations are earmarked as assembly points. Two assembly
points are identified by the company i.e. one near the main gate of the company and other one
is located near the second gate of the company. Depending upon the location of hazard, the
assembly points are to be used.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-33
C) Mock Drills
The company organizes periodical mock drill / rehearsal by creating an emergency situation
so as to verify preparedness and awareness as well as shortcomings on the part of the person
to overcome the same. Sufficient time is provided prior to mock drill to the emergency
services and public for proper response to exercise and provide training also. Record the
deficiencies of the system during the trial and take appropriate actions to improve the
efficiency of the plan in terms of preparedness and response.
D) Training
By imparting an effective training from time to time, the awareness is being kept alive all the
time to ensure safety awareness, preparedness for emergency situations, good housekeeping,
discipline, etc. Display of safety slogans, operative instructions and motivation for safety
should is made the part of the company‘s normal activities. All the persons earmarked for the
emergency services are trained to respond to the emergency. The company conducts internal
& external training for Environment Health & safety. The training is conducted at a
documented frequency. The external training is conducted six monthly and internal training is
conducted every month. Training is imparted to the employees by raising siren in specific
pattern. Employees are given training of escape routes, taking shelter, protecting from toxic
effects. Employees are provided with information related to fire hazards and first aid
measures.
E) Emergency Power Supply
Plant facilities would be connected to Generator and is placed in an auto mode. Thus, water
pumps, plant‘s lighting and emergency control centre, administrative building and other
auxiliary services are connected to emergency power supply. In all the blocks, flameproof
type emergency lamps are provided.
F) Wind Sock
Wind sock is provided in the company. The workers are trained in the mock drill regarding
the usage of the wind sock for identifying the directions for taking shelter or identifying the
area of high toxicity in case of emergency.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-34
G) Fire Fighting Facilities
Firefighting equipment suitable for emergency are maintained well in each section in the
plant. This would be developed according to the statutory requirements. However, fire
hydrant line covering major areas has been laid. Fire alarms will be located in the bulk
storage areas. The below details highlights the fire fighting facilities at site.
7.8.9. List of fire extinguishers provided
1. No. of fire extinguishers – 17 no.
2. Type of extinguishers – DCP/ABC
3. Location of Fire Extinguishers: As given below
Table No.7.7: Details of fire extinguishers with location
Sr. No
Ext No.
Location
Type
Capacity
1 U-01 Main Gate ABC 6 Kg
2 U-02 Meter Room ABC 6 Kg
3 U-03 Admin Office ABC 6 Kg
4 U-04 EO Can Filling ABC 6 Kg
5 U-05 MCC Room DCP 25 Kg
6 U-06 Fire Hydrant Room ABC 6 Kg
7 U-07 ETP DCP 5 Kg
8 A-01 Plant Building A-Wing DCP 5 Kg
9 A-02 Plant Building A-Wing DCP 5 Kg
10 B-01 Plant Building B-Wing DCP 5 Kg
11 C-01 Plant Building C-Wing DCP 5 Kg
12 C-02 Plant Building C-Wing ABC 4 Kg
13 R-01 R & D Center ABC 4 Kg
Fire Fighting Tank Details
Capacity of Fire Fighting tanks 250 KL
Type of tank Overhead/ Below head Below Head
Material of Construction RCC
Pump Capacity of fire fighting tank Main pump – 137 m3/hr
No of assembly points 2 Nos Near to each gate
No of exit points for emergency evacuation
6 No
Fire Hydrant system Yes
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-35
14 R-02 R & D Center ABC 4 Kg
15 R-03 R & D Center ABC 6 Kg
16 R-04 R & D Center ABC 4 Kg
17 R-05 R & D Center ABC 1 Kg
A. Water requirement for Fire Fighting and Back – up Time Calculation.
The amount of water required for firefighting purpose can be estimated by the below
formula:
Water required in liters per minutes = (A + B +C + D)/20
i.) The total area in sq.mtr of all Floors including galleries in all building of the factory (Total
Built up Area) = 1039.94 sq.m.
ii.) The total area in sq.mtr of all Floors and galleries including open spaces in which
combustible materials = 1686.64 sq.m.
iii.) The total area in sq.mtr of all Floors over 15 mtr above ground level = NIL sq.m.
iv.) The total area in sq.mtr of all floors of buildings other than those of fire resisting
construction of various floors is so certified by any fire association or fire insurance company
= NIL sq.m.
Water required in liters per minutes = (1039.94 +1686.64 + NIL+ NIL)/20
= 136.3 lit/min = 0.136 m3/min
The quantity of firefighting tank is 250 m3.
Time (min) = [Total water in fire fighting tank (m3)]/water required m
3/min
= 250/ 0.136
= 1838 min = 286/60 = 30 Hrs. 63 Minutes.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-36
B. Justification considering pump capacity
The pump capacity in the plant is 137m3/hr, therefore according to the discharge capacity of
the pump installed. The back-up time by which the tank will be empty is calculated below,
Time (min) = [Total water in fire fighting tank (m3)]/discharge capacity (m
3/hr)
= 250/137
= 1.82 Hours
Back-up time will be 1.82 Hrs
7.8.10. Medical Facilities
The total number of employees in M/s Pest Control India Pvt. Ltd would be around 50 Nos.
According to the Factories Act 1948 & Maharashtra Factories Rules, 1963, 5 first aiders to be
appointed out of which 1 should be at site at any given time. Occupational Health Center is
provided in which a part time factory medical officer shall visit the factory at least twice in a
week. Also one qualified person on First Aid measures will be on duty. First aid box will be
provided in every department of the company. At present there is only 5 first aid box with 5
people trained in using it. Necessary specific medicines for emergency treatment of burns
patients and for those affected by toxicity would be maintained. Breathing apparatus and
other emergency medical equipment would be provided and maintained in the OHC.
Private medical practitioners & government hospital would be approached in case of
emergency & short supply in the plant.
Names of medical personnel and medical facilities in the surrounding area would be prepared
and updated which can be identified in the security office and emergency control center. The
help of nearby industrial managements would be taken under mutual aid response group
agreement if required.
Keeping in view the nature of the emergency, two levels of co-ordination are proposed. In the
case of an On Site Emergency, resources within the organization would be mobilized as
explained in the above section and in the event of an extreme emergency; local authorities‘
help would be sought.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-37
In the event of an emergency developing into an offsite emergency, local authority and
District Emergency Authority (normally the Collector) would be appraised and under his
supervision, the Off Site Disaster Management Plan would be exercised. The detailed risk
analysis has indicated that the pool fire effects would be felt outside the factory. Therefore it
is necessary to prepare an offsite emergency plan.
For this purpose, the offsite emergency plan has been highlighted in the below section, for the
facilities that are available locally, i.e. medical, transport, personnel, rescue accommodation,
voluntary organizations etc. would be mustered. Necessary rehearsals and training in the form
of mock drills should be organized in consultation with the district emergency authority.
7.9. Off-Site Emergency Preparedness Plan
The off-site plan will be prepared with the help of the local district authorities. The proposed
plan will be based on the following guidelines.
7.9.1. Introduction
Off-site emergency plan follows the on-site emergency plan. When the consequences of an
emergency situation go beyond the plant boundaries, it becomes an off-site emergency. Off-
site emergency is essentially the responsibility of the public administration. However, the
factory management will provide the public administration with the technical information
relating to the nature, quantum and probable consequences on the neighboring population.
The off-site plan in detail will be based on those events, which are most likely to occur, but
other less likely events, which have severe consequence, will also be considered. Incidents,
which have very severe consequences yet have a small probability of occurrence, should also
be considered during the preparation of the plan. However, the key feature of a good off-site
emergency plan is flexibility in its application to emergencies other than those specifically
included in the formation of the plan.
The roles of the various parties who will be involved in the implementation of an off-site plan
are described below. Depending on local arrangements, the responsibility for the off-site plan
should either rest with the works management or, with the local authority. Either way, the
plan should identify an emergency coordinating officer, who would take the overall
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-38
command of the off-site activities. As with the on-site plan, an emergency control centre
should be set up with whom the emergency coordinating officer & emergency planning
officer can operate. An early decision will be required in many cases on the advice to be
given to people living "within range" of the accident; in particular, whether they should be
evacuated or told to go indoor. In the latter case, the decision can regularly be reviewed in the
event of an escalation of the incident.
Consideration of evacuation may include the following factors:
In the case of a major fire but without explosion risk (e.g. an oil storage tank), only
houses close to the fire are likely to need evacuation, although a severe smoke hazard
may require this to be reviewed periodically
If a fire is escalating and in turn threatening a store of hazardous material, it might be
necessary to evacuate people nearby, but only if there is time; if insufficient time
exists, people should be advised to stay indoors and shield themselves from the fire
For release or potential release of toxic materials, limited evacuation may be
appropriate downwind if there is time. The decision would depend partly on the type
of housing "at risk". Conventional housing of solid construction with windows closed
offers substantial protection from the effects of a toxic cloud, while shanty house,
which can exist close to factories, offers little or no protection.
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-39
Figure No. 7.2: Organizational Structure For Offsite Emergency Management
7.9.2. Role of the Chief Inspector
Chief Inspectors are likely to want to satisfy themselves that the organization responsible for
producing the off-site plan has made adequate arrangements for handling emergencies of all
types including major emergencies. Chief Inspector may verify the documented procedures
and evidence of exercise undertaken to test the onsite & offsite plan The copy of the
information furnished to the workers, local authority, general public & District Emergency
Authority is submitted to the Chief Inspector for review. If the Chief Inspector is not satisfied
with the content, he may direct the occupier to supply further information to the workers,
authority, general public & District Emergency Authority as deemed necessary.
7.9.3. Role of the Emergency Coordinating Officer
The various emergency services will be coordinated by an emergency coordinating officer
(ECO), who is designated by the District Collector. The ECO will liaise closely with the Site
Controller. Again, depending on local arrangements, for very severe incidents with major or
Site Controller
Emergency Co-ordinating
OfficerAppointed by District Authority
Emergency Planning
Officer Appointed by Local Authority
Chief
InspectorAppointed by State
Gov. Authority
General
Public
Fire
Authority
Heath
Authority
Police
Authority
State Pollution
Control Board
Emergency Plan
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-40
prolonged off-site consequences, the external control should be passed on to a Emergency
Planning Officer of the local authority administrator.
7.9.4. Role of the Local Authority
The company will enter into an agreement with the Emergency Planning Officer (EPO) of the
area, within whose jurisdiction the factory is situated for the Emergency officer to take
appropriate steps to inform the general public outside the factory who likely to be affected by
an accident. The information in the prescribed format would be shared with the EPO by the
site controller. The duty to prepare the off-site plan lies with the local authorities. The
emergency planning officer (EPO) appointed should carry out his duty in preparing for a
whole range of different emergencies within the local authority area. The EPO should liase
with the site controller for ensuring that the plan is continually updated.
It is the responsibility of the EPO to ensure that all those organizations, which will be
involved off site in, handling the emergency, know of their role and are able to accept it by
having for example, sufficient staff and appropriate equipment to cover their particular
responsibilities. Rehearsals for off-site plans is organized by the EPO.
7.9.5. Role of Fire Authorities
The control of a fire should normally be the responsibility of the senior fire brigade officer
who would take over the handling of the fire from the site incident controller on arrival at the
site. The senior fire brigade officer should also have a similar responsibility for other events,
such as explosions and toxic release. Fire authorities in the region should be apprised about
the location of all stores of flammable materials, water and foam supply points, and fire-
fighting equipment. They should be involved in on-site emergency rehearsals both as
participants and, on occasion, as observers of exercises involving on-site personnel.
7.9.6. Role of Health Authorities
Health authorities, including doctors, surgeons, hospitals, ambulances, and similar other
persons/institutions should have a vital part to play following a major accident, and they
should form an integral part of the emergency plan. For major fires, injuries should be the
result of the effects of thermal radiation to a varying degree, and the knowledge and
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-41
experience to handle this in all but extreme cases may be generally available in most
hospitals. For major toxic releases, the effects vary according to the chemical in question, and
the health authorities should be apprised about the likely toxic releases from the plant, which
will enable them to deal with the aftermath of a toxic release with treatment appropriate to
such casualties. Major off-site incidents are likely to require medical equipment and facilities
in additional to those available locally, and a medical "mutual aid" scheme should exist to
enable the assistance of neighboring authorities to be obtained in the event of an emergency.
7.9.7. Role of Police Authority
Formal duties of the police during an emergency include protecting life and property and
controlling traffic movements. Their functions should include controlling bystanders,
evacuating the public, identifying the dead and dealing with casualties, and informing
relatives of dead or injured.
7.9.7. Role of Pollution Control Board
Pollution control board has to ensure if there is any release of toxic substances / pollutants
during emergency by carrying site monitoring etc. and inform about the same to district
authority.
7.9.8. External agencies contact details involved during emergency
Table No. 7.8: Details of external agencies to be involved during emergency
Details of Hospitals
Sr.
No.
Name of Hospital Address Telephone Distances
1 Dr. Vaidya,
Central Hospital,
Cbf Building,
Taloja, Raigad-
Maharashtra -
410208
93222 64037 1 km
2 MGM Hospital Sector 4E,
Kalamboli, Navi
Mumbai,
Maharashtra 410218
022 2742 3405 4 km
Environmental Impact Assessment Report For Proposed Pesticide Manufacturing Unit of M/s Pest Control (India) Pvt. Ltd. Located At Taloja MIDC, Navade Village, Taluka Panvel, District Raigad in Maharashtra State. SEEPL/EIA/F/IND/PCI/001/2016-17/00
Chapter 7: Additional Studies
Sadekar Enviro Engineers Pvt. Ltd 7-42
3 Rana Hospital Taloja Phase 1,
Petali, Sector 2,
Taloja, Navi
Mumbai,
Maharashtra 410208
080823 22200 3.6 km
Details of Police Stations
Sr.
No.
Name of Police
Station
Address Telephone Distances
1 Taloja Police
Station
Maharashtra
Industrial
Development
Corporation, Taloja,
Navi Mumbai,
Maharashtra 410208
27412333/0425 1 km
Details of Fire Stations
Sr.
No.
Name of Fire
Station
Address Telephone Distances
1 Taloja MIDC Fire
station
Plot No 320, Taloja,
Raigad-Maharashtra
- 410208, Near
Deepak Fertilizer
27401055/27411432 2.7 km
Details of MIDC Offices
Sr.
No.
Name of MIDC Address Telephone Distances
1 Taloja MIDC Taloja MIDC 27412260 1 km
Details of Pollution Control Department
Sr.
No.
Name of PCD Address Telephone Distances
1 Maharashtra
pollution control
board ( MPCB)
Raigad Bavan, 7th
floor Sector - 11,
C.B.D Belapur, Navi
Mumbai
022 27572740 8.2km
7.10. Resettlement & Rehabilitation Details
The proposed activity will be carried out at the existing plot of the company located at
notified industrial area, Taloja. Hence rehabilitation & resettlement aspects are not
applicable in this project.