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Flat Plate MBRs – A Viable and Proven Technology

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Flat Plate MBRs A Viable and Proven Technology Scott Kafka, P.E. Hamlett Environmental Technologies Co. Title 22
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Flat Plate MBRs – A Viable and Proven Technology

Scott Kafka, P.E.

Hamlett Environmental Technologies Co.

Title 22

MBR Fundamentals What is an MBR System?

2

• Membrane Biological Reactor System, or MBR

• Suspended growth activated sludge and low-pressure membrane filtration

• Sum of associated process basins, membrane trains and ancillary equipment (e.g. air scour and membrane cleaning)

Membrane Bioreactor Submerged membranes filter mixed liquor through

multiple barriers (membrane + biofilm)

Early Stage

• 1969 – U.S. Patent 3,472,765 issued to

Dorr-Oliver for Membrane Separation in Biological Reactor System Concept

• 1989 –Submerged MBR Development

• Early 1990’s –Submerged membranes developed and commercialized in North America and Japan

• Mid 1990’s – 60 installed MBRs in Japan

• Late 1990’s – First North American submerged MBR installations

MBR Technology Development Timeline

Today

• Exponential growth since the 1990’s

• MBR Systems reliably meet tight Bionutrient Removal (BNR) limits, in a small footprint

• Proven, Best Available Technology (BAT) for wastewater treatment

• Reuse, Recycle, Reclaim

Future

• “MBR Technology is the future of wastewater treatment as costs come down and energy efficiency improves”

• MBR technology for Wastewater reclamation and Water reuse, essential component of sustainable water management

MBR Technology Development Today and Future

MBR at a Glance Mature, growing

5

6,000+ MBRs Worldwide 600+ US MBR Installations 20+ Years of Experience

“A decade ago the largest MBR in the World was just under 3.4 MGD…(Judd, 2010)”

MBR Experience MBR Systems

Municipal, Tribal, Commercial and

Industrial Applications

Decentralization

Reuse Including RO Pretreatment

Retrofit

Biological Nutrient

Removal (BNR) 6

Why MBR? Benefits

7

• High quality effluent

• Small footprint

• Ease of operation

• Reliability

• Lower total cost

MBR Facility Hampton Creek WRF, GA

Why MBR? MBR is considered Best Available Treatment (B.A.T)

MBR Permeate Quality

Parameters Typical Values

Achievable Values

BOD5 < 2.0 mg/l Non-Detect TSS < 2.0 mg/l Non-Detect

Ammonia (NH3) < 1.0 mg/l Non-Detect

Total Nitrogen (TN) < 10.0 mg/l < 3.0 mg/l

Phosphorus (TP) < 1.0 mg/l < 0.03 mg/l

Turbidity < 0.10 NTU <0.05 NTU

Fecal Coliform < 2.2 CFU/100ml Non-Detect SDI < 3 <2

8

1/2 the complexity

1/4 the footprint

Why MBR? ½ the complexity, ¼ the footprint

9

Conventional Treatment Producing Reuse Effluent and Stabilized Biosolids

MBR System Equivalent

Technology Overview How much of what is removed?

mm 0.001 0.01 0.1 1 10 100 1,000

RO UF Particle Filtration

NF MF

Sand

Virus Bacteria

MBR

• UF and MF perform the same in submerged MBR applications. • Non-detect total suspended solids (TSS) and < 0.05 NTU.

• 106 bacteria removed w/o post-disinfection.

• 104 viruses removed w/o post-disinfection.

• Does not remove salt.

Salt

10

Technology Overview Harmful pathogens are physically rejected, filtered

11

Hepatitis Salmonella Crypto

< 1mm

< 10mm

< 100mm

0.01mm

Pore Size

CAS Effluent = 105 Fecal Coliforms

MBR Effluent = Non-Detect Fecal Coliforms

Technology Overview MBR Systems are comprehensive solutions

Stormflow Management

12

Biosolids Handling

Wastewater Treatment

MBR System Basic MBR System Process

13

• Activated Sludge Process

• Process selection and biological configuration depend on treatment objectives (e.g. TN , TP)

• For the same biomass inventory, the biological volume and footprint will be smaller. MBRs typically operate at 8,000-14,000 mg/L MLSS concentration

Technology Overview Membrane Biological Reactor

14

• A Membrane Biological Reactor is “one part” of a biological process where: • Small microbes degrade dissolved pollutants

• Air mixes the tank, provides oxygen and scours membranes for cleaning

• Water (permeate) is filtered through submerged membrane units or SMU; recycle mixed liquor returns to the process

• Rejected solids form biofilm that determines sustainable flux and plant hydraulics

Module Cassette MBR

MBR System Sub-Systems for a Fully-Functional WWTP

• Headworks

Fine Screens

Piping, Valves, Instrumentation

• Process Basins

(Anaerobic, Anoxic/ Post-Anoxic)

Mixers, Pumps

Piping, Valves, Instrumentation

• Aeration Basins

Fine Bubble Diffusers

Piping, Valves, Instrumentation

• Recycle System

RAS Pumps

Piping, Valves, Instrumentation

• Permeate System

Pumps

Piping, Valves, Instrumentation

• MBR Basin

Membrane Units

Piping, Valves, Instrumentation

• Aeration System (MBR, Pre-aeration)

Blowers

Piping, Valves, Instrumentation

• Chemical Cleaning

Mazzei Injector

Piping, Valves, Instrumentation

Chemicals

Sodium hypochlorite, oxalic acid or

citric acid

• Controls and Integration

PLC, SCADA, MCP

Hardware and software

Technology Overview Membrane Technology for MBR Systems

• RO & NF = High Pressure

• UF & MF = Low Pressure

• External & Submerged Membranes

• FS & HF for MBR

• Different flavors of each

• Focus on FS technologies

Technology Overview Membrane Technology – Flat Sheet, Flat Plate, Hollow Fiber, Spiral Wound

Hollow

Fiber

Flexible Flat

Sheet

Spiral

Wound

Flat

Plate

Technology Overview Membrane Configurations - Membrane Units

Flat Plate Flat Sheet

18

Hollow Fiber Spiral Wound

Manifold

Membrane Case

Membrane Cartridges

Diffuser Case

Diffuser

Tubes

19

Flat Plate Configuration Membrane Unit Components

Flat Plate Configuration Membrane Data

• Membrane sheet made of chlorinated polyethylene

• Nominal pore size 0.4 µm, effective pore size 0.2 µm

• ABS (Acrylonitrile Butadiene Styrene) support plate with a spacer layer between it and an ultrasonically welded flat sheet membrane on both sides

• Effective filtration area (varies): 8.6 –15.6 ft2 per cartridge; 107.64 ft2 per module

• Membrane Area (varies depending on model): 3,444 ft2/unit; 6,231 ft2/unit; 4,306 ft2/unit

Nozzle

Panel

Spacer

Membrane

Sheet

20

Flat Sheet Configuration Membrane Unit Components

21

Lifting Bars

Flat Sheets

Diffuser Assembly

Physical Characteristics Dry weight 1,764 lbs

Wet weight 2,425 lbs

Length 5.9 ft

Width 3.8 ft

Height 9.1 ft

Area per module 4,306 ft² (400 m²)

Base

Permeate Conn.

Cassette

Flat Sheet Configuration Membrane Unit Components

• 4 Cassettes per Membrane Unit

• PVC Framework for Sheet Support

• Flexible Flat Sheets

• 25 Sheets per Cassette

• Sheet Dimensions: 1 m x 2 m

• 4 m2 (43.06 ft2 Membrane per sheet)

22

Cassette

Base

Flat Sheets

23

Flat Sheet Configuration Membrane Sheets

24

Flat Sheet Configuration Membrane Data

Factor Description

Pore Size 0.04mm

Type Hydrophilic

Material Polyethersulfone (PES)

Spacer Material Polyester

Fouling Potential Low

Chem./Mech. Stability High

Other Self Healing

(“Bullet Proof”)

Max. Warranty Period Lifetime

Flat Sheet Configuration How it works

Membrane

Permeate spacer

Laminary composite

Permeate removal

Guide plate

2 mm 8 mm 2 mm

Permeate Flow Solids are filtered out,

rejected by the membranes

(and biofilm). Permeate

moves through the plenum to

common manifold and drawn

out under vacuum

26

Flat Sheet Configuration Bullet Proof

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

30 60 90 120 150 180 210 240

NTU

Time (sec.)

Turbidity Data

Scratch

Cut edge

Bullet hole

Intact membrane sheet ( 0.04 NTU )

Self-healing Membrane Sheets

Turbidity trends show recovery after being

scraped, cut and punctured. Because of design, maximum

self healing in roughly 3 minutes.

27

Flat Plate Fouling

Organic Fouling

28

Flat Plate Fouling

Inorganic Fouling Causes:

- High Hardness/Iron levels in the

background water

- FeCl3 addition for Phosphorus

removal

29

Flat Plate Cleaning System

Technology Overview Biosolids Treatment with Flat Sheet/Flat Plate Membranes

Digester 1

Digester 2

Anoxic

Basin

MBT

Membrane Thickening Aerobic Digestion Process (MBT), utilizes flat sheet or flat plate membranes for thickening waste activated sludge (WAS).

• Reliably thickening sludge up to 4% solids concentration without adding polymers

• Provides Class B stabilized sludge in a reduced tank footprint

• Reducing sludge holding costs

Aerobic Digestion with Membrane Thickening (PAD®-K) - Dundee, MI

Membrane Thickener (MBT) - Woodside, NY

Membrane Thickener (MBT) – Westford Acton, MA

Technology Overview Biosolids Treatment with Flat Plate/Flat Sheet Membranes

Membrane Thickener (MBT) – Cayce, SC

Technology Overview Stormflow Management

Spiral wound ultrafiltration membranes can be utilized for a physical/chemical side-stream treatment of peak flows (stormBlox™), in lieu of biological treatment.

• Provide TSS, BOD, and COD removal • Alum injected into raw influent to enhance filterability

and contaminant removal • Utilizes iSEP™ flat-sheet, spiral wound, PVDF, ultra

filtration membranes (0.03 micron pore size) • Vacuum driven • Require periodic cleaning

• Improves reduction of soluble BOD • Works by adsorption • Spent media to be replaced disposed of in landfill

Activated Carbon BOD Removal

Ultrafiltration TSS Removal

Zeolite Ammonia Removal

• Naturally occurring mineral • Works by ion exchange with ammonium

Technology Overview Stormflow Management

Santa Lucia Preserve, CA (MBR + stormBlox™)

• Retrofit of an existing 0.05 MGD trickling filter • Upgrade included MBR + stormBLOX™ • StormBLOX System (71,000 GPD)

• Membrane skid (8ft x 10ft) • GAC media bed • 2 pumps, control valves • Alum addition

• MBR System (50,000 GPD) • Qty. 2 SMUs (RM150, KUBOTA®)

Michigan Flat Plate MBR Systems

Michigan Case Studies

- Dundee, MI

- Leoni, MI

- Odawa Casino, MI

- Gun Lake Casino, MI

34

Dundee, MI

35

Retrofit SBR tank = Pre-Air Tank

Covered MBR Tanks

Design Avg Q = 1.5 MGD

July 2005 Start-up

Pumped Permeate

Dundee, MI – PAD(K)

36

Aerobic Digester

Membrane Thickener

Dundee, MI

37

Leoni Twp., MI

38

Design Avg Q = 3.0 MGD

June 2010 Start-up Gravity flow Permeate with Pump Assist

Leoni, MI

39

Pre-Air Tank

Anoxic Tank

Leoni, MI

40

MBR Tanks

Leoni, MI

41

Odawa Casino Petoskey, MI

42

Entire Treatment Plant is

located in building

June 2008 Start-up

Gun Lake Casino Gun Lake, MI

43

1 Anoxic tank

2 Pre-Air Tanks

2 Covered MBR Tanks

Feb. 2011 Start-up

Anoxic tank and Pre-Air tanks

covered with netting to catch

leaves and debris

MBR Case Studies

1. Upper Wallkill, NJ 2. Pembroke, MA 3. Callao, VA

Case Study: Upper Wallkill, NJ MBR process achieving TN<3 mg/l for reuse at low influent temp (6° C)

• Original facility built in 1984

• Serves Franklin, Hamburg and Sussex boroughs

• Surface Water discharge (DSW)

• Actual flow 1.5 MGD; permitted for 3.0 MGD

• Permit NH3< 1mg/l, TP < 1 mg/l

45

Existing Facility

Case Study: Upper Wallkill, NJ Expansion/Upgrade Project • In 2005-06, Cerenzio & Panaro Consulting Engineers evaluated the plant expansion

to provide service to Vernon Town Center and Mountain Creek Development. Additional flow of 0.265 MGD

• Actual flow was 1.5 MGD compared to 3.0 MGD permitted flow but all the allocations were done, so a new Ground Water Discharge permit had to be issued

• Ground water discharge (DGW) and has to be replenished in the same area where the wastewater was received from

• Evaluated three options: • CAS (initial design)

• Use existing plant and aeration basin 3

• Add a Primary and Secondary Clarifier

• Add a Denitrification Filter/Ultraviolet Disinfection Building

• CAS (Alt “A”)

• Add a new independent CAS Plant, aeration basin 4

• Add a Denitrification Filter/Ultraviolet Disinfection Building

• MBR (Alt “B”)

• Add a new MBR system

• With little or no additional treatment, spray irrigation could be accommodated if it becomes desirable

46

Case Study: Upper Wallkill, NJ Evaluation of Estimated Construction Costs – Technology Comparison

47

CAS MBR Item (Alt "A") (Alt "B")

Mechanical Screen $160,000 $160,000

Rate Controller $65,000 $90,000

Pretreatment $372,000

Primary Clarifier $510,000

Primary Sludge Pump Station $275,000

Existing P.C. Pump Station $15,000 $15,000

Pipe Interconnection AB No.3

Aeration Basin No. 4 $1,425,000

Mix Chamber/Distribution Box $195,000

Final Clarifier (DGW) $555,000

Filter/UV Building $1,275,000

Reactors/Membrane Building $2,700,000

Site piping, Other Civil $375,000 $325,000

Sub-Total $4,850,000 $3,662,000

Contingency @ 5% $242,500 $183,100

Sub-Total $5,092,500 $3,845,100

Adjust for ENR CCI - 7660 $5,111,612 $3,850,643

Final Clarifier (DSW) $1,200,000 $1,700,000

Total $6,311,612 $5,550,643

Case Study: Upper Wallkill, NJ 0.265 MGD MBR System

48

Influent Characteristics

Parameters Typical Values (mg/l)

BOD5 200

TSS 260

TKN 45

Total Nitrogen (TN) 45

Phosphorus (TP) 8

Design Effluent Quality Parameters Typical Values

(mg/l)

BOD5 < 9.5

TSS < 2.2

TKN -

Total Nitrogen (TN) < 7

Phosphorus (TP) -

Design Parameters:

• Four Stage Process Design • Design flow: 0.265 MGD • No Peak Flows • Min Temp: 5.6 ° C • Max MLSS: 18,000 mg/l • No Carbon addition

MBR (Membrane Zone) Design

Filtration Mode: Pumped # of Reactors: 2

Submerged Membrane Unit (SMU):

ES200, KUBOTA®

# SMU: 16 Design Flux: 9.7 gfd

Minimum Temperature: 5.6°C Peak Factor: 1.0

# of Maintenance Cleans: 2

Case Study: Upper Wallkill, NJ 0.265 MGD MBR System

49

• Construction started in • May 2008; commissioned

in Jan 2010 • Serves Vernon Town

Center and Mountain Creek development

• Ground Water discharge (DGW)

• Permitted for 0.265 MGD; actual flow ~0.2 MGD

• Effluent pumped back up 6 miles to Vernon leach fields

• Permit TN<10 mg/l, Fecal coliforms <200/100ml

MBR System

Case Study: Upper Wallkill, NJ 0.265 MGD MBR System

50

Pre-Anoxic | Pre-Air | Post - Anoxic | MBR

Case Study: Pembroke, MA Single Stage MBR process technology achieving TN<10

• Retrofit of trickling filtration system

• Located in a suburb of South Boston, serves 3 commercial shopping plazas and an office building

• Existing facility design flow: 40,000 GPD MMF

• Original facility was built in 2006

• Permit BOD<30, TSS<30, TN < 10 mg/l

51

Existing Facility

Case Study: Pembroke, MA Upgrade Project

• In 2012, Onsite Engineering evaluated plant upgrades utilizing MBR technology

• MBR system selected. Construction started in August of 2012. Time to build: 8 months

• Commissioned in March of 2013

• Total installed project cost: Less than $1M

52

MBR System

Case Study: Pembroke, MA 40,000 GPD MBR System

53

MBR System Layout

A single-stage MBR process utilizes saturated oxygen technology to satisfy process aeration requirements and eliminate the need for fine bubble diffusers. In addition, the process operates at an increased MLSS concentration and uses simultaneous nitrification/denitrification, the combination of which further intensifies the biological process into a significantly smaller footprint.

Case Study: Pembroke, MA 40,000 GPD MBR System

54

Influent Characteristics

Parameters Typical Values (mg/l)

BOD5 400

TSS 300

TKN 60

Total Nitrogen (TN) 60

Phosphorus (TP) 8

Design Effluent Quality Parameters Typical Values

(mg/l)

BOD5 <30

TSS <30

Total Nitrogen (TN) < 10

Design Parameters:

• Single Stage Process Design (microBLOX™)

• Design flow (MMF): 40,000 GPD

• No Peak Flows

• Min Temp: 10 ° C; Max Temp: 25 ° C

• Max MLSS: 25,000 mg/l

MBR (Membrane Zone) Design

Filtration Mode: Gravity # of Reactors: 1

Submerged Membrane Unit (SMU):

RM200, KUBOTA®

Supplemental Aeration Technology:

Oxygen concentrator + IR loop + Injector

# SMU: 2

Design Flux: 6.41 gfd Peak Factor: 1.0

# of Maintenance Cleans: 2

Case Study: Callao, VA MBR System Retrofit

• Retrofit of MBR system

• Located in North Cumberland County, VA

• Municipal application

• Original facility used GE hollow fiber membranes

• Existing facility design flow: 60,000 GPD MMF

• Original facility was built in 2005

55

Existing Facility

Case Study: Callao, VA MBR System Upgrade Project

• MBR tanks were retrofitted

with OV400 flat sheet membrane units. The upgrade project also included piping modifications, new PLC, and programming modifications

• Construction started in July of 2013

• Commissioned in August of 2013

• The new flat sheet membrane units provided instant capacity increase, and will be less susceptible to sludge accumulation, which will result in less risk and easier operation

56

MBR System

Case Study: Callao, VA 60,000 GPD MBR System

57

MBR System Layout

Case Study: Callao, VA 60,000 GPD MBR System

58

Influent Characteristics

Parameters Typical Values (mg/l)

BOD5 250

TSS 250

TKN 40

Total Nitrogen (TN) 40

Phosphorus (TP) 8

Design Effluent Quality Parameters Typical Values

(mg/l)

BOD5 <5

TSS <5

Total Nitrogen (TN) <10

Design Parameters:

• Three Stage Process Design

• Design flow: 60,000 GPD

• Peak Flow: 80,000 GPD

• Min Temp: 10 ° C; Max Temp: 25 ° C

• Max MLSS: 10,000 mg/l

MBR (Membrane Zone) Design

Filtration Mode: Suction # of Reactors: 2

Submerged Membrane Unit (SMU):

OV400, OVIVO

# SMU: 2 Design Flux: 10.0 gfd

Peak: 1.3 # of Maintenance Cleans: 2

Scott Kafka, P.E. Hamlett Environmental Technologies, Co.

905 Gulley Rd. Howell, MI 48843 Ph: 517-545-2500

[email protected]

www.hamlettenvironmental.com


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