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Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D...

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Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning July 1) Scientific Thermal pressure studies in laser heated DAC at 20-35 GPa (Kubo, Duffy, Shen) Finite element modeling of thermal structures in laser-heated diamond cell (Kiefer and Duffy) Ultrahigh P-T studies of crystal structures and phase relations SiO2 (Shieh, Duffy, Shen) MgSiO3 (Shim, Jeanloz, Duffy, Shen) Outreach Laser heating workshop held in March 2004 at APS
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Page 1: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

Compres Laser Heating Activities

Technical

CO2 laser heating system at GSECARS

Component of ID-D upgrade (in progress)

Staff: Andy Campbell (50%, beginning July 1)

Scientific

Thermal pressure studies in laser heated DAC at 20-35 GPa (Kubo, Duffy, Shen)

Finite element modeling of thermal structures in laser-heated diamond cell (Kiefer and Duffy)

Ultrahigh P-T studies of crystal structures and phase relations

SiO2 (Shieh, Duffy, Shen)

MgSiO3 (Shim, Jeanloz, Duffy, Shen)

Outreach

Laser heating workshop held in March 2004 at APS

Page 2: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

Laser-Heated Diamond Anvil Cell

Page 3: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.
Page 4: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.
Page 5: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.
Page 6: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

Gasket

InsulationDiamond

Diamond

Sample

Al2O3

The Computational Grid

Finite element modeling (Flexpde) * Local refinement of mesh. * 1600-4000 nodes

Page 7: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

Temperature (K/1000)

Insulation

Sample

Al2O3

Temperature Distribution in LHDAC

Page 8: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

ΔTaxial (K)

Predicted Axial Temperature Drop

Page 9: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

YAG:Ce

Ruby

Ar

Silicate + Pt

175m

X-ray fluorescence of YAG:Ce

Thermal emission from heated sample After multiple heating cycles

Laser heating of Pyrope (Mg3Al2Si3O12) Garnet at ~30 GPa

Precision (~3 micron) alignment of heating and x-ray spots achieved using fluorescent YAG:Ce crystals

Page 10: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

10 15 20

?

?

Pt1

11

Pt2

00

Pt2

20

Pt3

11

Pt2

22

Pt3

31A

r422

Pt4

20

Pt4

00+

Ar4

20A

r331

Ar3

11

Ar2

20

Ar2

00

Ar1

11

MgO

422

MgO

420

MgO

331

MgO

400

MgO

222

MgO

311+

Ar2

22MgO

220

MgO

200

Inte

nsi

ty (

a.u

.)

2Theta / degrees (lambda=0.3311A)

before laser heating after laser heating

MgO

111

MgO+Pt (in argon)

~18GPa

Page 11: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

20181614121086

Two Theta (

Inte

nsi

ty

Pt PtPt Pt Pt

Pt Pt

C

Pt

Pt

C

Pt

CCC

C

PtPt

PtPt

Pt

PtPtPt

Pt

Pt

C

CaCl2

PbO2

121(2) GPaT quench

117(2) GPaPreheat

129(4) GPa1860(400) K

123(3) GPa~1000(400) K

d (Å)3 2 1

Highest pressure experiments (stishovite starting material)

3500

3000

2500

2000

1500

1000

500

2500200015001000Depth (km)

3500

3000

2500

2000

1500

1000

500

Tem

pe

ratu

re (

K)

120100806040

Pressure (GPa)

Stishovite Cristobalite Silica glass

Murakami

CaCl2-type

Stishovite

Geotherm

Murakami

Page 12: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

Inte

nsi

ty

20181614121086

Two Theta (2

P

P

P

P

C

CC C

ReRe

Pt

Pt

Ar Ar

Ar

Pt

D

77GPa, 300K

79GPa,1870K

101GPa,1500K

3 2d (Å)

2.5 1.5

85GPa,2200K

CaCl2PbO2

Cristobalite starting material

Page 13: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

Conclusions:

CaCl2-phase of SiO2 stable to 131 GPa (2800 km depth in the mantle)

Complications:

Kinetic factors/ metastable phases

length, homogeneity of heating

starting material

stishovite (CaCl2-type)

glass

cristobalite

deviatoric stress, minor elements

low temperature (<1000 K) metastable phases also observed (Prakapenka et al., 2004)

Teter et al., 1998

Page 14: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

MgSiO3 perovskite to 116 GPa (2550 km depth)

Shim et al., Science 2001; Geophys. Res. Lett., in press.

Page 15: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

MgSiO3 perovskite at 140 GPa

Cmcm post-perovskite phase (Murakami et al., Science 2004) +

Modified MgSiO3 perovskite

(Shim et al., Science 2001)

Shim et al., Geophys. Res. Lett., in press

Page 16: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

5 10 15

MgGeO3

Intensity / a.u.

2Theta / degrees

74 GPa, RT (Pv)

40 GPa, RT (Pv)

10 GPa, RT (En)

en

enen

en

en

enen

en en en?ar

ar

ar

steel

pt

steel

en?

pt

pv

?

?pv

arpvpv

pv

?

ptpv

ar

pt

steel

steelpv

pvpv

arpvpv

pv

pv

pvpv

pv

pv

pvpv

pv

arpv

arpv

pv + pt

steel pv?

arpt steel pvpv

pv

pvpv

pv

?

Enstatite -type

Perovskite -type

10 GPa

40 GPa

74 GPa

Laser Heating of

MgGeO3 at

HPCAT, April, 2004

Page 17: Compres Laser Heating Activities Technical CO2 laser heating system at GSECARS Component of ID-D upgrade (in progress) Staff: Andy Campbell (50%, beginning.

Laser heating workshop

  -- March 19-20, 2004 at the Advanced Photon Source

-- 41 participants including representation from Europe, Japan, and the US

-- Sponsored by COMPRES and GSECARS

-- Invited Speakers:

Heinz (Chicago) Yoo (LLNL) Kavner (UCLA)

Tschauner (UNLV) Shen (Chicago) Kiefer (NMSU)

Shim (MIT) Lin (CIW) Zha (Cornell)

Sturhahn (ANL) Meng (HPCAT) Clark (LBNL)

Sata (JAMSTEC) Dubrovinsky (Bayreuth)

 -- Discussion Sessions:

What features are required in the next generation laser heating system at GSECARS?

What are the key technical issues for next-generation laser heating?

What community-wide efforts are needed to advance laser heating capabilities at synchrotrons?

-- Dissemination

Meeting presentations (PPT) posted at COMPRES website

Meeting summary document available for dissemination

 

 

 


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