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GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE
Report prepared for:
GOLDCORP - PORCUPINE GOLD MINES P.O. Box 70, 4315 Gold Mine Road South Porcupine, Ontario P0N 1H0
Report prepared by:
ECOMETRIX INCORPORATED 6800 Campobello Road Mississauga, Ontario L5N 2L8
Ref. 07-1430 June 2008
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE
Original Signed By
Michael Venhuis, M.Sc., P.Geo. Project Manager
Original Signed By
Ronald V. Nicholson, Ph.D. Project Principal
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE Executive Summary
Ref. 07-1430 June 2008 i
EXECUTIVE SUMMARYA characterization study was completed for waste rock associated with the proposed open pit mining operations at the former Hollinger Mine in Timmins, ON. The investigation was focused on identifying and assessing potential environmental risks associated with waste rock from the proposed mining operation. Goldcorp collected and submitted over 80 diamond drill core samples for static testing, including metal content, Acid Base Accounting (ABA) and Synthetic Precipitate Leachate Procedure (SPLP) analyses. The samples were organized by rock type as identified by PGM geologists into groups including feldspar porphyry, mafic volcanics and various sedimentary lithologies.
The ABA results suggest that acid generation is not likely to be an issue with the waste rock generated from the proposed Hollinger Open Pit. There appears to be sufficient useful NP in all rock types to prevent acidification. Metal content analyses suggest that the key constituents of potential concern include antimony, arsenic and zinc. However, results of the SPLP tests suggest that most constituents of potential concern (COPC) appear to be relatively immobile and leachate concentrations were typically below laboratory detection limits. Arsenic and zinc have the highest leachate concentrations relative to water quality objectives and these results suggest further assessment of these COPCs.
Temporal trends in sulphate loadings from humidity cell testing on the argillite sediments are indicative of both flushing of soluble products from the rock and longer term oxidative release. The loadings of cobalt, molybdenum, selenium and zinc in the argillite sediments appear to be correlated with sulphate concentrations, and are indicative of rinsing of the rock (selenium and molybdenum) and longer term release due to oxidation (cobalt and zinc). Steady state loadings of cobalt and zinc from the argillite sediments averages about 42 and 520 kg/Mt/a, respectively, based on humidity cells with no adjustment for field conditions.
Arsenic loadings from the feldspar porphyries are indicative of flushing of residual arsenic from the surface of the rock. However, peak loading rates ranged between 2,600 and 4,680 kg/Mt/a for the two duplicate samples. The elevated arsenic levels are consistent with arsenic observations in tailings associated with the Hollinger and McIntyre mines.
Further assessment is required for the argillite sediments during the Hollinger Feasibility stage and should include evaluation of management options for the waste materials, including the potential for segregation of the various wastes, as part of the feasibility study. Volume estimates of each potential waste type should be completed to allow for estimation of the total loadings from the waste and to assist with the assessment of potential segregation strategies.
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE Table of Contents
Ref. 07-1430 June 2008 ii
TABLE OF CONTENTS
Page
EXECUTIVE SUMMARY........................................................................................................i
1.0 INTRODUCTION..................................................................................................1.1
2.0 WASTE CHARACTERIZATION AND CLASSIFICATION ..................................2.1
3.0 LABORATORY TESTING ...................................................................................3.13.1 Sample Selection .................................................................................................3.1 3.2 Humidity Cell Test Methods .................................................................................3.1 3.3 Humidity Cell Test Results ...................................................................................3.1
4.0 ENVIRONMENTAL IMPLICATIONS ...................................................................4.1
5.0 SHAFT WATER FROM THE EXISTING HOLLINGER UNDERGROUND MINE .................................................................................................................5.1
6.0 CONCLUSIONS...................................................................................................6.1
7.0 REFERENCES.....................................................................................................7.1
APPENDIX 1: Compilation of Metal, ABA and SPLP Data APPENDIX 2: Compilation of Humidity Cell Testing Data
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE Table of Contents
Ref. 07-1430 June 2008 iii
LIST OF TABLES
Table No.
2.1: Summary of Metal Contents in Waste Rock 2.2: Summary of Acid Base Accounting Results for Waste Rock 2.3: Summary of Synthetic Precipitate Leachate Procedure (SPLP) Testing Results for
Waste Rock
5.1: Summary of Hollinger Shaft Sludge Chemistry 5.2: Summary of Hollinger Shaft Water Chemistry
LIST OF FIGURES
Figure No.
2.1: Distribution of Sobek and Carbonate NP/AP with Sulphide Content in Hollinger Waste Rock Samples
2.2: Comparison of Sobek and Carbonate Neutralization Potentials
3.1: Modified Humidity Test Cell Set-up 3.2: Summary of Humidity Cell Testing Results for Selected Constituents of Concern
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE Introduction
Ref. 07-1430 June 2008 1.1
1.0 INTRODUCTION Goldcorp Canada Ltd. Porcupine Gold Mines (PGM) is currently evaluating the possibility of resuming mining operations at the former Hollinger Mine in Timmins, ON. PGM has been actively exploring the site over the past few years and has collected a substantial amount of diamond drill core. As part of the pre-feasibility study, PGM requires an assessment of the potential environmental issues related to drainage from potential waste rock associated with the open pit mine and implications for managing the waste rock.
EcoMetrix Incorporated (EcoMetrix) was retained by PGM to provide a preliminary characterization of the waste rock inventory for the proposed Hollinger Mine. The results of the investigation are intended to provide guidance for mitigation of the potential environmental issues related to drainage from waste rock, as appropriate, through classification and management of each of the waste rock types during the mining operation.
The overall objective of the program is to provide assistance with appropriate classification and management of each of the waste rock types during the mining operation. Specifically, the program was focused on identifying and assessing potential environmental concerns from waste rock from the proposed open pit mine. Once the rock types are classified in terms of potential environmental behavior, operational monitoring and management strategies will be required to provide cost effective and safe storage of waste rock for the long term.
This program involved characterization of the rock and assessment of the environmental implications of the various rock types. The data collected to date indicates that much of the waste rock will likely represent a low risk for environmental effects. However, there is potential for some of the waste rock to represent a higher risk to drainage quality. The results of the current testing assist in differentiating between the majority of low risk material and the minority of higher risk materials, and also assist in determining cost effective mitigation strategies for these higher risk rock types.
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE Waste Characterization and Classification
Ref. 07-1430 June 2008 2.1
2.0 WASTE CHARACTERIZATION AND CLASSIFICATION In 2006 a drilling program was initiated at the Hollinger Mine and carried out by PGM. Since then, PGM has submitted over 80 core samples, collected as approximately 1m sections, for static testing, including metal content, Acid Base Accounting (ABA) and Synthetic Precipitate Leachate Procedure (SPLP with 20:1 water:solids ratio).
The samples are organized by rock type identified by PGM geologists into groups including feldspar porphyries (F), mafic volcanics (VM) and various sedimentary lithologies (SS).
Results from the metal content analysis are summarized as minimum, maximum and geometric mean values in Table 2.1 and are compared to average crustal abundances for each potential constituent of concern. Results from the ABA and SPLP testing are summarized in Tables 2.2 and 2.3, respectively. Complete results as analyzed by SGS Lakefield Research Limited (SGS Lakefield) and provided by PGM are presented in Appendix 1.
Review of the ABA results (Table 2.2) suggest that the majority of rock samples will not be at risk for acid generation, with only 4 of the 80 samples (5%) categorized as possibly acid generating (Sobek-NP/AP ratios less than 2) based on criteria provided in BC Draft Guidelines (Price, 1997). An additional 4 samples exhibited ratios between 2 and 4, suggesting low potential for acid generation (Figure 2.1). All but one of these samples with low NP/AP ratios are of mafic volcanic lithology, and the other sample is a feldspar porphyry sample.
Based on the samples to date, there appears to be sufficient useful NP to prevent acidification, therefore, acid generation is not likely to be an issue with the waste rock generated from the proposed Hollinger Open Pit. This conclusion is further supported by data available from historical and current mining operations in the Timmins area (McIntyre, Hollinger, Pamour) for which there are abundant data for the historic tailings on surface in that area.
In general, carbonate NP values, which are calculated from the carbonate content of the rock material, are slightly greater than the Sobek NP values which are determined through laboratory titrations (Figure 2.2). This suggests that a small portion of the carbonate minerals either react slowly or may not provide any net neutralization capacity, as would be the case with iron or manganese carbonate.
Although the waste rock is not expected to pose an acid generation problem, assessment of metal leaching at neutral pH required consideration for the assessment and development of waste rock management strategies. The geometric mean of the arsenic content of the potential waste rock is 12.6 mg/kg, with antimony and zinc contents with geometric means of 0.4 and 148 mg/kg, respectively (Table 2.1). The geometric mean is 48 mg/kg for nickel
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE Waste Characterization and Classification
Ref. 07-1430 June 2008 2.2
and 53 mg/kg for copper. However, results of the SPLP tests (Table 2.3) suggest that most parameters appear to be relatively immobile as leachate concentrations were typically low and below laboratory detection limits, although the low concentrations may be a result of dilution due to the high water to solids ratio.
Based on screening criteria of 10x the average crustal abundance and SPLP testing, the results suggest that the key constituents of potential concern include antimony, arsenic and zinc. It is important to note that although the concentration of molybdenum in the solids is low (geometric mean=0.35 mg/kg), molybdenum was easily leached from some samples during the SPLP testing. The concentration of molybdenum leached during the tests ranged between 0.002 and 278 mg/kg. In addition, previous evaluations of mine tailings from the Hollinger area (McIntyre, former Hollinger Mine) suggest that leaching of cadmium, cobalt, copper, nickel, lead and selenium may also represent potential environmental risks. Although tailings geochemistry may be more representative of ore materials, the results from the historic mines provide an indication of constituents of potential concern that warrant further scrutiny.
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE Laboratory Testing
Ref. 07-1430 June 2008 3.1
3.0 LABORATORY TESTING As part of the pre-feasibility study for resuming mining operations at the Hollinger Mine, PGM requires an assessment of the potential environmental issues related to drainage from waste rock associated with the open pit mine. Characteristics of the waste rock have previously been investigated by PGM using ABA and SPLP testing, as described above. In order to further evaluate the waste rock at the Hollinger Mine, EcoMetrix completed laboratory studies in order to assess the leachability of metals from potential waste rock.
3.1 Sample Selection
Crushed rock samples from the 80 core segments used for the metals, ABA and SPLP analyses were delivered to EcoMetrix and divided into three composites, representing the three different rock types, feldspar porphyry (19 core samples), mafic volcanics (55 core samples) and argillite sediments (8 core samples). Each composite sample comprised of equal amounts of each core segment to create a 4kg sample. Two 1kg sub-samples of each composite were used for the humidity cell testing with the remaining composite material archived for further analysis, if required.
3.2 Humidity Cell Test Methods
The modified humidity cell test procedure involved weekly flushing and collection of leachate for analysis for the duplicate composite rock samples representing feldspar porphyries (F-1 and F-2), mafic volcanics (VM-1 and VM-2) and argillite sediments (SS-1 and SS-2). Approximately 1 kg (dry weight) of the crushed rock material was placed into the top portion of a high density polyethylene (HDPE) funnel (Figure 3.1). A layer of Nitex screen between two sheets of Whatman filter paper was placed in the bottom of the funnel, prior to rock addition, in order to retain the rock, while allowing for water to filter through. Each week, distilled water was poured over the rock and allowed to gravity drain into dedicated collection flasks. Samples were taken from the collection flasks and the conductivity and pH were measured immediately after sample collection. After sampling, the funnels were loosely covered with cellophane to prevent excessive evaporation and left undisturbed until the next sampling event. Leachate samples for metals analysis were filtered using (45 µm), acidified (nitric acid to pH < 2) and stored at 4 °C prior to submission for analysis. Samples collected for alkalinity/acidity were filtered and stored at 4°C prior to analysis. All samples were submitted to ALS Environmental Laboratories (ALS) in Mississauga, ON for analysis.
3.3 Humidity Cell Test Results
The results for the humidity cell test are presented in Figure 3.2. As the methods used for the humidity cell tests are consistent over time, the time trends for the loading rates of individual COCs are similar to the trends for concentrations, thus, loading rates are
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE Laboratory Testing
Ref. 07-1430 June 2008 3.2
presented as mg-metal/kg-tailings/week. Complete results of the humidity cell tests are provided in Appendix 2.
Although fluctuations were observed in the weekly pH measurements, the pH values of the leachate from all the samples generally ranged between 6.5 and 8.5. Some exceptions with respect to the general pH range existed during the initial stages of testing. Sample SS-2 exhibited an initial leachate pH of 6.2 on the first day of testing, while samples F-1, F-2 and VM-2 had pH values of between 8.5 and 9.0 on the first sampling event (Day 0).
Concentrations of antimony, copper, cadmium, nickel and lead in the humidity cell leachates were generally below detection limits for all samples over the course of the testing, and therefore are not discussed further in this section of the report.
The highest arsenic loading trends were observed in the feldspar porphyry samples, F-1 and F-2 (Figure 3.2), with maximum loadings of 0.092 and 0.05 mg/kg/wk, respectively, or between 2,600 and 4,680 Kg/Mt/a. All other samples had arsenic loadings less than 0.02 mg/kg/wk, with either a steady or slightly decreasing trend with time, with the exception of VM-2, which appeared to have slightly increasing trend during the first 15 weeks before exhibiting a slight decrease after 15 weeks.
Loadings of cobalt, molybdenum and selenium were generally below detection (0.0005, 0.001 and 0.005 mg/L, respectively) in all of the feldspar porphyry and mafic volcanic samples. However, concentrations were detected in the argillite sediment samples with cobalt loadings ranging between <0.0005 and 0.0016 mg/kg/wk and with no consistent trend over time. Concentrations of molybdenum were highest in the initial flushing of the humidity cells, with loadings of 0.011 and 0.007 mg/kg/wk for the SS-1 and SS-2 samples, respectively. Maximum selenium loadings of approximately 0.021 and 0.018 mg/kg/wk were observed within a few weeks of rinsing and decreased with further testing.
The loadings of zinc during the beginning of testing were below or near detection limits for the feldspar porphyry and mafic volcanic samples (F-1, F-2, VM-1 and VM-2). However, after about 15 weeks of testing, spikes in zinc loadings were observed, although the overall loading of the samples generally remained below 0.005 mg/kg/wk. Zinc loadings in the SS-1 and SS-2 samples exhibited a general increasing trend, with maximum loadings of about 0.017 and 0.012 mg/kg/wk, respectively.
Sulphate loadings were relatively constant and below 20 mg/kg/wk for the feldspar porphyry and mafic volcanic samples, with the exception of sample F-2 which exhibited increases after 14 weeks of testing (Figure 3.2). The argillite sediment samples had sulphate loadings ranging between 27 and 111 mg/kg/wk for sample SS-1 and 24 and 75 for sample SS-2. In general, sulphate loadings show an overall decreasing trend with time in the sediment samples.
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE Environmental Implications
Ref. 07-1430 June 2008 4.1
4.0 ENVIRONMENTAL IMPLICATIONS The humidity cell testing was completed to provide a screening evaluation for any potential environmental issues related to drainage from the waste rock arising from the proposed Hollinger Mine and was not corrected for field conditions. The investigation was intended to allow for identification of any additional screening of COCs and/or rock types that could be completed as part of the feasibility program for the proposed mine should results of this study suggest that environmental effects were anticipated.
The results of Humidity Cell testing in addition to the ABA results indicate that the potential risk for acid generation is low if rock is stored in large stockpiles on surface. All samples exhibited neutral pH values in the humidity cell leachate, providing no indication that the samples could go acidic during the test period. However, sulphate loadings were steady around 30 mg/kg/wk for the argillite sediments by the end of the testing period. The initial loading of sulphate is likely a result of flushing of sulphate contained on the rock as a result of oxidation during sample collection and processing (crushing) prior to testing. However, the constant loadings at the end of the testing are an indication of longer-term oxidation and suggest that sulphate is being produced and that sulphide minerals will be subject to ongoing oxidation. The sulphate loadings also suggest that other metals may be subject to ongoing release during oxidation.
Loadings of cobalt, molybdenum, selenium and zinc in the argillite sediments correlate with sulphate release, and represent both flushing of these constituents from the rock (selenium and molybdenum) and longer term release due to oxidation (cobalt and zinc). Steady-state loadings from the argillite sediment samples averaged around 0.0008 and 0.01 mg/kg/wk for cobalt and zinc, respectively, or about 42 and 520 kg/Mt/a, respectively.
Sulphate loadings from one of the two duplicate feldspar samples exhibited increases after 14 weeks, although the second duplicate sample had not yet exhibited this increasing trend in concentration at week 20. The observed increase suggests that longer-term oxidation may also be occurring for the feldspar material. However, there were no correlated metal releases observed with the increased sulphate release.
The observed trend in arsenic loadings for the feldspar material is consistent with flushing of soluble arsenic contained on the rock as a result of oxidation during sample collection and processing. In addition, the lack of correlation with sulphate in the same sample cells suggests that these concentrations have not resulted from oxidative leaching. None-the-less, peak arsenic loadings during the initial rinsing of the waste may represent an environmental concern, and should be re-assessed after waste inventories and water flow balances are better defined.
The metal loadings observed for the argillite sediments indicates a potential risk and suggests that further assessment is warranted in the feasibility study for the site to evaluate
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE Environmental Implications
Ref. 07-1430 June 2008 4.2
the management options for waste disposal. As part of the feasibility stage, an assessment of grade control should be completed, including screening of blast hole cuttings to allow for material identification and potential separation during drilling of potential metal leaching material.
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE Environmental Implications
Ref. 07-1430 June 2008 5.1
5.0 SHAFT WATER FROM THE EXISITNG HOLLINGER UNDERGROUND MINE
Concern for the water quality in the Hollinger shaft was expressed by Goldcorp personnel after excessive corrosion of the water pump was noted in 2008. The pump and associated steel parts required replacement after only one year of operation compared to the ongoing operation of a similar pump in the McIntyre shaft. Goldcorp requested that EcoMetrix assess the conditions that may be responsible for the conditions related to the pump corrosion in the Hollinger shaft. Samples of sludge were collected from the pump when it was removed for maintenance and sent for chemical analysis. Water samples from the shaft were also collected and analyzed.
The sludge sample contained approximately 39% iron and 9% sulphur (Table 5.1). The sulphur is the key to understanding the corrosion issue. It appears that the iron is corroded by the formation of FeS rather than iron oxide. The FeS is consistent with the appearance of the “black” coloured sludge.
The water samples support this hypothesis (Table 5.2). The water contains sulphate (600 to 2,700 mg/L) and therefore has a source of sulphur. Only one sample was analyzed for dissolved sulphide and that sample exhibited a concentration of 0.03 mg/L, a relatively high value for sulphide in water. In addition, the water had a neutral pH (7.4) and elevated alkalinity (460 to 580 mg/L and CaCO3). The neutral pH suggests that the water is not corrosive due to acidic conditions. The high alkalinity is consistent with sulphate reduction or the production of sulphide (dissolved or gas) during reactions between sulphate and some organic source.
It is understood that the current flow rate from the Hollinger shaft is relatively low (approximately 1,000 m3/d). This means that there is a long residence time in the shaft and adequate time for bacterial activity to mediate the sulphate reduction reactions. However, if mine dewatering is planned in the future, then greater pumping rates are anticipated and shorter residence times are expected. It is likely that greater pumping will not allow as much sulphate reduction and the potential for corrosion by this mechanism will decline. If small pumping rates are expected to continue, then stainless steel pumps or other mitigation (such as aeration of shaft water) should be considered.
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE Conclusions
Ref. 07-1430 June 2008 6.1
6.0 CONCLUSIONS The following conclusions are based on the results of this investigation:
� ABA results indicate that the majority of the potential waste rock material is not likely to produce acid, with only 8 of the 80 samples having NP/AP ratios less than 4 and all samples exhibiting NP/AP values greater than 1;
� SPLP testing suggests that most parameters appear to be relatively immobile as leachate concentrations were typically low and below laboratory detection limits, although the low concentrations may be a result of dilution due to the high 20:1 water to solids ratio. Arsenic and zinc exhibited the highest leachate concentrations relative to water quality objectives;
� Constituents of Primary Concern include arsenic, cobalt, molybdenum, selenium and zinc;
� Temporal trends in sulphate loadings from humidity cell testing on the argillite sediments are indicative of both flushing from the rock and longer term oxidation;
� The loadings of cobalt, molybdenum, selenium and zinc in the argillite sediments appear to be correlated with sulphate concentrations, and are indicative of rinsing of the rock (selenium and molybdenum) and longer term release due to oxidation (cobalt and zinc);
� Steady state loadings of cobalt and zinc from the argillite sediments averages about 42 and 520 kg/Mt/a, respectively, based on humidity cells with no adjustment for field conditions;
� Arsenic loadings from the feldspar porphyries are indicative of flushing of residual arsenic from the surface of the rock. However, peak concentrations ranged between 2,600 and 4,680 kg/Mt/a for the two duplicate samples. The elevated arsenic levels are consistent with arsenic observations in tailings associated with the Hollinger and McIntyre mines.
� Further assessment is required for the argillite sediments during the Hollinger Feasibility stage and should include evaluation of management options for the waste material. In addition, segregation should be considered for various wastes as part of the feasibility study; and
� Volume estimates of each potential waste type should be completed to allow for estimation of the total loadings from the waste.
GEOCHEMICAL EVALUATION OF WASTE ROCK – HOLLINGER MINE References
Ref. 07-1430 June 2008 7.1
7.0 REFERENCES Price, W.A. 1997. Draft Guidelines and Recommended Methods for the Prediction of Metal
Leaching and Acid Rock Drainage at Minesites in British Columbia. B.C. Ministry of Employment and Investment (note: Ministry of Employment and Investment was the former home of the present Ministry of Energy and Mines).
ParameterAverage Crustal
Abundance (mg/kg) 1Minimum (mg/kg) Maximum (mg/kg)
Geometric Mean (mg/kg) 2,3
Felspar Porphyries (n=19)Antimony 0.20 0.20 2.90 0.66Arsenic 1 <2 91 15.3Cobalt 29 4.30 91.0 13.6Copper 75 1.80 96.0 10.4Iron 24,830 15,000 65,000 25,455Lead 8 2.50 178 16.6Molybdenum 1 0.08 24.0 0.44Nickel 105 7.20 91.0 26.4Selenium 0.05 <1 2 1Zinc 80 28 2500 192Mafic Volcanics (n=55)Antimony 0.20 <0.1 1.30 0.28Arsenic 1 <2 130 11.3Cobalt 29 18.0 100 38.7Copper 75 27.0 550 80.6Iron 24,830 39,000 147,000 68,945Lead 8 0.20 14 2.0Molybdenum 1 <0.05 12 0.30Nickel 105 13.0 300 60.1Selenium 0.05 <1 7 2Zinc 80 37 1800 112Sedimentary Lithologies (n=8)Antimony 0.20 0.60 2.70 1.07Arsenic 1 20 96 41.3Cobalt 29 32.0 60.0 39.2Copper 75 77 540 234Iron 24,830 30,000 108,000 67,296Lead 8 3.90 170 11.3Molybdenum 1 0.42 10 1.76Nickel 105 56 90 72.3Selenium 0.05 2 6 3Zinc 80 110 2900 978
Notes:1 - From Faure (1998) Geochemistry of Natural Waters. Prentice-Hall, Table A.10 pg. 5132 - Assumes a value equivalent to detection limit for values in data set reported less than detection3 - Bold values are more than 10 times average crustal abundance
Table 2.1Summary of Metal Contents in Waste Rock
Parameter Units Minimum Maximum Geometric Mean
Feldspar Porphyries (n=19)pH --- 8.40 9.35 8.81Acid Generating Potential kg CaCO3/t 0.31 69.6 5.0Sobek Neuralization Potential kg CaCO3/t 48 284 167Carbonate Neutralization Potential kg CaCO3/t 64 331 206Sobek NP/AP --- 1.70 771 33.0Carbonate NP/AP --- 3.50 927 40.8Sulphide Sulphur % 0.01 2.23 0.16Total Sulphur % 0.06 2.72 0.24Sulphate Sulphur % <0.4 <0.4 <0.4CO2 % 2.94 19.6 10.8Mafic Volcanics (n=55)pH --- 8.44 9.86 9.21Acid Generating Potential kg CaCO3/t 0.31 65.3 3.82Sobek Neuralization Potential kg CaCO3/t 58 331 139Carbonate Neutralization Potential kg CaCO3/t 86 394 165Sobek NP/AP --- 1.30 1067 36.5Carbonate NP/AP --- 1.93 1272 43.3Sulphide Sulphur % 0.01 2.09 0.12Total Sulphur % 0.01 2.75 0.20Sulphate Sulphur % <0.4 <0.4 <0.4CO2 % 4.33 21.7 8.58Sedimentary Lithologies (n=8)pH --- 8.29 9.21 8.75Acid Generating Potential kg CaCO3/t 0.31 27 3.1Sobek Neuralization Potential kg CaCO3/t 85 263 162Carbonate Neutralization Potential kg CaCO3/t 122 310 212Sobek NP/AP --- 5.90 850 52.7Carbonate NP/AP --- 9.01 1000 68.9Sulphide Sulphur % 0.01 0.85 0.10Total Sulphur % 0.09 1.2 0.31Sulphate Sulphur % <0.4 <0.4 <0.4CO2 % 5.71 17.2 10.7
Table 2.2Summary of Acid Base Accounting Results for Waste Rock
Para
met
erU
nits
PWQ
OM
inim
umM
axim
umG
eom
etric
Mea
n1
Rat
io(G
eom
ean/
PWQ
O)2
Feld
spar
Por
phyr
ies
Ant
imon
ym
g/L
0.02
0.00
040.
0042
0.00
20.
1A
rsen
icm
g/L
0.00
50.
002
0.07
00.
012
2.5
Cob
alt
mg/
L0.
009
0.00
0036
0.00
0360
0.00
009
0.01
Cop
per
mg/
L0.
001
0.00
050.
0013
0.00
070.
7Iro
nm
g/L
0.3
<0.0
10.
640.
060.
2Le
adm
g/L
0.00
50.
0003
90.
0056
60.
0011
0.2
Mol
ybde
num
mg/
L0.
040.
0001
913
.90
0.00
30.
1N
icke
lm
g/L
0.02
5<0
.000
070.
0025
0.00
050.
02S
elen
ium
mg/
L0.
1<0
.000
3<0
.001
0.00
080.
008
Zinc
mg/
L0.
020.
003
0.27
30.
096
4.8
Maf
ic V
olca
nic s
Ant
imon
ym
g/L
0.02
0.00
020.
0044
0.00
20.
1A
rsen
icm
g/L
0.00
5<0
.000
20.
0173
0.00
10.
2C
obal
tm
g/L
0.00
9<0
.000
010.
0005
90.
0000
20.
003
Cop
per
mg/
L0.
001
<0.0
001
0.00
160.
0004
0.4
Iron
mg/
L0.
3<0
.01
1.40
0.02
0.1
Lead
mg/
L0.
005
<0.0
002
0.00
220.
0005
40.
5M
olyb
denu
mm
g/L
0.04
0.00
019.
670.
409.
9N
icke
lm
g/L
0.02
5<0
.000
020.
0010
00.
0001
0.00
5S
elen
ium
mg/
L0.
1<0
.000
30.
0010
0.00
050.
005
Zinc
mg/
L0.
020.
003
0.25
20.
057
2.8
Sedi
men
tary
Lith
olog
ies
Ant
imon
ym
g/L
0.02
0.00
250.
0050
0.00
30.
2A
rsen
icm
g/L
0.00
5<0
.000
50.
0486
0.00
30.
6C
obal
tm
g/L
0.00
9<0
.000
010.
0002
30.
0000
40.
004
Cop
per
mg/
L0.
001
0.00
020.
0024
0.00
070.
7Iro
nm
g/L
0.3
<0.0
10.
180.
030.
1Le
adm
g/L
0.00
50.
0003
50.
0052
00.
0018
0.4
Mol
ybde
num
mg/
L0.
040.
0003
9.24
1.86
46.5
Nic
kel
mg/
L0.
025
<0.0
0002
0.00
080
0.00
010.
005
Sel
eniu
mm
g/L
0.1
<0.0
003
0.00
100.
0004
0.00
4Zi
ncm
g/L
0.02
0.00
60.
181
0.06
63.
3
Not
es:
1 - A
ssum
es a
val
ue e
quiv
alen
t to
dete
ctio
n lim
it fo
r val
ues
in d
ata
set r
epor
ted
less
than
det
ectio
n2
- Rat
ios
of le
acha
te c
once
ntra
tion
to P
rovi
ncia
l Wat
er Q
ualit
y O
bjec
tives
(PW
QO
) sho
wn
for s
cree
ning
inde
x on
ly -
ther
e ar
e no
regu
lato
ry li
mits
for S
PLP
resu
lts
Tabl
e 2.
3Su
mm
ary
of S
ynth
etic
Pre
cipi
tate
Lea
chat
e Pr
oced
ure
(SPL
P) T
estin
g R
esul
ts fo
r Was
te R
ock
Sludge3-Mar-08
Antimony mg/kg <10 Arsenic mg/kg 710 Cobalt mg/kg 850 Copper mg/kg 630
Iron % 39 Molybdenum mg/kg 41
Nickel mg/kg 700 Zinc mg/kg 440
Sulphur % 8.98
Sample IDSample Date
Table 5.1Summary of Hollinger Shaft Sludge Chemistry
Hol
linge
r Sha
ft Ta
nkH
ollin
ger S
haft
Tank
Hol
linge
r Sha
ft Ta
nkH
ollin
ger S
haft
Tank
Hol
linge
r Sha
ft29
-Jan
-08
5-Fe
b-08
25-F
eb-0
83-
Mar
-08
7-A
pr-0
8La
b pH
pH u
nit
7.25
7.33
7.42
7.32
7.42
Aci
dity
(pH
8.3
)m
g C
aCO
3/L
8966
.961
.652
.458
.9To
tal A
lkal
inity
mg
CaC
O3/
L58
446
046
745
545
9 S
ulph
ate
mg/
L27
2158
057
059
162
4To
tal S
ulph
ide
mg/
L0.
03TO
TAL
MET
AL S
Ant
imon
ym
g/L
<0.0
03<0
.003
<0.0
03<0
.003
Ars
enic
mg/
L0.
0061
0.05
510.
0525
0.06
530.
0633
Cob
alt
mg/
L<0
.000
50.
0163
0.01
110.
0168
Cop
per
mg/
L<0
.000
5<0
.000
5<0
.000
50.
0008
<0.0
005
Iron
mg/
L26
.412
.211
.311
.810
.1 M
olyb
denu
mm
g/L
0.00
74<0
.002
<0.0
02<0
.002
Nic
kel
mg/
L0.
0021
<0.0
005
0.00
470.
0057
0.00
36 Z
inc
mg/
L0.
0933
0.02
240.
0172
0.01
570.
0227
DIS
SOLV
ED M
ETA
LS A
ntim
ony
mg/
L<0
.003
<0.0
03<0
.003
<0.0
03 A
rsen
icm
g/L
0.00
320.
0495
0.01
570.
0144
Cob
alt
mg/
L<0
.000
50.
0161
0.01
640.
0158
Cop
per
mg/
L0.
0015
<0.0
005
<0.0
005
<0.0
005
Iron
mg/
L22
.510
.61
0.00
79 M
olyb
denu
mm
g/L
0.00
6<0
.002
<0.0
02<0
.002
Nic
kel
mg/
L0.
0041
<0.0
005
0.00
490.
0072
Zin
cm
g/L
0.07
220.
005
0.00
260.
0054
Sam
ple
Loca
tion
Sam
ple
Dat
e
Tabl
e 5.
2Su
mm
ary
of H
ollin
ger S
haft
Wat
er C
hem
istr
y
0.1
1
10
100
1000
10000
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0
Sulphide Content (%)
So
be
k N
P/A
P
Feldspar Porphyries
Argillite Sediments
Mafic Volcanics
0.1
1
10
100
1000
10000
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0
Sulphide Content (%)
Ca
rbo
na
te N
P/A
P
Feldspar Porphyries
Argillite Sediments
Mafic Volcanics
NP/AP = 4
NP/AP = 3
NP/AP = 1
NP/AP = 4
NP/AP = 3
NP/AP = 1
EcoMetrix I N C O R P O R A T E D
Distribution of Sobek and Carbonate NP/AP with
Sulphide Content in Hollinger Waste Rock Samples
Goldcorp Canada Ltd. - Porcupine Gold Mines
April 2008 Figure 2.1
EcoM
etrix
IN
CO
RP
OR
AT
ED
Co
mp
ariso
n o
f S
ob
ek a
nd
Ca
rbo
na
te
Ne
utr
aliz
atio
n P
ote
ntia
ls
Go
ldco
rp C
an
ad
a L
td.
- P
orc
up
ine G
old
Min
es
April 2008
Fig
ure
2.2
0
20
0
40
0
60
0
80
0
10
00
12
00
14
00
16
00
02
00
40
06
00
80
01
00
01
20
01
40
0
So
be
k N
P/A
P
Carbonate NP/AP
Mafic V
olc
anic
sF
eld
sp
ar
Po
rphyrie
sA
rgill
ite
Se
dim
ents
Carb
NP
= S
ob
ek N
P
Tailings (inside funnel)
Connection for vacuum
Cellophane cover to
prevent evaporation
Leachate Collection Vessel
Layer of Nytex screen
between sheets of
Whatman filter paper
EcoMetrix I N C O R P O R A T E D
Modified Humidity Test Cell Set-up
Goldcorp Canada Ltd. - Porcupine Gold Mines
April 2008 Figure 3.1
EcoMetrix I N C O R P O R A T E D
Summary of Humidity Cell Testing Results for
Selected Constituents of Concern
Goldcorp Canada Ltd. - Porcupine Gold Mines
April 2008 Figure 3.2
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21
Week
pH
0
20
40
60
80
100
120
0 5 10 15 20 25
Week
Su
lph
ate
(m
g/k
g/w
k)
0
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0 5 10 15 20 25
Week
Ars
en
ic (
mg
/kg
/wk)
0
0.0002
0.0004
0.0006
0.0008
0.001
0.0012
0.0014
0.0016
0.0018
0 5 10 15 20 25
Week
Co
balt
(m
g/k
g/w
k)
0
0.002
0.004
0.006
0.008
0.01
0.012
0 5 10 15 20 25
Week
Mo
lyb
den
um
(m
g/k
g/w
k)
0
0.005
0.01
0.015
0.02
0.025
0 5 10 15 20 25
Week
Sele
niu
m (
mg
/kg
/wk)
0
0.002
0.004
0.006
0.008
0.01
0.012
0.014
0.016
0.018
0 5 10 15 20 25
Week
Zin
c (
mg
/kg
/wk)
0
10
20
30
40
50
60
70
80
90
0 5 10 15 20 25
Week
Alk
alin
ity (
mg
CaC
O3/k
g/w
k)
SS-1 F-1 VM-1
SS-2 F-2 VM-2
APPENDIX 1
Compilation of Metal, ABA and SPLP Data
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDE
4146
20E
4146
88E
4165
07E
4300
13E
4468
47E
4463
35E
4463
36E
4463
37E
4463
45E
4463
66E
4463
53E
4463
54E
4463
55E
4463
56E
4463
57E
4463
58E
4463
59D
epth
From
109.
2015
4.70
96.8
032
0.00
11.0
0To
110.
2015
5.70
97.8
032
1.00
12.0
0
Lith
olog
yFP
FPFP
FPFP
Por
ph (M
T)P
orph
(MT)
Por
ph (M
T)P
orph
(MT)
Por
ph(M
T)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)U
nits
Solid
s C
onte
ntS
ilver
(Ag)
ug/g
0.26
0.37
0.23
0.30
0.30
0.36
0.47
0.35
2.3
0.89
0.59
0.45
0.41
0.70
0.64
0.81
0.44
Alu
min
um (A
l)ug
/g88
000
8900
049
000
7300
084
000
7600
067
000
7700
072
000
7900
078
000
7500
073
000
8100
081
000
7000
078
000
Ars
enic
(As)
ug/g
9116
1311
30<2
<2<2
1955
1628
3112
2423
10B
ariu
m (B
a)ug
/g30
029
022
040
025
032
016
034
028
037
060
056
039
070
019
045
028
0B
eryl
ium
(Be)
ug/g
0.8
0.9
0.6
0.9
0.8
0.8
0.6
0.9
0.9
0.9
0.8
0.8
0.9
1.0
1.1
0.5
1.1
Bor
on (B
)ug
/g17
963
107
95
139
283
511
87
78
Bis
mut
h (B
i)ug
/g0.
11<0
.06
0.26
<0.0
60.
29<0
.06
0.17
0.08
0.20
0.66
0.28
0.10
0.69
0.07
<0.0
60.
410.
08C
alci
um (C
a)ug
/g12
000
1400
019
000
3400
022
000
2700
054
000
2100
024
000
1600
019
000
2500
020
000
2700
018
000
3100
022
000
Cad
miu
m (C
d)ug
/g0.
430.
170.
100.
250.
240.
510.
320.
180.
400.
601.
30.
750.
550.
631.
71.
95.
5C
obal
t (C
o)ug
/g40
5.6
918.
66.
17.
225
4.8
4.3
1011
1117
1314
4425
Chr
omiu
m (C
r)ug
/g60
138.
417
1112
4713
9.0
7923
3794
3141
8620
Cop
per (
Cu)
ug/g
124.
82.
87.
46.
02.
996
1.8
3.3
149.
611
179.
818
8312
Iron
(Fe)
ug/g
1800
018
000
1600
024
000
2200
017
000
4700
016
000
1500
018
000
2200
025
000
4700
029
000
4000
065
000
3200
0P
otas
sium
(K)
ug/g
2100
021
000
1600
019
000
1700
013
000
9300
2400
022
000
2000
020
000
1700
020
000
2000
026
000
1300
021
000
Lith
ium
(Li)
ug/g
<5<5
525
<57
10<5
<5<5
1419
3728
2254
36M
agne
sium
(Mg)
ug/g
4500
4500
6400
1300
059
0087
0017
000
5800
4800
5300
1000
015
000
2400
014
000
1600
037
000
1600
0M
anga
nese
(Mn)
ug/g
850
600
750
440
1300
340
1300
1200
760
770
770
1400
1600
1300
2300
1900
1800
Mol
ybde
num
(Mo)
ug/g
240.
280.
240.
560.
270.
530.
560.
290.
114.
30.
200.
080.
331.
10.
260.
600.
26S
odiu
m (N
a)ug
/g31
000
3700
085
0011
000
4200
027
000
2400
021
000
2200
024
000
1900
015
000
6200
1200
065
0060
0079
00N
icke
l (N
i)ug
/g91
1018
2013
1240
7.2
9.2
2328
3876
2241
6725
Lead
(Pb)
ug/g
6.0
9.5
3.2
8.6
4.4
282.
55.
563
1434
1919
3482
5313
Ant
imon
y (S
b)ug
/g0.
60.
40.
30.
20.
52.
90.
90.
60.
40.
40.
30.
41.
50.
91.
12.
00.
8S
elen
ium
(Se)
ug/g
<1<1
<12
<11
1<1
<1<1
21
<11
11
<1Ti
n (S
n)ug
/g2.
40.
50.
40.
90.
41.
11.
30.
70.
90.
90.
70.
51.
30.
90.
70.
81.
3Ti
tani
um (T
i)ug
/g28
024
016
025
039
016
020
0035
027
038
021
019
016
023
021
015
017
0Th
aliu
m (T
l)ug
/g0.
70.
80.
30.
30.
50.
60.
20.
80.
50.
50.
50.
30.
40.
50.
50.
30.
4U
rani
um (U
)ug
/g0.
710.
590.
320.
780.
590.
810.
260.
520.
510.
500.
730.
730.
630.
790.
740.
280.
78V
anad
ium
(V)
ug/g
7021
2226
1720
8517
1640
2630
3726
3586
25Y
ttriu
m (Y
)ug
/g3.
13.
72.
55.
54.
35.
213
3.9
3.9
3.5
4.2
4.4
3.7
4.3
4.2
3.9
4.1
Zinc
(Zn)
ug/g
110
4239
8557
130
7428
100
170
650
340
290
260
730
880
2500
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDD
epth
From To
Lith
olog
y
Uni
tsSo
lids
Con
tent
Silv
er (A
g)ug
/gA
lum
inum
(Al)
ug/g
Ars
enic
(As)
ug/g
Bar
ium
(Ba)
ug/g
Ber
yliu
m (B
e)ug
/gB
oron
(B)
ug/g
Bis
mut
h (B
i)ug
/gC
alci
um (C
a)ug
/gC
adm
ium
(Cd)
ug/g
Cob
alt (
Co)
ug/g
Chr
omiu
m (C
r)ug
/gC
oppe
r (C
u)ug
/gIro
n (F
e)ug
/gP
otas
sium
(K)
ug/g
Lith
ium
(Li)
ug/g
Mag
nesi
um (M
g)ug
/gM
anga
nese
(Mn)
ug/g
Mol
ybde
num
(Mo)
ug/g
Sod
ium
(Na)
ug/g
Nic
kel (
Ni)
ug/g
Lead
(Pb)
ug/g
Ant
imon
y (S
b)ug
/gS
elen
ium
(Se)
ug/g
Tin
(Sn)
ug/g
Tita
nium
(Ti)
ug/g
Thal
ium
(Tl)
ug/g
Ura
nium
(U)
ug/g
Van
adiu
m (V
)ug
/gY
ttriu
m (Y
)ug
/gZi
nc (Z
n)ug
/g
E44
6360
E44
6361
E44
6363
E43
1875
E43
1918
E42
9186
E42
9259
E42
9712
E43
0756
E47
1903
E41
4574
E41
4780
E41
4794
E41
6101
E41
6463
E42
8991
E42
9051
E42
9111
131.
6118
0.74
210.
5527
2.00
39.0
014
2.10
258.
0049
.60
83.2
012
7.80
122.
6545
.00
50.0
010
1.00
151.
0013
3.04
182.
0021
1.30
273.
0040
.00
142.
8525
8.98
50.6
084
.20
128.
8012
3.65
46.0
051
.00
102.
0015
2.00
Por
ph(P
LP)
Por
ph(P
LP)
Sed
SS
10S
S10
SS
8S
S8
SS
8S
S8
SS
8V
MV
MV
MV
MV
MV
MV
MV
M
0.74
1.3
0.45
0.77
1.2
0.52
0.64
0.60
0.55
4.3
0.25
0.18
0.14
0.43
0.19
0.24
0.08
0.15
7200
075
000
7400
053
000
3800
055
000
7600
064
000
8300
039
000
7000
058
000
6300
061
000
5700
075
000
6600
071
000
2330
5333
2034
3161
9639
3815
927
846
205
540
360
320
200
2024
063
040
063
021
012
012
083
4921
280
180
110
0.9
1.0
0.7
0.8
0.3
0.5
0.5
0.6
1.6
0.3
0.2
0.2
0.1
0.2
<0.1
0.6
0.4
0.4
57
513
1112
2015
67
1211
67
34
134
0.09
0.13
<0.0
60.
681.
2<0
.06
0.43
0.30
0.13
0.52
<0.0
6<0
.06
0.06
<0.0
6<0
.06
<0.0
6<0
.06
<0.0
633
000
2200
033
000
4400
044
000
6200
044
000
2200
055
000
4300
073
000
7100
076
000
5800
079
000
5300
061
000
5100
01.
01.
01.
96.
22.
50.
391.
76.
20.
826.
80.
310.
220.
130.
450.
370.
100.
090.
2015
1434
4060
3241
3537
4040
4047
4440
3750
3251
5312
075
100
6112
013
039
8666
3727
8113
059
7664
1528
150
400
540
7727
027
011
045
093
8775
8613
096
7887
3000
029
000
7300
010
8000
1020
0061
000
7100
030
000
6100
066
000
7000
090
000
9000
091
000
1080
0046
000
8500
053
000
1400
021
000
2300
073
0065
056
0029
000
2100
022
000
1400
054
0031
0028
0037
0021
0016
000
8500
2100
4027
2322
2822
10<5
3212
2831
4241
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2836
2100
016
000
1200
012
000
1400
019
000
1600
067
0014
000
1400
029
000
3100
027
000
3300
031
000
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031
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2200
022
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0019
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0014
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280.
210.
5310
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000
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0023
0022
0013
000
2200
057
4681
6964
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064
110
6391
5616
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6.0
143.
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22.
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03.
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11.
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10.
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00.
60.
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50.
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22
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33.
50.
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23.
311
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0.7
0.3
0.6
0.3
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0.6
0.4
160
200
390
280
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028
048
026
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034
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20.
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290.
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140.
250.
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020.
030.
030.
030.
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040.
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170
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26.
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086
026
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027
0053
029
0014
097
9825
016
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8812
0
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDD
epth
From To
Lith
olog
y
Uni
tsSo
lids
Con
tent
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er (A
g)ug
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inum
(Al)
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enic
(As)
ug/g
Bar
ium
(Ba)
ug/g
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yliu
m (B
e)ug
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oron
(B)
ug/g
Bis
mut
h (B
i)ug
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alci
um (C
a)ug
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adm
ium
(Cd)
ug/g
Cob
alt (
Co)
ug/g
Chr
omiu
m (C
r)ug
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oppe
r (C
u)ug
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n (F
e)ug
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otas
sium
(K)
ug/g
Lith
ium
(Li)
ug/g
Mag
nesi
um (M
g)ug
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anga
nese
(Mn)
ug/g
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ybde
num
(Mo)
ug/g
Sod
ium
(Na)
ug/g
Nic
kel (
Ni)
ug/g
Lead
(Pb)
ug/g
Ant
imon
y (S
b)ug
/gS
elen
ium
(Se)
ug/g
Tin
(Sn)
ug/g
Tita
nium
(Ti)
ug/g
Thal
ium
(Tl)
ug/g
Ura
nium
(U)
ug/g
Van
adiu
m (V
)ug
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ttriu
m (Y
)ug
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nc (Z
n)ug
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E42
9867
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9962
E43
0694
E43
0723
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0787
E43
0991
E43
1039
E43
1807
E44
6417
E44
6913
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7310
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7504
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1636
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1732
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167.
0024
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30.0
086
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199.
0014
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100.
0050
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219.
6062
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122.
0017
0.00
260.
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1.00
196.
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150.
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168.
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31.0
087
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200.
0015
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101.
0051
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220.
6063
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1.00
261.
0013
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197.
5070
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151.
0021
1.50
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
1
0.83
0.09
0.24
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0.25
0.24
0.37
0.12
0.20
0.39
0.14
0.26
0.16
0.16
0.24
0.18
0.27
6200
066
000
6000
057
000
6600
062
000
6800
067
000
7200
074
000
6800
078
000
8700
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000
6700
068
000
7100
055
000
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2213
022
1210
3311
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26
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038
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40.
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80.
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000
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000
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034
000
4300
051
000
6100
069
000
5000
058
000
6100
063
000
5500
059
000
0.23
0.13
0.30
3.8
0.13
0.28
0.30
0.22
0.04
0.09
0.25
0.09
0.09
0.29
0.14
0.19
0.16
0.20
4433
2234
4426
1849
5246
100
4047
4143
3533
3569
3422
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2219
080
190
180
160
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330
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8632
3031
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011
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000
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000
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000
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0060
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000
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110
1100
076
0071
020
0037
0051
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0023
1610
1027
189
1929
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000
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000
1600
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000
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000
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000
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023
000
2700
026
000
2300
025
000
2100
031
000
1800
1200
2200
4000
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1600
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1300
2000
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000
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000
1400
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0026
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2700
023
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1800
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0077
5625
6074
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3677
9030
090
110
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61.
32.
05.
32.
11.
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72.
50.
93.
511
0.9
1.4
1.5
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2.2
2.0
4.2
0.8
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0.1
0.8
0.2
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0.2
0.7
0.2
1.1
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0.1
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0.8
0.6
0.3
0.4
26
24
12
22
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15
22
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24
2.3
0.2
1.3
4.9
1.0
1.5
1.5
1.6
0.5
0.4
0.9
0.4
0.6
0.7
0.5
0.6
0.7
0.7
190
310
3500
460
5300
6700
5700
630
170
200
330
310
2800
3600
250
960
400
400
0.3
0.5
0.1
0.2
0.1
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0.2
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0.1
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0.10
0.03
0.08
0.22
0.08
0.11
0.11
0.14
0.01
0.02
0.03
0.02
0.03
0.04
0.03
0.09
0.06
0.02
100
120
1743
220
2120
1621
012
011
011
012
013
012
012
013
092
3.5
3.3
8.5
7.7
2524
1217
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2.7
4.9
3.4
1117
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103.
519
064
150
1800
6713
012
062
9313
018
071
8016
098
9813
013
0
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDD
epth
From To
Lith
olog
y
Uni
tsSo
lids
Con
tent
Silv
er (A
g)ug
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lum
inum
(Al)
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enic
(As)
ug/g
Bar
ium
(Ba)
ug/g
Ber
yliu
m (B
e)ug
/gB
oron
(B)
ug/g
Bis
mut
h (B
i)ug
/gC
alci
um (C
a)ug
/gC
adm
ium
(Cd)
ug/g
Cob
alt (
Co)
ug/g
Chr
omiu
m (C
r)ug
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oppe
r (C
u)ug
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n (F
e)ug
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otas
sium
(K)
ug/g
Lith
ium
(Li)
ug/g
Mag
nesi
um (M
g)ug
/gM
anga
nese
(Mn)
ug/g
Mol
ybde
num
(Mo)
ug/g
Sod
ium
(Na)
ug/g
Nic
kel (
Ni)
ug/g
Lead
(Pb)
ug/g
Ant
imon
y (S
b)ug
/gS
elen
ium
(Se)
ug/g
Tin
(Sn)
ug/g
Tita
nium
(Ti)
ug/g
Thal
ium
(Tl)
ug/g
Ura
nium
(U)
ug/g
Van
adiu
m (V
)ug
/gY
ttriu
m (Y
)ug
/gZi
nc (Z
n)ug
/g
E41
5991
E41
6050
E41
6139
E41
6152
E41
6544
E42
9326
E42
9787
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7184
E44
7259
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7267
E44
7461
E44
7481
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6338
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6340
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6343
16.8
069
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196.
0026
1.00
128.
7032
4.00
100.
0010
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56.0
013
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129.
7032
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101.
0011
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57.0
013
1.50
15.7
063
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VM
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M1
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1V
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M1
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M1
Vol
cV
olc
Vol
cV
olc
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low
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olc
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olc
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low
)
0.20
0.29
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0.13
0.16
0.13
0.10
0.11
0.14
0.12
0.16
0.29
0.20
0.14
0.14
0.18
5700
075
000
6300
041
000
6000
056
000
6400
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000
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075
000
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059
000
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000
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000
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2810
341
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000
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000
4000
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000
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013
047
130
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550
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4880
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120
5013
029
3066
5083
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000
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064
000
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010
4000
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000
6000
041
000
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000
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1050
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000
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075
000
2100
1800
019
000
750
1200
071
0013
000
9600
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500
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000
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022
000
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000
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029
000
3100
035
000
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014
000
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000
2600
026
000
1400
1900
1200
1600
1600
1300
1100
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2000
1700
1200
1200
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50.
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550.
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0.32
0.11
6900
3100
3200
2800
4000
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6500
6200
7900
7900
1400
098
0019
000
1800
067
0012
000
1600
018
000
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9544
4960
4310
080
7673
5969
1315
6242
511.
83.
51.
414
3.2
0.9
1.7
2.9
1.3
5.3
1.8
2.0
3.5
0.9
2.0
3.4
0.2
0.6
0.5
0.2
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0.8
0.4
0.4
0.5
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0.3
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0.4
0.3
0.6
0.2
0.1
0.2
0.2
0.6
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57
2<1
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2<1
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11
0.6
0.3
0.4
3.1
0.4
0.5
0.4
0.3
0.5
0.5
0.3
0.3
0.5
1.6
0.4
0.3
0.8
1.0
160
260
380
9416
023
028
019
027
0035
028
015
013
0071
0011
0023
035
046
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30.
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020.
030.
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020.
050.
050.
020.
020.
020.
020.
020.
020.
120.
100.
020.
060.
0821
012
010
032
190
200
180
9620
010
023
016
013
018
9.3
110
100
110
4.2
2.3
3.1
7.1
3.7
4.8
4.9
2.7
118.
74.
12.
78.
027
125.
16.
631
7416
068
1000
110
110
8383
7780
7337
100
160
130
8885
89
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDD
epth
From To
Lith
olog
y
Uni
tsSo
lids
Con
tent
Silv
er (A
g)ug
/gA
lum
inum
(Al)
ug/g
Ars
enic
(As)
ug/g
Bar
ium
(Ba)
ug/g
Ber
yliu
m (B
e)ug
/gB
oron
(B)
ug/g
Bis
mut
h (B
i)ug
/gC
alci
um (C
a)ug
/gC
adm
ium
(Cd)
ug/g
Cob
alt (
Co)
ug/g
Chr
omiu
m (C
r)ug
/gC
oppe
r (C
u)ug
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n (F
e)ug
/gP
otas
sium
(K)
ug/g
Lith
ium
(Li)
ug/g
Mag
nesi
um (M
g)ug
/gM
anga
nese
(Mn)
ug/g
Mol
ybde
num
(Mo)
ug/g
Sod
ium
(Na)
ug/g
Nic
kel (
Ni)
ug/g
Lead
(Pb)
ug/g
Ant
imon
y (S
b)ug
/gS
elen
ium
(Se)
ug/g
Tin
(Sn)
ug/g
Tita
nium
(Ti)
ug/g
Thal
ium
(Tl)
ug/g
Ura
nium
(U)
ug/g
Van
adiu
m (V
)ug
/gY
ttriu
m (Y
)ug
/gZi
nc (Z
n)ug
/g
E44
6344
E44
6348
E44
6349
E44
6350
E44
6351
E44
6352
E44
6362
E44
6365
E55
6364
E44
6346
E44
6347
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c (C
ntl)
Vol
c (C
ntl)
Vol
c/S
edV
olc/
Sed
0.20
0.18
0.17
0.28
0.16
0.18
0.26
0.15
0.34
0.20
0.19
6400
059
000
6300
063
000
6600
059
000
7000
064
000
6700
070
000
6200
010
23<2
74
415
2718
53
180
200
1624
045
250
210
110
170
170
180
0.4
0.2
0.3
0.4
<0.1
0.3
0.6
0.3
0.3
0.5
0.4
4<3
45
<3<3
86
7<3
<3<0
.06
<0.0
6<0
.06
<0.0
60.
24<0
.06
<0.0
60.
09<0
.06
<0.0
6<0
.06
5200
042
000
3500
041
000
5500
049
000
4000
069
000
6200
036
000
4100
00.
130.
130.
180.
160.
090.
140.
140.
220.
260.
100.
1336
3637
3741
3252
4037
4342
2447
5150
6239
7065
8628
2086
4469
8611
042
5996
7798
8074
000
9200
094
000
7500
083
000
8500
087
000
7800
072
000
7700
082
000
8000
7700
220
8000
2700
1000
012
000
6800
7200
5900
5900
1219
1419
3313
3629
2925
2520
000
2900
029
000
1600
032
000
1900
016
000
2600
031
000
1800
020
000
1400
1500
1300
1100
1400
1500
1300
1500
1300
1100
1300
0.32
0.24
0.22
0.29
0.08
<0.0
50.
461.
32.
20.
410.
1418
000
1300
023
000
1900
015
000
1700
019
000
1000
011
000
1500
011
000
4546
4545
6038
4966
6671
640.
81.
50.
61.
91.
80.
83.
01.
310
0.7
0.8
0.1
1.3
0.6
0.3
0.2
<0.1
0.7
0.4
0.3
0.4
0.2
22
<12
22
1<1
12
10.
40.
30.
60.
40.
20.
30.
70.
80.
50.
50.
326
025
056
0029
013
039
061
023
042
042
034
0<0
.10.
1<0
.10.
1<0
.1<0
.10.
2<0
.1<0
.10.
30.
20.
060.
050.
090.
060.
010.
060.
150.
030.
150.
060.
0695
100
120
100
120
9910
021
018
014
014
05.
96.
225
6.6
3.1
7.0
7.2
3.4
3.5
6.4
6.5
7586
120
9311
088
8213
013
011
010
0
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDE
4146
20E
4146
88E
4165
07E
4300
13E
4468
47E
4463
35E
4463
36E
4463
37E
4463
45E
4463
66E
4463
53E
4463
54E
4463
55E
4463
56E
4463
57E
4463
58E
4463
59D
epth
From
109.
2015
4.70
96.8
032
0.00
11.0
0To
110.
2015
5.70
97.8
032
1.00
12.0
0
Lith
olog
yFP
FPFP
FPFP
Por
ph (M
T)P
orph
(MT)
Por
ph (M
T)P
orph
(MT)
Por
ph(M
T)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)U
nits
SPLP
Che
mis
try
Alu
min
um (A
l)m
g/L
2.55
2.35
0.83
0.80
0.67
0.49
50.
576
0.70
00.
686
0.49
80.
353
0.56
00.
440
0.42
10.
330
0.51
0A
rsen
ic (A
s)m
g/L
0.06
040.
0107
0.01
760.
0206
0.01
400.
0018
0.00
730.
0181
0.02
680.
0104
0.04
500.
0703
0.01
390.
0025
0.00
880.
0022
Silv
er (A
g)m
g/L
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
Bar
ium
(Ba)
mg/
L0.
933
0.87
00.
766
0.85
80.
244
0.67
30.
656
0.74
10.
694
0.66
10.
699
0.64
30.
851
0.78
20.
849
0.71
9B
eryl
ium
(Be)
mg/
L0.
0001
80.
0000
80.
0000
80.
0000
5<0
.000
04<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4B
oron
(B)
mg/
L0.
486
0.42
20.
406
0.57
10.
007
0.29
50.
251
0.26
10.
324
0.41
40.
350
0.36
50.
481
0.41
30.
393
0.43
6B
ism
uth
(Bi)
mg/
L0.
0000
5<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
020.
0000
3<0
.000
02<0
.000
020.
0000
3<0
.000
02<0
.000
02<0
.000
020.
0000
2C
alci
um (C
a)m
g/L
6.04
7.19
7.35
5.99
9.01
7.51
7.84
8.61
7.71
5.57
6.44
4.25
7.16
5.35
7.44
5.84
Cad
miu
m (C
d)m
g/L
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
Cob
alt (
Co)
mg/
L0.
0007
000.
0002
660.
0000
820.
0001
620.
0000
360.
0000
890.
0000
920.
0001
080.
0000
980.
0000
510.
0001
080.
0001
540.
0001
050.
0000
500.
0000
570.
0000
59C
hrom
ium
(Cr)
mg/
L0.
0016
0.00
110.
0009
0.00
15<0
.000
30.
0007
0.00
100.
0005
0.00
060.
0009
0.00
080.
0019
0.00
090.
0008
0.00
070.
0008
Cop
per (
Cu)
mg/
L0.
0008
0.00
050.
0006
0.00
050.
0005
0.00
070.
0013
0.00
110.
0006
0.00
050.
0005
0.00
100.
0006
0.00
070.
0007
0.00
10Iro
n (F
e)m
g/L
0.54
0.64
0.08
0.07
<0.0
10.
070.
180.
080.
100.
070.
090.
210.
050.
040.
030.
07P
otas
sium
(K)
mg/
L<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
0.90
0.82
2.61
1.42
0.92
0.66
0.85
0.83
1.03
0.83
1.04
Lith
ium
(Li)
mg/
L1.
410.
964
1.36
1.44
1.25
<0.0
007
<0.0
007
<0.0
007
<0.0
007
0.00
220.
0011
0.00
100.
0015
<0.0
007
0.00
080.
0011
Mag
nesi
um (M
g)m
g/L
1.00
1.23
1.31
0.83
32.
222.
452.
142.
122.
733.
342.
18M
anga
nses
(Mn)
mg/
L0.
0010
40.
0000
90.
0004
00.
0001
90.
0001
20.
0012
40.
0034
90.
0108
0.00
385
0.00
353
0.00
741
0.00
874
0.00
485
0.01
290.
0020
90.
0103
Mol
ybde
num
(Mo)
mg/
L13
.411
.410
.513
.92.
150.
0006
40.
0013
20.
0007
40.
0004
10.
0002
60.
0002
20.
0002
40.
0004
20.
0002
00.
0003
70.
0002
4S
odiu
m (N
a)m
g/L
0.00
180.
0007
<0.0
007
0.00
07<0
.000
78.
786.
798.
168.
3010
.79.
398.
919.
728.
077.
688.
86N
icke
l (N
i)m
g/L
0.00
064
0.00
134
<0.0
0002
0.00
007
0.00
017
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
0.00
070.
0016
<0.0
007
<0.0
007
<0.0
007
<0.0
007
Lead
(Pb)
mg/
L0.
0021
0.00
120.
0010
0.00
250.
0014
0.00
091
0.00
064
0.00
039
0.00
154
0.00
106
0.00
072
0.00
101
0.00
081
0.00
209
0.00
045
0.00
047
Ant
imon
y (S
b)m
g/L
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
030.
0004
0.00
150.
0009
0.00
130.
0033
0.00
330.
0020
0.00
170.
0029
0.00
320.
0017
Sel
eniu
m (S
e)m
g/L
0.00
08<0
.000
30.
0004
0.00
04<0
.000
3<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
Tin
(Sn)
mg/
L0.
0273
0.02
550.
0178
0.02
33<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3S
tont
ium
(Sr)
mg/
L0.
0143
0.03
520.
0432
0.04
630.
0397
0.04
790.
0487
0.03
890.
0529
0.03
710.
0439
0.04
54Ti
tani
um (T
i)m
g/L
0.01
160.
0114
0.00
360.
0024
<0.0
002
0.00
140.
0135
0.00
200.
0021
0.00
130.
0007
0.00
140.
0010
0.00
100.
0009
0.00
11Th
aliu
m (T
l)m
g/L
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
Ura
nium
(U)
mg/
L0.
0001
70.
0001
60.
0000
90.
0000
70.
0001
20.
0000
7<0
.000
020.
0001
20.
0001
00.
0000
40.
0000
20.
0000
20.
0000
40.
0000
3<0
.000
020.
0000
2V
anad
ium
(V)
mg/
L0.
0022
90.
0017
10.
0009
50.
0012
90.
0005
70.
0020
30.
0029
80.
0013
70.
0012
00.
0013
20.
0015
20.
0016
60.
0009
00.
0006
80.
0012
50.
0008
2Tu
ngst
en (W
)m
g/L
0.00
050
0.00
021
0.00
030
0.00
024
0.00
031
0.00
010
0.00
040
0.00
026
<0.0
0007
0.00
053
0.00
024
0.00
024
0.00
032
0.00
014
0.00
031
0.00
029
Yttr
ium
(Y)
mg/
L<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
40.
0000
400.
0000
370.
0000
450.
0000
450.
0000
700.
0000
470.
0000
720.
0000
600.
0000
570.
0000
330.
0000
62Zi
nc (Z
n)m
g/L
0.18
50.
152
0.13
90.
218
0.00
270.
0871
0.08
040.
0586
0.09
600.
126
0.10
90.
112
0.22
70.
215
0.21
20.
193
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDD
epth
From To
Lith
olog
y
Uni
tsSP
LP C
hem
istr
y
Alu
min
um (A
l)m
g/L
Ars
enic
(As)
mg/
LS
ilver
(Ag)
mg/
LB
ariu
m (B
a)m
g/L
Ber
yliu
m (B
e)m
g/L
Bor
on (B
)m
g/L
Bis
mut
h (B
i)m
g/L
Cal
cium
(Ca)
mg/
LC
adm
ium
(Cd)
mg/
LC
obal
t (C
o)m
g/L
Chr
omiu
m (C
r)m
g/L
Cop
per (
Cu)
mg/
LIro
n (F
e)m
g/L
Pot
assi
um (K
)m
g/L
Lith
ium
(Li)
mg/
LM
agne
sium
(Mg)
mg/
LM
anga
nses
(Mn)
mg/
LM
olyb
denu
m (M
o)m
g/L
Sod
ium
(Na)
mg/
LN
icke
l (N
i)m
g/L
Lead
(Pb)
mg/
LA
ntim
ony
(Sb)
mg/
LS
elen
ium
(Se)
mg/
LTi
n (S
n)m
g/L
Sto
ntiu
m (S
r)m
g/L
Tita
nium
(Ti)
mg/
LTh
aliu
m (T
l)m
g/L
Ura
nium
(U)
mg/
LV
anad
ium
(V)
mg/
LTu
ngst
en (W
)m
g/L
Yttr
ium
(Y)
mg/
LZi
nc (Z
n)m
g/L
E44
6360
E44
6361
E44
6363
E43
1875
E43
1918
E42
9186
E42
9259
E42
9712
E43
0756
E47
1903
E41
4574
E41
4780
E41
4794
E41
6101
E41
6463
E42
8991
E42
9051
E42
9111
131.
6118
0.74
210.
5527
2.00
39.0
014
2.10
258.
0049
.60
83.2
012
7.80
122.
6545
.00
50.0
010
1.00
151.
0013
3.04
182.
0021
1.30
273.
0040
.00
142.
8525
8.98
50.6
084
.20
128.
8012
3.65
46.0
051
.00
102.
0015
2.00
Por
ph(P
LP)
Por
ph(P
LP)
Sed
SS
10S
S10
SS
8S
S8
SS
8S
S8
SS
8V
MV
MV
MV
MV
MV
MV
MV
M
0.35
61.
150.
346
0.23
0.07
0.24
0.33
0.34
0.44
0.21
0.44
0.34
0.52
0.18
0.24
0.59
0.36
0.94
0.03
440.
0593
0.02
33<0
.000
5<0
.000
50.
0015
0.00
140.
0228
0.04
860.
0006
0.00
16<0
.000
50.
0007
0.00
080.
0006
0.01
020.
0011
<0.0
005
<0.0
001
<0.0
001
<0.0
001
<0.0
0003
0.00
004
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
0.88
60.
948
0.83
80.
217
0.31
20.
588
0.56
20.
647
0.58
60.
590
0.66
80.
617
0.67
90.
531
0.56
20.
674
0.74
30.
178
<0.0
004
<0.0
004
<0.0
004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
0.00
006
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
0.44
00.
521
0.32
80.
013
0.23
40.
323
0.27
10.
321
0.38
20.
281
0.31
40.
248
0.37
10.
283
0.30
10.
256
0.33
70.
005
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
5.90
6.17
11.8
14.8
16.3
9.85
10.3
10.3
8.56
14.5
7.16
8.62
7.81
8.14
8.08
8.00
7.81
8.38
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
0.00
0036
0.00
0360
0.00
0155
0.00
0011
<0.0
0001
<0.0
0001
0.00
0070
0.00
0231
0.00
0064
0.00
0045
0.00
0007
<0.0
0001
<0.0
0001
<0.0
0001
0.00
0027
0.00
0062
0.00
0023
<0.0
0001
0.00
080.
0019
0.00
09<0
.000
30.
0004
0.00
060.
0007
0.00
130.
0007
0.00
070.
0007
0.00
050.
0007
0.00
060.
0007
0.00
060.
0009
<0.0
003
0.00
060.
0010
0.00
170.
0002
0.00
050.
0007
0.00
070.
0024
0.00
060.
0007
0.00
030.
0003
0.00
02<0
.000
10.
0004
0.00
060.
0003
0.00
020.
020.
160.
18<0
.01
<0.0
1<0
.01
0.03
0.08
0.09
0.03
0.02
<0.0
1<0
.01
<0.0
10.
010.
06<0
.01
<0.0
10.
621.
552.
33<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
0.00
100.
0012
<0.0
007
2.77
1.66
2.93
2.22
1.76
0.55
53.
681.
852.
730.
952
2.19
1.39
0.64
62.
260.
954
2.42
1.76
2.42
0.00
260
0.02
710.
0091
10.
0021
90.
0049
70.
0001
00.
0012
90.
0003
40.
0006
10.
0004
80.
0000
90.
0001
10.
0001
00.
0000
50.
0001
40.
0001
30.
0000
60.
0000
70.
0001
90.
0002
30.
0003
01.
836.
167.
668.
458.
979.
247.
909.
476.
457.
858.
637.
956.
928.
041.
358.
9210
.37.
64<0
.000
70.
0016
<0.0
007
0.00
180.
0013
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
0.00
11<0
.000
70.
0025
0.00
080.
0001
50.
0002
5<0
.000
020.
0002
60.
0000
9<0
.000
020.
0001
9<0
.000
02<0
.000
02<0
.000
020.
0002
0<0
.000
02<0
.000
02<0
.000
020.
0001
70.
0004
50.
0056
60.
0003
50.
0020
0.00
090.
0024
0.00
310.
0028
0.00
200.
0052
0.00
040.
0004
0.00
070.
0013
0.00
050.
0009
0.00
180.
0017
0.00
360.
0042
0.00
25<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
030.
005
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
01<0
.001
<0.0
01<0
.000
3<0
.000
30.
0005
<0.0
003
0.00
03<0
.000
30.
0007
<0.0
003
<0.0
003
<0.0
003
<0.0
003
0.00
05<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
30.
0317
0.01
590.
0221
0.02
020.
0127
0.02
440.
0293
0.01
340.
0190
0.01
990.
0503
0.05
110.
0345
0.03
400.
0440
0.02
270.
0200
0.04
670.
0010
0.00
290.
0015
<0.0
002
0.00
12<0
.000
20.
0013
0.00
360.
0016
0.00
040.
0005
<0.0
002
0.00
020.
0004
0.00
050.
0016
0.00
06<0
.000
2<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
020.
0001
3<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
020.
0014
00.
0024
50.
0008
6<0
.000
060.
0001
30.
0002
90.
0008
50.
0008
70.
0045
30.
0003
70.
0021
70.
0005
20.
0012
00.
0006
70.
0003
80.
0028
00.
0013
20.
0019
70.
0001
60.
0006
80.
0016
10.
0007
4<0
.000
070.
0001
3<0
.000
070.
0001
50.
0003
20.
0001
5<0
.000
070.
0001
00.
0000
9<0
.000
070.
0002
00.
0000
90.
0000
9<0
.000
070.
0000
620.
0001
880.
0000
51<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
40.
273
0.26
90.
181
0.00
610.
0539
0.10
20.
0723
0.10
90.
0937
0.07
610.
105
0.06
360.
148
0.09
070.
0913
0.08
070.
124
0.00
27
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDD
epth
From To
Lith
olog
y
Uni
tsSP
LP C
hem
istr
y
Alu
min
um (A
l)m
g/L
Ars
enic
(As)
mg/
LS
ilver
(Ag)
mg/
LB
ariu
m (B
a)m
g/L
Ber
yliu
m (B
e)m
g/L
Bor
on (B
)m
g/L
Bis
mut
h (B
i)m
g/L
Cal
cium
(Ca)
mg/
LC
adm
ium
(Cd)
mg/
LC
obal
t (C
o)m
g/L
Chr
omiu
m (C
r)m
g/L
Cop
per (
Cu)
mg/
LIro
n (F
e)m
g/L
Pot
assi
um (K
)m
g/L
Lith
ium
(Li)
mg/
LM
agne
sium
(Mg)
mg/
LM
anga
nses
(Mn)
mg/
LM
olyb
denu
m (M
o)m
g/L
Sod
ium
(Na)
mg/
LN
icke
l (N
i)m
g/L
Lead
(Pb)
mg/
LA
ntim
ony
(Sb)
mg/
LS
elen
ium
(Se)
mg/
LTi
n (S
n)m
g/L
Sto
ntiu
m (S
r)m
g/L
Tita
nium
(Ti)
mg/
LTh
aliu
m (T
l)m
g/L
Ura
nium
(U)
mg/
LV
anad
ium
(V)
mg/
LTu
ngst
en (W
)m
g/L
Yttr
ium
(Y)
mg/
LZi
nc (Z
n)m
g/L
E42
9867
E42
9962
E43
0694
E43
0723
E43
0787
E43
0991
E43
1039
E43
1807
E44
6417
E44
6913
E44
6973
E44
7310
E44
7328
E44
7504
E44
7522
E47
1636
E47
1732
E41
4703
167.
0024
0.00
30.0
086
.00
199.
0014
.00
100.
0050
.00
219.
6062
.00
122.
0017
0.00
260.
0013
1.00
196.
0069
.00
150.
0021
0.50
168.
0024
1.00
31.0
087
.00
200.
0015
.00
101.
0051
.50
220.
6063
.00
123.
0017
1.00
261.
0013
2.50
197.
5070
.00
151.
0021
1.50
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
1
0.25
0.56
0.18
0.16
0.49
0.84
1.06
0.63
0.49
0.74
0.51
0.57
0.52
0.55
0.46
0.30
0.37
0.53
0.00
950.
0005
0.00
190.
0071
0.00
080.
0014
<0.0
005
0.00
13<0
.000
50.
0020
<0.0
005
<0.0
005
0.00
28<0
.000
5<0
.000
50.
0008
0.00
530.
0005
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
0.53
80.
263
0.55
50.
606
0.59
00.
182
0.20
40.
224
0.70
10.
232
0.58
50.
645
0.73
40.
588
0.57
40.
665
0.65
10.
692
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
0.00
005
<0.0
0004
0.00
007
<0.0
0004
<0.0
0004
<0.0
0004
0.26
10.
012
0.30
70.
290
0.25
40.
007
0.00
70.
012
0.30
80.
012
0.29
70.
358
0.34
80.
281
0.26
80.
342
0.31
60.
398
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
11.6
9.12
11.7
17.1
7.01
8.36
9.09
9.72
7.49
8.22
7.69
7.01
6.42
6.82
7.22
8.16
8.11
6.75
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
0.00
0024
<0.0
0001
0.00
0009
0.00
0047
0.00
0042
<0.0
0001
<0.0
0001
<0.0
0001
0.00
0069
<0.0
0001
0.00
0024
<0.0
0001
0.00
0047
0.00
0022
0.00
0011
0.00
0012
<0.0
0001
0.00
0008
0.00
04<0
.000
30.
0006
0.00
050.
0004
<0.0
003
<0.0
003
<0.0
003
0.00
15<0
.000
30.
0006
0.00
080.
0010
0.00
050.
0006
0.00
080.
0005
0.00
130.
0005
0.00
030.
0002
0.00
020.
0005
<0.0
001
0.00
050.
0002
0.00
09<0
.000
10.
0004
0.00
030.
0004
0.00
030.
0003
0.00
040.
0004
0.00
03<0
.01
<0.0
10.
02<0
.01
0.05
<0.0
1<0
.01
<0.0
10.
15<0
.01
0.01
0.02
0.05
0.02
0.01
<0.0
10.
010.
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
022.
942.
851.
843.
120.
514
0.55
90.
431
1.32
1.13
2.76
0.88
30.
673
0.56
70.
625
0.72
22.
391.
520.
797
0.00
016
0.00
006
0.00
054
0.00
091
0.00
014
0.00
015
0.00
016
0.00
019
0.00
008
<0.0
001
0.00
007
0.00
012
0.00
009
0.00
005
0.00
005
0.00
010
0.00
006
0.00
013
8.45
1.97
8.40
7.53
6.08
1.83
1.95
3.28
8.74
1.99
6.31
8.98
8.01
6.75
6.16
8.90
9.14
8.57
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
0.00
004
0.00
014
0.00
022
<0.0
0002
<0.0
0002
0.00
015
0.00
018
0.00
012
<0.0
0002
0.00
020
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
0.00
200.
0011
<0.0
002
0.00
10<0
.000
20.
0003
0.00
040.
0010
0.00
060.
0007
0.00
080.
0003
0.00
03<0
.000
20.
0017
0.00
220.
0014
0.00
08<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
03<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
30.
0003
<0.0
003
0.00
04<0
.000
30.
0004
0.00
04<0
.000
3<0
.000
30.
0178
0.02
450.
0188
0.01
830.
0229
0.02
050.
0221
0.01
870.
0301
0.02
070.
0180
0.02
200.
0171
0.02
830.
0273
0.03
960.
0196
0.01
240.
0003
<0.0
002
0.00
080.
0004
0.00
51<0
.000
20.
0002
<0.0
002
0.00
48<0
.000
20.
0004
0.00
080.
0028
0.00
130.
0005
0.00
040.
0004
0.00
08<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
02<0
.000
020.
0008
60.
0011
80.
0001
0<0
.000
060.
0035
30.
0005
60.
0004
10.
0001
50.
0024
30.
0012
10.
0012
80.
0020
00.
0045
30.
0034
70.
0021
40.
0007
30.
0006
60.
0028
00.
0001
90.
0005
50.
0082
00.
0002
70.
0003
00.
0006
6<0
.000
070.
0002
70.
0001
6<0
.000
070.
0000
8<0
.000
070.
0002
80.
0000
80.
0001
40.
0001
00.
0001
10.
0002
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
40.
0705
0.00
320.
110
0.07
360.
0733
0.00
280.
0034
0.00
330.
105
0.00
470.
0956
0.12
00.
125
0.09
820.
0949
0.09
130.
0854
0.14
4
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDD
epth
From To
Lith
olog
y
Uni
tsSP
LP C
hem
istr
y
Alu
min
um (A
l)m
g/L
Ars
enic
(As)
mg/
LS
ilver
(Ag)
mg/
LB
ariu
m (B
a)m
g/L
Ber
yliu
m (B
e)m
g/L
Bor
on (B
)m
g/L
Bis
mut
h (B
i)m
g/L
Cal
cium
(Ca)
mg/
LC
adm
ium
(Cd)
mg/
LC
obal
t (C
o)m
g/L
Chr
omiu
m (C
r)m
g/L
Cop
per (
Cu)
mg/
LIro
n (F
e)m
g/L
Pot
assi
um (K
)m
g/L
Lith
ium
(Li)
mg/
LM
agne
sium
(Mg)
mg/
LM
anga
nses
(Mn)
mg/
LM
olyb
denu
m (M
o)m
g/L
Sod
ium
(Na)
mg/
LN
icke
l (N
i)m
g/L
Lead
(Pb)
mg/
LA
ntim
ony
(Sb)
mg/
LS
elen
ium
(Se)
mg/
LTi
n (S
n)m
g/L
Sto
ntiu
m (S
r)m
g/L
Tita
nium
(Ti)
mg/
LTh
aliu
m (T
l)m
g/L
Ura
nium
(U)
mg/
LV
anad
ium
(V)
mg/
LTu
ngst
en (W
)m
g/L
Yttr
ium
(Y)
mg/
LZi
nc (Z
n)m
g/L
E41
5991
E41
6050
E41
6139
E41
6152
E41
6544
E42
9326
E42
9787
E44
7184
E44
7259
E44
7267
E44
7461
E44
7481
E44
6338
E44
6340
E44
6341
E44
6339
E44
6342
E44
6343
16.8
069
.00
196.
0026
1.00
128.
7032
4.00
100.
0010
.00
56.0
013
0.50
14.7
062
.30
17.8
070
.00
197.
0026
2.00
129.
7032
5.00
101.
0011
.00
57.0
013
1.50
15.7
063
.30
VM
1V
M1
VM
1V
M1
VM
1V
M1
VM
1V
M1
VM
1V
M1
VM
1V
M1
Vol
cV
olc
Vol
cV
olc
(99F
low
)V
olc
(99F
low
)V
olc
(99F
low
)
0.31
0.16
0.30
0.25
0.27
0.31
0.59
0.25
0.49
0.50
0.85
0.28
0.49
70.
600
0.26
40.
504
0.32
50.
319
<0.0
005
0.00
760.
0173
0.00
780.
0021
<0.0
005
<0.0
005
0.00
16<0
.000
50.
0006
<0.0
005
0.00
88<0
.000
20.
0004
0.00
050.
0007
<0.0
002
<0.0
002
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
0003
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
0.54
10.
579
0.60
50.
546
0.71
10.
686
0.20
00.
621
0.72
80.
634
0.17
00.
545
0.64
90.
654
0.60
20.
669
0.66
50.
641
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
0004
0.00
009
<0.0
0004
<0.0
0004
<0.0
0004
<0.0
004
<0.0
004
<0.0
004
<0.0
004
<0.0
004
<0.0
004
0.30
50.
260
0.27
20.
239
0.36
90.
283
0.00
70.
287
0.35
70.
300
0.00
50.
233
0.26
90.
262
0.28
50.
264
0.29
30.
277
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
0.00
005
0.00
002
<0.0
0002
8.57
7.99
8.17
7.59
7.41
10.2
10.5
6.84
6.80
6.82
7.55
7.69
7.47
8.91
8.92
7.61
8.41
7.39
0.00
010
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
0.00
0071
0.00
0013
<0.0
0001
<0.0
0001
0.00
0018
0.00
0017
<0.0
0001
0.00
0014
0.00
0023
0.00
0016
<0.0
0001
0.00
0018
0.00
0037
0.00
0075
0.00
0059
0.00
0058
0.00
0038
0.00
0025
0.00
060.
0005
0.00
050.
0005
0.00
090.
0006
<0.0
003
0.00
070.
0008
0.00
07<0
.000
30.
0006
0.00
050.
0005
0.00
050.
0007
0.00
050.
0005
0.00
020.
0001
0.00
080.
0002
0.00
040.
0003
<0.0
001
0.00
070.
0004
0.00
030.
0003
0.00
020.
0011
0.00
080.
0008
0.00
110.
0010
0.00
04<0
.01
<0.0
1<0
.01
<0.0
10.
01<0
.01
<0.0
1<0
.01
0.02
0.02
<0.0
1<0
.01
0.02
0.05
0.16
0.02
0.04
0.04
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
0.29
0.26
0.26
0.54
0.37
0.24
2.06
2.27
2.93
2.70
2.33
2.71
2.98
1.85
0.56
90.
645
0.81
53.
34<0
.000
7<0
.000
7<0
.000
7<0
.000
7<0
.000
7<0
.000
70.
722
0.48
60.
419
0.57
51.
780.
506
0.00
014
0.00
007
0.00
008
0.00
006
0.00
010
0.00
019
<0.0
001
0.00
009
0.00
010
0.00
007
<0.0
001
0.00
014
0.00
072
0.00
111
0.00
439
0.00
070
0.00
090
0.00
077
9.18
7.88
7.29
8.34
9.67
7.97
1.37
7.03
7.90
7.47
1.37
8.33
0.00
067
0.00
028
0.00
072
0.00
033
0.00
059
0.00
025
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
6.58
5.76
5.89
6.21
6.38
5.34
0.00
035
0.00
025
0.00
034
0.00
025
<0.0
0002
<0.0
0002
0.00
032
<0.0
0002
<0.0
0002
<0.0
0002
0.00
017
0.00
029
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
<0.0
007
0.00
080.
0010
0.00
080.
0006
0.00
050.
0009
0.00
090.
0002
0.00
04<0
.000
20.
0008
0.00
040.
0010
80.
0003
50.
0002
60.
0006
90.
0003
30.
0002
3<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
03<0
.003
<0.0
030.
0004
0.00
050.
0002
0.00
040.
0006
0.00
04<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
30.
0005
<0.0
003
0.00
030.
0005
<0.0
003
<0.0
003
<0.0
003
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
0.01
700.
0232
0.01
200.
0172
0.01
49<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
30.
0220
0.01
360.
0134
0.02
130.
0255
0.01
770.
0121
0.03
000.
0459
0.02
780.
0259
0.04
360.
0380
0.00
060.
0009
0.00
040.
0002
0.00
06<0
.000
2<0
.000
2<0
.000
20.
0009
0.00
06<0
.000
20.
0002
0.00
080.
0022
0.00
090.
0004
0.00
060.
0028
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
0.00
073
0.00
118
0.00
167
0.00
136
0.00
133
0.00
046
0.00
076
0.00
099
0.00
235
0.00
249
0.00
246
0.00
102
0.00
344
0.00
023
0.00
012
0.00
232
0.00
067
0.00
143
<0.0
0007
<0.0
0007
0.00
070
0.00
037
0.00
030
0.00
008
0.00
007
0.00
012
0.00
025
0.00
008
0.00
009
0.00
017
<0.0
0007
0.00
013
<0.0
0007
0.00
014
<0.0
0007
<0.0
0007
<0.0
004
<0.0
004
<0.0
004
<0.0
004
<0.0
004
<0.0
004
<0.0
004
<0.0
004
<0.0
004
<0.0
004
<0.0
004
<0.0
004
0.00
0017
0.00
0045
0.00
0030
0.00
0016
0.00
0022
0.00
0033
0.07
280.
0861
0.12
20.
0525
0.10
20.
0795
0.00
350.
0806
0.13
50.
102
0.00
270.
0604
0.08
450.
0839
0.08
850.
0781
0.08
590.
0959
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDD
epth
From To
Lith
olog
y
Uni
tsSP
LP C
hem
istr
y
Alu
min
um (A
l)m
g/L
Ars
enic
(As)
mg/
LS
ilver
(Ag)
mg/
LB
ariu
m (B
a)m
g/L
Ber
yliu
m (B
e)m
g/L
Bor
on (B
)m
g/L
Bis
mut
h (B
i)m
g/L
Cal
cium
(Ca)
mg/
LC
adm
ium
(Cd)
mg/
LC
obal
t (C
o)m
g/L
Chr
omiu
m (C
r)m
g/L
Cop
per (
Cu)
mg/
LIro
n (F
e)m
g/L
Pot
assi
um (K
)m
g/L
Lith
ium
(Li)
mg/
LM
agne
sium
(Mg)
mg/
LM
anga
nses
(Mn)
mg/
LM
olyb
denu
m (M
o)m
g/L
Sod
ium
(Na)
mg/
LN
icke
l (N
i)m
g/L
Lead
(Pb)
mg/
LA
ntim
ony
(Sb)
mg/
LS
elen
ium
(Se)
mg/
LTi
n (S
n)m
g/L
Sto
ntiu
m (S
r)m
g/L
Tita
nium
(Ti)
mg/
LTh
aliu
m (T
l)m
g/L
Ura
nium
(U)
mg/
LV
anad
ium
(V)
mg/
LTu
ngst
en (W
)m
g/L
Yttr
ium
(Y)
mg/
LZi
nc (Z
n)m
g/L
E44
6344
E44
6348
E44
6349
E44
6350
E44
6351
E44
6352
E44
6362
E44
6365
E55
6364
E44
6346
E44
6347
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c (C
ntl)
Vol
c (C
ntl)
Vol
c/S
edV
olc/
Sed
0.36
90.
297
0.49
50.
368
0.38
20.
317
0.84
50.
546
0.47
70.
0002
0.00
06<0
.000
20.
0006
0.00
05<0
.000
20.
0022
0.00
290.
0014
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
0.66
70.
707
0.66
70.
781
0.73
30.
767
0.90
80.
646
0.65
3<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
4<0
.000
40.
295
0.27
90.
292
0.28
90.
316
0.29
10.
402
0.30
10.
289
<0.0
0002
<0.0
0002
<0.0
0002
0.00
003
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
8.04
10.1
7.44
9.03
7.85
10.2
12.0
8.18
8.65
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
<0.0
0006
0.00
0037
0.00
0028
0.00
0044
0.00
0055
0.00
0031
0.00
0017
0.00
0586
0.00
0087
0.00
0049
0.00
060.
0006
0.00
050.
0007
0.00
070.
0005
0.00
160.
0006
0.00
050.
0005
0.00
090.
0009
0.00
060.
0005
0.00
060.
0016
0.00
080.
0005
0.03
<0.0
10.
070.
060.
030.
011.
400.
110.
070.
500.
460.
270.
460.
340.
511.
070.
460.
49<0
.000
7<0
.000
7<0
.000
70.
0013
0.00
160.
0009
0.00
07<0
.000
7<0
.000
71.
312.
670.
720
2.19
1.46
2.13
2.91
0.74
00.
952
0.00
156
0.00
084
0.00
089
0.00
278
0.00
095
0.00
214
0.02
480.
0015
20.
0015
50.
0005
20.
0003
50.
0001
80.
0002
40.
0003
80.
0004
10.
0001
20.
0004
30.
0002
96.
766.
376.
066.
866.
636.
647.
837.
076.
84<0
.000
7<0
.000
7<0
.000
7<0
.000
7<0
.000
7<0
.000
70.
0010
<0.0
007
<0.0
007
0.00
033
0.00
030
0.00
018
0.00
018
0.00
017
0.00
018
0.00
032
0.00
031
0.00
022
0.00
080.
0019
0.00
050.
0015
0.00
440.
0004
0.00
130.
0019
0.00
13<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
003
<0.0
003
<0.0
003
<0.0
003
<0.0
003
<0.0
003
<0.0
003
<0.0
003
<0.0
003
0.03
620.
0337
0.05
660.
0457
0.03
390.
0390
0.04
740.
0317
0.03
240.
0006
0.00
080.
0072
0.00
110.
0008
0.00
050.
0061
0.00
100.
0009
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
<0.0
0002
0.00
095
0.00
059
0.00
189
0.00
130
0.00
123
0.00
053
0.00
253
0.00
271
0.00
161
<0.0
0007
0.00
012
0.00
044
0.00
027
0.00
023
0.00
015
0.00
015
0.00
014
0.00
015
0.00
0018
0.00
0016
0.00
0040
0.00
0025
0.00
0021
0.00
0018
0.00
0123
0.00
0031
0.00
0034
0.08
080.
0904
0.10
00.
0969
0.12
10.
0919
0.25
20.
0996
0.08
75
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDE
4146
20E
4146
88E
4165
07E
4300
13E
4468
47E
4463
35E
4463
36E
4463
37E
4463
45E
4463
66E
4463
53E
4463
54E
4463
55E
4463
56E
4463
57E
4463
58E
4463
59D
epth
From
109.
2015
4.70
96.8
032
0.00
11.0
0To
110.
2015
5.70
97.8
032
1.00
12.0
0
Lith
olog
yFP
FPFP
FPFP
Por
ph (M
T)P
orph
(MT)
Por
ph (M
T)P
orph
(MT)
Por
ph(M
T)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)P
orph
(PLP
)U
nits
Aci
d B
ase
Acc
ount
ing
Pas
te p
Hun
its8.
628.
998.
738.
718.
588.
409.
069.
319.
199.
358.
528.
468.
689.
238.
768.
469.
03S
obec
k N
Pt C
aCO
3/10
237
47.8
54.0
193
230
207
248
239
223
284
118
240
68.6
252
158
183
159
Car
bona
te N
Pt C
aCO
3/10
276.
764
.265
.028
5.9
274.
222
0.0
258.
428
7.5
276.
733
0.9
243.
327
5.0
91.7
289.
216
3.3
216.
716
2.5
AP
t CaC
O3/
102.
54.
25.
93.
15.
12.
96.
30.
3110
.74.
369
.613
.211
.63.
31.
32.
70.
94N
et N
Pt C
aCO
3/10
234
43.5
48.2
190
225
204
241
239
213
279
48.9
226
57.1
249
157
181
158
Sob
eck
NP
/AP
ratio
93.5
11.2
9.2
62.4
45.1
71.9
39.4
771
20.8
65.3
1.7
18.1
5.9
76.8
118
68.2
169
Car
bona
te N
P/A
Pra
tio11
0.7
15.3
11.0
92.2
53.8
75.9
41.0
927.
525
.976
.93.
520
.87.
987
.612
5.6
80.3
172.
9S
2-%
0.08
80.
140.
240.
130.
220.
120.
300.
130.
510.
212.
720.
580.
340.
140.
069
0.08
30.
065
Sul
phid
e%
0.08
0.14
0.19
0.10
0.16
0.09
0.20
<0.0
10.
340.
142.
230.
420.
370.
100.
040.
090.
03S
O4
%<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4C
(t)%
3.32
0.77
0.78
3.43
3.29
2.64
3.10
3.45
3.32
3.97
2.92
3.30
1.10
3.47
1.96
2.60
1.95
Car
bona
te%
15.8
2.94
3.06
17.5
13.9
12.7
13.7
16.3
14.4
19.6
7.79
15.1
4.87
16.1
9.28
11.8
9.13
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDD
epth
From To
Lith
olog
y
Uni
tsA
cid
Bas
e A
ccou
ntin
g
Pas
te p
Hun
itsS
obec
k N
Pt C
aCO
3/10
Car
bona
te N
Pt C
aCO
3/10
AP
t CaC
O3/
10N
et N
Pt C
aCO
3/10
Sob
eck
NP
/AP
ratio
Car
bona
te N
P/A
Pra
tioS
2-%
Sul
phid
e%
SO
4%
C(t)
%C
arbo
nate
%
E44
6360
E44
6361
E44
6363
E43
1875
E43
1918
E42
9186
E42
9259
E42
9712
E43
0756
E47
1903
E41
4574
E41
4780
E41
4794
E41
6101
E41
6463
E42
8991
E42
9051
E42
9111
131.
6118
0.74
210.
5527
2.00
39.0
014
2.10
258.
0049
.60
83.2
012
7.80
122.
6545
.00
50.0
010
1.00
151.
0013
3.04
182.
0021
1.30
273.
0040
.00
142.
8525
8.98
50.6
084
.20
128.
8012
3.65
46.0
051
.00
102.
0015
2.00
Por
ph(P
LP)
Por
ph(P
LP)
Sed
SS
10S
S10
SS
8S
S8
SS
8S
S8
SS
8V
MV
MV
MV
MV
MV
MV
MV
M
8.43
9.05
8.29
8.71
9.07
8.61
9.21
8.84
8.88
8.42
8.69
8.98
9.16
9.20
9.17
8.69
9.35
9.70
226
161
191
84.6
188
182
263
144
141
158
144
155
90.9
112
88.4
130
284
99.3
281.
723
5.0
237.
512
1.7
225.
823
2.5
310.
017
1.7
185.
826
8.4
158.
315
0.0
86.7
113.
310
0.8
209.
232
9.2
113.
332
.923
.44.
813
.50.
3122
.60.
316.
80.
3126
.723
.01.
92.
20.
314.
338
.89.
00.
6219
313
718
671
.118
715
926
313
814
113
212
115
388
.711
284
.191
.127
598
.76.
96.
939
.96.
360
58.
085
021
.345
55.
96.
381
.541
.336
220
.53.
431
.616
08.
610
.049
.59.
072
8.5
10.3
1000
.125
.259
9.5
10.1
6.9
79.0
39.4
365.
623
.55.
436
.618
2.8
1.85
0.89
0.19
0.54
0.09
41.
130.
093
0.34
0.22
1.22
0.97
0.08
20.
090
0.16
0.15
1.43
0.37
0.07
81.
050.
750.
150.
43<0
.01
0.72
<0.0
10.
22<0
.01
0.85
0.74
0.06
0.07
<0.0
10.
141.
240.
290.
02<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.43.
382.
822.
851.
462.
712.
793.
722.
062.
233.
221.
901.
801.
041.
361.
212.
513.
951.
3614
.411
.512
.15.
7112
.312
.117
.29.
2710
.210
.38.
308.
684.
606.
135.
197.
6818
.06.
09
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDD
epth
From To
Lith
olog
y
Uni
tsA
cid
Bas
e A
ccou
ntin
g
Pas
te p
Hun
itsS
obec
k N
Pt C
aCO
3/10
Car
bona
te N
Pt C
aCO
3/10
AP
t CaC
O3/
10N
et N
Pt C
aCO
3/10
Sob
eck
NP
/AP
ratio
Car
bona
te N
P/A
Pra
tioS
2-%
Sul
phid
e%
SO
4%
C(t)
%C
arbo
nate
%
E42
9867
E42
9962
E43
0694
E43
0723
E43
0787
E43
0991
E43
1039
E43
1807
E44
6417
E44
6913
E44
6973
E44
7310
E44
7328
E44
7504
E44
7522
E47
1636
E47
1732
E41
4703
167.
0024
0.00
30.0
086
.00
199.
0014
.00
100.
0050
.00
219.
6062
.00
122.
0017
0.00
260.
0013
1.00
196.
0069
.00
150.
0021
0.50
168.
0024
1.00
31.0
087
.00
200.
0015
.00
101.
0051
.50
220.
6063
.00
123.
0017
1.00
261.
0013
2.50
197.
5070
.00
151.
0021
1.50
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
VM
1
9.50
9.67
9.27
9.28
9.12
8.79
9.11
9.17
9.26
9.67
9.37
9.17
9.23
9.34
9.43
9.23
9.08
9.75
159
84.6
193
185
102
102
153
160
170
81.7
104
127
186
88.4
173
183
180
91.6
173.
310
5.8
200.
019
1.7
99.2
96.7
180.
016
5.0
188.
396
.710
7.5
134.
222
3.3
85.8
222.
520
0.8
210.
811
0.0
0.94
0.31
1.25
1.88
2.50
1.88
1.88
0.62
1.88
1.88
8.12
4.06
11.2
1.56
4.06
4.38
0.31
39.7
158
84.3
192
183
99.1
100
151
160
168
79.9
96.0
123
175
86.9
169
179
180
51.9
169
273
155
98.5
40.6
54.2
81.5
259
90.4
43.5
12.8
31.3
16.6
56.7
42.6
41.8
582
2.3
184.
434
1.4
160.
010
2.0
39.7
51.4
95.8
266.
110
0.2
51.4
13.2
33.0
19.9
55.0
54.8
45.9
680.
22.
80.
078
0.03
30.
088
0.09
00.
084
0.08
40.
068
0.03
90.
084
0.03
70.
284
0.14
60.
397
0.08
30.
170
0.17
00.
025
1.21
0.03
0.01
0.04
0.06
0.08
0.06
0.06
0.02
0.06
0.06
0.26
0.13
0.36
0.05
0.13
0.14
<0.0
11.
27<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.4<0
.42.
081.
272.
402.
301.
191.
162.
161.
982.
261.
161.
291.
612.
681.
032.
672.
412.
531.
329.
965.
6511
.611
.45.
675.
4310
.19.
5810
.75.
136.
107.
6812
.45.
0111
.811
.712
.05.
04
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDD
epth
From To
Lith
olog
y
Uni
tsA
cid
Bas
e A
ccou
ntin
g
Pas
te p
Hun
itsS
obec
k N
Pt C
aCO
3/10
Car
bona
te N
Pt C
aCO
3/10
AP
t CaC
O3/
10N
et N
Pt C
aCO
3/10
Sob
eck
NP
/AP
ratio
Car
bona
te N
P/A
Pra
tioS
2-%
Sul
phid
e%
SO
4%
C(t)
%C
arbo
nate
%
E41
5991
E41
6050
E41
6139
E41
6152
E41
6544
E42
9326
E42
9787
E44
7184
E44
7259
E44
7267
E44
7461
E44
7481
E44
6338
E44
6340
E44
6341
E44
6339
E44
6342
E44
6343
16.8
069
.00
196.
0026
1.00
128.
7032
4.00
100.
0010
.00
56.0
013
0.50
14.7
062
.30
17.8
070
.00
197.
0026
2.00
129.
7032
5.00
101.
0011
.00
57.0
013
1.50
15.7
063
.30
VM
1V
M1
VM
1V
M1
VM
1V
M1
VM
1V
M1
VM
1V
M1
VM
1V
M1
Vol
cV
olc
Vol
cV
olc
(99F
low
)V
olc
(99F
low
)V
olc
(99F
low
)
9.84
9.68
9.73
9.68
9.59
9.61
9.86
9.72
9.38
9.35
8.59
9.28
9.12
8.80
9.40
8.81
8.92
8.79
116
93.5
111
83.3
143
102
152
103
148
124
130
83.4
194
192
273
218
57.6
209
164.
216
0.0
146.
713
9.2
230.
011
6.7
210.
815
8.3
219.
219
7.5
156.
710
4.2
221.
718
5.8
301.
721
5.0
179.
221
2.5
22.2
56.2
15.0
65.3
35.0
60.3
28.7
47.8
10.9
14.7
0.31
7.5
5.3
12.3
2.8
0.8
0.31
2.1
94.3
37.3
96.2
17.9
108
41.3
124
54.8
138
110
130
75.9
188
180
270
217
57.3
207
5.2
1.7
7.4
1.3
4.1
1.7
5.3
2.1
13.6
8.5
421
11.1
36.4
15.6
97.4
279
186
98.5
7.4
2.8
9.8
2.1
6.6
1.9
7.3
3.3
20.1
13.4
505.
413
.941
.815
.110
7.7
268.
857
8.0
101.
20.
737
1.77
0.48
72.
271.
112.
040.
929
1.53
0.41
20.
508
0.01
40.
350.
210.
580.
120.
035
0.04
00.
081
0.71
1.80
0.48
2.09
1.12
1.93
0.92
1.53
0.35
0.47
<0.0
10.
240.
170.
400.
090.
02<0
.01
0.07
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
1.97
1.92
1.76
1.67
2.76
1.40
2.53
1.90
2.63
2.37
1.88
1.25
2.66
2.23
3.62
2.58
2.15
2.55
7.23
5.28
6.95
4.33
8.46
5.70
9.65
6.24
10.3
7.61
8.75
5.19
12.9
10.8
17.7
12.6
10.5
12.2
App
endi
x 1
Com
pila
tion
of M
etal
s, A
BA
and
SP
LP D
ata
Sam
ple
IDD
epth
From To
Lith
olog
y
Uni
tsA
cid
Bas
e A
ccou
ntin
g
Pas
te p
Hun
itsS
obec
k N
Pt C
aCO
3/10
Car
bona
te N
Pt C
aCO
3/10
AP
t CaC
O3/
10N
et N
Pt C
aCO
3/10
Sob
eck
NP
/AP
ratio
Car
bona
te N
P/A
Pra
tioS
2-%
Sul
phid
e%
SO
4%
C(t)
%C
arbo
nate
%
E44
6344
E44
6348
E44
6349
E44
6350
E44
6351
E44
6352
E44
6362
E44
6365
E55
6364
E44
6346
E44
6347
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c(9
9Flo
w)
Vol
c (C
ntl)
Vol
c (C
ntl)
Vol
c/S
edV
olc/
Sed
8.89
9.15
9.37
8.50
8.75
9.12
8.66
8.44
141
178
331
166
201
198
183
170
140.
817
3.3
394.
216
3.3
195.
822
6.7
205.
023
2.5
0.31
0.31
0.31
2.4
8.7
2.5
3.5
57.8
141
178
330
163
192
195
180
112
454
574
1067
68.9
23.1
79.1
51.9
2.9
454.
355
9.2
1271
.668
.122
.590
.758
.64.
00.
068
0.09
80.
230.
150.
310.
110.
132.
75<0
.01
<0.0
1<0
.01
0.08
0.28
0.08
0.11
1.85
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
1.69
2.08
4.73
1.96
2.35
2.72
2.46
2.79
8.16
9.76
21.7
9.29
10.9
12.6
11.7
11.0
APPENDIX 2
Compilation of Humidity Cell Testing Data
App
endi
x 2
Com
pila
tion
of H
umid
ity C
ell T
est D
ata
Para
met
erSS
-1D
ay 0
SS-1
Day
7SS
-1D
ay 1
3SS
-1D
ay 2
1SS
-1D
ay 2
8SS
-1D
ay 3
5SS
-1D
ay 4
2SS
-1D
ay 4
9SS
-1D
ay 5
5SS
-1D
ay 6
3SS
-1D
ay 7
0SS
-1D
ay 7
7SS
-1D
ay 8
4SS
-1D
ay 9
1SS
-1D
ay 9
8SS
-1D
ay 1
05SS
-1D
ay 1
12SS
-1D
ay 1
19SS
-1D
ay 1
26SS
-1D
ay 1
33SS
-1D
ay 1
40
Da y
07
1321
2835
4249
5563
7077
8491
9810
511
211
912
613
314
0W
eek
Uni
ts0
12
34
56
78
910
1112
1314
1516
1718
1920
Vol
ume
Wat
er A
dded
L2.
001.
001.
001.
001.
001.
001.
001.
001.
001.
001.
001.
001.
001.
001.
001.
001.
001.
001.
001.
001.
00V
olum
e W
ater
Rec
over
edL
1.71
1.04
1.05
0.95
0.99
0.93
0.95
0.98
1.10
0.90
1.00
0.97
0.95
0.97
0.98
0.98
0.98
0.99
1.00
1.00
1.00
pH--
-6.
627.
417.
026.
937.
526.
817.
457.
437.
518.
027.
667.
377.
727.
807.
587.
147.
607.
457.
517.
687.
19S
peci
fic C
ondu
ctan
cem
S0.
240.
200.
160.
170.
150.
110.
170.
230.
210.
150.
160.
160.
040.
120.
080.
090.
100.
090.
150.
160.
10
Aci
dity
as
CaC
03m
g/L
5N
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MA
lkal
inity
as
CaC
03m
g/L
NM
7659
4038
2419
5557
4663
6322
4042
4844
4667
5045
Dis
solv
ed A
lum
inum
(Al)
mg/
L0.
060.
110.
090.
110.
090.
090.
080.
070.
090.
10.
090.
090.
070.
070.
060.
060.
060.
060.
040.
040.
05D
isso
lved
Ant
imon
y (S
b)m
g/L
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05D
isso
lved
Ars
enic
(As)
mg/
L<0
.001
0.00
40.
005
0.00
50.
003
0.00
30.
004
0.00
50.
004
0.00
40.
003
0.00
30.
002
0.00
20.
002
0.00
10.
001
0.00
1<0
.001
0.00
10.
001
Dis
solv
ed B
ariu
m (B
a)m
g/L
<0.0
10.
01<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
Dis
solv
ed B
eryl
lium
(Be)
mg/
L<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
Dis
solv
ed B
ism
uth
(Bi)
mg/
L<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
Dis
solv
ed B
oron
(B)
mg/
L<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
Dis
solv
ed C
adm
ium
(Cd)
mg/
L<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1D
isso
lved
Cal
cium
(Ca)
mg/
L31
.520
.218
.819
.618
.511
.518
.121
.219
.318
21.5
20.4
8.6
13.6
1416
.313
.513
.322
.817
.514
.8D
isso
lved
Chr
omiu
m (C
r)m
g/L
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01D
isso
lved
Cob
alt (
Co)
mg/
L<0
.000
50.
0006
0.00
110.
001
0.00
1<0
.000
50.
0009
0.00
130.
001
0.00
050.
001
0.00
1<0
.000
50.
0006
0.00
070.
0008
0.00
060.
0007
0.00
130.
0008
0.00
06D
isso
lved
Cop
per (
Cu)
mg/
L0.
001
0.00
10.
002
<0.0
01<0
.001
<0.0
010.
001
0.00
10.
002
<0.0
01<0
.001
<0.0
01<0
.001
0.00
10.
001
0.00
20.
001
0.00
2<0
.001
0.00
10.
002
Dis
solv
ed Ir
on (F
e)m
g/L
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5D
isso
lved
Lea
d (P
b)m
g/L
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01D
isso
lved
Mag
nesi
um (M
g)m
g/L
5.4
13.3
12.8
11.3
12.2
611
17.5
14.8
13.4
12.6
133.
77.
67.
410
.37.
87.
713
.68.
47.
1D
isso
lved
Man
gane
se (M
n)m
g/L
0.05
90.
052
0.07
50.
066
0.05
90.
041
0.05
30.
048
0.03
40.
032
0.03
80.
039
0.03
70.
045
0.05
10.
048
0.04
30.
046
0.06
10.
051
0.04
7D
isso
lved
Mol
ybde
num
(Mo)
mg/
L0.
011
0.01
0.00
60.
004
0.00
20.
005
0.00
20.
008
0.00
60.
003
0.00
30.
002
0.00
10.
004
0.00
20.
002
0.00
20.
002
0.00
30.
002
0.00
1D
isso
lved
Nic
kel (
Ni)
mg/
L<0
.002
0.00
30.
002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
Dis
solv
ed P
hosp
horu
s (P
)m
g/L
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5D
isso
lved
Pot
assi
um (K
)m
g/L
12.6
106
43
23
33
22
2<1
<1<1
<1<1
<1<1
<1<1
Dis
solv
ed S
elen
ium
(Se)
mg/
L0.
005
0.01
70.
018
0.02
10.
019
0.00
90.
019
0.02
10.
011
0.00
90.
007
0.00
7<0
.005
<0.0
05<0
.005
0.00
5<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
Dis
solv
ed S
ilico
n (S
i)m
g/L
0.6
1.5
1.6
1.1
0.6
0.3
0.3
11.
11
1.3
1.2
0.4
0.5
0.5
0.7
0.6
0.7
0.6
0.7
0.6
Dis
solv
ed S
ilver
(Ag)
mg/
L<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
10.
0003
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
Dis
solv
ed S
odiu
m (N
a)m
g/L
7.4
3.5
1.6
0.7
0.7
0.9
<0.5
0.7
0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
Dis
solv
ed S
tront
ium
(Sr)
mg/
L0.
080.
069
0.05
70.
060.
058
0.03
40.
072
0.08
70.
067
0.05
90.
071
0.06
80.
022
0.04
30.
045
0.05
10.
041
0.04
20.
069
0.04
80.
043
Dis
solv
ed S
ulph
ur (S
)m
g/L
3719
1621
2113
2832
1818
1417
510
1011
99
149
8D
isso
lved
Tha
llium
(Tl)
mg/
L<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3D
isso
lved
Tin
(Sn)
mg/
L<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
Dis
solv
ed T
itani
um (T
i)m
g/L
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02D
isso
lved
Tun
gste
n (W
)m
g/L
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1D
isso
lved
Ura
nium
(U)
mg/
L<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
Dis
solv
ed V
anad
ium
(V)
mg/
L<0
.001
0.00
20.
001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
Dis
solv
ed Z
inc
(Zn)
mg/
L0.
004
0.00
50.
010.
008
0.00
90.
006
0.01
10.
014
0.01
60.
007
0.01
10.
011
0.00
30.
012
0.01
0.01
10.
010.
015
0.01
70.
013
0.01
2D
isso
lved
Zirc
oniu
m (Z
r)m
g/L
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04
Sul
phat
e (S
O4)
mg/
L11
157
4863
6339
8496
5454
4251
1530
3033
2727
4227
24
App
endi
x 2
Com
pila
tion
of H
umid
ity C
ell T
est D
ata
Para
met
er
Da y
Wee
kU
nits
Vol
ume
Wat
er A
dded
LV
olum
e W
ater
Rec
over
edL
pH--
-S
peci
fic C
ondu
ctan
cem
S
Aci
dity
as
CaC
03m
g/L
Alk
alin
ity a
s C
aC03
mg/
L
Dis
solv
ed A
lum
inum
(Al)
mg/
LD
isso
lved
Ant
imon
y (S
b)m
g/L
Dis
solv
ed A
rsen
ic (A
s)m
g/L
Dis
solv
ed B
ariu
m (B
a)m
g/L
Dis
solv
ed B
eryl
lium
(Be)
mg/
LD
isso
lved
Bis
mut
h (B
i)m
g/L
Dis
solv
ed B
oron
(B)
mg/
LD
isso
lved
Cad
miu
m (C
d)m
g/L
Dis
solv
ed C
alci
um (C
a)m
g/L
Dis
solv
ed C
hrom
ium
(Cr)
mg/
LD
isso
lved
Cob
alt (
Co)
mg/
LD
isso
lved
Cop
per (
Cu)
mg/
LD
isso
lved
Iron
(Fe)
mg/
LD
isso
lved
Lea
d (P
b)m
g/L
Dis
solv
ed M
agne
sium
(Mg)
mg/
LD
isso
lved
Man
gane
se (M
n)m
g/L
Dis
solv
ed M
olyb
denu
m (M
o)m
g/L
Dis
solv
ed N
icke
l (N
i)m
g/L
Dis
solv
ed P
hosp
horu
s (P
)m
g/L
Dis
solv
ed P
otas
sium
(K)
mg/
LD
isso
lved
Sel
eniu
m (S
e)m
g/L
Dis
solv
ed S
ilico
n (S
i)m
g/L
Dis
solv
ed S
ilver
(Ag)
mg/
LD
isso
lved
Sod
ium
(Na)
mg/
LD
isso
lved
Stro
ntiu
m (S
r)m
g/L
Dis
solv
ed S
ulph
ur (S
)m
g/L
Dis
solv
ed T
halli
um (T
l)m
g/L
Dis
solv
ed T
in (S
n)m
g/L
Dis
solv
ed T
itani
um (T
i)m
g/L
Dis
solv
ed T
ungs
ten
(W)
mg/
LD
isso
lved
Ura
nium
(U)
mg/
LD
isso
lved
Van
adiu
m (V
)m
g/L
Dis
solv
ed Z
inc
(Zn)
mg/
LD
isso
lved
Zirc
oniu
m (Z
r)m
g/L
Sul
phat
e (S
O4)
mg/
L
SS-2
Day
0SS
-2D
ay 7
SS-2
Day
13
SS-2
Day
21
SS-2
Day
28
SS-2
Day
35
SS-2
Day
42
SS-2
Day
49
SS-2
Day
55
SS-2
Day
63
SS-2
Day
70
SS-2
Day
77
SS-2
Day
84
SS-2
Day
91
SS-2
Day
98
SS-2
Day
105
SS-2
Day
112
SS-2
Day
119
SS-2
Day
126
SS-2
Day
133
SS-2
Day
140
07
1321
2835
4249
5563
7077
8491
9810
511
211
912
613
314
00
12
34
56
78
910
1112
1314
1516
1718
1920
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.69
1.10
1.07
0.95
0.98
0.95
0.98
1.00
0.95
0.99
1.00
1.05
0.95
1.00
0.97
1.00
1.05
0.99
0.85
1.00
1.00
6.46
7.87
6.89
6.67
7.64
7.34
7.54
7.61
7.35
8.08
7.78
7.46
7.35
7.69
7.78
7.60
7.59
7.97
7.66
7.63
7.48
0.18
0.18
0.17
0.16
0.14
0.16
0.15
0.15
0.20
0.14
0.15
0.14
0.10
0.15
0.12
0.11
0.13
0.10
0.14
0.19
0.11
4N
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
MN
M79
6944
4928
5463
4358
6762
4864
6264
6451
5967
65
0.07
0.12
0.14
0.14
0.16
0.17
0.12
0.1
0.13
0.11
0.11
0.11
0.12
0.09
0.08
0.08
0.08
0.11
0.07
0.06
0.06
<0.0
050.
007
0.00
6<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
050.
001
0.01
10.
016
0.01
20.
012
0.01
0.01
0.00
80.
008
0.00
60.
006
0.00
50.
004
0.00
30.
003
0.00
30.
002
0.00
20.
002
0.00
20.
002
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
19.4
16.6
18.1
16.8
18.6
16.5
18.2
17.1
16.5
18.1
20.3
19.4
16.4
19.3
19.3
20.2
18.2
14.3
20.5
20.2
20.3
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.000
50.
0008
0.00
160.
0011
0.00
110.
0008
0.00
130.
0012
0.00
050.
0009
0.00
120.
0012
0.00
070.
0011
0.00
110.
0011
0.00
10.
0006
0.00
080.
001
0.00
090.
002
0.00
10.
001
<0.0
01<0
.001
<0.0
010.
001
<0.0
010.
002
<0.0
010.
001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
010.
001
<0.0
010.
001
<0.0
01<0
.001
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
411
.613
.110
.912
.210
.912
.212
.110
.713
.811
.611
.39.
610
9.9
11.2
9.9
7.4
1111
.610
.40.
018
0.03
60.
046
0.04
10.
035
0.02
70.
029
0.02
90.
020.
024
0.02
90.
029
0.02
10.
031
0.03
10.
030.
027
0.01
90.
029
0.02
90.
026
0.00
70.
006
0.00
40.
002
0.00
20.
002
0.00
10.
002
0.00
30.
002
0.00
1<0
.001
0.00
30.
001
0.00
20.
001
0.00
10.
001
0.00
20.
001
0.00
10.
005
0.00
40.
003
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
517
128
55
53
32
23
21
11
1<1
<1<1
<1<1
<0.0
050.
015
0.01
80.
018
0.01
70.
014
0.01
20.
009
0.00
80.
007
0.00
6<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
050.
71.
62.
21.
31.
20.
90.
71.
11.
21.
31.
51.
31.
11
1.1
1.1
10.
80.
70.
91
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
8.4
3.3
1.8
0.7
0.6
0.7
0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
0.05
50.
056
0.05
70.
051
0.05
60.
052
0.06
10.
060.
044
0.05
90.
065
0.05
70.
046
0.05
60.
058
0.05
60.
051
0.04
20.
054
0.05
60.
053
2514
1517
1918
1713
1514
1010
1010
1010
88
1210
10<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.000
3<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.001
0.00
20.
002
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
0.00
60.
004
0.00
50.
005
0.00
50.
006
0.00
90.
007
0.00
90.
006
0.00
70.
007
0.00
40.
012
0.00
80.
009
0.01
10.
011
0.00
60.
008
0.00
7<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
7542
4551
5754
5139
4542
3030
3030
3030
2424
3630
30
App
endi
x 2
Com
pila
tion
of H
umid
ity C
ell T
est D
ata
Para
met
er
Da y
Wee
kU
nits
Vol
ume
Wat
er A
dded
LV
olum
e W
ater
Rec
over
edL
pH--
-S
peci
fic C
ondu
ctan
cem
S
Aci
dity
as
CaC
03m
g/L
Alk
alin
ity a
s C
aC03
mg/
L
Dis
solv
ed A
lum
inum
(Al)
mg/
LD
isso
lved
Ant
imon
y (S
b)m
g/L
Dis
solv
ed A
rsen
ic (A
s)m
g/L
Dis
solv
ed B
ariu
m (B
a)m
g/L
Dis
solv
ed B
eryl
lium
(Be)
mg/
LD
isso
lved
Bis
mut
h (B
i)m
g/L
Dis
solv
ed B
oron
(B)
mg/
LD
isso
lved
Cad
miu
m (C
d)m
g/L
Dis
solv
ed C
alci
um (C
a)m
g/L
Dis
solv
ed C
hrom
ium
(Cr)
mg/
LD
isso
lved
Cob
alt (
Co)
mg/
LD
isso
lved
Cop
per (
Cu)
mg/
LD
isso
lved
Iron
(Fe)
mg/
LD
isso
lved
Lea
d (P
b)m
g/L
Dis
solv
ed M
agne
sium
(Mg)
mg/
LD
isso
lved
Man
gane
se (M
n)m
g/L
Dis
solv
ed M
olyb
denu
m (M
o)m
g/L
Dis
solv
ed N
icke
l (N
i)m
g/L
Dis
solv
ed P
hosp
horu
s (P
)m
g/L
Dis
solv
ed P
otas
sium
(K)
mg/
LD
isso
lved
Sel
eniu
m (S
e)m
g/L
Dis
solv
ed S
ilico
n (S
i)m
g/L
Dis
solv
ed S
ilver
(Ag)
mg/
LD
isso
lved
Sod
ium
(Na)
mg/
LD
isso
lved
Stro
ntiu
m (S
r)m
g/L
Dis
solv
ed S
ulph
ur (S
)m
g/L
Dis
solv
ed T
halli
um (T
l)m
g/L
Dis
solv
ed T
in (S
n)m
g/L
Dis
solv
ed T
itani
um (T
i)m
g/L
Dis
solv
ed T
ungs
ten
(W)
mg/
LD
isso
lved
Ura
nium
(U)
mg/
LD
isso
lved
Van
adiu
m (V
)m
g/L
Dis
solv
ed Z
inc
(Zn)
mg/
LD
isso
lved
Zirc
oniu
m (Z
r)m
g/L
Sul
phat
e (S
O4)
mg/
L
FP-1
Day
0FP
-1D
ay 7
FP-1
Day
13
FP-1
Day
21
FP-1
Day
28
FP-1
Day
35
FP-1
Day
42
FP-1
Day
49
FP-1
Day
55
FP-1
Day
63
FP-1
Day
70
FP-1
Day
77
FP-1
Day
84
FP-1
Day
91
FP-1
Day
98
FP-1
Day
105
FP-1
Day
112
FP-1
Day
119
FP-1
Day
126
FP-1
Day
133
FP-1
Day
140
07
1321
2835
4249
5563
7077
8491
9810
511
211
912
613
314
00
12
34
56
78
910
1112
1314
1516
1718
1920
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.74
1.00
0.99
0.99
0.99
0.90
0.98
1.05
1.05
0.91
1.05
0.98
0.99
0.96
1.00
0.95
1.12
1.06
0.92
1.01
0.99
8.73
7.49
7.37
6.78
7.46
6.62
7.15
7.50
7.70
7.19
7.37
6.87
7.14
7.32
6.97
7.36
7.34
7.53
7.44
7.59
7.28
0.05
0.08
0.10
0.08
0.07
0.08
0.10
0.05
0.05
0.04
0.06
0.07
0.03
0.06
0.05
0.06
0.06
0.04
0.07
0.11
0.06
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
2335
4642
4028
3035
2725
2930
3032
3533
3530
4033
33
0.19
0.16
0.1
0.14
0.21
0.18
0.13
0.2
0.35
0.35
0.31
0.32
0.26
0.19
0.22
0.27
0.37
0.29
0.19
0.25
0.27
<0.0
050.
008
0.01
0.00
70.
008
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
0.00
90.
063
0.07
80.
092
0.08
90.
055
0.05
10.
068
0.07
90.
068
0.06
30.
058
0.04
70.
037
0.04
0.04
40.
035
0.03
50.
024
0.02
90.
027
0.02
0.02
0.02
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
15.
16.
99.
29
9.7
7.6
9.6
9.3
8.1
7.8
1110
.310
.411
.211
11.6
11.8
9.2
13.5
1211
.7<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
0.00
20.
002
0.00
1<0
.001
<0.0
01<0
.001
0.00
2<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
0.00
5<0
.001
<0.0
01<0
.001
<0.0
01<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
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5<0
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01<0
.001
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01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
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01<0
.001
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01<0
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12.
34.
33.
63.
62.
52.
62.
92.
62.
52.
62.
52.
62.
12.
32.
52.
21.
72.
71.
92
0.00
90.
025
0.03
60.
028
0.02
80.
025
0.03
40.
032
0.02
0.02
0.03
80.
039
0.04
0.04
70.
052
0.05
10.
058
0.04
0.06
10.
055
0.05
2<0
.001
0.00
30.
004
0.00
2<0
.001
0.00
3<0
.001
<0.0
01<0
.001
<0.0
010.
002
0.00
2<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
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01<0
.001
0.00
1<0
.001
0.00
50.
002
0.00
40.
004
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
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5<0
.05
<0.0
5<0
.05
46
75
42
22
22
21
11
<11
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.005
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05<0
.005
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05<0
.005
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05<0
.005
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05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
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05<0
.005
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05<0
.005
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71.
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30.
80.
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61.
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61.
31.
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31.
31.
41.
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1<0
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1<0
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.000
1<0
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1<0
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.000
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.000
1<0
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15.
28.
410
3.8
1.9
1.2
0.8
0.7
0.6
0.5
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<0.5
<0.5
<0.5
<0.5
<0.5
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80.
039
0.06
0.05
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047
0.03
60.
038
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70.
027
0.02
60.
037
0.03
60.
035
0.03
40.
035
0.03
50.
036
0.02
90.
039
0.03
30.
031
24
64
43
32
32
22
21
22
21
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22
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003
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003
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003
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003
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003
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003
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003
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003
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003
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003
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003
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003
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003
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003
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003
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01<0
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01<0
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01<0
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01<0
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01<0
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01<0
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01<0
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01<0
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01<0
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01<0
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01<0
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02<0
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02<0
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02<0
.002
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02<0
.002
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02<0
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02<0
.002
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02<0
.002
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02<0
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02<0
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1<0
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1<0
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1<0
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1<0
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1<0
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1<0
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1<0
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1<0
.01
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1<0
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1<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
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05<0
.005
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05<0
.005
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05<0
.005
<0.0
05<0
.005
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05<0
.005
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05<0
.005
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05<0
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05<0
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001
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20.
001
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001
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10.
001
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001
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10.
001
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01<0
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03<0
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030.
003
<0.0
03<0
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03<0
.003
0.00
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016
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7<0
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03<0
.003
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04<0
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04<0
.004
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04<0
.004
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04<0
.004
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04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04
612
1812
129
96
96
66
63
66
63
<36
6
App
endi
x 2
Com
pila
tion
of H
umid
ity C
ell T
est D
ata
Para
met
er
Da y
Wee
kU
nits
Vol
ume
Wat
er A
dded
LV
olum
e W
ater
Rec
over
edL
pH--
-S
peci
fic C
ondu
ctan
cem
S
Aci
dity
as
CaC
03m
g/L
Alk
alin
ity a
s C
aC03
mg/
L
Dis
solv
ed A
lum
inum
(Al)
mg/
LD
isso
lved
Ant
imon
y (S
b)m
g/L
Dis
solv
ed A
rsen
ic (A
s)m
g/L
Dis
solv
ed B
ariu
m (B
a)m
g/L
Dis
solv
ed B
eryl
lium
(Be)
mg/
LD
isso
lved
Bis
mut
h (B
i)m
g/L
Dis
solv
ed B
oron
(B)
mg/
LD
isso
lved
Cad
miu
m (C
d)m
g/L
Dis
solv
ed C
alci
um (C
a)m
g/L
Dis
solv
ed C
hrom
ium
(Cr)
mg/
LD
isso
lved
Cob
alt (
Co)
mg/
LD
isso
lved
Cop
per (
Cu)
mg/
LD
isso
lved
Iron
(Fe)
mg/
LD
isso
lved
Lea
d (P
b)m
g/L
Dis
solv
ed M
agne
sium
(Mg)
mg/
LD
isso
lved
Man
gane
se (M
n)m
g/L
Dis
solv
ed M
olyb
denu
m (M
o)m
g/L
Dis
solv
ed N
icke
l (N
i)m
g/L
Dis
solv
ed P
hosp
horu
s (P
)m
g/L
Dis
solv
ed P
otas
sium
(K)
mg/
LD
isso
lved
Sel
eniu
m (S
e)m
g/L
Dis
solv
ed S
ilico
n (S
i)m
g/L
Dis
solv
ed S
ilver
(Ag)
mg/
LD
isso
lved
Sod
ium
(Na)
mg/
LD
isso
lved
Stro
ntiu
m (S
r)m
g/L
Dis
solv
ed S
ulph
ur (S
)m
g/L
Dis
solv
ed T
halli
um (T
l)m
g/L
Dis
solv
ed T
in (S
n)m
g/L
Dis
solv
ed T
itani
um (T
i)m
g/L
Dis
solv
ed T
ungs
ten
(W)
mg/
LD
isso
lved
Ura
nium
(U)
mg/
LD
isso
lved
Van
adiu
m (V
)m
g/L
Dis
solv
ed Z
inc
(Zn)
mg/
LD
isso
lved
Zirc
oniu
m (Z
r)m
g/L
Sul
phat
e (S
O4)
mg/
L
FP-2
Day
0FP
-2D
ay 7
FP-2
Day
13
FP-2
Day
21
FP-2
Day
28
FP-2
Day
35
FP-2
Day
42
FP-2
Day
49
FP-2
Day
55
FP-2
Day
63
FP-2
Day
70
FP-2
Day
77
FP-2
Day
84
FP-2
Day
91
FP-2
Day
98
FP-2
Day
105
FP-2
Day
112
FP-2
Day
119
FP-2
Day
126
FP-2
Day
133
FP-2
Day
140
07
1321
2835
4249
5563
7077
8491
9810
511
211
912
613
314
00
12
34
56
78
910
1112
1314
1516
1718
1920
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.77
0.96
1.05
0.96
1.00
0.90
0.99
0.97
1.10
0.94
1.01
1.00
1.00
1.00
1.00
0.96
1.00
0.99
1.00
1.00
0.96
8.87
8.03
7.01
7.45
7.62
6.96
7.70
7.63
7.80
7.16
7.28
7.34
7.08
6.79
7.02
6.65
6.74
6.90
7.26
7.49
7.07
0.04
0.08
0.08
0.06
0.08
0.11
0.05
0.05
0.05
0.05
0.06
0.06
0.10
0.09
0.06
0.06
0.08
0.06
0.12
0.10
0.08
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
2134
3831
3432
2830
3329
3029
2629
3230
3229
4033
32
0.18
0.13
0.12
0.1
0.14
0.18
0.11
0.12
0.18
0.19
0.19
0.17
0.14
0.11
0.11
0.12
0.1
0.11
0.08
0.09
0.09
<0.0
050.
007
0.00
7<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
050.
007
0.04
80.
050.
036
0.03
70.
043
0.03
10.
028
0.03
50.
034
0.03
30.
029
0.02
20.
019
0.01
70.
016
0.01
20.
010.
009
0.00
90.
009
0.02
0.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
0.00
03<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
1<0
.000
15.
36.
38
7.1
8.1
7.6
87.
48.
88.
79.
69.
69.
19.
511
.112
.114
.213
22.7
16.4
15.4
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.000
5<0
.000
5<0
.000
5<0
.000
5<0
.000
5<0
.000
50.
0006
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
005
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
0.00
1<0
.001
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01<0
.001
<0.0
01<0
.001
<0.0
010.
001
0.00
20.
001
0.00
10.
001
0.00
1<0
.001
<0.0
01<0
.05
<0.0
5<0
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<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
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01<0
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.001
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011.
12.
43.
22.
72.
92.
72.
52.
23.
22.
92.
42.
52.
42.
12.
12.
83.
23
4.8
3.6
3.3
0.00
70.
030.
038
0.03
50.
036
0.03
10.
035
0.03
40.
030.
030.
037
0.03
90.
035
0.04
20.
040.
034
0.03
0.02
40.
032
0.02
60.
019
<0.0
010.
003
0.00
30.
002
<0.0
01<0
.001
0.00
10.
001
<0.0
010.
001
<0.0
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.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.002
<0.0
020.
002
0.00
2<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
54
66
44
31
22
22
11
11
11
<11
<1<1
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
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05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
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05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
050.
70.
91.
21
0.9
0.9
0.5
0.7
1.1
1.1
1.2
1.1
11
11
11.
11.
21.
11.
1<0
.000
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.000
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1<0
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.000
1<0
.000
1<0
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1<0
.000
1<0
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1<0
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0.03
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0.03
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0.03
80.
025
0.02
90.
031
0.03
30.
032
0.03
30.
030.
032
0.03
30.
037
0.04
30.
042
0.06
30.
045
0.04
23
55
33
33
12
21
21
22
47
711
88
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003
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003
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003
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003
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003
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003
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003
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01<0
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01<0
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01<0
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01<0
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01<0
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.002
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05<0
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05<0
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05<0
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05<0
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05<0
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05<0
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10.
001
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01<0
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01<0
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01<0
.001
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01<0
.001
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01<0
.001
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01<0
.001
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01<0
.003
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03<0
.003
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03<0
.003
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03<0
.003
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03<0
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03<0
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03<0
.003
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40.
004
0.00
50.
004
0.00
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04<0
.004
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04<0
.004
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04<0
.004
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04<0
.004
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04<0
.004
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04<0
.004
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04<0
.004
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04<0
.004
<0.0
04<0
.004
<0.0
04<0
.004
<0.0
04
915
159
99
93
66
36
36
612
2121
3324
24
App
endi
x 2
Com
pila
tion
of H
umid
ity C
ell T
est D
ata
Para
met
er
Da y
Wee
kU
nits
Vol
ume
Wat
er A
dded
LV
olum
e W
ater
Rec
over
edL
pH--
-S
peci
fic C
ondu
ctan
cem
S
Aci
dity
as
CaC
03m
g/L
Alk
alin
ity a
s C
aC03
mg/
L
Dis
solv
ed A
lum
inum
(Al)
mg/
LD
isso
lved
Ant
imon
y (S
b)m
g/L
Dis
solv
ed A
rsen
ic (A
s)m
g/L
Dis
solv
ed B
ariu
m (B
a)m
g/L
Dis
solv
ed B
eryl
lium
(Be)
mg/
LD
isso
lved
Bis
mut
h (B
i)m
g/L
Dis
solv
ed B
oron
(B)
mg/
LD
isso
lved
Cad
miu
m (C
d)m
g/L
Dis
solv
ed C
alci
um (C
a)m
g/L
Dis
solv
ed C
hrom
ium
(Cr)
mg/
LD
isso
lved
Cob
alt (
Co)
mg/
LD
isso
lved
Cop
per (
Cu)
mg/
LD
isso
lved
Iron
(Fe)
mg/
LD
isso
lved
Lea
d (P
b)m
g/L
Dis
solv
ed M
agne
sium
(Mg)
mg/
LD
isso
lved
Man
gane
se (M
n)m
g/L
Dis
solv
ed M
olyb
denu
m (M
o)m
g/L
Dis
solv
ed N
icke
l (N
i)m
g/L
Dis
solv
ed P
hosp
horu
s (P
)m
g/L
Dis
solv
ed P
otas
sium
(K)
mg/
LD
isso
lved
Sel
eniu
m (S
e)m
g/L
Dis
solv
ed S
ilico
n (S
i)m
g/L
Dis
solv
ed S
ilver
(Ag)
mg/
LD
isso
lved
Sod
ium
(Na)
mg/
LD
isso
lved
Stro
ntiu
m (S
r)m
g/L
Dis
solv
ed S
ulph
ur (S
)m
g/L
Dis
solv
ed T
halli
um (T
l)m
g/L
Dis
solv
ed T
in (S
n)m
g/L
Dis
solv
ed T
itani
um (T
i)m
g/L
Dis
solv
ed T
ungs
ten
(W)
mg/
LD
isso
lved
Ura
nium
(U)
mg/
LD
isso
lved
Van
adiu
m (V
)m
g/L
Dis
solv
ed Z
inc
(Zn)
mg/
LD
isso
lved
Zirc
oniu
m (Z
r)m
g/L
Sul
phat
e (S
O4)
mg/
L
VM-1
Day
0VM
-1D
ay 7
VM-1
Day
13
VM-1
Day
21
VM-1
Day
28
VM-1
Day
35
VM-1
Day
42
VM-1
Day
49
VM-1
Day
55
VM-1
Day
63
VM-1
Day
70
VM-1
Day
77
VM-1
Day
84
VM-1
Day
91
VM-1
Day
98
VM-1
Day
105
VM-1
Day
112
VM-1
Day
119
VM-1
Day
126
VM-1
Day
133
VM-1
Day
140
07
1321
2835
4249
5563
7077
8491
9810
511
211
912
613
314
00
12
34
56
78
910
1112
1314
1516
1718
1920
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.76
1.00
1.10
0.90
1.05
1.00
1.01
0.92
0.78
1.00
0.85
0.97
1.02
0.96
1.05
0.90
0.97
0.98
1.00
0.97
0.98
8.05
7.61
7.19
7.47
7.94
7.34
7.94
8.09
8.10
8.01
7.75
7.57
7.01
7.68
8.07
7.56
7.04
7.65
7.51
7.51
7.27
0.07
0.10
0.10
0.07
0.07
0.12
0.06
0.07
0.08
0.08
0.06
0.07
0.05
0.09
0.06
0.05
0.08
0.04
0.11
0.17
0.08
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
3463
5441
5343
3639
2747
3843
4243
4840
4833
6451
48
0.13
0.21
0.34
0.3
0.28
0.37
0.33
0.31
0.2
0.3
0.34
0.32
0.28
0.26
0.28
0.28
0.24
0.15
0.16
0.21
0.21
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
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05<0
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05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.001
0.00
60.
008
0.00
60.
005
0.00
60.
007
0.00
80.
005
0.00
70.
009
0.00
70.
006
0.00
60.
006
0.00
60.
005
0.00
40.
004
0.00
50.
004
<0.0
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<0.0
1<0
.01
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1<0
.01
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1<0
.01
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1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.01
<0.0
1<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
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01<0
.001
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01<0
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01<0
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01<0
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01<0
.001
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01<0
.001
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01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
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5<0
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5<0
.05
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5<0
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5<0
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5<0
.05
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5<0
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<0.0
5<0
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5<0
.05
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5<0
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5<0
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
8.1
1011
.49.
210
.89.
810
9.1
8.5
11.5
10.7
11.5
11.9
11.1
12.3
11.4
128.
817
.114
.613
<0.0
01<0
.001
<0.0
01<0
.001
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01<0
.001
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.001
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01<0
.001
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01<0
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01<0
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01<0
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01<0
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5<0
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50.
002
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.001
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01<0
.001
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010.
002
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.001
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01<0
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01<0
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010.
002
0.00
10.
001
<0.0
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<0.0
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5<0
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5<0
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5<0
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5<0
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5<0
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5<0
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01<0
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01<0
.001
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01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
01<0
.001
<0.0
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1.7
8.3
8.1
5.4
7.1
5.9
4.4
4.7
3.5
74.
55.
96.
35
55.
15.
63.
18.
66.
25.
70.
007
0.01
30.
013
0.01
40.
014
0.01
10.
011
0.01
20.
013
0.01
40.
014
0.01
60.
016
0.01
70.
017
0.01
80.
022
0.02
0.02
40.
018
0.01
80.
001
0.00
30.
002
0.00
1<0
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010.
002
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.001
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.001
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01<0
.001
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.001
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01<0
.001
<0.0
010.
002
<0.0
01<0
.001
<0.0
02<0
.002
<0.0
02<0
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<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.002
<0.0
02<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
<0.0
5<0
.05
34
31
21
1<1
.0<1
.0<1
.0<1
.0<1
.0<1
.0<1
.0<1
.0<1
.0<1
.0<1
.0<1
.0<1
.0<1
.0<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
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05<0
.005
<0.0
05<0
.005
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05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
<0.0
05<0
.005
0.5
1.1
1.8
1.1
0.9
0.8
0.5
0.8
0.6
1.2
1.1
1.1
1.2
0.9
11
10.
60.
91.
11
<0.0
001
<0.0
001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
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001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
<0.0
001
10.2
5.6
2.5
1.1
1.2
1.1
0.7
0.6
0.6
0.7
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
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80.
040.
044
0.03
10.
036
0.02
90.
025
0.02
30.
018
0.02
80.
025
0.02
90.
028
0.02
70.
030.
026
0.02
90.
019
0.04
0.03
10.
028
34
43
33
32
23
23
22
22
21
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32
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003
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003
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003
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003
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003
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003
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003
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003
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003
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003
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003
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003
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003
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003
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02<0
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1<0
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1<0
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1<0
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1<0
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1<0
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05<0
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05<0
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05<0
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002
0.00
20.
001
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.001
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001
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04<0
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04<0
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912
129
99
96
69
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66
66
63
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6
App
endi
x 2
Com
pila
tion
of H
umid
ity C
ell T
est D
ata
Para
met
er
Da y
Wee
kU
nits
Vol
ume
Wat
er A
dded
LV
olum
e W
ater
Rec
over
edL
pH--
-S
peci
fic C
ondu
ctan
cem
S
Aci
dity
as
CaC
03m
g/L
Alk
alin
ity a
s C
aC03
mg/
L
Dis
solv
ed A
lum
inum
(Al)
mg/
LD
isso
lved
Ant
imon
y (S
b)m
g/L
Dis
solv
ed A
rsen
ic (A
s)m
g/L
Dis
solv
ed B
ariu
m (B
a)m
g/L
Dis
solv
ed B
eryl
lium
(Be)
mg/
LD
isso
lved
Bis
mut
h (B
i)m
g/L
Dis
solv
ed B
oron
(B)
mg/
LD
isso
lved
Cad
miu
m (C
d)m
g/L
Dis
solv
ed C
alci
um (C
a)m
g/L
Dis
solv
ed C
hrom
ium
(Cr)
mg/
LD
isso
lved
Cob
alt (
Co)
mg/
LD
isso
lved
Cop
per (
Cu)
mg/
LD
isso
lved
Iron
(Fe)
mg/
LD
isso
lved
Lea
d (P
b)m
g/L
Dis
solv
ed M
agne
sium
(Mg)
mg/
LD
isso
lved
Man
gane
se (M
n)m
g/L
Dis
solv
ed M
olyb
denu
m (M
o)m
g/L
Dis
solv
ed N
icke
l (N
i)m
g/L
Dis
solv
ed P
hosp
horu
s (P
)m
g/L
Dis
solv
ed P
otas
sium
(K)
mg/
LD
isso
lved
Sel
eniu
m (S
e)m
g/L
Dis
solv
ed S
ilico
n (S
i)m
g/L
Dis
solv
ed S
ilver
(Ag)
mg/
LD
isso
lved
Sod
ium
(Na)
mg/
LD
isso
lved
Stro
ntiu
m (S
r)m
g/L
Dis
solv
ed S
ulph
ur (S
)m
g/L
Dis
solv
ed T
halli
um (T
l)m
g/L
Dis
solv
ed T
in (S
n)m
g/L
Dis
solv
ed T
itani
um (T
i)m
g/L
Dis
solv
ed T
ungs
ten
(W)
mg/
LD
isso
lved
Ura
nium
(U)
mg/
LD
isso
lved
Van
adiu
m (V
)m
g/L
Dis
solv
ed Z
inc
(Zn)
mg/
LD
isso
lved
Zirc
oniu
m (Z
r)m
g/L
Sul
phat
e (S
O4)
mg/
L
VM-2
Day
0VM
-2D
ay 7
VM-2
Day
13
VM-2
Day
21
VM-2
Day
28
VM-2
Day
35
VM-2
Day
42
VM-2
Day
49
VM-2
Day
55
VM-2
Day
63
VM-2
Day
70
VM-2
Day
77
VM-2
Day
84
VM-2
Day
91
VM-2
Day
98
VM-2
Day
105
VM-2
Day
112
VM-2
Day
119
VM-2
Day
126
VM-2
Day
133
VM-2
Day
140
07
1321
2835
4249
5563
7077
8491
9810
511
211
912
613
314
00
12
34
56
78
910
1112
1314
1516
1718
1920
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.75
1.06
1.02
1.00
0.98
0.95
1.02
1.00
0.78
0.93
0.99
0.99
1.00
1.00
0.99
1.00
1.05
0.95
0.90
1.00
1.01
8.60
7.40
7.52
7.45
7.84
7.22
7.67
7.93
8.05
8.16
8.08
7.36
7.53
6.83
7.45
7.21
7.62
7.60
7.54
7.74
7.36
0.06
0.09
0.07
0.08
0.07
0.13
0.07
0.07
0.07
0.05
0.06
0.05
0.04
0.08
0.06
0.06
0.07
0.05
0.10
0.08
0.06
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
2749
4051
4749
4044
2127
3330
3038
4042
4044
5744
39
0.15
0.19
0.24
0.27
0.33
0.38
0.26
0.31
0.17
0.19
0.21
0.19
0.17
0.17
0.19
0.22
0.24
0.29
0.18
0.21
0.23
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05<0
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05<0
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05<0
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<0.0
05<0
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<0.0
05<0
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05<0
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05<0
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0.00
70.
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0.01
0.00
90.
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80.
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40.
013
0.01
30.
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0.01
50.
016
0.01
50.
014
0.01
10.
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1<0
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1<0
.01
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1<0
.01
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1<0
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1<0
.01
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1<0
.01
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01<0
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01<0
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01<0
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01<0
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01<0
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01<0
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01<0
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01<0
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01<0
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01<0
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01<0
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37.
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53
32
22
21
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96
99
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99
36
66
66
66
63
<36
6
