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Mike Eastman, Technology Manager National Energy Technology Laboratory SECA Annual Workshop and Core Technology Program Peer Review Boston, MA May 11, 2004 FutureGen FutureGen Electricity, Hydrogen and Carbon Electricity, Hydrogen and Carbon Sequestration from Coal Sequestration from Coal
Transcript
Page 1: FutureGen – Electricity, Hydrogen and Carbon Sequestration from … · 2014. 7. 30. · carbon dioxide emissions from coal power plants, and ... MLE-SECA-051104 Weyburn CO 2 EOR

Mike Eastman, Technology ManagerNational Energy Technology Laboratory

SECA Annual Workshop and Core Technology Program Peer Review

Boston, MA May 11, 2004

FutureGenFutureGen –– Electricity, Hydrogen and Carbon Electricity, Hydrogen and Carbon Sequestration from CoalSequestration from Coal

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Energy Use Compared to Economic Growth

GDP: History - U.S. DOC, Bureau of Economic Analysis; Forecast - Annual Energy Outlook 2004 Energy & Electricity: EIA, Annual Energy Review 2002; Annual Energy Outlook 2004

80120160200240280320360400440480

1970

1975

1980

1985

1990

1995

2000

2005

2010

2015

2020

2025

Inde

x: 1

973

= 10

0

Year

Real GDP

ElectricityGeneration

Total EnergyConsumption

+ 86 BkWh/year

$2.48 GDP/kWh

$3.20 GDP/kWh

$2.12 GDP/kWh

$2.21 GDP/kWh

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MLE-SECA-051104Annual Energy Outlook 2004, Reference Case

Coal Expected To Provide 50% of Incremental kWhs(2003 to 2009) Despite Few Additions

Fuel Mix for Electricity Growth AEO’04

0

1,000

2,000

3,000

4,000

5,000

6,000

7,000

2000 2005 2010 2015 2020

Coal Natural Gas Petroleum Nuclear Power Renewable Sources

Coal 59%of kWh Growth

2010 – 2025

Natural Gas 31%

Bill

ion

Kilo

wa t

t Hou

rs /

Y ea r

Natural Gas 33%

Coal 50%of kWh Growth

2003 – 2009

Coal 56% of Overall

kWh Growth

2003-2025

Was 43% in AEO 2003

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Increasing Natural Gas Price Forecasts

$1.50

$2.00

$2.50

$3.00

$3.50

$4.00

$4.50

$5.00

$5.50

1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 2018 2020 2022 2024

’99’00’01’02

’03

$/M

cf

Annual Energy OutlookPublication Year

’04

AEO 2004 Natural Gas Price Forecasts (Short-term forecasts indicate higher prices)

EIA April 2004 STEO(wellhead price forecast)

+ 30%2004 +42%

2005

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Natural Gas / Coal Competition

Increasing Desire for Energy Security0

1

2

3

4

5

6G

as p

rice

$ /

MM

Btu

Gas wins

Coal wins

• Coal wins short-term dispatch• Gas wins long-term capacity share

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Changing Natural Gas Generation ForecastsParadigm Shift in Fuel Use for Electricity

500600700800900

1,0001,1001,2001,3001,4001,5001,6001,7001,8001,9002,000

2001 2003 2005 2007 2009 2011 2013 2015 2017 2019 2021 2023 2025

’01

’02 ’03

BkW

h/Ye

ar

Annual Energy OutlookPublication Year

’04

Gradual Recognition of Natural Gas Supply ConstraintsThree Year Decline (2020) Nearly Equal to Today’s Gas kWh Production

47% More Than ‘04

- 600BkWh

Reduced Estimate Now Supported by Substantial Increase in LNG Imports

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Changing LNG Import ForecastsShift in Imported Fuel for Gas-fired Generation

0.1

0.6

1.1

1.6

2.1

2.6

3.1

3.6

4.1

4.6

2001 2003 2005 2007 2009 2011 2013 2015 2017 2019 2021 2023 2025

’02

’03

Tcf/Y

ear

’04

Rapid Increase in LNG Supply AssumptionSupports Natural Gas Generation Potential

+ 3.3 Tcf 500% increase

+ 2.6 Tcf

Annual Energy Outlook 2002, 2003 and 2004

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North American LNG Regasification Terminals

A

C

1 3 4

28

27

6

18

20

5

11

21

12

197

14

B

D

16

17

9

28

30

29

31

10

15

22232425

2631

333413

35

FERC, December, 2003

ExistingProposed

• 4 existing terminals• 32 active proposals• 15 Tcf if all built• None under

construction• 7-year construction

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Dramatically Changed Perspectives On Infrastructure Security

Is It Safe?, Boston Globe, July 27, 2003

Tanker Docked at Everett, Massachusetts

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0

1

2

3

4

1970 1980 1990 2000

Coal Use

Contaminant Emissions Down SharplyU.S. Power Plants

Inde

x: 1

970

= 1.

0

ElectricityGeneration

Nitrogen Oxides

Sulfur DioxideParticulateMatter

Natural Gas Use

EPA, National Air Quality and Emissions Trends Report, 1999 (March 2001)DOE, EIA Annual Energy Review

Year

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Cradle to Grave: The Environmental Impacts from Coal,Clean Air Task Force, Boston, MA,June 2001

Broad Environmental Concerns About Coal

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Comparison of Emissions Between IGCC and other Coal-Fired Technologies

0

2

4

6

8

10

12

IGCC Plant(without SCR)

AFBC Plant (with SNCR) PFBC Plant (withoutSNCR)

PC-Fired Plant with FGD& SCR

SO2 (lb/MWh) NOx (lb/MWh) PM10 (lb/MWh)CO2 (10E-3 lb/MWh) Total Solids , (10E-2 lb/MWh)

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February 27, 2003FutureGen Initiative --“…the United States will sponsor a $1 billion, 10-year demonstration project to create the world's first coal-based, zero-emissions electricity and hydrogen power plant …”

Presidential Initiatives

January 28, 2003Hydrogen Fuel Initiative – “Tonight I’m proposing $1.2 billion in research funding so that America can lead the world in developing clean, hydrogen-powered automobiles.”

February 14, 2002Clear Skies Initiative -- calls for “… new tough standards to dramatically reduce the three most significant forms of pollution from power plants, sulfur dioxides, nitrogen oxides, and mercury.”

Climate Change Initiative – “will set America on a path to slow the growth of our greenhouse gas emissions and, as science justifies, to stop and then reverse the growth of emissions.”

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FutureGen• Integrated Sequestration,

Hydrogen, and Power Research Facility

All ProgramAll ProgramElements Elements SupportSupport

Presidential Presidential InitiativesInitiatives

Demonstration Program• Clean Coal Power Initiative

Elements of Coal & Power Program

Core R&D Program• Innovations for

Existing Plants• FutureGen Support

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Clean Coal Technology Roadmap Addresses Near- and Long-range Needs

• Short-term: existing fleet− Cost-effective

environmental control technologies to comply with current and emerging regulations

• Long-term: future energy plants− Near-zero emissions

power and clean fuels plants with CO2management capability

Can be found on CURC website

www.coal.organd NETL

www.netl.doe.gov/coalpower

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2000 2005 2010 2015 2020 2025 2030O2

Membrane

AdvancedGasifier/

Combustor

SequestrationReady Integrated

Adv. Power System

Near-Zero Emission Plants with

Sequestration

Integrated Adv. Power System

Sequestration Ready Near-Zero Emission Power

Plants

Integrated Adv. Power System w/Fuel Cell

IGCC &CFB

Demos

Envr. Control(Hg, water, byproducts)

Gas Cleaning Advances in System

ComponentsATS Syngas Turbine

SECA Fuel Cell

ATS Turbine

CO2 Capture

CO2 Sequestration

Sequestration ReadyNear-Zero Emission

Plants w/CoproductionPower/Fuel

Coproduction Liquids

H2Membrane

Fuel Cell/IGCC Test

IGCC Demos

FutureGen-Coproduction Hydrogen/Power/Sequestration

Technology Roadmap – Future Energy Plants

Technology Module Demos

Integrated Plant Demos

Near-Zero Emission Plants

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FutureGen Project Description

Pioneer advanced hydrogen production from coalEmit virtually no air pollutantsCapture and permanently sequester carbon dioxideIntegrate operations at full-scale –a key step to proving feasibility

World’s first near-zero emission, coal-based power plant to:

Goals1) Operate a full-scale (275 MW) integrated research plant2) Capture >90% of CO2 and permanently sequester (1 million tons/year)3) Prove effectiveness, safety and permanence of CO2 sequestration4) Test and validate cutting-edge technologies in “living laboratory”5) Push toward Clean Coal Technology Roadmap 2020 near-zero

emission targets

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Why FutureGen Is Needed• FutureGen is a key step to creating a zero emission

coal energy option• FutureGen will enable us to:

− Meet our growing energy needs with zero-emissions coal

− Secure this country’s economic and energy future through the clean use of coal, our most abundant, strategic, domestic energy resource

− Remove all environmental concerns over coal’s use including climate change concerns by sequestering carbon dioxide emissions from coal power plants, and

− Produce clean low-cost hydrogen with zero emissions for power generation or for transportation

• Integration of concepts and components is the key to proving the technical and operational viability

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Weyburn CO2 EOR Project• Pan Canadian Resources• 200-mile CO2 pipeline from Dakota

Gasification Plant• 130M barrels oil over 20-year project• $28M

Sleipner North Sea Project• Statoil• Currently monitoring CO2 migration• $80M “incremental cost”• $35/ ton CO2 tax

Geologic Sequestration Highlights(1 Million TPY CO2 , ~ 100 MW Coal Power Plant)

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Sequestration R&D• Barrier Issues

• Health, safety and environmental risks • Permanence and large scale verification• Capacity evaluation• Infrastructure• Uncertain regulatory frameworks• Protocols for identifying amenable storage sites

• Pathways• Depleting oil reservoirs• Unmineable coal seams• Saline formations• Enhanced terrestrial uptake• Ocean fertilization and injection• Regional Partnerships

Figure 2

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Gasifier

Coal

H2O

AirSeparation

Air

N2

O2

MarketableAsh/Slag By-product

SulfurRecovery

Gas Cleaning and Shift

Conversionto H2

H2O

MarketableSulfur

By-product

Gasifier

Coal

H2O

AirSeparation

Air

N2

O2

MarketableAsh/Slag By-product

Gasifier

Coal

H2O

AirSeparation

Air

N2

O2

MarketableAsh/Slag By-product

SulfurRecovery

Gas Cleaning and Shift

Conversionto H2

H2O

MarketableSulfur

By-product

FutureGen Flow Diagram

Deep Saline Aquifer

Depleted Oil & GasReservoirsUnminable

Coal BedsEnhanced

Oil Recovery

CO2

Refinery

Transportation

Air

SteamTurbine

H2 Turbine

Electricity

CO2Separation

H2Separation

H2 RichStream

H2 Product

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Hydrogen From Coal --- Objectives• Production: Central Pathway --- By 2015, demonstrate a 60% efficient , zero emissions, coal-fueled hydrogen and power co-production facility that reduces the cost of hydrogen by 25% compared to current coal-based technology (~$6/MM Btu)

• Production: Hydrocarbon Pathway --- By 2010, complete tests and evaluations of most promising hydrogen-rich, coal-derived liquids for reforming applications

• Storage --- By 2015, work with other DOE Offices to develop safe, affordable technology capable of storing 9 wt. % hydrogen

• Utilization --- By 2010, complete tests & evaluations of H2/natural gas mixtures in modified and advanced internal combustion engines

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Hydrogen Production --- Technology Hurdles• Production…Gasifier Reliability, Air Separation Cost and

Efficiency, Hydrogen Separation Cost and Efficiency, Co-Production Process Integration, Multi-contaminant Gas Cleaning, Syngas Convresion reactor Design and Performance, Catalyst-Wax Separation

• Storage…Materials

• Utilization: H2/natural gas combustion in ICEs, Performance and emissions control

• Process Engineering: Process Intensification

• CO2 Sequestration – Capture and sequester impact on cost of cost of electricity, MMV

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FutureGen Technology Developments & Challenges

Traditional Advanced Technology

Cryogenic SeparationAmine ScrubbersAmine ScrubbersGas Stream Clean-UpSyngas TurbineFuel Cell ($4,000/kW)EOR basedExisting GasifierSystem IntegrationPlant Controls

Research InventionsO2 MembranesHydrogen Membranes“Clathrate” CO2 Separation“Dirty” Shift ReactorHydrogen TurbineSECA Fuel Cell ($400/kW design)

Sequestration TechnologyAdvanced Transport Reactor“First of a Kind” System Integration

“Smart” Dynamic Plant Controls & CO2 Management Systems

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Project Cost & Cost-sharing• Total project cost is $950 million• $500 million (53%) -- direct project funding from DOE• $120 million (13%) -- from DOE sequestration program

DOE will use its best efforts to achieve or exceed a minimum 80/20 cost share for this R&D portion from partners outside the existing consortium

• $250 million (26%) -- direct funding is expected to be provided by the industry consortium

• $80 million (8%) -- to be provided by International partners

950Total10Site Monitoring

191Sequestration (design and construction)188Shakedown and Full-Scale Operation 480Plant Procurement and Construction 81Plant Definition, Baselining, and NEPA

EstimatedCosts ($M)

Cost Element

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Project Schedule --- Key Events

Major ProjectMilestones

2003 2005 2007 2009 2011 2013Fiscal Year 2015

Supporting Research*

Design / Construction

Shakedown / Operation

SiteCharacterization

Follow-onTesting

* Supporting research includes research embedded in FutureGenproject and additional research in FE’s carbon sequestration, IGCC, turbines, and fuel cell R&D programs

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Project Schedule

BP0 – Project Definition,Baselining and NEPA

Procurement

BP2 - Shakedown, Full ScaleOperation, & Sequestration

Site Monitoring & Characterization

NEPA (EIS)

Permitting

Candidate Sites Identified

Preliminary Design

BP1 – Plant Detailed Design,Procurement & Construction

ConstructionBase Plant

Detailed Design

Shake-down and Start-up

Full-Scale Operation(inc. sequestration)

Sequestration (Phase 1)

ConstructionDesign & Procurement

Technology Assessment

Site Selection

BP3 – Site Monitoring

(FY)2004 (FY)2005 (FY)2006

Jan.

04

Apr.

Jul.

Jan.

05

Apr

.Ju

l.

Jan.

06

Apr.

Jul.

Jan.

07

Apr

.

Jan.

08

Apr

.

Jan.

09

Apr

.Ju

l.

Jan.

10

Apr

.Ju

l.

Jan.

11

Apr

.

Jul.

Jul.

Jul.

(FY)2007 (FY)2008 (FY)2009 (FY)2010 (FY)2011 (FY)2012

Apr.

Jul.

Jan.

12

(FY)2013

Apr.

Jul.

Jan.

13

Oct

.

Oct

.

Oct

.

Oct

.

Oct

.

Oct

.

Oct

.

Oct

.

Oct

.

Oct

.

(FY)2014

Apr

.Ja

n. 1

4

Jul.

Oct

.

(FY)2015

Oct

.

Apr

.Ju

l.

Jan.

15

( to2018)

Oct

.

Phase 2 Sequestration

BP0 $61MM BP1 $571MM BP2 $308MM BP3 $10MM

FE R&D Advanced Technology(base plant design)

Continuous PowerFirst Plant Revenue

Cooperative Agreement Award

NEPA Record of Decision

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Progress to Date• February 27, 2003 - Presidential announcement

− Received strong support from states, industry, international community and some NGOs

• April 2003 - Project plan developed, RFI in Federal Register

• October 2003 - Completed departmental Critical Decision (CD)-0 process and later for CD-1 Acquisition Strategy

• October 2003 - Congress provided $9M for FutureGen for first year; subject to submission of FutureGenProgram Plan

• March 4, 2004 – Submitted FutureGen Program Plan to Congress

• Ongoing: Internally working on negotiations strategy, drafting selection criteria, test planning, and start of NEPA and project development

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FutureGen Test Plan• Base plant technologies

−Oxygen production−Gasification−Gas separation & clean-up−Steam and combustion turbines−Alternate feedstocks (coal types)

• Advanced cutting edge technologies (“living laboratory”)− ITM oxygen production−Hydrogen production−Hydrogen combustion turbines−Fuel cells and hybrids

• Sequestration system (Phase 1 & 2)• Integrated Plant Performance Verification• Long-term monitoring

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FY04 Activities($9M DOE)

(Assuming an award is made to industry in late 2004)

− FutureGen preliminary design activities will be initiated. − $2 million - Work on a draft Environmental Impact

Statement (EIS) will be initiated.− $1 million - Consortium will identify candidate sites and

gather environmental information so that potential sites can be fully characterized and analyzed.

− $6 million - ‘Preliminary design’, consisting of early or conceptual design and engineering activities, can proceed in advance of NEPA-related activities. NEPA precludes DOE sharing in any design and/or construction costs that extend beyond preliminary design, until after NEPA is completed. (cost shared activity)

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Next Steps• Department completed initial internal management

review requirements− Department may now begin negotiations with an

industry partner -- forecast awarding the cooperative agreement in late 2004

• Department will begin NEPA process • High priority -- develop a set of technical siting

criteria that will be used in an open, fair, and transparent competitive process

• Proposed sites will be qualified for consideration based on the technical and environmental criteria

• Qualified sites will be further evaluated on the technical criteria in parallel with the NEPA process for the project

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Key Issues• Consortium development awaiting outcome of

DOE out-year funding commitment− Impacts pre-award engagement− Need to identify key business issues and path

forward (liability, title ownership, intellectual property, revenue treatment, site selection…)

• Cost-sharing− Industry indicated willingness to invest $200M

for “missionary work” with no expectation of return on investment

• Sequestration introduces complexities− Site selection, ES&H issues, NEPA issues

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CoalGasification

Coal HydrogenFuel CellsIC Engines

Geologic CO2 Sequestration

Zero Emission H2

FutureGen Opens Door to “Reuse” of Coal in Transportation Sector

CoalGasification

High Quality Diesel Fuels

Clean Diesel Fuel

Shift and Separation

Fischer-Tropsch

Synthesis

H2

COCoal

H2

CO

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In Summary• Goal: By 2015, a 60

percent efficient, zero emissions, coal-fueled hydrogen and power co-production facility is operational

• Benefits:−Energy security−Early source of hydrogen

for fuel cell vehicles−Reduced emissions of

pollutants and GHGs

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Visit NETL Websitewww.netl.doe.gov

Also:www.fe.doe.gov

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Background Information

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Fossil Fuels with Sequestration

Renewables

Dream Source• Fusion• Thermochemical• Photochemical

Biomass photo: NREL, Calvert Cliffs Nuclear Plant

Hydrogen Production Options

Nuclear Power

Sources of Heat to Sources of Heat to Drive ReactionDrive Reaction

Water

Sources of Sources of HydrogenHydrogen The U.S. uses 14MM BPD of

oil for transportation14MM BPD = 220MM TPY of H2 at current efficiencies

Increasing annual coal production by 33% (330MM

tons) would provide 50MMTPY of H2

50MM TPY of H2 = 50% of our current

transportation requirements at Freedom Car efficiencies Biomass

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Hydrogen Production…How important is Coal?The National Academy of Engineering recently completed

a year long study of: “The Hydrogen Economy: Opportunities, Costs, Barriers and R&D Needs”

Key Findings…General and those specific to coal:

• Hydrogen could fundamentally transform the U.S. energy system; therefore a robust, ongoing hydrogen program is important

• Fossil Fuels will be one of the principal sources of hydrogen for the hydrogen economy…but carbon capture and storage technologies will be required

• The U.S. has vast coal resources…hydrogen from coal can be inexpensive…and…coal must be a significant component of R&D aimed at making very large amounts of hydrogen.

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Hydrogen from Coal Program Roadmap

* Incorporates technology being developed under the complementary Advanced Gasification and Sequestration for carbon dioxide capture and storage programs

2005 2010 2015

Advanced gas separation technology including membranes tolerant to trace contaminants identified

Determine optimum liquids and reforming parameters; initiate advanced liquids production research

Complete tests of sulfur-tolerant membranes and design of separation modules (CCPI)

Complete engineering designs and tests of advanced reforming and syngas processes

Complete tests of H2/nat’l gas mixtures in conventional and advanced ICEs)

Complete bench tests and design of prototype hydrogen storage module

Central Production

Utilization

Complete Commercial Scale Demonstrations*

FreedomCARand other

Applications

Liquids Production

Infra-structure

Complete lab tests of hydrogen storage …carbon and/or metal organic –based

Perform exploratory research on use of H2/nat’l gas mixtures in ICEs

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MLE-SECA-051104

Water Gas Shift - Hydrogen Separation Membrane Reactor

CO + H2O CO2 + H2

H2

Membrane Tube Reactor Shell

catalyst

•Removal of hydrogen drives reaction to completion•Carbon dioxide stream at high pressure, ready for sequestration•Hydrogen available as a clean energy source

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MLE-SECA-051104

GasificationCarbon Capture and Sequestration


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