+ All Categories
Home > Documents > Date Received: 2601 Agriculture Drive, PO Box 7996 Madison ...

Date Received: 2601 Agriculture Drive, PO Box 7996 Madison ...

Date post: 26-Mar-2022
Category:
Upload: others
View: 6 times
Download: 0 times
Share this document with a friend
41
Page 1 of 41 Laboratory Report Wisconsin State Laboratory of Hygiene 2601 Agriculture Drive, PO Box 7996 Madison, WI 53707-7996 (800)442-4618 - FAX (608)224-6213 http://www.slh.wisc.edu D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director Environmental Health Division WDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID: 113133790 E37658 WI00007, WI00008 105-415 384341001 WSLH Sample: ZANA SJIAN WISCONSIN DNR WT093 ZANA SJIAN WISCONSIN DNR Collection End: 5/23/2018 12:55:00 PM Point or Outfall: Project No: Date Received: Date Reported: Sample Depth: 5/24/2018 6/8/2018 Customer ID: Report To: Invoice To: Field #: TREMP@ARCADIA Collection Start: Collected By: County: Sample Type: Sample Reason: Sample Location: Sample Description: CAMILLE BRUHN SU-SURFACE WATER TREMPEALEAU RIVER X-619206 Y- 4901212 ID#: Waterbody: Program Code: Region Code: 0.5F Sample Comments For the dissolved metals tests, the sample was filtered and preserved at the lab. Analyzed past the 15 minutes holding time: Method SM4500-H+B analyzed on 05/24/18 1330 NITRIC ACID USED IN FIELD WAS EXPIRED. Analyte Result Units LOD LOQ Inorganic Chemistry Analysis Method 05/25/18 05/25/18 Prep Date Analysis Date 52.3 TOTAL SUSPENDED SOLIDS mg/L 3.3 3.3 SM2540D 05/24/18 05/24/18 Prep Date Analysis Date 18.8 Chloride mg/L 1.00 3.20 SM4500-CL-E 05/24/18 05/24/18 Prep Date Analysis Date Comments: Analyzed past the 15 minutes holding time. 7.83 pH SU 1.00 1.00 SM4500-H+B 05/25/18 05/25/18 Prep Date Analysis Date 33.9 Turbidity NTU 0.100 0.100 SM2130B DRAFT Report ID: 0000.25.2.WSLH.0 Report Rev:
Transcript

Page 1 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341001WSLH Sample:

ZANA SJIANWISCONSIN DNR

WT093

ZANA SJIANWISCONSIN DNR

Collection End: 5/23/2018 12:55:00 PM

Point or Outfall:

Project No:

Date Received:Date Reported: Sample Depth:

5/24/20186/8/2018

Customer ID:

Report To: Invoice To:

Field #: TREMP@ARCADIA

Collection Start: Collected By:

County:

Sample Type:

Sample Reason:

Sample Location:Sample Description:

CAMILLE BRUHNSU-SURFACE WATER

TREMPEALEAU RIVER X-619206 Y-4901212

ID#:

Waterbody:

Program Code:Region Code:

0.5F

Sample Comments

For the dissolved metals tests, the sample was filtered and preserved at the lab.

Analyzed past the 15 minutes holding time: Method SM4500-H+B analyzed on 05/24/18 1330

NITRIC ACID USED IN FIELD WAS EXPIRED.

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

52.3TOTAL SUSPENDED SOLIDS mg/L 3.3 3.3SM2540D

05/24/18 05/24/18Prep Date Analysis Date

18.8Chloride mg/L 1.00 3.20SM4500-CL-E

05/24/18 05/24/18Prep Date Analysis Date

Comments:Analyzed past the 15 minutes holding time.

7.83pH SU 1.00 1.00SM4500-H+B

05/25/18 05/25/18Prep Date Analysis Date

33.9Turbidity NTU 0.100 0.100SM2130B

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 2 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341001WSLH Sample:

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/29/18 05/30/18Prep Date Analysis Date

0.413Phosphorus mg/L 0.00500 0.0160EPA 365.1

Analyte Result Units LOD LOQ

Inorganic Chemistry, Dissolved

Analysis Method

05/24/18 05/25/18Prep Date Analysis Date

0.0412FAmmonia mg/L 0.0150 0.0480EPA 350.1

Analyte Result Units LOD LOQ

Metals, Total Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

670Aluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

1.03FChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

3.15Iron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

4.45FNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

5.94FZinc ug/L 5.00 15.0EPA 200.7

30.1Calcium mg/L 0.100 0.300EPA 200.7

12.3Magnesium mg/L 0.100 0.300EPA 200.7

126Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 3 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341001WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Total

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

Analyte Result Units LOD LOQ

Metals, Total, Low Level

Analysis Method

05/24/18 05/24/18Prep Date Analysis Date

0.453Total Chromium ug/L 0.00150 0.0232Hi Res ICPMS

0.0914Chromium (VI) ug/L 0.0122 0.0232Hi Res ICPMS

20.2% Chromium (VI) %Hi Res ICPMS

Analyte Result Units LOD LOQ

Metals, Dissolved Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

14.8FAluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

NDIron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

3.40FNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

NDZinc ug/L 5.00 15.0EPA 200.7

29.3Calcium mg/L 0.100 0.300EPA 200.7

12.4Magnesium mg/L 0.100 0.300EPA 200.7

124Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 4 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341001WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Dissolved

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

Analyte Result Units

Field Data

Analysis Method

15.72Sample Temp-field (C) CentigradeField Data

9.29DO field (mg/L) mg/LField Data

95.3% Saturation %Field Data

7.61pH (SU) field SUField Data

100Cloud Cover % %Field Data

281Cond-fld(uS/CM@25C) UMHOS/CMField Data

28Transparency Tube (cm) CMField Data

LOD = Level of detection LOQ = Level of quantification ND = None detected. Results are less than the LOD F next to result = Result is between LOD and LOQ Z next to result = Result is between 0 (zero) and LOD if LOD=LOQ, Limits were not statistically derived

Test results for NELAP accredited tests are certified to meet the requirements of the NELAC standards. For a list of accredited analytes see http://www.slh.wisc.edu/about/compliance/nelac-laboratory-accreditationResults, LOD and LOQ values have been adjusted for analytical dilutions and percent moisture where applicable.Results relate only to the items tested.This Laboratory Report shall not be reproduced except in full, without written approval of the laboratory.The water microbiology unit analyzes samples as received and not all samples are tested for preservation before analysis is performed.

List of Abbreviations:

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 5 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341001WSLH Sample:

Responsible PartyMicrobiology: Sharon Kluender, Lab Manager, 608-224-6262Inorganic Chemistry: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Metals: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Organic Chemistry: Al Spallato, Lab Manager, 608-224-6269Emergency Chemical Response: Noel Stanton, Lab Manager, 608-224-6251Environmental Toxicology: Tracy Hanke, Lab Manager, 608-224-6270

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 6 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341002WSLH Sample:

ZANA SJIANWISCONSIN DNR

WT093

ZANA SJIANWISCONSIN DNR

Collection End: 5/23/2018 12:26:00 PM

Point or Outfall:

Project No:

Date Received:Date Reported: Sample Depth:

5/24/20186/8/2018

Customer ID:

Report To: Invoice To:

Field #: TREMP@DODGE

Collection Start: Collected By:

County:

Sample Type:

Sample Reason:

Sample Location:Sample Description:

CAMILLE BRUHNSU-SURFACE WATER

X-651729 Y-4887538

ID#:

Waterbody:

Program Code:Region Code:

0.5F

Sample Comments

NITRIC ACID USED IN FIELD WAS EXPIRED.

For the dissolved metals tests, the sample was filtered and preserved at the lab.

Analyzed past the 15 minutes holding time: Method SM4500-H+B analyzed on 05/24/18 1330

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

86.0TOTAL SUSPENDED SOLIDS mg/L 5.0 5.0SM2540D

05/24/18 05/24/18Prep Date Analysis Date

20.5Chloride mg/L 1.00 3.20SM4500-CL-E

05/24/18 05/24/18Prep Date Analysis Date

Comments:Analyzed past the 15 minutes holding time.

7.96pH SU 1.00 1.00SM4500-H+B

05/25/18 05/25/18Prep Date Analysis Date

64.1Turbidity NTU 0.100 0.100SM2130B

05/29/18 05/30/18Prep Date Analysis Date

0.547Phosphorus mg/L 0.00500 0.0160EPA 365.1

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 7 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341002WSLH Sample:

Analyte Result Units LOD LOQ

Inorganic Chemistry, Dissolved

Analysis Method

05/24/18 05/25/18Prep Date Analysis Date

0.0213FAmmonia mg/L 0.0150 0.0480EPA 350.1

Analyte Result Units LOD LOQ

Metals, Total Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

1380Aluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

2.02FChromium ug/L 1.00 3.00EPA 200.7

7.48FCopper ug/L 5.00 15.0EPA 200.7

5.57Iron mg/L 0.100 0.300EPA 200.7

4.63FLead ug/L 3.00 10.0EPA 200.7

5.79FNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

7.63FZinc ug/L 5.00 15.0EPA 200.7

36.9Calcium mg/L 0.100 0.300EPA 200.7

15.9Magnesium mg/L 0.100 0.300EPA 200.7

157Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

Analyte Result Units LOD LOQ

Metals, Total

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 8 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341002WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Total, Low Level

Analysis Method

05/24/18 05/24/18Prep Date Analysis Date

1.44Total Chromium ug/L 0.00150 0.0232Hi Res ICPMS

0.0939Chromium (VI) ug/L 0.0122 0.0232Hi Res ICPMS

6.52% Chromium (VI) %Hi Res ICPMS

Analyte Result Units LOD LOQ

Metals, Dissolved Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

12.4FAluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

NDIron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

2.29FNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

NDZinc ug/L 5.00 15.0EPA 200.7

37.6Calcium mg/L 0.100 0.300EPA 200.7

16.1Magnesium mg/L 0.100 0.300EPA 200.7

160Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

Analyte Result Units LOD LOQ

Metals, Dissolved

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 9 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341002WSLH Sample:

Analyte Result Units

Field Data

Analysis Method

15.84Sample Temp-field (C) CentigradeField Data

9.21DO field (mg/L) mg/LField Data

94.8% Saturation %Field Data

7.70pH (SU) field SUField Data

90Cloud Cover % %Field Data

327Cond-fld(uS/CM@25C) UMHOS/CMField Data

16.0Transparency Tube (cm) CMField Data

LOD = Level of detection LOQ = Level of quantification ND = None detected. Results are less than the LOD F next to result = Result is between LOD and LOQ Z next to result = Result is between 0 (zero) and LOD if LOD=LOQ, Limits were not statistically derived

Test results for NELAP accredited tests are certified to meet the requirements of the NELAC standards. For a list of accredited analytes see http://www.slh.wisc.edu/about/compliance/nelac-laboratory-accreditationResults, LOD and LOQ values have been adjusted for analytical dilutions and percent moisture where applicable.Results relate only to the items tested.This Laboratory Report shall not be reproduced except in full, without written approval of the laboratory.The water microbiology unit analyzes samples as received and not all samples are tested for preservation before analysis is performed.

List of Abbreviations:

Responsible PartyMicrobiology: Sharon Kluender, Lab Manager, 608-224-6262Inorganic Chemistry: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Metals: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Organic Chemistry: Al Spallato, Lab Manager, 608-224-6269Emergency Chemical Response: Noel Stanton, Lab Manager, 608-224-6251Environmental Toxicology: Tracy Hanke, Lab Manager, 608-224-6270

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 10 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341003WSLH Sample:

ZANA SJIANWISCONSIN DNR

WT093

ZANA SJIANWISCONSIN DNR

Collection End: 5/23/2018 11:21:00 AM

Point or Outfall:

Project No:

Date Received:Date Reported: Sample Depth:

5/24/20186/8/2018

Customer ID:

Report To: Invoice To:

Field #: LD6

Collection Start: Collected By:

County:

Sample Type:

Sample Reason:

Sample Location:Sample Description:

CAMILLE BRUHNSU-SURFACE WATER

X-625241 Y-4873056

ID#:

Waterbody:

Program Code:Region Code:

Sample Comments

NITRIC ACID USED IN FIELD WAS EXPIRED.

For the dissolved metals tests, the sample was filtered and preserved at the lab.

Analyzed past the 15 minutes holding time: Method SM4500-H+B analyzed on 05/24/18 1330

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

26.0TOTAL SUSPENDED SOLIDS mg/L 5.0 5.0SM2540D

05/24/18 05/24/18Prep Date Analysis Date

19.0Chloride mg/L 1.00 3.20SM4500-CL-E

05/24/18 05/24/18Prep Date Analysis Date

Comments:Analyzed past the 15 minutes holding time.

8.32pH SU 1.00 1.00SM4500-H+B

05/25/18 05/25/18Prep Date Analysis Date

21.5Turbidity NTU 0.100 0.100SM2130B

05/29/18 05/30/18Prep Date Analysis Date

0.141Phosphorus mg/L 0.00500 0.0160EPA 365.1

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 11 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341003WSLH Sample:

Analyte Result Units LOD LOQ

Inorganic Chemistry, Dissolved

Analysis Method

05/24/18 05/25/18Prep Date Analysis Date

0.0163FAmmonia mg/L 0.0150 0.0480EPA 350.1

Analyte Result Units LOD LOQ

Metals, Total Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

339Aluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

1.20Iron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

3.01FNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

NDZinc ug/L 5.00 15.0EPA 200.7

55.9Calcium mg/L 0.100 0.300EPA 200.7

22.1Magnesium mg/L 0.100 0.300EPA 200.7

230Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

Analyte Result Units LOD LOQ

Metals, Total

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 12 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341003WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Total, Low Level

Analysis Method

05/24/18 05/24/18Prep Date Analysis Date

0.537Total Chromium ug/L 0.00150 0.0232Hi Res ICPMS

0.0796Chromium (VI) ug/L 0.0122 0.0232Hi Res ICPMS

14.8% Chromium (VI) %Hi Res ICPMS

Analyte Result Units LOD LOQ

Metals, Dissolved Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

12.7FAluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

NDIron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

2.36FNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

NDZinc ug/L 5.00 15.0EPA 200.7

57.6Calcium mg/L 0.100 0.300EPA 200.7

22.7Magnesium mg/L 0.100 0.300EPA 200.7

237Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

Analyte Result Units LOD LOQ

Metals, Dissolved

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 13 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341003WSLH Sample:

Analyte Result Units

Field Data

Analysis Method

17.95Sample Temp-field (C) CentigradeField Data

9.19DO field (mg/L) mg/LField Data

98.8% Saturation %Field Data

8.21pH (SU) field SUField Data

50Cloud Cover % %Field Data

469Cond-fld(uS/CM@25C) UMHOS/CMField Data

29.0Transparency Tube (cm) CMField Data

LOD = Level of detection LOQ = Level of quantification ND = None detected. Results are less than the LOD F next to result = Result is between LOD and LOQ Z next to result = Result is between 0 (zero) and LOD if LOD=LOQ, Limits were not statistically derived

Test results for NELAP accredited tests are certified to meet the requirements of the NELAC standards. For a list of accredited analytes see http://www.slh.wisc.edu/about/compliance/nelac-laboratory-accreditationResults, LOD and LOQ values have been adjusted for analytical dilutions and percent moisture where applicable.Results relate only to the items tested.This Laboratory Report shall not be reproduced except in full, without written approval of the laboratory.The water microbiology unit analyzes samples as received and not all samples are tested for preservation before analysis is performed.

List of Abbreviations:

Responsible PartyMicrobiology: Sharon Kluender, Lab Manager, 608-224-6262Inorganic Chemistry: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Metals: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Organic Chemistry: Al Spallato, Lab Manager, 608-224-6269Emergency Chemical Response: Noel Stanton, Lab Manager, 608-224-6251Environmental Toxicology: Tracy Hanke, Lab Manager, 608-224-6270

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 14 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341004WSLH Sample:

ZANA SJIANWISCONSIN DNR

WT093

ZANA SJIANWISCONSIN DNR

Collection End: 5/23/2018 10:49:00 AM

Point or Outfall:

Project No:

Date Received:Date Reported: Sample Depth:

5/24/20186/8/2018

Customer ID:

Report To: Invoice To:

Field #: PERROT

Collection Start: Collected By:

County:

Sample Type:

Sample Reason:

Sample Location:Sample Description:

CAMILLE BRUHNSU-SURFACE WATER

TREMPEALEAU RIVER X-622126 Y-4875013

ID#:

Waterbody:

Program Code:Region Code:

0.5F

Sample Comments

NITRIC ACID USED IN FIELD WAS EXPIRED.

For the dissolved metals tests, the sample was filtered and preserved at the lab.

Analyzed past the 15 minutes holding time: Method SM4500-H+B analyzed on 05/24/18 1330

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

133TOTAL SUSPENDED SOLIDS mg/L 5.0 5.0SM2540D

05/24/18 05/24/18Prep Date Analysis Date

25.0Chloride mg/L 1.00 3.20SM4500-CL-E

05/24/18 05/24/18Prep Date Analysis Date

Comments:Analyzed past the 15 minutes holding time.

8.04pH SU 1.00 1.00SM4500-H+B

05/25/18 05/25/18Prep Date Analysis Date

147Turbidity NTU 0.100 0.100SM2130B

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 15 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341004WSLH Sample:

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/29/18 05/30/18Prep Date Analysis Date

0.873Phosphorus mg/L 0.00500 0.0160EPA 365.1

Analyte Result Units LOD LOQ

Inorganic Chemistry, Dissolved

Analysis Method

05/24/18 05/25/18Prep Date Analysis Date

0.0396FAmmonia mg/L 0.0150 0.0480EPA 350.1

Analyte Result Units LOD LOQ

Metals, Total Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

2420Aluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

4.13Chromium ug/L 1.00 3.00EPA 200.7

14.0FCopper ug/L 5.00 15.0EPA 200.7

10.4Iron mg/L 0.100 0.300EPA 200.7

7.98FLead ug/L 3.00 10.0EPA 200.7

7.39Nickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

7.48FZinc ug/L 5.00 15.0EPA 200.7

42.1Calcium mg/L 0.100 0.300EPA 200.7

17.9Magnesium mg/L 0.100 0.300EPA 200.7

179Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 16 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341004WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Total

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

Analyte Result Units LOD LOQ

Metals, Total, Low Level

Analysis Method

05/24/18 05/24/18Prep Date Analysis Date

4.67Total Chromium ug/L 0.00150 0.0232Hi Res ICPMS

0.122Chromium (VI) ug/L 0.0122 0.0232Hi Res ICPMS

2.61% Chromium (VI) %Hi Res ICPMS

Analyte Result Units LOD LOQ

Metals, Dissolved Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

NDAluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

NDIron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

2.63FNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

NDZinc ug/L 5.00 15.0EPA 200.7

41.0Calcium mg/L 0.100 0.300EPA 200.7

17.8Magnesium mg/L 0.100 0.300EPA 200.7

175Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 17 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341004WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Dissolved

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

Analyte Result Units

Field Data

Analysis Method

15.74Sample Temp-field (C) CentigradeField Data

8.92DO field (mg/L) mg/LField Data

91.4% Saturation %Field Data

7.82pH (SU) field SUField Data

40Cloud Cover % %Field Data

356Cond-fld(uS/CM@25C) UMHOS/CMField Data

5.0Transparency Tube (cm) CMField Data

LOD = Level of detection LOQ = Level of quantification ND = None detected. Results are less than the LOD F next to result = Result is between LOD and LOQ Z next to result = Result is between 0 (zero) and LOD if LOD=LOQ, Limits were not statistically derived

Test results for NELAP accredited tests are certified to meet the requirements of the NELAC standards. For a list of accredited analytes see http://www.slh.wisc.edu/about/compliance/nelac-laboratory-accreditationResults, LOD and LOQ values have been adjusted for analytical dilutions and percent moisture where applicable.Results relate only to the items tested.This Laboratory Report shall not be reproduced except in full, without written approval of the laboratory.The water microbiology unit analyzes samples as received and not all samples are tested for preservation before analysis is performed.

List of Abbreviations:

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 18 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341004WSLH Sample:

Responsible PartyMicrobiology: Sharon Kluender, Lab Manager, 608-224-6262Inorganic Chemistry: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Metals: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Organic Chemistry: Al Spallato, Lab Manager, 608-224-6269Emergency Chemical Response: Noel Stanton, Lab Manager, 608-224-6251Environmental Toxicology: Tracy Hanke, Lab Manager, 608-224-6270

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 19 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341005WSLH Sample:

ZANA SJIANWISCONSIN DNR

WT093

ZANA SJIANWISCONSIN DNR

Collection End: 5/23/2018 11:55:00 AM

Point or Outfall:

Project No:

Date Received:Date Reported: Sample Depth:

5/24/20186/8/2018

Customer ID:

Report To: Invoice To:

Field #: T35

Collection Start: Collected By:

County:

Sample Type:

Sample Reason:

Sample Location:

Sample Description:

CAMILLE BRUHNSU-SURFACE WATER

TEMPEALEAU RIVER NEARCENTERVILLEX-616720 Y-4880708

ID#: 623002

Waterbody:

Program Code:Region Code:

0.5F

Sample Comments

NITRIC ACID USED IN FIELD WAS EXPIRED.

For the dissolved metals tests, the sample was filtered and preserved at the lab.

Analyzed past the 15 minutes holding time: Method SM4500-H+B analyzed on 05/24/18 1330

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

86.0TOTAL SUSPENDED SOLIDS mg/L 10.0 10.0SM2540D

05/24/18 05/24/18Prep Date Analysis Date

21.0Chloride mg/L 1.00 3.20SM4500-CL-E

05/24/18 05/24/18Prep Date Analysis Date

Comments:Analyzed past the 15 minutes holding time.

8.09pH SU 1.00 1.00SM4500-H+B

05/25/18 05/25/18Prep Date Analysis Date

87.0Turbidity NTU 0.100 0.100SM2130B

05/29/18 05/30/18Prep Date Analysis Date

0.581Phosphorus mg/L 0.00500 0.0160EPA 365.1

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 20 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341005WSLH Sample:

Analyte Result Units LOD LOQ

Inorganic Chemistry, Dissolved

Analysis Method

05/24/18 05/25/18Prep Date Analysis Date

0.0264FAmmonia mg/L 0.0150 0.0480EPA 350.1

Analyte Result Units LOD LOQ

Metals, Total Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

1670Aluminum ug/L 10.0 30.0EPA 200.7

SPIKE QC EXCEEDED. SPIKE RECOVERY: 196%

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

2.54FChromium ug/L 1.00 3.00EPA 200.7

8.49FCopper ug/L 5.00 15.0EPA 200.7

6.65Iron mg/L 0.100 0.300EPA 200.7

4.63FLead ug/L 3.00 10.0EPA 200.7

6.00Nickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

7.48FZinc ug/L 5.00 15.0EPA 200.7

40.3Calcium mg/L 0.100 0.300EPA 200.7

17.8Magnesium mg/L 0.100 0.300EPA 200.7

174Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

Analyte Result Units LOD LOQ

Metals, Total

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 21 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341005WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Total, Low Level

Analysis Method

05/24/18 05/24/18Prep Date Analysis Date

1.84Total Chromium ug/L 0.00150 0.0232Hi Res ICPMS

0.0935Chromium (VI) ug/L 0.0122 0.0232Hi Res ICPMS

5.08% Chromium (VI) %Hi Res ICPMS

Analyte Result Units LOD LOQ

Metals, Dissolved Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

19.5FAluminum ug/L 10.0 30.0EPA 200.7

SPIKE QC EXCEEDED. SPIKE RECOVERY: 196%

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

NDIron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

2.25FNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

NDZinc ug/L 5.00 15.0EPA 200.7

39.6Calcium mg/L 0.100 0.300EPA 200.7

17.6Magnesium mg/L 0.100 0.300EPA 200.7

171Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

Analyte Result Units LOD LOQ

Metals, Dissolved

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 22 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341005WSLH Sample:

Analyte Result Units

Field Data

Analysis Method

16.62Sample Temp-field (C) CentigradeField Data

9.73DO field (mg/L) mg/LField Data

101.8% Saturation %Field Data

7.89pH (SU) field SUField Data

80Cloud Cover % %Field Data

342Cond-fld(uS/CM@25C) UMHOS/CMField Data

14.0Transparency Tube (cm) CMField Data

LOD = Level of detection LOQ = Level of quantification ND = None detected. Results are less than the LOD F next to result = Result is between LOD and LOQ Z next to result = Result is between 0 (zero) and LOD if LOD=LOQ, Limits were not statistically derived

Test results for NELAP accredited tests are certified to meet the requirements of the NELAC standards. For a list of accredited analytes see http://www.slh.wisc.edu/about/compliance/nelac-laboratory-accreditationResults, LOD and LOQ values have been adjusted for analytical dilutions and percent moisture where applicable.Results relate only to the items tested.This Laboratory Report shall not be reproduced except in full, without written approval of the laboratory.The water microbiology unit analyzes samples as received and not all samples are tested for preservation before analysis is performed.

List of Abbreviations:

Responsible PartyMicrobiology: Sharon Kluender, Lab Manager, 608-224-6262Inorganic Chemistry: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Metals: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Organic Chemistry: Al Spallato, Lab Manager, 608-224-6269Emergency Chemical Response: Noel Stanton, Lab Manager, 608-224-6251Environmental Toxicology: Tracy Hanke, Lab Manager, 608-224-6270

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 23 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341006WSLH Sample:

ZANA SJIANWISCONSIN DNR

WT093

ZANA SJIANWISCONSIN DNR

Collection End: 5/23/2018 2:26:00 PM

Point or Outfall:

Project No:

Date Received:Date Reported: Sample Depth:

5/24/20186/8/2018

Customer ID:

Report To: Invoice To:

Field #: POKER REFERENCE

Collection Start: Collected By:

County:

Sample Type:

Sample Reason:

Sample Location:Sample Description:

CAMILLE BRUHNSU-SURFACE WATER

POKER COULEE CREEK X 629892 Y-4910534

ID#:

Waterbody:

Program Code:Region Code:

0.5F

Sample Comments

NITRIC ACID USED IN FIELD WAS EXPIRED.

For the dissolved metals tests, the sample was filtered and preserved at the lab.

Analyzed past the 15 minutes holding time: Method SM4500-H+B analyzed on 05/24/18 1330

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

16.0TOTAL SUSPENDED SOLIDS mg/L 2.5 2.5SM2540D

05/24/18 05/24/18Prep Date Analysis Date

9.04Chloride mg/L 1.00 3.20SM4500-CL-E

05/24/18 05/24/18Prep Date Analysis Date

Comments:Analyzed past the 15 minutes holding time.

8.03pH SU 1.00 1.00SM4500-H+B

05/25/18 05/25/18Prep Date Analysis Date

9.74Turbidity NTU 0.100 0.100SM2130B

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 24 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341006WSLH Sample:

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/29/18 05/30/18Prep Date Analysis Date

0.259Phosphorus mg/L 0.00500 0.0160EPA 365.1

Analyte Result Units LOD LOQ

Inorganic Chemistry, Dissolved

Analysis Method

05/24/18 05/25/18Prep Date Analysis Date

0.0197FAmmonia mg/L 0.0150 0.0480EPA 350.1

Analyte Result Units LOD LOQ

Metals, Total Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

215Aluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

0.443Iron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

NDNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

NDZinc ug/L 5.00 15.0EPA 200.7

27.0Calcium mg/L 0.100 0.300EPA 200.7

11.4Magnesium mg/L 0.100 0.300EPA 200.7

114Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 25 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341006WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Total

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

Analyte Result Units LOD LOQ

Metals, Total, Low Level

Analysis Method

05/24/18 05/24/18Prep Date Analysis Date

0.208Total Chromium ug/L 0.00150 0.0232Hi Res ICPMS

0.147Chromium (VI) ug/L 0.0122 0.0232Hi Res ICPMS

70.7% Chromium (VI) %Hi Res ICPMS

Analyte Result Units LOD LOQ

Metals, Dissolved Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

11.8FAluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

NDIron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

NDNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

NDZinc ug/L 5.00 15.0EPA 200.7

25.5Calcium mg/L 0.100 0.300EPA 200.7

10.8Magnesium mg/L 0.100 0.300EPA 200.7

108Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 26 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341006WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Dissolved

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

Analyte Result Units

Field Data

Analysis Method

15.92Sample Temp-field (C) CentigradeField Data

10.04DO field (mg/L) mg/LField Data

103.3% Saturation %Field Data

7.7pH (SU) field SUField Data

100Cloud Cover % %Field Data

216Cond-fld(uS/CM@25C) UMHOS/CMField Data

86.0Transparency Tube (cm) CMField Data

LOD = Level of detection LOQ = Level of quantification ND = None detected. Results are less than the LOD F next to result = Result is between LOD and LOQ Z next to result = Result is between 0 (zero) and LOD if LOD=LOQ, Limits were not statistically derived

Test results for NELAP accredited tests are certified to meet the requirements of the NELAC standards. For a list of accredited analytes see http://www.slh.wisc.edu/about/compliance/nelac-laboratory-accreditationResults, LOD and LOQ values have been adjusted for analytical dilutions and percent moisture where applicable.Results relate only to the items tested.This Laboratory Report shall not be reproduced except in full, without written approval of the laboratory.The water microbiology unit analyzes samples as received and not all samples are tested for preservation before analysis is performed.

List of Abbreviations:

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 27 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341006WSLH Sample:

Responsible PartyMicrobiology: Sharon Kluender, Lab Manager, 608-224-6262Inorganic Chemistry: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Metals: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Organic Chemistry: Al Spallato, Lab Manager, 608-224-6269Emergency Chemical Response: Noel Stanton, Lab Manager, 608-224-6251Environmental Toxicology: Tracy Hanke, Lab Manager, 608-224-6270

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 28 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341007WSLH Sample:

ZANA SJIANWISCONSIN DNR

WT093

ZANA SJIANWISCONSIN DNR

Collection End: 5/23/2018 2:53:00 PM

Point or Outfall:

Project No:

Date Received:Date Reported: Sample Depth:

5/24/20186/8/2018

Customer ID:

Report To: Invoice To:

Field #: TREMP@Q

Collection Start: Collected By:

County:

Sample Type:

Sample Reason:

Sample Location:Sample Description:

CAMILLE BRUHNSU-SURFACE WATER

X-625991 Y-4911901

ID#:

Waterbody:

Program Code:Region Code:

0.5F

Sample Comments

For the dissolved metals tests, the sample was filtered and preserved at the lab.

Analyzed past the 15 minutes holding time: Method SM4500-H+B analyzed on 05/24/18 1330

NITRIC ACID USED IN FIELD WAS EXPIRED.

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

26.7TOTAL SUSPENDED SOLIDS mg/L 4.8 4.8SM2540D

05/24/18 05/24/18Prep Date Analysis Date

16.1Chloride mg/L 1.00 3.20SM4500-CL-E

05/24/18 05/24/18Prep Date Analysis Date

Comments:Analyzed past the 15 minutes holding time.

7.72pH SU 1.00 1.00SM4500-H+B

05/25/18 05/25/18Prep Date Analysis Date

20.1Turbidity NTU 0.100 0.100SM2130B

05/29/18 05/30/18Prep Date Analysis Date

0.349Phosphorus mg/L 0.00500 0.0160EPA 365.1

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 29 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341007WSLH Sample:

Analyte Result Units LOD LOQ

Inorganic Chemistry, Dissolved

Analysis Method

05/24/18 05/25/18Prep Date Analysis Date

0.112Ammonia mg/L 0.0150 0.0480EPA 350.1

Analyte Result Units LOD LOQ

Metals, Total Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

365Aluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

2.24Iron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

5.28FNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

13.4FZinc ug/L 5.00 15.0EPA 200.7

24.3Calcium mg/L 0.100 0.300EPA 200.7

9.79Magnesium mg/L 0.100 0.300EPA 200.7

101Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

Analyte Result Units LOD LOQ

Metals, Total

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 30 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341007WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Total, Low Level

Analysis Method

05/24/18 05/24/18Prep Date Analysis Date

0.420Total Chromium ug/L 0.00150 0.0232Hi Res ICPMS

0.0956Chromium (VI) ug/L 0.0122 0.0232Hi Res ICPMS

22.8% Chromium (VI) %Hi Res ICPMS

Analyte Result Units LOD LOQ

Metals, Dissolved Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

10.9FAluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

NDIron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

4.32FNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

NDZinc ug/L 5.00 15.0EPA 200.7

23.5Calcium mg/L 0.100 0.300EPA 200.7

9.31Magnesium mg/L 0.100 0.300EPA 200.7

97.0Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

Analyte Result Units LOD LOQ

Metals, Dissolved

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 31 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341007WSLH Sample:

Analyte Result Units

Field Data

Analysis Method

15.11Sample Temp-field (C) CentigradeField Data

9.12DO field (mg/L) mg/LField Data

92.4% Saturation %Field Data

7.36pH (SU) field SUField Data

80Cloud Cover % %Field Data

230Cond-fld(uS/CM@25C) UMHOS/CMField Data

50.0Transparency Tube (cm) CMField Data

LOD = Level of detection LOQ = Level of quantification ND = None detected. Results are less than the LOD F next to result = Result is between LOD and LOQ Z next to result = Result is between 0 (zero) and LOD if LOD=LOQ, Limits were not statistically derived

Test results for NELAP accredited tests are certified to meet the requirements of the NELAC standards. For a list of accredited analytes see http://www.slh.wisc.edu/about/compliance/nelac-laboratory-accreditationResults, LOD and LOQ values have been adjusted for analytical dilutions and percent moisture where applicable.Results relate only to the items tested.This Laboratory Report shall not be reproduced except in full, without written approval of the laboratory.The water microbiology unit analyzes samples as received and not all samples are tested for preservation before analysis is performed.

List of Abbreviations:

Responsible PartyMicrobiology: Sharon Kluender, Lab Manager, 608-224-6262Inorganic Chemistry: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Metals: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Organic Chemistry: Al Spallato, Lab Manager, 608-224-6269Emergency Chemical Response: Noel Stanton, Lab Manager, 608-224-6251Environmental Toxicology: Tracy Hanke, Lab Manager, 608-224-6270

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 32 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341008WSLH Sample:

ZANA SJIANWISCONSIN DNR

WT093

ZANA SJIANWISCONSIN DNR

Collection End: 5/23/2018 1:43:00 PM

Point or Outfall:

Project No:

Date Received:Date Reported: Sample Depth:

5/24/20186/8/2018

Customer ID:

Report To: Invoice To:

Field #: TREMP@121

Collection Start: Collected By:

County:

Sample Type:

Sample Reason:

Sample Location:Sample Description:

CAMILLE BRUHNSU-SURFACE WATER

TREAMPEALEAU RIVER X-629994 Y-4914148

ID#:

Waterbody:

Program Code:Region Code:

0.5F

Sample Comments

NITRIC ACID USED IN FIELD WAS EXPIRED.

For the dissolved metals tests, the sample was filtered and preserved at the lab.

Analyzed past the 15 minutes holding time: Method SM4500-H+B analyzed on 05/24/18 1330

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

20.0TOTAL SUSPENDED SOLIDS mg/L 3.3 3.3SM2540D

05/24/18 05/24/18Prep Date Analysis Date

16.7Chloride mg/L 1.00 3.20SM4500-CL-E

05/24/18 05/24/18Prep Date Analysis Date

Comments:Analyzed past the 15 minutes holding time.

7.66pH SU 1.00 1.00SM4500-H+B

05/25/18 05/25/18Prep Date Analysis Date

15.6Turbidity NTU 0.100 0.100SM2130B

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 33 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341008WSLH Sample:

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/29/18 05/30/18Prep Date Analysis Date

0.326Phosphorus mg/L 0.00500 0.0160EPA 365.1

Analyte Result Units LOD LOQ

Inorganic Chemistry, Dissolved

Analysis Method

05/24/18 05/25/18Prep Date Analysis Date

0.112Ammonia mg/L 0.0150 0.0480EPA 350.1

Analyte Result Units LOD LOQ

Metals, Total Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

237Aluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

1.80Iron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

5.06FNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

8.83FZinc ug/L 5.00 15.0EPA 200.7

20.7Calcium mg/L 0.100 0.300EPA 200.7

7.80Magnesium mg/L 0.100 0.300EPA 200.7

83.8Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 34 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341008WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Total

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

Analyte Result Units LOD LOQ

Metals, Total, Low Level

Analysis Method

05/24/18 05/24/18Prep Date Analysis Date

0.367Total Chromium ug/L 0.00150 0.0232Hi Res ICPMS

0.114Chromium (VI) ug/L 0.0122 0.0232Hi Res ICPMS

31.1% Chromium (VI) %Hi Res ICPMS

Analyte Result Units LOD LOQ

Metals, Dissolved Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

NDAluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

NDIron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

5.09FNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

NDZinc ug/L 5.00 15.0EPA 200.7

22.0Calcium mg/L 0.100 0.300EPA 200.7

8.49Magnesium mg/L 0.100 0.300EPA 200.7

89.8Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 35 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341008WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Dissolved

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

Analyte Result Units

Field Data

Analysis Method

14.98Sample Temp-field (C) CentigradeField Data

8.91DO field (mg/L) mg/LField Data

90.0% Saturation %Field Data

7.25pH (SU) field SUField Data

100Cloud Cover % %Field Data

212Cond-fld(uS/CM@25C) UMHOS/CMField Data

69.0Transparency Tube (cm) CMField Data

LOD = Level of detection LOQ = Level of quantification ND = None detected. Results are less than the LOD F next to result = Result is between LOD and LOQ Z next to result = Result is between 0 (zero) and LOD if LOD=LOQ, Limits were not statistically derived

Test results for NELAP accredited tests are certified to meet the requirements of the NELAC standards. For a list of accredited analytes see http://www.slh.wisc.edu/about/compliance/nelac-laboratory-accreditationResults, LOD and LOQ values have been adjusted for analytical dilutions and percent moisture where applicable.Results relate only to the items tested.This Laboratory Report shall not be reproduced except in full, without written approval of the laboratory.The water microbiology unit analyzes samples as received and not all samples are tested for preservation before analysis is performed.

List of Abbreviations:

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 36 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341008WSLH Sample:

Responsible PartyMicrobiology: Sharon Kluender, Lab Manager, 608-224-6262Inorganic Chemistry: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Metals: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Organic Chemistry: Al Spallato, Lab Manager, 608-224-6269Emergency Chemical Response: Noel Stanton, Lab Manager, 608-224-6251Environmental Toxicology: Tracy Hanke, Lab Manager, 608-224-6270

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 37 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341009WSLH Sample:

ZANA SJIANWISCONSIN DNR

WT093

ZANA SJIANWISCONSIN DNR

Collection End: 5/23/2018 2:12:00 PM

Point or Outfall:

Project No:

Date Received:Date Reported: Sample Depth:

5/24/20186/8/2018

Customer ID:

Report To: Invoice To:

Field #: POKER BELOW SPILL

Collection Start: Collected By:

County:

Sample Type:

Sample Reason:

Sample Location:Sample Description:

CAMILLE BRUHNSU-SURFACE WATER

POKER COULEE CREEK X 629383 Y-4911304

ID#:

Waterbody:

Program Code:Region Code:

0.5F

Sample Comments

NITRIC ACID USED IN FIELD WAS EXPIRED.

For the dissolved metals tests, the sample was filtered and preserved at the lab.

Analyzed past the 15 minutes holding time: Method SM4500-H+B analyzed on 05/24/18 1330

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

204TOTAL SUSPENDED SOLIDS mg/L 10.0 10.0SM2540D

05/24/18 05/24/18Prep Date Analysis Date

18.7Chloride mg/L 1.00 3.20SM4500-CL-E

05/24/18 05/24/18Prep Date Analysis Date

Comments:Analyzed past the 15 minutes holding time.

7.74pH SU 1.00 1.00SM4500-H+B

05/25/18 05/25/18Prep Date Analysis Date

209Turbidity NTU 0.100 0.100SM2130B

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 38 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341009WSLH Sample:

Analyte Result Units LOD LOQ

Inorganic Chemistry

Analysis Method

05/29/18 05/30/18Prep Date Analysis Date

1.27Phosphorus mg/L 0.0100 0.0320EPA 365.1

Analyte Result Units LOD LOQ

Inorganic Chemistry, Dissolved

Analysis Method

05/24/18 05/25/18Prep Date Analysis Date

0.0635Ammonia mg/L 0.0150 0.0480EPA 350.1

Analyte Result Units LOD LOQ

Metals, Total Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

1.29FCadmium ug/L 1.00 3.00EPA 200.7

6.40Chromium ug/L 1.00 3.00EPA 200.7

18.5Copper ug/L 5.00 15.0EPA 200.7

13.7Iron mg/L 0.100 0.300EPA 200.7

11.1Lead ug/L 3.00 10.0EPA 200.7

10.2Nickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

9.19FZinc ug/L 5.00 15.0EPA 200.7

30.4Calcium mg/L 0.100 0.300EPA 200.7

12.9Magnesium mg/L 0.100 0.300EPA 200.7

129Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

3770Aluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 39 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341009WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Total

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

Analyte Result Units LOD LOQ

Metals, Total, Low Level

Analysis Method

05/24/18 05/24/18Prep Date Analysis Date

3.90Total Chromium ug/L 0.00150 0.0232Hi Res ICPMS

0.289Chromium (VI) ug/L 0.0122 0.0232Hi Res ICPMS

7.41% Chromium (VI) %Hi Res ICPMS

Analyte Result Units LOD LOQ

Metals, Dissolved Recoverable

Analysis Method

05/25/18 05/29/18Prep Date Analysis Date

NDAluminum ug/L 10.0 30.0EPA 200.7

MATRIX SPIKE QC EXCEEDED.

NDAntimony ug/L 5.00 16.0EPA 200.7

NDBeryllium ug/L 0.500 1.60EPA 200.7

NDCadmium ug/L 1.00 3.00EPA 200.7

NDChromium ug/L 1.00 3.00EPA 200.7

NDCopper ug/L 5.00 15.0EPA 200.7

NDIron mg/L 0.100 0.300EPA 200.7

NDLead ug/L 3.00 10.0EPA 200.7

NDNickel ug/L 2.00 6.00EPA 200.7

NDSelenium ug/L 10.0 30.0EPA 200.7

NDSilver ug/L 2.00 6.00EPA 200.7

NDZinc ug/L 5.00 15.0EPA 200.7

28.6Calcium mg/L 0.100 0.300EPA 200.7

12.2Magnesium mg/L 0.100 0.300EPA 200.7

122Hardness (SM 2340B) mg/L 0.660 2.00EPA 200.7

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 40 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341009WSLH Sample:

Analyte Result Units LOD LOQ

Metals, Dissolved

Analysis Method

05/25/18 05/25/18Prep Date Analysis Date

NDMercury ug/L 0.030 0.080EPA 245.1

Analyte Result Units

Field Data

Analysis Method

15.40Sample Temp-field (C) CentigradeField Data

8.88DO field (mg/L) mg/LField Data

90.4% Saturation %Field Data

7.15pH (SU) field SUField Data

100Cloud Cover % %Field Data

242Cond-fld(uS/CM@25C) UMHOS/CMField Data

5.0Transparency Tube (cm) CMField Data

LOD = Level of detection LOQ = Level of quantification ND = None detected. Results are less than the LOD F next to result = Result is between LOD and LOQ Z next to result = Result is between 0 (zero) and LOD if LOD=LOQ, Limits were not statistically derived

Test results for NELAP accredited tests are certified to meet the requirements of the NELAC standards. For a list of accredited analytes see http://www.slh.wisc.edu/about/compliance/nelac-laboratory-accreditationResults, LOD and LOQ values have been adjusted for analytical dilutions and percent moisture where applicable.Results relate only to the items tested.This Laboratory Report shall not be reproduced except in full, without written approval of the laboratory.The water microbiology unit analyzes samples as received and not all samples are tested for preservation before analysis is performed.

List of Abbreviations:

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:

Page 41 of 41

Laboratory ReportWisconsin State Laboratory of Hygiene

2601 Agriculture Drive, PO Box 7996Madison, WI 53707-7996

(800)442-4618 - FAX (608)224-6213http://www.slh.wisc.edu

D.F. Kurtycz, M.D., Medical Director - Prof. James J. Schauer, Ph.D., Director

Environmental Health DivisionWDNR LAB ID: NELAP LAB ID: EPA LAB ID: WI DATCP ID:113133790 E37658 WI00007, WI00008 105-415

384341009WSLH Sample:

Responsible PartyMicrobiology: Sharon Kluender, Lab Manager, 608-224-6262Inorganic Chemistry: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Metals: DeWayne Kennedy-Parker, Lab Manager, 608-224-6282Organic Chemistry: Al Spallato, Lab Manager, 608-224-6269Emergency Chemical Response: Noel Stanton, Lab Manager, 608-224-6251Environmental Toxicology: Tracy Hanke, Lab Manager, 608-224-6270

DRAFTReport ID: 0000.25.2.WSLH.0Report Rev:


Recommended