Commercialization and Commercialization and implementation of the energy- implementation of the energy-

and recourse-saving and recourse-saving technologies at the enterprises technologies at the enterprises

of Saint-Petersburg Polymer of Saint-Petersburg Polymer ClusterCluster

Alena V. DyninaAlena V. Dynina““KP” Plant, LLCKP” Plant, LLC

International innovation weekInternational innovation week

The NetherlandsThe Netherlands

The newest nanotechnologies along with computer-information The newest nanotechnologies along with computer-information technologies and biotechnologies are the ground of scientific technologies and biotechnologies are the ground of scientific and technological revolution of the XXIst century comparable and technological revolution of the XXIst century comparable with transformations in techniques and in the society caused by with transformations in techniques and in the society caused by the most influential discoveries of the XXth century. And these the most influential discoveries of the XXth century. And these technologies sometimes can surpass transformations in scales technologies sometimes can surpass transformations in scales

Nanotechnologies may become a powerful instrument of the Nanotechnologies may become a powerful instrument of the Russian technological complex integration in the international Russian technological complex integration in the international market of Hi-Tech and provide competitiveness of domestic market of Hi-Tech and provide competitiveness of domestic productsproducts

Nanotechnologies RevolutionNanotechnologies Revolution

Nanomaterials and Nanomaterials and pulping technologiespulping technologies

Nanomaterials is the materialsNanomaterials is the materialswhich contain the structuralwhich contain the structuralelements with geometricalelements with geometricaldimensions less then 100dimensions less then 100nanometers and which havenanometers and which haveabsolutely new properties,absolutely new properties,operational and functional operational and functional characteristicscharacteristics

The 7The 7thth International Conference on nanotechnologies International Conference on nanotechnologies (Visbaden, 2004) (Visbaden, 2004)

- Nano bodies, nano fibersNano bodies, nano fibers

- Nano pipes and fullerenesNano pipes and fullerenes

- Nanoporous structuresNanoporous structures- NanodispersionsNanodispersions

- Nanostructured surfaces andNanostructured surfaces and filmsfilms- Nano crystal materialsNano crystal materials

According to the Conference the following nanomaterials were underlined:

Structures on base of carbonStructures on base of carbon

*Graphene model in the form of *Graphene model in the form of 2D hexagonal latitude2D hexagonal latitude

**Fullerene modelFullerene model

*Mono wall carbon nano pipe model*Mono wall carbon nano pipe model **Poly walls carbon nano pipe modelPoly walls carbon nano pipe model

Upwards technologyUpwards technology

The technology " upwards " is coming down to nanoscale object production by means of particular atoms and molecules construction. In almost every technology of atoms collecting from separate atoms condensation is reasonable

*Condensation (from lat. condenso – to compact, to thicken) is a substance transfer from gas to liquid or solid caused by cooling or compression

Within condensation of nanoelements production there is a need to dissolve atoms from their micro body. Dissolving can be conducted by means of thermal or laser heating of micro body. Dissolved atoms should be transferred to lower temperature zone where condensation will start.

On base of condensation fullerenes, carbon pipes, nano clusters, and nano elements of different scales can be produced.

Downwards technologyDownwards technology

The "downwards" technology is based on scales reduction of bodies by mechanicalThe "downwards" technology is based on scales reduction of bodies by mechanicalor other processing up to the nanometers scale production. For example nano or other processing up to the nanometers scale production. For example nano elements can be produced by macro scale material milling in special millelements can be produced by macro scale material milling in special mill

Structure by lithographyStructure by lithography

NANOCOVERINGSNANOCOVERINGS-Coverings combining polymer layers and nano Coverings combining polymer layers and nano elements of chrystal (automobile mirrors, elements of chrystal (automobile mirrors, bathroom mirrors, glasses of digital cameras, sport bathroom mirrors, glasses of digital cameras, sport glasses etc.);glasses etc.);

-CoveringsCoverings on base of sol/jelly –technologies (can on base of sol/jelly –technologies (can be applied to wind screens to make them more be applied to wind screens to make them more sustained to scratches);sustained to scratches);

-Dirt- and humidity resisting color for outwalls;Dirt- and humidity resisting color for outwalls;

-Multilayer paper for inkjet printers.Multilayer paper for inkjet printers.

*Nanocovering for automobile mirror. *Nanocovering for automobile mirror. On the picture above the left side of On the picture above the left side of mirror id processed, on the lower mirror id processed, on the lower picture – the right sidepicture – the right side

Nanotechnologies in medicineNanotechnologies in medicine

-Ag nano elements antibacterialAg nano elements antibacterial

For instance antibacterial dressings with nano elements of Ag. Nano elements kill even For instance antibacterial dressings with nano elements of Ag. Nano elements kill even those micro organisms who are not sensitive to standard antisepticsthose micro organisms who are not sensitive to standard antiseptics. . Tube wheel’s Tube wheel’s coating antisepticise clothes during washingcoating antisepticise clothes during washing.. The German scientists introduced ions of The German scientists introduced ions of Ag in clothes and bed-clothes which are recommended to use by people with eczema Ag in clothes and bed-clothes which are recommended to use by people with eczema and other skin diseases.and other skin diseases.

-creation of up-molecular medicinal capsulesUsing these capsules high dozes of medicines can be transferred in the source of Using these capsules high dozes of medicines can be transferred in the source of disease minimizing by-effectsdisease minimizing by-effects

Use of technologies of PPU and UHMWPE spraying.

Warm loses reduction owing to heat- and hydro-insulation.

Suah coatings’ application leads to energy consumption reduction on 435 гКал/ч (323,64 гКал/мес).

*According to the SPbSUFE payback period in energy-saving sphere - 4,8 years

POLYMER COATING OF ROOF PLACES AND POLYMER COATING OF ROOF PLACES AND SUBBASEMENTSSUBBASEMENTS

POLYMER NANO COATINGS AND DE-ICING MATERIALS POLYMER NANO COATINGS AND DE-ICING MATERIALS IMPLEMENTATIONIMPLEMENTATION

De-icing and nano materials De-icing and nano materials coatings of buildings 'roofs coatings of buildings 'roofs by colors of “Pigment” and by colors of “Pigment” and SPbSTI (TU)SPbSTI (TU)

Use of UHMWPE sheets vice Use of UHMWPE sheets vice galvanized irongalvanized iron

De-icing and nano materials De-icing and nano materials coatings of buildings 'roofs coatings of buildings 'roofs by colors of “Pigment” and by colors of “Pigment” and SPbSTI (TU)SPbSTI (TU)

Use of UHMWPE sheets vice Use of UHMWPE sheets vice galvanized irongalvanized iron

Roof spaces covering by Roof spaces covering by heat-insulation materials heat-insulation materials (PPU), produced by LLC (PPU), produced by LLC “Institute of polymers”:“Institute of polymers”:

««foamed glassfoamed glass», »,

««isothermisotherm»»

Buildings visors’ de-icing covering Buildings visors’ de-icing covering on base of UHMWPE. Technology on base of UHMWPE. Technology is produced by SPbSU, CRDI is produced by SPbSU, CRDI “Prometi” and LLC “Institute of “Prometi” and LLC “Institute of polymers”polymers”

Subbasement coating (hydro Subbasement coating (hydro isolation) by composite isolation) by composite materials on base of materials on base of UHMWPE. Technologies are UHMWPE. Technologies are produced by chemical produced by chemical faculty of SPbSU, LLC faculty of SPbSU, LLC “Institute of polymers”. Pre-“Institute of polymers”. Pre-preg siding by Ioffe Institute. preg siding by Ioffe Institute. Powdered colors spraying of Powdered colors spraying of plumbing wareplumbing wareHeat- and hydro isolation of Heat- and hydro isolation of

subbasements by PPU. subbasements by PPU. Technology is produced by LLC Technology is produced by LLC “Institute of polymers”“Institute of polymers”

Heat- and hydro isolation of Heat- and hydro isolation of subbasements by PPU. subbasements by PPU. Technology is produced by LLC Technology is produced by LLC “Institute of polymers”“Institute of polymers”

Heat isolation of heating tubesHeat isolation of heating tubes

Energy-saving lightening Energy-saving lightening devices and devices and management systemmanagement system

UHMWPE coverings of metal UHMWPE coverings of metal weeperweeper

утеплитель из ППУ

ВоздухT ≈ 0 °C

Теплый воздухT ≈ 25 °C

СнегАнтиобледенительное покрытие

Водосточный гребеньНаноантиобледенительное покрытие

Теплый воздух от стен и подвала

Снежный гранулят

ARRANGEMENTS COMPLEX FOR ICING PREVENTIONARRANGEMENTS COMPLEX FOR ICING PREVENTION

PPU COATINGPPU COATING

LIST OF SAMPLES IN NATURE TESTING LABLIST OF SAMPLES IN NATURE TESTING LAB

№ п/п Type of coating№

п/п Type of coating

1 СВМПЭ газопламенным методом 12Органосиликатная композиция (шаровая)

без грунтовки

2 Композиция на основе СВМПЭ газопламенным методом 13Органосиликатная композиция (зеленая) с

нанодобавками

3 Листы с СВМПЭ 1х1 м электростатический метод 14Органосиликатная композиция на грунтовке

(вариант 2)36 часов

4 Листы с порошковым окрашиванием 1х1 м 15Органосиликатная композиция на грунтовке

(вариант 1)36 часов

5 Порошковые краски с нанодобавками 16Органосиликатная композиция на грунтовке

(вариант 1)

72 часа

6 Краска «Пигмент» 17Органосиликатная композиция на грунтовке

(вариант 2)72 часа

7 Краска «Пигмент» с нанодобавками 18 Грунтовый слой + эпоксидная смола

8 Органосиликатная композиция (зеленая) без грунтовки 19Композиция с СВМПЭ с грунтовкой и чистый

СВМПЭ

9Органосиликатная композиция (красно – коричневая)

без грунтовки20 Чистый лист СВМЭТолщина 30 ммТолщина 2 мм

10Композиция с СВМПЭ с грунтовкой и СВМПЭ+

гидроокись алюминия21

Листы 1х1 м препрега и 6 листов 3м (длина)х1,2 м (ширина) под окрашивание композицией

института силикатов

11 Композиция СВМПЭ с грунтовкой и СВМПЭ+ тальк 22 Композиция с СВМПЭ с нанодобавкой

FIRST TESTING RESULTSFIRST TESTING RESULTS

This is the samples of organo silicate compounds with nano elementsThis is the samples of organo silicate compounds with nano elements

FIRST TESTING RESULTSFIRST TESTING RESULTS

FIRST TESTING RESULTSFIRST TESTING RESULTS

UHMWPE SHEETSUHMWPE SHEETS

Thin 30 mm Thin 2 mm

Samples of coatings by color OS-12-03 with pre-coating

SAMPLES OF COATINGS AND FIRST SAMPLES OF COATINGS AND FIRST RESULTSRESULTS

Покрытие Характеристика покрытия

Натурные наблюдения

Покрытие Характеристика покрытия

Натурные наблюдения

СВМПЭ

(газопламенное напыление

Шероховатая поверхность, толщина неравномерная.

Материал при нанесении выгорает

Наледь хорошо скатывается

Первый слой грунтовка(вариант 1), второй слой шаровая органосиликатная композиция

Разводы темного цвета, небольшая шероховатость на отдельных участках листа

Снег легко счищается с кровли

Органосиликатная композиция ОС–12-03

(шаровая)

наномодифицированная

Поверхность ровная, гладкая

Наледь хорошо скатывается (лучше, чем на образцах I-1, I-2, I-3, I-4), но при отбивке материал с кровельного железа отстает

Первый слой грунтовка(вариант 2), второй слой шаровая органосиликатная композиция

Покрытие ровное, гладкое

Снег легко счищается с кровли

Органосиликатная композиция (красно-коричневая),наномодифицированная

Поверхность ровная, гладкая

Наледь хорошо скатывается (лучше, чем на образцах I-1, I-2, I-3, I-4), но при отбивке материал с кровельного железа отстает

Композиция на основе СВМПЭ с нанодобавками

Шероховатая поверхность, толщина неравномерная, материал при нанесении выгорает

Снег легко счищается с кровли

Органосиликатная композиция (зеленая)наномодифицированная

Поверхность ровная, гладкая

Наледь хорошо скатывается (лучше, чем на образцах I-1, I-2, I-3, I-4), но при отбивке материал с кровельного железа отстает

Лист СВМПЭ марки 2.7 ×1.2 м толщиной 30 мм

Поверхность ровная, гладкая

Наледь хорошо скатывается, остаются небольшие области наледи

Композиция на основе СВМПЭ

Шероховатая поверхность, толщина неравномерная, материал при нанесении полностью не расплавляется.

Часть наледи остается на поверхности, плохо скатывается

Лист СВМПЭ марки 2.7 ×1.2 м толщиной 2 мм

Поверхность ровная, гладкая

Наледь хорошо скатывается

ANTI-ICING COATINGS

Polymer anti-icing coatings on base of UHMWPE can decide a number of Polymer anti-icing coatings on base of UHMWPE can decide a number of problemsproblems::

Owing to liquidity index of UHMWPE during heating material closes existing doors Owing to liquidity index of UHMWPE during heating material closes existing doors and holes and pot probe hemsand holes and pot probe hems;;

High level of resistance protect the surface of the roof from the mechanical High level of resistance protect the surface of the roof from the mechanical influenceinfluence;;

UHMWPE elasticity index helps to preserve proof during thermal enlargements in UHMWPE elasticity index helps to preserve proof during thermal enlargements in winter and summer seasonwinter and summer season;;

High adhesion of anti-icing coatings on base of UHMWPE protects the surface from High adhesion of anti-icing coatings on base of UHMWPE protects the surface from corrosion and thus polymer coating’s exploitation period can be more than 10 corrosion and thus polymer coating’s exploitation period can be more than 10 years.years.

THANK YOU!

Alena DyninaPolymer cluster