FORM-I
for
PROPOSED EXPANSION OF SPECIALTY CHEMICALS, BULK
DRUGS, BULK DRUG INTERMEDIATES MANUFACTURING
AND PESTICIDES FORMULATION UNIT
of
M/s. WANKSONS CHEMICAL INDUSTRIES PVT. LTD.
Plot No. 518, GIDC Industrial Estate, Panoli - 394 116,
Taluka: Ankleshwar, Dist. Bharuch, Gujarat, INDIA.
NABL Accredited Testing Laboratory
ISO 9001:2008 Certified Company
Aqua-Air Environmental Engineers P. Ltd.
403, Centre Point, Nr. Kadiwala School, Ring
Road, Surat - 395002
Prepared By:
NABL Accredited Testing Laboratory
ISO 9001:2008 Certified Company
Aqua-Air Environmental Engineers P. Ltd.
403, Centre Point, Nr. Kadiwala School, Ring
Road, Surat - 395002
NABL Accredited Testing Laboratory
ISO 9001:2008 Certified Company
Aqua-Air Environmental Engineers P. Ltd.
403, Centre Point, Nr. Kadiwala School, Ring
Road, Surat - 395002
Prepared By:
APPENDIX I
FORM 1 (I) Basic Information
Sr.
No.
Item Details
1. Name of the Project/s M/s. Wanksons Chemical Industries Pvt. Ltd.
2. S. No. in the Schedule 5(f)
3. Proposed capacity / area / length /
tonnage to be handled/command
area/lease area/number of wells to be
drilled
• Existing Production Capacity:
� Specialty Chemicals & Bulk Drug Intermediates:
286 MT/Month
� Pesticides Formulation: 1150 MT/Month
• Total Production Capacity after Proposed
Expansion:
� Specialty Chemicals, Bulk drugs & Bulk Drug
Intermediates: 576 MT/Month
� Pesticides Formulation: 1150 MT/Month
- Reference: Annexure-1.
• Total Plot Area: 10,290 m2
• No bore well is and will be drilled within the
premises.
4. New/Expansion/Modernization Expansion
5. Existing capacity/area etc. • Existing Production Capacity:
� Specialty Chemicals & Bulk Drug Intermediates:
286 MT/Month
� Pesticides Formulation: 1150 MT/Month
• Existing Plot Area: 10,290 m2
6. Category of project i.e. ‘A’ or ‘B’ ‘A’
7. Does it attract the general condition?
If yes, please specify.
Yes. Located within 5 km of critically polluted area
(Ankleshwar).
8. Does it attract the specific condition?
If yes, please specify.
No.
9. Location
Plot/Survey/Khasra No. Plot. No. 518
Village GIDC Industrial Estate, Panoli - 394 116
Tehsil Ankleshwar
District Bharuch
State Gujarat
10. Nearest railway station/airport along
with distance in kms.
By road distance:
Nearest Railway Station: Panoli = 2.5 km (approx.)
Nearest Airport : Surat = 60 km (approx.)
11. Nearest Town, city, District
Headquarters along with distance in
kms.
By road distance: Nearest Town : Panoli = 2 km (approx.)
Nearest District Head Quarter : Bharuch = 15 km
(approx.)
12. Village Panchayats, Zilla Parishad,
Municipal corporation, Local body
(Complete postal addresses with
telephone nos. to be given)
Notified Area Authority, Panoli
13. Name of the applicant M/s. Wanksons Chemical Industries Pvt. Ltd.
14. Registered address Plot. No. 518, GIDC Industrial Estate, Panoli -394 116,
Tal: Ankleshwar, Dist: Bharuch, Gujarat.
15. Address for correspondence:
Name Mr. Indrasinh H. Parmar
Designation (Owner/Partner/CEO) GM (Production)
Address M/s. Wanksons Chemical Industries Pvt. Ltd.
Plot. No. 518, GIDC Industrial Estate, Panoli -394 116,
Tal: Ankleshwar, Dist: Bharuch, Gujarat.
Pin Code 394 116
E-Mail [email protected]
Telephone No. Tel: +91-7490032431/9427178117
Mob.: +91 9724302128
Fax No. --
16. Details of Alternative Sites examined,
if any location of these sites should be
shown on a topo sheet.
No
17. Interlinked Projects No
18. Whether separate application of
interlinked project has been
submitted?
No interlinked project has been submitted.
19. If Yes, date of submission Not applicable
20. If no., reason Not applicable
21. Whether the proposal involves
approval/clearance under: If yes,
details of the same and their status to
be given.
(a) The Forest (Conservation) Act,
1980?
(b) The Wildlife (Protection) Act,
1972?
Not applicable as proposed expansion activity will be
within GIDC Industrial Estate, Panoli, Taluka
Ankleshwar, Dist. Bharuch, Gujarat.
(c) The C.R.Z Notification, 1991?
22. Whether there is any Government
order/policy relevant/relating to the
site?
No
23. Forest land involved (hectares) No
24. Whether there is any litigation
pending against the project and/or
land in which the project is propose to
be set up?
(a) Name of the Court
(b) Case No.
(c) Orders/directions of the Court,
if any and its relevance with the
proposed project.
No
(II) Activity
1. Construction, operation or decommissioning of the Project involving actions, which
will cause physical changes in the locality (topography, land use, changes in water
bodies, etc.)
Sr.
No.
Information/Checklist confirmation Yes
/No?
Details thereof (with approximate
quantities / rates, wherever possible)
with source of information data
1.1 Permanent or temporary change in land
use, land cover or topography including
increase in intensity of land use (with
respect to local land use plan)
No --
1.2 Clearance of existing land, vegetation
and buildings?
No --
1.3 Creation of new land uses? No Land is for industrial purpose. Proposed
expansion activity will be carried out
within existing site which is located on
level ground does not require any land
filling for area grading work.
1.4 Pre-construction investigations e.g. bore
houses, soil testing?
No As any kind of construction activity won’t
require in proposed expansion activity,
pre-construction investigations are not
required.
1.5 Construction works? No No, any kind of construction works is not
required. Existing infrastructures and
ancillary facilities are adequate for
proposed expansion activity.
- Reference: Annexure - 2.
1.6 Demolition works? No --
1.7
Temporary sites used for construction
workers or housing of construction
workers?
No --
1.8 Above ground buildings, structures or
earthworks including linear structures,
cut and fill or excavations
No As existing infrastructures are adequate
for proposed expansion activity, no kind of
excavation work is required.
- Reference: Annexure - 2.
1.9
Underground works including mining or
tunneling?
No --
1.10 Reclamation works? No --
1.11 Dredging? No --
1.12 Offshore structures? No --
1.13 Production and manufacturing
processes?
Yes Reference: Anneure-3.
1.14 Facilities for storage of goods or
materials?
Yes Existing storage facilities/area is available
as an existing infrastructure for storage of
existing raw materials, finished products,
hazardous/solid wastes, etc.
Existing infrastructure for storage of raw
materials, finished products,
hazardous/solid wastes, etc. are adequate
for storage of additional raw materials,
finished products, hazardous/solid wastes,
etc.
1.15
Facilities for treatment or disposal of
solid waste or liquid effluents?
Yes • Water consumption & Waste water
generation details
– Reference: Anneure-4.
• Effluent Treatment Plant details
– Reference: Anneure-5.
• Hazardous/Solid wastes generation and
disposal mode details
– Reference: Anneure-6.
1.16
Facilities for long term housing of
operational workers?
No --
1.17 New road, rail or sea traffic during
construction or operation?
No --
1.18 New road, rail, air waterborne or other
airports etc?
No The proposed expansion activity will be
carried out within existing site located in
well developed Industrial Estate having all
infrastructural facilities. Existing
transportation system is adequate too.
1.19 Closure or diversion of existing
transport routes or infrastructure
leading to changes in traffic
movements?
No --
1.20 New or diverted transmission lines or
pipelines?
No --
1.21
Impoundment, damming, converting,
realignment or other changes to the
hydrology of watercourses or aquifers?
No --
1.22 Stream crossings? No --
1.23
Abstraction or transfers or the water
form ground or surface waters?
Yes • No ground water is and shall be used.
• Raw water requirement is met through
GIDC water supply and will be met
through same source after proposed
expansion.
1.24
Changes in water bodies or the land
surface affecting drainage or run-off?
No --
1.25
Transport of personnel or materials for
construction, operation or
decommissioning?
Yes Transportation of personnel or raw
materials/finished products is primarily by
road only & it will be done through the
same way after proposed expansion.
1.26 Long-term dismantling or
decommissioning or restoration works?
No --
1.27 Ongoing activity during
decommissioning which could have an
impact on the environment?
No --
1.28
Influx of people to an area in either
temporarily or permanently?
No --
1.29 Introduction of alien species? No --
1.30 Loss of native species of genetic
diversity?
No --
1.31 Any other actions? No --
2. Use of Natural resources for construction or operation of the Project (such as land, water,
materials or energy, especially any resources which are non-renewable or in short supply):
Sr.
No
Information/checklist confirmation Yes/
No?
Details there of (with approximate
quantities/rates, wherever possible) with
source of information data
2.1 Land especially undeveloped or
agriculture land (ha)
No --
2.2 Water (expected source & competing Yes • Raw water requirement is met through
users) unit: KLD GIDC water supply and will be met
through the same source after proposed
expansion.
• Water consumption & Waste water
generation details
– Reference: Anneure-4.
2.3 Minerals (MT) No --
2.4
Construction material - stone,
aggregates, sand / soil (expected source
MT)
No --
2.5 Forests and timber (source - MT) No --
2.6
Energy including electricity and fuels
source, competing users Unit: fuel (MT),
energy (MW)
Yes Reference: Anneure-7.
2.7 Any other natural resources (use
appropriates standard units)
No --
3. Use, storage, transport, handling or production of substances or materials, which could be
harmful to human health or the environment or raise concerns about actual or perceived
risks to human health.
Sr.
No.
Information / Checklist confirmation Yes/
No?
Details thereof (with approximate
quantities / rates wherever possible) with
source of information data
3.1 Use of substances or materials, which are
hazardous (as per MSIHC rules) to human
health or the environment (flora, fauna,
and water supplies)
Yes
Reference: Annexure -8.
3.2 Changes in occurrence of disease or
affect disease vectors (e.g. insect or
water borne diseases)
No --
3.3 Affect the welfare of people e.g. by
changing living conditions?
No --
3.4
Vulnerable groups of people who could
be affected by the project e.g. hospital
patients, children, the elderly etc.,
No
--
3.5 Any other causes No --
4. Production of solid wastes during construction or operation or decommissioning
MT/month)
Sr.
No.
Information/Checklist confirmation Yes/
No?
Details thereof (with approximate
quantities / rates, wherever possible)
with source of information data
4.1 Spoil, overburden or mine wastes No --
4.2
Municipal waste (domestic and or
commercial wastes) No --
4.3
Hazardous wastes (as per Hazardous
Waste Management Rules)
Yes Reference: Anneure-6.
4.4 Other industrial process wastes Yes Reference: Anneure-6.
4.5 Surplus product No --
4.6
Sewage sludge or other sludge from
effluent treatment
Yes Reference: Anneure-6.
4.7 Construction or demolition wastes No --
4.8 Redundant machinery or equipment No --
4.9 Contaminated soils or other materials No --
4.10 Agricultural wastes No --
4.11 Other solid wastes Yes Reference: Anneure-6.
5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr)
Sr.
No.
Information/Checklist confirmation Yes/
No?
Details thereof (with approximate
quantities/rates, wherever possible) with
source of information data
5.1 Emissions from combustion of fossil
fuels From stationary or mobile sources
Yes Reference: Annexure -9.
5.2 Emissions from production processes Yes Reference: Annexure -9.
5.3 Emissions from materials handling
including storage or transport.
Yes • Raw materials receive in
drums/carboys/bags/tankers and handled
in closed charging system with proper
ventilation and charged through close
pipeline in to reactors/treatment units. It
will be done through same way after
proposed expansion.
• Thus there won't be any kind of emission
through storage and transport.
5.4 Emissions from construction activities
including plant and equipment
No --
5.5
Dust or odours from handling of
materials including construction
materials, sewage and waste
No --
5.6 Emissions from incineration of waste No --
5.7 Emissions from burning of waste in
open air (e.g. slash materials,
construction debris)
No --
5.8 Emissions from any other sources No --
6. Generation of Noise and Vibration, and Emissions of Light and Heat:
Sr.
No.
Information/Checklist confirmation Yes/
No?
Details there of (with approximate
Quantities /rates, wherever possible) With
source of source of information data
6.1
From operation of equipment e.g.
engines, ventilation plant, crushers
Yes • There are few activities due to which noise
generates. The equipments resulting in
noise generation are machineries of plant
and diesel generator. Adequate noise
controls measures are provided.
• Proper and timely oiling, lubrication and
preventive maintenance is carried out for
the machineries & equipments to reduce
noise generation.
• Use of PPEs like ear plugs and ear muffs are
made compulsory near the high noise
generating machines.
• Noise monitoring is done regularly in plant
area.
• D.G. Set is installed in a closed room and
provided with acoustic enclosure.
• Above system will be followed after
proposed expansion to prevent/reduce
noise to be generated.
• The unit has developed plantation within
the premises which helps to prevent the
noise pollution within site as well as
surrounding area.
6.2 From industrial or similar processes Yes • All machinery/equipment is well
maintained, have proper foundation with
anti vibrating pads wherever applicable and
thus, noise levels is within permissible
limits.
• An acoustic enclosure is provided for D.G.
set.
• Above system will be followed after
proposed expansion to prevent/reduce
noise to be generated.
6.3 From construction or demolition No --
6.4 From blasting or piling No --
6.5 From construction or operational traffic No --
6.6 From lighting or cooling systems No --
6.7 From any other sources No --
7. Risks of contamination of land or water from releases of pollutants into the ground or
into sewers, surface waters, groundwater, coastal waters or the sea:
Sr.
No
Information/Checklist confirmation Yes/
No?
Details thereof (with approximate
quantities / rates, wherever possible) with
source of information data
7.1
From handling, storage, use or spillage
of hazardous materials
Yes • All hazardous materials are stored safely &
separately in designated storage area.
• Dyke walls are provided around
raw/hazardous materials storage tanks.
• Materials stored in bags / drums keep on
pallets with concrete flooring and company
takes preventive action for no spillage likely
to occur.
• Above system will be followed after
proposed expansion.
• Reference: Annexure -8.
7.2
From discharge of sewage or other
effluents to water or the land
(expected mode and place of
discharge)
Yes Sewage is disposed of through septic
tank/soak pit & to be done through same
way after proposed expansion.
7.3
By deposition of pollutants emitted to
air into the land or into water
No --
7.4 From any other sources No --
7.5 Is there a risk of long term build up of
pollution in the environment from
these sources?
Yes
• Environmental Management System (EMS)
is installed i.e. ETP, Air Pollution Control
systems, Hazardous Waste Handling and
Management system as per rules, etc.
which eliminates the possibility of building
up of pollution.
• In proposed expansion activity, additional
EMS will be implemented, if required.
8. Risks of accident during construction or operation of the Project, which could affect
human health or the environment:
Sr.
No
Information/Checklist confirmation
Yes/
No?
Details thereof (with approximate
quantities / rates, wherever possible) with
source of information data
8.1 From explosions, spillages, fires etc.
from storage, handling, use or
production of hazardous substances
Yes Reference: Annexure -8.
8.2 From any other causes No --
8.3 Could the project be affected by natural
disasters causing environmental damage
(e.g. floods, earthquakes, landslides,
cloudburst etc)?
No --
9. Factors which should be considered (such as consequential development) which could lead
to environmental effects or the potential for cumulative impacts with other existing or
planned activities in the locality
Sr.
No.
Information/Checklist confirmation Yes/
No?
Details thereof (with approximate
quantities / rates, wherever possible) with
source of information data
9.1 Lead to development of supporting.
laities, ancillary development or
development stimulated by the project
which could have impact on the
environment e.g.:
* Supporting infrastructure (roads,
power supply, waste or waste water
treatment, etc.)
• housing development
• extractive industries
• supply industries
• other
Yes • Plot is located within GIDC, Panoli, Taluka:
Ankleshwar, having entire required
infrastructural facility i.e. road
infrastructure, water supply, power supply,
etc.
• Local people are employed and no housing
is required.
• Reference: Annexure – 10.
9.2
Lead to after-use of the site, which
could have an impact on the
environment
No
--
9.3 Set a precedent for later developments No --
9.4 Have cumulative effects due to
proximity to Other existing or planned
projects with similar effects
No --
(III) Environmental Sensitivity
Sr.
No
Information/Checklist confirmation Name /
Identity
Aerial distance (within 25 km). Proposed
Project Location Boundary.
1 Areas protected under international
conventions national or local
legislation for their ecological,
landscape, cultural or other related
value
No Plot is located in GIDC, Panoli, Taluka:
Ankleshwar, Dist. Bharuch, Gujarat.
2 Areas which are important or sensitive
for Ecological reasons - Wetlands,
watercourses or other water bodies,
coastal zone, biospheres, mountains,
forests
No Plot is located in GIDC, Panoli, Taluka:
Ankleshwar, Dist. Bharuch, Gujarat.
3 Areas used by protected, important or
sensitive species of flora or fauna for
breeding, nesting, foraging, resting,
over wintering, migration
No Plot is located in GIDC, Panoli, Takula:
Ankleshwar, Dist. Bharuch, Gujarat.
4 Inland, coastal, marine or
underground waters
Yes • Sea Coast : 20 Km (approx.)
• River Narmada : 14.6 Km (approx.)
• Amla Khadi : 5.5 Km (approx.)
5 State, National boundaries No --
6 Routes or facilities used by the public
for to recreation or other tourist,
pilgrim areas.
No --
7 Defense installations No --
8 Densely populated or built-up area Yes Ankleshwar city: 2 Lakh population
(approx.)
9 Areas occupied by sensitive man-
made land community facilities)
No
10 Areas containing important, high
quality or scarce resources (ground
water resources, surface resources,
forestry, agriculture, fisheries,
tourism, tourism, minerals)
Yes
• No ground water will be used.
• Plot is located in industrial area & does
not affect agricultural land.
11 Areas already subjected to pollution
or environmental damage. (those
where existing legal environmental
standards are exceeded)
Yes Plot is located in GIDC, Panoli, Taluka:
Ankleshwar, Dist. Bharuch, Gujarat.
12 Are as susceptible to natural hazard
which could cause the project to
present environmental problems
(earthquakes, subsidence ,landslides,
No --
flooding erosion, or extreme or adverse
climatic conditions)
IV). Proposed Terms of Reference for EIA studies: Please refer Annexure – 11.
23/05/2017
ANNEXURES
ANNEXURE
NO.
PARTICULARS
1 List of Products with their Production Capacity and Raw Materials Consumption
2 Plot layout
3 Brief Manufacturing Process Description
4 Details of water consumption & waste water generation
5 Description of Effluent Treatment Plant
6 Details of Hazardous/Solid Wastes Generation, Management and Disposal Mode
7 Power and Fuel Requirement
8 Hazardous Chemicals Storage and Handling Details
9 Details of Sources of Emissions and Air Pollution Control Equipments (APCM)
10 Socio - Economic Impacts
11 Proposed Terms of References
12 Copy of Land Possession/Plot Allotment Letter
13 Copy of CETP and Spray Dryer Membership Letter
14 Copy of Common TSDF & HWIF Membership Letter
15 Toposheet
16 Copy of GIDC Letter for Water Supply
ANNEXURE – 1
LIST OF PRODUCTS WITH THEIR PRODUCTION CAPACITY
Sr.
No.
Products CAS No. Production Capacity
(MT/Month)
Existing Total after Proposed
Expansion
1 Chloral (Trichloro
Acetaldehyde)
75-87-6 213 400
2 Meta Chloro Propio
Phenone (3-cpp)
936-59-4 10 15
3 Dichlorovos Technical
(DDVP)
62-73-7 20 50
4
3-(Bromo ethyl)-2-chloro-4-
(methyl sulfonyl) Benzoic
Acid (PIA-4)
53250-83-2 25 Nil
5 S-Benzyl O, O Diisopropyl
Phosphorothioate (PIZ)
26087-47-8 10 Nil
6 Dimethyl Amine
Hydrochloride
(DMA - HCl)
506-59-2
10
25 7
Iso Propyl Alcohol
Hydrochloride
(IPA HCL)
7647-01-0
8 Methanolic Hydrochloride 9004-54-0
9 Ethyl Acetate Hydrochloride 5407-04-5 -
10 Ethyl Alcohol Hydrochloride 9004-54-0 -
11 Propionyl chloride 79-03-8 - 24
12 Propiophenone 93-55-0 - 30
13 2-Bromo 3-Chloro
Propiophenone
34911-51-8 - 4
14 3-Methoxy Propiophenone 37951-49-8 - 4
15 3-Hydroxy Propiophenone 13103-80-5 - 4
16 Cyano Acetic Acid 372-09-8 - 10
17 7-Ethyl Tryptophol (7-ETP) 41340-36-7 - 5
18 Closantel Amine 57808-65-8 - 5
Total 286 576
Formulations
19 Fanvalrate 20% EC 51638-58-1 100 100
20 Chloropyriphos 20% EC 2921-88-2 100 100
21 Chloropyriphos 48% EC 2921-88-2 100 100
22 Cypermetherin 25% EC 52315-07-8 100 100
23 Monocrotophos 36% EC 6923-22-4 100 100
24 Cypermetherin 10% EC 52315-07-8 100 100
25 Dichlorovos Technical
(DDVP) 76% EC
62-73-7 100 100
26 2,4,D Ethyl Ester 38% EC 94-75-7 100 100
27 Imida Chlopride 17.8% SL 138261-41-3 100 100
28 Methyl Parathion 50 % EC 298-00-0 100 100
29 Mancozeb 75 % WP 8018-01-7 75 75
30 Acephate 75 % SP 30560-19-1 75 75
Total 1150 1150
LIST OF BY-PRODUCTS WITH THEIR PRODUCTION CAPACITY
Sr.
No.
By-Products CAS No. Production Capacity
(MT/Month)
Existing Total after Proposed
Expansion
1 Regenerated Sulfuric Acid
(72%)
7664-93-9 283.75 533
2 Dilute Hydrochloric Acid (30-
32%)
7647-01-0 656* 1200*
Dilute Hydrochloric Acid
(20%)
0.723** 1.257**
3 Ethyl Chloride 75-00-3 95.83 180
4 Methyl Chloride 74-87-3 2.29# 4.58
#
5 HBr 10035-10-6 6.45 6.45
6 Poly Aluminium Chloride 1327-41-9 7.5 46
(PAC) – 100%
7 Sodium Hypochlorite (10%) 7681-52-9 90 120
8 Spent H2SO4 7664-93-9 90 120
* Existing: (656 - 11.5 = 644.5 MT). 11.5 MT converts to HCl gas & Consumes as raw material in
existing products i.e. DMA – Hydrochloride, IPA HCL and Methaonolic Hydrochloride.
* Total after Proposed Expansion: (1200 – 25 = 1175 MT). 25 MT will be converted to HCl gas
& Consumed as raw material in existing products i.e. 3-CPP, DMA – Hydrochloride, IPA HCL
and Methaonolic Hydrochloride and Propiophenone.
** HCl (20%) converts and to be converted to HCl (30-32%) and sell to actual user.
RAW MATERIAL CONSUMPTION:
Raw Material Consumption Quantity
(MT/MT)
Chloral
Ethyl Alcohol 0.624
Chlorine 1.925
Sulfuric Acid (98%) 1.223
Meta Chloro Propio Phenone (3-cpp)
Benzene 1.078
Aluminium Chloride 0.105
Propionyl Chloride 0.816
Ethylene Dichloride 0.5
Chlorine 0.421
HCl 0.025
Dichlorovos Technical (DDVP)
Chloral 0.668
Tri Methyl Phosphate 0.561
3-(Bromo ethyl)-2-chloro-4-(methyl sulfonyl) Benzoic Acid (PIA-4)
2-Chloro-6-(methyl thio) Toluene (PIO) 0.535
Ethylene Dichloride 2.25
Aluminium Chloride 0.3
Acetyl Chloride 0.25
Methanol 1.5
Hydrogen Peroxide 0.315
Catalyst 0.054
HCl 0.05
Bromine 0.49
ODCB 1.0
S-Benzyl O, O Diisopropyl Phosphorothioate (PIZ)
Ammonium Salt 0.64
Benzyl Chloride 0.36
Toluene 0.33
Dimethyl Amine Hydrochloride
DMA Soln. (40%) 1.11
Dry HCl gas 0.56
Iso Propyl Alcohol Hydrochloride
IPA 0.75
Dry HCl gas 0.25
Methaonolic Hydrochloride
Methanol 0.75
Dry HCl gas 0.25
Ethyl Acetate Hydrochloride
Ethyl Acetate 0.671
Hydrochloric Acid 0.329
Ethyl Alcohol Hydrochloride
Ethyl Alcohol 0.411
Hydrochloric Acid 0.59
Propionyl chloride
Propionic Acid 0.8
Thionyl Chloride 1.46
Propiophenone
Propionyl Chloride 0.76
Benzoic Acid / Benzene 0.91 / 0.74
Catalyst / AlCl3 0.042 / 1.18
2-Bromo 3-Chloro Propiophenone
Bromin Soln. 1.05
3-CPP 0.64
Sodium Thiosulphate Soln. 3.19 KL
MDC 2.78 KL
3-Methxy Propiophenone
3- Chloropropiophenone 1.02
Methanol 0.2
3-Hydroxy Propiophenone
3- Chloropropiophenone 1.12
Sodium Hydroxide 0.27
Cyano Acetic Acid
Mono Chloro Acetic Acid 1.11
NaCN 0.576
H2SO4 1.153
Carbon 0.141
MIBK 1.178
7-Ethyl Tryptophol (7-ETP)
EPH 1.0
2,3-dihydro furan 0.44
Methanol 0.2
Toluene 7.0
Catalyst 0.04
Closantel Amine
4-Chloro Benzyl Cyanide 0.52
4-Chloro 2 Nitro Toluene 0.59
Methanol 0.11
KOH 0.193
NaHS 0.193
Toluene 0.316
Activated Carbon 0.041
Fanvalrate 20% EC
Fanvalrate Tech. 0.225
Solvent 0.61
Emulsifier 0.165
Chloropyriphos 20% EC
Chloropyriphos (T) 0.215
Solvent Aromax 0.725
Emulsifier 0.06
Chloropyriphos 48% EC
Chloropyriphos (T) 0.511
Solvent Aromax 0.409
Emulsifier 0.08
Cypermetherin 25% EC
Cypermetherin (T) 0.27
Solvent Aromax 0.253
Emulsifier 0.478
Monocrotophos 36% EC
Monocrotophos (T) 0.53
Solvent 0.47
Cypermetherin 10% EC
Cypermetherin 0.093
Solvent Aromax 0.384
Emulsifier 0.524
Dichlorovos Technical (DDVP) 76% EC
Dichlorvos 0.83
Solvent Aromax 0.099
Emulsifier 0.07
Dye 0.001
2,4,D Ethyl Ester 38% EC
2,4,D Ethyl Ester 0.4
Solvent Aromax 0.55
Emulsifier 0.05
Imida Chlopride 17.8% SL
Imidachlorprid (T) 0.178
Solvent 0.752
Emulsifier 0.07
Methyl Parathion 50 % EC
Methyl Parathion (T) 0.625
Solvent 0.205
Emulsifier 0.17
Mancozeb 75 % WP
Mancozeb (T) 0.882
Suspensioning Agent 0.06
China Clay 0.0577
Acephate 75 % SP
Acephate 0.75
Acrosol OTB 0.005
Fine Silica 0.245
ANNEXURE-2
PLOT LAYOUT
ANNEXURE-3
BRIEF MANUFACTURING PROCESS DESCRIPTION
Chloral:
Process Description:
Ethyl alcohol charge in to glass line reactor and chlorine is pass under control temp. condition.
HCl gas is being produced as a by-product which further react with ethyl alcohol and ethyl
chloride is being produced. HCl gas is being scrub into series of scrubber and ten in to caustic
scrubber to get ethyl chloride. Ethyl Chloride then condenses in minus temp and cylinders are
being filled to sale as by-product HCl 30% is also being recovered and sale as a by-product.
Chlorinated mass alcoholate is treated with sulfuric acid 98% for getting pure chloral. Sulfuric
Acid is being regenerated as 75% acid and sale as by-product.
Chemical Reaction:
Mass Balance:
Meta Chloro Propio Phenone (3-cpp):
Process Description:
Stage-1:
Friedel Craft Reaction – Charge Benzoic Acid / Benzene and catalyst in GLR and cool at 10-12
0C. Add propionyl chloride slowly keep temperature at <12
0C.
Distillation – Apply vaccum and distill propiophenone.
Stage-2:
Chlorination – Charge required quantity of solvent (EDC) cool to 10 0C then charged reactant
propiophenone and again chilled to 4 0C then start slow addition of catalyst AlCl3 with
controlling temperature after completion of catalyst charging purged chlorine with control rate
and temperature then quench the reaction in dilute HCl maintaining temperature belo 20 0C.
Solvent recovery & Fraction Distillation – Washed neutral organic layer to be taken for
atmosphere solvent recovery after completion of solvent recovery start & complete high
vaccum, high temperature fraction distillation to get dilute MCPP.
Centrifugation – Dilute MCPP is centrifuge to get wet cake of crude MCPP and after drying get
pure product.
Chemical Reaction:
Mass Balance:
Stage-1
506 kg Water
217 kg HCl
795 kg Propiophenone 723 kg
500 kgEthylene
dichloride30-33% HCl solution
55 kg Catalyst-1
421 kg Chlorine
1554 kg
100 kg Water / Ice
25 kg HCl
1679 kg
100 kg Hexane 55 kg
1724 kg
Recover EDC 95% 475 kg
EDC loss 25 kg
Recover Hexane 98% 98 kg
Hexane loss 2 kg
Water Recovered &
Reuse50 kg
Wetcake 1074 kg
Drying loss 74 kg
1000 kg 3CPP
Catalyst-1 recover &
recycle
Sent to centrifuge
if required
Chlorination
Quenching
Centrifuge
Scrubber
Distillation
Drying
Benzoic Acid /
Dichlorovos Technical (DDVP):
Process Description:
Charge chloral required quantity and addition of Trimethyl phosphate slowly at 50 0C. After
addition of TMP charge epichlorohydrine and maintain the reaction mass under vaccum for
about 3 hrs. until impurities are within specification. Then pack the material.
Chemical Reaction:
Mass Balance:
3-(Bromo ethyl)-2-chloro-4-(methyl sulfonyl) Benzoic Acid (PIA-4)
Process Description:
Charge (EDC) in GLR. Check sample for m/c. Charge catalyst cool the mass with CHW up to 10-
15 0C and start addition of Acetyl Chloride. Maintain temp. under stirring and start feeding of
PIA. Stir the mass for 3.0 hrs. at same temp. Send sample for QC. After confirming result quench
the mass in other GLR.
Receive concentrate organic mass from SSR. Charge (catalyst) soln. Apply heating. Do the
addition of H2SO4 by maintaining temp. at 65-65 0C. Give sample after getting result start
cooling transfer mass to GLR. Flush reactor to GLR.
Receive organic mass from GLR in crystallizer. Cool the mass and maintain temp. to 32-35 0C.
Start addition of HCl. Do the sample for pH it should be < 1.0. Do the centrifuging lot. Collect
aqueous in tank for recovery. Give the wash of DM Water. Unload wet cake. Do the drying in
RVD after drying fill up the drums in 50 Kg.
Chemical Reaction:
Mass Balance:
S-Benzyl O, O Diisopropyl Phosphorothioate (PIZ):
Process Description:
Charge PIZ-001 (Ammonium Salt) in GLR maintain temp. 25 to 30 oC by chilling water to adjust
pH by PIZ-002 (HCl) to 6.5 to 6.8 – maintain for 1.3 hr.-charge PIZ-003 & 004 (Toluene and
Benzyl Chloride) – heat the mass upto 80-85 oC – maintain it for 2.3 to 3 hr – send sample for
GC – settle the mass for 1.0 hr at 75 to 8 oC – separate the bottom aqueous – retain organic
mass in GLR – Charge DM water under agitation – settle mass for 1 hr – separate bottom
organic mass in GLR – start vacuum and heating to recovered PIZ-003 (Toluene) by maintain
temp and vacuum – send sample to QC – fill up the drums for final packing.
Chemical Reaction:
Mass Balance:
Dimethyl Amine Hydrochloride:
Process Description:
Take 40 % solution of DMA in GLR and start Dry HCL gas Purging at Room temperature
and adjust pH 5.5 keep 1 hour stirring then distilled Out water from Reaction mixture
after water distillation residual Reaction Mass to be Crystallized . Centrifuge and Dry the
material till moisture level Comes below 0.10 %. Final product will be packed in LDPE Bags
having PVC auto sealed Liner inside.
Chemical Reaction:
(CH3)2.N + HCl(g) (CH3)2.NHCl
Mass Balance:
40 % DMA solution 500 kg Dry HCL gas 250 kg
Wet cake 475 kg
Dry weight 450 kg DMA.HCl
GLR
Crystaliser SSTD
Tray
Dryer
This water will be
feed to scrubber
system 275 kg water
for HCl
Drying Loss 25 kg
Iso Propyl Alcohol Hydrochloride (IPA HCL):
Process Description:
Dry HCL gas is injected to IPA to get IPA HCl and monitoring the Assay by Keeping Law
temperature of Reaction mass. After achieving Desired Results material is packed in HDPE
Drums and sealed with Plaster of Paris.
Chemical Reaction:
(CH3)2.CHOH + HCl(g) CH3.CH2.CH2.OH .HCl
Mass Balance:
IPA Dry HCL gas of chloral
1200 kg plant 400 kg
Assay 18 % to 25 %
As per Demand
GLR
25% IPA.HCl
1600 kg
Methanolic Hydrochloride:
Process Description:
Dry HCL gas is injected to Methanol to get Methaonolic HCL and monitoring the Assay by
Keeping Law temperature of Reaction mass. After achieving Desired Results material is packed
in HDPE Drums and sealed with Plaster of Paris.
Chemical Reaction:
CH3OH + HCl(g) CH3OH .HCl
Mass Balance:
Methanol Dry HCL gas of chloral
1200 kg plant 400 kg
Assay 18 % to 25 %
As per Demand
GLR
25% MeOH.HCl
1600 kg
Ethyl Acetate Hydrochloride:
Process Description:
Dry HCL gas Is injected to Ethylacetate to get Ethylacetate Hydrochloride and monitoring the
Assay by Keeping low temperature of Reaction mass. After Achieving of desire results Material
is packed in HDPE Drums and sealed with Plaster of paris.
Chemical Reaction:
+ HCl (g) C4H8O2 .HCL
C4H8O2 Hydrogen chloride gas Ethylacetate Hydrochloride
Ethylacetate
Mass Balance:
Ethyl Acetate (671 kg)
Hydrochloric acid (329 kg)
Ethylacetate Hydrochloride
(1000 kg)
REACTION
Ethyl Alcohol Hydrochloride:
Process Description:
Dry HCL gas Is injected to Ethyl alcohol to get Ethyl alcohol Hydrochloride and monitoring the
Assay by Keeping low temperature of Reaction mass. After Achieving of desire results Material
is packed in HDPE Drums and sealed with Plaster of Paris.
Chemical Reaction:
C2H5OH + HCl (g) C2H5OH.HCl
Ethyl Alcohol Hydrogen chloride gas Ethyl Alcohol Hydrochloride
M.W. = 46 M.W. = 36.5 M.W = 82.5
Mass Balance:
Ethyl Alcohol (460 kg)
Hydrochloric acid (658 kg)
Ethyl Alcohol Hydrochloride
(1118 kg )
REACTION
Propionyl chloride:
Process Description:
Propionic acid reacted with thionyl chloride produce propionyl chloride and sulfuric acid.
Chemical Reaction:
O
OHCH3 +2
SO2Cl2
O
ClCH32 + H2SO4
Propionic AcidM.W. 74
Thionyl ChlorideM.W. 135
Propionyl Chloride M.W. 92.5
Sulfuric AcidM.W. 98
Mass Balance:
Propionic Acid (296 Kg) H2SO4 (392 Kg)
Thionyl Chloride (540 Kg)
Propionyl Chloride (370 Kg)
REACTION
Propionyl Chloride (900 Kg)
Addition of PC Hcl gas (322kg)
Benzoic acid / Benzene
(1078 kg / 875 kg)
Catalyst / Alcl3
(50 kg / 1400 kg) 30 to32% Hcl Soln Bi product(Qty 976 kg)
Chilled water (250kg) Co2 gas (388 kg)
Catalyst for Re use
Water (250 kg) - Reuse
Propiophenone (1184 kg)
GLR – 301
(3KL)
GLR – 211 (4 KL)
GLR-03 (10 KL)
Quenching
SSR-01 (5 KL)
Distillation (1434 kg)
Scrubber
(Water)
654 kg
C/F (for
Catalyst
Recovery &
Re use)
HDPE Tank-1.5 KL
(Product) - 1434 kg
Propiophenone:
Process Description:
Charge Propionyl chloride and Benzoic acid / Benzene in to GLR. In presence of aluminium
chloride they reaction occur. It generates HCl gas which scrubs in water scrubber. Reaction
mass is quenched with chilled water which further goes for catalyst recovery. Thereafter
distillation is carried out to distilled water and remaining is product.
Mass Balance:
2-Bromo 3-Chloro Propiophenone:
Process Description:
Dissolved 3’-Chloropropiophenone in Dichloromethane and stirring the Reaction mass for 10-15
min.at 25-35°C temperature. Then add prior prepared bromine solution to reaction mass
within 3-4 hours with temperature control.then maintain the reaction mass 45 min.with
temperature control.
Then wash with process water and separate the bottam organic layer in RBF and discard the
aq.layer. then wash with sodium thiosulphate solution and agains separate the bottam organics
layer in RBF and discard the aq.layer. then wash the reaction mass with process water and
separate the bottam organic layer and discard the aq.layer.
Filter the reaction mass through celite bed and wash with Dichloromethane. Then distilled out
dichloromethane atmospherically completely.
Then apply the vacuum for removal of traces of solvent for 45 min. at 50°C and get the final
product 2-Bromo-3’-chloropropiophenone then packed in HDPE drums
Chemical Reaction:
+ Br2 Br + HBr
Cl Cl
Mass Balance:
Bromin soln. 190 kg Process Water 500 lit.
3-CPP 115 kg MDC 460 lit.
Recovery and recycle
Sodium Thiosulphate Aq.layer 550 lit.
Solution 575 lit.
ETP
Process water 500 lit. Aq.layer 575 lit.
ETP
ETP
Aq.layer 575 lit.
MDC 510 lit.
Distilled MDC
510 lit.
180 kg 2-Bromo-3-chloropropiophenone
Reactor
Separator
Reactor
Separator
Reactor
Separator
Organic layer
O
CH3
Cl
3'- ChloropropiophenoneM.W.168.62
C9H9ClO
+ CH3OH
Metanol M.W.32.04
- HCl
3-Methoxy Propiophenone:
Process Description:
3- Chloropropiophenone reacts with methanol generates 3- Methoxy propiophenone and HCl.
Chemical Reaction:
Mass Balance:
3- Chloropropiophenone (674.48 Kg)
Methanol (128.16 Kg) HCl (18.04 Kg)
3’- Methoxy propiophenone (656.08 Kg)
REACTION
3-Hydroxy Propiophenone:
Process Description:
3- Chloropropiophenone reacts with NaOH generates 3- Hydroxy propiophenone and NaCl.
Chemical Reaction:
O
CH3
Cl
+ NaOH
O
CH3
OH
+ NaCl
3'- ChloropropiophenoneM.W.168.62
C9H9ClO
Sodium hydroxideM.W. 40
3'- Hydroxy ChloropropiophenoneM.W.150.12
C9H9O2H
Sodium chlorideM.W. 58.5
Mass Balance:
3- Chloropropiophenone (674.48 Kg)
Sodium hydroxide (160 Kg) NaCl (234 Kg)
3’- Hydroxy Chloropropiophenone (600.48 Kg)
REACTION
Cyano Acetic Acid:
Process Description:
Monochloro acetic acid is taken into reactor. Add water to make liquid. Heat mass to 50 oC.
Then add sodium cyanide cake slowly. Keeping temp. below 70 oC. Check absence of sodium
cyanide by TLC. Also check cyanide content is nil through cyanide test. Once reaction is
completed, cool the mass. The mass is washed with sulfuric acid to remove impurities. Take
organic layer for extraction using MIBK as solvent to receive pure CAA in MIBK leaving sodium
Chloride in aqueous soln. MIBK containing CAA is distilled to remove MIBK. Cool and chill mass
up to 10 oC. Centrifuge pure crystals. Recycle ML for next batch. Dry crystals.
Chemical Reaction:
NaCN + + NaCl
O Cl
OH
O CN
OH
H2SO4
MIBK
Mass Balance:
Charging Vessels
Carbon Treatment
Extraction
ETP
1000 Kg
Solvent Recovery
Crystallizer
C/F
ETP
773 Kg
Mono Chloro Acetic Acid 1110 Kg
NaCN 576 Kg
H2SO4 1153 Kg
Carbon 141 Kg
MIBK 1178 Kg
Recycle
1175 Kg
CAA
1000 Kg
Dyer Loss
210 Kg
NHNH2HCl
O+ DMAC
NH
H2O
OH
+ HCl + NH 3
2-Ethyl phenyl hydrazine HCl 2,3-Dihydrofuran 7-Ethyl Tryptophol
7-Ethyl Tryptophol (7-ETP):
Process Description:
To stirred solution of 2-ethyl phenyl hydrazine HCl and DMAc-H2O. Dropwise add 2,3 dihydro
furan at 25-30 oC. Heat the mass upto 50 oC and stirred for 30 min. Completion of reaction is
monitored by TLC. Add conc. H2SO4 at 50 oC and maintain reaction mass for 3-4 hrs. After
completion of reaction mixure is allowed to cool to RT. Adjust pH 4-5 by using dilute Na2CO3
soln. and then extract with MDC. Crude distilled out and cool to get yellow colour product.
Chemical Reaction:
Mass Balance:
D. M. water 500 lit. EPH 250 kg
2,3-dihydro furan Toluene 1750 lit.
110 kg Methanol 50 kg Catalyst 10 kg
Layer separation
Recovery and recycle
Tar layer 2170 lit. Aq. layer 500 lit.
Toluene 600 lit.
Organic layer Aq. layer 500 lit.
Toluene 2300 lit.
Recycle
Recycle
Inter Cut 140 kg
7-ETP 250 kg
Reactor
Reactor
Separator
Extracture
Solvent recovery
Fractional distillation
Lower cut 80
kg.
Cl
N
+
ClN+
O + CH3OH + KOHCH3OH
+ NaHS
Cl Cl
CN
CH3
NH2
+ O2
4-Chloro Benzyl 4-Chloro-2-nitro- Closantel Amine Cyanide toluene
M.W. 151.59 171.58 291.14 32
C8H6ClN C 7H6ClNO2 C15H12N2Cl2
Closantel Amine
Process Description:
4-Chlorobenzyl Cyanide and 4-Chloro Nitro Toluene is added into reactor. Methanol is added
and heat upto 50 oC. Add solution of hydrosulfite powder as catalyst slowly. Keeping temp
below 50 oC. Add potassium hydroxide flakes into reactor and reflux mass for 12 hrs. Check
completion of reaction. If traces of PCBC seen, further reflux till it is absent. Cool product and
add DM water into it. Stir the product and then centrifuge product. Allow to settle layer.
Remove organic layer and filter mass. Collect filtrate in distillation vessel. Remove toluene by
distillation. Centrifuge the mass. Collect wet cake and dry it.
Chemical Reaction:
Mass Balance:
SS Reactor
4-Chloro Benzyl Cyanide 520 Kg
4-Chloro 2 Nitro Toluene 590 Kg
SS Reactor Methanol 110 Kg
KOH 193 Kg
NaHS 193 Kg
Centrifuge DM Water 62 Kg
SS Reactor Toluene 316 Kg
Activated Carbon 41 Kg
Filter
SS Crystallizer Toluene 311 Kg Recovered
Dryer
Closantel Amine
1000 Kg
Loss 100 Kg
Aq. Layer 573 Kg
Activated Carbon 41 Kg
Fanvalrate 20% EC
Process Description:
Charge solvent & add emulsifier stirr well & charge Fanvalrate [T] to uniform mix for 2.0 hr and
check Q.C. for base & other parameter to pack 200.0 kg net wt.
Mass Balance:
Chloropyriphos 20% EC
Process Description:
Charge solvent & add emulsifier stirr well & charge Chloropyriphos [T] to uniform mix for 2.0 hr
and check Q.C. for base & other parameter to pack 200.0 kg net wt.
Mass Balance:
Chloropyriphos 48% EC
Process Description:
Charge solvent & add emulsifier stirr well & charge Chloropyriphos [T] to uniform mix for 2.0 hr
and check Q.C. for base & other parameter to pack 200.0 kg net wt.
Mass Balance:
Cypermetherin 25% EC
Process Description:
Charge solvent & add emulsifier stirr well & charge Cypermetherin [T] to uniform mix for 2.0 hr
and check Q.C. for base & other parameter to pack 200.0 kg net wt.
Mass Balance:
Monocrotophos 36% EC
Process Description:
Charge solvent stirr well & charge Monocrotophos[T] to uniform mix for 2.0 hr and check Q.C.
for base & other parameter to pack 200.0 kg net wt.
Mass Balance:
Cypermetherin 10% EC
Process Description:
Charge solvent & add emulsifier stirr well & charge Cypermetherin [T] to uniform mix for 2.0 hr
and check Q.C. for base & other parameter to pack 200.0 kg net wt.
Mass Balance:
Dichlorovos Technical (DDVP) 76% EC
Process Description:
Charge solvent & add emulsifier stirr well & charge Dichlorvos[T] to uniform mix & add Dye mix
for 6.0 hr and check Q.C. for base & other parameter to pack 200.0 kg net wt.
Mass Balance:
2,4,D Ethyl Ester 38% EC
Process Description:
Charge solvent & add emulsifier stirr well & charge 2,4,D Ethyl Ester[T] to uniform mix for 2.0 hr
and check Q.C. for base & other parameter to pack 200.0 kg net wt.
Mass Balance:
Imida Chlopride 17.8% SL
Process Description:
Charge solvent & add emulsifier stirr well & charge Imidachlorprid [T] to uniform mix for 2.0 hr
and check Q.C. for base & other parameter to pack.
Mass Balance:
Product 1000 Kg
178 Kg
752 Kg
70 Kg
Methyl Parathion 50 % EC
Process Description:
Charge solvent & add emulsifier stirr well & charge Methyl Parathion [T] to uniform mix for 2.0
hr and check Q.C. for base & other parameter to pack.
Mass Balance:
Product 1000 Kg
625 Kg 205 Kg
170 Kg
Mancozeb 75 % WP
Process Description:
Charge Mancozeb (T), Suspensioning Agent & China Clay in blender, mixed well to uniform mix
for 4.0 hr and check Q.C. for base & other parameter to pack.
Mass Balance:
Product 1000 Kg
Mancozeb (T) 882.3 Kg
Suspensioning Agent 60 Kg
China Clay 57.7 Kg
Acephate 75 % SP
Process Description:
Charge Acephate (T), Acrosol OTB & Fine Silica in blender, mixed well to uniform mix for 4.0 hr
and check Q.C. for base & other parameter to pack.
Mass Balance:
Acephate (T) 750 Kg
Acrosol OTB 5 Kg
Fine Silica 245 Kg
ANNEXURE-4
DETAILS OF WATER CONSUMPTION & WASTE WATER GENERATION
SR.
NO.
DESCRIPTION EXISTING (KL/Day) TOTAL AFTER PROPOSED
EXPANSION (KL/Day)
WATER
CONSUMPTION
WASTE WATER
GENERATION
WATER
CONSUMPTION
WASTE WATER
GENERATION
1 Process 0.01 0.008* 22.5 12.0
2 Boiler 15.0 3.5 15.0 3.5
3 Cooling & Chilling 5.0 1.274 25.0 6.5
4 Washing 1.6 1.6 5.0 5.0
5 Scrubber/APCM 23.09 -- 54.0 --
Total Industrial
44.7 6.382 – 0.008 =
6.374
121.5 27.0
7 Domestic 5.5 5 # 24.5 23.5
#
8 Gardening -- -- 10.5 --
Grand Total 50.2 11.374 156.5 50.5
* Water is reused in process (Product: Meta Chloro Propio Phenone).
# Domestic waste water is & will be disposed of through septic tank & soak pit.
ANNEXURE-5
EFFLUENT TREATMENT PLANT
In existing, M/s. Wanksons Chemical Industries Pvt. Ltd. has an Effluent Treatment Plant (ETP)
of primary treatment (neutralization) facility. Treated effluent sends to Common Effluent
Treatment Plant (CETP) of M/s. Panoli Enviro Technology Ltd. (PETL), Panoli for further
treatment and disposal.
EXISTING ETP FLOW DIAGRAM:
5 KL
Equalization cum
Neutralization Tank
Raw Effluent
5 KL
Equalization cum
Neutralization Tank
5 KL
Equalization cum
Neutralization Tank
Caustic
Filter Press
30 KL
Raw Effluent Storage
Tank
Near 3-CPP Plant
10 KL
Treated Effluent
Storage Tank
10 KL
Treated Effluent
Storage Tank
10 KL
Treated Effluent
Storage Tank
PETL, Panoli
After proposed expansion, M/s. Wanksons Chemical Industries Pvt. Ltd. is going to discontinue
two existing 5 KL Equalization cum Neutralization Tanks and proposes 3 nos. of 60 KL
Equalization cum Neutralization Tanks. Other treatment facilities and disposal mode will remain
same as existing.
PROPOSED ETP FLOW DIAGRAM:
5 KL
Equalization cum
Neutralization Tank
Raw Effluent
Caustic
Filter Press
30 KL
Raw Effluent Storage
Tank
Near 3-CPP Plant
10 KL
Treated Effluent
Storage Tank
10 KL
Treated Effluent
Storage Tank
20 KL
Treated Effluent
Storage Tank
PETL, Panoli
60 KL
Equalization cum
Neutralization
Tank
60 KL
Equalization cum
Neutralization
Tank
60 KL
Equalization cum
Neutralization
Tank
10 KL
Treated Effluent
Storage Tank
ANNEXURE-6
DETAILS OF HAZARDOUS/SOLID WASTE GENERATION, MANAGEMENT AND DISPOSAL
SR.
NO.
TYPE OF WASTE CATEGORY
NO.
QUANTITY MODE OF DISPOSAL
EXISTING
(As per
current
CC&A)
TOTAL
AFTER
PROPOSED
EXPANSION
1 Used oil 5.1 0.008
MT/Month
0.092
MT/Month
Collection, Storage & sell
to MoEF/GPCB approved
vendor.
2 Discarded
Drums/Carboys/
HDPE
Bags/liners
33.1 1.6
MT/Month
(30 #/Month)
92
Nos./Month
Collection, Storage,
Decontamination & sell
to GPCB authorized
vendor.
3 ETP sludge 34.3 0.41
MT/Month
2.91
MT/Month
Collection, Storage &
send to common TSDF
site of M/s. BEIL, or M/s.
SEPPL.
4 Distillation
Residue
36.4 -- 9.16
MT/Month
Collection, Storage &
send to CHWIF of M/s.
BEIL or M/s. SEPPL.
ANNEXURE-7
POWER AND FUEL REQUIREMENTS
• Power Requirement
Sr.
No.
Requirement Source
Existing Total After
Proposed
Expansion
Existing After Proposed Expansion
1. 1000 KVA 1000 KVA • DGVCL (GEB)
• D.G. Set - 1 no.
- 350 KVA capacity
(emergency standby)
• DGVCL (GEB)
• D.G. Sets - 3 nos.
- 350 KVA capacity (1 Nos.)
- 380 KVA capacity (1 Nos.)
- 250 KVA capacity (1 Nos.)
(emergency standby)
• Fuel Requirement
Sr.
No.
Fuel Requirement (to be used in emergency only)
Existing Total After Proposed
Expansion
1. Natural Gas 2290 SM3/day*
(206 SM3/day)**
2490 SM3/day
2. Diesel 90 Liter/hr.*
(20 Liter/hr.)**
235 Liter/hr.
* Actual quantity used
** Typographic error in current CC&A valid up to 4/4/2019.
ANNEXURE-8
HAZARDOUS CHEMICAL STORAGE AND HANDLING DETAILS
Sr.
No.
Name of
Hazardous
chemical
Quantity Places of its
Storage
(Storage
tank
/drums
/cylinders
/barrels)
No. of
Storages
Places of its
Storage State
Type of
Hazards
Control measures
provided Max. that
Can be
Stored
Actually
stored
(Including in
process
& handling)
1. Toluene 10 KL 8 KL Tank 1 Tank Farm
Area
Liquid Flammable/
Toxic
• Closed handling and
transferring systems
for Hazardous
chemicals.
• Dyke walls and
material collection
systems are provided
to all material storage
tanks.
• Fire Extinguishers and
absorbents will be
available near storage
tanks and storage area.
• Drums to be stored on
pallet with the suitable
trap.
2. Methanol 12 KL 12 KL Drums 60 # Storage Area Liquid Flammable
3. Chlorine 900 Kg (60 x 900 Kg) Tonner 60 #
(54 MT)
Storage Area Liquid Flammable
4. Sodium
Methoxide
4 MT 4 MT Bags 80 # Storage Area Liquid Flammable
5. Bromine 3 MT 3 MT Glass Bottle 1000 # Storage Area Liquid Toxic &
Corrosive
6. HCl
(30-32%)
125 KL 125 KL PP Storage
Tank
5 Tank Farm
Area
Liquid Corrosive
7. H2SO4 (98%) 40 KL 40 KL Storage
Tank (20 KL)
2 Tank Farm
Area
Liquid Corrosive
8. Ethyl
Alcohol
330 KL 256 KL Storage
Tank
5 Tank Farm
Area
Liquid Flammable
9. Thionyl
Chloride
5 MT 5 MT Drums 25 # Storage Area Liquid Toxic &
Corrosive
10 Benzene 10 KL 10 KL Tank 1 Tank Farm
Area
Liquid Flammable
11 IPA 10 MT 10 MT Drums 50 # Storage Area Liquid Flammable
12 o-Xylene 1 MT 1 MT Drums 5 # Storage Area Liquid Flammable
13 MDC 3 MT 3 MT Drums 15 # Storage Area Liquid Flammable
ANNEXURE-9
DETAILS OF SOURCE OF EMISSION
Sr.
No.
Stack/Vent attached
to
Stack
Height
(meter)
Stack
Diameter
(meter)
Fuel name &
Quantity
Type of
Emission
APCM
Existing
1 Boiler
(3 TPH)
30 # 0.406 Natural Gas
2290 SM3/day*
(206
SM3/day)**
PM
SO2
NOx
--
2 Process Vent
(Chlorinator &
Distillation Reactor)
13 0.15
-- HCl
Cl2
Existing
Water Scrubbers
(4 Nos.) + Caustic
Scrubber (1 Nos.)
+
Additional (Proposed)
Water Scrubber
(1 Nos.) + Caustic
Scrubber (1 Nos.)
3 Dust Collector
(Power –
Formulation Unit)
20 0.15 -- PM
SO2
NOx
--
4 D.G. Set
(350 KVA)
(Use in emergency
only.)
-- -- Diesel
90 Liter/hr.*
(20 Liter/hr.)**
PM
SO2
NOx
--
Proposed
5 Thermc Fluid Heater
(4 Lac Kcal/hr)
30 # 0.406 Natural Gas
(200 SM3/day)
--
6 D.G. Set
(380 KVA)
(To be use in
emergency only.)
-- -- Diesel
90 Liter/hr.
PM
SO2
NOx
--
7 D.G. Set
(250 KVA)
(To be use in
emergency only.)
-- -- Diesel
55 Liter/hr.
PM
SO2
NOx
--
* Actual quantity used.
** Typographic error in current CC&A valid up to 4/4/2019.
# Common stack between existing boiler and proposed thermic fluid heater.
ANNEXURE - 10
SOCIO - ECONOMIC IMPACTS
1) EMPLOYMENT OPPORTUNITIES
The manpower requirement is expected to generate some permanent jobs and secondary jobs
for the operation and maintenance of plant. This will increase direct/indirect employment
opportunities and ancillary business development to some extent for the local population. This
phase is expected to create a beneficial impact on the local socio-economic environment.
2) INDUSTRIES
Require raw materials and skilled & unskilled laborers will be utilized maximum from local area.
The increasing industrial activity will boost the commercial and economical status of the locality,
to some extent.
3) PUBLIC HEALTH
The company will regularly examine, inspects and tests its emission from sources to make sure
that the emission will keep below the permissible limit. Hence, there will not be any significant
change in the status of sanitation and the community health of the area, as sufficient measures
will be taken under the EMP.
4) TRANSPORTATION AND COMMUNICATION
Since the existing Panoli GIDC estate is having proper linkage for transport and communication,
the development of this project will not cause any additional impact.
In brief, as a result of the proposed project, there will be no adverse impact on sanitation,
communication and community health, as sufficient measures will be proposed to be taken
under the EMP. Hence, proposed project is not expected to make any significant change in the
existing status of the socio - economic environment of this region.
ANNEXURE – 11
PROPOSED DRAFT TERMS OF REFERENCE
1. Project Description
• Justification of project.
• Promoters and their back ground
• Project site location along with site map of 10 km area and site details providing various
industries, surface water bodies, forests etc.
• Project cost
• Project location and Plant layout.
• Infrastructure facilities
• Water source and utilization including water balance.
• List of Products & their production capacity
• Details of manufacturing process of proposed products
• List of hazardous chemicals
• Storage and Transportation of raw materials and products.
2. Description of the Environment and Baseline Data Collection
• Micrometeorological data for wind speed, direction, temperature, humidity and rainfall in 5 km
area.
• Other industries in the impact area
• Prevailing environment quality standards
• Existing environmental status vis a vis air, water, noise, soil in 10 km area from the project site.
• Ground water quality at 5-6 locations within 10 km.
• Complete water balance
3. Socio Economic Data
• Existing socio-economic status, land use pattern and infrastructure facilities available in the study
area were surveyed.
4. Impacts Identification and Mitigatory Measures
• Identification of impacting activities from the proposed project during construction and
operational phase.
• Impact on air and mitigation measures including green belt
• Impact on water environment and mitigation measures
• Soil pollution source and mitigation measures
• Noise generation and control.
• Hazardous/Solid waste quantification and disposal.
• Control of fugitive emissions
5. Environmental Management Plan
• Details of pollution control measures
• Environment management team
• Proposed schedule for environmental monitoring including
6. Risk Assessment
• Objectives, Philosophy and methodology of risk assessment
• Details on storage facilities
• Process safety, transportation, fire fighting systems, safety features and emergency capabilities to
be adopted.
• Identification of hazards
• Consequence analysis
• Recommendations on the basis of risk assessment done
• Disaster Management Plan.
7. Information for Control of Fugitive Emissions
8. Information on Rain Water Harvesting
9. Green Belt Development plan
ANNEXURE – 12
COPY OF LAND POSSESSION / PLOT ALLOTMENT LETTER
ANNEXURE – 13
COPY OF CETP AND SPRAY DRYER MEMBERSHIP LETTER
ANNEXURE – 14
COPY OF COMMON TSDF & HWIF MEMBERSHIP LETTER
ANNEXURE – 15
TOPOSHEET
ANNEXURE – 16
COPY OF GIDC LETTER FOR WATER SUPPLY