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Chemistry NotesPeriodic Table and Basic Bonding
Syed Kamran
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Chemistry Notes
Periodic Table and Basic Bonding
PERIODIC T ABLE Presently there are 118 elements on the periodic table of elements, however more are
still being discovered. It is one the most useful tools to chemists. The table is organized so
that you can determine its physical properties just by looking at its position.
ElementsScientists have identified 92 naturally occurring elements and created about
26 others. The elements alone or in combinations, make up our bodies, our world, our
sun, and in fact, the entire universe.
Valence Electrons Valence electrons are the number of electrons at the outer energy level of an
atom. These are the electrons that are used when atoms bond together.
Main Categories of the Periodic Table
Metals: Metals are good conductors of
heat and electricity. They are shiny,
ductile, and malleable. Metal corrode
in water.
Non-Metals: Non-metals are poorconductors of heat and electricity. They
are not ductile, and malleable. Solid
non-metals are brittle, break easily
and are dull. Many non-metals are
gases.
Metalloids: Metalloids have properties of both metals and non-metals. They can be
shiny or dull. They can conduct heat and electricity, however not as well as metals.
They are also ductile, and malleable.
Groups and PeriodsWithin the Periodic table of elements, elements are also organized via groups
and periods.
Groups (families): Groups are the vertical columns that have similar properties.
Some of the columns have been given special names to distinguish them. All
elements in a family have the same number of valence electrons.
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Periods: Periods are the horizontal rows that do not have similar properties. Sizes of
atoms decrease as we move left to right across a period; this is due to the increasing
number of protons in the nucleus, resulting in a stronger electrical attraction
between the nucleus and electrons. In addition the electronegativity increase as you
move left to right across a period. The first element in a period is always an active
solid, and the last is always an inactive gas.
ClassesThere are many classes within the Periodic table of elements; most of the
elements have similar properties.
Hydrogen: The hydrogen square sits atop of Group 1, but it is not a member of that
family. It is a gas at room temperature. It has one proton and one electron in its
electron level.
Alkali Metals: The alkali family is found in the first column of the periodic table.
Atoms of the alkali metals have a single valence electron. They are shiny, have the
consistency of clay, and are easily cut with a knife. They are the most reactive
metals, and react violently with water. Alkali metals are never found as free
elements in nature, however always bonded with another element.
Alkaline Earth Metals: Have two valence electrons and are never found
uncombined in nature.
Transition Metals: They are good conductors of heat and electricity. Can
chemically combine with oxygen to form compounds.
Halogen Family: Halogens have seven valence electrons, why they are the most
active. They are never found free in nature.
Noble Gases: Noble gases are colorless and extremely unreactive. They outer most
energy level is full, and due to this they are called inert. They are found in small
amounts in earth’s atmosphere.
Rare Earth Elements: The thirty rare earth elements are composed of the
lanthanide and actinide series. Most of these elements are synthetic or man-made.
Groups (families) Periods
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DRAWING DIAGRAMS There are a couple of diagrams you need to be able to draw for the test. They are as
follows.
Bohr-Rutherford DiagramLets take an element, with an atomic number less than 20.
Oxygen
• Eight Protons
• Seven Neutrons
• Eight Electrons
Bohr-Rutherford Ion DiagramLets take an element, with an atomic number less than 20.
Oxide (II) ion
• Eight Protons
• Seven Neutrons
• Ten Electrons
Lewis DiagramsLets take any element for example Sodium it has the chemical symbol of Na.
Sodium
• The symbol represents neutrons, protons and all electrons excluding valance
electrons.
• Valences electrons are represented by dots on each side of the symbol.
• The order of placing the dots is Top, Bottom, Right, Left.
• Since Sodium has one valence electron it would look like this:
• With Ions will have the valence electron layer full with either
8 electrons or two.
8 P
8 N
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IONS
Introduction Atoms are made up of particles, which either have a positive charge or
negative charge. The positive or negative charges cancel each other out, so the net
charge in an atom is zero. The positively charged particle is called a proton, and thenegatively charged particle is called the electron. In atoms the protons are in the
center and the electrons are on the outside, only electrons can be removed from
atoms. If you add electrons to an atoms in becomes negatively charged, and if you
remove them they become positively charged. An atom with a positive or negative
charge is called an Ion.
Cations
Cations are ions with a positive charge. If an atom loses an electron
or more it is called cation.
Anions
Anions are ions with a negative charge. If an atom gains an electron
or more it is called an anion.
Why does this occur?
All atoms want to become stable, and in order to become
stable there outer most energy level must be
complete. To do this they can either lose an
electron and become a cation or gain an electron
and become anion. The atom will do what ever is
easier, in other words it would prefer losing an
electron instead on gaining seven in the following
case.
* Note: We only work with groups 1, 2,13,15,16,
and 17 when dealing with ions.
Naming IonsPositive Ions: The name is the same of the element followed by ion.
E.g. Na+ = Sodium ion
Negative Ions: The name is determined by removing the end and adding ide.
E.g. O- = Oxide ion
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IONIC BONDING Ions have charges to them, either they are negatively charged or positively. Due to
this fact some ions are attracted to others and form bonds, this results in and Ionic
compound with a neutral charge.
How it Works You begin with two Ion’s a metal and a non-metal. The metal will have a
positive charge and the non-metal will have a negative charge. Follow the following
instructions to make the ionic compound.
1. Write the symbol of the metal first with its charge on the top. (Lithium
ion)
Li!!
2. Next write the symbol of the non-metal with it’s charge on the top. (Oxide
ion)
Li!! O!!
3. Swap the charges and write them as subscripts, remove the positive or
negative signs.
Li!O!
4. If there is a 1 in the subscript remove it (1 is assumed) or if the subscripts
can be simplified. Simplify them.
Li!O 5. Voilà you have your Ionic Compound.
Ion+1 Ion-1 Netural
IonicCompound
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POLYATOMIC BONDING Some ions bond with each other and instead of making neutral bonds they make
charged polyatomic compounds. These compounds, their formula and charges are listed
below.
You do not have to memorize these polyatomic ions. There will be a chart similar to
this given on a test. These ions bond with other ions to become natural.
How it Works You begin with a polyatomic compound, and an Ion. The one with the positive
charge is written first and the one with the negative charge is written after.
1. Write the compound or ion that has the positive charge first and the one
with the negative charge second
Ca!! PO!!! 2. Swap the charges, remove the plus and minus signs and simplify if
possible (get ride of the 1’s as well)
Ca!(PO!)!
Polyatomic
Compound Ion+ or -
NeturalPolyatmoicCompound
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MOLECULAR COMPOUNDS Unlike how Ionic Compounds bond attracted ions, molecular compounds form when
you have two non-metals that can share electrons (something the electrons are around one
nuclei and sometimes the other). This type of bonding is also known as covalent compounds
How it worksWhen two non-metals have enough electrons to satisfy the other atom’s needs
to become stable, and there is enough energy they will bonded and share some
electrons. Consider the following example:
We have two hydrogen atoms having one valences electron, and one oxygen
atom with six valence electrons. If one hydrogen atom, and the oxygen atom were to
share one electron with each other, the hydrogen would have a complete set but the
oxygen still would need one more electron. If the oxygen shared another electron with
the other hydrogen, the hydrogen shared its electron. All the atoms would be stable
in terms of reactivity, and you would form the compound known as Dihydrogen
Monoxide, commonly called water.
1p+1p+ 8p+
8no
Two hydrogen atoms One oxygen atom (only
valence electrons drawn)
One molecule of
DiHydrogen Monoxide
8p+
8no
1p+1p+
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Types of bondsThere are three types of bonds; atoms can make in order to combine into a
compound. The bonds vary based upon the amount of electrons available and the
abundance of an atom.
Single Bond A single bond is similar to the example on the page above, where both
atoms are sharing one electron with the other (2 electrons in total). In the
case above, each hydrogen atom was sharing one electron with oxygen, and
oxygen was sharing one electron with each hydrogen atom.
Double Bond
A double bond occurs when each atom shares two of its electrons with
the other atom, making four electrons in total. This can be seen in Carbon
Dioxide, where the carbon atom, and the oxygen atoms are sharing two
electrons each to form the bond.
Triple Bond
A triple bond occurs when three pairs of electrons are shared. Usually
one shares four, and the other shares two. This can be observed in Carbon
Monoxide.
Naming the CompoundsNaming a molecular compound is fairly simple there are a set of rules and
prefixes, which have to be memorized.
1. Write the atom in the lower left of the periodic table first, followed by the
second atom.
2. Next count the number of atoms for each element.
3. Change the ending of the second element to –ide.
4. Place the appropriate prefix in front of the name.
5. If there is mono in front of the first element, remove it.
Exceptions
Some compounds have common name they are as follows:
Value Prefix
1 Mono
2 Di
3 Tri
4 Tetra
5 Penta6 Hexa
7 Hepta
CH4 - Methane
H2O2 – Hydrogen Peroxide
NH2 - Ammonia
O3 - Ozone
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Diatomic GasesDiatomic gases are gases that are always bonded, with them to form stable
gas compounds. All of the Halogens plus Hydrogen, Oxygen, and Nitrogen form
diatomic gases. You will never find just a single atom of these elements in the open.
CHEMICAL REACTIONS There are two parts of a chemical reaction, the reactants and the products. The
products the end result of the equation, and the reactants are what you start with. After each
compound in the equation you add (s) for solid, (g) for gas, (aq) for aqueous, and (l) for liquid.
There are five types of chemical reactions, theses reactions result in different products, and
start with different reactants.
DecompositionDecomposition is when you have a single compound, which breaks down into
two or more different elements.
Single ReplacementSingle replacement is where a metal or non-metal will replace another metal
or non-metal in a compound.
Double ReplacementDouble replacement is when the ions in the compounds, switch places with
each other.
Synthesis A synthesis reaction occurs when two substances form one compound.
CombustionSimilar to a synthesis reaction, except when two or more substance react to
produce an oxide and energy.
CHEMICAL EQUATIONS In order to describe a chemical reaction we can right chemical equations. You will be
given a word equation, which will be converted in chemical equations. The following steps
are used to convert a word equation into a chemical equation.
1. Write the compounds one by one, making sure of the charges.
2. Place (s), (l), (g), (aq), to indicated the state of the compound.
3. Balance each side of the equation.
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Balancing EquationsWhen balancing equations we must realize that matter cannot be made nor
destroyed. If you to have 2 atoms of Hydrogen on one side of the equation, you must
have 2 atoms of Hydrogen on the other side. Once you have written the compounds
properly you can balance the equation. Following is an example of balancing a
chemical equation.
! + ! = ! – Write all the compounds in the equations.
! + ! = 2! – We have two oxygen’s on the left side and one of the other,
so we add a two as the coefficient of H2O.
2! + ! = 2! – Now we have 4 atoms of hydrogen on the right, and two on
the left, so we can add 2 as the coefficient.
2! + ! = 2! – Now you have a balanced equation.