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Acorn vyater

water treatment specialists

D D D Q 0 0 0 D

IB

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Associated company Acorn Chemicals Ltd. Registered in Ireland No. 175001. Directors: William Holland & Eileen Holland. Web: htto://www.acornwater.ie, Email: info@acornwater,ie

n

Acorn water, Glasslyn Road,

Bandon, CO Cork

“for all your water needs”

MATERIAL SAFETY AND DATA SHEET

Section 1: Identification of the substance and of the company

Product Name: Aluminium Sulphate Liquor

Chemical Name: Aluminium Sulphate, Alum.

Company Identification

Acorn Chemicals Ltd. T/A Acorn Water Glassslyn Rd. Bandon, Co. Cork. Rep. Of Ireland. Tel: (023) 43466 Fax: (023) 43467

Emergency Tel No. (023) 43466

~~~ ~

Section 2: Chemical compositiodInformation on Ingredients

Aluminium as Alumina ( A1203 ): 8 YO * 0.2 YO

Section 3: Hazards Identification

Eve/Skin contact: Harmful if absorbed through skin. Causes bums. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract, eyes and skin. Inhalation: may be fatal as a result of spasm, inflammation and edema of the larynx and bronchi, chemical phneumonitis and pulmonary edema. Ingestion: May be fatal if swallowed, Symptoms of exposure may include burning sensation coughing, wheezing, laryngitis, and shortness of breath, headache, nausea and vomiting.

1

VAT No. I€ 6575001N. Tel: +353 23 43466 Fax: +353 23 43467

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li 0

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Section 4: First Aid

Eye/Skin contact: After contact, immediately flush eyes or skin with amounts of water for at least 15 minutes. Consult a physician if irritation persists. Inhalation: If after spasm due to inhalation, remove to fresh air and check for breathing and pulse. Provide artificial respiration, if person is not breathing. Ingestion: Wash out mouth with water provided person is conscious. Obtain medical attention immediately.

Section 5: Fire fighting measures

Use extinguishing media appropriate to surrounding fue conditions. Wear fully protective suit and self-contained respiratory protective device. Note: Toxic fumes are liberated above 600°C.

Section 6: Accidental release measures

Evacuate area. Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. Cover with dry lime, sand or soda ash. Ventilate area and wash spill after material pickup is complete.

Section 7: Handling and Storage

Treat as a weak acid. Avoid contact with eyes, skin and clothing. Avoid prolonged or repeated exposure. Do not store with incompatible materials e.g. cyanides, sulphides, carbonates. Avoid contact with most common metals. Can be stored long term in stainless steel, plastic or rubber lined mild steel surfaces.

Section 8: Exposure controls/ Personal Protection Wear appropriate NIOSHMSHA-approved respirator, chemical-resistant gloves, safety goggles, other protective clothing. Safety shower and eyes bath must be readily accessible. The occupational exposure limit (O.E.L.) for aluminium salts is 2mgm”(long term).

Associated company Acorn Chemicals Ltd. Registered in Ireland No. 175001. Directors: William Holland & Eileen Holland. Web: htto://www.acornwater.ie, Email: info@acornwater.ie

2

VAT No. IE 6575001N. Tel: +353 23 43466 Fax: +353 23 43467

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Section 9: Physical and Chemical Properties

Appearance: Odour: Boiling Point: Freezing point: Flash point: Specific Gravity ( g/cm3 ) : pH at 20 "C: Organic solvents content: Flammability: Explosive properties: Oxidising properties: Vapour pressure: Solubility:

Liquor None 101 "C -15°C N/A 1.32 ( at 20°C ) 0.8-1.5 0.0 % N/A N/A N/A 17mm @60"C Miscible in all proportions with water.

Section 10: Stability and reactivity

No decomposition if used according to specification. Dangerous reactions with bases i.e. chlorites, hypochlorites, sulphites, cyanides and sulphides. Avoid contact with most common metals (aluminium, copper, zinc and their alloys). Can liberate toxic and corrosive fumes of SO1 and SO3 under extreme conditions when boiled to dryness or heated above 600°C.

Section 11 : Toxicological Information

Eve/Skin contact: Liquid aluminium sulphate has been found to be a minimal irritant to a rabbit's eye and a non-imtant to rabbit skin. Ingestion: Unlikely to be acutely harmful. Acute oral toxicity in rats (LDso) exceeded 5000mgkg.

Section 12: Ecological Information

On contact with water, aluminium sulphate will hydrolyse to give sulphuric acid and gelatinous aluminium hydroxide. Discharge to the aquatic environment should be avoided as aluminium sulphate can clog the tentacles and gills of marine life.

Section 13: Disposal Considerations

Dispose in accordance with all applicable federal, state and local environmental regulations.

Associated company Acorn Chemicals Ltd. Registered in Ireland No. 175001. Directors: William Holland & Eileen Holland. Web: -, Email: info@acornwater.ie

3

VAT No. IE 6575001N. Tel: +353 23 43466 Fax: +353 23 43467

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- . . . . . . . . . . . . . . - . . . . . .. . . . . . . . - . . . . - - - -

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Section 14: Transport Information

UN NumberAIescription: Not classified, not a transport hazard in the EC.

Section 15: Regulatory Information

Dangerous Substances Directive 67/548/EEC: This applies Dangerous PreDarations Directive 88/379/EEC: This applies Label Information: Aluminium Sulphate, “Xi” irritant, R36 irritating to eyes, S26-37 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. Control of substances hazardous to health (COSHH) remdations: These regulations apply in the UK.

Section 16: Other Information

Other sources of data used to compile this information.

Draft BSEN 878-Chemicals used for the treatment of water intended for human consumption, Aluminium sulphate, iron free grade.

U This information is given without any warranty or representation. We do not assume any legal responsibility for same, nor do we give permission, inducement, or recommendation to practise any patented invention without a license. It is offered solely for your consideration, investigation and verification. Before using any product, read its label.

4

Associated company Acorn Chemicals Ltd. Registered in Ireland No. 175001. Directors: William Holland & Eileen Holland. Web: htto://www.acornwater.ie, Email: info@acornwater.ie

VAT No. IE 6575001N. Tel: +353 23 43466 Fax: +353 23 43467

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P . 2

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MATERIAL SAFETY AND DATA SHEET

Section 1: Identification of the substance and of the company

Product Name : Cellfloc C19

Corn Danv Identification

Celtic Watercare Ltd Unit 27A Euro Business Park Little Island CO Cork Ireland Tel: +353 (0)21 4524716 Fax: +353 (0,)21 452471 7 Emergency: t 353(0) 876678860 E-inail:cclticwatercarebd@eirconi .net

Sectiori 2: Inforniation on Ingredients

Chemical Characterisation: Water soluble polymer

Section 3: Hazards Indentifactian

May be mildly irritating to eyes and skin.

Hazardous Components. Risk Phrases. R36 Irritating to eyes R38 Irritating to skin

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63 P . 3

Section 4: First Aid Measures U

0.

' 0

Eve contact: Rinse well with water for at least fifteen minutes, if irritation persists seek medical advice. Skin Contact. Wash with soap and water. Remove contaminated clothing. Ingestion. Do not induce vomiting. Wash out mouth with water. Inhalation. Remove to fiesh air and rest.,If imtation persists seek medical advice.

' '

Section 5: Fire Fighting Measures

SDecial hazards: This material is non-flammable

Extinguishing rncdia suitable: a. Foam Spills produce extremely slippery surfhce.

b. Carbon Dioxide c. Water spray-jet d. Powder

Snecial protective emipment for fire fighter: (a) No special equipment required

Section 6: Accidental Release Measures

Personal Precautions: A. Avoid contact with skin and eyes. B. Wear gloves and goggles

Environmental Precautions: a. Keep away from drains. b. Avoid contact with Surface water or ground water c. Inform local authority in case o f large spills.

Methods for cleaning UP: a. Collect with absorbent material such as sand or earth. Place in a skip

b. Spillages are slippery.

Section 7: Handling and Storage

Handling Emergency Shower and eye wash facilities should be available

Storage: Avoid extremes o f temperature. Store between 0-3O'C.

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. - - . . - . __ - .. . . . . -. . . . . . . . . . . . . . . . . . . . . . - - -. . . . . . - . . . - .

( I * Q U

13

13

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Section 8: Exposure ControYPersonal Protection

General Pmtwtion: Avoid spillages. Persowl Protection : Wear Rubber gloves.

Wear safety goggles In cases of insufficient ventilation wear suitable respiratory equipment

I

Section 9: Physical and Chemical Properties

ADsearancc: Off whitc viscous liquid. Odour: Characteristic.

Viscositv: Particulate matter negligible SDecific Gravitv: Approximately I .O approx.

PHI 5.0 - 8.0

Section 10: Stability and Reactivity

Stable under normal conditions.

Section 11 : Toxicological Information

Low ordcr of acute toxicity (LD50>5000mg/kg oral mouse) Eye and skin irritant.

Section 12: Ecological Information

No experimental toxicity values available.

Section 13: Disposal Consideration

Dispose of observing all local authority regulation to an authorised disposal facility.

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Section 14: Transport Information

No special requirements.

Section 15: Regulatory Information

Labelling No Special requirements. Risk phrases R36 Irritating to eyes

R38 Irritating to skin Safety Phrases S24 Avoid contact with skin

S25 Avoid contact with eyes S3G Wear suitable protective clolhing

Section 16: Otber Information

Petwn to contact: John 0' Connor, Celtic Watercare Ltd Training advice. N/A Further infomation, N/A

Thc information provided in this Safety Data Sheet is correct to the best of our current knowledge and is given in good f'dilh. However, it should not be construed as a warranty fbr which Celtic Watercare Limited assumes legal responsibility.

P.5

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Trade h4arks 3nd Synonyms (if any) Sodium Cwhonatc - Soda Ash

Physical Form White crysbllhnc Hygroscopic powder. Responsible Person :

L'hemllloc Ltd,

Shnnnnn. CO, Clarc. +353 61 -708650

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Smitbstown Ind. Estate,

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. _-..".+ ._- Chcmicol Nanica and Synonyms Sodium Csrhnate Sod;# Ash Sdal ctyktals Wnsbing Sudo, Molecular Formula

Emetgcncy Telephone : NltlCO:, ".

Chcmifloc Ltd, +353 61 -7086-W

-

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HAZARDS IDENTIFICATION

A primary a k i n irritant. Can came drynew and An eye irritant, may injure the outer coeting nf ttic cornm.

Modcrntcly irritating to the nasal mcrnhranc.

SECTION 3

Occupational Exposurc Limit (OEL) Nnt Specified

-- --

I i 0

,.__ Boiling t'oint Cdeg. C)

Autoignition (deg. C) Nuue Solubility in Wntcr 1431, w/w 15°C

- Y * I _ _ . L L y y . " N/A

Ref: MSDS/SOI. Kev: 1 06rnsm~

Melting Point (deg. C) Flash Point ((leg. C) Spccific Gravity 8Sl"C None NIA Planmiable Limit ("5 by Vol. in Air) Nuu flalurllnClc? NIA Sulubility in Other Solv&ts N/A

-.U- .- Vapour Prcssurc (mm Hg)

Oxidising Properties . , -..*_

-- N!!L-..

MATEMAL SAFETY DATA SHEET Chemifloc Ltd

SODTUM CARBONATE

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' 0 l

Shbilily

D

I Unstnblc ..".- Conditions to Avoid N/A Stwhlc X

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Rcf MSDS/SOl. Rev: I Ob/os/O.;

'1 SECTION S STABTLTTY AlYb REACTIVTTY

I_

- Attrrkn Alirrniniilrn nnrl ita ~lloyc.

Hazardous Decomposition Products Solutions producc hydrogen a Rslmmahle gas which forins ewplfi%ivc! mirtiirrrc with air in contnct with aluminium and its atloys. I

SECTION 6 TOXICITY DATA

Short term cflwts ofovcr cxposurc when :

In contact with skin : A primary irritant - tonstant exposure can CAUSC dryness and crrctcing.

In conm wlch eye$ : Solutions may rxtjlire the outer coating ol tbc cornca.

Inhaled : Moderately irritating to tlic nrsrl membrane.

Ingcstcd Permitted food additive. Litrgc doses rnriy cnuse currusion of thc niucnus meinbranc of the gastrointestinal tract.

Long Tenn Exposurc : Prolonged repeated expogure may cause ulceration of the nasal aeptiim, prngresaing to perforstioir rnd In time, to coniplete destruction of thc nasal cartilage.

+.NI_

SECTTON 7 FlRST AID MEASURES Skln C:onracr : H C ~ O V C cont,qtnmrtea clothing and wash sfre&-& nrca wit11

copious quaittitics of water.

Eyc ContaGt : Immediately irrigate with wrtcr lor at lersr 15 minutes. Seck medical attention if irritation m t l hiflaiiiuihtioii persists.

Rernuvo patient to freeh air, lceop \vam rnd nL rcst. Seek medical ettention.

lngestion : Do not induce vomiting. Give copious quantities of water to drink. Obtain medical attcntion,

Pirrthet Medical Advice : If in doubt seek medial attention. Medical advise may be required fur eye injury nr akin lesions hut these conditions sbollld respond to :rppropriate local medication.

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B a

Would any matcrial saturated with this product be subjcct to

Y

-.- YES Mtutlials :

NO X

G1

-- ... . .

--. --4 SECTION 9 PERSONAL PROTECTION

General Precautions : Lye and skin protcction should bc used wlieu Imidliug Sodium Carbnnatc.

UUWIII.

Ventilation Requirements : Respiratory Protection : None Avoid dust weer n brcutbing mnrk.

‘ U

Protective Clothing (;loves and overalls should be worn,

U

-- 1 Eye protection : Coggles or MI face mrsk

G3 1-3

.. .. . ..,...’. r.... . ...... .

SECTlON 8 . FIRE AND EXPLOSIVE UZAR”D DATA

HANDLTNG ANTI STORAGE - - _.------- -__._ .

I lrurdling : Avoid contact with skin and cycs Avoid inhalation Keep away from Aluminium and its olloys.

/--

Material should be stored ambient temperature is A slow change known BS weathering due to absorption of water and carbon dioxide from the atmosphere cnuses calcmg rncr lump formation.

Storagc :

SECTTON 11 SPILLAGE/ACCLDENTAL RELEKSE

Stnall Spillnge. ! Wash r w r y with L rge quantities of water, or sweep up and place in receptacle for future dispmal,

Swcep up and remove: to properly designated land fill. Inform tlrc b i i c e nnd local authority Immediately if prvduct has entered public drains or waterworks.

Pcrsonal Precautions :

Neutralising Chemicals : Not specified.

Weilr full protective clothing including hrcrthing rpyaratiis.

-”.A_-,

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B

UN No. NR

IMDG Class

I SECTION 12 WASTE DISPOSAL I

UN PAck. Group

AnWRJD Class AI3lUF&ID Ttcni

ICACJflAT A C,l&?S ...- ", .

iccordiag to local regulations. ---i . h P

SECTTON 13 ENVTRONMENTAL INFORMATION

' fhvirotlmental Pate and6stributioh lfigh tonnage nirtcrial produced In wholly contained syyfcnis.

High toiinagc niatcrial used in partially contailed systems. 'lhc substmoc is soluble in wrtor.

Vlnlikdy tn raiiw harmfiil effwtp. Persistence and Degradation

Toxicity No scute toxicity.

Effect on Effluent Treatment Used for pH adjustment in effluent treatment.

. . .

I

SECTlON 14 REGULATORY INFORMATION - .

I Risk Phrases : I-- Safe& Phrases : Keep out of reach of chiltfren (S21

In case of contact with eyes, Rinse immediately with plenty of water atid seck medical advise. 626).

SECTION 16 OTHER INFO-~~ATION

The information provided in this Safety Dab Sheet is correct to the best of our knowledge. information and bclief at thc dak ofils publicition. The information givm is dcsigncd only as B guidance for safe handling, we, processhkg, storage, transportation, disposal and r&ase, md is no1 to bc considcred a w a m t y or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any uthcr materials or in m y process Lmlw specitied in the text.

_I_

According to Ec Directive 91/155/EEC Pige 4 uf 4

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Ref; MXWA02. Rev: 2 I 5/1 O/W

SECTION 5 STABILTTY AND REACTIVITY

Sttibility Conditions to Avoid

Incompfilibilily (Miikricils cancl Condilions to Avoid) Some oxidiriirg ngcnts. eg Chlorites and Hypochlorites. Attacks most metals libernting ti ydmgcn.

nwardous I’lecomposition Products Coalcl emit toric oxides or Sulphur when heated to decomposition.

SECTION 6 . TOXlClTY DATA

Aculc cll~cu: ofover oxposirre when ;

In wnlrul with skin Irritant - after prolonged cnntact with skin prnduces snres and possible dermatitis.

In conlwt with eye5 : Irritates immcdiatcly and could cause severe damage which could kat1 to permanent visual defects or even tots1 loss of vision.

lnhulcd :

Ingested :

May cause irritation to the mucous membrnne of Hic respirrlory tract.

Very astringent to mouth, nose and thrunt, normally followed by -rapid expectoration.

Long Tcrm Exposure; Aluminium accumulates in the brain tissue, resulting in seizuras and brain dysfunction.

Tnxicity nata: I .lh iiZMm&/kg (Oral-Mnara)

Skin Cunlucl : Rcmovc contaminated clothing and wash nffcctcd area with copious quantititn nf water. Seek nredicol sdvice IP irritation ycrsists.

Immediately irr ipte with water for at least 10 minutes. LSceR meareal attention,

Eye Contact ;

Iiihnlatioii . fngestion :

Remuve tu fresh air, IWMU clulliiiig arid seek i i r l x l i a l advice.

Provided patient is conscious wnsh out rnoutfi with wnicr and give Sa! Sodiirm Bicarbonate solution followed by I dr?nwilrr?nt rarh 3- milk. .%ck m e d i d advim immedintrly

Further Medical Advice : If in doubt seek medical attcrttion.

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Worrld m y material sahmUed with lhiv prodlid bc subjcct to spontaneous combustion ?

Rd’: MYDS/A07. Kcv: 2 IS/IO/O~

YES Materials :

NO X

I SECTION 8 FIRE AND EXPLOSIVE HAZARD DATA I

Ventilation Itequirements : None

Prottr:tiva rlltrlhing CIovcs and Acid resistant foohvenr are essenthl.

- -- I<espiratniy Yrntcction : Wear dusk mnak.

Fyc pmt(:t.tinn *

<;ogles or full facc mask.

amounts of water.

Wear full protective clothing. I:ire Pighting I’mtective Equipment

_--- SECTION 10 HANDLING AND STORAGE

I-landling : Avoid contact with skin and eyes Keep away Luur metals, uqiiuir: iualariils, uitmtes, eliluntcs carbides.

-I..

Storage : No special handling equipment. Minimire production of durt-

1 Inusual Fiw and Explosive Hazards In contrct with metals. Alumidium Sulfate may liberate thc flammable xas Hydrogen.

__I

SECTION 9 PERSON AI, PROTECTTON

SECTTON 1 1 SPILLAGE/ACCTDENTAL RELEASE ,. .....a-.

Small Spillrye :

Large Spillagc :

Wash sway with hrgc qiiantitias of water.

Nentralise with Lime or Soda Ash then dispose of according to Iiiuul regubliiiiis. Wvbr CYII be used ilwsshings can gv tu rh ln .

Wenr full protective clothing, Parmoal Prwautinnr, :

Acmdina tn EC Directive OIIISSRFC r 4 c 3 fir 4

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. . . - - . - . . -. .. . . . -. . . . . . . . . . . . . . . . . -. . . .. - -. - . . -

IMDGClass NR

13

ADlURlD Class NR ADI~/IU> Item

,

arid belidat the dale: d i t h publiuttiini. Tllc ilifoiliiatiuii givcii is dcsigild u d y a +.~IIILX Tur d e hnndling, use, processing, storage, transportation, disposal and release, and is not to he considered a wurrunty or quitlily SpipLurifiuation. The inlbrmiuion relates only LO the cpeoilio mattoriul Josignut~.d unci may not be valid for such mulcriol uscd in combinulion wilh uny othcr malcnltls or in any proccss iinlrqq qw.rificC1 iii thP text

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SECTION 12 WASTE DISPOSAL

Ncritrslise with Lime and lmdfill hi accorfhncc with Local Regulatiuns.

SECTION 13 ENVIRONMENTAL TNFORMATlON

I :nvitnnniental Face and Distribution High tonnage nirterirl produeetl in wholly contained systems. High tonnage material used in partially contained systems. '1 ht substancc 1s soiiiblc tn water.

Unllkely TO cause harmful eacrs. Remnins indefinitely ia the environment IS Ilydroxida

Large discharges may contribute to the ncidification af watcr and soil arid will injure nqrwtic lido and soil micra - orpnkms.

Persistence and kgmdalion

Toxicity

liffect on Effluent 'I'mttnent Large dbchrrges may contribute to the acidification of emuent treatment systems and will injure treatment oixanisms. The product is n primary caegulnnt and may cnnse solid settlement in treatment systcrns.

SECTION 14 'mCULATORY IN'FORMATION

IXC Classificatim: Irritant

Riek Phrasw

Safety I'hra.eq !

Ilazard Symbol: Xi

Risk uf serious dumrEe to eyes (R4l).

In crse'of contact with eyw. rinse immediately with plcnty (IC water rnrl seck mecticnl advise. (S 26).

htbr contact with skid, wash immcdintcly wilh plenty of water. (S 28).

Wear suitable gloves (S 37)

SECTION 15 TRANSPORT INFORMATION

UN No. NR I UN Pock. Group I ICAOAATA Cfuan: NIX

7 -I._ ..I .-- )--- OTHER iNFORMATlON

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