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Chemical Resistance of Plastics and Elastomers Used in ... resistance chart.pdf · Pipes made from...

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2.1 www.us.piping.georgefischer.com Chemical Resistance Guide 2 1. Introduction It is now inconceivable to construct pipelines without the use of plastics. Pipes made from plastics are used not only for drinking water, water for gen- eral use and waste water, but also for the conveyance of aggressive liquids and gases. Expensive pipe materials such as lined metal, ceramic or glass, have been largely superseded by plastic pipes. It is, however, important that the most suitable plastic material is selected for each application. This "Chemical Resistance List” serves as a useful guide in this respect. The list is periodically revised to include the latest findings. It contains all plastics and elastomers in the George Fischer product range which can come into direct contact with the media. The information is based on experiments, immersion and, when available, on data from tests which include temperature and pressure as stress factors. The results achieved in immersion experi- ments cannot be applied without reser- vation to pipes under stress, i.e. internal pressure, as the factor “stress corrosion cracking” is not taken into consideration. In certain cases it can be of advantage to test the suitability under the planned working conditions. The tests referred to have been carried out partly by George Fischer and partly by the International Standardization Organization (ISO) or national standards organizations. Pure chemicals were used for the tests. If a mixture of chemicals is to be conveyed in practice this may affect the chemical resistance of the plastic. It is possible in special cases to carry out appropriate tests with the specific mixture. Suitable test equipment is available at George Fischer for this purpose, which we regard as part of our service to the customer. It goes without saying that we are willing to give individual advice at any time. In this connection it is worth mentioning that George Fischer already possesses information concerning the behavior towards plastics of a number of chemi- cals or mixtures of chemicals which are not yet included in this list. The “Chemi- cal Resistance List” gives valuable assistance in the planning of plastic pipelines. Please refer to the following instructions, which are important for the application and evaluation of this list. 2. Instructions for the Use of the Chemical Resistance List 2.1 General As stated in the introduction, the “Chemi- cal Resistance List” is only intended as a guide. Changes in the composition of the medium or special working condi- tions could lead to deviations. If there is any doubt, it is advisable to test the behavior of the material under the specific working conditions, by means of a pilot installation. No guarantees can be given in respect of the information contained in this booklet. The data shown is based upon information available at the time of printing, but it may, however, be revised from time to time in the light of subsequent research and experience. 2.2 Classification The customary classifications: resistant, conditionally resistant and not recommended are depicted by the signs: +, O, and –, which allow simple presentation and application. These classifications are defined as: Resistant: + Within the acceptable limits of pressure and temperature the material is unaf- fected or only insignificantly affected. Conditionally Resistant: O The medium can attack the material or cause swelling. Restrictions must be made in regard to pressure and/or temperature, taking the expected service life into account. The service life of the installation can be noticeably shortened. Further consultation with George Fischer is recommended. Not recommended: – The material cannot be used with the medium at all, or only under special conditions. The Chemical Resistance Guide is also available on our website Chemical Resistance of Plastics and Elastomers Used in Pipeline Construction 2
Transcript
Page 1: Chemical Resistance of Plastics and Elastomers Used in ... resistance chart.pdf · Pipes made from plastics are used not ... solvent cement joining is classified as ... (PVC-C), PVC-C

2.1www.us.piping.georgefischer.com

Chemical Resistance Guide

21. Introduction

It is now inconceivable to constructpipelines without the use of plastics.Pipes made from plastics are used notonly for drinking water, water for gen-eral use and waste water, but also forthe conveyance of aggressive liquidsand gases. Expensive pipe materialssuch as lined metal, ceramic or glass,have been largely superseded by plasticpipes. It is, however, important that themost suitable plastic material is selectedfor each application. This "ChemicalResistance List” serves as a useful guidein this respect. The list is periodicallyrevised to include the latest findings. Itcontains all plastics and elastomers inthe George Fischer product range whichcan come into direct contact with themedia.

The information is based on experiments,immersion and, when available, on datafrom tests which include temperatureand pressure as stress factors. Theresults achieved in immersion experi-ments cannot be applied without reser-vation to pipes under stress, i.e. internalpressure, as the factor “stress corrosioncracking” is not taken into consideration.In certain cases it can be of advantageto test the suitability under the plannedworking conditions. The tests referred tohave been carried out partly by GeorgeFischer and partly by the InternationalStandardization Organization (ISO) ornational standards organizations.

Pure chemicals were used for the tests. Ifa mixture of chemicals is to be conveyedin practice this may affect the chemicalresistance of the plastic. It is possible inspecial cases to carry out appropriatetests with the specific mixture. Suitabletest equipment is available at GeorgeFischer for this purpose, which we regardas part of our service to the customer. Itgoes without saying that we are willingto give individual advice at any time. Inthis connection it is worth mentioningthat George Fischer already possessesinformation concerning the behaviortowards plastics of a number of chemi-cals or mixtures of chemicals which are

not yet included in this list. The “Chemi-cal Resistance List” gives valuableassistance in the planning of plasticpipelines. Please refer to the followinginstructions, which are important for theapplication and evaluation of this list.

2. Instructions for the Use ofthe Chemical Resistance List

2.1 GeneralAs stated in the introduction, the “Chemi-cal Resistance List” is only intended as aguide. Changes in the composition ofthe medium or special working condi-tions could lead to deviations. If there isany doubt, it is advisable to test thebehavior of the material under thespecific working conditions, by means ofa pilot installation. No guarantees canbe given in respect of the informationcontained in this booklet. The datashown is based upon informationavailable at the time of printing, but itmay, however, be revised from time totime in the light of subsequent researchand experience.

2.2 ClassificationThe customary classifications:resistant, conditionally resistant andnot recommended are depicted by thesigns: +, O, and –, which allow simplepresentation and application. Theseclassifications are defined as:

Resistant: +Within the acceptable limits of pressureand temperature the material is unaf-fected or only insignificantly affected.

Conditionally Resistant: OThe medium can attack the material orcause swelling. Restrictions must bemade in regard to pressure and/ortemperature, taking the expected servicelife into account. The service life of theinstallation can be noticeably shortened.Further consultation with George Fischeris recommended.

Not recommended: –The material cannot be used with themedium at all, or only under specialconditions.

The Chemical ResistanceGuide is also availableon our website

Chemical Resistance of Plasticsand Elastomers Used in Pipeline Construction

2

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Page 2: Chemical Resistance of Plastics and Elastomers Used in ... resistance chart.pdf · Pipes made from plastics are used not ... solvent cement joining is classified as ... (PVC-C), PVC-C

2.2 ¬ ‡

2.3 Pipe Joints2.3.1 Solvent Cement Joints (PVC)Solvent cement joints made with stan-dard PVC cement and primer systemsare generally as resistant as the PVCmaterial itself. The following chemicalsare, however, an exception:• Sulphuric acid H

2SO

4 in concentrations

above 70 percent• Hydrochloric acid HCI in concentra-

tions above 25 percent• Nitric acid HNO

3 in concentrations

above 20 percent• Hydrofluoric acid in any concentration

In conjunction with the above media thesolvent cement joining is classified as“conditionally resistant”. Previouslyrecommended solvent cement (Dytex, byHenkel, Germany) used for pipe andfittings to carry concentrated acids, canno longer be brought into the UnitedStates because of its methylene chloridesolvent system being classified as acarcinogen. There is no known domesti-cally available substitute. Specialconsideration should be given to thepossible attack of the cemented joints bythese concentrated acids.

2.3.2 Fusion JointsIn the case of PE, PP, and PVDF (SYGEF®)heat fusion joints have practically thesame chemical resistance as the respec-tive material. In conjunction with mediawhich could cause stress cracking, thefused joints can be subjected to anincreased risk due to residual stress fromthe joining process.

2.4 Sealing MaterialsDepending upon the working conditionsand the stress involved, the life span ofthe sealing materials can differ from thatof the pipeline material. Seals in PTFE,which are not included in this list, areresistant to all the chemicals indicated.The greater permeability of PTFE should,however, be considered. Under certainworking conditions, for example whenconveying highly aggressive media suchas hydrochloric acid, this materialcharacteristic must be taken into ac-count.

2.5 General Summary and Limits ofApplicationThe following table includes all thematerials contained in the GeorgeFischer product range, and their abbre-viations. The summary gives preliminaryinformation regarding the generalbehavior of the materials and thetemperature limits.

2.6 StandardsThis list has been compiled with refer-ence to the following ISO standards:ISO/TR 7473Unplasticized polyvinyl chloride pipesand fittings – Chemical resistance withrespect to fluids.ISO/TR 7474High density polyethylene pipes andfittings – Chemical resistance withrespect to fluids to be conveyed.ISO/TR 7471Polypropylene (PP) pipes and fittings –Chemical resistance with respect tofluids.ISO TR 10358Plastic pipes and fittings – Combinedchemical resistance classification table.DVS 2205 Part ICalculations for thermoplastic con-tainers and appliances.DIN 8080 Supplement 1 «Pipes ofchlorinated polyvinyl chloride (PVC-C),PVC-C 250 – Chemical Resistance».

02_1-3 6/7/02, 10:28 AM2

Page 3: Chemical Resistance of Plastics and Elastomers Used in ... resistance chart.pdf · Pipes made from plastics are used not ... solvent cement joining is classified as ... (PVC-C), PVC-C

2.3www.us.piping.georgefischer.com

Chemical Resistance Guide

2

Material Abbre- Remarks Maximum Permissibleviation Temperature (Water) °C

Constant Short Term

PVC Resistant to most solutions of acids, alkalis and salts and to 60° 60°Polyvinyl Chloride organic compounds miscible with water. Not resistant to

aromatic and chlorinated hydrocarbons

Chlorinated CPVC Can be used similarly to PVC but at higher temperatures. 90° 110°Polyvinyl Chloride Consult factory for specific applications.

High-density PE 50 Resistant to hydrous solutions of acids, alkalis and salts as 60° 80°Polyethylene well as to a large number of organic solvents. Unsuitable for

concentrated oxidizing acids.

Polypropylene, heat stabilized PP Chemical resistance similar to that of PE but suitable for 90° 110°higher temperatures

Polyvinylidene PVDF Resistant to acids, solutions of salts, aliphatic, aromatic and 140° 150°Fluoride (SYGEF®) chlorinated hydrocarbons, alcohols and halogens. Conditio-

nally suitable for ketones, esters, organic bases andalkaline solutions

Polybutylene-1 PB Similar to PE 50, but can be used up to 90°C 90° 100°

Polyoxymethylene POM Resistant to most solvents and hydrous alkalis. Unsuitable for 60° 80°acids

Polytetrafluoroethylene PTFE Resistant to all chemicals in this list 250° 300°(e.g. Teflon®)

Nitrile Rubber NBR Good resistance to oil and petrol. Unsuitable for oxidizing 90° 120°media

Butyl Rubber IIR Good resistance to ozone and weather. Especially suitable 90° 120°Ethylene Propylene Rubber EPDM for aggressive chemicals. Unsuitable for oils and fats

Chloroprene Rubber CR Chemical resistance very similar to that of PVC-U and 80° 110°(e.g. Neoprene®) between that of Nitrile and Butyl Rubber

Fluorine Rubber FPM Has best chemical resistance to solvents of all elastomers 150° 200°(e.g. Viton®)

Chlorine Sulphonyl Polyethylene CSM Chemical resistance similar to that of EPDM 100° 140°(e.g. Hypalon®)

®Registered trademark of DuPont Dow Elastomers

The abbreviations listed below are found throughout the listings and have the following definition:

Q/E (Quellung/Erweichung) = swelling/softeningD/P (Diffusion/Permeation) = diffusion/permeationSpRB (Spannungsrissbildung) = environmental stress crackingG (Gas/Ausgasend/Gasbildend) = gas/outgassing/gas formingGL (Gesättigte Lösung) = saturated solutionFp (Fliesspunkt) = melting point^– (Hochgestelltes Minuszeichen) = diffusion/permeation

02_1-3 6/7/02, 10:28 AM3

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