Dyad data overviewUniversity of Vienna
31.03.2009
Janne Savolainen
University of Twente, the Netherlands
Structure
Purpurin (Pur)
Carotenoid (Car)
Absorption spectra
Pur
(dashed line)
Car (dash-dotted line)
Dyad (solid line)
Pur
Car
linker
Car: Transient absorption surface
Short Long
Car: Transient spectra and time traces
Car: SAS Target analysis results
KIC K1 K2 K3
100 fs 500 fs 7.4 ps 10.0 ps
Dyad
Structure and spectra
Fluorescence excitation spectrum: ET ~60%
Transient absorption data
carotenoid (donor)
porphyrin (acceptor)
S2
S1Q
y
S0
Sn
2
1 3S0
4
T1
Tn
Savolainen et al. J Phys Chem B 2008
Fits well to the data
Coherent Control
Feedback signals
Transient absorption spectrum at time delay of 8 ps
carotenoid (donor)
porphyrin (acceptor)
S 2
S 1Q y
S 0
70%
30%
50 fs
110 fs
S n
probe IC
pump
probe ET
S 0
7.7 psFew ns
Optimize the loss channel (IC/ET)
Optimize IC/ETusing Fourier parameterization
Optimize ET/ICusing Fourier parameterization
Savolainen et al. PNAS 2008
Savolainen et al. PNAS 2008
2D
SAS and the laser spectrum
2D at T=60 fs real part
2D at T=60 fs Car bleach
2D at T=60 fs Pur Bleach
2D at T=60 fs Qy ESA
2D at T=60 fs HotS0
2D at T=60 fs ???
2D amplitude spectrum at T=60 fs
Vibrational cross peak amplitude
Summary 2D at 60 fs real part
Carotenoid vs Dyad 2D at 0 fs amplitude spectra
Acknowledgments
FOM-institute AMOLF,University of Twente:Jennifer HerekNiels DijkuizenRiccardo Fanciulli
University of Vienna:Harald KauffmannJürgen HauerFranz Milota
Arizona state university:Ana Moore
University of Marburg:Marcus MotzkusTiago Buckup