1
The RTP Pyrolysis Pathway
Maximizing Value of Biomass Residues
April 2011
Ensyn Corporation overview
RTP Technology
Renewable Fuel Products
Project Initiatives
Summary
Presentation Overview
Ensyn is a US, technology-based producer of renewable fuels and chemicals
Core technology is Rapid Thermal Processing (RTP™), a fast pyrolysis technology for conversion of cellulosic wood feedstocks
Commercial production of renewable chemicals and fuels since 1989
Food chemicals application of RTP developed in mid 1980’s and sold to Red Arrow Products Company (Wisconsin)
Petroleum heavy crude upgrading application of RTP developed in late 1990s and sold to Ivanhoe Energy Inc in 2005
Ensyn Corporation - Overview
Major alliance for renewable liquid fuels established with UOP Inc., a Honeywell company, in 2008
Ensyn has now developed a market-ready, conditioned RTP Renewable Heating Oil (RHO) from cellulosic wood residues
RTP transportation fuels in development
Initial projects announced in Malaysia, Alberta and Italy
Business development initiatives worldwide
Ensyn’s role: License RTP technology Participate in RTP projects
Current Focus: Renewable Liquid Fuels
RTP Background
Continuous development since 1984 Current focus: renewable fuels
Envergent Technologies: UOP/Honeywell connection
UOP/Honeywell: Engineering / performance guarantees Piggy-back PyOil technology (upgrading) Credibility Development capabilities Worldwide sales network
Ensyn: RTP technology, patents, I.P. Operating history / partnerships Proven commercial roll-out in two industries Know-how (business and technical)
UOP: FCC & RTP
RTP is close analogue to FCC (Fluid Catalytic Cracking) FCC technology is key process in gasoline production UOP has been designing FCC units since the early 1940’s – a co-inventor Licensed over 250 units – more than 50% of world-wide capacity Unit sizes from 1,500 to 200,000 BPD of capacity
RTPTM UOP FCC
UOP facilitates scale-up, engineering and supply
RTP Technology
Prototype RTP Fuels Plant
Renfrew Fuels Commercial Prototype Facility
Producing RTP liquids since 2007
Renfrew, Ontario
Nameplate capacity: 75 dry tpd
Processing experience: up to 100 dry tpd –
Approx. 18,000 gal/day of RTP Renewable Heating Oil @ 75% yield
RTP: 20+ years of commercial operations
The world’s only commercial fast pyrolysis process Patented, proprietary
RTP Technology
Solid Biomass
Pyrolysis Oil
Minimal net utilities RTP is self-sustaining process
RTP Flow Diagram
0%10%20%30%40%50%60%70%80%
Bio-Oil
Bio-Gas
Char
Biomass
PyOil
Bio Gas
Char
Basic Product Yields
RTP Mass-Energy Balance – 75 tpd basis
Biomass Dryer
RTPTM
~47wt% moisture ~10,895 lb/hr ~48.9 MM btu/hr
~6 wt% moisture ~6,298 lb/hr ~48.9 MM btu/hr
Dry Biomass
Wet Biomass
Pyrolysis Heating
Oil
~5.3 MMbtu/hr
~4.8 MMbtu/hr Flue Gas
Net Energy for Drying
~4.0 MMbtu/hr Product Gas
PYROLYSIS HEATING OIL YIELDS
Mass ~ 73 wt% of dry biomass Energy ~ 71 % of dry biomass Energy Content ~ 75,000 btu/gal Equivalence Value ~ 1.3 Energy Density ~ 6 times dry feed
~72.7 wt% of feed ~34.8 MM btu/hr ~11,000 gal per day ** Net Utilities ~ 0.9 MM btu/dry ton processed **
Renewable Liquid Fuels
RTP PyOil Liquid Fuels Development
Crude RTP liquids have been combusted commercially for 20+ years for heating, drying or process steam
Crude RTP liquids combustion tests have been successfully carried out in numerous boiler/combustion systems up to 60 MWth (200 MMbtu/hr)
Conditioned heating oil product developed in 2010 for broader applications for heting and power generation
= RTP Renewable Heating Oil (RHO) RHO has enhanced properties compared to
ASTM-D7544-10 “Standard Specification for Pyrolysis Liquid Biofuel”
RTP liquids combustion boiler, Rhinelander,
Wisconsin
Crude RTP liquids production
Combustion of crude RTP liquids
for drying and space heating
Combustion of crude RTP liquids
in utility and industrial boilers
Combustion of conditioned RTP
Renewable Heating Oil (RHO) in
Industrial Heating and Power
Applications
Fully upgraded on-road
Transportation Fuels
1989 1992 1997 2010 2012
Evolution: RTP Liquid Fuels
RTP Renewable Heating Oil (RHO)
Development of a “Conditioned” heating oil for broad applications in heating and power generation= RHO
RHO can be co-fired or use alone in conventional boilers with little or no modifications
Additional uses for RHO in stationary diesels for power generation
A standardized PHO Combustion package developed to retrofit fuel oil boilers for 100% RHO use
RHO combustion emissions compare favorably with fossil fuel
Standardized RHO combustion test unit
RHO production footprint similar to other energy alternatives
GHG emission approaches zero
Assumed biomass transport distances: 200 km for logging residues 25 km for short rotation forest crops 0 km for sawmill residues
Comparison of GHG Emissions Cradle to Delivered Energy
0
20
40
60
80
100
120
Petroleum Crude Oil
Hard Coal
gCO
2 eq/
MJ
Natural Gas
Canadian Oil Sands Crude Oil
RHO from
Logging Residues
RHO from
Willow
RHO from
Poplar
Energy extraction GHG emissions
RHO Lifecycle footprint greener than other alternatives
70-90% lower GHG emission SOX emission similar to natural gas
Comparison of GHG Emissions Cradle to Delivered Energy, and Burned
0
20
40
60
80
100
120
Petroleum Fuel Oil
Hard Coal
gCO
2 eq/
MJ
Natural Gas
RHO from Logging Residues
RHO from Willow
RHO from Poplar
Life Cycle GHG emissions
through combustion
UOP 5398A-34
RHO from
Sawmill Residues
RHO from Sawmill
Residues
Renewable Heating Oil & GHG
Power generation with turbine genset is proven Ensyn is working with a leading diesel engine
manufacturer on a RHO-fed diesel genset Trials are underway Diesel engine with guarantees expected in late 2011 Dramatic increases in efficiency over conventional
cogen
Power Generation
Major initiative with UOP Production of gasoline, diesel and jet fuels from RTP LIquids Drop-in solution – products are indistinguishable from
petroleum counterparts Addition of hydrogen/use of catalysts Success in smaller scale Current focus on scale-up, logistics, catalyst optimization Commercial availability in 2012
Transport Fuels
Projects Initiatives
Joint venture established between Ensyn and Tolko Industries
JV to develop 400 tpd RTP facility in High Level, Northern Alberta
Feedstocks: wood residues from High Level dimensional lumber mill
Products: heat, power and resins
Resins to be used for Tolko engineered panels
Engineering and design: UOP
Construction to start late 2011
Tolko Industries - Alberta
Premium Renewable Energy established and licensed to develop RTP projects in Malaysia, Indonesia and part of India
Focus is palm residues and sugar cane baggasse
Premium has announced intent to build 29 RTP facilities over next ten years in Malaysia for conversion of palm residues. The entire project would:
Process 7.7 million tons of palm waste / year
Produce 3.8 million tons of RTP liquids / year
RTP liquids to be used for heat and power
Engineering: UOP
Construction to begin late 2011
Premium - Malaysia
premiumR E N E W A B L E E N E R G Y
RTP Project in central Italy being developed by Industria e Innovazione, a leading Italian power/renewable energy group
Project will process 150 tons per day of mixed-source wood residues
Principal product will be power (diesel genset)
Engineering: UOP
Constriction to start late 2011
INDI - Italy
Summary
Ensyn & RTP: a unique, patented pyrolysis technology with a proven
commercial track record across multiple industries Strategic partnership for liquid fuels with industry leaders UOP/Honeywell Focus on non-food wood and agricultural residues as RTP feedstocks RTP is an attractive technology “Pathway” that allows for the conversion
of wood/wood residues to: Available now: A series of commercial products with attractive
economic returns: heating fuels, power, chemicals Available soon: Transport fuels, specialty chemicals