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    I

    Dissertation Phase-I Report on

    Experimental investigation of Droplet Ignition of Biodiesel

    and its blends

    Prepared By

    Vimal D. Sonara

    M.E. 3rd

    (Automobile Engineering)

    Enrollment No. 120150735004

    Guided By

    Dr. Pravin P. Rathod

    Associate Professor,

    Mechanical Engineering Department,

    Government Engineering College, Bhuj

    December 2013

    Mechanical Engineering Department

    Government Engineering College- BhujBhuj - 370001

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    II

    Government Engineering College- Bhuj

    Bhuj 370001

    CERTIFICATE

    This is to certify that the work presented in the report of dissertation phaseI entitled

    Experimental investigation of Droplet Ignition of Biodiesel and

    its blends

    By

    Vimal D. Sonara

    Enrollment No.: 120150735004

    In a manner sufficiently to warrant its acceptance as a partial fulfillment of the course of the

    third semester of Master of engineering in Mechanical Engineering (with specialization in

    AUTOMOBILE ENGINEERING).

    Signature and Name of Guides:

    Prof. Dr. Pravin. P. Rathod

    Associate Professor

    Date:

    Place:

    Signature and Name of

    Head of Department

    Signature and Name of Principal

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    II

    TABLE OF CONTENTS

    Title Page I

    Certificate Page II

    Table of Contents III

    List of Figures V

    List of Tables VI

    Abstract VII

    Chapter 1 INTRODUCTION 1

    1.1 Bio-Diesel 1

    1.1.1 Bio-Diesel Basic 1

    1.2.1 Bio-Diesel in world 2

    1.2.2 Bio-Diesel in India 3

    1.2.3 Bio-Diesel Production in India 3

    1.2 Bio Diesel to meet Emission Norms 4

    Chapter 2 DIESEL COMBUSTION 5

    2.1 Heat Release Rate 5

    2.2 Ignition Delay 6

    2.2.1. Ignition delay correlations 8

    Chapter 3 LITERATURE REVIEW 9

    3.1 Review of Various Literature 9

    3.2 Objective of Study 14

    Chapter 4 EXPERIMENTAL DETAILS. 18

    4.1 Sub Systems of Experimental work 18

    4.1.1 Droplet Formation 18

    4.1.2 Furnace Chamber 18

    4.1.3 Proposed Specification for Furnace Chamber 19

    4.1.4 Observation & Photographic Recording System 20

    4.2 Properties of Bio-Diesel under Investigation 20

    Chapter 5 WORK PLAN 21

    5.1 Objectives achieved and to be achieved: 21

    LIST OF PUBLICATIONS 21REFERENCES 22

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    III

    Appendix A ABBREVIATIONS 24

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    IV

    LIST OF FIGURES

    Figure No. Title of figure Page

    No.

    Fig.2.1 Typical HRR plot 5

    Fig. 2.2 Illustration of the effect of ignition delay on the HRR 6

    Fig. 4.1 Schematic of Furnace Chamber 19

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    V

    LIST OF TABLES

    Table No. Title Details Page No.

    1.1Estimated Bio-diesel Requirements for Blending with

    Diesel3

    1.2 Annual Production of Non-edible Oil Seeds in India 4

    3.1 Review of various Literature 9

    4.1 Proposed specification of furnace 19

    4.2Comparison of properties Diesel, Jatropha and Neem

    Bio-Diesel with its blend with Diesel20

    5.1 Work plan for the dissertation work 21

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    VI

    ABSTRACT

    Biodiesel is one of the part solutions in alleviating the worlds dependence on fossil fuels due

    to the rapid depletion of non-renewable petroleum resources. Biodiesel is an alternative fuel

    produced from renewable resources with potential to substantially reduce emission associated

    with petroleum diesel usage.

    Combustion and Ignition analysis of Biodiesel and its blends with diesel gives insight into it.

    Diesel droplet ignition reveals stages of combustion and droplet vaporization at given

    condition. Further, investigation has proved the effect of Reynolds number on vaporization of

    droplet at various conditions. Few of the researchers have studied the different

    parameter(such as Cetane number engine power, economy, engine torque, brake specific fuel

    consumption ,brake thermal efficiency, exhaust gas temperature) and also find reduction in

    emission(NO,PM,CO,HC). All the fuel tested adheres to the relationship, more or less with

    droplet complicated size variation and with droplet surface area d2

    v/s time.

    Combustion and Ignition analysis of Biodiesel and its blends with diesel gives insight into it.

    Diesel droplet ignition reveals stages of combustion and droplet vaporization at given

    condition. Further, investigation has proved the effect of Reynolds number on vaporization of

    droplet at various conditions. Few of the researchers have studied the different

    parameter(such as Cetane number engine power, economy, engine torque, brake specific fuel

    consumption ,brake thermal efficiency, exhaust gas temperature) and also find reduction in

    emission(NO,PM,CO,HC). All the fuel tested adheres to the relationship, more or less with

    droplet complicated size variation and with droplet surface area d2 v/s time.

    Combustion characteristics as well as engine performance are measured for different

    biodieseldiesel blends. It has been shown from reviewed literature that delay period was

    measured and correlated for different blends. The effect of delay period with temperature and

    equivalence ratio will be found out.

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    Page 2

    animals, and these too are renewable. Used cooking oils are mostly plant based, but may also

    contain animal fats. Used cooking oils are both recycled and renewable. The Bio-Diesel

    manufacturing process converts oils and fats into chemicals called long-chain mono alkyl

    esters, or Bio-Diesel. These chemicals are also referred to as fatty acid methyl esters (FAME)

    and the process is referred to as trans esterification. Roughly speaking, 100 pounds of oil or

    fat are reacted with 10 pounds of a short-chain alcohol (usually methanol) in the presence of a

    catalyst (usually sodium hydroxide [NaOH] or potassium hydroxide [KOH]) to form 100

    pounds of Bio-Diesel and 10 pounds of glycerin. Glycerin is a sugar, and is a co product of

    the Bio-Diesel process.

    1.2.1 Bio-Diesel in World

    A volumetric blend of 20% bio-diesel with 80% petroleum diesel has demonstrated

    significant environmental benefits in US with a minimum increase in cost for fleet operations

    and other consumers[1]

    . Bio-diesel is registered as a fuel and fuel additive with the US

    Environmental Protection Agency and meets clean diesel standards established by the

    California Air Resources Board. Neat (100%) bio-diesel has been designated as an alternative

    fuel by the Department of Energy and the Department of Transportation of US[1]

    . Studies

    conducted with bio-diesel on engines have shown substantial reduction in Particulate matter

    (25 50%)[1]. However, a marginal increase in NOx (1-6%) is also reported; but it can be

    taken care of either by optimization of engine parts or by using De-NOx catalyst[1]

    (De-NOx

    catalyst will be necessary for Bharat-III / IV compliant engines). HC and CO emissions were

    also reported to be lower. Non-regulated emissions were also found to be lower. Bio-diesel

    has been accepted as clean alternative fuel by US and its production presently is about 100

    million Gallons[1]

    . Each State has passed specific bills to promote the use of bio-diesel by

    reduction of taxes. Sunflower, rapeseed etc. is the raw material used in Europe whereas soya

    bean is used in USA. USA uses blend of 20% bio-diesel with 80% petroleum diesel and pure

    bio-diesel, France uses 5% bio-diesel with 95% petroleum diesel as mandatory in all diesel

    fuel[1]

    . The viscosity of bio-diesel is higher (1.9 to 6.0 cSt) and is reported to result into gum

    formation on injector, cylinder liner etc. if used in neat form[1]

    . However, blends of up to

    20% bio-diesel should not give any problem. While an engine can be designed for 100% bio-

    diesel use, the existing engines can use 20% bio-diesel blend without any modification and

    reduction in torque output. In USA, 20% bio-diesel blend is being used; while in European

    countries 5 -15% blends have been adopted[1]

    .

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    1.2.2 Bio-diesel in India

    About 400 wild species found in India produce non edible oils that can be converted to bio-

    diesel[1]

    . A salient feature of Indias bio fuel program is to only utilize wastelands, degraded

    forest, and non-forest lands for cultivation of oil seed plants. Of about 55 million ha of

    wastelands in India, about 32 million ha are suitable for bio-diesel production[1]

    . Suitability

    here refers only to physical suitability; access to land for bio fuel plantations depends on a

    number of factors including climatic and soil conditions, access to infrastructure such as

    roads and electricity, as well as the ownership of the land. The available information about

    wasteland suitability for oil seed plantations is incomplete, and a proper wasteland mapping

    exercise should precede any major bio-diesel development program in India. The demand of

    Diesel (H.S.D) is projected to grow from 39.81 Million Metric Tonne in 2001-02 to 52.32

    MMT in 2006-07 @ 5.6% per annum [1]. Our crude oil production as per the Tenth Plan

    working Group is estimated to hover around 33-34 MMT per annum even though there will

    be increase in gas production from 86 MMSCMD (2002-03) to 103 MMSCMD in (2006-07)

    [1]. Only with joint venture abroad there is a hope of oil production to increase to 41 MMT by

    (2016-17) and the gas production would decline by this period to 73 MMSCMD[1]

    . The

    increasing gap between demand and domestically produced petroleum is a matter of serious

    concern. Targets need to be set up for bio-diesel production to achieve blending ratios of 5,

    10 and 20% in phased manner. The estimated bio-diesel requirements for blending with

    petro-diesel over the period of next 5 years are given in Table 1.1[1]

    .

    Table 1.1 Estimated Bio-diesel Requirements for Blending with Diesel[1]

    Year

    Diesel

    Demand

    MMT

    Bio-

    diesel@5%

    MMT

    Area

    @5%

    Mha

    Bio-

    diesel@10%

    MMT

    Area

    @10%

    Mha

    Bio-

    diesel@20

    MMT

    Area

    @20%

    Mha

    2001-02 39.81 1.99 - 3.98 - 7.96 -

    2006-07 52.33 2.62 2.19 5.23 4.38 10.47 8.76

    2011-12 66.90 3.35 2.79 6.69 5.58 13.38 11.19

    1.2.3 Bio-diesel production in India

    The annual estimated potential of bio-diesel is about 20 million tonnes per annum[1]

    . Wild

    crops cultivated in the wasteland also form a source of bio-diesel production in India and

    according to the Economic Survey of Government of India, out of the cultivated land area;

    about 175 million hectares are classified as waste and degraded land[1]

    . Table 1.2 below

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    2.0 Diesel Combustion

    While diesel engines are well known, an in-depth understanding of how a diesel engine

    works is required to understand this topic. Some aspects are introduced here, but for a more

    detailed description see the long report. The diesel engine is a form of compression ignition,

    internal combustion engine. First built by Rudolph Diesel in 1894, the original version ran on

    peanut oil. Diesels quickly evolved to use petroleum based diesel, which burnt more

    completely with less soot than vegetable oils. Diesels use some of the heavier fractions from

    distillation of crude oil and the fuel is generally composed of blends of C 11 to C

    hydrocarbon chains.

    2.1 Heat Release Rate

    One of the most common measures used in analyzing diesel combustion and ignition delay is

    the heat release rate (HRR), due to the large amount of information gained from it and the

    simple pressure diagnostics required to determine it. An example of a typical HRR plot is

    shown in Fig.2.1, showing the three major zones commonly associated with DI diesel

    engines. After fuel injection begins and before combustion, the fuel takes a short time to

    ignite. During this ignition delay fuel vaporizes and mixes with air, after igniting this mixture

    burns rapidly causing what is known as the premixed burn spike[17]

    . Once this prepared

    mixture has combusted, the burning rate is controlled by mixing of the fuel jet and fresh air.

    This period is called the diffusion flame, and lasts until the injector closes.

    Fig.2.1 typical HRR plot [17]

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    Page 6

    2.2 Ignition delay

    Ignition delay is commonly defined as the time between the start of injection (SOI) and the

    start of combustion (SOC). These two points in the engine cycle are rather arbitrarily defined.

    For example, experimental measurements for the start of injection often use Hall Effect

    transducers to measure needle lift, or monitor fuel rail pressure for a drop corresponding with

    injection.

    Fig. 2.2: Illustration of the effect of ignition delay on the HRR[17]

    Start of combustion (SOC) is also rather arbitrary with many defining it as the first moment of

    positive heat release, while researchers with visual access usually use the start of luminousflame. Ignition delay is an important tuning parameter. If a fuel is injected and then

    undergoes a delay before ignition, the fuel evaporates and mixes with the air charge in the

    cylinder. After ignition, this premixed charge burns very rapidly, producing high pressures.

    The effect of rapid burning can easily be seen in heat release rate diagrams, where the later

    the premixed combustion peak occurs the larger it is, as illustrated in Fig.2.2 This rapid

    combustion produces regions of high temperature which cause large NOx emissions through

    the thermal NO mechanism and also produce large peak pressures. The rapid pressure rise

    causes noisy engine running and also means that the design of the engine has to cope with a

    higher peak pressure. To break down the ignition delay further, it is known that in a perfectly

    prepared mixture suddenly raised to auto ignition conditions (temperature, pressure, etc.),

    there will be a delay before ignition. This is referred to as the chemical portion of the ignition

    delay and is the time required to form the reactive species from unreactive sources. However,

    the fuel and oxidizer require preparation before these chemical processes can occur. The fuel

    must vaporize and form a mixture within certain limits of fueltoair equivalence ratio. In a

    diesel engine, the fuel is injected as a liquid spray into hot gas. It then breaks up and forms

    droplets that greatly enlarge the fuels surface area, which in turn speeds the evaporation rate.

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    Page 7

    The time taken for this preparation is referred to as the physical delay. Obviously the physical

    delay depends on the fuel injection system, in cylinder conditions and fuel physical

    properties. The chemical delay is assumed to be dependent only on fuel properties,

    combustion chamber conditions and equivalence ratio.

    The ignition delay of a compression ignition (CI) engine is defined as the time (or crank

    angle) interval between the start of injection and start of combustion[17]

    . This delay is due to

    physical and chemical processes that takes place before a significant fraction of the chemical

    energy of the injected liquid fuel is released. The physical processes are: atomization of

    liquid fuel jet, evaporation of fuel droplets and mixing of fuel vapour with air. The chemical

    processes are pre combustion reactions of fuel, air, residual gas mixture that leads to auto

    ignition. These processes are affected by engine design, operating variables and fuel

    characteristics. Ignition quality of CI engine fuels are rated by its Cetane number and the

    ignition delay of CI engine fuel is inversely proportional to its Cetane number. Ignition delay

    of CI engine plays a significant role in combustion and emission characteristics of the engine.

    As the delay period increases the maximum rate of pressure rise increases and also engine

    noise. This will lead to engine knocking which reduce the engine life. Longer delay period

    will retard the start of combustion closer to TDC and major portion of the fuel gets burned

    during expansion stroke of the piston which reduces the power developed in the engine. Thisalso increases the BSFC and smoke emission of the engine. Shorter delay period increases the

    compression work against products of combustion which increase the combustion

    temperature and hence the NOx formation. As longer as well as shorter delay period leads to

    considerable side effects, the CI engine has to operate with optimum delay period for

    effective functioning of the engine. Ignition delay of CI engine was affected by both fuel

    characteristics and engine design & operating parameters. As the engine combustion and

    emission characteristics are influenced by ignition delay, its role is vital in diesel engine

    research. Research on reduction of diesel engine pollutants is progressed significantly to

    meet the stringent emission norms. Any methodology proposed for reducing the diesel engine

    pollutants has an effect on ignition delay of the engine. Research works have been carried out

    to reduce the diesel engine pollutants by modifying fuel injection timing. Effect of fuel

    injection timing on diesel engine pollutants fuelled with diesel and Bio-Diesel were

    investigated by many researchers.

    In their work engine pollutants were obtained for different fuel injection timings andoptimised injection timing was suggested for each fuel tested on the engine. Research work

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    Page 8

    conducted with different compression ratio suggested an optimum compression ratio by

    considering emission and performance of the engine. The effect of fuel injection pressure on

    engine emission and combustion characteristics and suggested optimum fuel injection

    pressure for the engine. From these experimental results it was inferred that the diesel engine

    design parameters have a significant influence on the performance, emission and combustion

    characteristics. It was also inferred that optimised engine parameters were proposed for each

    test fuels tested on the engine by the expense of severe experimental work and considerable

    amount of energy and time. Although various optimum engine design parameters were

    suggested to control the emission of a diesel engine, these parameters were restricted to a

    specific engine and for a specific fuel. Optimised design parameters of the engine may not be

    applicable for other fuels to be tested on the same engine since their characteristics will be

    different. Also the performance of the fuel will be different when the fuel was tested in

    another engine of different size which requires another series of experimental work to get an

    optimised result. In order to reduce the number of experimental work to be conducted a

    simple correlation relating fuel characteristics and engine design parameters would be

    preferable to evaluate the engine combustion and emission characteristics fuelled with diesel

    and Bio-Diesel. Engine emission and combustion parameters can be obtained from the

    correlation for a chosen fuel which will be helpful to predict the optimum condition before

    testing in the engine. As the ignition delay has an influence on the formation of diesel engine

    pollutants, this correlation will be a platform to predict the engine emission characteristics

    and also the obtained ignition delay can be used to develop a correlation to predict engine

    emission characteristics.

    2.2.1. Ignition delay correlations

    Arrhenus equation modified by EL-Bahnasy and El-Kotb[15]

    has been considered, with the

    help of Heywood [16] to calculate the delay period of Jatropha biodiesel blends [9] with diesel

    fuels as a function of cylinder pressure, cylinder temperature, and equivalence ratio as

    follows:

    id = A P-n

    1-m

    EXP( Ea /R-T)

    One can get the coefficients A, n, m and the general empirical relation of each blend. Some

    equations were obtained for each blend as a function of each parameter (P, T, ).

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    3.0 Literature Review

    3.1 Review of Various Literatures:

    The literature reviews in with this topic is in below table with chronological order.

    Author Year of

    paper

    published

    Parameter under

    observation

    Objective of the

    research paper

    Result

    C. K. LAW 1982 RECENT

    ADVANCES IN

    DROPLET

    VAPORIZATION

    ANDCOMBUSTION

    of

    multicomponent

    fuels including the

    miscible fuel

    blends,

    immiscible

    emulsions and

    coal-oil mixtures.

    Understanding

    the fundamental

    mechanisms

    governing

    dropletvaporization and

    combustion were

    reviewed.

    Topics include

    the classical d2-

    Law and its

    limitations; the

    major transient

    processes ofdroplet heating

    and fuel vapour

    accumulation.

    Droplet vaporization

    and combustion was

    summarized

    1.Unsteadiness during

    single dropletgasification has a

    variety of causes

    like unsteady

    diffusion, Droplet

    heating, Fuel vapour

    accumulation,

    Natural and forced

    convection,

    instantaneous dropletsize

    2. There were two

    major transient

    processes involved,

    namely droplet

    heating which mostly

    influences the initial

    droplet regression

    rate, and fuel vaporaccumulation

    C. H. WANG,

    X. Q. LIU, and

    C. K. LAW[12]

    1984 Combustion and

    Micro explosion

    of Freely Falling

    Multicomponent

    Droplets with

    droplet of n-

    hexadecane

    Multicomponent

    droplets freely

    falling in a hot,

    oxidizing gas

    flow were

    studied.

    1.Two-compone

    fuels substantiate a

    three-staged

    combustion

    behaviour, with

    diffusion being the

    dominant liquid-phase

    transport mechanism

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    2.Microexplosion

    show that its

    occurrence depends

    sensitively on the

    mixture concentration

    as well as the stability

    of the droplet

    generation mode

    M.

    RENKSIZBUL

    and

    BUSSMANN[4]

    1993 Multicomponent

    droplet

    evaporation at

    intermediate

    Reynolds

    numbers withhydrocarbon

    droplet (decane-

    hexadecane)

    The convective

    evaporation of a

    binary

    hydrocarbon

    droplet (decane-

    hexadecane) inair at 1000 K

    and at a pressure

    of 10

    atmospheres has

    been studied

    using numerical

    methods.

    1. At elevated

    pressures, the

    evaporation of

    relatively heavy

    hydrocarbon droplets

    is essentiallycontrolled by liquid

    phase heating.

    2. Reynolds number

    decreases largely due

    to the deceleration of

    the droplet, as droplet

    radius varies much

    more slowly.

    S.C. Anthony

    Lam and

    Andrzej

    Sobiesiak[2]

    2006 Investigated on

    Bio-Diesel , ultra-

    low sulphur diesel

    and, ethanol Bio-

    Diesel droplet,

    ethanol for the

    droplet

    combustion

    Burning rate

    and

    temperature

    histories

    were

    reported.

    Apparatus

    for

    determining

    droplet

    diameter &thermocoupl

    e

    arrangement

    to measure

    droplet

    temperature

    history

    Series of

    frames from

    a high-speed

    movie

    capturing the

    Three stages in

    droplet combustion

    1. Warm-up and

    combustion

    2. Combustion of the

    droplet with the

    liquid phase boiling

    3. Burn-off of

    vaporized fuel.

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    Page 11

    entire Bio-

    Diesel

    burning

    sequence

    Changes of

    dropletdiameter-

    squared over

    time and

    temperature

    Jiunn-Shyan

    Huang and

    Tsong-Sheng

    Lee[8]

    2006 Comparison Of

    Single-Droplet

    Combustion

    Characteristics

    Between Bio-

    Diesel AndDiesel

    Combustion

    characteristics of

    Bio-Diesel and

    diesel was

    experimentally

    investigated atReynolds

    numbers 93 to

    192

    Upper branch

    (93 to 192)

    Lower branch

    (192 to 93)

    1.Multiple state

    phenomenon was

    observed for Bio-

    Diesel droplet at

    119< Re

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    Page 12

    Hyun Kyu

    Suh,Hyun Gu

    Roh, Chang Sik

    Lee[6]

    2008 Spray and

    Combustion

    Characteristics of

    Bio-Diesel Diesel

    Blended Fuel in a

    Direct Injection

    Common-Rail

    Diesel Engine

    Effect of the

    blending

    ratio and

    pilot

    injection on

    the spray andcombustion

    characteristic

    s of diesel &

    Bio-Diesel

    fuel in a

    direct

    injection

    common-rail

    diesel

    engine.

    Exhaustemissions

    and engine

    performance

    were

    conducted at

    various Bio-

    Diesel

    blending

    ratios and

    injection

    conditions

    for engine

    operating

    conditions.

    1. Single injection,

    fuel injection profiles

    for diesel and Bio-

    Diesel blended fuels

    are very similar

    compare to pilot

    injection; an increase

    of the blending ratio

    induced a decrease of

    the peak injection

    rate.

    2. Effect of fuel

    blending and injection

    pressure on singlespray tip penetration

    is slight, and the pilot

    spray development of

    Bio-Diesel is shorter

    compared with the

    pilot and main

    injection of diesel

    fuel.

    3. CO emissions ofboth fuels with single

    injection decreased

    with advanced

    injection timing. The

    NO emissions of Bio-

    Diesel were increased

    as the injection

    pressure increased

    due to the higher heatrelease rate from the

    higher injection

    pressure. It can be

    seen that Nox

    increases dramatically

    as the pilot injection

    timing approaches the

    main injection timing

    because of a high rate

    of heat release.

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    Page 13

    Jyotirmoy

    Barman, R.P.

    Gakkhar,

    Vineet Kumar,

    Vipin Kumar,

    Sunita

    Gakkhar[14]

    2008 Experimental

    Investigation of

    Bio-Diesel

    Droplet Ignition

    Ignition

    delay of bio-

    diesel and its

    blends with

    diesel at

    differentatmosphere

    condition has

    been

    measured

    with

    different

    droplet

    diameter.

    1. Ignition Delay Bio-

    Diesel fuel has longer

    ignition delay than

    diesel fuel.

    2. The ignition delay

    decreases for blends

    and depends on the

    amount of diesel in

    the blend of diesel

    and bio-diesel.

    3. Activation Energy

    of diesel and bio-

    diesel calculated.

    K. Anbumani

    and Ajit Pal

    Singh[3]

    2010 Performance of

    Mustard & Neem

    oil blends

    Blending

    with pure

    diesel in the

    ratio of

    10:90,

    15:85,

    20:80, and

    25:75 by

    volume

    Engine

    (C.I.) was

    run at

    different

    loads (0, 4,

    8, 12, 16,

    and 20 kg)

    at a

    constant

    speed (1500

    rpm)

    separatelyon each

    blend and

    also on pure

    diesel.

    1. Blending vegetable

    oils with diesel a

    remarkable

    improvement in their

    physical and chemical

    properties was

    observed. Cetane

    number came to be

    very close to purediesel.

    2. However, mustard

    oil at 20% blend with

    diesel gave best

    performance as

    compared to neem oil

    blends in terms of low

    smoke intensity,

    emission of HC andNox.

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    Page 14

    T. Balusamy

    and R.

    Marappan

    2010 Effect Of Injection

    Time And

    Injection Pressure

    On CI Engine

    Fuelled With

    METPSO(Methyl

    Ester Of Thevetia

    Peruviana Seed

    Oil)

    Study the effect

    of injection

    timing and

    injection

    pressure on

    diesel engine

    fuelled with

    methyl ester of

    thevetia

    peruviana seed

    oil on

    automated,

    single cylinder,

    constant speed,

    and direct

    injection diesel

    engine.

    1. Initial phase of

    combustion, the

    premixed part.

    Advancing the

    injection timing by

    40crank angle (from

    230 to 270bTDC)

    resulted in the

    following

    improvements at full

    load:

    Increase in the

    brake thermal

    efficiency from

    31.22% to

    33.41%.

    Reduction in CO

    emission to 25%.

    Reduction in the

    HC level from 9.5

    to 7.7 ppm.

    Reduction in

    smoke level from

    48% to 35%.

    2. By optimizing the

    injection pressure

    (225 bar) and

    injection timing

    (27bTDC) the

    performance and

    emissions of the

    engine with METPSO

    can be improved

    significantly.

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    Page 15

    Jinlin Xue,

    Tony E. Grift,

    Alan

    C.Hansen[13]

    Nov 2010 Effect of Bio-

    Diesel on engine

    performances and

    emissions

    For CI engines,

    Bio-Diesel

    instead of diesel

    has been

    increasingly

    fuelled to study

    its effects on

    engine

    performances

    and emissions in

    the recent 10

    years. Studies

    have been rarely

    reviewed to

    favour

    understanding

    and

    popularization

    for Bio-Diesel

    so far for Bio-

    Diesel engine

    performances

    and emissions,

    were citedpreferentially

    since 2000 year.

    From these

    reports, the

    effect of Bio-

    Diesel on engine

    power,

    economy,

    durability and

    emissions

    including

    regulated and

    non-regulated

    emissions, and

    the

    corresponding

    effect factors are

    surveyed and

    analysed in

    The use of Bio-Diesel

    leads to the

    substantial reduction

    in PM, HC and CO

    emissions

    accompanying with

    the imperceptible

    power loss, the

    increase in fuel

    consumption and the

    increase in NO

    emission on

    conventional diesel

    engines with no or

    fewer modification.

    And it favours to

    reduce carbon deposit

    and wear of the key

    engine parts.

    Therefore, the blends

    of Bio-Diesel with

    small content in place

    of petroleum diesel

    can help incontrolling air

    pollution and easing

    the pressure on scarce

    resources without

    significantly

    sacrificing engine

    power and economy.

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    Page 16

    3.2 Objectives of Study

    From the reviewed literature following objectives has been derived for proposed research

    work:

    1. The insight of literature gives glimpse of combustion of Bio-diesel droplet in various

    conditions. Present study will undertake to compare the ignition behaviour of diesel, bio-

    diesel and blends of diesel (particularly for Jatropha Oil) and bio-diesel (by varying the

    percentage of diesel in the bio-diesel fuel) under varying temperature ranges and droplet

    diameter.

    detail.

    Mohammed

    EL-Kasaby &

    Medhat A.Nemit-allah

    [9]

    2012 Researched on

    ignition delay

    period &performance test

    for Jatropha oil

    Bio-Diesel

    Jatropha-curcas

    as a non-edible

    methyl esterBio-Diesel fuel

    Combustion

    characteristics as

    well as engine

    performance are

    measured for

    different Bio-

    Diesel diesel

    blends

    1. It has been shown

    that B50 gives the

    highest peak pressureat 1750 rpm, while

    B10 at low speed,

    1000 rpm.

    2. Higher percentage

    of NO in case of Bio-

    Diesel compared with

    that of diesel is

    attributed to the

    higher combustiontemperature of

    oxygenated Bio-

    Diesel resulted from

    advanced injection.

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    Page 17

    2. From this study, behaviour of the fuels such as ignition delay, Activation Energy and

    Droplet Diameter will be studied.

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    Page 18

    4.0 EXPERIMENTAL DETAILS:

    Experimental investigation will be carried out for the study of droplet ignition of suspended

    fuel in a chamber of fire brick with high temperature environment at atmospheric pressure.

    Below figure shows the different part with their salient features in the experimental set up. It

    will be divided into three different sub systems,

    A. Droplet Formation

    B. Furnace Chamber

    C. Observation and Photographic Recording System

    4.1 Sub Systems of Experimental workIn following section the sub system are briefly explained.

    4.1.1 Droplet Formation:

    A very fine nozzle will draw from diameter glass tube by heating it with oxyacetylene flame.

    The nozzle fix on to the glass syringe. Fine droplets miniature dimension will be produced by

    applying pressure to the syringe. The droplet will be introduced into the furnace.

    4.1.2 Furnace Chamber:

    An experimental set up planned as under:-

    A fire bricks chamber with inner dimensions of 500 300 250 mm having two windows

    130 50 mm on the two opposite walls of the furnace will made to record the droplet

    ignition photographically. One opening on the side wall (40 mm diameter) will made for the

    introduction of suspended in the furnace. There will one opening hole of diameter 40 mm for

    inserting the suspended fuel droplet to the furnace.

    The furnace will be heated with the help of six numbers 1 KW Nicrome wire wounded

    heaters. The locations of heaters are shown in the Figure 4.1.

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    Page 19

    Fig.4.1 Schematic of Furnace Chamber

    (1)Opening Port (Diameter of 40 mm);(2)Combustion Chamber;(3)Nicrome Wire Wounded

    Heater(6 Numbers);(4)Windows(130 x 50 mm);(5) Firebricks(6)Thermocouple(3 Numbers).

    4.1.3 Proposed Specification Of Furnace:

    Here is the proposed technical specification of finance in which the fuel combustion will be

    carried out, it is tentative, and it may be changed after fabrication of the experimental set up.

    Table 4.1 proposed specification of furnace

    Component Dimension

    Furnace Chamber Internal Length 500 mm

    Internal Width 300mm.

    Height 250 mm

    Fire Bricks Insulation Purpose

    Nicrome Wire Wounded Heaters Capacity of 1 Kw.

    Diameter 12 mm

    Thermocouple Chromel - Alumel

    Digital Temperature Indicator Display Temperature Reading in C

    Variac Capacity 0-260 V

    The temperature in the furnace will be controlled by varying the current flow through the

    Nicrome wire wounded heaters with the help of variacs. A 5 mm diameter Chromel-Alumel

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    Page 21

    5.0 Work Plan:

    Table 5.1 work plan for the dissertation work

    Work Plan Phase I Phase II

    Sr.

    No.Stage

    May-

    13

    Jul-

    13

    Aug-

    13

    Sep-

    13

    Oct-

    13

    Nov-

    13

    Dec-

    13

    Jan-

    14

    Feb-

    14

    Mar-

    14

    Apr-

    14

    May-

    14

    1Selection of Work

    Area

    2 Literature Review

    3Problem

    Identification

    4

    Further Literature

    Review

    5 Experimental Setup

    6Bio-diesel

    Preparation

    7Performance

    Testing

    8Results and

    Discussion

    9 Report Writing

    5.1 Objectives achieved and to be achieved:

    1. As mentioned in above table the after adequate literature review for the selected work

    the, the objective of the work is well defined.

    2. Sources to purchase the main components and equipments which are related to the

    experimentation work are searched out, yet to acquire.

    3. As per objective, the design of furnace is ready and it will be fabricated soon.

    4. The report writing is started with completion of 3 chapters.

    List of Publications:

    A review paper with the title A review study on Bio-Diesel Droplet Ignition is under

    process for publication in International Journal Of Engineering Research And

    Technology(ISSN:2278-0181) which relevant with this dissertation.

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    Page 22

    6. References:

    1. Dr. Tiwari, Report of Committee on Development of Biofuel Planning commission

    ofIndia, April 2003.

    2. S.C. Anthony Lam and Andrzej Sobiesiak, Biodiesel Droplet Combustion Journal

    of KONES Powertrain and Transport, Vol. 13, No. 2.

    3. K. Anbumani and Ajit Pal Singh , Performance Of Mustard And Neem Oil Blends

    With Diesel Fuel In C.I. Engine ,ARPN Journal of Engineering and Applied Sciences

    ISSN 1819-6608 VOL. 5, NO. 4, APRIL 2010.

    4. M. Renksizbul and M. Bussann Multicomponent droplet evaporation at intermediate

    Reynolds numbers, Hear Mass Transfer. Vol. 36,No. lI,pp.2827-2835, 1993.

    5. Chandrasekhar an, et al. Effect of Biodiesel, Jet Propellant (JP-8) and Ultra LowSulphur Diesel Fuel on Auto-Ignition, Combustion, Performance and Emissions in a

    Single Cylinder Diesel Engine Journal of Engineering for Gas Turbines and Power ,

    FEBRUARY 2012, Vol. 134 / 022801 by ASME.

    6. Hyun Kyu Suh et.al. Spray and Combustion Characteristics of Biodiesel/Diesel

    Blended Fuel in a Direct Injection Common-Rail Diesel Engine - Journal of

    Engineering for Gas Turbines and Power MAY 2008, Vol. 130 / 032807 2008 by

    ASME.

    7. C. K. LAW, Recent Advances in Droplet Vaporization and Combustion publish in

    Progress in Energy Combustion Science, Vol. 8. pp. 171-201.

    8. Jiunn-Shyan Huang and Tsong-Sheng Lee Comparison of Single-Droplet

    Combustion Characteristics between Biodiesel and Diesel, ICLASS-2006 Aug.27-

    Sept.1, 2006, Kyoto, Japan Paper ID ICLASS06-140.

    9. Mohammed EL-Kasaby, Medhat A. Nemit-allah Experimental investigations of

    ignition delay period and performance of a diesel engine operated with Jatropha oil

    biodiesel Alexandria Engineering Journal (2013) 52.page 141-149.

    10. Sergei Sazhin et.al. Biodiesel Fuel Droplets Modelling of Heating and Evaporation

    Processes, August 2013, university of Brighton.

    11. Guangwen Xu et. al. Combustion characteristics of droplets composed of light cycle

    oil and diesel light oil in a hot-air chamber published paper in Elsevier Science Ltd.

    PII: S0 01 6 - 2 36 1 (0 2) 00 2 764 page Fuel 82 (2003) 319330.

    12. C. H. Wang, X. Q. LIU, And C. K. LAW, Combustion and Micro explosion of

    Freely Falling Multicomponent Droplets COMBUSTION AND FLAME 56: 175-

    197 (1984) 175, NREL/TP-540-43672.

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    Page 23

    13. By Jinlin Xue et al. Effect of biodiesel on engine performances and emissions

    Renewable and Sustainable Energy Reviews journal 15(2011)1098-1116.

    14. Jyotirmoy Barman et al. Experimental Investigation of Bio-Diesel Droplet Ignition,

    International Journal of Oil, Gas and Coal Technology, 2008 Vol.1, No.4, pp.464

    477.

    15. S.H.M. El-Bahnasy, M.M. El-Kotb, Shock Tube Study for the Measurement of

    Ignition Delay Period of 1, 2-Epoxy Propane and n-Hexane. In: 6th International

    Conference in Fuel Atomization and Spray Systems, ICLASS-94, Ruene, France,

    1994.

    16. J.B. Heywood, Internal Combustion Engine Fundamentals, McGraw Hill Book Co.,

    1988.

    17. http://personal.mecheng.adelaide.edu.au/marcus.boyd/Marcus%20Boyd%20Short.pdf

    18. http://www.sciencedirect.com/science/article/pii/S0016236113002172

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    Page 24

    Appendix A ABBREVIATIONS

    BSEC Brake Specific Energy Consumption

    BSFC Brake Specific Fuel Consumption

    BTE Brake Thermal Efficiency

    CV Calorific Value

    CaO Calcium Oxide

    CI ENGINE Compression Ignition Engine

    CNG Compressed Natural Gas

    CO Carbon Monoxide

    CO2 Carbon Dioxide

    cSt Centistokes

    DI ENGINE Direct Injection Engine

    EGT Exhaust Gas Temperature

    HC Hydrocarbon

    HSD High Speed Diesel

    IC ENGINE Internal Combustion Engine

    IDI ENGINE Indirect Injection Engine

    JCO Jatropha Curcas Oils

    KOH Potassium Hydroxide

    LNG Liquefied Natural Gas

    LPH Litre per Hour

    LPM Litre per Minute

    MEK Methyl Ester of Karanj

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    Mha Million Hectare

    MMSCMD Million Standard Cubic Metres per Day

    MMT Million Metric Tonne

    MPNG Ministry of Petroleum and Natural Gas

    NaOH Sodium Hydroxide

    NO Nitrogen Oxide

    NO2 Nitrogen Dioxide

    NOME Neem Oil Methyl ester

    NOX Oxides of Nitrogen

    PAH Polycyclic Aromatic Hydrocarbons

    PPM Particles Per Million

    RPM Revolutions per Minute

    SAE Society of Automotive Engineers

    SVO Straight Vegetable Oil

    TDC Top Dead Center

    TEL Tetra Ethyl Lead

    WPO Wood Pyrolysis


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