Final Analytical Report · Environmental Protection Agency Region 6 Laboratory 10625 Fallstone...

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

Region 6 Laboratory 1 Environmental Services Branch

10625 Fallstone Road, Houston, TX 77099 Phone: (281)983-2100 Fax: (281)983-2248

Final Analytical Report

Site Name Marion Pressure Treating

Sample Collection Date(s)~ 03/20/13

Contact Bart Canellas (6SF-RL)

Report Date 05/03/13

Project # 13SF073

Work Order(s) 1303018

13 HAY 22 AH 10: 37

684424

Analyses included in this report:

Metals ESAT Mercury CLP Metals ICP/MS CLP

ABN CLP Low Level Metals ICP CLP

Report Narrative

Sample Management:

This report contains the semi-volatile and metals data only. The chloride, nitrate, nitrite, nitrate+nitrite, sulfate, sulfide, and TOC are analyses being done by the TCEQ Laboratory. The TCEQ data will be reported as soon as it is available.

Semi-volatiles:

Benzoic acid and Carbazole are quahfied as estimated, where reported, due to problems with calibration.

The surrogate Terphenyl-dl4 fails low in the BS. Acenaphthene, 2-ChlorophenoI, Phenol, and Pyrene recoveries fail low in the BS. Acenaphthene and Phenol recoveries fail high in the MS/MSD due to inadequate spike added. The RPD for Pyrene fails high. Because there were multiple failures for Acenaphthene, Phenol, and Pyrene in the BS/MS/MSD, these analytes are qualified as estimated, where reported.

Benzo(a)pyrene was found above the RL in the aliquot used for the MS at 2.0 ug/L. It was below the RL in the source (1303018-02) and the aliquot used for the MSD. Both were 1.8 ug/L.

005330

Report Narrative (cont'd)

Metals ICP: Batch: B3C2201:

MSl/MSDl: The sample concentration for iron exceeds the spike added concentration by a factor of four or more and can not be reUably calculated.

Standard procediu-es for quality assurance and quality control were followed in the analysis and reporting of the sample results. The results apply only to the samples tested. This final report should only be reproduced in full.

Reporting limits are adjusted for sample size and matrix interference.

Report Approvals

Ricnard McMillir Regron 6 Laboratory Manager

Ddsddêleigh Region 6 Laboratory Branch Chief

005331

Environmental Protection Agency

Region 6 Laboratory 10625 Fallstone Road, Houston, TX 77099

Plione:(281)983-2100 Fax:(281)983-2248

Semivolatiles by CLP OLM04.2 - GC/MS (Low Level) LablD: 1303018-01 Station ID: ER-1 Batch: B3C2101 Date Collected: 03/20/13 Sample Type: Liquid Sample Vol: 1012ml Sample Qualifiers: A

Surrogates

Anal5ê

2-Fluorophenol Phenol-dS 2-Chlorophenol-d4 1,2-Dichlorobenzene-d4 Nitrobenzene-d5 2-Fluorobiphenyl 2,4,6-Tribromophenol Terphenyl-dl4

Analyte (CAS Number) Acenaphthene (83-32-9) Acenaphthylene (208-96-8) Acetophenone (98-86-2) Anthracene (120-12-7) Atrazine (1912-24-9) Benzaldehyde (100-52-7) Benzoic acid (65-85-0) Benzo (a) anthracene (56-55-3) Benzo (a) pyrene (50-32-8) Benzo (b) fluoranthene (205-99-2) Benzo (g,h,i) perylene (191-24-2) Benzo (k) fluoranthene (207-08-9) Benzyl alcohol (100-51-6) l.l'-Biphenyl (92-52-4) Bis(2-chloroethoxy)methane (111-91-1) Bis(2-chloroethyl)ether (111 -44-4) Bis(2-chloro-1 -methylethy l)ether (108-60-1) Bis(2-ethylhexyl)phthalate (117-81-7) 4-Bromophenyl phenyl ether (101-55-3) Butyl benzyl phthalate (85-68-7) Carbazole (86-74-8) Caprolactam (105-60-2) 4-Chloroaniline (106-47-8) 2-ChIoronaphthalene (91-58-7)

Resuh ^g/L

7.05 6.76 6.62 3.73 4.77 4.58 6.95 5.11

Resuh Hg/L

0.9 U

u u u u u u u u u u u u u u u u u u u u u u

Analyte Quahfiers

Targets

Analjê Quahfiers

J

%Recovery

95.1 91.2 89.3 75.4 96.6 92.6 93.7 103

Reporting Limit

0.5 0.5 2.0 0.5 2.0 2.0 4.9 2.0 0.2 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0

%Recovery Limits

39-109 41-107 45-104 34-100 41-128 46-108 51-143 60-133

Dilution 1 It

tt

II

II

II

II

II

II

II

II

If

tl

tt

tt

tt

It

tl

II

It

tt

tt

It

It

Prepared Analyzed

03/22/13 03/25/13

Prepared Analyzed 03/22/13 03/25/13

Report Name: 1303018 FINAL 05 03 1.3 0926 Page 2 of 29 005332



Phone:(281)983-2100 Fax:(281)983-2248

SemivolatUes by CLP OLM04.2 - GC/MS (Low Level) Lab ID: 1303018-01 Station ID: ER-1 Batch: B3C2101 Date Collected: 03/20/13 Sample Type: Liquid Sample Vol: 1012inl Sample Quahfiers: A

Targets (Continued)

Analyte (CAS Number) 2-Chlorophenol (95-57-8) 4-Chlorophenyl phenyl ether (7005-72-3) 4-Chloro-3-methylphenol (59-50-7) Chrysene (218-01-9) Dibenzofuran (132-64-9) Dibenz (aji) anthracene (53-70-3) 1,2-Dichlorobenzene (95-50-1) 1,3-Dichlorobenzene (541-73-1) 1,4-Dichlorobenzene (106-46-7) 3,3 '-Dichlorobenzidine (91-94-1) 2,4-Dichlorophenol (120-83-2) Diethyl phthalate (84-66-2) 2,4-Dimethyiphenol (105-67-9) Dimethyl phthalate (131-11-3) 2,4-Dinitrophenol (51-28-5) 2,4-Dinitrotoluene (121-14-2) 2,6-Dinitrotoluene (606-20-2) 4,6-Dinitro-2-methylphenol (534-52-1) Di-n-butyl phthalate (84-74-2) Di-n-octyl phthalate (117-84-0) Fluoranthene (206-44-0) Fluorene (86-73-7) Hexachlorobenzene (118-74-1) Hexachlorobutadiene (87-68-3) Hexachlorocyclopentadiene (77-47-4) Hexachloroethane (67-72-1) hideno (1,2,3-cd) pyrene (193-39-5) Isophorone (78-59-1) 2-MethyInaphthaIene (91-57-6) 2-Methylphenol (95-48-7) 3 &/or4-Methylphenol (106-44-5) Naphthalene (91-20-3) 2-Nitroaniline (88-74-4) 3-Nitroaniline (99-09-2) 4-Nitroaniline (100-01-6) Nitrobenzene (98-95-3)

Result Analyte Reporting jig/L Quahfiers Lunit

U U

u u u u u u u u u u u u u u u u u u 1.6 0.7

u u u u u u 1.1

u u 1.9

u u u u

2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 9.9 2.0 2.0 9.9 2.0 2.0 0.5 0.5 1.0 2.0 2.0 2.0 2.0 2.0 0.5 2.0 2.0 0.5 4.0 4.0 4.0 2.0

Dilution Prepared Analyzed 1 03/22/13 03/25/13 tt »

It '

tt '

tt •

II 1

II t

II »

II t

II t

II t

II t

II t

II t

tl t

tl t

tl '

tt I

tt '

tt t

)t 1

tt 1

tt t

tt 1

tt '

tt '

tt t

tt 1

It 1

tt '

tt 1

tt 1

tt '

tl '

II f

II t

Report Name: 1303018 FINAL 05 03 13 0926 Page 3 of 29 005333



Phone:(281 )983-2100 Fax:(281 )983-2248

Semivolatiles by CLP OLM04.2 - GC/MS (Low Level) Lab ID: 1303018-01 Batch: B3C2101

Station ID: ER-1 Date Collected: 03/20/13

Sample Type: Liquid

Analyte (CAS Number) 2-Nitrophenol (88-75-5) 4-Nitrophenol (100-02-7) N-Nitrosodiphenylamine (86-30-6) Nf-Nitrosodi-n-propylamine (621-64-7) Pentachlorophenol (87-86-5) Phenanthrene (85-01-8) Phenol (108-95-2) Pyrene (129-00-0) 1,2,4-Trichlorobenzene (120-82-1) 2,4,5-Trichlorophenol (95-95-4) 2,4,6-Trichlorophenol (88-06-2)

Sample Vol: 1012ml

Targe t s (Con t inued )

Result Jig/L

U U

u u 2.0 3.1

u 1.3 U

u u

Analyte Quahfiers

J

Reporting Limit

2.0 5.9 2.0 2.0 1.0 0.5 2.0 0.5 2.0 2.0 2.0

Dilution

1 It

II

II

tl

tt

tt

It

It

II

It

Sample Qualifiers: A


DS

Report Name: 1303018 FINAL 05 03 13 0926 Page 4 of29 005334



Phone:(281)983-2100 Fax:(281)983-2248

Metals by CLP ILM05.3 - ICP Lab ID: 1303018-01 Batch: B3C2201 Sample Type: Liquid

Analyte (CAS Number) Aluminum (7429-90-5) Barium (7440-39-3) Beryllium (7440^1-7) Cadmium (7440^3-9) Calcium (7440-70-2) Chromium (7440-47-3) Cobalt (7440-48-4) Copper (7440-50-8) Iron (7439-89-6) Magnesium (7439-95-4) Manganese (7439-96-5) Nickel (7440-02-2) Potassium (7440-09-7) Silver (7440-22-4) Sodium (7440-23-5) Vanadium (7440-62-2) Zinc (7440-66-6)

L a b l D : 1303018-01 Batch: B3C2202 Sample Type: Liquid

Analyte (CAS Number) Antimony (7440-36-0) Arsenic (7440-38-2) Lead (7439-92-1) Selenium (7782-49-2) Thallium (7440-28-0)

Date Collected: 03/20/13 Sample Vol: 50ml

Resuh Mg/L

U U U U U U

u u u u u u u u u u u

Targets

Analyte Quahfiers

Reporting Limit

100 10.0 5.0 5.0 150 10.0 20.0 20.0 25.0 150 5.0

20.0 1,000 10.0 500 20.0 20.0

Dilution 1 tt

tt

tt

tl

tt

tt

tt

tt

tt

tt

Metals by CLP ILM05.3 - ICP/MS


Result Mg/L

U U U U U

Targets

Analyte Qualifiers

Reporting Limit

2.0 2.0 2.0 2.0 2.0

Dilution 4 II

II

II

II

Station ID: ER-1

Sample Qtialifters:


ts

Station ID: ER-1

Sample Qualifiers:


It tt

tt tt

tt tl

tt t t

KD

Report Name: 1303018 FINAL 05 03 13 0926 Page 5 of 29

005335



Phone:(281 )983-2100 Fax:(281 )983-2248

Metals by CLP ILM05.3 - CVAAS Lab ID: 1303018-01 Batch: B3D0302 Sample Type: Liquid


Station ID: ER-1

Sample Qualifiers:

Targets

Analyte (CAS Number) Result Analyte )itg/L Quahfiers

Reporting Limit Dilution Prepared Analyzed

Mercury (7439-97-6) U 0.200 1 04/03/13 04/04/13




Phone:(281)983-2100 Fax:(281)983-2248

SemlvolatUes by CLP OLM04.2 - GC/MS (Low Level) Lab ID: 1303018-02 Station D): MW-14 Batch: B3C2101 Date Collected: 03/20/13 Sample Type: Liquid Sample Vol: 100ml Sample Qualifiers: A

Surrogates

Analyte 2-Fluowphenol Phenol-d5 2-Chlorophenol-d4 l,2-Dichlorobenzene-d4 Nitrobenzene-d5 2-Fluorobiphenyl 2,4,6- Tribromophenol Terphenyl-dJ4

Analyte (CAS Number) Acenaphthene (83-32-9) Acenaphthylene (208-96-8) Acetophenone (98-86-2) Anthracene (120-12-7) Atrazine (1912-24-9) Benzaldehyde (100-52-7) Benzoic acid (65-85-0) Benzo (a) anthracene (56-55-3) Benzo (a) pyrene (50-32-8) Benzo (b) fluoranthene (205-99-2) Benzo (g,h,i) perylene (191-24-2) Benzo (k) fluoranthene (207-08-9) Benzyl alcohol (100-51-6) l,l'-Biphenyl (92-52-4) Bis(2-chloroethoxy)methane (111-91-1) Bis(2-chloroethyl)ether (111-44-4) Bis(2-chloro-1 -methylethy l)ether (108-60-1) Bis(2-ethylhexyl)phthalate (117-81-7) 4-Bromophenyl phenyl ether (101-55-3) Butyl benzyl phthalate (85-68-7) Carbazole (86-74-8) Caprolactam (105-60-2)

4-Chloroaniline (106-47-8) 2-Chloronaphthalene (91-58-7)

Resuh Mg/L

64.3 61.5 58.2 32.9 21.9 39.0 84.4 53.5

Result Mg/L

582 29.8

U 15.6

U U

209 U

u u u u u

107

u u u u u u

413

u u u

Analyte Quahfiers

Targets Analyte

Qualifiers J

J

J

%Recovery 85.7 82.0 77.6 65.8 43.8 78.0 113 107

Reporting Limit 50.0 5.0

20.0 5.0

20.0 20.0 50.0 20.0 2.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 200 20.0 20.0 20.0

%Recovery Limits 39-109 41-107 45-104 34-100 41-128 46-108 51-143 60-133

Dilution 10 1 II

tl

tl

tl

II

tl

II

II

II

It

II

II

It

II

It

tt

tl

II

10

1 It

It

Prepared 03/22/13

tt

tl

tt

tt

tt

tt

tt

Analyzed 03/25/13

Prepared Analyzed | 03/22/13

tt

tl

tt

tt

tl

tl

II

II

II

II

II

II

II

It

It

It

tt

tt

tl

II

II

II

II

03/26/13 03/25/13

03/26/13 03/25/13

II

tl

Report Name: 1303018 FINAL 05 03 13 0926 Page 7 of29

005337



Phone:(281 )983-2100 Fax:(281 )983-2248

Semivolatiles by CLP OLM04.2 - GC/MS (Low Level) LablD: 1303018-02 Station ID: MW-14 Batch: B3C2101 Date Collected: 03/20/13 Sample Type: Liquid Sample Vol: 100ml Sample Quahfiers: A

Targets (Continued)

Analyte (CAS Number) 2-Chlorophenol (95-57-8) 4-Chlorophenyl phenyl ether (7005-72-3) 4-Chloro-3-methylphenol (59-50-7) Chrysene (218-01-9) Dibenzofuran (132-64-9) Dibenz (aji) anthracene (53-70-3) 1,2-Dichlorobenzene (95-50-1) 1,3-Dichlorobenzene (541-73-1) 1,4-Dichlorobenzene (106-46-7) 3,3 '-Dichlorobenzidine (91 -94-1) 2,4-Dichlorophenol (120-83-2) Diethyl phthalate (84-66-2) 2,4-Dimethylphenol (105-67-9) Dimethyl phthalate (131-11-3) 2,4-Dinitrophenol (51-28-5) 2,4-Dinitrotoluene (121-14-2) 2,6-Dinitrotoluene (606-20-2) 4,6-Dinitro-2-methylphenol (534-52-1) Di-n-butyl phthalate (84-74-2) Di-n-octyl phthalate (117-84-0) Fluoranthene (206-44-0) Fluorene (86-73-7) Hexachlorobenzene (118-74-1) Hexachlorobutadiene (87-68-3) Hexachlorocyclopentadiene (77-47-4) Hexachioroediane (67-72-1) Indeno (1,2,3-cd) pyrene (193-39-5) Isophorone (78-59-1) 2-Methylnaphthalene (91-57-6) 2-MethyIphenol (95-48-7) 3 &/or 4-MethyIphenol (106-44-5) Naphthalene (91-20-3) 2-Nitroaniline (88-74-4) 3-Nitroaniline (99-09-2) 4-Nitroaniline (100-01-6) Nitrobenzene (98-95-3)

Result Analyte Reporting fig/L Quahfiers Lunit

U U

u u

284 U

u u u u u u

59.5

u u u u u u u

35.4 213 U

u u u u u

679 91.4 165

9,820 U

u u u

20.0 20.0 20.0 20.0 200 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 100 20.0 20.0 100 20.0 20.0 5.0

50.0 10.0 20.0 20.0 20.0 20.0 20.0 50.0 20.0 20.0 500 40.0 40.0 40.0 20.0

Dilution Prepared Analyzed 1 03/22/13 03/25/13 tt 1

It •»

tt 1

10

1 II t

II t

II t

tl 1

tl 1

tl <

tt 1

tt 1

tt '

tt 1

tt t

tt '

It t

It t

M t

10

1 II t

II '

II •

II '

II '

10 1 tt 1

100

1 It 1

tt t

tt 1

1 II

1 It

1 II

03/26/13 03/25/13

t It

t II

t II

t II

t tl

t II

1 M

t It

t II

t II

t II

t II

1 II

1 tl

t "

03/26/13 03/25/13

t tl

t It

t tt

t tt

1 It

03/26/13 03/25/13

1 H

03/26/13 03/25/13

1 II

1 tl

II




Phone:(281)983-2100 Fax:(281)983-2248

SemlvolatUes by CLP OLM04.2 - GC/MS (Low Level) Lab lD: 1303018-02 Station ID: MW-14 Batch: B3C2101 Date Collected: 03/20/13 Sample Type: Liquid Sample Vol: 100ml Sample Qualifiers: A

Targets (Continued)

Analyte (CAS Number) 2-Nitrophenol (88-75-5) 4-Nitrophenol (100-02-7) N-Nitrosodiphenylamine (86-30-6) N-Nitrosodi-n-propylamine (621-64-7) Pentachlorophenol (87-86-5) Phenanthrene (85-01-8) Phenol (108-95-2) Pyrene (129-00-0) 1,2,4-Trichlorobenzene (120-82-1) 2,4,5-Trichlorophenol (95-95-4) 2,4,6-Trichlorophenol (88-06-2)

Resuh Mg/L

U U

u u u

218 202 30.1

U

u u

Analyte Quahfiers

J J

Reporting Limit 20.0 60.0 20.0 20.0 10.0 50.0 200 5.0

20.0 20.0 20.0

Dilution 1 II

II

II

II

10 II

1 II

II

II


t It

t It

t ir

t It

03/26/13 t If

03/25/13 t 11

t If

t fl

DS




Phone:(281)983-2100 Fax:(281)983-2248

Metals by CLP ILM05.3 - ICP L a b l D : 1303018-02 Batch: B3C2201 Sample Type: Liquid

Analyte (CAS Number) Aluminum (7429-90-5) Barium (7440-39-3) Beryllium (7440-41-7) Cadmium (7440-43-9) Calcium (7440-70-2) Chromium (7440-47-3) Cobalt (7440-48^) Copper (7440-50-8) Iron (7439-89-6) Magnesium (7439-95-4) Manganese (7439-96-5) Nickel (7440-02-2) Potassium (7440-09-7) SUver (7440-22-4) Sodium (7440-23-5) Vanadium (7440-62-2) Zinc (7440-66-6)

Lab ID: 1303018-02 Batch: B3C2202 Sample Type: Liquid

Analyte (CAS Number) Antimony (7440-36-0) Arsenic (7440-38-2) Lead (7439-92-1) Selenium (7782-49-2) Thallium (7440-28-0)


Result Mg/L

U 124 U

u 7,980

U

u u

10,700 3,920 236 U

2,350 U

. 18,000

u u

Targets

Analyte Reporting Qualifiers Lunit

100 10.0 5.0 5.0 150 10.0 20.0 20.0 25.0 150 5.0

20.0 1,000 10.0 500 20.0 20.0

Station ID: MW-14

Sample Qualifiers:

Dilution Prepared Analyzed 1 03/22/13 04/24/13 tt 1

It t

It t

n t

II 1

It t

tt <

tt t

tt 1

(t 1

It 1

t) 1

II t

) ' t

tt t

tt t

ts

Metals by CLP ILM05.3 - ICP/MS


Result Mg/L

U U U U U

Targets

Analyte Reporting Qualifiers Lunit

2.0 2.0 2.0 2.0 2.0

Station ID: MW-14

Sample Qualifiers:

Dilution Prepared Analyzed 4 03/22/13 04/23/13 II " tl

II II It

II II "

II 1 t 1 t

KD




Phone:(281)983-2100 Fax:(281)983-2248

Lab ID: 1303018-02 Batch: B3D0302 Sample Type: Liquid

Metals by CLP ILM05.3 - CVAAS


Targets

Station ID: MW-14

Sample Quahfiers:

Analyte (CAS Number) Resuh Analyte Ug/L Quahfiers

Reporting Limit Dilution Prepared Analyzed

Mercury (7439-97-6) U 0.200 1 04/03/13 04/04/13


005341



Phone:(281 )983-2100 Fax:(281)983-2248

Semivolatiles by CLP OLM04.2 - GC/MS (Low Level) - Quality Control

Batch: B3C2101 Sample Type: Liquid

Blank (B3C2101-BLK1) Prepared: 3/22/2013 Analyzed: 3/25/2013

Surrogates

ANALYTE Result Analyte Mg/L Qualifier

Spike Level

%REC %REC Lunits

2-Fluorophenol Phenol-d5 2-Chlorophenol-d4 1,2-Dichlorobenzene-d4 Nitrobenzene-d5 2-Fluorobiphenyl 2,4,6- Tribromophenol Terphenyl-dl4

6.93 6.81 6.55 3.36 4.74 4.56 6.89 5.59

7.50 7.50 7.50 5.00 5.00 5.00 7.50 5.00

92.4 90.8 87.3 67.2 94.8 91.2 91.9 112

39-109 41-107 45-104 34-100 41-128 46-108 51-143 60-133

Blanlc (B3C2101-BLK1) Prepared: 3/22/2013 Analyzed: 3/25/2013

Targets

ANALYTE

Acenaphthene

Acenaphthylene

Acetophenone

Anthracene

Atrazine

Benzaldehyde

Benzoic acid

Benzo (a) anthracene

Benzo (a) pyrene

Benzo (b) fluoranthene

Benzo (g,h,i) perylene

Benzo (k) fluoranthene

Betizyl alcohol

l,r-Biphenyl

Bis(2-chloroethoxy)methane

Bis(2-chloroethyl)ether

Result Mg/L

U

U

U

U

U

U

U

U

U

U

U

U

U

U

u u

Analyte] Qualifiers

Reporting Limit

0.5

0.5

2.0

0.5

2.0

2.0

5.0

2.0

0.2

2.0

2.0

2.0

2.0

2.0

2.0

2.0




Phone:(281)983-2100 Fax:(281)983-2248




Targets (Continued)

ANALYTE

Bis(2-chloro-1 -methylethyl)ether

Bis(2-ediylhexyl)phthalate 4-Bromophenyl phenyl ether Butyl benzyl phthalate

Carbazole

Caprolactam 4-Chloroaniline 2-Chloronaphthalene

2-Chlorophenol 4-Chloroi3henyl phenyl ether 4-Chloro-3-methylphenol

Chrysene

Dibenzofiiran Dibenz (a,h) anthracene 1,2-Dichlorobenzene 1,3-Dichlorobenzene

1,4-Dichlorobenzene 3,3 '-Dichlorobenzidine

2,4-Dichlorophenol Diethyl phthalate

2,4-Dimethylphenol Dimethyl phdialate 2,4-Dinitrophenol 2,4-Dinitrotoluene

2,6-Dinitrotoluene 4,6-Dinitro-2-methylphenol

Di-n-butyl phthalate

Di-n-octyl phthalate

Fluoranthene Fluorene

Resuh Mg/L

U

U U

u u u u u u u u u u u u u u u u u u u u u u u u u u u

Analyte Reporting Quahfiers Lunit

. 2 . 0

2.0 2.0 2.0 2.0 2.0

2.0

2.0 2.0

2.0

2.0 2.0

2.0 2.0 2.0

2.0 2.0

2.0 2.0 2.0

2.0

2.0 10.0 2.0

2.0 10.0

2.0 2.0

0.5

0.5


005343



Phone:(281 )983-2100 Fax :(281 )983-2248




Targets (Continued)

ANALYTE Result Analyte Reportmg ^g/L Quahfiers Lunit

Hexachlorpb.enzene

Hexachlorobutadiene

Hexachlorocyclopentadiene

Hexachloroethane

Indeno (1,2,3-cd) pyrene

Isophorone

2-Methyhiaphthalene

2-Methylphenol

3 &/or 4-Methylphenol

Naphthalene

2-Nitroaniline

3-Nitroaniline

4-Nitroaniline

Nitrobenzene

2-Nitrophenol

4-Nitrophenol

N-Nitrosodiphenylamine

N-Nitrosodi-n-propylamine

Pentachlorophenol

Phenanthrene

Phenol

Pyrene

1,2,4-Trichlorobenzene

2,4,5-Trichlorophenol

2,4,6-Trichlorophenol

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

u U "

u u u u u u u u

1.0

2.0

2.0

2.0

2.0

2.0

0.5

2.0

2.0

0.5

4.0

4.0

4.0

2.0

2.0

6.0

2.0

2.0

1.0

0.5

2.0

0.5

2.0

2.0

2.0




Phone:(281)983-2100 Fax:(281)983-2248



LCS (B3C2101-BS1) Prepared: 3/22/2013 Analyzed: 3/25/2013

Surrogates

ANALYTE Result Analyte Mg/L Quahfier

Spike Level

%REC %REC Lunits


4.61 4.81 4.54 2.54 3.23 2.92 4.45 2.44

7.50 7.50 7.50 5.00 5.00 5.00 7.50 5.00

61.5 64.1 60.5 50.8 64.6 58.4 59.3 48.8 #

39-109 41-107 45-104 34-100 41-128 46-108 51-143 60-133


Targets

ANALYTE

Acenaphthene

2-Chlorophenol

4-Chloro-3-methylphenol

1,4-Dichlorobenzene

2,4-Dinitrotoluene

4-Nitrophenol


Pentachlorophenol

Phenol

Pyrene


Resuh Mg/L

3.0

4.6

4.9

2.0

3.4

6.7

3.1

4.0

4.6

2.6

2.3

Analyte Reporting Spike Qualifiers Lunit Level

0.5

2.0

2.0

2.0

2.0

6.0

2.0

1.0

2.0

0.5

2.0

5.00

7.50

7.50

5.00

5.00

7.50

5.00

7.50

7.50

5.00

5.00

%REC %REC Lunits

60.9*61-116

61.5 #66-115

65.0 63-119

39.7 36-100

68.0 61-121

89.5 52-132

62.1 61-123

53.9 49-134

61.8 #62-115

51.5 #58-134

45.3 40-100




Phone:(281)983-2100 Fax:(281)983-2248

Semivolatiles by CLP OLM04.2 - GC/MS (Low Level) - QuaUty Control

Batch: B3C2101

Source: 1303018-02

ANALYTE

2-Fluorophenol Phenol-d5 2-Chlorophenol-d4 1,2-Dichlorobenzene-d4 Nitrobenzene-d5 2-Fluorobiphenyl 2,4.6-Tribromophenol Terphenyl-dl4

Source: 1303018-02

ANALYTE

Acenaphthene

2-Chlorophenol 4-Chloro-3-methylphenol 1,4-Dichlorobenzene

2,4-Dinitrotoluene

4-Nitrophenol N-Nitrosodi-n-propylamine

Pentachlorophenol Phenol

Pyrene


Matrix Spike Prepared:

Result Mg/L

75.5 73.4 68.7 37.8 26.2 45.3 86.9 56.3

3/22/2013 (B3C2101-MS1) Analyzed:

Surrogates Analyte Quahfier

Matrix Spike Prepared:

Result Mg/L

763

71.9 38.4

33.5

44.1

84.3 45.2

81.1 329 94.7

24.8

3/22/2013

3/25/2013

Spike Level

75.0 75.0 75.0 50.0 50.0 50.0 75.0 50.0

(B3C2101-MS1) Analyzed:

Targets

3/25/2013

Analyte Reportmg Spike Source Qualifiers Lunit

50.0

20.0 20.0

20.0 20.0

60.0 20.0

10.0 200

5.0 20.0

Level Result

50.0 75.0 75.0

50.0

50.0 75.0

50.0

75.0 75.0

50.0 50.0

582

202

30.1

Sample Type: Liquid

%REC

101 97.9 91.6 75.6 52.4 90.6 116 113

%REC ; Limits

39-109 41-107 45-104 34-100 41-128 46-108 51-143 60-133

%REC %REC Lunits

363 #43-129

95.9 51.2

67.0

88.2 112

90.5

108 170 «

129 49.7

41-117 43-137

35-100 54-124

36-151 42-122

53-147 '36-117

53-132

39-101




Phone:(281 )983-2100 Fax:(281 )983-2248

SemlvolatUes by CLP OLM04.2 - GC/MS (Low Level) - QuaUty Control

Batch: B3C2101

Source: 1303018-02

ANALYTE


Source: 1303018-02

ANALYTE

Acenaphthene

2-Chlorophenol 4-Chloro-3-methylphenol 1,4-Dichlorobenzene 2,4-Dinitrotoluene 4-Nitrophenol


Pentachlorophenol Phenol

Pyrene


Matrix Spike Dup (B3C2101-MSD1) Prepared:

Result Mg/L

73.5 72.3 66.5 38.2 25.1 43.3 84.6 45.8

3/22/2013 Analyzed:

Surrogates Analyte Quahfiei

3/25/2013

Spike Level

75.0 75.0 75.0 50.0 50.0 50.0 75.0 50.0


Result Mg/L

728

67.2

35.8 34.9 42.7 79.9

42.0 82.5 313 74.8

24.5

3/22/2013 Analyzed:

Targets Analyte

3/25/2013

Reporting Spike Quahfiers Lunit

50.0

20.0

20.0 20.0 20.0 60.0 20.0

10.0 200 5.0

20.0

Level

50.0 75.0

75.0 50.0 50.0 75.0

50.0

75.0 75.0 50.0

50.0

Som-ce Result

582

202

30.1

Sample Type: Liquid

%REC

98.0 96.4 88.7 76.4 50.2 86.6 113 91.6

%REC Limits

39-109 41-107 45-104 34-100 41-128 46-108 51-143 60-133

%REC RPDI %REC Lunits RPD Lunit

291 «

89.6

47.7 69.8 85.4

106 84.1

110 148 « 89.5

49.1

'43-129 21.8

41-117 6.86

43-137 7.15 35-100 3.98 54-124 3.25

36-151 5.46 42-122 7.33

53-147 1.61 '36-117 13.3

34

27

30 34 21 35

29

24 34

53-132 36.4 # 19

39-101 1.26 24


005347



Phone:(281)983-2100 Fax:(281 )983-2248

Metals by CLP ILM05.3 - ICP - QuaUty Control



Targets

ANALYTE Result Analyte Reportmg lig/L Qualifiers Limit

Alumimun Barium Beryllium Cadmium Calcitmi Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassiimi

Silver Sodium Vanadium

Zinc

u u u u u u u u u u u u u u u u u

100

10.0

5.0

5.0

150

10.0

20.0

20.0

25.0

150

5.0

20.0

1,000

10.0

500

20.0

20.0


Targets

ANALYTE Result Analyte Reportmg Spike ^g/L Qualifiers Limit Level

%REC %REC Lunits

Aluminimi Barium Beryllium Cadmiimi

Calcium Chromium

984

1,870

47.1

47.1

93,800

376

100

10.0

5.0

5.0

150

10.0

1,000

2,000

50.0

50.0

100,000

400

98.4

93.6

94.3

94.1

93.8

93.9

75-125

75-125

75-125

75-125

75-125

75-125




Phone:(281)983-2100 Fax:(281)983-2248




Targets (Continued)

ANALYTE Result Analyte Reporting Spike Ug/L Quahfiers Lunit Level %REC

%REC Limits

Cobalt

Copper

Iron

Magnesium

Manganese

Nickel

Potassiimi

Silver

Soditmi

Vanadiimi

Zinc

179

379

940

95,700

370

350

100,000

42.8

97,200

393

905

20.0

20.0

25.0

150

5.0

20.0

1,000

10.0

500

20.0

20.0

200

400

1,000

100,000

400

400

100,000

50.0

100,000

400

1,000

89.3

94.7

94.0

95.7

92.6

87.4

100

85.5

97.2

98.2

90.5

75-125

75-125

75-125

75-125

75-125

75-125

75-125

75-125

75-125

75-125

75-125

Source: 1303018-02

Matrix Spike (B3C2201-MS1) Prepared: 3/22/2013 Analyzed: 4/24/2013

Targets

ANALYTE Result Analyte Reportmg Spike Source %REC jig/L Qualifiers Lunit Level Result %REC Lunits

Aluminum

Barium

Beryllium

Cadmiiun

Calciimi

Chromium

Cobalt

Copper

Iron

Magnesium

Manganese

Nickel

985

1,960

46.7

46.0

99,900

363

174

371

10,700

98,200

578

341

100

10.0

5.0

5.0

150

10.0

20.0

20.0

25.0

150

5.0

20.0

1,000

2,000

50.0

50.0

100,000

400

200

400

1,000

100,000

400

400

5.4

124

0.09

0.4

7,980

0.7

1.0

10,700

3,920

236

1.1

97.9

91.7

93.2

91.2

92.0

90.8

86.6

92.4

N R <

94.3

85.6

84.9

75-125

75-125

75-125

75-125

75-125

75-125

75-125

75-125

»75-125

75-125

75-125

75-125


005349



Phone:(281 )983-2100 Fax:(281)983-2248


Batch: B3C2201

Source: 1303018-02

ANALYTE

Potassiimi

Silver

Sodium

Vanadium

Zinc

Source: 1303018-02

ANALYTE

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Matrix Spike (B3C2201-MS1) Prepared:

Result Mg/L

100,000

43.3

112,000

386

888

3/22/2013 Analyzed: 4/24/2013

Targets (Continued) Analyte Reportmg Spike

Quahfiers Lunit Level

1,000

10.0

500

20.0

20.0

100,000

50.0

100,000

400

1,000

Source Result

2,350

18,000

0.6

16.7


Result Mg/L

998

1,980

47.9

47.5

101,000

371

178

374

10,800

99,000

585

344

101,000

46.6

113,000

388

897

3/22/2013 Analyzed:

Targets

4/24/2013

Analyte Reportmg Spike Quahfiers Lunit Level

100

10.0

5.0

5.0

150

10.0

20.0

20.0

25.0

150

5.0

20.0

1,000

10.0

500

20.0

20.0

1,000

2,000

50.0

50.0

100,000

400

200

400

1,000

100,000

400

400

100,000

50.0

100,000

400

1,000

Source Result

5.4

124

0.09

0.4

7,980

0.7

1.0

10,700

3,920

236

1.1

2,350

18,000

0.6

16.7

1 Sample Type: Liquid

%REC %REC Lunits

98.1

86.7

94.1

96.4

87.1

7.5-125

75-125

75-125

75-125

75-125

%REC %REC Lunits

99.3

92.7

95.6

94.1

92.8

92.9

88.8

93.2

17.3

95.1

87.4

85.8

99.1

93.1

95.3

96.9

88.1

75-125

75-125

75-125

75-125

75-125

75-125

75-125

75-125

»75-125

75-125

75-125

75-125

75-125

75-125

75-125

75-125

75-125

RPD RPD Limit

1.38

1.03

2.49

3.11

0.81

2.20

2.48

0.87

1.65

0.82

1.27

1.10

1.02

7.19

1.01

0.52

1.05

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20




Phone:(281 )983-2100 Fax:(281 )983-2248

Metals by CLP ILM05.3 - ICP/MS - QuaUty Control



Targets

ANALYTE Resuh Analyte Reportmg p,g/L Quahfiers Lunit

Antimony Arsenic Lead Selenium Thallium

u u u u u

2.0 2.0 2.0 2.0

2.0


Targets

ANALYTE

Antimony

Arsenic Lead

Selenium Thallium

Source: 1303018-02

ANALYTE

Antimony Arsenic

Lead Selenium Thallium

Resuh Mg/L

212

209 212 215 219

Analyte Reportmg Spike Quahfiers Lunit Level

2.0

2.0

2.0 2.0 2.0

200

200

200 200 200

Matrix Spike (B3C2202-MS1) Prepared: 3/22/2013 Analyzed: 4/23/2013

Resuh Mg/L

204

217

206 208

206

Targets Analyte Reportmg Spike Source

Qualifiers Lunit Level Result

2.0 2.0

2.0 2.0 2.0

200 200

200 200

200

0.07 0.8 0.2

0.006

%REC %REC Lunits

106

104

106 107 109

85-115

85-115

85-115

85-115 85-115

%REC %REC Lunits

102

108

103 104

103

70-130 70-130

70-130 70-130

70-130




Phone:(281)983-2100 Fax:(281)983-2248

Metals by CLP ILM05.3 - ICP/MS - QuaUty Control


Source: 1303018-02 Matrix Spike Dup (B3C2202-MSD1)

Prepared: 3/22/2013 Analyzed: 4/23/2013

Targets

ANALYTE Result Analyte Reportmg Spike Source %REC RPD ^g/L Quahfiers Lunit Level Result %REC Lunits RPD Lunit

Antimoiiy

Arsenic

Lead

Seletiium

Thallium

205

217

206

210

206

2.0

2.0

2.0

2.0

2.0

200

200

200

200

200

0.07

0.8

0.2

0.006

103

108

103

105

103

70-130

70-130

70-130

70-130

70-130

0.30

0.23

0.08

0.65

0.00

20

20

20

20

20




Phone:(281)983-2100 Fax:(281)983-2248

Metals by CLP ILM05.3 - CVAAS - QuaUty Control

Batch: B3D0302 Sample Type: Liquid

Blank (B3D0302-BLK1) Prepared: 4/3/2013 Analyzed: 4/4/2013

Targets

ANALYTE Result Analyte Reportmg jig/L Quahfiers Limit

Mercury U 0.200


Targets

ANALYTE Result Analyte Reporting pg/L Quahfiers Lunit

Mercury U 0.200


Targets

ANALYTE Result Analyte Reportmg pg/L Quahfiers Lunit

Mercury U 0.200

LCS (B3D0302-BS1) Prepared: 4/3/2013 Analyzed: 4/4/2013

Targets

ANALYTE Resuh Analyte Reportmg Spike pg/L Qualifiers Lunit Level

%REC %REC Lunits

Mercury 1.02 0.200 1.00 102 80-120




Phone:(281 )983-2100 Fax:(281 )983-2248

Metals by CLP ILM05.3 - CVAAS - QuaUty Control

Batch: B3D0302 Sample Type: Liquid

Source: 1303018-02 Matrix Spike (B3D0302-MS1)


Targets

ANALYTE Result Analyte Reportmg Spike Source %REC pg/L Quahfiers Lunit Level Result %REC Lunits

Merciuy 1.04 0.200 1.00 104 75-125

Source: 1303018-02 Matrix Spike Dup (B3D0302-MSD1)


Targets

ANALYTE Result Analyte Reportmg Spike Source %REC RPD pg/L Quahfiers Lunit Level Result %REC Lunits RPD Lunit

Mercury 1.03 0.200 1.00 103 75-125 0.97 20


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Phone:(281)983-2100 Fax:(281)983-2248

Notes and Definitions

J

A

HTS

ABN

AES

BS

CVAA

DCB

ECD

GC

ICP

ISTD

LCS

MS

MS/MSD

NA

NPD

NR

PCB

RL

RT

TCLP

TCMX

The identification ofthe analyte is acceptable; i

This sample was extracted at a single acid pH.

Sample was prepared and/or analyzed past recc considered minimum values.

Acid Base Neutrals (Semivolatile Compounds)

Atomic Emission Spectrometer

Blank Spike

Cold Vapor Atomic Absoiption

Decachlorobiphenyl

Electron Capture Detector

Gas Chromatograph

Inductively Coupled Plasma

Internal Standard

Laboratory Control Sample

Mass Spectrometer

Matrix Spike/Matrix Spike Duplicate

Not Applicable

Nitrogen Phosphorous Detector

Not Reported

Polychlorinatedbiphenyl

Reporting Limit

Retention Time

Toxicity Characteristic Leaching Procedure

Tetrachloro-meta-xylene




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U Undetected

VOA Volatile Organic Analysis

# Out of QC limits

Initial pressure in air analyses is the pressure at which the canister was received in psia (potmds per square inch absolute pressure).

The pH reported for Volatile liquid samples was tested using a 0-14 pH indicator strip for the purpose of verifying chemical preservation.

The statistical software used for the reporting of toxicity data is ToxCalc 5.0.32, Environmental Toxicity Data Analysis System 1994-2007 Tidepool Scientific Software.


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