Inorganica Chimica Acta Journal of Solid State ... · topics in Inorganic Chemistry. - In occasion...

Curriculum Vitae

- Since 1994, Piero Zanello is full professor of Inorganic Chemistry at the Dipartimento di Chimica (now Dipartimento di Biotecnologie, Chimica e Farmacia) of the University of Siena, Via A. De Gasperi 2, 53100 Siena, Italy. - He retired in November 2011. - He has been the Director of the same Department from 1996 to 2002. - Since 1987, he has been fellow of the Inorganic Chemistry Division of the Italian Chemical Society and member of the Management Committee of the same Division in the triennium 2006-2008. - He has been member of the management of the inter-university Consortium "Research in Chemistry of Metals in Biological Systems" (CIRCMSB) since its foundation (1992). - He has been fellow of the American Chemical Society (ACS) from 2007 to 2011. - Since 1998, he was the organizer of the biennial conference: Chianti Meeting on Inorganic Electrochemistry (ChiMIE). - From more than 30 years he deals with the determination of the redox propeties of organometallic and coordination compounds through the use of electrochemical and spectroelectrochemical techniques. During this period he collaborated with many Italian and foreign research groups, facing often with recent topics in Inorganic Chemistry. - In occasion of his 65° birthday, the journal Inorganica Chimica Acta devoted him a special volume of the series “Protagonists in Chemistry” (issue 6 of the Volume 361, 2008). In the same occasion, the Journal of Solid State Electrochemistry also devoted him a special volume (issue 12, volume 11, 2007). - He is included in the Top Italian Scientists (TIS) of the VIA Academy. - He has been invited to have lectures in Italian and foreign universities. - He acted periodically as reviewer for European as well as American scientific journals. - He is author/coauthor of 398 scientific papers. - His bibliometric parameters are shown below (from Google Scholar, January 2020)

FIELDS OF RESEARCH The main research interests are concerned with the study of the electron-transfer ability of metal complexes (from coordination to organometallic derivatives) by modern electrochemical techniques . The redox processes emerging from electrochemical investigations are further elucidated through both spectroscopic techniques on macroelectrolysis (UV-vis., IR, EPR) or microelectrolysis (UV-vis-NIR spectroelectrochemistry) and theoretical analysis (EH, ab initio/DFT). His publishing activity in the field of electrochemistry of inorganic compounds can be schematically classified as follows: 1 INVITED LECTURES 2 REVIEWS AND CONTRIBUTIONS TO BOOKS 3 METAL CLUSTERS (a) Metal-sulfur clusters (b) Metal-carbonyl clusters (c) Metal clusters of other ligands 4 SANDWICH COMPLEXES (a) Ferrocenes (b) Metallocenes and Metallametallocenes (c) Carboranes and Metallacarboranes (d) Other sandwich ligands 5 METAL COMPLEXES CONTAINING REDOX-ACTIVE LIGANDS (a) Ferrocenes (b) Fullerenes and carbon curved surfaces (c) Porphyrins (d) Dithiolenes (e) Dioxolenes 6 PHARMACO-BIO-METALLICS 7 MISCELLANEOUS SUBJECTS 8 TEXTBOOKS

1 INVITED LECTURES - Structural aspects of the redox flexibility of Group VIII metal complexes with tripodal polyphosphine ligands The 30th International Conference on Coordination Chemistry", Kyoto (Giappone), Luglio, 1994 - Bimetallic Effects in the Electrochemical Behaviour of Transition Metal Carbonyl Clusters “Bimetallic Effects in Chemistry”- European Science Foundation, Parma (Italy), Aprile 1995 - L'Elettrochimica in Chimica Inorganica Dalla Chimica Organometallica alla Chimica Bioinorganica. University of Camerino (Italy), May 1997 - Ferrocenes: an excellent gymnasium for aspiring electrochemists International School of Organometallic Chemistry, Camerino (Italy), September 1997

- Metallocene electrochemistry: does it still constitute a topical subject? Technical University of Munich (Germany), December 1997 - Ferrocenes:an endless field of research in electrochemistry University of Bielefeld (Germany), December 1997 - Transition-metal carbonyl clusters containing interstitial or semi-interstitial (N,P) heteroatoms. Electrochemical and structural aspects University of Brest (France), January 1999 - Structural and electrochemical aspects of (exohedral) metallafullerenes V Iberian Meeting of Electrochemistry, University of Evora (Portugal), April 1999 - Electrochemical and Structural Aspects of Metallofullerenes Coimbra Group, German-Italian Meeting. University of Pavia (Italy), October 1999 - Homoleptic, Mononuclear Transition Metal Complexes of 1,2-Dithiolenes.Updating their Electrochemical- to-Structural Properties New trends in Molecular Electrochemistry. Lisbon (Portugal), 16-20 Settembre 2003 - The redox propensity of polynuclear MC2B4 metallacarboranes (M = Fe, Co) with different molecular architectures Third Italian-Korean Joint Meeting on Inorganic Chemistry. Seoul (South Korea), 23-25 Settembre 2003 - Electrochemistry of metallofullerenes. Perspectives in Electrochemistry of Complex Systems. Modena (Italy), 29 Aprile 2004 - Polynuclear metallo-carboranes with different molecular architectures. Electrochemical and spectroelectrochemical aspects IX Scuola Nazionale per dottorandi. Chimica Organometallica. Venezia (Italy), 27 Giugno - 1 Luglio 2004 - The role of electrochemistry in bioinorganic chemistry X Scuola nazionale per dottorandi. Chimica Bioinorganica. Catania (Italy), 12-14 Settembre 2005 - Electrochemistry of metallacarboranes: the preliminary insight into their electronic mobility XIII imeBoron, Platja D’Aro (Spain), 21-25 Settembre 2008 - Metallacarborani: una versatile classe di derivati ad elevata attitudine redox Inorganic Day. Parma (Italy), 23 Ottobre, 2009 - Electron reservoir activity of high-nuclearity transition metal carbonyl clusters IME XII, Lisbon, 8-11 Settembre 2010. - Electrochemical techniques in Inorganic Electrochemistry. A glance to theory and application University of Perugia (Italy), May 2011 - Electron transfer and Metallo-Protein Electrochemistry Scuola Nazionale di Chimica Bioinorganica. Siena, 3-6 Luglio 2011

2 REVIEWS AND CONTRIBUTIONS TO BOOKS

1. P. Zanello, S. Tamburini, P.A. Vigato and G.A. Mazzocchin, SYNTHESIS, STRUCTURE AND ELECTRO CHEMICAL CHARACTERIZATION OF HOMO- AND HETERO-DINUCLEAR COPPER COMPLEXES WITH COMPARTMENTAL LIGANDS Coord.Chem.Rev., 77, 165-273 (1987). 2. P. Zanello, ELECTROCHEMISTRY OF METAL-SULFUR CLUSTERS: STEREOCHEMICAL CONSEQUENCES OF THERMODYNAMICALLY CHARATERIZED REDOX CHANGES. PART I. HOMOMETAL CLUSTERS Coord.Chem.Rev., 83, 199-275 (1988). 3. P. Zanello, ELECTROCHEMISTRY OF METAL-SULFUR CLUSTERS: STEREOCHEMICAL CONSEQUENCES OF THERMODYNAMICALLY CHARACTERIZED REDOX CHANGES. PART II. HETEROMETAL CLUSTERS Coord.Chem.Rev., 87, 1-54 (1988). 4. P. Zanello, REDOX CHANGES IN MONONUCLEAR COPPER COMPLEXES CONTAINING THE N2S2 DONOR SET. ELECTROCHEMICAL PARAMETERS AS A PROBE OF THE STRUCTURAL FEATURES Comments Inorg.Chem., 8, 45-78 (1988). 5. P. Zanello, ELECTROCHEMISTRY OF MONONUCLEAR COPPER COMPLEXES. STRUCTURAL REORGANIZATIONS ACCOMPANYING REDOX CHANGES. "Stereochemistry of Organometallic and Inorganic Compounds", I. Bernal, ed.; Elsevier, Amsterdam. Vol. 4, 181-366 (1990). 6. P. Zanello, CAN ELECTROCHEMISTRY DISTINGUISH CLASSICAL FROM NONCLASSICAL TRANSITION- METAL POLYHYDRIDE? Comments Inorg.Chem., 11, 339-359 (1992). 7. C. Bianchini, M. Peruzzini, F. Laschi and P. Zanello, SYNTHESIS, CHARACTERIZATION AND CHEMISTRY OF RHODIUM(II) ORGANOMETALLIC COMPLEXES STABILIZED BY TRIPODAL POLYPHOSPHINE LIGANDS, "Topics in Physical Organometallic Chemistry" M. Gielen, ed.; Freund Publishing House, London; Vol. 4, 1992, p. 139. 8. P. Zanello, STEREOCHEMICAL ASPECTS ASSOCIATED WITH THE REDOX BEHAVIOUR OF HETEROMETAL CARBONYL CLUSTERS Struct.Bonding (Berlin), 79, 101-214 (1992). 9. P. Zanello, THE REDOX PROPERTIES OF HIGH NUCLEARITY METAL CLUSTERS, NATO ASI Series C: MATEMATICAL AND PHYSICAL SCIENCES, Kluwer Academic Publishers, The Netherlands; A. Pombeiro, ed.; 229-245 (1992). 10. P. Zanello, STEREOCHEMICAL ASPECTS OF THE REDOX PROPENSITY OF HOMOMETAL CARBONYL CLUSTERS. "Stereochemistry of Organometallic and Inorganic Compounds", P.Zanello, ed.; Elsevier, Amsterdam; Vol. 5, (1994) 163. 11. P. Zanello, ELECTROCHEMICAL AND X-RAY STRUCTURAL ASPECTS OF TRANSITION METAL COMPLEXES CONTAINING REDOX-ACTIVE FERROCENE LIGANDS. "Ferrocenes. From Homogeneous Catalysis to Material Science", T.Hayashi and A.Togni eds.; VCH-Publishers. 1995, Chapt. 7.

12. P. Zanello, STRUCTURAL ASPECTS OF THE REDOX FLEXIBILITY OF GROUP VIII METAL COMPLEXES WITH TRIPODAL POLYPHOSPHINE LIGANDS, Pure & Appl.Chem, 67, 323 (1995). 13. P. Zanello and F. Fabrizi de Biani, BIMETALLIC EFFECTS ON THE REDOX ACTIVITY OF TRANSITION- METAL CARBONYL CLUSTERS, "Metal Clusters in Chemistry" P. Braunstein, L.A. Oro, P.R. Raithby Eds., Wiley-VCH, Vol. 2, 1999, pp. 1104-1136. 14. G. Longoni, C.Femoni, M.C.Iapalucci and P.Zanello, ELECTRON-SINK FEATURES OF HOMOLEPTIC TRANSITION-METAL CARBONYL CLUSTERS. "Metal Clusters in Chemistry" P. Braunstein, L.A. Oro, P.R. Raithby Eds., Wiley-VCH, Vol.2, 1999, 1137-1158. 15. P. Zanello, ELECTROCHEMICAL AND STRUCTURAL ASPECTS OF METALLOFULLERENES. "Chemistry at the Beginning of the Third Millennium", L. Fabbrizzi and A. Poggi, eds. Springer, 2000, pp. 247-278. 16. P. Zanello, STRUCTURE AND ELECTROCHEMISTRY OF TRANSITION METAL CARBONYL CLUSTERS WITH INTERSTITIAL OR SEMI-INTERSTITIAL ATOMS: CONTRAST BETWEEN NITRIDES OR PHOSPHIDES AND CARBIDES. "Physical Organometallic Chemistry. Vol. 3. Unusual Structures and Physical Properties in Organometallic Chemistry", M. Gielen, R.Willem, B.Wrackmeyer, eds., John Wiley, Chichester, UK. 2002, pp. 1-49. 17. D. Collini, C.Femoni, M.C.Iapalucci, G.Longoni and P. Zanello, MODULATION OF ELECTRONIC BEHAVIOUR OF METAL CARBONYL CLUSTERS, “Perspectives in Organometallic Chemistry”, C.G. Screttas and B.R.Steele eds., Royal Society of Chemistry, 183-195 (2003). 18. P. Zanello and E.Grigiotti, HOMOLEPTIC, MONONUCLEAR TRANSITION METAL COMPLEXES OF 1,2-DITHIOLENES: UPDATING THEIR ELECTROCHEMICAL-TO-STRUCTURAL PROPERTIES. “Trends in Inorganic Molecular Electrochemistry”, A.Pombeiro and C.Amatore, Eds., Marcel Dekker Inc.; Fontis Media S.A. 2004, pp. 3-70. 19. M. Corsini, F.Fabrizi de Biani and P.Zanello, MONONUCLEAR METALLACARBORANES OF GROUPS 6–10 METALS: ANALOGUES OF METALLOCENES. ELECTROCHEMICAL AND X-RAY STRUCTURAL ASPECTS, Coord. Chem. Rev., 250, 1351 (2006). 20. P.Zanello and M.Corsini, HOMOLEPTIC, MONONUCLEAR TRANSITION METAL COMPLEXES OF 1,2-DIOXOLENES: UPDATING THEIR ELECTROCHEMICAL-TO-STRUCTURAL (X-RAY) PROPERTIES, Coord. Chem. Rev., 250, 2000 (2006). 21. G.Pampaloni and P.Zanello, REDOX CHEMISTRY AND ELECTROCHEMISTRY OF METAL ENOLATES, "The Chemistry of Metal Enolates", J.Zabicky ed.; Wiley. (2009) Chapt. 9. Patai Series: The Chemistry of Functional Groups; Zvi Rappoport Series Ed. 22. F. Rossi and P. Zanello, ELECTRON RESERVOIR ACTIVITY OF HIGH-NUCLEARITY TRANSITION METAL CARBONYL CLUSTERS Portugaliae Electrochimica Acta, 29, 309-327 (2011). 23. F. Fabrizi de Biani and P. Zanello, ENDOHEDRAL METALLOFULLERENES TODAY: MORE AND MORE VERSATILE SHIPS IN MULTIFORM BOTTLES. ELECTROCHEMISTRY OF X-RAY CHARACTERIZED MONOMETALLOFULLERENES, “Advances in Organometallic Chemistry and Catalysis”, A. J. L. Pombeiro Ed., Wiley, 2013, Chapter 51.

24. P.Zanello, THE COMPETITION BETWEEN CHEMISTRY AND BIOLOGY IN ASSEMBLING IRON–SULFUR DERIVATIVES. MOLECULAR STRUCTURES AND ELECTROCHEMISTRY. PART I. {Fe(SCys)4} PROTEINS. Coord. Chem. Rev., 257, 1777 (2013). 25. F. Fabrizi de Biani, M. Corsini, P. Zanello, REDOX CHEMISTRY AND ELECTROCHEMISTRY OF HOMOLEPTIC METAL PHENOLATES, The Chemistry of Metal Phenolates, J. Zabicky, Ed., John Wiley & Sons, 2014, Chapter 9. 26. P. Zanello, THE COMPETITION BETWEEN CHEMISTRY AND BIOLOGY IN ASSEMBLING IRON–SULFUR DERIVATIVES. MOLECULAR STRUCTURES AND ELECTROCHEMISTRY. PART II. {[Fe2S2](Sγ

Cys)4} PROTEINS, Coord. Chem. Rev., 280, 54-83 (2014). 27. P. Zanello, THE COMPETITION BETWEEN CHEMISTRY AND BIOLOGY IN ASSEMBLING IRON– SULFUR DERIVATIVES. MOLECULAR STRUCTURES AND ELECTROCHEMISTRY. PART III. [Fe2S2](SγCys)3(X)} (X = Asp, Arg, His) and {[Fe2S2](Sγ

Cys)2(His)2} PROTEINS, Coord. Chem. Rev., 306, 420-442 (2016). 28. F. Fabrizi de Biani and P. Zanello, in “Metals Systems for a Sustainable Chemistry “, Part 2; THE COMPETITION BETWEEN CHEMISTRY AND BIOLOGY IN ASSEMBLING IRON-SULFUR DERIVATIVES. MOLECULAR STRUCTURES AND ELECTROCHEMISTRY. PART IV. {[Fe3S4](Sγ

Cys)3} PROTEINS Inorg. Chim. Acta, 455, 319-328 (2017). 29. P. Zanello, THE COMPETITION BETWEEN CHEMISTRY AND BIOLOGY IN ASSEMBLING IRON-SULFUR DERIVATIVES. MOLECULAR STRUCTURES AND ELECTROCHEMISTRY. PART V. {[Fe4S4](Sγ

Cys)4} PROTEINS Coord. Chem. Rev., 335, 172-227 (2017). 30. P. Zanello and M. Corsini, THE COMPETITION BETWEEN CHEMISTRY AND BIOLOGY IN ASSEMBLING IRON-SULFUR DERIVATIVES. MOLECULAR STRUCTURES AND ELECTROCHEMISTRY. PART VI. {[Fe4S4](Sγ

Cys)3(nonthiolate ligand)} PROTEINS Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Elsevier, 2017 (https://www.sciencedirect.com/science/article/pii/B9780124095472127088). 31. P. Zanello, STRUCTURE AND ELECTROCHEMISTRY OF PROTEINS HARBORING IRON-SULFUR CLUSTERS OF DIFFERENT NUCLEARITIES. PART I. [4Fe-4S] + [2Fe-2S] IRON-SULFUR CLUSTER PROTEINS J. Struct. Biol. 200, 1-19 (2017). 32. P. Zanello, STRUCTURE AND ELECTROCHEMISTRY OF PROTEINS HARBORING IRON-SULFUR CLUSTERS OF DIFFERENT NUCLEARITIES. PART II. [4Fe-4S] AND [3Fe-4S] IRON-SULFUR CLUSTER PROTEINS J. Struct. Biol. 202, 250-263 (2018). 32. P. Zanello, STRUCTURE AND ELECTROCHEMISTRY OF PROTEINS HARBORING IRON-SULFUR CLUSTERS

OF DIFFERENT NUCLEARITIES. PART II. [4Fe-4S], [3Fe-4S] AND [2FE-2S] IRON-SULFUR CLUSTER PROTEINS. J. Struct. Biol. 202, 264-274 (2018).

33. P. Zanello, STRUCTURE AND ELECTROCHEMISTRY OF PROTEINS HARBORING IRON- SULFUR CLUSTERS OF DIFFERENT NUCLEARITIES. Part IV. CANONICAL, NON-CANONICAL AND HYBRID IRON-SULFUR PROTEINS. J. Struct. Biol., 205, 103-120 (2019).

3 METAL CLUSTERS

(a) Metal-sulfur clusters 1. F.Cecconi, C.A.Ghilardi, S.Midollini, A.Orlandini and P.Zanello SYNTHESIS, PROPERTIES AND STRUCTURES OF THE TWO ELECTRON-RICH COBALT-SULFUR CLUSTERS [Co6(µ3-S)8(PEt3)6]+,0 Polyhedron, 5, 2021 (1986). 2. F.Cecconi, C.A.Ghilardi, S.Midollini, A.Orlandini and P.Zanello REDOX BEHAVIOUR OF THE IRON-SULFUR CLUSTER [Fe6(µ3-S)8(PEt3)6]2+. CRYSTAL STRUCTURE OF THE NOVEL PARAMAGNETIC MONOPOSITIVE SPECIES [Fe6(µ3-S)8(PEt3)6]+ J.Chem.Soc., Dalton Trans., 831 (1987).

3. S.D'Addario, F.Demartin, L.Grossi, M.C.Iapalucci, F.Laschi, G.Longoni and P.Zanello REDOX BEHAVIOUR OF THE BLACK ROUSSINATE [Fe4S3(NO)7]− MONOANION. SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF THE [Fe4S3(NO)7]n− (n = 2, 3) ANIONS AND CRYSTAL STRUCTURE OF THE MONO- AND DI-ANION IN THEIR [NEt4]+ SALTS Inorg.Chem., 32, 1153 (1993). 4. F.Cecconi, C.A.Ghilardi, S.Midollini, A.Orlandini, P.Zanello, A.Cinquantini, A.Bencini, M.Uytterhoeven and G.Giorgi SYNTHESIS, CHARACTERIZATION, AND ELECTRONIC STRUCTURE OF THE NOVEL STELLATED OCTAHEDRAL CLUSTER [Co6(S)7(H)(PEt 3)6]+. CRYSTAL AND MOLECULAR STRUCTURE OF [Co6(S)7(H)(PEt3)6]. 0.7[Co6(S)8(PEt3)6].0.3 [BPh4] J.Chem.Soc., Dalton Trans., 3881 (1995). 5. F.Calderoni, F.Demartin, M.C.Iapalucci, F.Laschi, G.Longoni and P.Zanello SYNTHESIS AND CHEMICAL AND ELECTROCHEMICAL CHARACTERIZATION OF Fe-S CARBONYL CLUSTERS. X-RAY CRYSTAL STRUCTURES OF [N(PPh3)2]2[Fe5S2(CO)14] AND [N(PPh3)2]2[Fe6S6(CO)12] Inorg.Chem., 35, 898 (1996). 6. P.Barbaro, F.Cecconi, C.A.Ghilardi, S.Midollini, A.Orlandini, F.Fabrizi de Biani, F.Laschi and P.Zanello SYNTHESIS, PROPERTIES AND CHARACTERIZATION OF THE TRINUCLEAR CLUSTERS [Co3(µ-SR)6(PEt3)3]X (R=Me or Et, X=BPh4

− or PF6−)

J.Chem.Soc., Dalton Trans., 4337 (1996). 7. J.J.Schneider, J.Hagen, D.Spickermann, D.Bläser, R.Boese, F.Fabrizi de Biani, F.Laschi, P.Zanello SYNTHESIS, STRUCTURE, AND SPECTROELECTROCHEMICAL INVESTIGATION OF NOVEL TERNARY Co/S(Se)/Sn CLUSTERS DERIVED FROM BINARY COBALT STANNANEDIYL COMPLEXES Chem.Eur.J., 6, 237 (2000). 8. F.Fabrizi de Biani, C.Graiff, G.Opromolla, G.Predieri, A.Tiripicchio and P.Zanello A RE-EXAMINATION OF THE REACTION BETWEEN 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE (dppf) DISELENIDE AND [Ru3(CO)12]. ELECTROCHEMICAL BEHAVIOUR OF THE ISOMERIC NIDO-CLUSTERS [Ru3(µ3-Se)2(dppf)(CO)7] AND [Ru3(µ3-Se)2(µ-dppf)(CO)7] AND CRYSTAL STRUCTURE OF [Ru3Se{µ-P(Ph)C5H4FeC5H4PPh2}(µ-OCPh)(CO)6] J.Organomet.Chem., 637-639, 586 (2001). 9. K.Herbst, P.Zanello, M.Corsini, N.D’Amelio, L.Dahlenburg, and M.Brorson A COMPLETE FAMILY OF ISOSTRUCTURAL CLUSTER COMPOUNDS WITH CUBANE-LIKE M3S4M’ CORES (m = Mo, W; M’ = Ni, Pd, Pt): COMPARATIVE CRYSTALLOGRAPHY AND ELECTROCHEMISTRY

Inorg.Chem., 42, 974 (2003). (b) Metal-carbonyl clusters 1. P.Zanello, S.Aime and D.Osella ELECTROCHEMICAL INVESTIGATION OF A SERIES OF ORGANO- TRIRUTHENIUM CLUSTERS Organometallics, 3, 1374 (1984). 2. D.Osella, R.Gobetto, P.Montangero, P.Zanello and A.Cinquantini REORIENTATION OF THE ALKYNE MOIETY IN Fe3(CO)9(RC2R) CLUSTERS INDUCED BY A TWO-ELECTRON ELECTROCHEMICAL REDUCTION Organometallics, 5, 1247 (1986). 3. D.Osella, G.Arman, M.Botta, R.Gobetto, F.Laschi, and P.Zanello SPECTROSCOPIC AND ELECTROCHEMICAL STUDY OF TRINUCLEAR FERRA-CYCLOPENTADIENYL CLUSTERS [Fe3(µ-CO)2(CO)6(RC2R)2] Organometallics, 8, 620 (1989). 4. D.Osella, G.Arman, R.Gobetto, F.Laschi, P.Zanello, S.Ayrton, V.Goodfellow, C.E.Housecroft and S.N.Owen ELECTROCHEMICAL, SPECTROSCOPIC AND THEORETICAL STUDY OF TRINUCLEAR RUTHENA- CYCLOPENTADIENYL CLUSTERS [Ru3(µ-CO)2(CO)6(RC2R)2] Organometallics, 8, 2689 (1989). 5. D.Osella, R.Gobetto, L.Milone, P.Zanello and S.Mangani REGIOSPECIFIC ALLYL-ALKYNE COUPLING ON AN ORGANOTRIRUTHENIUM CARBONYL CLUSTER. CRYSTAL STRUCTURE OF Ru3(CO)8(µ-η1:η1:η4-PhC=C(Ph)C(Me)=CCH2NMe2) Organometallics, 9, 2167 (1990). 6. R.Della Pergola, L.Garlaschelli, C.Mealli, D.M.Proserpio and P.Zanello ELECTROCHEMISTRY OF THE TWO-DIMENSIONAL HETERONUCLEAR [Fe3Pt3(CO)15]n CLUSTERS (n=2-,1-,0): MO TREATMENT OF THE SKELETAL ADJUSTMENT IN 86-84 e− CONGENERS J.Cluster Science, 1, 93 (1990). 7. V.G.Albano, F.Demartin, M.C.Iapalucci, F.Laschi, G.Longoni, A.Sironi and P.Zanello ICOSAHEDRAL CARBONYL CLUSTERS [Ni10Sb2(µ12-Ni){Ni(CO)3}2(CO)18]n− (n = 2, 3 or 4); SYNTHESIS, SPECTROSCOPIC, ELECTROCHEMICAL AND BONDING ANALYSIS. CRYSTAL STRUCTURES OF [Ni10Sb2(µ12-Ni){Ni(CO)3}2(CO)18]n− (n = 2, or 3) J.Chem.Soc., Dalton Trans., 739 (1991). 8. C.E.Housecroft, M.S.Shongwe, A.L.Rheingold and P.Zanello SYNTHESIS AND MOLECULAR STRUCTURE OF THE BORIDO CLUSTER Fe4(CO)12BHAu2{AsPh3}2 AND AN INVESTIGATION OF THE ELECTROCHEMISTRY OF Fe4(CO)12BHAu2L2, L = AsPh3 or PPh3 J.Organomet.Chem., 408, 7 (1991). 9. D.Osella, E.Stein, C.Nervi, P.Zanello, F.Laschi, A.Cinquantini, E.Rosenberg and J.Fiedler REDOX BEHAVIOUR OF THE ELECTRONICALLY UNSATURATED CLUSTERS Os3(µ-H)2(CO)9L AND THEIR SATURATED CONGENERS Os3(µ-H)(H)(CO)10 L (L = CO, PPh 3, AsPh 3 ) Organometallics, 10, 1929 (1991). 10. A.Cinquantini, P.Zanello, R.Della Pergola, L.Garlaschelli and S.Martinengo ELECTROCHEMISTRY OF [M6(CO)15]2− ANIONIC CLUSTERS (M = Co AND Ir). PREPARATION AND

CHEMICAL CHARACTERIZATION OF [Ir6(CO)14(NCO)]− AND OF THE RADICAL ANION [Ir6(CO)15]−. PROPOSED MECHANISM OF FORMATION OF THE HEXANUCLEAR SUBSTITUTED CLUSTERS [Ir6(CO)15Cl]− J.Organomet.Chem., 412, 215 (1991). 11. A.Ceriotti, R.Della Pergola, L.Garlaschelli, F.Laschi, M.Manassero, N.Masciocchi, M.Sansoni and P.Zanello IRON-IRIDIUM MIXED-METAL CARBONYL CLUSTERS. 3. SYNTHESIS, CHEMICAL CHARACTERIZATION, ELECTROCHEMICAL BEHAVIOR, AND SOLID-STATE STRUCTURES OF [NEt4]3[FeIr5(CO)15], [NMe3(CH2Ph)]2[HFeIr5(CO)15] AND [NMe3(CH2Ph)][FeIr(CO)16]. SPECTROSCOPIC AND CHEMICAL EVIDENCE FOR THE EXISTENCE OF [HFe3Ir(CO)12]2−, [H2Fe3Ir(CO)12]− and [H2FeIr5(CO)15]− Inorg.Chem., 30, 3349 (1991). 12. D.Osella, M.Ravera, C.Nervi, C.E.Housecroft, P.R.Raithby, P.Zanello and F.Laschi ELECTROCHEMICAL, THEORETICAL, AND STRUCTURAL INVESTIGATIONS ON THE "BUTTERFLY" Co4(CO)8L2(RC2R) (L = CO, PPh3; R = H, Et, Ph) CLUSTERS Organometallics, 10, 3253 (1991). 13. D.Osella, M.Ravera, A.K.Smith, A.J.Mathews and P.Zanello ELECTROCHEMICAL BEHAVIOUR OF THE ELECTRONICALLY AND COORDINATIVELY UNSATURATED CLUSTER [Os3(µ-H)(CO)8{Ph2PCH2P(Ph)C6H4}] J.Organomet.Chem., 423, 255 (1992). 14. V.G.Albano, F.Demartin, M.C.Iapalucci, G.Longoni, M.Monari and P.Zanello NEW ICOSAHEDRAL HETEROMETALLIC NICKEL CARBONYL CLUSTERS CONTAINING BISMUTH J.Chem.Soc., Dalton Trans., 497 (1992). 15. A.Ceriotti, R.Della Pergola, L.Garlaschelli, G.Longoni, M.Manassero, N.Masciocchi, M.Sansoni and P.Zanello SYNTHESIS AND CHEMICAL BEHAVIOUR OF THE [Co6Ni2C2(CO)16]2− CLUSTER. ELECTROGENERATION OF [Co6Ni2C2(CO)16]n− (n =1,2,3,4) CLUSTER ANIONS. CRYSTAL AND MOLECULAR STRUCTURES OF [NEt4]2[Co6Ni2C2(CO)16] and [NEt4]2[Co6Ni2C2(CO)14(CH3CN)2] Gazz.Chim.Ital., 122, 365 (1992). 16. R.Hourihane, T.R.Spalding, G.Ferguson. T.Deeney and P.Zanello CHARACTERIZATION OF A NEW SOLID STATE ISOMER OF THE [Fe5N(CO)14]− ION J.Chem.Soc., Dalton Trans., 43 (1993). 17. R.Della Pergola, F.Demartin, L.Garlaschelli, M.Manassero, S.Martinengo, N.Masciocchi and P.Zanello, CHEMISTRY OF IRIDIUM CARBONYL CLUSTER COMPLEXES. SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF [PPh4][Ir12(CO)5(CO)19] CONTAINING AN UNPRECEDENTED METAL SKELETON Inorg.Chem., 32, 3670 (1993). 18. R.Della Pergola, L.Garlaschelli, M.Manassero, N.Masciocchi and P.Zanello SYNTHESIS, CRYSTAL STRUCTURE AND ELECTROCHEMICAL BEHAVIOUR OF THE PARAMAGNETIC ANION [Ir14(CO)27]− POSSESSING A TRIGONAL BIPYRAMIDAL ARRANGEMENT OF METAL ATOMS Angew.Chem.Int.Ed.Engl., 32, 1347 (1993). 19. V.G.Albano, R.Aureli, M.C.Iapalucci, F.Laschi, G.Longoni, M.Monari and P.Zanello SYNTHESIS, CHARACTERIZATION AND ELECTROCHEMICAL BEHAVIOUR OF THE [Fe4Au(CO)16]n− (n = 1, 2, 3) CLUSTERS. X-RAY STRUCTURE OF [NMe3CH2Ph]2[Fe4Au(CO)16]Cl J.Chem.Soc., Chem.Commun., 1501 (1993).

20. M.K.Brown, P.A.Dolby, M.Harding, A. J.Mathews, A.K.Smith, D.Osella, M.Arbrun, R.Gobetto, P.R.Raithby and P.Zanello REACTIONS OF THE CO-ORDINATIVELY UNSATURED CLUSTER [Os3(µ-H)(CO)8[Ph2PCH2P(Ph)C6H4]] WITH ALKYNES RCCR (R = Ph, C6H4Me, Me OR CF3); CRYSTAL STRUCTURES OF [Os3(CO)8 [µ3-η2(||)-RC2R](Ph2PCH2PPh)] (R = Me OR CF3) AND ELECTROCHEMICAL BEHAVIOUR OF TRIOSMIUM-ALKYNE CLUSTERS J.Chem.Soc., Dalton Trans., 827 (1993). 21. R. Della Pergola, L. Garlaschelli, M. Manassero, N. Masciocchi and P. Zanello STRUCTURE AND ELECTROCHEMICAL BEHAVIOUR OF THE PARAMAGNETIC ANION [Ir14(CO)27]− POSSESSING A TRIGONAL BIPYRAMIDAL ARRANGEMENT OF METAL ATOMS Angew.Chem. Int.Ed., 32, 1347 (1993). 22. E.Brivio, A.Ceriotti, R.Della Pergola, L.Garlaschelli, F.Demartin, M.Manassero, M.Sansoni, P.Zanello and B.T.Heaton SYNTHESIS AND SOLID-STATE STRUCTURE OF [Pd6Ru6(CO)24]2−. ELECTROCHEMISTRY AND 13C NUCLEAR MAGNETIC RESONANCE SPECTRA OF [Fe6Pd6H(CO)24]3− AND [Pd6Ru6(CO)24]2− J.Chem.Soc., Dalton Trans., 3237 (1994). 23. P.Zanello, F.Laschi, A.Cinquantini, R.Della Pergola, L.Garlaschelli, M.Cucco, F.Demartin and T.R.Spalding THE REDOX BEHAVIOUR OF THE CLUSTER ANION [Fe4N(CO)12]−. ELECTRON TRANSFER CHAIN CATALYTIC SUBSTITUTION REACTIONS. CRYSTAL STRUCTURE OF [Fe4N(CO)11(PPh3)]− Inorg.Chim.Acta, 226, 1 (1994). 24. V.G.Albano, F.Calderoni, M.C.Iapalucci, G.Longoni, M.Monari and P.Zanello SYNTHESIS, CHEMICAL, AND ELECTROCHEMICAL CHARACTERIZATION OF THE [Ag13{µ3-Fe(CO)4}8]n− (n = 3, 4, 5) CLUSTER ANIONS: X-RAY STRUCTURAL DETERMINATION OF [N(PPh3)2]3[Ag12(µ12-Ag){µ3-Fe(CO)4}8] J. Cluster Sci., 6, 1 (1995). 25. R.Della Pergola, C.Bandini, F.Demartin, E.Diana, L.Garlaschelli, P.L.Stanghellini and P.Zanello CHARACTERIZATION, REDOX PROPERTIES AND STRUCTURES OF THE IRON NITRIDOCARBONYL CLUSTERS [Fe4N(CO)11{C5H4FeC5H5)2}]−, [Fe6N(CO)15]3− AND [Fe6H(N)(CO)15]2− J.Chem.Soc., Dalton Trans., 747 (1996). 26. R.Della Pergola, A.Cinquantini, E.Diana, L.Garlaschelli, F.Laschi, P.Luzzini, M.Manassero, A.Repossi, M.Sansoni, P.L.Stanghellini and P.Zanello IRON-RHODIUM AND IRON-IRIDIUM MIXED-METAL NITRIDO-CARBONYL CLUSTERS. SYNTHESIS, CHARACTERIZATION, REDOX PROPERTIES, AND SOLID-STATE STRUCTURE OF THE OCTAHEDRAL CLUSTERS [Fe5RhN(CO)15]2−, [Fe5IrN(CO)15]2−, AND [Fe4Rh2N(CO)15]−. INFRARED AND NUCLEAR MAGNETIC RESONANCE SPECTROSCOPIC STUDIES ON THE INTERSTITIAL NITRIDE Inorg.Chem., 36, 3761 (1997). 27. R.Della Pergola, A.Ceriotti, A.Cinquantini, F.Fabrizi de Biani, L.Garlaschelli, M.Manassero, R.Piacentini, M.Sansoni and P.Zanello OCTAHEDRAL IRIDIUM CLUSTERS: SYNTHESIS, ELECTROCHEMICAL MECHANISMS OF FORMATION, AND SOLID-STATE STRUCTURES OF [Ir6(CO)14(µ-TePh)]− AND [Ir6(CO)13(µ-TePh)2] Organometallics, 17, 802 (1998). 28. F.Calderoni, F.Demartin, F.Fabrizi de Biani, C.Femoni, M.C.Iapalucci, G.Longoni and P.Zanello ELECTRON-SINK BEHAVIOUR OF THE CARBONYLNICKEL CLUSTERS [Ni32C6(CO)36]6− AND [Ni38C6(CO)42]6−:

SYNTHESIS AND CHARACTERISATION OF THE ANIONS [Ni32C6(CO)36]n− (n = 5-10) AND [Ni38C6(CO)42]n− (n = 5-9) AND CRYSTAL STRUCTURE OF [PPh3Me]6[Ni32C6(CO)36].4 MeCN Eur.J.Inorg.Chem., 663 (1999). 29. F.Fabrizi de Biani, C.Femoni, M.C.Iapalucci, G.Longoni, P.Zanello and A.Ceriotti REDOX BEHAVIOUR OF [H6-nNi38Pt6(CO)48]n− (n = 4-6) ANIONS: A SERIES OF METAL CARBONYL CLUSTERS DISPLAYING ELECTRON-SINK FEATURES Inorg.Chem., 38, 3721 (1999). 30. V.G.Albano, F.Demartin, C.Femoni, M.C.Iapalucci, G.Longoni, M.Monari and P.Zanello SYNTHESIS AND CHARACTERIZATION OF NEW PARAMAGNETIC NICKEL CARBONYL CLUSTERS CONTAINING ANTIMONY ATOMS: X-RAY STRUCTURE OF [NEt3CH2Ph]2[Ni15(µ12-Sb)(CO)24] AND [NEt4]3[Ni10Sb2(µ12-Ni)(CO)18] J.Organomet.Chem., 593-594, 325 (2000). 31. F.Demartin, F.Fabrizi de Biani, C.Femoni, M.C.Iapalucci, G.Longoni, P.Macchi and P.Zanello SYNTHESIS, ELECTROCHEMISTRY AND CRYSTAL STRUCTURE OF THE [Ni36Pt4(CO)45]6− AND [Ni37Pt4(CO)46]6− HEXAANIONS J.Cluster Sci., 12, 61 (2001). 32. R.Della Pergola, L.Garlaschelli, M.Manassero, M.Sansoni, D.Strumolo, F.Fabrizi de Biani and P.Zanello REACTIVITY OF NITRIDO-CARBONYL CLUSTERS: SYNTHESIS AND SOLID STATE STRUCTURE OF [Fe5MnN(CO)16]2− AND [Fe6N(CO)14(NO)]2−; OXIDATION OF A CLUSTER-COORDINATED NITRIDE J.Chem.Soc., Dalton Trans., 2179 (2001). 33. G.Ciani, A.Sironi, S.Martinengo, L.Garlaschelli, R.Della Pergola, P.Zanello, F.Laschi and N.Masciocchi SYNTHESIS AND X-RAY CHARACTERIZATION OF THE PHOSPHIDO-CARBONYL CLUSTER ANIONS [Co9(µ8-P)(CO)21]2− AND [Co10(µ8-P)(CO)22]3− Inorg.Chem., 40, 3905 (2001). 34. D.Collini, C.Femoni, M.C.Iapalucci, G.Longoni, P.H.Svensson and P.Zanello TUNING ELECTRONIC BEHAVIOR OF CARBONYL METAL CLUSTERS BY SUBSTITUTIONOF INTERSTITIAL AND CAPPING ATOMS Angew.Chem.Int.Ed., 41, 3685 (2002). 35. R.Della Pergola, A.Bianchi, F.Fabrizi de Biani, L.Garlaschelli, M.Manassero, M.Sansoni, D.Strumolo and P.Zanello DIFFERENT BONDING MODES OF THE C7 RING ON IRIDIUM CLUSTERS. SYNTHESIS, ELECTROCHEMISTRY, AND SOLID STATE STRUCTURES OF [Ir6(CO)13(µ3-η2:η2:η2-C7H8)], [Ir6(CO)12(µ3-η2:η3:η2-C7H7)]−, and [Ir6(CO)12(µ3-η2:η2:η2-C7H8)]2− Organometallics, 21, 5642 (2002). 36. A.Fumagalli, M.Costa, R.Della Pergola, P.Zanello, F.Fabrizi de Biani, P.Macchi and A.Sironi SYNTHESIS, STRUCTURAL AND ELECTROCHEMICAL CHARACTERIZATION OF THE NITRIDO-CARBONYL CLUSTER ANION [Co13N2(CO)24]3−. THE DIFFERENT REDOX PROPENSITY OF THE TWO ISOSTRUCTURAL FAMILIES [Co13N2(CO)24]n− AND [Co13C2(CO)24]m− Inorg.Chim.Acta, 350, 187 (2003). 37. C.Femoni, M.C.Iapalucci, G.Longoni, P.H.Svensson, P.Zanello and F.Fabrizi de Biani SYNTHESIS AND CHARACTERISATION OF ν3-OCTAHEDRAL [Ni36Pd8(CO)48]6− AND [Ni35Pd9(CO)48]6− CLUSTERS DISPLAYING UNEXPECTED SURFACE SEGREGATION OF Pt ATOMS AND MOLECULAR AND/OR CRYSTAL SUBSTITUTIONAL Ni/Pd AND Ni/Pt DISORDER Chem.Eur.J., 10, 2318 (2004).

38. A.Fumagalli, P.Ulivieri, M.Costa, O.Crispu, R.Della Pergola, F.Fabrizi de Biani, F.Laschi, P.Zanello, P.Macchi and A.Sironi ELECTRON TRANSFER AND CO ADDITION OF POLYNITRIDO COBALT CARBONYL CLUSTERS: PARALLEL PATHWAYS FOR CONVERSION OF THE [Co10N2(CO)19]4− ANION TO THE NOVEL [Co11N2(CO)21]3− ANION Inorg.Chem., 43, 2125 (2004). 39. R.Della Pergola, A.Fumagalli, F.Fabrizi de Biani, L.Garlaschelli, F.Laschi, M.C.Malatesta, M.Manassero, E.Roda, M.Sansoni and P.Zanello CARBONYL-NITRIDO MIXED-METAL CLUSTERS: SYNTHESIS, REACTIVITY, ELECTROCHEMICAL BEHAVIOR AND SOLID-STATE STRUCTURE OF [Co5MoN(CO)14]2− AND [Co5MoN(CO)14AuPPh3]− Eur.J.Inorg.Chem., 3901 (2004). 40. D.Belletti, C.Graiff, R.Pattacini, G.Predieri, A.Tiripicchio, F.Fabrizi de Biani and P.Zanello LIGAND SUBSTITUTION AND GROWTH REACTIONS WITH Ru3Se2 NIDO CLUSTERS. COORDINATION ISOMERISM IN [WRu3(µ4-Se)2(µ-CO)4(CO)7(L)] (L = PHOSPHINE LIGAND) AND ELECTROCHEMICAL BEHAVIOUR OF THE Ru3MSe2 CORE CLUSTERS (M = Ru, W) IN SOLUTION Inorg.Chim.Acta, 358, 161 (2005). 41. F.Fabrizi de Biani, A.Ienco, F.Laschi, P.Leoni, F.Marchetti, L.Marchetti, C.Mealli and P.Zanello FORMATION AND CHARACTERIZATION OF THE HEXANUCLEAR PLATINUM CLUSTER [Pt6(µ-PBut

2)4(CO)6](CF3SO3)2 THROUGH STRUCTURAL, ELECTROCHEMICAL, AND COMPUTATIONAL ANALYSES J.Am.Chem.Soc., 127, 3076 (2005). 42. R.Della Pergola, M.Bruschi, F.Fabrizi de Biani, A.Fumagalli, L.Garlaschelli, F.Laschi, M.Manassero, M.Sansoni and P.Zanello A NEW MULTIVALENT CLUSTER: SYNTHESIS, ELECTROCHEMISTRY, SOLID STATE STRUCTURE AND COMPUTATIONAL STUDIES ON THE IRON-NICKEL MIXED-METAL NITRIDE ANIONS [Fe6Ni6N2(CO)24]n− (n = 2 – 4) C.R.Chimie, 8, 1850 (2005).

43. A.Albinati, F.Fabrizi de Biani, P.Leoni, L.Marchetti, M.Pasquali, S.Rizzato and P.Zanello REDOX CONTROL OF LIGHT-INDUCED PLATINUM-CLUSTER-TO-IRON CHARGE TRANSFER IN A BIS(FERROCENYLETHYNYL)-SUBSTITUTED HEXANUCLEAR PLATINUM DERIVATIVE Angew.Chem.Int.Ed., 44, 5701 (2005). 44. D.Collini, S.Fedi, C.Femoni, F.Kaswalder, M.C.Iapalucci, G.Longoni, and P.Zanello, NEW BIMETALLIC Ni-Rh CARBONYL CLUSTERS: SYNTHESIS AND X-RAY STRUCTURE OF THE [Ni7Rh3(CO)18]3−, [Ni3Rh3(CO)13]3− AND [NiRh8(CO)19]2− CLUSTER ANIONS J.Cluster Science, 16, 455 (2005). 45. M.Costa, R. Della Pergola, A.Fumagalli, F.Laschi, S.Losi, P.Macchi, A.Sironi and P.Zanello MIXED Co-Rh NITRIDO-ENCAPSULATED CARBONYL CLUSTERS. SYNTHESIS, SOLID-STATE STRUCTURE, AND ELECTROCHEMICAL/EPR CHARACTERIZATION OF THE ANIONS [Co10Rh(N)2(CO)21]3−, [Co10Rh2(N)2(CO)24]2−, [Co11Rh(N)2(CO)24]2− Inorg. Chem. 46, 552 (2007). 46. D.Collini, F.Fabrizi De Biani, S.Fedi, C.Femoni, F.Kaswalder, M.C.Iapalucci, G.Longoni, C.Tiozzo, S.Zacchini and P.Zanello SYNTHESIS AND ELECTROCHEMISTRY OF NEW Rh-CENTERED AND CONJUNCTO RHODIUM CARBONYL

CLUSTERS. X-RAY STRUCTURE OF [NEt4]3[Rh15(CO)27], [NEt4]3[Rh15(CO)25(MeCN)2]·2MeCN, AND [NEt4]3[Rh17(CO)37] Inorg.Chem., 46, 7971 (2007). 47. C.Femoni, M.C.Iapalucci, G.Longoni, F.Ranuzzi, S.Zacchini, S.Fedi and P.Zanello CONDENSATION OF NICKEL-CARBONYL CLUSTERS WITH SOFT LEWIS ACIDS: SYNTHESIS AND CHARACTERISATION OF THE {Cd2Cl3[Ni6(CO)12]2}3− DIMER Eur.J.Inorg.Chem., 4064 (2007). 48. C.Bonaccorsi, F.Fabrizi de Biani, P.Leoni, F.Marchetti, L.Marchetti and P.Zanello SITE SELECTIVITY IN THE REACTIONS OF THE HEXANUCLEAR PLATINUM CLUSTER [Pt6(µ-PtBu2)4(CO)6][CF3SO3]2 Chem.Eur.J., 14, 847 (2008). 49. A.Bernardi, C.Femoni, M.C.Iapalucci, G.Longoni, F.Ranuzzi, S.Zacchini, P.Zanello and S.Fedi SYNTHESIS, MOLECULAR STRUCTURE AND PROPERTIES OF THE [H6-nNi30C4(CO)34(CdCl)2]n− (n=3-6) BIMETALLIC CARBIDE CARBONYL CLUSTER: A MODEL FOR THE GROWTH OF NONCOMPACT INTERSTITIAL METAL CARBIDES Chem.Eur.J., 14, 1924 (2008).

50. R.Della Pergola, L.Garlaschelli, M.Manassero, C.Manassero, A.Sironi, D.Strumolo, S.Fedi, E.Grigiotti and P.Zanello Fe–Rh AND Fe–Ir CLUSTERS SUBSTITUTED BY DIPHENYLACETYLENE: SYNTHESIS, SOLID STATE STRUCTURE AND ELECTROCHEMICAL BEHAVIOUR OF [Fe2Ir2(CO)10(µ4:η2-PhCCPh)]2−, [FeIr2(CO)9(µ3:η2-PhCCPh)], AND [Fe2Rh(CO)8(µ3:η2-PhCCPh)]− Inorg. Chim. Acta, 362, 331 (2009). 51. C.Cavazza, F.Fabrizi de Biani, T.Funaioli, P.Leoni, F.Marchetti, L.Marchetti and P. Zanello SYNTHESIS AND ELECTROCHEMICAL CHARACTERIZATION OF HALIDE, ISOCYANIDE, AND ALKYNYL SYNTHONS CONTAINING THE ENCUMBERED TRIANGULAR CLUSTER UNIT Pt3(µ-PtBu2)3 Inorg. Chem., 48, 1385 (2009). 52. C.Femoni, M.C.Iapalucci, G.Longoni, C.Tiozzo, S.Zacchini, B.T.Heaton, J.A.Iggo, P.Zanello, S.Fedi, M.V.Garland and C.Li THE LOSS OF CO FROM [Rh12(µ12-Sn)(CO)27]4-: SYNTHESIS, SPECTROSCOPIC AND STRUCTURAL CHARACTERIZATION OF THE ELECTRON-DEFICIENT, ICOSAHEDRAL [Rh12(µ12-Sn)(CO)25]4- AND [Rh12(µ12-Sn)(CO)26]4- TETRA-ANIONS Dalton Trans., 2217 (2009). 53. E.Leary, H.Van Zalinge, S.J.Higgins, R.J.Nichols, F.Fabrizi de Biani, P.Leoni, L.Marchetti and P.Zanello A MOLECULAR WIRE INCORPORATING A ROBUST HEXANUCLER PLATINUM CLUSTER Phys.Chem.Chem.Phys., 11, 5198 (2009). 54. S. Fedi, P.Zanello, F.Laschi, A. Ceriotti, S. El Afefey A JOINT ELECTROCHEMICAL/SPECTROELECTROCHEMICAL INSPECTION (AND RE-INSPECTION) OF HIGH- NUCLEARITY PLATINUM CARBONYL CLUSTERS J. Solid State Electrochem.,13, 1497 (2009). 55. R.Della Pergola, A.Sironi, L.Garlaschelli, D.Strumolo, C.Manassero, M.Manassero, S.Fedi, P.Zanello, F.Kaswalder and S.Zacchini Fe-Cu OCTAHEDRAL CARBIDE CLUSTERS AND THE REPLACEMENT OF THEIR LABILE HALIDE LIGANDS: SYNTHESIS, SOLID STATE STRUCTURE, SUBSTITUTION AND ELECTROCHEMICAL REACTIVITY OF

[Fe5C(CO)14(CuBr)]2−, [Fe4C(CO)12(CuCl)]2−, [{Fe4Cu2C(CO)12(µ-Cl)}]2−, [Fe5C(CO)14(CuOC4H8) ]− AND [Fe4C(CO)12(CuNCMe)2] Inorg.Chim.Acta, 363, 586 (2010). 56. C.Femoni, M.C.Iapalucci, G.Longoni, J.Wolowska, S.Zacchini, P.Zanello, S.Fedi, M.Riccò, D.Pontiroli and M.Mazzani MAGNETIC BEHAVIOR OF ODD- AND EVEN-ELECTRON METAL CARBONYL CLUSTERS: THE CASE STUDY OF [Co8Pt4C2(CO)24]n− ( n = 1, 2) CARBIDE CLUSTER J.Am.Chem.Soc., 132, 2919 (2010). 57. A.Bernardi, C.Femoni, M.C.Iapalucci, G.Longoni, S.Zacchini, S.Fedi and P.Zanello SYNTHESIS, STRUCTURES AND ELECTROCHEMISTRY OF NEW CARBONYL-NICKEL OCTACARBIDE CLUSTERS: THE DISTORTING ACTION OF CARBIDE ATOMS IN THE GROWTH OF Ni CAGES AND THE FIRST EXAMPLE OF THE INCLUSION OF A CARBON ATOM WITHIN A (DISTORTED) Ni OCTAHEDRAL CAGE Eur.J.Inorg.Chem., 4831 (2010). 58. R. Della Pergola, M. Bruschi, A. Sironi, M. Manassero, C. Manassero, D. Strumolo, S. Fedi and P.Zanello STRUCTURAL VARIATIONS, ELECTROCHEMICAL PROPERTIES AND COMPUTATIONAL STUDIES ON MONOMERIC AND DIMERIC Fe–Cu CARBIDE CLUSTERS, FORMING COPPER-BASED STAPLE ARRAYS Dalton Trans., 40, 5464 (2011). 59. L.Cherchi, A.Fumagalli, S.Fedi, P.Zanello, F.Fabrizi de Biani, F.Laschi, L.Garlaschelli, P.Macchi and A.Sironi SYNTHESIS, REACTIVITY, ELECTROCHEMICAL BEHAVIOR, AND CRYSTAL STRUCTURE OF A FAMILY OF MULTIVALENT METAL CARBIDO−CARBONYL CLUSTERS BASED ON THE Rh10(C)2Au4−6 FRAMEWORK Inorg. Chem., 51, 9171 (2012).

(c) Metal clusters of other ligands 1. M.Di Vaira, P.Stoppioni, S.Midollini, F.Laschi and P.Zanello H+ ADDITION TO THE HETEROATOMIC CoP3 CLUSTER. SYNTHESIS OF THE RADICAL CoP3

+ CLUSTER AND ELECTROCHEMICAL STUDY Polyhedron, 10, 2123 (1991). 2. I.Bachert, P.Braunstein, M.K.McCart, F.Fabrizi de Biani, F.Laschi, P.Zanello, G.Kickelbick and U.Schubert SYNTHESIS, STRUCTURE AND ELECTROCHEMICAL STUDIES OF THE FIRST MIXED-METAL CLUSTERS WITH THE P-N-P ASSEMBLING LIGANDS (Ph2P)2NH(dppa), (Ph2P)2N(CH3)(dppam) AND (Ph2P)2N(CH2)3Si(OEt)3(dppaSi) J.Organomet.Chem., 573, 47 (1999). 3. J.J.Schneider, J.Hagen, D.Bläser, R.Boese, F.Fabrizi de Biani, P.Zanello and C.Krüger SYNTHESIS, STRUCTURE ELECTROCHEMISTRY AND REACTVITY OF THE BIS (µ-σ-STANNEDIYL)DINICKEL BUTTERFLY CLUSTER [{{(SiMe3)2CH}2Sn-Ni(η5-Cp)}2](Ni2-Sn2) Eur.J.Inorg.Chem., 1987 (1999). 4. R.Bender, P.Braunstein, S.-E.Bouaoud, N.Merabet, D.Rouag, P.Zanello and M.Fontani

FIRST PLATINUM CLUSTERS CONTAINING A DIRECT Pt-Si BOND: MOLECULAR STRUCTURE OF [Pt3{Si(OSiMe3)3}(µ-PPh2)3(PPh3)2] AND ELECTROCHEMICAL STUDIES New J.Chem., 23, 1045 (1999). 5. A.Battisti, O.Bellina, P.Diversi, S.Losi, F.Marchetti and P.Zanello PREPARATION, STRUCTURE AND REACTIVITY OF POLYNUCLEAR GOLD(I) PHOSPHINO ALKANETHIOLATES Eur.J.Inorg.Chem., 865 (2007). 6. D.V.Muratov, F.M.Dolgushin, S.Fedi, P.Zanello and A.R. Kudinov OCTAHEDRAL (CYCLOPENTADIENYL) RHODIUM CLUSTERS [Rh6Cp6(µ6-C)]2+ AND [Rh6Cp6(µ3-CO)2]2+ : SYNTHESIS, STRUCTURES AND ELECTROCHEMISTRY Inorg. Chim. Acta, 374, 313 (2011).

4 SANDWICH COMPLEXES

(a) Ferrocenes 1. P.Zanello, G.Opromolla, M.Casarin, M.Herberhold and P.Leitner THE REDOX BEHAVIOUR OF FERROCENE DERIVATIVES. I. 1,2,3-TRITELLURA-[3]FERROCENOPHANE AND 1,3-DITELLURA[3]FERROCENOPHANES J.Organomet.Chem., 443, 199 (1993). 2. A.Cinquantini, G.Opromolla, P.Zanello and G.Giorgi THE REDOX BEHAVIOUR OF FERROCENE DERIVATIVES. II. 8-FERROCENYL-2-HYDROXYTRICYCLO[7,3,1,02,7]TRIDECAN-13-ONE AND tert-PENTYLFERROCENE J.Organomet.Chem., 444, 179 (1993). 3. P.Zanello, G.Opromolla, L.Pardi, K.H.Pannell and H.K.Sharma THE REDOX BAHAVIOUR OF FERROCENE DERIVATIVES. III. FERROCENYLACYL COMPLEXES (η5-C5H5)Fe(η5-C5H4-COER3), E=C,Si,Ge; R=Me, Ph J.Organomet.Chem., 450, 193 (1993). 4. J.C.Gallucci, G.Opromolla, L.A.Paquette, L.Pardi, P.F.T.Schirch, M.R.Sivik and P.Zanello THE REDOX BEHAVIOR OF FERROCENE DERIVATIVES. IV. 1BIS(η5-TRICYCLO[5.2.1.0 2,6 ]DECA-2,5,8-TRIEN-6-YL) IRON AND RELATED MOLECULES Inorg.Chem., 32, 2292 (1993). 5. P.Zanello, G.Opromolla, G.Giorgi, J.C.Van de Grampel and H.F.M.Schoo THE REDOX BEHAVIOUR OF FERROCENE DERIVATIVES. V. 5,5'-FERROCENEDIYLDI(5-FLUORO-1,3-DIPHENYL-1-λ6,3-λ6,2,4,6,5-λ5-DITHIATRIAZAPHOSPHORINE-1,3- DIOXIDE) Polyhedron, 12, 1329 (1993). 6. A.Togni, M.Hobi, G.Rihs, G.Rist, A.Albinati, P.Zanello, D.Zech and H.Keller 1,1'-DISUBSTITUTED FERROCENES AS DONORS FOR CHARGE-TRANSFER COMPLEXES. SYNTHESIS, STRUCTURE, CONDUCTIVITY, AND MAGNETIC PROPERTIES Organometallics, 13, 1224 (1994). 7. P.Zanello, A.Cinquantini, S.Mangani, G.Opromolla, L.Pardi, C.Janiak and M.D.Rausch THE REDOX BEHAVIOUR OF FERROCENE DERIVATIVES. VI. BENZYL-FERROCENES. THE CRYSTAL STRUCTURE OF DECABENZYLFERROCENIUM ION

J.Organomet.Chem., 471, 171 (1994). 8. P.Zanello, G.Opromolla, M.Herberhold and H.-D.Brendel REDOX BEHAVIOUR OF FERROCENE DERIVATIVES. VII. CHALCOGEN-BRIDGED TRI- AND TETRA-NUCLEAR FERROCENES J.Organomet.Chem., 484, 67 (1994). 9. N.J.Long, P.R.Raithby and P.Zanello SYNTHETIC, STRUCTURAL AND ELECTROCHEMICAL STUDIES ON SOME DOUBLY BRIDGED TRICHALCOGEN[3.3]FERROCENOPHANES J.Chem.Soc., Dalton Trans., 1245 (1995). 10. P.Zanello, M.Casarin, L.Pardi, M.Herberhold and G.-X.Jin ELECTROCHEMICAL, SPECTROSCOPIC AND THEORETICAL STUDIES OF A SERIES OF 1,1'-FERROCENE DICHALCOGENIDO-COMPLEXES OF RHODIUM AND IRIDIUM J.Organomet.Chem., 503, 243 (1995). 11. P.Zanello, G.Opromolla, G.Giorgi, G.Sasso and A.Togni REDOX BEHAVIOUR OF FERROCENE DERIVATIVES. VIII. 1,1'-BIS(DIPHENYL-PHOSPHINO)FERROCENES J.Organomet.Chem., 506, 61 (1996). 12. G.Ferguson, C.Glidewell, G.Opromolla, C.M.Zakaria and P.Zanello THE REDOX BEHAVIOUR OF FERROCENYL ALCOHOLS AND FERROCENEDIYL DIOLS: CRYSTAL AND MOLECULAR STRUCTURE OF FERROCENYL(2-FURYL)PHENYLMETHANOL J.Organomet.Chem., 506, 129 (1996). 13. A.G.Osborne, M.Webba da Silva, M.B.Hursthouse, K.M.A.Malik, G.Opromolla and P.Zanello SYNTHETIC, STRUCTURAL AND ELECTROCHEMICAL STUDIES ON SOME FERROCENYLAZINES: CRYSTAL STRUCTURE OF [4](1)(1,4-DIMETHYL-2,3-DIAZABUTA-1,3-DIEN) FERROCENOPHANE AND [42](1,1')BIS(1,4-DIMETHYL-2,3-DIAZABUTA-1,3-DIEN) FERROCENOPHANE J.Organomet.Chem., 516, 167 (1996). 14. G.Ferguson, C.Glidewell, G.Opromolla, C.M.Zakaria and P.Zanello THE REDOX BEHAVIOUR OF SOME BIS-FERROCENYL COMPOUNDS: CRYSTAL AND MOLECULAR STRUCTURES OF DIFERROCENYL METHANE AND DIFERROCENYL METHANOL J.Organomet.Chem., 517, 183 (1996). 15. M.Herberhold, B.Distler, H.Maisel, W.Milius, B.Wrackmeyer and P.Zanello FERROCENYL SULFINYLIMIDE AND DIFERROCENYL SULFURDIIMIDE, Fc-NSO AND Fc(NSN)Fc Z.anorg.allg.Chem., 622, 1515 (1996). 16. E.Herdtweck, F.Jäkle, G.Opromolla, M.Spiegler, M.Wagner and P.Zanello STRUCTURAL FEATURES AND ELECTROCHEMICAL PROPERTIES OF ANSA-FERROCENES WITH PYRAZABOLE BRIDGES Organometallics, 15, 5524 (1996). 17. P.Zanello, G.Opromolla, F.Fabrizi de Biani, A.Ceccanti, G.Giorgi THE REDOX BEHAVIOUR OF FERROCENE DERIVATIVES. XIII. FLUORENYL FERROCENES Inorg.Chim.Acta, 255, 47 (1997).

18. F.Fabrizi de Biani, F.Jäkle, M.Spiegler, M.Wagner and P.Zanello FERROCENE-BASED TRIS(1-PYRAZOLYL)BORATES: A NEW APPROACH TO HETEROOLIGOMETALLIC COMPLEXES AND ORGANOMETALLIC POLYMERS CONTAINING TRANSITION METAL ATOMS IN THE BACKBONE Inorg.Chem., 36, 2103 (1997). 19. H. Fink, N.J. Long, A.J. Martin, G. Opromolla, A.J.P. White, D.J. Williams and P. Zanello ETHYNYL FERROCENE COMPOUNDS OF 1,3,5-TRIBROMOBENZENE Organometallics, 16, 2646 (1997). 20. F.Fabrizi de Biani, T.Gmeinwieser, E.Herdtweck, F.Jäkle, F.Laschi, M.Wagner and P.Zanello MULTISTEP REDOX PROCESSES AND INTRAMOLECULAR CHARGE-TRANSFER IN FERROCENE-BASED 2,2'-BIPYRIDYL-BORONIUM SALTS Organometallics, 16, 4776 (1997). 21. B.Neuman, U.Siemeling, H.-G.Stammler, U.Vorfeld, J.G.P.Delis, P.W.N.M.van Leeuwen, K.Vrieze, J.Fraanje, K.Goubitz, F.Fabrizi de Biani and P.Zanello CO-ORDINATION CHEMISTRY OF OCTAMETHYL-5,5'-DI(2-PYRIDYL)FERROCENE J.Chem.Soc., Dalton Trans., 4705 (1997). 22. M.Herberhold, A.Hofmann, W.Milius, F.Fabrizi de Biani and P.Zanello OLIGONUCLEAR FERROCENOLATO AND 1,1'-FERROCENEDIOLATO DERIVATIVES OF PHOSPHOROUS: SYNTHESIS, STRUCTURE AND ELECTROCHEMICAL BEHAVIOUR Inorg.Chim.Acta, 273, 24 (1998). 23. M.Fontani, F.Peters, W.Scherer, W.Watcher, M.Wagner and P.Zanello ADDUCTS OF FERROCENYL BORANES AND PYRIDINE BASES: GENERATION OF CHARGE-TRANSFER COMPLEXES AND REVERSIBLE COORDINATION POLYMERS Eur.J.Inorg.Chem., 1453 (1998). 24. W.Palitzsch, C.Pietzsch, M.Puttnat, K.Jacob, K.Merzweiler, P.Zanello, A.Cinquantini, M.Fontani and G.Roewer BIS-(1,2-N,N-DIMETHYLAMINOMETHYLFERROCENYL)DICHLOROSILANE- STRUCTURE AND REACTIVITY J.Organomet.Chem., 587, 9 (1999). 25. P.Zanello, M.Fontani, S.Ahmed and C.Glidewell SYNTHESIS AND REDOX PROPERTIES OF FERROCENYL QUINOXALINES Polyhedron, 17, 4155 (1998). 26. B.Bildstein, M.Schweiger, H.Angleitner, H.Kopacka, K.Wurst, K.-H.Ongania, M.Fontani and P.Zanello TETRAFERROCENYL[5]CUMULENE, (Fc)2C=C=C=C=C=C(Fc)2: SYNTHESIS, ELECTROCHEMISTRY, AND REACTIVITY, INCLUDING NICHEL(0)-PROMOTED [3]FERROCENOPHANE FORMATION AND [2+2]CYCLOADDITION WITH FULLLERENE C60 Organometallics, 18, 4286 (1999). 27. B.Bildstein, M.Malaun, H.Kopacka, K.Wurst, M.Mitterböck, K.-H.Ongania, G.Opromolla and P.Zanello N,N’-DIFERROCENYL-N-HETEROCYCLIC CARBENES AND THEIR DERIVATIVES Organometallics, 18, 4325 (1999). 28. H.K.Sharma, K.H.Pannell, I.Ledoux, J.Zyss, A.Ceccanti and P.Zanello SYNTHESIS, SPECTROSCOPY, ELECTROCHEMICAL CHARACTERIZATION, AND NONLINEAR OPTICAL

PROPERTIES OF ERROCENYLOLIGOSILANES: FcSinMe2n(C6H5) (n=1-6) AND FcSi2Me4(C6H4-X) (X=m-CF3, p-Cl, p-Br, p-OMe, p-NMe2, p-CH=C(CN)2) Organometallics, 19, 770 (2000). 29. L.Ding, F.Fabrizi de Biani, M.Bolte, P.Zanello and M.Wagner REACTIVITY OF FERROCENYLBORANES: REARRANGEMENTS VERSUS ELECTRON TRANSFER REACTIONS Organometallics, 19, 5763 (2000). 30. L.Ding, K.Ma, F.Fabrizi de Biani, M.Bolte, P.Zanello and M.Wagner ELECTRONIC COMMUNICATION IN A NOVEL FIVE-STEP REDOX SYSTEM Organometallics, 20, 1041 (2001). 31. U.Siemeling, O.Kuhnert, B.Neumann, A.Stammler, H.-G.Stammler, B.Bildstein, M.Malun and P.Zanello FIRST EXAMPLES OF A NEW FAMILY OF REDOX-FUNCTIONALISED CHELATE COMPLEXES BASED ON A 1,1'-FERROCENEDIYL-BRIDGED DI(AMIDO) LIGAND Eur.J.Inorg.Chem., 913 (2001). 32. S.Guo, F.Peters, F.Fabrizi de Biani, J.W.Bats, E.Herdtweck, P.Zanello and M.Wagner ELECTRONIC COMMUNICATION IN OLIGOMETALLIC COMPLEXES WITH FERROCENE-BASED TRIS(1-PYRAZOLYL)-BORATE LIGANDS Inorg.Chem., 40, 4928 (2001). 33. L-Ding, K.Ma, M.Bolte, F.Fabrizi de Biani, P.Zanello and M.Wagner MULTISTEP REDOX PROPERTIES OF 2,2'-BIPYRIDYLBORONIUM SUBSTITUTED FERROCENES J.Organomet.Chem., 637-639, 390 (2001). 34. U.Siemeling, U.Vorfeld, B.Neumann, H.-G.Stammler, M.Fontani and P.Zanello SYNTHESIS AND CRYSTAL STRUCTURE OF 1,1'-BIS[4-(2,2':6',2"-TERPYRIDIN-4'-YL)PHENYL]OCTAMETHYLFERROCENE J.Organomet.Chem., 637-639, 733 (2001). 35. P.Zanello, A.Cinquantini, M.Fontani, M.Giardiello, G.Giorgi, C.R.Landis and B.F.M.Kimmich REDOX BEHAVIOR OF BORONATO-FUNCTIONALIZED 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENES J.Organomet.Chem., 637-639, 800 (2001). 36. L-Ding, K.Ma, M.Bolte, F.Fabrizi de Biani, P.Zanello and M.Wagner MULTISTEP REDOX PROPERTIES OF 2,2'-BIPYRIDYLBORONIUM SUBSTITUTED FERROCENES J.Organomet.Chem., 637-639, 390 (2001). 37. L.Ding, K.Ma, G.Dürner, M.Bolte, F.Fabrizi de Biani, P.Zanello and M.Wagner REACTIONS OF FERROCENYLBORANES WITH 2,5-BIS(PYRIDYL)PYRAZINE AND QUATERPYRIDINE: CHARGE-TRANSFER COMPLEXES AND REDOX-ACTIVE MACROCYCLES J.Chem.Soc., Dalton Trans., 1566 (2002). 38. R.Steudel, K.Hassenberg, J.Pickardt, E.Grigiotti and P.Zanello SYNTHETIC AND ELECTROCHEMICAL STUDIES ON 1,1'-DITHIA-SUBSTITUTED DERIVATIVES OF FERROCENE AND STRUCTURE OF 1,3-DITHIA[3]FERROCENOPHANE [Fe(C5H4S)2CH2] Organometallics, 21, 2604 (2002). 39. K.Ma, F.Fabrizi deBiani, M.Bolte, P.Zanello and M.Wagner

ELECTRONIC COMMUNICATION IN A SERIES OF NOVEL MULTISTEP REDOX SYSTEMS Organometallics, 21, 3979 (2002). 40. D.H.Hua, J.W.McGill, K.Lou, A.Ueki, B.Helfrich, J.Desper, P.Zanello, A.Cinquantini, M.Corsini and M.Fontani PARALLEL AND PERPENDICULAR STACKING OF FERROCENE RINGS. SYNTHESES, X-RAY STRUCTURES, AND ELECTROCHEMISTRY OF 1,8-BIS-[1-(1’-PHENYLTHIO)FERROCENYL]NAPHTHALENE AND 8,8’-BIS-[1-(1’-PHENYLTHIO)FERROCENYL]-1,1’-BINAPHTHYL Inorg.Chim.Acta, 350, 259 (2003). 41. E.I.Klimova, T.K.Berestneva, L.R.Ramirez, A.Cinquantini, M.Corsini, P.Zanello, S.Hernández-Ortega and M.M.García 2,3-DIFERROCENYLCYCLOPROPENONE: SYNTHESIS, STRUCTURE, AND SOME CHEMICAL AND ELECTROCHEMICAL PROPERTIES Eur.J.Org.Chem., 4265 (2003). 42. E.I.Klimova, T.K.Berestneva, A.Cinquantini, M.Corsini, P.Zanello, R.A.Toscano, S.Hernández-Ortega and M.M.García 3,3-DIETHYL- AND 3,3-DIBENZYL-1,2-DIFERROCENYLCYCLOPROPENES Org.Biomol.Chem., 1, 4458 (2003). 43. W.Skibar, H.Kopacka, K.Wurst, C.Salzmann, K.-H.Ongania, F.Fabrizi de Biani, P.Zanello and B.Bildstein α,ω-DIFERROCENYL CUMULENE MOLECULAR WIRES. SYNTHESIS, SPECTROSCOPY, STRUCTURE, AND ELECTROCHEMISTRY Organometallics, 23, 1024 (2004). 44. M.D.Thomson, M.Novosel, H.G.Roskos, T.Müller, M.Scheibitz, M.Wagner, F.Fabrizi de Biani and P. Zanello, ELECTRONIC STRUCTURE, PHOTOPHYSICS, AND RELAXATION DYNAMICS OF CHARGE TRANSFER EXCITED STATES IN BORON-NITROGEN-BRIDGED FERROCENE-DONOR ORGANIC- ACCEPTOR COMPOUNDS J.Phys.Chem., A 108, 3281 (2004). 45. T.Höcher, A.Cinquantini, P.Zanello and E.Hey-Hawkins NOVEL [3]FERROCENOPHANES: SYNTHESIS, REDOX PROPERTIES AND MOLECULAR STRUCTURES OF [Fe{η5-C5H4)CMe2}2PR] (R = Ph, Cy), Polyhedron, 24, 1340 (2005). 46. V.Barba, N.Farfán, S.Losi and P.Zanello FERROCENYLBORONATES; CRYSTAL STRUCTURES AND ELECTROCHEMICAL PROPERTIES Inorg.Chim.Acta, 359, 1269 (2006). 47. L.Tebben, M.Neumann, G.Kehr, R.Fröhlich, G.Erker, S.Losi and P.Zanello DEVELOPMENT OF A CONVENIENT NEW SYNTHETIC ROUTE TO [3]FERROCENOPHANONES Dalton Trans., 1715 (2006).

(b) Metallocenes and Metallametallocenes 1. W.Buchowicz, L.B.Jerzykiewicz, A.Krasińska, S.Losi, A.Pietrzykowski and P.Zanello ANSA-NICKELOCENES BY THE RING-CLOSING METATHESIS ROUTE: SYNTHESES, X-RAY CRYSTAL STRUCTURES, AND PHYSICAL PROPERTIES

Organometallics, 25, 5076 (2006). 2. S.Losi, F.Rossi, F.Laschi, F.Fabrizi de Biani, P.Zanello, P.Buchalski, K.Burakowska, K.Piwowar, J.Zbrzezna, S.Pasynkiewcz, A.Pietrzykowski, K.Suwińska and L.Jerzykiewicz ELECTRON TRANSFER ACTIVITY OF NICKELACYCLIC COMPLEXES ANALOGUES OF NICKELOCENE. SYNTHESIS OF (η5-R-CYCLOPENTADIENYL)-{η4-[1-(η5-R-CYCLOPENTADIENYL)]-2,3,4,5-TETRAPHENYL-1- NICKELA-2-CYCLOPENTENYL}NICKEL COMPLEXES (R = H, CH3) AND CRYSTAL STRUCTURES OF THE REDOX COUPLES [(η5-METHYL CYCLOPENTADIENYL) {η4-[1-(η5-METHYLCYCLOPENTADIENYL)]-2,3,4,5- TETRAPHENYL-1-NICKELA-2-CYCLOPENTENYL}NICKEL]0/+ AND [(η5-METHYLCYCLO PENTADIENYL){η5- [1-(η5 – METHYLCYCLOPENTADIENYL)-1- NICKELA FLUORENYL}NICKEL]0/+ Inorg.Chem., 46, 10659 (2007). 3. P. Buchalski, E.Kamińska, K.Piwowar, K.Suwińska, L.Jerzykiewicz, F.Rossi, F.Laschi, F.Fabrizi de Biani and P.Zanello NICKELACYCLIC-COBALTOCENE vs. NICKELACYCLIC-NICKELOCENE. SYNTHESIS, STRUCTURES, ELECTRON TRANSFER ACTIVITY, EPR SPECTROSCOPY, AND THEORETICAL CALCULATIONS Inorg. Chem., 48, 4934 (2009).

(c) Carboranes and Metallacarboranes 1. F.Fabrizi de Biani, M.Fontani, E.Ruiz, P.Zanello, J.M.Russell and R.N.Grimes ELECTRONIC INTERACTIONS IN (η6-ARENE) FERRACARBORANES Organometallics, 21, 4129 (2002). 2. A.R.Kudinov, D.A.Loginov, Z.A.Starikova, P.V.Petrovskii, M.Corsini and P.Zanello IRON- AND RUTHENIUM-CONTAINING TRIPLE-DECKER COMPLEXES WITH A CENTRAL PENTAPHOSPHOLYL LIGAND. X-RAY STRUCTURES OF [(η-C5H5)Fe(µ-η:η-P5)Ru(η-C5Me5)]PF6 AND [(η-C5Me5)Ru(µ-η:η-P5)Ru(η-C5Me5 )]PF6 Eur.J.Inorg.Chem., 3018 (2002). 3. H.Yao, M.Sabat, R.N.Grimes, F.Fabrizi de Biani and P.Zanello METALLACARBORANE-BASED NANOSTRUCTURES: A CARBON-WIRED PLANAR OCTAGON Angew.Chem.Int.Ed., 42, 1002 (2003). 4. H.Yao, M.Sabat, R.N.Grimes, P.Zanello and F.Fabrizi de Biani ALKYNYL-LINKED POLY(COBALTA-CARBORANES). DIRECTED SYNTHESIS, STRUCTURES, AND ELECTROCHEMISTRY OF LINEAR COMPLEXES AND BENZENE-CENTERED PINWHEELS Organometallics, 22, 2581 (2003). 5. H.Yao, R.N.Grimes, M.Corsini and P.Zanello POLYNUCLEAR METALLACARBORANE-HYDROCARBON ASSEMBLIES: METALLACARBORANE DENDRIMERS Organometallics, 22, 4381 (2003). 6. F.Fabrizi de Biani, M.Corsini, P.Zanello, H.Yao, M.E.Bluhm and R.N.Grimes ELECTRONIC PROPERTIES OF MONONUCLEAR, DINUCLEAR, AND POLYNUCLEAR COBALTACARBORANES: ELECTROCHEMICAL AND SPECTROELECTROCHEMICAL STUDIES

J.Am.Chem.Soc., 126, 11360 (2004). 7. I.Meshcheryakov, P.S.Kitaev, K.A.Lissenko, Z.A.Starikova, P.V.Petrovskii, Z.Janoušek, M.Corsini, F.Laschi, P.Zanello and A.R.Kudinov (TETRAMETHYLCYCLOBUTADIENE)COBALT COMPLEXES WITH MONOANIONIC CARBORANE LIGANDS [9-L-7,8-C2B9H10]− (L = SMe2, NMe3 and py) J.Organomet.Chem., 690, 4745 (2005). 8. D.A.Loginov, D.V.Muratov, P.V.Petrovskii, Z.A.Starikova, M.Corsini, F.Laschi, F.de Biani Fabrizi, P.Zanello, and A.R.Kudinov REACTIONS OF THE B-PHENYLBOROLE COMPLEX CpRh(η5-C4H4BPh) WITH METALLOELECTROPHILES [(RING)M]2+ Eur.J.Inorg.Chem., 1737 (2005). 9. M.Corsini, P.Zanello, A.R.Kudinov, V.J.Meshcheryakov, D.S.Perekalin, and K.A.Lissenko ELECTROCHEMICAL BEHAVIOUR OF COBALTA-DICARBOLLIDE SANDWICH COMPLEXES WITH DIFFERENT CAPPING UNITS J.Solid State Electrochem., 9, 750 (2005). 10. R.H.Herber, A.R.Kudinov, P.Zanello, I.Nowik, D.S.Perekalin, V.I.Meshcheryakov, K.A.Lissenko, M.Corsini and S.Fedi SYNTHESIS, STRUCTURE, ELECTROCHEMISTRY, AND METAL-ATOM DYNAMICS OF CYCLOPENTADIENYL FERRACARBORANES Eur.J.Inorg.Chem., 1786 (2006). 11. E.V.Mutseneck, D.S.Perekalin, J.Holub, Z.A.Starikova, P.V.Petrovskii, P.Zanello, M.Corsini, B.Štibr, and A.R.Kudinov (TETRAMETHYLCYCLOBUTADIENE)COBALT COMPLEXES WITH PHOSPHACARBORANE LIGANDS Organometallics, 25, 2419 (2006). 12. M.Corsini, S.Losi, E.Grigiotti, F.Rossi, P.Zanello, A.R.Kudinov, D.A.Loginov, M.M.Vinogradov, Z.A.Starikova AN ELECTROCHEMICAL INVESTIGATION ON THE REDUCTION PATH OF THE ARENE COMPLEXES [CpM(arene)]2+ and [(η-9-SMe2-7,8-C2B9H10)M(arene)]2+ (M = Rh, Ir) J.Solid State Electrochem., 11, 1643 (2007). 13. A.R.Kudinov, R.H.Herber, P.Zanello, D.S.Perekalin, I.V.Glukhov, I.Nowik, M.Corsini, S.Fedi, F.Laschi SYNTHESIS, STRUCTURE, ELECTROCHEMISTRY, AND MÖSSBAUER EFFECT STUDIES OF THE FERRAPHOSPHADICARBOLLIDES [(C5R5)Fe(PC2B8H10)] (R = H, Me) Eur.J.Inorg.Chem., 4190 (2007). 14. W.Siebert, A.R.Kudinov, P.Zanello, M.Yu.Antipin, V.V.Scherban, A.S.Romanov, D.V.Muratov, Z.A.Starikova, M. Corsini SYNTHESIS OF µ-DIBOROLYL TRIPLE-DECKER COMPLEXES BY ELECTROPHILIC STACKING. SIMILAR BONDING PROPERTIES OF ANIONS [CpCo(1,3-C3B2H5)]– AND Cp– TOWARD TRANSITION METALS Organometallics, 28, 2707 (2009). 15. G.Scott, A.McAnaw, D.McKay, A.S.F.Boyd, D.Ellis, G.M.Rosair, S.A.Macgregor, A.J.Welch, F.Laschi, F.Rossi, P.Zanello SUPRAICOSAHEDRAL INDENYL COBALTACARBORANES Dalton Trans., 39, 5286 (2010).

16. A.R.Kudinov, P.Zanello, R.H.Herber, D.A.Loginov, M.M.Vinogradov, A.V.Vologzhanina, Z.A.Starikova, M.Corsini, G.Giorgi, I. Nowik FERRACARBORANE BENZENE COMPLEXES [(η-9-L-7,8-C2B9H10)Fe(η-C6H6)]+ (L = SMe2, NMe3): SYNTHESIS, REACTIVITY, ELECTROCHEMISTRY, MÖSSBAUER EFFECT STUDIES, AND BONDING Organometallics, 29, 2260 (2010). 17. H.Tricas, M.Colon, D.Ellis, S.A.Macgregor, D.McKay, G.M.Rosair, A.J.Welch, I.V.Glukhov, F.Rossi, F.Laschi, and P.Zanello SPECTROSCOPIC, STRUCTURAL, COMPUTATIONAL AND (SPECTRO)ELECTROCHEMICAL STUDIES OF ICOSAHEDRAL CARBORANES BEARING FLUORINATED ARYL GROUPS Dalton Trans., 40, 4200 (2011). 18. D.V.Muratov, A.S.Romanov, T.V.Timofeeva, W.Siebert, M.Corsini, S.Fedi, P.Zanello and A.R.Kudinov MONOCATIONIC µ-DIBOROLYL TRIPLE-DECKER COMPLEXES [CpCo(µ-1,3-C3B2Me5)M(RING)]+: SYNTHESIS, STRUCTURES, AND ELECTROCHEMISTRY Organometallics, 32, 2713 (2013).

(d) Other sandwich ligands 1. E.V.Mutseneck, Z.A.Starikova, K.A.Lyssenko, P.V.Petrovskii, P.Zanello, M.Corsini and A.R.Kudinov SLIPPED Μ-INDENYL TRIPLE-DECKER COMPLEXES CONTAINING (C4Me4)Co AND (C5R5)Ru FRAGMENTS, Eur.J.Inorg.Chem., 4519 (2006). 2. D.S.Perekalin, M.V.Babak, V.V.Novikov, P.V.Petrovskii, K.A.Lyssenko, M.Corsini, P.Zanello and A.R. Kudinov A NEW APPROACH TO THE PHOTOCHEMICALLY CONTROLLED CROWN ETHERS: (TETRAMETHYLCYCLOBUTADIENE) COBALT COMPLEXES WITH BENZO-15-CROWN-5 AND DIBENZO-18-CROWN-6 Organometallics, 27, 3654, (2008). 3. P.Zanello, R.H.Herber, A.R.Kudinov, M.Corsini, F.Fabrizi de Biani, I.Nowik, D.A.Loginov, M.M.Vinogradov, L.S.Shul’pina, I.A.Ivanov and A.V.Vologzhanina SYNTHESIS, STRUCTURE, ELECTROCHEMISTRY, AND MÖSSBAUER EFFECT STUDIES OF (RING)Fe COMPLEXES (RING = Cp, Cp*, AND C6H7). PHOTOCHEMICAL REPLACEMENT OF BENZENE IN THE CYCLOHEXADIENYL COMPLEX [(η5-C6H7)Fe{(η-C6H6)] J.Organomet.Chem., 694, 1161 (2009). 4. D.S.Perekalin, M.V.Babak, V.V.Novikov, K.A.Lyssenko, M.Corsini, P.Zanello and A.R. Kudinov (MESITYLENE)RUTHENIUM π-COMPLEXES WITH BENZO-15-CROWN-5 AND DIBENZO-18-CROWN-6 J.Organomet. Chem., 695, 1200 (2010).

5 METAL COMPLEXES CONTAINING REDOX-ACTIVE LIGANDS

(a) Ferrocenes

1. P.Braunstein, L.Douce, F.Balegroune, D.Grandjean, D.Bayeul, Y.Dusausoy and P.Zanello

COMPLEXES WITH FUNCTIONAL PHOSPHINES. 20. SYNTHESIS AND ELECTROCHEMISTRY OF RHENIUM COMPLEXES WITH KETOPHOSPHINE AND PHOSPHINO- ENOLATE LIGANDS. CRYSTAL STRUCTURES OF fac-[ReBr(CO)3{Ph2PCH2C(O)(η5-C5H4)-Fe(η5-C5H4)}] AND [Me4N][fac-ReClBr(CO)2{Ph2PCH ... C( ... O)Ph] New J.Chem., 16, 925 (1992). 2. R.Della Pergola, C.Bandini, F.Demartin, E.Diana, L.Garlaschelli, P.L.Stanghellini and P.Zanello CHARACTERIZATION, REDOX PROPERTIES AND STRUCTURES OF THE IRON NITRIDOCARBONYL CLUSTERS [Fe4N(CO)11{C5H4FeC5H5)2}]−, [Fe6N(CO)15]3− AND [Fe6H(N)(CO)15]2− J.Chem.Soc., Dalton Trans., 747 (1996). 3. K.Jacob, F.Voigt, K.Merzweiler, C.Wagner, P.Zanello, M.Fontani and C.Pietzsch HETEROBIMETALLISCHE 2-(DIMETHYLAMINOMETHYL)FERROCENYL-DERIVATE DES EINWERTIGEN GOLDES J.Organomet.Chem., 552, 265 (1998). 4. P.Zanello, F.Fabrizi de Biani, C.Glidewell, J.Koenig and S.J.Marsh ISOMERISM AND REDOX PROPERTIES OF 1-FERROCENYL-1,3-BUTANEDIONATE COMPLEXES Polyhedron, 17, 1795 (1998). 5. K.Jacob, P.Zanello, F.Voigt and M.Fontani ON HETEROMETALLIC FERROCENYL COMPOUNDS OF GOLD AND PLATINUM Monatsch.Chem., 129, 1213 (1998). 6. U.Siemeling, U.Vorfeld, B.Neumann, H.-G.Stammler, P.Zanello and F.Fabrizi de Biani TERPYRIDINES FUNCTIONALISED WITH FERROCENYL GROUPS OF DIFFERENT REDOX POTENTIAL Eur.J.Inorg.Chem., 1 (1999). 7. M.Herberhold, W.Milius, U.Steffl, K.Vitzithum, B.Wrackmeyer, R.H.Herber, M.Fontani and P.Zanello 1,1'-BIS(STANNYL)- AND 1,1'-BIS(CHOLOSTANNYL)FERROCENES STUDIED BY MULTINUCLEAR MAGNETIC RESONANCE, TEMPERATURE-DEPENDENT 57Fe- AND 119Sn-MÖSSBAUER SPECTROSCOPY, AND ELECTROCHEMISTRY Eur.J.Inorg.Chem., 145 (1999). 8. N.J.Long, J.Martin, G.Opromolla, A.J.P.White, D.J.Williams and P.Zanello SYNTHESIS AND CHARACTERISATION OF 1-(DIPHENYLPHOSPHINO)-1'-(METHYLSULFANYL)FERROCENE AND A SERIES OF METAL (CuI, AgI)-FERROCENYLENE COMPLEXES J.Chem.Soc., Dalton Trans., 1981 (1999). 9. R.Altmann, O.Gausset, D.Horn, K.Jurkshat, M.Schürmann, M.Fontani and P.Zanello NOVEL SILICON-AND TIN-CONTAINING FERROCENOPHANES AND RELATED COMPOUNDS AS LEWIS ACIDS Organometallics, 19, 430 (2000). 10. B.Bildstein, M.Malaun, H.Kopacka, M.Fontani and P.Zanello SYNTHESIS AND ELECTROCHEMISTRY OF FERROCENYLDIAZABUTADIENE METAL COMPLEXES (Fc-DAB)M(CO)4 [M = Cr, Mo, W] Inorg.Chim.Acta, 300-302, 16 (2000). 11. K.Jacob, N.Seidel, F.Voigt, A.Fisher, C.Pietzsch, J.Holecek, A.Lycka, M.Fontani, E.Grigiotti and P.Zanello HETEROBIMETALLORGANISCHE 1,2-(N,N-DIMETHYLAMINOMETHYL)-FERROCENYL-DERIVATE DES VIER- UND ZWEIWERTIGEN ZINNS: SYNTHESEN, CHARAKTERISTIKA UND KRISTALL STRUKTUREN J.Prakt.Chem., 342, 574 (2000).

12. N.J.Long, A.J.Martin, A.J.P.White, D.J.Williams, M.Fontani, F.Laschi and P.Zanello SYNTHESIS AND CHARACTERISATION OF UNSYMMETRICAL METAL (RuII, OsII) AND FERROCENYL COMPLEXES OF 1,3,5-TRIETHYNYLBENZENE J.Chem.Soc., Dalton Trans., 3387 (2000). 13. F.Voigt, K.Jacob, N.Seidel, A.Fisher, C.Pietzsch and P.Zanello HETEROBIMETALLISCHE KOMPLEXE DES BORS UND ALUMINIUMS MIT DEM 2-(DIMETHYLAMINOMETHYL)-FERROCENYL-LIGANDEN: SYNTHESEN, CHARAKTERISTIKA UND KRISTALLSTRUKTUREN J.Prakt.Chem., 342, 666 (2000). 14. N.Seidel, K.Jacob, A.Fisher, C.Pietzsch, P.Zanello and M.Fontani STRUCTURAL STUDIES AND SOLUTION DYNAMICS OF COMPLEXES OF MAGNESIUM WITH THE N,N-DIMETHYLAMINOMETHYL FERROCENYL LIGAND Eur.J.Inorg.Chem., 145 (2001). 15. N.Seidel, K.Jacob, P.Zanello and M.Fontani STUDY ON STRUCTURAL PROPERTIES AND SOLUTION DYNAMICS OF ZINC COMPLEXES WITH THE N,N-DIMETHYLAMINOMETHYLFERROCENYL LIGAND J.Organomet.Chem., 620, 243 (2001). 16. I.R.Butler, U.Griesbach, P.Zanello, M.Fontani, D.Hibbs, M.Hursthouse, K.Malik DIFERROCENYLTRIPHOSPHINES 1. FIVE-COORDINATE RUTHENIUM COMPLEXES J.Organomet.Chem., 565, 243 (1998). 17. N.Seidel, K.Jacob, A.K.Fisher, K.Merzweiler, C.Wagner, M.Fontani and P.Zanello [2-(N,N-DYMETHYLAMINOMETHYL)FERROCENYL] AS A LIGAND TOWARDS MERCURY J.Organomet.Chem., 630, 149 (2001). 18. K.Bushell, C.Gialou, C.H.Goh, N.J.Long, J.Martin, A.J.P.White, C.K.Williams, D.J.Williams, M.Fontani and P.Zanello SYNTHESIS AND CHARACTERISATION OF NOVEL MULTIDENTATE FERROCENE LIGANDS AND THEIR Re(I) AND Pt(II) COMPLEXES J.Organomet.Chem., 637-639, 418 (2001). 19. I.R.Butler, S.J.Coles, M.Fontani, M.B.Hursthouse, E.Lewis, K.L.Malik, M.Meunier and P.Zanello DIFERROCENYLTRIPHOSPHINES. 2. REVERSIBLE PHOSPHINE DELIGATION IN THE CHEMISTRY OF DIFERROCENYLTRIPHOSPHINE Ru(II) DICHLORIDE COMPLEXES WITH NITRILES AND PYRIDINES: TOWARDS A pH-SWITCHABLE CATALYST ? J.Organomet.Chem., 637-639, 538 (2001). 20. F.Fabrizi de Biani, C.Graiff, G.Opromolla, G.Predieri, A.Tiripicchio and P.Zanello A RE-EXAMINATION OF THE REACTION BETWEEN 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE (dppf) DISELENIDE AND [Ru3(CO)12]. ELECTROCHEMICAL BEHAVIOUR OF THE ISOMERIC NIDO-CLUSTERS [Ru3(µ3-Se)2(dppf)(CO)7] AND [Ru3(µ3-Se)2(µ-dppf)(CO)7] AND CRYSTAL STRUCTURE OF [Ru3Se{µ-P(Ph)C5H4FeC5H4PPh2}(µ-OCPh)(CO)6] J.Organomet.Chem., 637-639, 586 (2001). 21. S.Guo, F.Peters, F.Fabrizi de Biani, J.W.Bats, E.Herdtweck, P.Zanello and M.Wagner ELECTRONIC COMMUNICATION IN OLIGOMETALLIC COMPLEXES WITH FERROCENE-BASED TRIS(1-PYRAZOLYL)BORATE LIGANDS Inorg.Chem., 40, 4928 (2001).

22. V.C.Gibson, N.J.Long, A.J.P.White, C.K.Williams, D.J.Williams, M.Fontani and P.Zanello SYNTHESIS, CHARACTERISATION AND CATALYTIC ACTIVITY OF METAL COMPLEXES OF NEUTRAL, UNSYMMETRICAL P/S FERROCENEDIYL LIGANDS J.Chem.Soc., Dalton Trans., 3280 (2002). 23. T.Avilés, A.Dinis, J.O.Gonçalves, V.Félix, M.J.Calhorda, Â.Prazeres, M.G.B.Drew, H.Alves, R.T.Henriques, V. da Gama, P.Zanello and M.Fontani SYNTHESIS, X-RAY STRUCTURES, ELECTROCHEMISTRY, MAGNETIC PROPERTIES, AND THEORETICAL STUDIES OF THE NOVEL MONOMERIC [CoI2(dppfO2)] AND POLYMERIC CHAIN [CoI2(dppfO2)] J.Chem.Soc., Dalton Trans., 4595 (2002). 24. U.Siemeling, J.Vor der Brüggen, U.Vorfeld, B.Neumann, A.Stammler, H.-G.Stammler, A.Brockinke, R.Plessow, P.Zanello, F.Laschi, F.Fabrizi de Biani, M.Fontani, S.Steenken, M.Stapper and G.Gurzadyan FERROCENYL-FUNCTIONALISED TERPYRIDINES AND THEIR TRANSITION-METAL COMPLEXES: SYNTHESES, STRUCTURES AND SPECTROSCOPIC AND ELECTROCHEMICAL PROPERTIES Chem. Eur.J., 9, 2819 (2003). 25. V.C.Gibson, N.J.Long, C.K.Williams, M.Fontani and P.Zanello NEW UNSYMMETRICAL THIOETHER- AND THIOLATE-SUBSTITUTED FERROCENEDIYL LIGANDS AND THEIR METAL COMPLEXES J.Chem.Soc., Dalton Trans., 3599 (2003). 26. K.Jacob, P.Zanello, M.Fontani, C.Pietzsch, K.Bohmhammer and V.Lorenz THERMOGRAVIMETRIC, CYCLOVOLTAMMETRIC, AND MÖSSBAUER SPECTROSCOPIC INVESTIGATIONS ON HETERO BIMETALLIC ORGANO DERIVATIVES OF SILICON AND GERMANIUM WITH THE 2-(DIMETHYLAMINOMETHYL)-FERROCENYL LIGAND (η5-C5H5)Fe[η5-C5H3(CH2NMe2)], FcN Z.Anorg.Allg.Chem., 629, 2004 (2003). 27. V.C.Gibson, N.J.Long, R.J.Long; A.J.P.White, C.K.Williams, D.J.Williams, E.Grigiotti and P.Zanello SYNTHESIS, CHARACTERIZATION, AND METAL COMPLEXATION OF UNSYMMETRICAL 1,1'-BIS(ORGANYLTHIOLATO)FERROCENES Organometallics, 23, 95 (2004). 28. A.Albinati, F.Fabrizi de Biani, P.Leoni, L.Marchetti, M.Pasquali, S.Rizzato and P.Zanello REDOX CONTROL OF LIGHT-INDUCED PLATINUM-CLUSTER-TO-IRON CHARGE TRANSFER IN A BIS(FERROCENYLETHYNYL)-SUBSTITUTED HEXANUCLEAR PLATINUM DERIVATIVE Angew.Chem.Int.Ed., 44, 5701 (2005). 29. M.Henn, M.Schürmann, B.Mahieu, P.Zanello, A.Cinquantini and K.Jurkschat A FERROCENYL-BRIDGED INTRAMOLECULARLY COORDINATED BIS(DIORGANOSTANNYLENE): SYNTHESIS, MOLECULAR STRUCTURE AND REACTIVITY OF [4-t-Bu-2,6-{P(O)(O-i-Pr)2C6H2Sn}C5H4]2Fe J.Organomet. Chem., 691, 1560 (2006). 30. P.N.Martinho, S.Quintal, P.J.Costa, S.Losi, V.Félix, M.C.Gimeno, A.Laguna, M.G.B.Drew, P.Zanello and M.J.Calhorda NEW POLYNUCLEAR Mo-Fe COMPLEXES WITH FERROCENYLAMIDOBENZIMIDAZOLE LIGANDS Eur.J.Inorg.Chem., 4096 (2006). 31. R.Kalio, P.Lönnecke, A.Cinquantini, P.Zanello and E.Hey-Hawkins

CYCLOPENTADIENYL TANTALUM(V) COMPLEXES WITH PRIMARY AND SECONDARY FERROCENYLPHOSPHINE LIGANDS Z.Anorg.Allg.Chem., 633, 2470 (2007). 32. S.Guo, R.Hauptmann, S.Losi, P.Zanello and J.J.Schneider 1,1’-FERROCENYLDIOL AS CHELATING LIGAND FOR COBALT IN FIVEFOLD AND SIXFOLD COORDINATION GEOMETRY: SYNTHESIS, ELECTROCHEMISTRY AND X-RAY CRYSTAL STRUCTURE OF [{((1,1’O2(η5-C5H5)2Fe)3}Co(OEt2){(η5-Me5C5)Co}2] AND [{((1,1’O2(η5-C5H5)2Fe)3}Co{(η5-EtMe4C5)Co}2] J.Organomet. Chem., 694, 1022 (2009). 33. S. Quintal, S. Fedi, J. Barbetti, P. Pinto, V. Félix, M.G.B. Drew, P. Zanello and M.J. Calhorda SYNTHESIS AND PROPERTIES OF NEW Mo(II) COMPLEXES WITH N-HETEROCYCLIC AND FERROCENYL LIGANDS J. Organomet. Chem., 696, 2142 (2011). (b) Fullerenes and carbon curved surfaces 1. P.Zanello, F.Laschi, M.Fontani, C.Mealli, A.Ienco, K.Tang, X.Jin and L.Li REDOX BEHAVIOR OF THE MOLYBDENUM AND TUNGSTEN METALLAFULLERENES M(η2-C60)(CO)2(phen)(dbm) (phen = 1,10-phenanthroline; dbm = dibutyl maleate): (SPECTRO)ELECTROCHEMISTRY AND THEORETICAL CONSIDERATIONS J.Chem.Soc., Dalton Trans., 965 (1999). 2. P.Zanello, F.Laschi, M.Fontani, L.-C.Song and Y.-H.Zhu REDOX BEHAVIOUR OF THE MOLYBDENUM AND TUNGSTEN METALLAFULLERENES Mo(CO)3(dppe)(η2-C60) (dppe = bis-(1,2-diphenylphosphino)ethane) AND W(CO)3(dppb)(η2-C60) (dppb = bis-(1,2-diphenylphosphino)benzene) J.Organomet.Chem., 593-594, 7 (2000). 4. P.Zanello, F.Laschi, A.Cinquantini, M.Fontani, K.Tang, X.Jin and L.Li THE REDOX BEHAVIOUR OF THE FAMILY (C60)[Mo(CO)2(phen)(dbm)]n (n = 1-3). A COMPARISON WITH THE ANALOG (η2-C70)[Mo(CO)2(phen)(dbm)] (phen = 1,10-Phenanthroline; dbm = Dibutyl Maleate) Eur.J.Inorg.Chem., 1345 (2000). 5. L.-C.Song, P.-C.Liu, Q.-M.Hu, Y.-H.Zhu, P.Zanello and M.Fontani SYNTHESIS OF TWO PENTAARYLATED [60]FULLERENE DERIVATIVES Ar5C60H (Ar = p-MeC6H4, m-MeC6H4) AND THEIR NOVEL ELECTROCHEMICAL PROPERTIES Chin.J.Chem., 18, 395 (2000). 6. L.-C.Song, J.-T.Liu, Q.-M.Hu, G.-F.Wang, P.Zanello and M.Fontani SYNTHESIS, CHARACTERIZATION, AND ELECTROCHEMICAL PROPERTIES OF ORGANOTRANSITION METAL FULLERENE DERIVATIVES CONTAINING dppf LIGANDS. CRYSTAL STRUCTURES OF fac-Mo(CO)3(dppf)(CH3CN), W(CO)4(dppf), AND mer-W(CO)3(dppf)(η2-C60) Organometallics, 19, 5342 (2000). 7. L.-C.Song, P.-C.Liu, J.-T.Liu, F.-H.Su, G.-F.Wang, Q.-M.Hu, P.Zanello, F.Laschi and M.Fontani SYNTHESIS, CHARACTERISATION AND ELECTROCHEMICAL PROPERTIES OF OPTICALLY ACTIVE [60]FULLERENE ORGANOTRANSITION METAL COMPLEXES mer-[η2-C60)M(CO)3{(-)-DIOP}] (M = Mo, W), mer-[(η2-C60)M(CO)3{(+)-DIOP}] (M = Mo, W) and [(η2-C60)M{(-)-DIOP}] (M = Pd, Pt) – CRYSTAL STRUCTURE OF [(η2-C60)Pt{(-)-DIOP}] Eur.J.Inorg.Chem., 3201 (2003).

8. P.Zanello, F.Fabrizi de Biani, A.Cinquantini and E.Grigiotti ELECTROCHEMISTRY OF THE METALLO-BISFULLERENE [Mo(η2-C60)2(CO)2(dbc-bipy)] (dbc-bipy = 4,4’-di(butylcarboxyl)-2,2’-bipyridine), C.R.Chimie, 8, 1655 (2005). 9. L.-C.Song, F.-H.Su, Q.-M.Hu, E.Grigiotti and P.Zanello SYNTHESIS, CHARACTERIZATION, AND ELECTROCHEMICAL PROPERTIES OF NOVEL TRANSITION METAL- FULLERENE COMPLEXES CONTAINING DI- AND TETRAPHOSPHANE LIGANDS Eur.J.Inorg.Chem., 422 (2006). 10. R.J.Angelici, B.Zhou, S.Fedi, F.Laschi and P.Zanello ELECTROCHEMICAL AND EPR STUDIES OF THE CORANNULENE RUTHENIUM(II) SANDWICH COMPLEX [η6-C6Me6)Ru(η6-C20H10)](SbF6)2 Inorg.Chem., 46, 10901 (2007). 11. V.I.Sokolov, N.V.Abramova, E.V.Mutseneck, A.S.Romanov, A.R.Kudinov, P.Zanello, J.Barbetti and S.M.Peregudova SYNTHESIS AND ELECTROCHEMISTRY OF 2-POLYMETHYLMETALLOCENYL-SUBSTITUTED PYRROLIDINO[60]FULLERENE Mendeleev Commun., 17, 202 (2007). 12. P.Zanello, S.Fedi, F.Fabrizi de Biani, G.Giorgi, T.Amaya, H.Sakane and T.Hirao THE ELECTROCHEMICAL INSPECTION OF THE REDOX ACTIVITY OF SUMANENE AND ITS CONCAVE CpFe COMPLEX Dalton Trans., 9192 (2009). 13. C.Dubceac, A.V. Zabula, A.S. Filatova, F.Rossi, P.Zanello and M.A. Petrukhina BOWL-SHAPED CARBOCATIONS: EASY TO PRODUCE, HARD TO REDUCE J. Phys. Org. Chem., 25, 553 (2012).

(c) Porphyrins

1. E.Stultz, J.K.M.Sanders, M.Montalti, L.Prodi, N.Zaccheroni, F.Fabrizi de Biani, E.Grigiotti and P.Zanello PHOSPHINE AND PHOSPHONITE COMPLEXES OF A Ru(II) PORPHYRIN. 2. PHOTOPHYSICAL AND ELECTROCHEMICAL STUDIES Inorg.Chem., 41, 5269 (2002). 2. F.Fabrizi de Biani, E.Grigiotti, F.Laschi, P.Zanello, A.Juris, L.Prodi, K.S.Chichak and N.R. Branda SUPRAMOLECULAR METAL-POLYPYRIDYL AND Ru(II) PORPHYRIN COMPLEXES: PHOTOPHYSICAL, ELECTRON PARAMAGNETIC RESONANCE, AND ELECTROCHEMICAL STUDIES Inorg. Chem., 47, 5425 (2008). 3. M.P. Donzello, E. Viola, L.A. Tomachinskaya, C. Ercolani, M. Corsini, P.Zanello and P.A.Stuzhin SYNTHESIS AND PROPERTIES OF STYRYL-SUBSTITUED TETRAPYRAZINOPORPHYRAZINES [St8PyzPzM] M = 2NaI, MgII(H2O) AND ZnII J. Porphyrins Phthalocyanines, 14, 793 (2010).

(d) Dithiolenes

1. M.C.Aragoni, M.Arca, C.Denotti, F.A.Devillanova, E.Grigiotti, F.Isaia, F.Laschi, V.Lippolis, L.Pala, A.M.Z.Slawin, P.Zanello and D.Woollins A FACILE SYNTHESIS OF A PUSH-PULL MIXED-LIGAND Pd-DITHIOLENE COMPLEX CONTAINING Et2timdt LIGAND (Et2timdt = MONOREDUCED DIETHYL IMIDAZOLIDINE-2,4,5-TRITHIONE) Eur.J.Inorg.Chem., 1291 (2003). 2. E.Grigiotti, F.Laschi, P.Zanello, M.Arca, C.Denotti and F.A.Devillanova METAL-DITHIOLENES OF DISUBSTITUTED IMIDAZOLIDINE-2,4,5-TRITHIONE MONOANION. AN ELECTROCHEMICAL AND EPR STUDY Portugaliae Electrochimica Acta, 22, 25 (2004). 3. M.C.Aragoni, M.Arca, M.Caironi, C.Denotti, F.A.Devillanova, E.Grigiotti, F.Isaia, F.Laschi, V.Lippolis, D.Natali, L.Pala, M.Sampietro and P.Zanello MONOREDUCED [M(R,R’timdt)2]− DITHIOLENES (M = Ni, Pd, Pt; R,R’timdt = DISUBSTITUTED IMIDAZOLINE-2,4,5-TRITHIONE): SOLID STATE PHOTOCONDUCTING PROPERTIES IN THE THIRD OPTICAL FIBER WINDOW Chem.Commun., 1882 (2004). (e) Dioxolenes 1. G.Margraf, T.Kretz, F.Fabrizi de Biani, F.Laschi, S.Losi, P.Zanello, J.W.Bats, B.Wolf, K.Remović-Langer, M.Lang, A.Prokofiev, W.Assmus, H.-W.Lerner and M.Wagner MONO-, DI-, AND OLIGONUCLEAR COMPLEXES OF CuII IONS AND p-HYDROQUINONE LIGANDS: SYNTHESES, ELECTROCHEMICAL PROPERTIES, AND MAGNETIC BEHAVIOR Inorg.Chem., 45, 1277 (2006). 2. C.Bianchini, D.Masi, C.Mealli, A.Meli, G.Martini, F.Laschi and P.Zanello COMPREHENSIVE EXPERIMENTAL AND INTERPRETATIONAL STUDY OF THE COMPLEX FORMATION AND TRANSFORMATIONS INVOLVING o-QUINOID MOLECULES AND AN L3M-TYPE METAL FRAGMENT (M = COBALT) Inorg.Chem., 26, 3683 (1987). 3. C.Bianchini, P.Frediani, F.Laschi, A.Meli, F.Vizza and P.Zanello A NOVEL OXYGEN-CARRYING AND ACTIVATING SYSTEM OF RHODIUM(III). OXIDATION AND OXYGENATION REACTIONS OF 3,5-DI-tert-BUTYLCATECHOL CATALYZED BY A RHODIUM(III) CATECHOLATE THROUGH ITS (η1-SUPEROXO)(η2-SEMIQUINONATO)RHODIUM(III) COMPLEX Inorg.Chem., 29, 3402 (1990). 4. P.Barbaro, C.Bianchini, K.Linn, C.Mealli, A.Meli, F.Vizza, F.Laschi and P.Zanello DIOXYGEN UPTAKE AND TRANSFER BY Co(III), Rh(III) AND Ir(III) CATECHOLATE COMPLEXES Inorg.Chim.Acta, 198-200, 31 (1992). 5. H.-W.Lerner, G.Margraf, T.Kretz, O.Schiemann, J.W.Bats, G.Dürner, F.Fabrizi de Biani, P.Zanello, M.Bolte and M.Wagner REDOX BEHAVIOUR OF PYRAZOLYL-SUBSTITUTED 1,4-DIHYDROXYARENES: FORMATION OF THE CORRESPONDING SEMIQUINONES, QUINHYDRONES AND QUINONES, Z.Naturforsch., 61b, 252 (2006).

6 PHARMACO-BIO-METALLICS

1. M.Cospito, P.Zanello and G.Raspi DETERMINATION OF α-TOCOPHEROL BY VOLUMETRIC OR COULOMETRIC TITRATION WITH VANADIUM(V) Z.Anal.Chem., 271, 200 (1974). 2. A.Cinquantini, R.Cini and P.Zanello ELECTROANALYTICAL INVESTIGATION ON THE INTERACTION BETWEEN 6-MERCAPTOPURINE AND ZINC(II), LEAD(II) AND CADMIUM(II) IONS IN NONAQUEOUS SOLVENTS J.Inorg.Biochem., 12, 157 (1980). 3. P.Zanello, C.Bartocci, M.Maldotti and O.Traverso SELF-REDUCTION OF CHLOROHEMIN IN PYRIDINE: COMPARISON WITH THE PHOTOREDUCTION PROCESS Polyhedron, 2, 791 (1983). 4. P.Zanello, C.Bartocci, M.Maldotti and O.Traverso SELF-REDUCTION OF CHLOROHEMIN IN PYRIDINE: COMPARISON WITH THE PHOTOREDUCTION PROCESS Polyhedron, 2, 791 (1983). 5. C.Bianchini, A.Meli, P.Dapporto, A.Tofanari and P.Zanello CHEMICAL AND ELECTROCHEMICAL OXIDATION OF THE PHOSPHONIODICHALCOGENOFORMATE COMPLEXES (triphos)RhCl(X2CPEt3) (triphos= MeC(CH2PPh2)3 ; X=S,Se). SYNTHESIS OF METAL DICHALCOGENOCARBONATES FROM O2 AND PHOSPHONIUM-BETAINE-LIKE COMPLEXES. X-RAY STRUCTURE OF [(triphos)Rh(S2CH(PEt3))](BPh4)2 Inorg.Chem., 26, 3677 (1987). 6. L.Casella, M.Gullotti, A.Pintar, F.Pinciroli, R.Viganò and P.Zanello BLUE COPPER MODELS. SPECTROSCOPIC AND ELECTROCHEMICAL STUDIES OF COPPER(II) COMPLEXES WITH NEW LIGAND SYSTEM CONTAINING SULPHUR AND NITROGEN DONOR ATOMS J.Chem.Soc., Dalton Trans., 1161 (1989). 7. L.Casella, M.Gullotti, E.Suardi, M.Sisti, R.Pagliarin and P.Zanello BLUE COPPER MODELS. SYNTHESIS AND CHARACTERIZATION OF COPPER(II) ENETHIOLATE COMPLEXES DERIVED FROM (1R)-3-HYDROXY-METHYLENE-BORNANE-2-THIONE AND 2-AMINOTHIA-ALKYL-1-METHYL-BENZIMIDAZOLES (DONOR SET N2SS*) OR DIAMINES (DONOR SET N2S2) J.Chem.Soc., Dalton Trans., 2843 (1990). 8. A.C.van Steenbergen, E.Bowman, R.A.G.de Graaff, W.L.Driessen, J.Reedijk and P.Zanello COPPER CO-ORDINATION COMPOUNDS OF A CHELATING IMIDAZOLE-THIOETHER LIGAND. THE MOLECULAR STRUCTURE OF [1,3-BIS(5-METHYL-4-IMIDAZOLYL)-2 THIAPROPANE] BIS(NITRATO) COPPER(II) AND BIS[1,3-BIS(5-METHYL-4-IMIDAZOLYL)-2-THIAPROPANE]COPPER(II) BIS(TETRAFLUORO- BORATE)-ETHANOL(1/2) J.Chem.Soc., Dalton Trans., 3175 (1990). 9. M.Zoeteman, E.Bouwman, R.A.G.de Graaff, W.L.Driessen, J.Reedijk and P.Zanello SYNTHESIS AND SPECTROSCOPY OF COPPER(II) COMPOUNDS OF A CHELATING IMIDAZOLE-THIOETHER LIGAND. MOLECULAR STRUCTURES OF (1,5-BIS(4-IMIDAZOLYL)-3-THIAPENTANE)DICHLOROCOPPER(II),

(1,5-BIS(4-IMIDAZOLYL)-3-THIAPENTANE)BIS(THIOCYANATO-N)COPPER(II), AND BIS[(µ-CHLORO)(1,5-BIS (4-IMIDAZOLYL)-3-THIA-PENTANE)COPPER(II)]BIS(PERCHLORATE) Inorg.Chem., 29, 3487 (1990). 10. D.Osella, E.Stein, G.Jauen and P.Zanello TRANSITION METAL COMPLEXES AS ELECTROCHEMICAL MARKERS FOR STEROIDS J.Organomet.Chem., 401, 37 (1991). 11. P.Barbaro, C.Bianchini, K.Linn, C.Mealli, A.Meli, F.Vizza, F.Laschi and P.Zanello DIOXYGEN UPTAKE AND TRANSFER BY Co(III), Rh(III) AND Ir(III) CATECHOLATE COMPLEXES Inorg.Chim.Acta, 198-200, 31 (1992). 12. L.Casella, O.Carugo, M.Gullotti, S.Garofani and P.Zanello HEMOCYANIN AND TYROSINASE MODELS. SYNTHESIS, AZIDE BINDING AND ELECTROCHEMISTRY OF DINUCLEAR COPPER(II) COMPLEXES WITH POLYBENZIMIDAZOLE LIGANDS MODELING THE MET FORM OF THE PROTEINS Inorg.Chem., 32, 2056 (1993). 13. E.Monzani, G.Battaini, A.Perotti, L.Casella, M.Gullotti, L.Santagostini, G.Nardin, L.Randaccio, S.Geremia, P.Zanello and G.Opromolla MECHANISTIC, STRUCTURAL, AND SPECTROSCOPIC STUDIES ON THE CATECHOLASE ACTIVITY OF A DINUCLEAR COPPER COMPLEX BY DIOXYGEN Inorg.Chem., 38, 5359 (1999). 14. E.Monzani, G.J.Anthony, A.Koolhaas, A.Spandre, E.Leggieri, L.Casella, M.Gullotti, G.Nardin, L.Randaccio, M.Fontani, P.Zanello and J.Reedijk BINDING OF NITRITE AND ITS REDUCTIVE ACTIVATION TO NITRIC OXIDE AT BIOMIMETIC COPPER CENTERS J.Biol.Inorg.Chem., 251 (2000). 15. D.Osella, M.Ferrali, P.Zanello, F.Laschi, M.Fontani, C.Nervi and G.Cavigliolo ON THE MECHANISM OF THE ANTITUMOR ACTIVITY OF FERROCENIUM DERIVATIVES Inorg.Chim.Acta, 306, 42 (2000). 16. L.Messori, F.Abbate, G.Marcon, P.Orioli, M.Fontani, E.Mini, T.Mazzei, S.Carotti, T.O'Donnell and P.Zanello GOLD(III) COMPLEXES AS POTENTIAL ANTITUMOR AGENTS: SOLUTION CHEMISTRY AND CYTOTOXIC PROPERTIES OF SOME SELECTED GOLD(III) COMPOUNDS J.Med.Chem., 43, 3541 (2000). 17. M.Ferrali, S.Bambagioni, A.Ceccanti, D.Donati, G.Giorgi, M.Fontani, F.Laschi, P.Zanello, M.Casolaro and A.Pietrangelo DESIGN, SYNTHESIS, AND PHYSICOCHEMICAL CHARACTERIZATION OF A NEW IRON CHELATOR OF THE FAMILY OF HYDROXYCHROMENES J.Med.Chem., 45, 5776 (2002). 18. L.Messori, G.Marcon, P.Orioli, M.Fontani, P.Zanello, A.Bergamo, G.Sava and P.Mura MOLECULAR STRUCTURE, SOLUTION CHEMISTRY AND BIOLOGICAL PROPERTIES OF THE NOVEL [ImH][trans-IrCl4(Im)(DMSO)], (I), AND THE ORANGE FORM [(DMSO)2H] [trans-IrCl4(DMSO)2], (II) J.Inorg.Biochem., 95, 37 (2003).

19. R.Cini, G.Tamasi, S.Defazio, M.Corsini, P.Zanello, L.Messori, G.Marcon, F.Piccioli and P.Orioli STUDY OF RUTHENIUM(II) COMPLEXES WITH ANTICANCER DRUGS AS LIGANDS. DESIGN OF METAL- BASED PHOTOTHERAPEUTIC AGENTS Inorg. Chem., 42, 8038 (2003). 20. P.Mura, M.Camalli, L.Messori, F.Piccioli, P.Zanello and M.Corsini SYNTHESIS, STRUCTURAL CHARACTERIZATION, SOLUTION CHEMISTRY, AND PRELIMINARY BIOLOGICAL STUDIES OF THE RUTHENIUM(III) COMPLEXES [TzH][trans-RuCl4(Tz)2] AND [TzH][trans-RuCl4(DMSO)(Tz)]·(DMSO), THE THIAZOLE ANALOGUES OF ANTITUMOR ICR AND NAMI A Inorg.Chem., 43, 3863 (2004). 21. M.Ravera, S.Baracco, C.Cassino, P.Zanello and D.Osella APPRAISAL OF THE REDOX BEHAVIOUR OF THE ANTIMETASTATIC RUTHENIUM(II) COMPLEX [ImH][RuCl4(DMSO)(Im)], NAMI-A Dalton Trans., 2347 (2004). 22. L.Ronconi, C.Marzano, P.Zanello, M.Corsini, G.Miolo, A.Trevisan and D.Fregona GOLD(III) DITHIOCARBAMATE DERIVATIVES FOR THE TREATMENT OF CANCER: SOLUTION CHEMISTRY, DNA BINDING, AND HEMOLYTIC PROPERTIES J.Med.Chem., 49, 1648 (2006). 23. A.B.Olejniczak, M.Corsini, S.Fedi, P.Zanello and Z.J.Lesnikowsky NUCLEOSIDE-METALLACARBORANE CONJUGATES FOR MULTIPOTENTIAL ELECTROCHEMICAL CODING OF DNA Electrochem. Commun., 9, 1007 (2007). 24. P.Mura, M.Camalli, A.Bindoli, F.Sorrentino, A.Casini, C,Gabbiani, M.Corsini, P. Zanello, M.P.Rigobello and L.Messori ACTIVITY OF RAT CYTOSOLIC THIOREDOXIN REDUCTASE IS STRONGLY DECREASED BY trans-[BIS(2-AMINO-5-METHYLTHIAZOLE)TETRACHLORO-RUTHENATE(III)]: FIRST REPORT OF RELEVANT THIOREDOXIN REDUCTASE INHIBITION FOR A RUTHENIUM COMPOUND J.Med.Chem., 50, 5871 (2007). 25. C.Gabbiani, A.Casini, L.Messori, A.Guerri, M.A.Cinellu, G.Minghetti, M.Corsini, C.Rosani, P.Zanello and M.Arca STRUCTURAL CHARACTERIZATION. SOLUTION STUDIES, AND DFT CALCULATIONS ON A SERIES OF BINUCLEAR GOLD(III) OXO COMPLEXES: RELATIONSHIPS TO BIOLOGICAL PROPERTIES Inorg.Chem., 47, 2368 (2008). 26. L.Giovagnini, S.Sitran, M.Montopoli, L.Caparrotta, M.Corsini, C.Rosani, P.Zanello, Q.Ping Dou and D.Fregona CHEMICAL AND BIOLOGICAL PROFILES OF NOVEL COPPER(II) COMPLEXES CONTAINING σ-DONOR LIGANDS FOR THE TREATMENT OF CANCER Inorg.Chem., 47, 6336 (2008). 27. L.Giovagnini, S.Sitran, I.Castagliuolo, P.Brun, M.Corsini, P.Zanello, A.Zoleo, A.Maniero, B.Biondi and D.Fregona Ru(III) BASED COMPOUNDS WITH SULFUR DONOR LIGANDS: SYNTHESIS, CHARACTERIZATION, ELECTROCHEMICAL BEHAVIOUR AND ANTICANCER ACTIVITY

Dalton Trans., 6699 (2008). 28. G. Tamasi, M. Corsini, P. Zanello and R. Cini RAME E FANS CONTRO LO STRESS OSSIDATIVO, Sapere, 5, 18 (2012).

7 MISCELLANEOUS SUBJECTS

1. P.Zanello and G.Raspi VOLTAMMETRIC DETERMINATION OF URANIUM(VI) BY URANYL-PEROXO DICARBONATE OXIDATION Anal.Chim.Acta, 61, 177 (1972). 2. P.Zanello and M.Cospito VOLTAMMETRIC DETERMINATION OF URANIUM(IV) WITH A PLATINIZED PLATINUM MICROELECTRODE WITH PERIODICAL RENEWAL OF THE DIFFUSION LAYER J.Electroanal.Chem., 52, 133 (1974). 3. M.Cospito, P.Zanello, L.Lucarini APPLICAZIONE DELL'ELETTRODO DI MERCURIO A GORGOGLIAMENTO ALLA VOLTAMMETRIA DI RIDISCIOGLIMENTO ANODICO. DETERMINAZIONE DI ZINCO, CADMIO, PIOMBO E RAME IN ACQUE NATURALI E DI SCARICO INDUSTRIALE Atti Soc. Tosc.Sc.Nat.,Mem., A 80, 266 (1975). (English version by the British Defense Ministry, DRIC T 6565 (1982)). 4. A.Cinquantini, G.Raspi and P.Zanello ELECTROCHEMICAL OXIDATION OF α-HIPONYTRATE ION AND ITS ANALYTICAL APPLICATIONS Anal.Chim.Acta, 79, 59 (1975). 5. P.Zanello, G.Raspi and A.Cinquantini ELECTROREDUCTION OF URANIUM(VI) AT A PLATINUM ELECTRODE AND ITS ANALYTICAL APPLICATIONS Talanta, 23, 103 (1976). 6. A.Cinquantini, G.Raspi and P.Zanello VOLTAMMETRIC BEHAVIOUR OF HIPONITRITE ION AND ITS ANALYTICAL APPLICATIONS Anal.Chim.Acta, 87, 51 (1976). 7. P.Zanello and G.Raspi ELECTROXIDATION OF CHROMIUM(III) IN ALKALINE HYDROXIDE SOLUTION AT A PLATINUM ELECTRODE Anal.Chim.Acta, 88, 237 (1977). 8. P.Zanello, G.Raspi and A.Cinquantini ELECTROREDUCTION OF MOLYBDENUM(VI) AT A PREHYDROGENATED PLATINUM ELECTRODE Talanta, 24, 25 (1977). 9. P.Zanello, A.Cinquantini and G.A.Mazzocchin VOLTAMMETRIC BEHAVIOUR OF URANYL-DIETHYL DITHIOCARBAMATE COMPLEXES IN APROTIC MEDIUM Inorg.Chim.Acta, 21, 195 (1977). 10. P.Zanello, A.Cinquantini, P.Di Bernardo and L.Magon

POLAROGRAPHIC INVESTIGATIONS ON URANYL(VI) COMPLEXES IN DIMETHYL-SULFOXIDE. I. MONOCARBOXILIC LIGANDS Inorg.Chim.Acta, 24, 131 (1977). 11. A.Cinquantini, P.Zanello and G.A.Mazzocchin VOLTAMMETRIC BEHAVIOUR OF HYDROXAMIC ACIDS J.Electroanal.Chem., 80, 387 (1977). 12. A.Cinquantini, P.Zanello, G.A.Mazzocchin and O.Traverso POLAROGRAPHIC INVESTIGATIONS ON URANYL(VI) COMPLEXES IN DIMETHYL-SULFOXIDE. II. ALIPHATIC AMINES Inorg.Chim.Acta, 25, 141 (1977). 13. R.Seeber, A.Cinquantini, P.Zanello and G.A.Mazzocchin ANODIC OXIDATION OF DIPHENYLSELENIDE IN APROTIC SOLVENT J.Electroanal.Chem., 88, 137 (1978). 14. P.Zanello, A.Cinquantini, G.A.Mazzocchin, and O.Traverso POLAROGRAPHIC INVESTIGATIONS ON URANYL(VI) COMPLEXES IN DIMETHYL-SULFOXIDE. III. HALIDES AND PSEUDOHALIDES Inorg.Chim.Acta, 27, 157 (1978). 15. P.Zanello, A.Cinquantini, R.Seeber and G.Pieri POLAROGRAPHIC INVESTIGATIONS ON URANYL(VI) COMPLEXES IN DIMETHYL-SULFOXIDE. IV. AMMONIA AND POLYAMINES Inorg.Chim.Acta, 29, 171 (1978). 16. P.Di Bernardo, P.Zanello, D.Curto and R.Portanova THERMODYNAMIC PROPERTIES OF ACTINIDE COMPLEXES. PART VI. THORIUM(IV)-MONOCHLOROACETATE SYSTEM Inorg.Chim.Acta, 29, L185 (1978). 17. P.Zanello, A.Cinquantini, R.Seeber and G.A.Mazzocchin VOLTAMMETRIC INVESTIGATIONS ON THE INTERACTION BETWEEN THORIUM(IV) AND ELECTROGENERATED SUPEROXIDE ION Ann.Chim. (Rome), 68, 143 (1978). 18. R.Seeber, P.Zanello, A.Cinquantini and G.A.Mazzocchin VOLTAMMETRIC INVESTIGATIONS ON MERCURY(II) AND SILVER(I) POLYAMINE COMPLEXES IN DIMETHYL SULFOXIDE SOLUTION J.Chem.Soc., Dalton Trans., 1274 (1979). 19. P.Zanello, R.Seeber, B.Crociani and M.Nicolini ELECTROCHEMICAL INVESTIGATIONS OF CATIONIC trans-HALOARYL-ISOCYANIDE BIS(TERTIARYPHOSPHINO)PLATINUM(II) COMPLEXES Transition Met.Chem., 5, 45 (1980). 20. P.Zanello, R.Seeber, A.Cinquantini and B.Crociani ELECTROCHEMICAL BEHAVIOUR OF cis-DICHLORO(ARYLISOCYANIDE)(TERTIARYPHOSPHINE) PLATINUM(II) COMPLEXES IN AN APROTIC SOLVENT Transition Met.Chem., 5, 226 (1980).

21. A.Cinquantini, R.Cini, R.Seeber and P.Zanello VOLTAMMETRIC BEHAVIOUR OF TRANSITION METAL COMPLEXES WITH EXTENDED π SYSTEMS SCHIFF BASE LIGANDS. THE N,N'-ETHYLENEBIS-(MONOTHIOACETYLACETONIMINATO)NICKEL(II) COMPLEX J.Electroanal.Chem., 111, 309 (1980). 22. P.Zanello, R.Seeber, A.Cinquantini and R.Ros THE EQUILIBRIUM BETWEEN MONOMERIC AND DIMERIC BENZYL- AND CYANOBENZYLPALLADIUM(II) COMPLEXES IN APROTIC MEDIA J.Inorg.Nucl.Chem., 43, 1095 (1981). 23. A.Cinquantini, R.Cini, R.Seeber and P.Zanello VOLTAMMETRIC BEHAVIOUR OF TRANSITION METAL COMPLEXES WITH EXTENDED π SYSTEMS SCHIFF BASE LIGANDS. N,N'-ETHYLENEBIS(MONOTHIO-ACETYLACETONIMINATO)COBALT(II) AND PALLADIUM(II) COMPLEXES Inorg.Chim.Acta, 52, 97 (1981). 24. P.Zanello, A.Cinquantini and G.A.Mazzocchin ELECTROCHEMICAL BEHAVIOUR OF URANYL(VI) ION IN DIFFERENT NONAQUEOUS SOLVENTS J.Electroanal.Chem., 131, 215 (1982). 25. E.Roncari, U.Mazzi, R.Seeber and P.Zanello ELECTROCHEMICAL INVESTIGATION ON THE PHOSPHINE-RHENIUM COMPLEXES [ReC3(PMe2Ph)3] AND [ReCl4(PMe2Ph)2] IN AN APROTIC MEDIUM J.Electroanal.Chem., 132, 221 (1982). 26. P.Zanello, R.Seeber and A.Cinquantini POLAROGRAPHIC INVESTIGATIONS ON URANYL(VI) COMPLEXES IN DIMETHYLSULPHOXIDE. V. 14-MEMBERED TETRA-AZAMACROCYCLES Inorg.Chim.Acta, 65, L43 (1982). 27. P.Zanello, R.Cini, A.Cinquantini and P.L.Orioli X-RAY AND ELECTROCHEMICAL INVESTIGATION ON A SERIES OF COBALT(II) COMPLEXES WITH QUINQUEDENTATE LIGANDS AND THEIR REACTIVITY TOWARDS DIOXYGEN J.Chem.Soc., Dalton Trans., 2159 (1983). 28. P.Zanello, R.Cini, A.Cinquantini, and P.L.Orioli X-RAY AND ELECTROCHEMICAL INVESTIGATION ON A SERIES OF COBALT(II) COMPLEXES WITH QUINQUEDENTATE LIGANDS AND THEIR REACTIVITY TOWARDS DIOXYGEN J.Chem.Soc., Dalton Trans., 2159 (1983). 29. R.Cini, P.Zanello, A.Cinquantini, A.Colligiani, C.Pinzino and G.Valentini FIVE-COORDINATE METAL COMPLEXES OF BIS(2-HYDROXY-1-NAPHTHYL-IDENEIMINE-3-PROPYL)AMINE AND THEIR REACTIVITY TOWARDS DIOXYGEN. PART I. AN ELECTROCHEMICAL INVESTIGATION ON MANGANESE(II), IRON(II), COBALT(II), NICKEL(II) AND COPPER(II) COMPLEXES Inorg.Chim.Acta, 88, 105 (1984). 30. R.Seeber and P.Zanello SOLVENT EFFECTS ON THE REDOX POTENTIAL OF THE U(VI)/U(V) COUPLE

J.Chem.Soc., Dalton Trans., 601 (1985). 31. P.Zanello, R.Cini, and A.Cinquantini REDOX PROPERTIES OF N,N'-X-PHENYLENEBIS(Y-SALYCILIDENEIMINATO)IRON(II) COMPLEXES AND REACTIVITY OF THE CORRESPONDING IRON(III) COMPLEXES TOWARDS CATECHOLATES Polyhedron, 4, 1383 (1985). 32. A.Colligiani, C.Pinzino, G.Valentini, R.Cini, P.Zanello and A.Cinquantini FIVE COORDINATED METAL COMPLEXES OF BIS(2-HYDROXY-1-NAPHTHYLIDENE IMINE-3-PROPYL)- AMINE AND THEIR REACTIVITY TOWARDS DIOXYGEN. PART II. EPR EVIDENCES ON THE ROLE OF THE SOLVENT ON THE STABILITY OF THE Co(III)O2− SPECIES Inorg.Chim.Acta, 103, 105 (1985). 33. P.Zanello and A.Cinquantini ELECTROCHEMICAL BEHAVIOUR OF A SERIES OF N,N'-PHENYLENEBIS (SALYCILIDENEIMIN)ATO TRANSITION METAL COMPLEXES Transition Met.Chem., 10, 370 (1985). 34. C.Bianchini, A.Meli and P.Zanello SYNTHESIS AND ELECTROCHEMISTRY OF SOME HOMO- AND HETERO-DINUCLEAR TRIHYDRIDE COMPLEXES OF RHODIUM, IRON, COBALT AND NICKEL J.Chem.Soc., Chem.Commun., 628 (1986). 35. P.Piraino, G.Bruno, G.Tresoldi, S.Lo Schiavo and P.Zanello CHEMICAL OXIDATION OF BINUCLEAR RHODIUM(I) COMPLEXES WITH SILVER SALTS. SYNTHESIS, X-RAY CRYSTAL STRUCTURE, AND ELECTROCHEMICAL PROPERTIES OF THE Rh2

4+ MIXED LIGAND COMPLEX Rh2(form)2(O2CCF3)2(H2O)2 .0.5 C6H6 (form = N,N'-di-p-tolylformamidinate anion) Inorg.Chem., 26, 91 (1987). 36. C.Bianchini, C.Mealli, A.Meli, M.Sabat and P.Zanello GENESIS OF TETRATHIOOXALATE-LIKE C2S4 AND C2Se4 UNITS. A MULTIFORM EXPERIMENTAL STUDY AND THE RELEVANT THEORETICAL IMPLICATIONS FOR THE ROLE OF TRANSITION METAL FRAGMENTS J.Am.Chem.Soc., 109, 185 (1987). 37. P.Piraino, G.Bruno, S.Lo Schiavo, F.Laschi and P.Zanello SYNTHESIS, X-RAY STRUCTURE, AND ELECTROCHEMICAL PROPERTIES OF THE Rh2

4+ COMPLEX Rh2(form)4 (form = N,N'-di-p-tolylformamidinate anion) Inorg.Chem., 26, 2205 (1987). 38. P.Zanello, A.Cinquantini, F.Laschi, R.Rossi, A.Duatti, A.Marchi and L.Magon REDOX PROPERTIES OF A SERIES OF PSEUDOALLYL RHENIUM(I) COMPLEXES Polyhedron, 7, 195 (1988). 39. D.Osella, M.Botta, R.Gobetto, F.Laschi and P.Zanello ELECTROCHEMISTRY OF IRON AND RUTHENIUM FLYOVER BRIDGE COMPLEXES Organometallics, 7, 283 (1988). 40. P.Leoni, F.Marchetti, M.Pasquali and P.Zanello REACTIVITY OF CATIONIC MOLYBDENUM(II) COMPLEXES. 2. ELECTROCHEMICAL REDUCTION OF THE EIGHTEEN-ELECTRON COMPLEXES [Mo(CO)3(η5-C5Me5)L]+ (L=CO, p-MeC6H4NC, or P(OMe)3). CRYSTAL STRUCTURE OF [Mo(CO)6(η5-C5Me5)2]+

J.Chem.Soc., Dalton Trans., 635 (1988). 41. C.Bianchini, A.Meli, F.Laschi, A.Vacca and P.Zanello METAL ASSISTED THREE-FRAGMENT DEMOLITION OF THE DITHIOCARBONATE LIGAND: A NEW SYNTHETIC ROUTE TO HOMO- AND HETERO-BINUCLEAR BIS(µ-SULFIDO)METAL COMPLEXES. CHEMICAL, ELECTROCHEMICAL, AND SPECTROSCOPIC CHARACTERIZATION OF A FAMILY OF COMPLEXES OF IRON, COBALT, RHODIUM, AND PLATINUM WITH BRIDGING SULFIDO LIGANDS J.Am.Chem.Soc., 110, 3913 (1988). 42. C.Bianchini, F.Laschi, F.Ottaviani, M.Peruzzini and P.Zanello UNPRECEDENTED TRANSFORMATION OF A VINYLIDENE LIGAND. SYNTHESIS AND ESR CHARACTERIZATION OF A PARAMAGNETIC η-ACETYLIDE COMPLEX OF RHODIUM(II) Organometallics, 7, 1660 (1988). 43. F.Cecconi, C.A.Ghilardi, S.Midollini, A.Orlandini, P.Zanello, B.T.Heaton, L.H.Jonathan, A.Iggo and S.Bordoni THE REACTIVITY OF THE METAL-METAL BOND IN THE DIMER [(CH3C(CH2PPh2)3)2Rh2(CO)2].(CH3)2CO. SYNTHESIS AND X-RAY STRUCTURE OF A PARAMAGNETIC DINUCLEAR RHODIUM COMPLEX J.Organomet.Chem., 353, C5 (1988). 44. S.Bianchini, F.Laschi, A.Meli, M.Peruzzini, P.Zanello and P.Frediani REDOX-INDUCED REVERSIBLE MIGRATION OF HYDROGEN FROM METAL TO ALKENE Organometallics, 7, 2575 (1988). 45. C.Bianchini, A.Meli, F.Laschi, J.A.Ramirez, P.Zanello and A.Vacca SYNTHESIS, CHARACTERIZATION AND ELECTROCHEMICAL PROPERTIES OF A FAMILY OF DINUCLEAR RHODIUM COMPLEXES CONTAINING TWO TERMINAL HYDRIDE LIGANDS AND TWO HYDRIDE (OR CHLORIDE) BRIDGES. STOICHIOMETRIC AND CATALYTIC HYDROGENATION REACTIONS OF ALKYNES AND ALKENES, Inorg.Chem., 27, 4429 (1988). 46. R.Seeber, P.Piu, P.Piraino and P.Zanello THE STANDARD REDOX POTENTIAL IN THE STUDY OF SOLUTE-SOLVENT INTERACTIONS. DIRHODIUM COMPLEXES Inorg.Chim.Acta, 155, 27 (1989). 47. P.Zanello, F.Laschi, A.Cinquantini and P.Piraino CHEMICAL AND ELECTROCHEMICAL OXIDATION OF A SERIES OF p-TOLYL FORMAMIDINATEDIRHODIUM(I) COMPLEXES Inorg.Chim.Acta, 155, 49 (1989). 48. C.Bianchini, A.Meli, F.Laschi, F.Vizza and P.Zanello NOVEL REACTIONS OF THE [BPh4]− SALT OF THE BIFUNCTIONAL COMPLEX [(triphos)Rh(S2CO)]+ (triphos = MeC(CH2PPh2)3): ONE-ELECTRON REDUCTION, CLEAVAGE OF B-H AND B-C BONDS, AND METATHESIS OF CS2-LIKE HETEROALLENE MOLECULES Inorg.Chem., 28, 227 (1989). 49. C.Bianchini, F.Laschi, M.F.Ottaviani, M.Peruzzini, P.Zanello and F.Zanobini NUCLEOPHILIC PROPERTIES AND ELECTROCHEMISTRY OF FIVE-COORDINATE RHODIUM η-CYANIDE COMPLEXES. SYNTHESIS AND CHARACTERIZATION OF STABLE CIS HYDRIDE CYANIDE COMPLEXES OF RHODIUM(III)

Organometallics, 8, 893 (1989). 50. E.Bouwman, W.L.Driessen, J.Reedijk, C.Smykalla, J.M.M.Smits, P.T.Beurskens, F.Laschi and P.Zanello A UNIQUE BROMO- AND THIOETHER-BRIDGED TETRANUCLEAR MIXED-VALENCE COPPER(I)- COPPER(II) COMPOUND WITH THE N,S-DONOR LIGAND 4-((ETHYLTHIO)METHYL)-5-METHYL IMIDAZOLE Inorg.Chem., 29, 4881 (1990). 53. C.Bianchini, F.Laschi, D.Masi, C.Mealli, A.Meli, F.M.Ottaviani, D.M.Proserpio, M.Sabat and P.Zanello, HOMO- AND HETEROBIMETALLIC TRIHYDRIDE COMPLEXES STABILIZED BY THE TRIPODAL PHOSPHINE LIGAND MeC(CH2PPh2)3. EXPERIMENTAL AND THEORETICAL STUDIES Inorg.Chem., 28, 2552 (1989). 54. C.Bianchini, A.Meli, M.Peruzzini, F.Zanobini and P.Zanello SYNTHESIS, REDOX PROPERTIES, AND REACTIVITY OF A NOVEL FAMILY OF ELECTRON-RICH VINYLIDENE AND VINYLPHOSPHONIUM COMPLEXES OF RHODIUM(I) Organometallics, 9, 241 (1990). 55. C.Bianchini, A.Meli, M.Peruzzini, A.Vacca, F.Laschi, P.Zanello and F.M.Ottaviani σ-ACETYLIDE COMPLEXES OF RHODIUM(I), RHODIUM(II), AND RHODIUM(III). CORRELATION BETWEEN ELECTROCHEMICAL (E°’) AND SPECTROSCOPIC (Δν(C≡C)) PARAMETERS AND dπ (METAL) → π*(ACETYLIDE) TRANSFER Organometallics, 9, 360 (1990). 56. D.Osella, O.Gambino, R.Gobetto, P.Zanello, F.Laschi, C.E.Housecroft and S.M.Owen INVESTIGATION OF THE ELECTROCHEMICAL BEHAVIOR AND ELECTRONIC STRUCTURE OF (µ-BUTATRIENE)HEXACARBONYLDIIRON COMPLEXES Organometallics, 9, 1792 (1990). 57. C.Bianchini, F.Laschi, M.Peruzzini, F.M.Ottaviani, A.Vacca and P.Zanello ELECTROCHEMISTRY AS A DIAGNOSTIC TOOL TO DISCRIMINATE BETWEEN CLASSICAL M-(H)2 AND NONCLASSICAL M-(H2) STRUCTURES WITHIN A FAMILY OF DIHYDRIDE AND DIHYDROGEN METAL COMPLEXES Inorg.Chem., 29, 3394 (1990). 58. C.Bianchini, P.Innocenti, A.Meli, M.Peruzzini, F.Zanobini and P.Zanello REACTIONS OF THE TRIGONAL-BIPYRAMIDAL COBALT(I) HYDRIDE [{P(CH2CH2PPh2)3}CoH] WITH 1-ALKYNES. SYNTHESIS AND REACTIVITY OF ACETYLIDE, ALKENYL, AND VINYLIDENE COMPLEXES Organometallics, 9, 2514 (1990). 59. C.A.Ghilardi, C.Mealli, S.Midollini, A.Orlandini, D.M.Proserpio, A.Cinquantini and P.Zanello STEPWISE ELECTRON-INDUCED DEMOLITION OF THE Ni-I σ-BOND IN COMPLEXES WITH TETRADENTATE TRIPODAL LIGANDS: A THEORETICAL RATIONALIZATION OF STRUCTURAL AND ELECTROCHEMICAL RESULTS Struct.Chem., 1, 441 (1990). 60. P.Zanello, A.Cinquantini. C.A.Ghilardi, S.Midollini, S.Moneti, A.Orlandini and A.Bencini STRUCTURAL REORGANIZATIONS ACCOMPANYING THE NICKEL(II)-NICKEL(I) REDOX CHANGE IN NICKEL COMPLEXES WITH THE TRIPODAL LIGAND MeC(CH2PPh2)3 (Triphos, L). X-RAY CRYSTAL STRUCTURE OF [NiL(I)]2[As6I8] J.Chem.Soc., Dalton Trans., 3761 (1990).

61. C.Bianchini, D.Masi, A.Meli, M.Peruzzini, A.Vacca, F.Laschi and P.Zanello COUPLING OF TWO ETHYNE MOLECULES AT RHODIUM VERSUS COUPLING OF TWO RHODIUM ATOMS AT ETHYNE. 1. ELECTRONIC CONTROL ON THE INTERCONVERSION OF (µ-η2,η2-ETHYNE)- AND (µ-η1,η1-ETHYNE) DIRHODIUM COMPLEXES Organometallics, 10, 636 (1991). 62. L.D.Field, A.V.George, F.Laschi, E.Y.Malouf and P.Zanello ELECTROCHEMISTRY OF ACETYLIDE COMPLEXES OF IRON J.Organomet.Chem., 435, 347 (1992). 63. P.Diversi, S.Iacoponi, G.Ingrosso, F.Laschi, A.Lucherini and P.Zanello ELECTRON TRANSFER REACTIONS IN Ir(III) DIALKYL COMPLEXES: ACTIVATION OF C-H BONDS ON OXIDATION OF [IrMe2(η5-C5Me5)(PR3)] (R=Ph,Me) J.Chem.Soc., Dalton Trans., 351 (1993). 64. C.Bianchini, F.Laschi, D.Masi, F.M.Ottaviani, A.Pastor, M.Peruzzini, P.Zanello and F.Zanobini A FAMILY OF STABLE IRON(I) σ-ALKYNYL COMPLEXES. SYNTHESIS, CHARACTERIZATION, STRUCTURE AND ELECTRON-TRANSFER CHEMISTRY J.Am.Chem.Soc., 115, 2723 (1993). 65. P.Leoni, M.Pasquali, M.Sommovigo, F.Laschi, P.Zanello, A.Albinati, F.Lianza, P.S.Pregosin and H.Rüegger CHEMISTRY OF PHOSPHIDO-BRIDGED Pd(II) DIMERS. η2 Pd-H-Pd INTERACTIONS: A NEW BONDING MODE FOR SECONDARY PHOSPHINES Organometallics, 12, 1702 (1993). 66. D.Osella, R.Gobetto, L.Milone, C.Nervi, M.Ravera, E.Stein, P.Zanello and F.Laschi ELECTROCHEMICAL BEHAVIOUR OF TROPONE DIIRONPENTACARBONYL COMPLEXES Fe2(CO)5[(RC2R)3CO] (R = Me, Et, n-Pr). FORMATION OF A CARBON-CARBON BOND UPON REDUCTION Inorg.Chim.Acta, 212, 311 (1993). 67. P.Barbaro, C.Bianchini, F.Laschi, S.Midollini, S.Moneti, G.Scapacci and P.Zanello DIOXYGEN AND CARBON MONOXIDE UPTAKE BY Ir(I) COMPLEXES STABILIZED BY MIXED N,P-DONOR LIGANDS Inorg.Chem., 33, 1622 (1994). 66. P.Braunstein, M.Knorr, M.Strampfer, Y.Dusausoy, D.Bayeul, A.DeCian, J.Fischer and P.Zanello SYNTHESIS, STRUCTURE, AND ELECTROCHEMISTRY OF Ph2PCH2PPh2-BRIDGED, HETEROMETALLIC COMPLEXES CONTAINING A (C5H4Me)Mn(CO)2 FRAGMENT J.Chem.Soc., Dalton Trans., 1533 (1994). 67. P.Barbaro, C.Bianchini, G.Scapacci, D.Masi and P.Zanello DIOXOMOLYBDENUM(VI) COMPLEXES STABILIZED BY POLYDENTATE LIGANDS WITH NO3, N2O2, and NS2 DONOR-ATOM SETS Inorg.Chem., 33, 3180 (1994). 68. C.Bianchini, F.Laschi, M.Peruzzini and P.Zanello A FIVE-COORDINATE RUTHENIUM(I) COMPLEX Gazz.Chim.Ital., 124, 271 (1994). 69. C.A.Ghilardi, F.Laschi, S.Midollini, A.Orlandini, G.Scapacci and P.Zanello SYNTHESIS, CRYSTAL STRUCTURE, ELECTROCHEMISTRY AND ELECTRONIC PARAMAGNETIC RESONANCE

SPECTROSCOPY OF [M{PPh2CH2)3CMe}(o-S2C6H4)][PF6]n (M = Fe, Co or Rh; n = 0 or 1), J.Chem.Soc., Dalton Trans., 531 (1995). 70. S.Bordoni, L.Busetto, F.Calderoni, L.Carlucci, F.Laschi, P.Zanello and V.Zanotti REDOX CHEMISTRY AND SUBSTITUTION REACTIONS OF THE µ-CYANO-ALKYLIDENE COMPLEXES [Fe2(CO)2(µ-CO){µ-C(CN)(X)}]n+ (n = 0; X = CN, H, Me, SMe, OMe, OEt, OPh, OCH2CH=CH2, PEt2, or NC5H10; n = 1, X = PMe2Ph) J.Organomet.Chem., 496, 27 (1995). 71. P.Diversi, S.Iacoponi, G.Ingrosso, F.Laschi, A.Lucherini, C.Pinzino, G.Uccello-Barretta and P.Zanello ELECTRON TRANSFER CATALYSIS IN THE ACTIVATION OF C-H BONDS BY IRIDIUM COMPLEXES Organometallics, 14, 3275 (1995). 72. C.Bianchini, V.Herrera, M.V.Jimenez, F.Laschi, A.Meli, R.Sánchez-Delgado, F.Vizza and P.Zanello, REDOX-INDUCED CONVERSION PATHWAYS IN RHODIUM AND IRIDIUM COMPLEXES CONTAINING C-S BOND CLEAVED BENZO[b]THIOPHENE Organometallics, 14, 4390 (1995). 73. V.Zanotti, S.Bordoni, L.Busetto, L.Carlucci, A.Palazzi, R.Serra, V.G.Albano, M.Monari, F.Prestopino, F.Laschi and P.Zanello DIIRON AMINOALKYLIDENE COMPLEXES Organometallics, 14, 5232 (1995). 74. G.Tresoldi, S.Lo Schiavo, P.Piraino and P.Zanello, SYNTHESIS OF THE NEW BINUCLEATING COMPOUND PYRAZIN-2-YL 2-PYRIDYL SULFIDE FOR STEPWISE OR DIRECT APPROACH TO ASYMMETRIC BINUCLEAR RUTHENIUM(II) COMPLEXES J.Chem.Soc., Dalton Trans., 885 (1996). 75. P.Diversi, A.Ferrarini, G.Ingrosso, A.Lucherini, G.Uccello-Barretta, C.Pinzino, F. de Biani Fabrizi, F.Laschi and P.Zanello ELECTRON-TRANSFER CATALYSIS IN THE ACTIVATION OF ARENE C-H BONDS BY IRIDIUM COMPLEXES AND THE IMPORTANCE OF STERIC FACTORS IN DETERMINING THE NATURE OF THE ACTIVATION PRODUCTS Gazz.Chim.Ital., 126, 391 (1996). 76. F.P.Fanizzi, G.Natile, M.Lanfranchi, A.Tiripicchio, F.Laschi and P.Zanello STERIC CROWDING AND REDOX REACTIVITY IN PLATINUM(II) AND PLATINUM(IV) COMPLEXES CONTAINING SUBSTITUTED 1,10-PHENANTHROLINES Inorg.Chem., 35, 3173 (1996). 77. A.Ceccanti, P.Diversi, G.Ingrosso, F.Laschi, A.Lucherini, S.Magagna and P.Zanello ELECTRON TRANSFER CATALYSIS IN THE ACTIVATION OF C-H BONDS BY RUTHENIUM COMPLEXES J.Organomet.Chem.,526, 251 (1996). 78. K.R.Justin Thomas, V.Chandrasekhar, P.Zanello and F.Laschi PLATINUM(II) AND PALLADIUM(II) COMPLEXES OF TETRAKIS-(PYRAZOLYL) CYCLOTRIPHOSPHAZENES Polyhedron, 16, 1003 (1997). 79. S.Lo Schiavo, G.Bruno, P.Zanello, F.Laschi and P.Piraino NEW ADDUCTS OF DIRHODIUM(II) FORMAMIDINATE WITH POLYCYANO ACCEPTOR MOLECULES. X-RAY CRYSTAL STRUCTURE OF THE TRICYANO- METHANIDE COMPLEX Rh2(form)4[C(CN)3] (form = N,N'-Di-p-

tolyl-formamidinate), Inorg.Chem., 36, 1004 (1997). 80. C.Bianchini, M.Peruzzini, A.Ceccanti, F.Laschi and P.Zanello ANODICALLY-INDUCED METAL DEPROTONATION OF THE HYDRIDO COMPLEXES [P(CH2CH2PPh2)3]M(H)Cl] (M= Fe,Ru,Os): THE FIRST STEP TO THE ELECTROGENERATION OF Fe(I), Ru(I) AND Os(I) FIVE-COORDINATE COMPLEXES Inorg.Chim.Acta, 259, 61 (1997). 81. N.J.Long, A.J.Martin, F.Fabrizi de Biani and P.Zanello SYNTHETIC AND ELECTROCHEMICAL STUDIES OF SOME METAL COMPLEXES OF 1,3,5-TRIETHYNYLBENZENE J.Chem.Soc., Dalton Trans., 2017 (1998). 82. J.J.Schneider, J.Hagen, O.Heinemann, C.Krüger, F.Fabrizi de Biani and P.Zanello SYNTHESIS, STRUCTURE, SPECTROELECTROCHEMICAL AND THEORETICAL INVESTIGATIONS OF [(η5-Me5Cp)Co(η4-MeC=CMe-CMe=CMe)Sn{CH(SiMe3)2}2]. FORMATION OF A COBALT COMPLEXED STANNACYCLE VIA A MIXED ALKYNE-STANNYLENE CYCLOADDITION REACTION Inorg.Chim.Acta, 281, 53 (1998). 83. A.Caneschi, F.Fabrizi de Biani, L.Kloo and P.Zanello MAGNETIC AND REDOX PROPERTIES IN HYDROXO- AND ALKOXO-BRIDGED Fe(III) BINUCLEAR COMPLEXES: A DENSITY FUNCTIONAL STUDY J.Quantum Chem., 72, 61 (1999). 84. P.Bergamini, F.Fabrizi de Biani, L Marvelli, N.Mascellani, M.Peruzzini, R.Rossi and P.Zanello SUBSTITUTION OF LABILE TRIFLATE IN [(triphos)Re(CO)2(Otf)]: A NEW SYNTHETIC ROUTE TO MONONUCLEAR AND DINUCLEAR ReI COMPLEXES New J.Chem., 207 (1999). 85. P.Diversi, F.Fabrizi de Biani, G.Ingrosso, F.Laschi, A.Lucherini, C.Pinzino and P.Zanello SYNTHESIS AND SOME REACTIVITY OF CATIONIC ALKYL NITROSYL IRIDIUM(III) DERIVATIVES J.Organomet.Chem., 584, 73 (1999). 86. C.Bianchini, H.M.Lee, A.Meli, S.Moneti, F.Vizza, M.Fontani and P.Zanello COPOLYMERIZATION OF CARBON MONOXIDE WITH ETHENE CATALYZED BY PALLADIUM(II) COMPLEXES OF 1,3-BIS(DIPHENYLPHOSPHINO)PROPANE LIGANDS BEARING DIFFERENT SUBSTITUENTS ON THE CARBON BACKBONE Macromolecules, 32, 4183 (1999). 87. J.J.Schneider, N.Czap, D.Spickermann, C.W.Lehmann, M.Fontani, F.Laschi and P.Zanello SYNTHESIS, STRUCTURE AND SPECTROELECTROCHEMISTRY OF BIS(η6-1,4-TRI-TERT-BUTYL-BENZENE)CHROMIUM(0) AND BIS(η5-1,2,4-TRI-TERT-BUTYL-CYCLOPENTADIENYL)COBALT(II). DIA- AND PARAMAGNETIC SANDWICH COMPLEXES DERIVED FROM STERICALLY HIGHLY DEMANDING π-LIGANDS J.Organomet.Chem., 590, 7 (1999). 88. D.G.Hamilton, M.Montalti, L.Prodi, M.Fontani, P.Zanello and J.K.M.Sanders PHOTOPHYSICAL AND ELECTROCHEMICAL CHARACTERISATION OF THE INTERACTIONS BETWEEN COMPONENTS IN NEUTRAL π-ASSOCIATED [2] CATENANES Chem.Eur.J., 608 (2000).

89. J.J.Schneider, D.Spickermann, T.Labahn, J.Magull, M.Fontani, F.Laschi and P.Zanello MONO-, DI-, AND TRIMETALLIC COMPLEXES OF THE NONALTERNATING POLYCONDENSED π-PERIMETER DECACYCLENE, C36H18: SYNTHESIS, STRUCTURE, AND SPECTROELECTROCHEMISTRY OF [{(η5-Me4EtC5)Co}2(µ-η5:η4-C36H18)] Chem.Eur.J., 6, 3686 (2000). 90. F.Fabrizi de Biani, F.Laschi, P.Zanello, G.Ferguson, J.Trotter, G.M.O'Riordan and T.R.Spalding, SYNTHESIS, STRUCTURE, SPETROSCOPIC AND ELECTROCHEMICAL STUDY OF THE PARAMAGNETIC COMPOUND [2-(η7-C7H7)-7,11-F2-2,1-closo-MoTeB10H8] J.Chem.Soc., Dalton Trans., 1520 (2001). 91. P. Diversi, M. Fontani, M. Fuligni, F. Laschi, S. Matteoni, C. Pinzino, P. Zanello OXIDATIVE REACTIONS OF "HALF-SANDWICH" RUTHENIUM COMPOUNDS: FORMATION OF CATIONIC NITROSYL RUTHENIUM(II) DERIVATES J.Organomet.Chem., 626, 145 (2001). 92. F.Bachechi, A.Burini, M.Fontani, R.Galassi, A.Macchioni, B.R.Pietroni, P.Zanello and C.Zuccaccia SOLID STATE AND SOLUTION INVESTIGATIONS OF DERIVATIVES OF GROUP 11 METAL IONS WITH 1-BENZYL-2-IMIDAZOLYLDIPHENYLPHOSPHINE (L). ELECTROCHEMICAL BEHAVIOR OF [M2L3]2+ (M = CuI; AgI) AND [AuL2]+ COMPLEXES Inorg.Chim.Acta, 323, 45 (2001). 93. R.Cini, C.Bellucci, G.Tamasi, M.Corsini, M.Fontani and P.Zanello SYNTHESIS, ELECTROCHEMICAL STUDIES, DENSITY FUNCTIONAL ANALYSIS AND X-RAY STRUCTURES OF trans,cis,cis-[RuCl2(N-methylimidazole)2(SbPh3)2] AND trans,cis,cis-[RuCl2(N-methylpyrimidine)2(SbPh3)2]. THE ROLE OF C-H···Cl INTERACTIONS IN PYRIMIDINE PAIRINGS AND IN TUNING THE ANGULAR APPROACH OF IMIDAZOLE RESIDUES TO METALS Inorg.Chim.Acta, 339, 89 (2002). 94. H.Liu, M.J.Calhorda, M.G.B.Drew, V.Félix, J.Novosad, L.F.Veiros, F.Fabrizi de Biani and P.Zanello NEW Cu(I) AND Ag(I) BINUCLEAR COMPLEXES CONTAINING THE dppa LIGAND J.Chem.Soc., Dalton Trans., 4365 (2002). 95. C.Bianchini, G.Giambastiani, F.Laschi, P.Mariani, A.Vacca, F.Vizza and P.Zanello SYNTHESIS, CHARACTERIZATION AND COORDINATION CHEMISTRY OF THE NEW TETRAAZACYCLODODECANE-1,7-BIS(METHANEPHOSPHONIC ACID MONOETHYL ESTER) DIPOTASSIUM SALT Org.Biomol.Chem., 1, 879 (2003). 96. M.Corsini, E.Grigiotti, F.Laschi, P.Zanello, J.Burgess, J.Fawcett and S.R.Gilani AN ELECTROCHEMICAL INVESTIGATION OF THE STRUCTURE OF COPPER(II) COMPLEXES OF SCHIFF BASE LIGANDS DERIVED FROM SALICYLALDEHIDE AND SUBSTITUTED ANILINES Collect.Czech.Chem.Commun., 68, 1449 (2003). 97. P.Diversi, M.Fontani, M.Fuligni, F.Laschi, F.Marchetti, S.Matteoni, C.Pinzino and P.Zanello REDUCTION OF THE NO+ LIGAND IN “HALF-SANDWICH” RUTHENIUM DERIVATIVES J.Organomet.Chem., 675, 21 (2003). 98. S.Antonini, F.Calderazzo, U.Englert, E.Grigiotti, G.Pampaloni and P.Zanello SYNTHESIS, ELECTROCHEMISTRY, AND CRYSTAL STRUCTURES OF SOME MOLYBDENUM(0) ARENE DERIVATIVES WITH FLUORINATED AND PHENYL-SUBSTITUTED ARENE LIGANDS J.Organomet.Chem., 689, 2158 (2004).

99. H.Liu, N.A.G.Bandeira, M.J.Calhorda, M.G.B.Drew, V.Félix, J.Novosad, F.Fabrizi de Biani and P.Zanello Cu(I) AND Ag(I) COMPLEXES OF CHALCOGENIDE DERIVATIVES OF THE ORGANOMETALLIC LIGAND dppf AND THE dppa ANALOGUE J.Organomet.Chem., 689, 2808 (2004). 100. E.V.Mutseneck, D.A.Loginov, D.S.Perekalin, Z.A.Starikova, D.G.Golovanov, P.V.Petrovskii, P.Zanello, M.Corsini, F.Laschi and A.R.Kudinov (TETRAMETHYLCYCLOBUTADIENE)COBALT COMPLEXES WITH FIVE-ELECTRON CARBO- AND HETEROCYCLIC LIGANDS Organometallics, 23, 5944 (2004). 101. M.D.Godbole, E.Grigiotti, P.Zanello, A.M.Mills, A.L.Spek and E.Bouwman CRYSTAL STRUCTURE OF THE MONONUCLEAR COMPLEX [Mn(mesalim)2Cl] AND ELECTROCHEMICAL STUDIES OF MANGANESE COMPLEXES OF THE LIGAND Hmesalim Inorg.Chim.Acta, 358, 233 (2005). 102. N.Mantovani, M.Brugnati, L.Gonsalvi, E.Grigiotti, F.Laschi, L.Marvelli, M.Peruzzini, G.Reginato, R.Rossi and P.Zanello SYNTHESIS, CHARACTERIZATION, AND ELECTROCHEMICAL BEHAVIOR OF MONO- AND BIMETALLIC RUTHENIUM AND RHENIUM ALLENYLIDENES BEARING MULTICONJUGATED ORGANIC SPACERS Organometallics, 24, 405 (2005). 103. F.Benetollo, E.Grigiotti, F.Laschi, G.Pampaloni, M.Volpe and P.Zanello ELECTROCHEMICAL AND EPR INVESTIGATION ON BIS-TOLUENE Cr(I) COMPLEXES. [Cr(η6-CH3C6H5)2][dbcp-NO2]([dbcp-NO2] = 1,2-DIBENZOYL-4-NITROCYCLOPENTADIENYL ANION): THE FIRST EXAMPLE OF A [Cr(η6-CH3C6H5)2] CATION CONTAINING A cis-ECLIPSED ARRANGEMENT OF TOLUENE RINGS J.Solid State Electrochem., 9, 732 (2005). 104. L.Calucci, U.Englert, E.Grigiotti, F.Laschi, G.Pampaloni, C.Pinzino, M.Volpe and P.Zanello SYNTHESIS AND CHARACTERIZATION OF CHROMIUM(I) BIS(η6-TOLUENE) DERIVATIVES CONTAINING STERICALLY DEMANDING ANIONS J.Organomet. Chem., 691, 829 (2006). 105. M.Corsini, P.Zanello, R.Cini ande G.Tamasi X-RAY STRUCTURE AND DENSITY FUNCTIONAL THEORY STUDIES OF AN UNEXPECTED PRODUCT: trans-BIS{2-[(2-CYANOETHYL)-IMINOMETHYL]PHENOLATO}- COPPER(II) Acta Cryst., C65, m219 (2009). 8 TEXTBOOKS 1. P.Zanello, S.Mangani, G.Valensin, Le basi della chimica, Casa Editrice Ambrosiana, Milano, 2001. 2. P.Zanello, Inorganic Electrochemistry. Theory, Practice and Application, RS·C, Cambridge, UK., 2003 3. P.Zanello, R.Gobetto, R.Zanoni, Conoscere la chimica, Casa Editrice Ambrosiana, Milano, 2009. 4. P. Zanello, C. Nervi, F. Fabrizi de Biani, Inorganic Electrochemistry. Theory, Practice and Application, II Edition, RS·C, Cambridge, UK., 2011

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