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R2R Printed Electro-Mechanical System 2019 R2R USA 2019. 10. 09 Seung-Hyun Lee, PhD Senior Researcher Dept. Printed Electronics Korea Institute of Machinery and Materials, 171 Jang-Dong, Yuseong-Gu, Daejeon, 305-343, KOREA Email: [email protected] Development of Transparent Conductive Electrode for Flexible Electronics Applications 1/29
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  • R2R Printed Electro-Mechanical System

    2019 R2R USA

    2019. 10. 09

    Seung-Hyun Lee, PhDSenior ResearcherDept. Printed ElectronicsKorea Institute of Machinery and Materials, 171 Jang-Dong, Yuseong-Gu, Daejeon, 305-343, KOREA Email: [email protected]

    Development of Transparent ConductiveElectrode for Flexible Electronics Applications

    1/29

    mailto:[email protected]

  • R2R Printed Electro-Mechanical System

    1. Printed Electronics @ KIMM

  • 2019 R2R USA

    Introduction of KIMM1976 Established as Korea Test Institute of Machinery and Metals1992 Renamed as Korea Institute of Machinery and Materials (KIMM)2007 Established Korea Institute of Materials Science (KIMS) as an affiliated Institute2010 Established Daegu Research Center for Medical Devices and Green Energy2013 Established Busan Laser Application Support Center

    History

    Mission : Performing R&D on key technology in the area of mechanical engineering: Reliability tests, evaluates machine components materials: Commercializes through technology transfer and support

    Personnel : Permanent 492 (2019)

    352

    Research Scientists

    73 67

    TechnicalStaff

    AdministrationStaff

    146

    GovernmentFunding

    57

    Institute Revenue

    89

    Chart1

    Institute Revenue

    Government Funding

    판매

    Income (M$)

    95

    62

    Sheet1

    판매

    Institute Revenue95

    Government Funding62

    차트 데이터 범위의 크기를 조정하려면 범위의 오른쪽 아래 모서리를 끄십시오.

  • 2019 R2R USA

    4/41

    Vice President

    Energy SystemsResearch Division

    Nano-Convergence Mechanical Systems Research Division

    Environmental SystemResearch Division

    Dept. of R&D Strategy

    Dept. of Planning and Budget

    Dept. of Human Resource Development

    Dept. of General Affairs and Accounting

    President Auditor

    Dept. of Audit

    Board of Trustees

    Advanced Manufacturing Systems Research Division

    Mechanical Systems Safety Research Division

    Dept. of Small and Medium Enterprise Technology Support

    Administration DivisionStrategy Planning Division

    Dept. of Facility Operations and Procurement

    Daegu Research Center for Medical Devices and Green Energy

    Dept. of Knowledge Management & PR

    Dept. of R&D Management

    Korea Institute of Materials Science (KIMS)

    Busan Machinery Research Center forLaser Technology & Nuclear Equipment

    Introduction of KIMM

  • 2019 R2R USA

    5/36

    Introduction of KIMM

    KRICT (R2R ASIA 2019)

    KIMM

    Daeduck Science Town in Daejeon : National Lab (KIMM, KRICT, KARI,

    KAERI, KRISS, ETRI, KRISO, KIER …)

  • 2019 R2R USA

    Materials EquipmentProcessing& Analysis

    Functional electronic devices

    - Synthesis of NPs…

    - E-ink (paste)

    formulation

    - Fine tuning for ink

    printability

    - Etc.

    - Reverse (offset)

    - (R2R) Gravure (offset)

    - (R2R) Slot-die coating

    - (R2R) Imprinting

    - Spin / Bar coating

    - Screen printing

    - (R2R) IPL

    - (R2R) UV/NIR/MIR

    - (R2R) Plasma treatment

    - Multi-measurement system

    - UV-VIS spectroscopy

    - Solar simulator

    Development of largearea & low cost electronics OPV / OLED / TFT / RFID / Sensors / Supercapacitor / Etc.

    Dept. Printed Electronics @ KIMM

    Development of R2R based printing & coating system for mass production of various flexible electronics applicationsMission

  • 2019 R2R USA

    Common characteristics

    Size Large -> Large area patterningDemand High -> Mass productionPrecision medium -> Several or tens of micronPrice cheap -> Cheap process Flexibility -> Plastic or paper substrate

    Roll-to-roll printing/coating system

    , Gravure printing, InkJet printing, screen printing, Slot-die coating, Spray coating

    R2R printing/coating system for Flexible Electronics

    2015–2020 : IoT, Wearable, Flexible era.

    IoT

    Solar cell

    Flexible diaply

    Smartpackage market

    Display market

    Solar cell market

    Dept. Printed Electronics @ KIMM

  • 2019 R2R USA

    활용분야

    Touch ScreenPrinted Solar Cell

    Printed RFID Tag

    Printed Battery and Display

    Applications

    Printed Transistor

    Printed Antenna

    Printed Memory

    Dept. Printed Electronics @ KIMM

  • R2R Printed Electro-Mechanical System

    2. Flexible Transparent ConductiveElectrode

  • 2019 R2R USA

    Trend in TCE in Various Electronics

  • 2019 R2R USA

    Trend in TCE in Various Electronics

  • 2019 R2R USA

    Trend in TCE in Various Electronics

  • 2019 R2R USA

    Trend in TCE in Various Electronics

  • 2019 R2R USA

    14

    Trend in TCE in Various Electronics

  • 2019 R2R USA

    Trend in TCE in Various Electronics

  • 2019 R2R USA

    DisplayOLED Solar cellAs is

    To-be Deformable displaysDeformable lightings Flexible, large area solar cells

    Based on glass (rigid) substrate / expensive material & process /

    • Wearable electronics• Deformable battery+ Multi-function (Integration)

    Trend in TCE in Various Electronics

    http://www.solarenergybase.com/how-do-solar-panels-work/

  • 2019 R2R USA

    Trend in TCE in Various Electronics

    Problem of ITO

    • High Resistance (>150 Ω/sq)• Low Transparency ($80/㎡)

    • Brittle, Low Flexibility

    Market Needs

    • Low Resistance : 89%

    • Low Cost : R2R Wet Process

    • High Flexibility

    Need for New Flexible Transparent Conductive Electrode

    : High Performance AgNW or Metal Mesh TCE by R2R Coating & Printing

    Ref: Cambrios WebsiteClearOhmTM Silver Nanowire 23’’ LG V325 All-in-One PC

  • R2R Printed Electro-Mechanical System

    3. Printed Metal Mesh TransparentConductive Electrode

  • 2019 R2R USA

    Development of R2R Gravure/Gravure-offset Printing System

    96bit RFID antenna pattern with Ag nano ink

    Multi R2R Printing System (Gravure, Gravure-offset, Flexo Printing)

    Development of R2R Printing System

    [HF Printed Antenna] [UHF Printed Antenna]

    Registration control for multi-layer printing

  • 2019 R2R USA

    Plastic film

    Patterned metal grid

    Coated transparent electrode

    Only PET film Transparent Conductive Film

    Ag metal grid mesh + Conductive polymer

    Line width: 7.11 um Height: 501 nm

    Sheet resistance: 9.65 Ω/□Transparency: 83.69 % (550nm)

    Development of R2R Printing System

  • 2019 R2R USA

    Knowledge, Innovation, Motivation, Marketability

    Flexo

    InkJet

    Gravure-offset

    GravureTFTTSP

    Minimum feature size (㎛)

    Thro

    ughp

    ut (m

    2 /s)

    1 10 500

    10-4

    10-2

    1

    100

    100

    Flat screen

    Rotary screen

    3um

    Reverseoffset

    Development of Reverse-offset Printing System

  • 2019 R2R USA

    Coating Process Roll Off Process Cliché Patterning Set Process

    22

    Patterning area : 50mm*50mm Patterning area : 8 inch wafer

    Development of Reverse-offset Printing System

  • 2019 R2R USA

    Ink Separation Interface Separation

    23

    Easy to control the amount of transferred ink Good surface roughness in area printing8

    Development of Reverse-offset Printing System

  • 2019 R2R USA

    24

    Development of Reverse-offset Printing System

  • 2019 R2R USA

    100x Microscope image

    Line width ~ 1.0 ± 0.2 ㎛

    Thickness : 0.2 ±0.05 ㎛

    Transparency ~ 96%

    Line width ~ 4.7 ㎛

    Thickness ~ 0.2 ㎛

    Transparency ~ 88.5% (including substrate)

    Haze ~ 1.9% (including substrate)

    Sheet resistance ~ 28.4 ohm/sq.

    Development of Reverse-offset Printing System

  • 2019 R2R USA

    7” Printed Metal Mesh Touch Screen SensorChoi. et. al., Journal of Information Display, 16(1), 37-41 (2015)

    Development of Reverse-offset Printing System

    Roughnessof electrodeRa=6 nm

  • 2019 R2R USA

    27

    ITO TCE : PCE ~2.76%Ag mesh TCE: PCE ~ 2.82%

    Transparency : 85~86% (including substrate)

    Sheet resistance : 20 ohm/sq.

    Development of Reverse-offset Printing System

  • 2019 R2R USA

    • Imprinted disposable cliché using UV imprinting

    - Cliché : PET - Printed Sample (LW= 3.6 ~ 3.9 ㎛)

    Glass TCE

    Printed Metal mesh

    Technology Transferred to PNT Co.

    Development of Reverse-offset Printing System

  • 2019 R2R USA

    Development of Roll-to-roll Imprinting Process & System

    R2R UV Micro/Nano Imprinting System for Optical Film

    R2R Thermal Imprinting System for TCE(Technology Transferred to Duckin Co.)

    Development of R2R Printing System & Applications

    R2R Nanoimprinting System

    (Technology Transferred to Goldmax Co., IPEN Co.)

  • 2019 R2R USA

    Comparison between Positive & Negative TCE

    (Technology Transferred to DCN Co.)

    Development of R2R Imprinting System

  • 2019 R2R USA

    ITO-free TCF by Thermal Imprinting for OPV

    Development of R2R Printing System & Applications

    J.-S. Yu et al. Solar Energy Materials & Solar Cells, Vol. 109, 142-147, 2013(Collaborative research with Dr. Krebin RISO-DTU)

  • R2R Printed Electro-Mechanical System

    4. Metal Nanowire TransparentConductive Electrode

  • 2019 R2R USA

    Development of AgNW Slot-die Coating Process

    Development of R2R Coating System & Applications

    Schematic of Slot-die Coating Process

  • 2019 R2R USA

    Development of AgNW Slot-die Coating Process

    Development of R2R Coating System & Applications

    Conductivity is not constatnt with film thickness: Transition (Network => Bulk)

    S. De et al. ACS Nano, 2009

  • 2019 R2R USA

    Development of AgNW Slot-die Coating System

    Development of R2R Coating System & Applications

    Sheet Resistance UniformityAverage : 25.69Ω/□Standard Deviation : 0.72Ω/□, ±2.8%

    Technology Transferred to IPEN Co.

  • 2019 R2R USA

    Photonic sintering

    Ref. 1 Chem. Mater. 2015, 27, 7788Ref. 2 Adv. Mater. 2014, 26, 5808Ref. 3 Nanoscale, 2014, 6, 5980

    - Rs and T% could be controlled by adjusting NW ink concentration

    - Higher performance compared to other previous reports

    Ref. 4 Nano Lett., 2014, 14, 6298Ref. 5 Adv. Energy Mater. 2014, 4, 1300737Ref. 6 J. Am. Chem. Soc. 2012, 134, 14283

    Development of Photonic Sintering Process

    Novacentrix PulseForge 1300

    Development of CuNW TCE by Intense Pulsed Light

    Woo K., Small, 14, 1800676, (2018), Front cover

  • 2019 R2R USA

    Selective Light Induced Patterning (SLIP) process

    NWs on non-irradiated area was

    clearly removed out by wiping

    Development of Photonic Sintering Process

  • 2019 R2R USA

    Surface roughness Adhesion property

    Oxidation stability Mechanical stability

    Better oxidation stability due the reduction of surface area exposed to air

    1.08 fold increase

    Nanoscale, 2016, 8, 8995

    Development of Photonic Sintering Process

  • 2019 R2R USA

    Collaboration with DGIST (Prof. Lee Y. G.)

    Flexible TCE for OLED Flexible Transparent Heater

    Development of Photonic Sintering Process

  • 2019 R2R USA

    40

    Kwangyoung Kim (Ph.D. )Printing System Design &

    Manufacturing [email protected]

    Jeongdai Jo (Ph.D.)Printing/ Coating/ Patterning Process

    [email protected]

    Taikmin Lee (Ph.D.)Printing System Design &

    Manufacturing

    [email protected]

    Inyoung Kim (Ph.D.)Printing Materials & Device Fabrication

    [email protected]

    Sin Kwon (Ph.D.) Printing System Design &

    Manufacturing [email protected]

    Dongwoo Kang (Ph.D.)Printing System Design &

    Manufacturing [email protected]

    Yunseok Jang (Ph.D.)Printing Materials & Device Fabrication

    [email protected]

    Seunghyun Lee (Ph.D.)R2R Printing & Coating System

    [email protected]

    Kyoohee Woo (Ph.D.)Printing Materials & Device Fabrication

    [email protected]

    Hyunchang Kim (Ph.D.)Printing system design & integration

    [email protected]

    Jaeyoung Seok (Ph.D.)Printing Processes & Device

    Fabrication

    [email protected]

    Pyoungwon Park

    (Senior technologist)Printing Equipment & Part Design

    [email protected]

    Hyuntae Kim (Technologist)Printing System Control &

    Manufacturing

    [email protected]

    Jaeyoung Kim (Ph.D.)R2R Printing Control Design & Data

    Signal Processing

    [email protected]

    Key Memebers

  • 2019 R2R USA

    Seung-Hyun Lee, PhDSenior Researcher

    Korea Institute of Machinery and Materials, 171 Jang-Dong, Yuseong-Gu, Daejeon, KOREA 305-343

    Email: [email protected]

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