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Cultivation Protocol Manual

ProKure V LIQUID

Disinfectant & Deodorizer EPA Reg. No. 87508-3-89334 EPA Est. No. 62788-AL-001

ProKure D GAS Deodorizer


The purpose of this document is to provide Federal- and State-compliant Protocols for Good Manufacturing, safety requirements along with MSDS, and other related information needed for the disinfection and deodorization of agriculture facilities, equipment, tools, cloning beds, grow beds, racks, hoses, extraction equipment, kitchen, water systems and most other facility equipment. ProKure V is a hospital-grade EPA-registered disinfectant for hard, non-porous surfaces. ProKure V is environmentally safe and, per the registered EPA claim, ProKure V leaves no harmful residue, unlike other disinfectants. ProKure V is not approved by the EPA for use on plants. It is a violation of Federal Law to use this product in a manner inconsistent with the labeling. Read the entire EPA label and use strictly in accordance with precautionary statements and instructions. ProKure D is a gas deodorizer that may be used in enclosed, unoccupied areas to eliminate the odors associated with indoor growing environments. The information presented has been compiled from sources considered to be dependable and is accurate to the best of Clarion’s knowledge. Please check all State, Federal and local guidelines for your facility. Agriculture and horticulture will be referred to within as agriculture.


Table of Contents

ProKure Products 4 – 5 ProKure V Liquid Disinfectant & Deodorizer 4 ProKure D Gas Deodorizer 4 ProKure Applica on Accessories 5 Personal Protec Equipment (PPE) 5 Product Prepara on 6 – 8 Prepara on of Disinfec on Strength ProKure V 6 ProKure V, Available Sizes and Dispensers 6 Prepara on and Storage Instruc ons 6 ProKure V Concentra and Use Chart 7 Calcula ng Cubic Feet ( 3) for ProKure D Fast & Extended Use Gas 8 ProKure D Extended Use for Odor Control 8 ProKure D Fast Use

Two Methods of Ac ng Fast Use Gas 9 9

General Disinfec on and Deodoriza on of Facility, Tools and Equipment 10 What To Do In Case of an Outbreak 10 Protocols for Disinfec on and Deodoriza on of Indoor Spaces 10 – 11 Cul on, Clone, and Vegeta oms Drying Rooms Trimming and Packaging Areas Kitchens Protocols for Disinfec on and Deodoriza on of Equipment, Tools, and Hard Surfaces 12 – 13 Grow Beds, Cloning Beds, and Humidity Domes Removing Slime and Algae from Tanks, Drums, Water Lines, and Pumps Scissors, Cu ers, Tools, and Jars Nutrient Totes, Drums, and Other Tanks Drying Racks Kitchen Equipment, Extrac n Equipment, and Other Food-Contact Surfaces ProKure D Fast Use “Gas in Use” Warning Placard 14 Material Safety Data Sheets (MSDS / SDS) 15 – 30

Contact a ProKure1 Agriculture Specialist:

Cassandra Dittus

Clarion, LLC.

[email protected](866) 206-1301

Please visit www.prokure1.com for training and support materials.

http://www.prokure1.com/


ProKure Products The active ingredient in ProKure products is chlorine dioxide (ClO2). When it is finished working, ClO2 breaks

down into water and table salt, leaving no harmful residues.

ProKure V, when used as directed, is an effective Disinfectant,

Sanitizer, Tuberculocide, Virucide*, Fungicide, Algaecide, Slimicide

and Deodorizer. ProKure V is an EPA-registered hospital-grade

liquid disinfectant for hard, non-porous surfaces that is effective in

the prevention, control and removal of mold, mildew, fungus, odor

and other issues that negatively affect the safety and viability of

industrially grown crops. When combined with cool water, the

ProKure V pouch generates a liquid solution of (ClO2).

The ProKure V pouch is available in four sizes; One Quart, One

Gallon, Five Gallons, and 25 Gallons; and can be applied by spraying, pouring, wiping and mopping onto any

hard, non-porous surface.

ProKure D is a deodorizer that releases ClO2 gas to neutralize odors associated with enclosed, unoccupied

facilities.

ProKure D Fast Use Gas Pouch releases a powerful gas upon contact with water and removes

odors within approximately 4 hours of activation. Wear gloves, non-ventilated safety goggles,

and a respirator with acid/gas cartridges when activating the product. Depart the space as

quickly as possible after activating the product and allow 1 hour for treated space to air out

before reoccupying. Product may oxidize and harm plants. Remove people, pets, and fish from

space prior to treatment.

ProKure D Extended Use Gas Pouches generate small amounts of gas with exposure to

humidity in the air to continuously control odors for up to 30 days inside facilities of all

types. ProKure D Extended Release Gas treatment pouches, when used as directed, emit

low levels of ClO2 gas to keep rooms odor-free.

Read all labels and protocols prior to use.


ProKure Application Accessories

[123-0029] Black Pump Sprayer 2 gallon

[123-0033] 8 Gallon Roller Sprayer

Assorted Sizes of ProKure Dispensers [185-2004] 20-Gallon Closed Head Drum [185-2002] 5-Gallon Stacker Dispenser [185-3008] 32 oz. Spray Bottle w/ Sprayer

Personal Protective Equipment (PPE) required: Always wear PPE, including gloves, non-ventilated safety goggles, and a respirator with acid/gas cartridge when activating ProKure D Fast Use Deodorizing Gas pouches and when spraying ProKure V Liquid Disinfectant. Prior to using ProKure V, verify formula concentration via ClO2 test strips.

[123-0025]

Medium [123-0038]

Large [123-0039]

[123-0043] [185-4006]

Non-Vented Safety Goggles 3M Reusable Respirator Half-Face 3M 60923 Organic Vapor/Acid Gas

Cartridge/Filter Combo P100 – 2/pkg. LaMotte ClO2 Test Strips

– 50 ct. 6200 (Medium) 6300 (Large)


To disinfect hard, non-porous surfaces, use ProKure V Liquid Disinfectant.

Product Preparation – Disinfection Strength ProKure V liquid at 100 parts per million (PPM) While ProKure V is available in many sizes, most facilities use either the 5-gallon or 20-gallon systems. ProKure

V kills odor-causing bacteria, mold, and mildew on hard, non-porous surfaces. Contact us at (866) 206-1301 for

assistance or any questions.

Immersing the pre-measured ProKure V pouch(es) in the appropriate amount of water creates a 100 PPM

solution of ClO2. Allow one (1) hour before use to ensure solution reaches full strength. Apply ProKure V by

mopping, spraying, pouring, or wiping and allow the treated area to remain wet for 10 minutes. Wipe any non-

stainless metals, glass and mirrors after application to avoid smears. ProKure V is safe for use on floors, walls,

furniture, stainless steel, glass, vinyl, polypropylene, PVC or other hard, non-permeable surfaces and may be

allowed to air dry.

ProKure V, Available Sizes and Dispensers

Water Volume 32 Ounces @

100 ppm One (1) Gallon @

100 ppm Five (5) Gallons @

100 ppm Twenty-Five

(25) Gallons @ 100 ppm

Packet SKU 185-0006 185-0008 185-0005B 185-0002B

ProKure V Pouch(es) One One One Two

Pouch Size 0.042 oz. 0.17 oz. 0.84 oz. 4.2 oz.

Dispenser SKU 185-3008 185-3009 185-2002 185-2004

Dispenser 32 oz. Spray

Bottle Gallon Bottle 5 Gallon Dispenser

20 Gallon Closed-Head Drum

ProKure V Liquid Disinfectant Preparation and Storage Instructions:

5. If preparing large quantities of solution, transfer into appropriate applicator. 6. Don PPE and apply by spraying, pouring, wiping and mopping. See Protocols for Disinfection of

Facility, Tools, and Equipment (pages 10-13) for specific application instructions. Activated ProKure V solution lasts for 15 days when stored in an oxidation-proof, dark, closed or sealed container in a cool, dark location. Prior to use, verify formula concentration via chlorine dioxide test strips (185-4006) to determine appropriate concentration. When solution is exhausted, remove the spent white pouch and discard. Please see full directions and precautions on the ProKure V EPA label (EPA Reg. No. 87508-3-89334), including safety information and dilution directions.


ProKure V Concentration and Use Chart

Uses Category Concentration

in Parts Per Million (PPM)

Dilution from 100 PPM

Dilution from 500 PPM

Recommended Contact Time

Soaking Tools (cutters, scissors), Mopping Floors

Heavy Odor and Resin Removal

500 N/A N/A < 10 Minutes

All Hard Surfaces, Medium Deodorization, Water Systems

Hard Surface Disinfection & Odor Control

100 N/A

1:4 (one part 500 PPM solution to four [4]

parts water)

10 Minutes

Final Rinse for Plastic, Glass, or Metal Containers

Sanitizer 30

1:3 (one part 100 PPM solution to two [2]

parts water)

1:16 (one part 500 ppm solution to fifteen [15] parts water)

Allow to Dry

No-Rinse Surface Sanitizer for Hard, Non-Porous, Non-Food-Contact Surfaces

Sanitizer 20

1:5 (one part 100 PPM solution to four [4]

parts water)

1:25 (one part 500 ppm solution to twenty-

four [24] parts water)

5 Minutes

No-Rinse Hard Surface/Food Contact Surface Sanitizer and Fruit/Vegetable Wash, Extend Life of Cut Flowers

Sanitizer 5

1:20 (one part 100 PPM

solution to nineteen [19] parts water)

1:100 (one part 500 ppm solution to ninety-

nine [99] parts water)

5 Minutes


To deodorize your unoccupied, enclosed facility use ProKure D Fast or Extended Use Gases.

Calculating Cubic Feet (ft3) for ProKure D Fast or Extended Use Gas To calculate the cubic feet of a room, multiply the measurements (in feet) of the length x width x height and round up to the nearest whole number. For example, the room is 32 feet long, 25 feet wide, and 10 feet tall. 32’ x 25’ x 10’ = 8,000 cubic feet (ft3). Always round up when calculating the number of pouches needed.

SKU Description Treatment Area Number of Pouches Required

185-1010 Fast Use Gas 25g Up to 2,500 ft3 8,000 ft3 / 2,500 ft3 = 4 pouches

185-1012 Fast Use Gas 10g Up to 1,000 ft3 8,000 ft3 / 1,000 ft3 = 8 pouches

185-1014 Extended Use Gas 50g Up to 4,000 ft3 8,000 ft3 / 4,000 ft3 = 2 pouches

185-1016 Extended Use Gas 10g Up to 1,000 ft3 8,000 ft3 / 1,000 ft3 = 8 pouches

ProKure D Fast Use Gas 25g is also available without the clamshell and sponge. SKU 185-1010NC.

ProKure D Extended Use Gas For Ongoing Odor Control of Indoor Agriculture Facilities ProKure D Extended Use Gas Pouches generate small amounts of gas with exposure to humidity in the air for up to 30

days. Perfect for controlling odor outside of cultivation facilities by use near exhaust vents, doors, windows and other

openings for extended periods of time. Keep out of reach of children and 18” away from metals and fabrics.

Room

Length = 32 ft.

Hei

ght

= 1

0 f

t.


ProKure D Fast Use Gas For Odor of Indoor Agriculture Facilities Two methods of releasing the ProKure D Fast Use Gas are available. ProKure D Fast Use Gases are sold with a clamshell and sponge for activation (Option 1). The 25-gram product can also be ordered without the clamshell and sponge (185-1010NC) and can be activated using a 12- to 16-ounce plastic cup (Option 2). For best results, clean the space with ProKure V prior to treatment. Spaces being treated with ProKure D should be kept as dark as possible. Fans and closed circulation systems improve performance. If additional organic material is in the room (such as vegetation, soil, fertilizer, mulch, etc.), more packets may be necessary for full effectiveness. Space pouches equally apart in the area to ensure complete coverage. The patented inner white Tyvek® pouch takes approximately 30 to 90 seconds to activate leaving time to exit the space. The gas releases much slower than a fogger. Depart the area as quickly as possible following activation. PPE should be worn at all times.

Two Methods of Activating ProKure D Fast Use Gas Deodorizer TREATMENT PROTOCOL – OPTION 1 (Using the sponge and plastic clamshell) Instructions for use in unoccupied, enclosed spaces: 1. Tear open the foil packet and remove the inner white

pouch. DO NOT OPEN THE INNER WHITE POUCH. 2. Shake the white pouch. 3. Dampen enclosed sponge with water. 4. Insert the base of the white pouch with the wicking

squares (teeth-like indentions) into the dampened sponge.

5. Place pouch with attached sponge into plastic clamshell and snap lid shut. Place clamshell with holes facing up on any flat surface, near the center of the area and approximately 18” away from mirrors, leather, metals, plated surfaces and electronics. Ensure clamshell is out of reach of children and pets.

6. Ensure all doors, windows, and vents (if applicable) are shut and leave the area as dark as possible.

7. Place DO NOT ENTER placard and caution tape at all entry ways.

8. Allow at least four to six hours for the system to work. 9. When treatment is complete, don PPE and enter the

space to remove and dispose of clamshells. 10. Turn on lights and mechanical system and allow

treated area to air out for one (1) hour prior to reoccupying by opening all doors, windows, vents, etc. A mild, residual “indoor pool” smell may persist for 1-2 days after treatment, but diminishes with exposure to light.

TREATMENT PROTOCOL – OPTION 2 (Using single pouch only – No sponge or plastic clamshell) Instructions for use in unoccupied, enclosed spaces: 1. Tear open the foil packet and remove the inner white

pouch. DO NOT OPEN THE INNER WHITE POUCH. 2. Shake the white pouch. 3. Fill a plastic cup with approximately 1.5” of water. 4. Insert the base of the white pouch with the wicking

squares (teeth-like indentions) into the water. Do not spill liquid in cup after white pouch activates.

5. Place plastic cup with pouch on any flat surface, near the center of the area and approxiimately 18” away from mirrors, leather, metals, plated surfaces and electronics. Ensure cup is out of reach of children and pets.

6. Ensure all doors, windows, and vents (if applicable) are shut and leave the area as dark as possible.

7. Place DO NOT ENTER placard and caution tape at all entry ways.

8. Allow at least four to six hours for the system to work. 9. When treatment is complete, don PPE and enter the

space to remove and dispose of pouches. 10. Turn on lights and mechanical system and allow

treated area to air out for one (1) hour prior to reoccupying by opening all doors, windows, vents, etc. A mild, residual “indoor pool” smell may persist for 1-2 days after treatment, but diminishes with exposure to light.

Pouch withwicking squares

Fill with1.5” water

16-oz Cup(or equivalent)


General Disinfection and Deodorization of Facility, Tools and Equipment ProKure V Liquid can be used at disinfection strength (100 PPM) on all hard, non-porous surfaces in a cultivation

facility by spraying, mopping, pouring or wiping floors, walls, sinks, counter tops, bathrooms and any other

equipment not negatively affected by water. ProKure V Liquid Disinfectant is not intended for use on plants.

Depending on the size, growth phase, health and variety, ProKure V liquid can oxidize and harm plants.

ProKure V Liquid at sanitizer strength (5 PPM) is registered as a no-rinse sanitizer for hard, non-porous food-

contact surfaces. Always check manufacturer’s recommendations for disassembling and cleaning your

equipment.

ProKure D Fast Use deodorizing pouches produce ClO2 gas that is able to seep into cracks and crevices, reaching

odors that mechanical cleaning and liquid application cannot reach. ProKure D is intended to be used in

confined, unoccupied indoor spaces. No people, pets or fish may remain in the room during treatment.

Following are protocols designed to maximize the effectiveness of ProKure products on your equipment for

specific applications in your facility.

In case of an outbreak of mold, mildew, and other microorganisms in your grow facility It is rare that a facility using ProKure products will have an outbreak of mold, mildew or other microorganisms. Each grow facility is unique and many variables factor into mitigating an outbreak. If you have an outbreak, please call us as soon as possible at (866) 206-1301 for a free consultation. Our qualified specialists will help you to determine the scope of the outbreak and the best solution to contain and eliminate it.

Protocols for Disinfection and Deodorization of Indoor Spaces The following protocols are intended to disinfect, sanitize, and deodorize grow rooms, buildings and/or greenhouses before and after harvest. Use PPE when applying the product. Always check manufacturer’s recommendations for disassembling and cleaning your equipment. Read instructions fully before proceeding. The following protocol may be used for:

Cultivation, Clone, and Vegetation Rooms

Drying Rooms

Trimming and Packaging Areas

Kitchens


Step 1: Prepare the Space 1. Prepare 100 PPM ProKure V Liquid solution at least 1 hour before disinfection.

2. Walk the area before application. Turn off CO2 generators and exhaust fans. Tape up and/or close all openings, exhaust vents, cracks or other areas where the ProKure gas could escape.

3. Cover and tape any carbon dioxide (CO2) sensors and smoke detectors. 4. Power wash walls, floors, grow beds, racks, tools, hoses, inserts and equipment to remove all dirt,

plant material and other debris prior to disinfection. 5. Apply the ProKure V liquid disinfectant first, then release the ProKure D deodorizing gas per the

instructions below.

Step 2: Apply ProKure V Liquid Disinfectant See page 6 for preparation instructions.

1. Using a sprayer like the ones listed on page 5 of this document, lightly mist walls taking care not to wet any electrical equipment such as electrical outlets, switches, sensors, lights or other items that may be harmed by water.

2. Thoroughly spray down and soak floors, grow beds, drying racks and all other hard surfaces to be disinfected.

3. Allow surfaces to remain visibly wet for 10 minutes.

Step 3: Set up and Activate ProKure D Fast Use Deodorizing Gas Packets See page 8 for calculating the correct number of packets.

1. Prepare the correct number of ProKure D Fast Use Gas Pouches in the space using either Option 1 or Option 2 on page 9. If possible, place clamshells or cups on a stable surface 4 to 6 feet off the ground. ProKure D gas is heavier than air and tends to sink. If running the fan on an enclosed HVAC system, place several of the pouches under the return air vent.

2. Place the ProKure D Fast Use gas pouches in the space to be treated and spread out as evenly as possible to cover the entire space.

3. Turn on wall or ceiling fans to move the air around for better gas dispersion into the space. 4. Turn off all lights, leave the space and close the door behind. 5. Using duct tape or the equivalent, seal any cracks or openings in the door, especially at the bottom

of the door. 6. Place DO NOT ENTER placard and caution tape at all entry ways.

Allow the ProKure D Fast Use gas to circulate for a minimum of 4 hours. Overnight is optimal. The more time ProKure has in contact with all of the room surfaces, the better.

Step 4: After the space has been treated Don PPE if entering the treated area to do the following:

1. Turn on exhaust fans to ventilate the remaining gas. 2. Turn on all of the lights in the space. Light breaks down the ProKure D gas quickly. 3. Remove spent ProKure D pouches and dispose of them in an outside trash receptacle. 4. Pour the liquid remaining in the cups or clamshell down a toilet. Save the cups for the next use. 5. Uncover the CO2 sensors and smoke detectors. 6. Allow one hour for the treated space to air out prior to entering without PPE.

Once the space has aired out, work can begin to set up the space for the next series of plants.


Protocols for Disinfection and Deodorization of Equipment, Tools, and Hard Surfaces

This protocol is intended to fully disinfect, sanitize, and deodorize tools, grow beds, racks, hoses, inserts and most all other grow facility equipment before and after harvest. Use PPE when applying the product. Always check manufacturer’s recommendations for disassembling and cleaning your equipment. Read instructions fully before proceeding.

Grow Beds, Cloning Beds, and Humidity Domes 1. Prepare 100 PPM ProKure V liquid solution at least 1 hour before disinfection. 2. Cloning Bed and Humidity Dome Only:

a. Remove neoprene inserts, mist emitters, pipe fittings and pump. b. Soak in ProKure V solution for at least 10 minutes. No rinse is necessary prior to reassembly.

3. Disassemble the equipment: a. Cloning Bed – cover, cloning bed, wheeled cart, pipes, pipe fittings, reservoir tank and hoses. b. Humidity Dome – trays, dome, and heat mats. c. Grow Bed – grow bed, wheeled cart, potting buckets and any other components.

4. Power wash or rinse to remove dirt and debris. 5. In a well-ventilated area, use a pump sprayer to spray ProKure V on all sides and surfaces of the

equipment. 6. Keep surfaces visibly wet for 10 minutes. 7. Allow to air dry. 8. Reassemble equipment.

Removing Slime & Algae from Tanks, Drums, Water Lines, and Pumps: This product will help control, inhibit or remove algae, fungi, slime or other organic buildups in recirculating water systems. If not removed completely, these can cause future issues. Pumps can be disassembled and the parts soaked in ProKure V to remove slime, algae, hard water deposits, and rust. To disinfect tanks, drums, water lines, and pumps:

1. Flush the system with water 2. Fill the system with ProKure V Disinfection Strength 100 PPM and allow it to dwell for 10 minutes. For

systems with large amounts of additional organic material such as nutrients or thick slime, allow the solution to dwell for up to one hour. The solution will be more effective with a longer exposure time.

3. Purge the system and empty the remaining ProKure solution into a toilet.

ProKure products leave no hazardous residue so the system can be immediately recharged without rinsing.


Disinfection of Scissors, Cutters, Tools, and Jars Cutters, scissors and other implements can be soaked in ProKure V Disinfection Strength 100 PPM for 10 minutes for full disinfection. A stronger solution of ProKure V (~500 PPM) will remove the resins faster.

1. Prepare ProKure V liquid solution in a sealed dispenser at the desired strength at least 1 hour before disinfection.

2. Transfer prepared product from dispenser to a container large enough to completely submerge the desired tool or portion of the tool you wish to clean.

3. Submerge tool in ProKure V liquid and allow it to soak for 10 minutes. 4. Remove tool and firmly wipe off any remaining resins with a paper towel or rag. The tool is now ready

to use. 5. Repeat as tools begin to build up resin.

Disinfection of Nutrient Totes, Drums, and Other Tanks Totes, drums, and tanks hold plant nutrients and contain fungi, algae, and slime that can be difficult to remove. To clean and disinfect, use a concentration of 100 PPM ProKure V liquid.

1. Prepare 100 PPM ProKure V liquid solution at least 1 hour before disinfection. 2. Thoroughly rinse the inside of the tank. 3. Completely drain. 4. Spray all surfaces generously using ProKure V liquid. 5. Let solution sit for at least 30 minutes to dislodge and dissolve organic fungi, algae, and slime. 6. Power wash the inside of the tank. 7. Drain the tank. The equipment is now ready to use.

Drying Rack Decontamination 1. Prepare 100 PPM ProKure V liquid solution at least 1 hour before disinfection. 2. Remove all plant material and debris. 3. Spray ProKure V liquid with a pump sprayer (in a well ventilated area) to all sides and surfaces. 4. Keep surface visibly wet for 10 minutes. 5. Rinse with potable water 6. Allow rack to completely dry before placing plant material.

Kitchen Equipment, Extraction Equipment, and Other Food-Contact Surfaces ProKure V is registered as a liquid sanitizer for hard, non-porous food-contact surfaces. Use the following

dilution instructions per the EPA label. Always check manufacturer’s recommendations for disassembling and

cleaning your equipment.

Concentration Use Use a Dilution Device or Sprayer

with a Dilution Ratio of

100 PPM Disinfectant Strength: For use on all non-porous hard surfaces, including non-porous food-contact surfaces. Food contact surfaces should be rinsed with potable water.

See page 6 for dilution instructions

20 PPM Sanitizer Strength: For use as a no-rinse, non-food-contact surface sanitizer for an exposure time of 5 minutes.

1:5 (one part 100 PPM ProKure solution to 4 parts water)

5 PPM Sanitizer Strength: For use as a no-rinse sanitizer on previously cleaned food preparation surfaces, glassware, plates, utensils and food and beverage processing equipment for an exposure time of 5 minutes.

1:20 (one part 100 PPM ProKure solution to 19 parts water)


Warning Placard – please print/copy and post when using ProKure D Fast Use Gas

DANGER

DO NOT ENTER Chlorine Dioxide Gas Treatment in Progress

Air out space at least 1 hour before reentry.

Material Safety Data Sheets – please print/copy and place with all the other MSDS for the facility.

ProKureTM V MSDS Page 1 of 7

SAFETY DATA SHEET This SDS complies with REACH 1907/2006 and 2001/58/EC, GHS, OSHA 29CFR 1910.1200

Section 1: Chemical Product and Company Identification CHEMICAL SUPPLIER COMPANY NAME EMERGENCY TELEPHONE

ProKure Solutions

225 West Deer Valley Road Chemtrec 24 hrs: 800-424-9300

Phoenix, AZ 85027 Information: 623-780-2296

Fax: 623-516-0414

Safety Data Sheet Competent Person: [email protected]

MANUFACTURER’S NAME: ProKure Solutions

ADDRESS: 225 West Deer Valley Road

TELEPHONE NUMBER: 623-780-2296

1-888-824-2918

DATE PREPARED: July 25, 2014 DATE REVIEWED: September 5, 2014

PRODUCT NAMES: ProKure V

FORMULA: Mixture

PRODUCT USE: Disinfectant/ Sanitizer/ Tuberculocide/ Virucide/ Fungicide/ Algaecide/ Slimicide/

Deodorizer

The product is designed to generate up to a 500 ppm of chlorine dioxide solution when the ProKure V pouch is placed in specified amount of

water. The product design limits both the amount of gas generated and the rate of release into solution. The product produces chlorine dioxide

gas when the contents are adequately wetted.

Section 2: Hazards Identification

1. 500ppm chlorine dioxide (ClO2) solution in water: After adding the ProKure V pouch to water, low levels of

chlorine dioxide is generated and dissolved in the water. Follow usage instructions for applicable amounts of water to use.

GHS Hazard Class Acute Toxicity Dermal -- Category 5 No Symbol

Signal word: Warning Hazard Statement: May be harmful if in contact with skin

Precautionary Statements: Prevention No Precautionary statement

Response Call a Poison Control center or doctor/physician if you feel unwell Storage No Precautionary statement

NFPA RATINGS:

Component Health (Blue) Flammability (Red) Instability (Yellow) Special (White)

Chlorine Dioxide (ClO2): 1 0 0 ---

2. Used, reacted pouch: Used pouch can be disposed of in general trash, municipal trash.

NFPA RATINGS:


Used / reacted pouch 0 0 0 No Water


3. Unreacted chemical mixture inside sealed, tear resistant pouch: The chemical mixture inside the sealed pouch is

not expected to pose a hazard unless the pouch is damaged and the powder mixture is exposed. This section specifically

applies to exposure to the white granular powder mixture inside the sealed pouch.

GHS Hazard Class Acute Toxicity Oral -- Category 4

Acute Toxicity Dermal – Category 3

Acute Toxicity Inhalation -- Category 3

Skin Corrosive -- Category 1B

Eye Corrosive -- Category 1 Specific target organ toxicity, single exposure Category 2 (Kidney)

Specific target organ toxicity, repeated exposure Category 2 (Blood)

Hazardous to the Aquatic Environment—Hazard -- Category 1

Hazardous to the Aquatic Environment—Long Term Hazard -- Category 1

Signal word: Danger

Hazard Statement: Harmful if swallowed Toxic in contact with skin

Toxic if inhaled

Causes severe skin burns Causes serious eye damage

May form combustible dust concentrations in air. May cause damage to organs (Kidney) May cause damage to organs (Blood) through prolonged or repeated exposure.

Very toxic to aquatic life Very toxic to aquatic life with long lasting effects

Precautionary Statements: Prevention Wash hands thoroughly after handling.

Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection.

Avoid breathing dust/fume/gas/mist/vapours/spray

Use only outdoors or in a well-ventilated area. Avoid release to the environment

Response If Swallowed: Call a Poison Control center/doctor/physician if you feel unwell.

Rinse mouth. Do NOT induce vomiting.

IF ON SKIN (or hair): Wash with plenty of water.

Immediately call a Poison Control center or doctor/physician if you feel unwell.

Take off immediately all contaminated clothing and wash it before reuse. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for

breathing.

Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and

easy to do so. Continue rinsing.

Collect spillage Storage Store locked up

Store in a well-ventilated place. Keep container tightly closed.

Disposal Dispose of waste materials and container by following the waste disposal requirements of your country, state, or local authorities.

HAZARD CLASSIFICATION: Classified as Hazardous based on IATA, IMDG, and DOT. FIRE AND EXPLOSION: Not applicable

POTENTIAL HEALTH EFFECTS: <0 % of mixture consists of ingredients of unknown acute toxicity

EYE CONTACT: Causes severe eye damage.

SKIN CONTACT: Causes severe skin burns.

INHALATION: Harmful if inhaled. May cause respiratory irritation.

INGESTION: Harmful if swallowed. OTHER: None

CHRONIC EFFECTS OF OVEREXPOSURE: None

APPEARANCE: White granular powder

NFPA RATINGS:


Unreacted chemical mixture inside

sealed, tear resistant pouch 3 1 0 No Water


Section 3: Composition / Information on Ingredients

Product 500 ppm

ClO2 ----- ----- ----- 10049-04-4 233-162-8 ----- ----- Y Y

Some items on this MSDS may be designated as trade secrets (TS). Bona fide requests for disclosure of trade secret

information to medical personnel must be made in accordance with the provisions contained in 29 CFR 1910.1200 I 1-13.

The Full List for all R phrases is shown in Section 16.

Section 4: First Aid Measures INHALATION: Remove to fresh air. If not breathing, provide CPR (cardio pulmonary

resuscitation). Get immediate medical attention.

SKIN CONTACT: Immediately flush skin with plenty of soap and water for at least 15 minutes.

Remove contaminated clothing.

EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate

medical attention.

INGESTION: If swallowed do not induce vomiting, give large quantities of water to drink. Never

give anything to an unconscious person. Get immediate medical attention.

Section 5: Fire-fighting Measures FLASH POINT: Not applicable

FLAMMABLE LIMITS IN AIR (% by vol): Not applicable

EXTINGUISHING MEDIA: CO2, Dry chemical, foam, water fog,

SPECIAL FIREFIGHTING PROCEDURES: Self-contained breathing apparatus and full protective clothing must be worn.

UNUSUAL FIRE AND EXPLOSION HAZARDS: If unreacted pouch, approach fire from upwind to avoid hazardous vapors and toxic

composition products. Wear self-contained breathing apparatus and protective clothing when fighting fire involving chemicals. If large

amounts of products are involved in a fire, it is possible that the application of water will release high concentrations of chlorine dioxide gas

into the water.

Section 6: Accidental Release Measures ACTION TO BE TAKEN IF UNREACTED POUCH IS RELEASED OR SPILLED:

Wear proper protective equipment as specified in Section 8: Exposure Controls/Personal Protection

Contain spill.

Recover spill by using absorbent, mop, or towels.

Place material into a chemical waste container.

Eliminate all sources of ignition and ventilate area.

Prevent spills or contaminated rinse water from entering sewers or watercourses.

DISPOSAL METHOD:

Disposal of this container: Reference Section 13 of this MSDS.

PRODUCT

COMPOSITION

APPROX

%

ACGI

H

TLV

OSHA

PEL

NIOSH

REL

CAS

NO. REACH

DANGER

SYMBOL

R-RISK

PHRASE DSL TSCA

TS-1 60.5 ----- ----- ----- TS ----- ----- ----- Y Y

Sodium Chlorite 30.5 ----- ----- ----- 7758-19-2 231-836-6 ----- ----- Y Y


Section 7: Handling and Storage PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:

Store upright in a cool, dark, dry place.

Keep container closed when not in use.

Use only with adequate ventilation.

Wear proper protective equipment when handling this material.

Avoid contact with skin, eyes, or clothing.

Wash hands and face after handling this material.

Follow all applicable local regulations for handling and storage.

Utilize chemical segregation.

INFORMATION ON EMPTIED CONTAINER

Dispose of this container according to local, state, and federal laws in your country.

SPECIFIC USES: Disinfectant/ Sanitizer/ Tuberculocide/ Virucide/ Fungicide/ Algaecide/ Slimicide/ Deodorizer

Section 8: Exposure Controls/Personal Protection

VENTILATION: Always provide good general, mechanical room ventilation where this

chemical/material is used.

RESPIRATORY PROTECTION: No respiratory protection normally required.

PROTECTIVE GLOVES: Wear chemical impervious gloves at all times while working with this

product. Recommended glove types include: Laminate Film, Nitrile, or

Tri-polymer. Check with your company’s glove supplier to ensure

chemical resistance.

EYE PROTECTION: Safety Glasses, Chemical goggles, face shield

PROTECTIVE CLOTHING: Wear suitable protective clothing to prevent skin contact.

WORK/HYGIENE PRACTICES: Avoid breathing vapor. Avoid contact with eyes. Wash hands after handling.

Section 9: Physical and Chemical Properties

UNREACTED POUCH

CRITERIA

PRODUCT CRITERIA

APPEARANCE - COLOR: White Yellow green

PHYSICAL STATE: Powder Liquid

ODOR: Slight Chlorine Chlorine

ODOR THRESHOLD Not Available for product 0.2—1.0 PPM

PH Not Available for product 2-3 at 8g/l

FLASH POINT: Not Available for product Not Available for product

LOWER EXPLOSIVE LIMIT; UPPER EXPLOSIVE LIMIT Not Available for product Not Available for product

FLAMMABILITY (Solid, gas) Not Available for product Not Available for product

EXPLOSIVE PROPERTIES Not Available for product Not Available for product

OXIDIZING PROPERTIES Not Available for product Not Available for product

SPECIFIC GRAVITY (@25 oC): Not Available for product ~1.0 (Water)

EVAPORATION RATE: Not Available for product Not Available for product

% VOLATILE by VOLUME Not Available for product Not Available for product

PARTITION COEFFICIENT Not Available for product Not Available for product

AUTO IGNITION TEMPERATURE Not Available for product Not Available for product

DECOMPOSITION TEMPERATURE Not Available for product Not Available for product

BOILING POINT: Not Available for product Not Available for product

MELTING POINT: Not applicable Not applicable

VAPOR PRESSURE Not Available for product Not Available for product

VAPOR DENSITY (AIR = 1) Not Available for product 2.4

SOLUBILITY IN WATER: Complete 8 g/l at 15 °C

FREEZING POINT: Not Available for product Not Available for product

VISCOSITY Not Available for product Not Available for product

VOC CONTENT Not Available for product Not Available for product

RINSIBILITY Not Available for product Not Available for product

CORROSIVE Not Available for product Not Available for product

∆H (Delta Heat of Combustion) Not Available for product Not Available for product


Section 10: Stability and React Section

UNREACTED POUCH PRODUCT STABILITY: Stable under normal conditions. Stable under normal

conditions.

CONDITIONS TO AVOID: Temperatures above 347°F (175°C),

do not store dry product where exposed to moist conditions and

contamination with combustible

materials.

Excessive heat or

contamination which could cause the product to

decompose.

INCOMPATIBILITY (MATERIALS TO AVOID): Acids, reducing agents, combustible

materials, oxidizers (e.g. hypochlorites) or easily oxidizable

materials

Combustibles, oxidizable

organic materials, hydrogen sulfide, metallic

dusts.

HAZARDOUS POLYMERIZATION: Will not occur Will not occur

Section 11: Toxicological Information

GHS Required Criteria Toxicity Criteria Data Comments Chemical Constituent Acute Toxicity LD50 Oral Rat 506 mg/kg Unreacted Pouch Contents

LD50 Dermal Rabbit 315 mg/kg Unreacted Pouch Contents

LC50 Inhalation Rat 0.68 mg/l Unreacted Pouch Contents

LD50 Dermal Rabbit >2000 mg/kg 500 ppm ClO2 Solution

Skin Corrosion/Irritation Rabbit - Corrosive Sodium Chlorite

Serious Eye Damage /

Eye Irritation Rabbit - Severe eye irritation 24h Sodium Chlorite

Respiratory or Skin Sensitization No information is available

Germ Cell Mutagenicity No information is available

Carcinogenicity No information is available

No information is available NTP

No information is available OSHA

Reproductive Toxicity No information is available

STOST -- Single Exposure No information is available

STOST – Repeated Exposure No information is available

Aspiration Hazard No information is available

Ames test No information is available

STOST = Specific Target Organ Systemic Toxicity

OTHER INFORMATION:

Only selected Registry of Toxic Effects of Chemical Substances (RTECS) data is presented here. See actual entry in RTECS for complete

information.

Section 12: Ecological Information Chemical Component

BIODEGRADATION: No information is available.

BIOACCUMULATION: No information is available.

ECO TOXICITY: LC50 - Cyprinodon variegatus (sheepshead minnow) 177mg/l Unreacted Pouch Contents

EC50 - Daphnia magna (Water flea) – 105 mg/l Unreacted Pouch Contents

LC50 - Cyprinodon variegatus (sheepshead minnow) 150 g/l 500 ppm ClO2 Solution

EC50 - Daphnia magna (Water flea) – 580 mg/l 500 ppm ClO2 Solution

EC50 - Daphnia magna (Water flea) – .29 mg/l 48hrs Sodium chlorite

MOBILITY: No information is available.


Section 13: Disposal Considerations WASTE FROM RESIDUES / UNUSED PRODUCTS / CONTAMINATED PACKAGING:

Dispose of in accordance with federal, state, and local disposal regulations.

RINSATE: Do not dispose of rinse water containing product in a storm water drainage system.

Section 14: Transport Information ROAD TRANSPORT:

ADR = International Carriage of Dangerous Goods by Road UN NUMBER: UN3261

DOT PROPER SHIPPING NAME Corrosive solid, acidic, organic, N.O.S. (Sodium Chlorite)

DOT / ADR HAZARD CLASS: Corrosive DOT / ADR LABELS: Class 8

PLACARD: Corrosive, Class 8

DOT / ADR PACKAGING GROUP: III Special Provisions IB8, IP3, T1, TP33

Packaging Exception 154

Packaging Non Bulk 213 Packaging Bulk 240

SEA TRANSPORT: IMDG PROPER SHIPPING NAME Corrosive solid, acidic, organic, N.O.S. (Sodium Chlorite)

UN NUMBER SEA UN3261

CLASS: 8 PACKING GROUP: III

EmS No.: F-A, S-B

MARINE POLLUTANT: Yes SEA TRANSPORT NOTES: None

AIR TRANSPORT: IATA/ICAO UN NUMBER: UN3261

PROPER SHIPPING NAME Corrosive solid, acidic, organic, N.O.S. (Sodium Chlorite)

HAZARD CLASS: 8 PACKAGING GROUP: III

General Information: This product meets the limited quantities exception as follows: DOT/IMDG: Limited quantities up to 5.0 kg.

Section 15: Regulatory Information

TOXIC SUBSTANCES CONTROL ACT (TSCA) STATUS:

This product is in compliance with rules, regulations, and/or orders of TSCA.

SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) TITLE III SECTION 313 SUPPLIER

NOTIFICATION:

This regulation requires submission of annual reports of toxic chemical(s) that appear in section 313 of the Emergency Planning and

Community Right To Know Act of 1986 and 40 CFR 372. The toxic chemicals contained in this product are: None

CALIFORNIA PROPOSITION 65:

This regulation requires a warning for California Proposition 65 chemical(s) under the statute.

The California proposition 65 chemical(s) contained in this product are: None

STATE RIGHT-TO-KNOW TOXIC SUBSTANCE OR HAZARDOUS SUBSTANCE LIST:

Florida Toxic Substance(s): None

Massachusetts’s hazardous substance(s): None, Sodium Chlorite

Pennsylvania hazardous substance code(s): TS-1, Sodium Chlorite

New Jersey TS-1, Sodium Chlorite


Illinois None

Michigan: None

CANADA:

This MSDS/SDS will be non-compliant 3 years after the issue date. This MSDS contains all of the information required by the Controlled

Products Regulations (CPR).

WHMIS-INFORMATION:

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR), SOR/88-66, current to

February 20, 2012. The classes of controlled products listed in the CPR, Section 32, Part IV, have been reviewed and based on Professional

Judgment this product has been determined to be WHMIS controlled.

Unreacted Pouch Contents: Sodium Chlorite: C - Oxidizing material

D1B - Poisonous and infectious material - Immediate and serious effects – Toxic

TS1: E - Corrosive material

EUROPEAN UNION:

This product has been reviewed for compliance with the following European Community Directives: REACH 1907/2006; Directive

67/548/EEC, Regulation (EC) No 1272/2008 on classification, labeling and packaging (CLP) of substances and mixtures.

WGK: 0 (German Federal Water Management Act) (Water Hazard Class)

Section 16: Other Information

Full Text:

European Community Hazards Identification:

R: None

S: None

Danger Symbol(s): None

Revision Comments: Initial version August 1, 2014

Revision Number: 0

Information Sources: RTECS, REACH, OSHA 29CFR 1910.1200

The information presented herein has been compiled from sources considered to be dependable and is accurate to the best of ProKure Solutions’

knowledge; however, ProKure Solutions makes no warranty whatsoever, expressed or implied, of MERCHANTIBILITY or FITNESS FOR THE

PARTICULAR PURPOSE, regarding the accuracy of such data or the results to be obtained from the use thereof. ProKure Solutions assumes no

responsibility for the injury to recipient or to third persons or for any damage to any property and recipient assumes all such risks.

PDOC-30-486 Rev. 2.0 ProKure Solutions

ProKure™ D SDS Page 1 of 9

SAFETY DATA SHEET This SDS complies with REACH 1907/2006 and 2001/58/EC, GHS REVISION 5, OSHA 29CFR 1910.1200

Section 1: Chemical Product and Company Identification

PRODUCT NAME: ProKure™ D

FORMULA: Preparation/Mixture

PRODUCT USE: Deodorizer

MANUFACTURER’S NAME: ProKure Solutions ADDRESS: 225 West Deer Valley Road

Phoenix, AZ 85027

Safety Data Sheet Competent Person: [email protected]

SUPPLIER’S NAME: ProKure Solutions ADDRESS: 225 West Deer Valley Road

Phoenix, AZ 85027

TELEPHONE NUMBER: 623-780-2296

TOLL FREE: 1-888-608-7888 FAX: 623-516-0414

EMERGENCY TELEPHONE NUMBER: Chemtrec 24 hrs: 1-800-424-9300

Information: 623-780-2296 Fax: 623-516-0414

DATE PREPARED: October 9, 2015

DATE REVIEWED: December 3, 2015

Section 2: Hazards Identification

GHS Hazard Class: Combustible dust

Acute toxicity, oral (Category 4), H302 Acute toxicity, dermal (Category3), H311

Skin corrosive (Category 1B), H314

Eye damage (Category 1), H318

Specific Target Organ Toxicity (repeated exposure), (Category 2), H373 Aquatic acute toxicity (Category 1), H400

GHS Label elements, including precautionary statements:

Pictograms:

Signal word: Danger

Hazard Statement(s):

May form combustible dust concentrations in air.

H302 Harmful if swallowed. H311 Toxic in contact with skin.

H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

H373 May cause damage to organs (Spleen) through prolonged or repeated exposure. H400 Very toxic to aquatic life

Precautionary Statement(s):

P102 Keep out of reach of children P103 Read label before use

P260 Do not breathe dust, mist.



P264 Wash hands, forearms, and exposed areas thoroughly after handling.

P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment.

P280 Wear eye protection, face protection, protective clothing, protective gloves.

P301+P330+P331 If swallowed: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 If inhaled: Remove person to fresh air and keep at rest in a position comfortable for

breathing.

P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a poison center or doctor.

P321 Specific treatment (see Section 4 on this SDS).

P330 Rinse mouth. P361 Take off immediately all contaminated clothing. P363

Wash contaminated clothing before reuse.

P391 Collect spillage. P405 - Store locked up.

P501 Dispose of contents/container in accordance with local, regional, national, territorial, provincial, and international regulations.

POTENTIAL HEALTH EFFECTS: Not available

NFPA RATINGS:

COMPONENT Health

(Blue)

Flammability

(Red)

Reactivity

(Yellow)

Special

(White)

ProKure™ D 3 0 1 --

Section 3: Composition / Information on Ingredients

PRODUCT COMPOSITION APPROX % CAS NO. CANADA DSL

Citric acid 66.8 77-92-9 Y Sodium chlorite 20 7758-19-2 Y

Calcium chloride 13.2 10043-52-4 Y

Toxicity data of the ingredients are demonstrated in Section 11.

Section 4: First Aid Measures

Description of First Aid Measures

INHALATION: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Ventilate the area.

SKIN CONTACT: Immediately flush skin with plenty of water for at least 60 minutes. Remove

contaminated clothing. Immediately call a POISON CENTER or doctor. Wash

contaminated clothing before reuse EYE CONTACT: Rinse cautiously with water for several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing for at least 60 minutes. Immediately call a POISON

CENTER or doctor/physician.

INGESTION: Rinse mouth. Do not induce vomiting. Immediately call a POISON CENTER or doctor/physician.

Most important symptoms and effects, both acute and delayed

Symptoms/Injuries After Inhalation: Repeated or prolonged inhalation may damage lungs.

Symptoms/Injuries After Skin Contact: Toxic in contact with skin. Corrosive. Causes burns.

Symptoms/Injuries After Eye Contact: Causes serious eye damage. Causes permanent damage to the cornea, iris, or

conjunctiva

Symptoms/Injuries After Ingestion: Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat,

and gastrointestinal tract.

Chronic Symptoms: Causes damage to organs (Spleen) through prolonged or repeated exposure.



Indication of any immediate medical attention and special treatment needed

If exposed or concerned, get medical advice and attention. If medical advice is needed, have product container or label at hand.

Section 5: Fire-fighting Measures

Suitable extinguishing media Dry chemical, carbon dioxide (CO2), water spray, fog (flooding amounts)

Unsuitable extinguishing media: Do not use a heavy water stream. Heavy stream of water may spread fire

Special hazards arising from the substance or mixture Not flammable but will support combustion. Product itself is not explosive

but if dust is generated, dust clouds suspended in air can be explosive

Protective actions fire-fighters Use water spray or fog for cooling exposed containers. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of

explosion. Do not allow run-off from firefighting to enter drains or water

sources. Do not breathe fumes from fires or vapors from decomposition.

Closed containers exposed to heat may explode. Do not enter fire area without proper protective equipment, including respiratory protection.

Further information None.

Section 6: Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures Do not get in eyes, on skin, or on clothing. Do not breathe dust or fumes. Keep away from heat, sparks, open flames, hot

surfaces – No smoking. Eliminate every possible source of ignition. Evacuate danger area.

For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE).

Emergency Procedures: Evacuate unnecessary personnel.

For Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE).

Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous

goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as

conditions permit.

Environmental Precautions Prevent entry to sewers and public waters.

Methods and materials for containment and cleaning up

As an immediate precautionary measure, isolate spill or leak area in all directions. Contain and collect as any solid. Clean up

spills immediately and dispose of waste safely. Take up with inert, damp, non-combustible material using clean non-sparking

tools and place into loosely covered plastic containers for later disposal. Contact competent authorities after a spill.

Reference to other Sections For personal protection reference section 8. For disposal reference section 13.

Section 7: Handling and Storage

Precautions for safe handling

Do not handle until all safety precautions have been read and understood. Do not breathe dust. Keep away from heat,

sparks, open flames, hot surfaces. – No smoking. Do not allow contact with incompatible materials (see section 10).

Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with

mild soap and water before eating, drinking, or smoking and again when leaving work. Contaminated work clothing

should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Wash contaminated

clothing before reuse.

Conditions for safe storage, including any incompatibilities

Container remains hazardous when empty. Continue to observe all precautions. Ensure all national/local regulations are

observed. Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep in fireproof place.

Keep/Store away from direct sunlight, extremely high or low temperatures, and incompatible materials. Store locked up. Strong acids. Strong bases. Strong oxidizers. Combustible materials. May react with moisture. Flammable materials.

Organic compounds. Wood. Oils and lubricants.

Specific uses

Deodorizer



Section 8: Exposure Controls/Personal Protection Control Parameters For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier,

importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial

governments, or the Mexican government.

Ontario, for Calcium chloride:

OEL TWA (mg/m3): 5mg/m3

Exposure Controls Appropriate Engineering Controls: Emergency eye wash fountains and safety showers should be available in the

immediate vicinity of any potential exposure. Ensure adequate ventilation,

especially in confined areas. Proper grounding procedures to avoid static

electricity should be followed. Ensure all national/local regulations are observed. It is recommended that all dust control equipment such as local exhaust

ventilation and material transport systems involved in handling of this product

contain explosion relief vents or an explosion suppression system or an oxygen-

deficient environment.

Personal Protective Equipment: Gloves. Protective goggles. Face shield. Protective clothing. Insufficient

ventilation: wear respiratory protection.

Materials for Protective Clothing: Chemically resistant materials and fabrics.

Hand Protection: Wear chemically resistant protective gloves.

Eye Protection: Chemical safety goggles and face shield.

Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: If exposure limits are exceeded or irritation is experienced, approved respiratory

protection should be worn.

Consumer Exposure Controls: Do not eat, drink or smoke during use

Other Information: When using, do not eat, drink or smoke.

Section 9: Physical and Chemical Properties

APPEARANCE – COLOR: White powder

PHYSICAL STATE: Solid

ODOR: Chlorine

ODOR THRESHOLD: Not available

pH: Not available

MELTING POINT/FREEZING POINT: Not available INITIAL BOILING POINT AND BOILING RANGE: Not available

FLASH POINT: Not available

EVAPORATION RATE: Not available

FLAMMABILITY (Solid, gas): Not available

UPPER/LOWER FLAMMABILITY OR EXPOLSIVE LIMITS: Not available

VAPOR PRESSURE: Not available

VAPOR DENSITY (AIR = 1): Not available

RELATIVE DENSITY (@25 oC): Not available SOLUBILITY (IES): Soluble in water

OXIDIZING PROPERTIES: Not available

PARTITION COEFFICIENT: n-octanol/water: Not available

AUTO IGNITION TEMPERATURE: Not available DECOMPOSITION TEMPERATURE: Not available

VISCOSITY: Not available

EXPLOSIVE PROPERTY: Heating may cause a fire or explosion

EXPLOSION DATA: Static discharge could act as an ignition source



Section 10: Stability and Reactivity

REACTIVITY: Acidic salts, such as SODIUM BISULFATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions

and have pH's of less than 7.0. They react as acids to neutralize bases. May

catalyze organic reactions. Increased risk of explosion if mixed with

ethanol. If compressed and mixed with calcium hypochlorite, sodium hydrogen sulfate, starch, and sodium carbonate, materials will

incandescence and explode. SODIUM CHLORITE is self-reactive. The

trihydrate crystals of sodium chlorite explode on percussion. Sodium

chlorite reacts with acids to form spontaneously explosive chlorine dioxide gas (ClO2). If heated above 175 °C, the reaction yields enough heat to

become self-sustaining. Ammonia with chlorites produces ammonium

chlorite, which is a shock-sensitive compound. Finely divided metallic or

organic substances, if mixed with chlorites, are highly flammable and may be ignited on friction. A mixture of organic matter and sodium chlorite can

be extremely sensitive to heat, impact, or friction. Sodium chlorite reacts

very violently with organic materials containing divalent sulfur or with free

sulfur (may ignite). CHEMICAL STABILITY: Stable under recommended handling and storage conditions (see section 7).

CONDITIONS TO AVOID: Direct sunlight. Extremely high or low temperatures. Heat. Sparks.

Overheating. Open flame.

INCOMPATIBILITY (MATERIALS TO AVOID): Strong acids. Strong bases. Strong oxidizers. Combustible materials. May

react with moisture. Flammable materials. Organic compounds. Wood. Oils and lubricants.

HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition generates: Corrosive vapors. Chlorine. Sodium

oxides. Sulfur compounds. Carbon oxides (CO, CO2).

HAZARDOUS POLYMERIZATION: Will not occur

Section 11: Toxicological Information

There is no toxicological information available for the product or mixture.

GHS

Required Criteria Toxicity Criteria Data Comments

Chemical

Constituent

Acute Toxicity ATE, oral 825 mg/kg Product

ATE, dermal 536 mg/kg Product

LD50 Oral Rat 165m mg/kg Sodium chlorite

LD50 Dermal Rabbit 107.2 mg/kg Sodium chlorite LC50 Inhalation Rat 230 mg/m3 (4hr) Sodium chlorite

LD50 Oral Rat 5,400 mg/kg Citric acid

LD50 Dermal Rat >2,000 mg/kg Citric acid

LD50 Oral Rat 2301 mg/kg Calcium chloride

LD50 Dermal Rat 2630 mg/kg Calcium chloride LD50 Dermal Rabbit >5,000 mg/kg Calcium chloride

Skin Corrosion/Irritation

Cause severe skin burn

and eye damage Product

Serious Eye Damage /

Eye Irritation Cause serious eye damage Product

Respiratory or Skin

Sensitization Not classified Product

Germ Cell Mutagenicity Not classified Product

Carcinogenicity Not classified Product

STOST -- Single Exposure Not classified Product

STOST – Repeated Exposure

May cause damage to

organs through prolonged

or repeated exposure.

Product

Aspiration Hazard Not classified Product

STOST = Specific Target Organ Systemic Toxicity

OTHER INFORMATION:

Symptoms/Injuries After Inhalation: Repeated or prolonged inhalation may damage lungs.

Symptoms/Injuries After Skin Contact: Toxic in contact with skin. Corrosive. Causes burns. Symptoms/Injuries After Eye Contact: Causes permanent damage to the cornea, iris, or conjunctiva.



Symptoms/Injuries After Ingestion: Harmful if swallowed. May cause burns or irritation of the linings of the mouth,

throat, and gastrointestinal tract.

Chronic Symptoms: Causes damage to organs (Spleen) through prolonged or repeated exposure.

Section 12: Ecological Information

Environmental Impacts Chemical

Constituents

Toxicity LC50 Fish 1: 100-500mg/L (96hr, Brachydanio rerio [static]) Sodium chlorite

EC50 Daphnia1: 0.026mg/L (48hr, Daphnia magna) Sodium chlorite

LC50 Fish 2: >100mg/L (96hr, Lepomis macrochirus [static]) Sodium chlorite

EC50 Daphnia2: 0.25-0.33mg/L (48hr, Daphnia magna [Flow

through]) Sodium chlorite

LC50 Fish1: 1516 mg/L (96hr, Lepomis macrochirus [static]) Citric acid

LC50 Fish1: 10650 mg/l (96 h,Lepomis macrochirus [static]) Calcium chloride

EC50 Daphnia1: 2400 mg/l (48 h, Daphnia magna) Calcium chloride Bioaccumulative potential -1.72 (at 20 °C) Citric acid

BCF Fish 1: no bioaccumulation Calcium chloride

Persistence and degradability: Readily biodegradable in water. Citric acid

Mobility in soil: No information is available. PBT and vPvB assessment: No information is available.

Other adverse effects: Avoid release to the environment Product

Section 13: Disposal Considerations

Waste from residues/unused products

This material is hazardous to the aquatic environment. Keep out of sewers and waterways. Dispose of waste material in accordance

with all local, regional, national, provincial, territorial and international regulations.

Contaminated packaging

Contaminated packaging material should be disposed of as stated above for residues and unused product.

Section 14: Transport Information

In accordance with ICAO/IATA/DOT/TDG/IMDG

UN Number: UN3262 Proper shipping name (DOT/TDG/IATA/IMDG): CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (Contains Sodium

Chlorite), 8, II, Marine Pollutant

Transport Document Description (DOT/TDG): UN3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S.

(CONTAINS SODIUM CHLORITE), 8, II, Marine Pollutant

Transport Document Description (Adr)(IMDG/IATA): UN3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S.

(CONTAINS SODIUM CHLORITE), 8, II, Marine Pollutant, (E)

Transport Hazard Class(es): 8-Class8- Corrosive material 49 CFR 173.136

Hazard Label (DOT):

DOT Symbols: G- Identifies PSN requiring a technical name Packing Group (DOT): II (medium danger)

DOT Special Provisions (49 CFR 172.102): IB8 - Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B

and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2);

Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2);

Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2,

13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). IP2 - When

IBCs other than metal or rigid plastics IBCs are used, they must be offered

for transportation in a closed freight container or a closed transport vehicle.



IP4 - Flexible, fiberboard or wooden IBCs must be sift-proof and water-

resistant or be fitted with a sift-proof and water-resistant liner.T3 - 2.65

178.274(d)(2) Normal............. 178.275(d)(2)TP33 - The portable tank

instruction assigned for this substance applies for granular and powdered

solids and for solids which are filled and discharged at temperatures above

their melting point which are cooled and transported as a solid mass. Solid

substances transported or offered for transport above their melting point are

authorized for transportation in portable tanks conforming to the provisions

of portable tank instruction T4 for solid substances of packing group III or

T7 for solid substances of packing group II, unless a tank with more stringent

requirements for minimum shell thickness, maximum allowable working

pressure, pressure-relief devices or bottom outlets are assigned in which case

the more stringent tank instruction and special provisions shall apply. Filling

limits must be in accordance with portable tank special provision TP3.

Solids meeting the definition of an elevated temperature material must be

transported in accordance with the applicable requirements of this

subchapter.

DOT Packaging Exceptions (49 Cfr 173.xxx): 154

DOT Packaging Non Bulk (49 Cfr 173.xxx): 212

DOT Packaging Bulk (49 Cfr 173.xxx): 240

TDG Primary Hazard Class(es): 8-Class8- Corrosives

Hazard Label (TDG):

Packing Group (TDG): II (medium danger)

TDG Special provisions: 16 - 1) The technical name of the most dangerous substance related to the primary class must be shown, in parentheses, on the shipping

document following the shipping name in accordance with clause 3.5(1)(c)(i)(A) of Part 3, Documentation. The technical name must also

be shown, in parentheses, on a small means of containment or on a tag

following the shipping name in accordance with subsections 4.11(2) and

(3) of Part 4, Dangerous Goods Safety Marks.2) subsection (1), the technical name for the following dangerous goods is not required to be

shown on a shipping document or on a small means of containment

when Canadian law for domestic transport or an international

convention for international transport prohibits the disclosure of the technical: a) UN1544, ALKALOID SALTS, SOLID, N.O.S. or

ALKALOIDS, SOLID, N.O.S.; b) UN1851, MEDICINE, LIQUID,

TOXIC, N.O.S.; c) UN3140, ALKALOID SALTS, LIQUID, N.O.S. or

ALKALOIDS, LIQUID, N.O.S.; d) UN3248, MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S.; or e) UN3249, MEDICINE, SOLID,

TOXIC, N.O.S. An example in Canada is the “Food and Drugs Act”.

Explosive Limit And Limited Quantity Index: 1

Marine Pollutant: P

Passenger Carrying Road Vehicle Or Passenger: 15

Carrying Railway Vehicle index

Class (IMDG): 8

Danger label (IMDG): 8

Packing Group (IMDG): II

Class (IATA): 8

Hazard Label (IATA): 8



Packing Group (IATA): II – medium danger Marine Pollutant: P

Additional information: Emergency Response Guide (ERG) Number: 154

Transport by sea

Dot Vessel Stowage Location: B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a

cargo vessel and on a passenger vessel carrying a number of passengers

limited to not more than the larger of 25 passengers, or one passenger

per each 3 m of overall vessel length; and

(ii) ‘‘On deck only’’ on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Dot Vessel Stowage Other: 52 - Stow ‘‘separated from’’ acids

Limited Quantities (IMDG): 1 kg

Special Provisions (IMDG): 274 Excepted Quantities (IMDG): E2

IBC Packing Instructions (IMDG): IBC08

IBC Special Provisions (IMDG): B2, B4

Packing Instructions (IMDG): P002 Tank Instructions (IMDG): T3

Tank Special Provisions (IMDG): TP33

Stowage Category (IMDG): B

EMS-NO. (1): F-A

EMS-NO. (2): S-B

MFAG-NO: 154

Marine Pollutant: P

Air Transport

DOT Quantity Limitations Passenger Aircraft/Rail (49 CFR 173.27): 15kg DOT Quantity Limitations Cargo Aircraft Only (49 CFR 175.75): 50kg

CAO Packing Instructions (IATA): 863

CAO Max Net Quantity (IATA): 50kg

PCA Packing Instructions (IATA): 859 PCA Limited Quantities (IATA): Y844

PCA Limited Quantity Max Net Quantity (IATA): 5kg

PCA Max Net Quantity (IATA): 1kg

PCA Excepted Quantities (IATA): E2 CAO Max Net Quantity (IATA): 50kg

CAO Packing Instructions (IATA): 863

Special Provision (IATA): A3

Erg Code (IATA): 8L Instruction "cargo" (ICAO): 864 Instruction "cargo" - Limited Quantities (ICAO): 100kg

Section 15: Regulatory Information

TOXIC SUBSTANCES CONTROL ACT (TSCA) STATUS: All components are listed on TSCA.

SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) Section 311-312 Hazard Class Delayed (chronic) health hazard Product

Immediate (acute) health hazard Product

STATE RIGHT-TO-KNOW TOXIC SUBSTANCE OR HAZARDOUS SUBSTANCE LIST:

Massachusetts’s hazardous substance(s): Sodium chlorite,



Pennsylvania hazardous substance code(s): Sodium chlorite

New Jersey Sodium chlorite

CANADA:

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS

contains all of the information required by CPR.

WHMIS-INFORMATION:

WHMIS Classification for

Product: Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects

Class D Division 2 Subdivision B - Toxic material causing other toxic effects Class E - Corrosive Material

Sodium chlorite: Class C - Oxidizing Material

Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects

Class D Division 2 Subdivision B - Toxic material causing other toxic effects Class E - Corrosive Material

Citric acid: Class D Division 2 Subdivision B - Toxic material causing other toxic effects

Calcium chloride: Class D Division 2 Subdivision B - Toxic material causing other toxic effects

Section 16: Other Information

Revision Number: 2.0

Revision explanation Product Use updated Information Sources: RTECS, ECHA, REACH, OSHA 29CFR 1910.1200

The information presented herein has been compiled from sources considered to be dependable and is accurate to the best of ProKure

Solutions’ knowledge; however ProKure Solutions makes no warranty whatsoever, expressed or implied, of MERCHANTIBILITY or

FITNESS FOR THE PARTICULAR PURPOSE, regarding the accuracy of such data or the results to be obtained from the use thereof. ProKure Solutions assumes no responsibility for the injury to recipient or to third persons or for any damage to any property and recipient assumes

all such risks.

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