IASDATA\CHEMOURS\15418.002.017\POLYMERS REPORT SEPT 2019-AMD 10/25/2019 IXM MANUFACTURING PROCESSES POLYMERS STACK EMISSIONS TEST REPORT TEST DATES: 25-26 SEPTEMBER 2019 THE CHEMOURS COMPANY FAYETTEVILLE, NORTH CAROLINA Prepared for: THE CHEMOURS COMPANY 22828 NC Hwy 87 W Fayetteville, North Carolina 28306 Prepared by: WESTON SOLUTIONS, INC. 1400 Weston Way P.O. Box 2653 West Chester, Pennsylvania 19380 October 2019 W.O. No. 15418.002.017
6 DETAILED TEST RESULTS AND DISCUSSION 15 APPENDIX A PROCESS OPERATIONS DATA APPENDIX B RAW AND REDUCED TEST DATA APPENDIX C LABORATORY ANALYTICAL REPORT APPENDIX D SAMPLE CALCULATIONS APPENDIX E EQUIPMENT CALIBRATION RECORDS APPENDIX F LIST OF PROJECT PARTICIPANTS
IASDATACHEMOURS15418002017POLYMERS REPORT SEPT 2019-AMD 10252019 ii
LIST OF FIGURES
Title Page
Figure 4-1 Polymers Stack Test Port and Traverse Point Locations 7
captured as HFPO Dimer Acid emission testing on the Polymers Stack Testing was performed
on 25-26 September 2019 and generally followed the ldquoEmission Test Protocolrdquo reviewed and
approved by the North Carolina Department of Environmental Quality (NCDEQ) This report
provides the results from the emission test program
12 TEST OBJECTIVES
The specific objectives for this test program were as follows
Measure the emissions concentrations and mass emissions rates of HFPO Dimer Acid Fluoride from the Polymers stack which is located in the IXM processes
Monitor and record process data in conjunction with the test program Provide representative emissions data
13 TEST PROGRAM OVERVIEW
During the emissions test program the concentrations and mass emissions rates of HFPO Dimer
Acid Fluoride were measured on the Polymers stack
Table 1-1 provides a summary of the test location and the parameters that were measured along
with the samplinganalytical procedures that were followed
Sampling Point amp Location Polymers Stack Number of Tests 3 Parameters To Be Tested HFPO Dimer
Acid Fluoride (HFPO-DAF)
Volumetric Flow Rate and Gas Velocity
Carbon Dioxide
Oxygen Water Content
Sampling or Monitoring Method EPA M-0010 EPA M1 and M2 in
conjunction with M-0010
tests
EPA M33A EPA M4 in conjunction
with M-0010 tests
Sample Extraction Analysis Method(s) LCMSMS NA6 NA NA Sample Size gt 1m3 NA NA NA NA Total Number of Samples Collected1 3 3 3 3 3 Reagent Blanks (Solvents Resins)1 1 set 0 0 0 0 Field Blank Trains1 1 per source 0 0 0 0 Proof Blanks1 1 per train 0 0 0 0 Trip Blanks12 1 set 0 0 0 Lab Blanks 1 per fraction3 0 0 0 0 Laboratory or Batch Control Spike Samples (LCS)
1 per fraction3 0 0 0 0
Laboratory or Batch Control Spike Sample Duplicate (LCSD)
1 per fraction3 0 0 0 0
Media Blanks 1 set4 0 0 0 0 Isotope Dilution Internal Standard Spikes Each sample 0 0 0 0 Total No of Samples 75 3 3 3 3
Key 1 Sample collected in field 2 Trip blanks include one XAD-2 resin module and one methanol sample per sample shipment 3 Lab blank and LCSLCSD includes one set per analytical fraction (front half back half and condensate) 4 One set of media blank archived at laboratory at media preparation 5 Actual number of samples collected in field 6 Not applicable
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program
511 Pre-Test Determinations
Preliminary test data were obtained at the test location Stack geometry measurements were
measured and recorded and traverse point distances verified A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was
estimated by wet bulbdry bulb temperature measurements
A check for the presence or absence of cyclonic flow was previously conducted at the test
location The cyclonic flow checks were negative (lt 20deg) verifying that the source was
acceptable for testing
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures
Calibration of probe nozzles pitot tubes metering systems and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures
52 STACK PARAMETERS
521 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling was an EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle that attached directly to a heated borosilicate probe In order to minimize possible thermal degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack temperature to minimize water vapor condensation before the filter The probe was connected directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
6 DETAILED TEST RESULTS AND DISCUSSION 15 APPENDIX A PROCESS OPERATIONS DATA APPENDIX B RAW AND REDUCED TEST DATA APPENDIX C LABORATORY ANALYTICAL REPORT APPENDIX D SAMPLE CALCULATIONS APPENDIX E EQUIPMENT CALIBRATION RECORDS APPENDIX F LIST OF PROJECT PARTICIPANTS
IASDATACHEMOURS15418002017POLYMERS REPORT SEPT 2019-AMD 10252019 ii
LIST OF FIGURES
Title Page
Figure 4-1 Polymers Stack Test Port and Traverse Point Locations 7
captured as HFPO Dimer Acid emission testing on the Polymers Stack Testing was performed
on 25-26 September 2019 and generally followed the ldquoEmission Test Protocolrdquo reviewed and
approved by the North Carolina Department of Environmental Quality (NCDEQ) This report
provides the results from the emission test program
12 TEST OBJECTIVES
The specific objectives for this test program were as follows
Measure the emissions concentrations and mass emissions rates of HFPO Dimer Acid Fluoride from the Polymers stack which is located in the IXM processes
Monitor and record process data in conjunction with the test program Provide representative emissions data
13 TEST PROGRAM OVERVIEW
During the emissions test program the concentrations and mass emissions rates of HFPO Dimer
Acid Fluoride were measured on the Polymers stack
Table 1-1 provides a summary of the test location and the parameters that were measured along
with the samplinganalytical procedures that were followed
Sampling Point amp Location Polymers Stack Number of Tests 3 Parameters To Be Tested HFPO Dimer
Acid Fluoride (HFPO-DAF)
Volumetric Flow Rate and Gas Velocity
Carbon Dioxide
Oxygen Water Content
Sampling or Monitoring Method EPA M-0010 EPA M1 and M2 in
conjunction with M-0010
tests
EPA M33A EPA M4 in conjunction
with M-0010 tests
Sample Extraction Analysis Method(s) LCMSMS NA6 NA NA Sample Size gt 1m3 NA NA NA NA Total Number of Samples Collected1 3 3 3 3 3 Reagent Blanks (Solvents Resins)1 1 set 0 0 0 0 Field Blank Trains1 1 per source 0 0 0 0 Proof Blanks1 1 per train 0 0 0 0 Trip Blanks12 1 set 0 0 0 Lab Blanks 1 per fraction3 0 0 0 0 Laboratory or Batch Control Spike Samples (LCS)
1 per fraction3 0 0 0 0
Laboratory or Batch Control Spike Sample Duplicate (LCSD)
1 per fraction3 0 0 0 0
Media Blanks 1 set4 0 0 0 0 Isotope Dilution Internal Standard Spikes Each sample 0 0 0 0 Total No of Samples 75 3 3 3 3
Key 1 Sample collected in field 2 Trip blanks include one XAD-2 resin module and one methanol sample per sample shipment 3 Lab blank and LCSLCSD includes one set per analytical fraction (front half back half and condensate) 4 One set of media blank archived at laboratory at media preparation 5 Actual number of samples collected in field 6 Not applicable
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program
511 Pre-Test Determinations
Preliminary test data were obtained at the test location Stack geometry measurements were
measured and recorded and traverse point distances verified A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was
estimated by wet bulbdry bulb temperature measurements
A check for the presence or absence of cyclonic flow was previously conducted at the test
location The cyclonic flow checks were negative (lt 20deg) verifying that the source was
acceptable for testing
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures
Calibration of probe nozzles pitot tubes metering systems and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures
52 STACK PARAMETERS
521 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling was an EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle that attached directly to a heated borosilicate probe In order to minimize possible thermal degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack temperature to minimize water vapor condensation before the filter The probe was connected directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
captured as HFPO Dimer Acid emission testing on the Polymers Stack Testing was performed
on 25-26 September 2019 and generally followed the ldquoEmission Test Protocolrdquo reviewed and
approved by the North Carolina Department of Environmental Quality (NCDEQ) This report
provides the results from the emission test program
12 TEST OBJECTIVES
The specific objectives for this test program were as follows
Measure the emissions concentrations and mass emissions rates of HFPO Dimer Acid Fluoride from the Polymers stack which is located in the IXM processes
Monitor and record process data in conjunction with the test program Provide representative emissions data
13 TEST PROGRAM OVERVIEW
During the emissions test program the concentrations and mass emissions rates of HFPO Dimer
Acid Fluoride were measured on the Polymers stack
Table 1-1 provides a summary of the test location and the parameters that were measured along
with the samplinganalytical procedures that were followed
Sampling Point amp Location Polymers Stack Number of Tests 3 Parameters To Be Tested HFPO Dimer
Acid Fluoride (HFPO-DAF)
Volumetric Flow Rate and Gas Velocity
Carbon Dioxide
Oxygen Water Content
Sampling or Monitoring Method EPA M-0010 EPA M1 and M2 in
conjunction with M-0010
tests
EPA M33A EPA M4 in conjunction
with M-0010 tests
Sample Extraction Analysis Method(s) LCMSMS NA6 NA NA Sample Size gt 1m3 NA NA NA NA Total Number of Samples Collected1 3 3 3 3 3 Reagent Blanks (Solvents Resins)1 1 set 0 0 0 0 Field Blank Trains1 1 per source 0 0 0 0 Proof Blanks1 1 per train 0 0 0 0 Trip Blanks12 1 set 0 0 0 Lab Blanks 1 per fraction3 0 0 0 0 Laboratory or Batch Control Spike Samples (LCS)
1 per fraction3 0 0 0 0
Laboratory or Batch Control Spike Sample Duplicate (LCSD)
1 per fraction3 0 0 0 0
Media Blanks 1 set4 0 0 0 0 Isotope Dilution Internal Standard Spikes Each sample 0 0 0 0 Total No of Samples 75 3 3 3 3
Key 1 Sample collected in field 2 Trip blanks include one XAD-2 resin module and one methanol sample per sample shipment 3 Lab blank and LCSLCSD includes one set per analytical fraction (front half back half and condensate) 4 One set of media blank archived at laboratory at media preparation 5 Actual number of samples collected in field 6 Not applicable
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program
511 Pre-Test Determinations
Preliminary test data were obtained at the test location Stack geometry measurements were
measured and recorded and traverse point distances verified A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was
estimated by wet bulbdry bulb temperature measurements
A check for the presence or absence of cyclonic flow was previously conducted at the test
location The cyclonic flow checks were negative (lt 20deg) verifying that the source was
acceptable for testing
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures
Calibration of probe nozzles pitot tubes metering systems and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures
52 STACK PARAMETERS
521 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling was an EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle that attached directly to a heated borosilicate probe In order to minimize possible thermal degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack temperature to minimize water vapor condensation before the filter The probe was connected directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
captured as HFPO Dimer Acid emission testing on the Polymers Stack Testing was performed
on 25-26 September 2019 and generally followed the ldquoEmission Test Protocolrdquo reviewed and
approved by the North Carolina Department of Environmental Quality (NCDEQ) This report
provides the results from the emission test program
12 TEST OBJECTIVES
The specific objectives for this test program were as follows
Measure the emissions concentrations and mass emissions rates of HFPO Dimer Acid Fluoride from the Polymers stack which is located in the IXM processes
Monitor and record process data in conjunction with the test program Provide representative emissions data
13 TEST PROGRAM OVERVIEW
During the emissions test program the concentrations and mass emissions rates of HFPO Dimer
Acid Fluoride were measured on the Polymers stack
Table 1-1 provides a summary of the test location and the parameters that were measured along
with the samplinganalytical procedures that were followed
Sampling Point amp Location Polymers Stack Number of Tests 3 Parameters To Be Tested HFPO Dimer
Acid Fluoride (HFPO-DAF)
Volumetric Flow Rate and Gas Velocity
Carbon Dioxide
Oxygen Water Content
Sampling or Monitoring Method EPA M-0010 EPA M1 and M2 in
conjunction with M-0010
tests
EPA M33A EPA M4 in conjunction
with M-0010 tests
Sample Extraction Analysis Method(s) LCMSMS NA6 NA NA Sample Size gt 1m3 NA NA NA NA Total Number of Samples Collected1 3 3 3 3 3 Reagent Blanks (Solvents Resins)1 1 set 0 0 0 0 Field Blank Trains1 1 per source 0 0 0 0 Proof Blanks1 1 per train 0 0 0 0 Trip Blanks12 1 set 0 0 0 Lab Blanks 1 per fraction3 0 0 0 0 Laboratory or Batch Control Spike Samples (LCS)
1 per fraction3 0 0 0 0
Laboratory or Batch Control Spike Sample Duplicate (LCSD)
1 per fraction3 0 0 0 0
Media Blanks 1 set4 0 0 0 0 Isotope Dilution Internal Standard Spikes Each sample 0 0 0 0 Total No of Samples 75 3 3 3 3
Key 1 Sample collected in field 2 Trip blanks include one XAD-2 resin module and one methanol sample per sample shipment 3 Lab blank and LCSLCSD includes one set per analytical fraction (front half back half and condensate) 4 One set of media blank archived at laboratory at media preparation 5 Actual number of samples collected in field 6 Not applicable
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program
511 Pre-Test Determinations
Preliminary test data were obtained at the test location Stack geometry measurements were
measured and recorded and traverse point distances verified A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was
estimated by wet bulbdry bulb temperature measurements
A check for the presence or absence of cyclonic flow was previously conducted at the test
location The cyclonic flow checks were negative (lt 20deg) verifying that the source was
acceptable for testing
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures
Calibration of probe nozzles pitot tubes metering systems and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures
52 STACK PARAMETERS
521 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling was an EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle that attached directly to a heated borosilicate probe In order to minimize possible thermal degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack temperature to minimize water vapor condensation before the filter The probe was connected directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
captured as HFPO Dimer Acid emission testing on the Polymers Stack Testing was performed
on 25-26 September 2019 and generally followed the ldquoEmission Test Protocolrdquo reviewed and
approved by the North Carolina Department of Environmental Quality (NCDEQ) This report
provides the results from the emission test program
12 TEST OBJECTIVES
The specific objectives for this test program were as follows
Measure the emissions concentrations and mass emissions rates of HFPO Dimer Acid Fluoride from the Polymers stack which is located in the IXM processes
Monitor and record process data in conjunction with the test program Provide representative emissions data
13 TEST PROGRAM OVERVIEW
During the emissions test program the concentrations and mass emissions rates of HFPO Dimer
Acid Fluoride were measured on the Polymers stack
Table 1-1 provides a summary of the test location and the parameters that were measured along
with the samplinganalytical procedures that were followed
Sampling Point amp Location Polymers Stack Number of Tests 3 Parameters To Be Tested HFPO Dimer
Acid Fluoride (HFPO-DAF)
Volumetric Flow Rate and Gas Velocity
Carbon Dioxide
Oxygen Water Content
Sampling or Monitoring Method EPA M-0010 EPA M1 and M2 in
conjunction with M-0010
tests
EPA M33A EPA M4 in conjunction
with M-0010 tests
Sample Extraction Analysis Method(s) LCMSMS NA6 NA NA Sample Size gt 1m3 NA NA NA NA Total Number of Samples Collected1 3 3 3 3 3 Reagent Blanks (Solvents Resins)1 1 set 0 0 0 0 Field Blank Trains1 1 per source 0 0 0 0 Proof Blanks1 1 per train 0 0 0 0 Trip Blanks12 1 set 0 0 0 Lab Blanks 1 per fraction3 0 0 0 0 Laboratory or Batch Control Spike Samples (LCS)
1 per fraction3 0 0 0 0
Laboratory or Batch Control Spike Sample Duplicate (LCSD)
1 per fraction3 0 0 0 0
Media Blanks 1 set4 0 0 0 0 Isotope Dilution Internal Standard Spikes Each sample 0 0 0 0 Total No of Samples 75 3 3 3 3
Key 1 Sample collected in field 2 Trip blanks include one XAD-2 resin module and one methanol sample per sample shipment 3 Lab blank and LCSLCSD includes one set per analytical fraction (front half back half and condensate) 4 One set of media blank archived at laboratory at media preparation 5 Actual number of samples collected in field 6 Not applicable
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program
511 Pre-Test Determinations
Preliminary test data were obtained at the test location Stack geometry measurements were
measured and recorded and traverse point distances verified A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was
estimated by wet bulbdry bulb temperature measurements
A check for the presence or absence of cyclonic flow was previously conducted at the test
location The cyclonic flow checks were negative (lt 20deg) verifying that the source was
acceptable for testing
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures
Calibration of probe nozzles pitot tubes metering systems and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures
52 STACK PARAMETERS
521 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling was an EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle that attached directly to a heated borosilicate probe In order to minimize possible thermal degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack temperature to minimize water vapor condensation before the filter The probe was connected directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Sampling Point amp Location Polymers Stack Number of Tests 3 Parameters To Be Tested HFPO Dimer
Acid Fluoride (HFPO-DAF)
Volumetric Flow Rate and Gas Velocity
Carbon Dioxide
Oxygen Water Content
Sampling or Monitoring Method EPA M-0010 EPA M1 and M2 in
conjunction with M-0010
tests
EPA M33A EPA M4 in conjunction
with M-0010 tests
Sample Extraction Analysis Method(s) LCMSMS NA6 NA NA Sample Size gt 1m3 NA NA NA NA Total Number of Samples Collected1 3 3 3 3 3 Reagent Blanks (Solvents Resins)1 1 set 0 0 0 0 Field Blank Trains1 1 per source 0 0 0 0 Proof Blanks1 1 per train 0 0 0 0 Trip Blanks12 1 set 0 0 0 Lab Blanks 1 per fraction3 0 0 0 0 Laboratory or Batch Control Spike Samples (LCS)
1 per fraction3 0 0 0 0
Laboratory or Batch Control Spike Sample Duplicate (LCSD)
1 per fraction3 0 0 0 0
Media Blanks 1 set4 0 0 0 0 Isotope Dilution Internal Standard Spikes Each sample 0 0 0 0 Total No of Samples 75 3 3 3 3
Key 1 Sample collected in field 2 Trip blanks include one XAD-2 resin module and one methanol sample per sample shipment 3 Lab blank and LCSLCSD includes one set per analytical fraction (front half back half and condensate) 4 One set of media blank archived at laboratory at media preparation 5 Actual number of samples collected in field 6 Not applicable
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program
511 Pre-Test Determinations
Preliminary test data were obtained at the test location Stack geometry measurements were
measured and recorded and traverse point distances verified A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was
estimated by wet bulbdry bulb temperature measurements
A check for the presence or absence of cyclonic flow was previously conducted at the test
location The cyclonic flow checks were negative (lt 20deg) verifying that the source was
acceptable for testing
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures
Calibration of probe nozzles pitot tubes metering systems and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures
52 STACK PARAMETERS
521 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling was an EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle that attached directly to a heated borosilicate probe In order to minimize possible thermal degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack temperature to minimize water vapor condensation before the filter The probe was connected directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Sampling Point amp Location Polymers Stack Number of Tests 3 Parameters To Be Tested HFPO Dimer
Acid Fluoride (HFPO-DAF)
Volumetric Flow Rate and Gas Velocity
Carbon Dioxide
Oxygen Water Content
Sampling or Monitoring Method EPA M-0010 EPA M1 and M2 in
conjunction with M-0010
tests
EPA M33A EPA M4 in conjunction
with M-0010 tests
Sample Extraction Analysis Method(s) LCMSMS NA6 NA NA Sample Size gt 1m3 NA NA NA NA Total Number of Samples Collected1 3 3 3 3 3 Reagent Blanks (Solvents Resins)1 1 set 0 0 0 0 Field Blank Trains1 1 per source 0 0 0 0 Proof Blanks1 1 per train 0 0 0 0 Trip Blanks12 1 set 0 0 0 Lab Blanks 1 per fraction3 0 0 0 0 Laboratory or Batch Control Spike Samples (LCS)
1 per fraction3 0 0 0 0
Laboratory or Batch Control Spike Sample Duplicate (LCSD)
1 per fraction3 0 0 0 0
Media Blanks 1 set4 0 0 0 0 Isotope Dilution Internal Standard Spikes Each sample 0 0 0 0 Total No of Samples 75 3 3 3 3
Key 1 Sample collected in field 2 Trip blanks include one XAD-2 resin module and one methanol sample per sample shipment 3 Lab blank and LCSLCSD includes one set per analytical fraction (front half back half and condensate) 4 One set of media blank archived at laboratory at media preparation 5 Actual number of samples collected in field 6 Not applicable
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program
511 Pre-Test Determinations
Preliminary test data were obtained at the test location Stack geometry measurements were
measured and recorded and traverse point distances verified A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was
estimated by wet bulbdry bulb temperature measurements
A check for the presence or absence of cyclonic flow was previously conducted at the test
location The cyclonic flow checks were negative (lt 20deg) verifying that the source was
acceptable for testing
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures
Calibration of probe nozzles pitot tubes metering systems and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures
52 STACK PARAMETERS
521 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling was an EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle that attached directly to a heated borosilicate probe In order to minimize possible thermal degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack temperature to minimize water vapor condensation before the filter The probe was connected directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program
511 Pre-Test Determinations
Preliminary test data were obtained at the test location Stack geometry measurements were
measured and recorded and traverse point distances verified A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was
estimated by wet bulbdry bulb temperature measurements
A check for the presence or absence of cyclonic flow was previously conducted at the test
location The cyclonic flow checks were negative (lt 20deg) verifying that the source was
acceptable for testing
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures
Calibration of probe nozzles pitot tubes metering systems and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures
52 STACK PARAMETERS
521 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling was an EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle that attached directly to a heated borosilicate probe In order to minimize possible thermal degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack temperature to minimize water vapor condensation before the filter The probe was connected directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program
511 Pre-Test Determinations
Preliminary test data were obtained at the test location Stack geometry measurements were
measured and recorded and traverse point distances verified A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was
estimated by wet bulbdry bulb temperature measurements
A check for the presence or absence of cyclonic flow was previously conducted at the test
location The cyclonic flow checks were negative (lt 20deg) verifying that the source was
acceptable for testing
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures
Calibration of probe nozzles pitot tubes metering systems and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures
52 STACK PARAMETERS
521 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling was an EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle that attached directly to a heated borosilicate probe In order to minimize possible thermal degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack temperature to minimize water vapor condensation before the filter The probe was connected directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program
511 Pre-Test Determinations
Preliminary test data were obtained at the test location Stack geometry measurements were
measured and recorded and traverse point distances verified A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was
estimated by wet bulbdry bulb temperature measurements
A check for the presence or absence of cyclonic flow was previously conducted at the test
location The cyclonic flow checks were negative (lt 20deg) verifying that the source was
acceptable for testing
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures
Calibration of probe nozzles pitot tubes metering systems and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures
52 STACK PARAMETERS
521 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling was an EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle that attached directly to a heated borosilicate probe In order to minimize possible thermal degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack temperature to minimize water vapor condensation before the filter The probe was connected directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program
511 Pre-Test Determinations
Preliminary test data were obtained at the test location Stack geometry measurements were
measured and recorded and traverse point distances verified A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was
estimated by wet bulbdry bulb temperature measurements
A check for the presence or absence of cyclonic flow was previously conducted at the test
location The cyclonic flow checks were negative (lt 20deg) verifying that the source was
acceptable for testing
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures
Calibration of probe nozzles pitot tubes metering systems and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures
52 STACK PARAMETERS
521 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling was an EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle that attached directly to a heated borosilicate probe In order to minimize possible thermal degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack temperature to minimize water vapor condensation before the filter The probe was connected directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program
511 Pre-Test Determinations
Preliminary test data were obtained at the test location Stack geometry measurements were
measured and recorded and traverse point distances verified A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was
estimated by wet bulbdry bulb temperature measurements
A check for the presence or absence of cyclonic flow was previously conducted at the test
location The cyclonic flow checks were negative (lt 20deg) verifying that the source was
acceptable for testing
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures
Calibration of probe nozzles pitot tubes metering systems and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures
52 STACK PARAMETERS
521 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling was an EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle that attached directly to a heated borosilicate probe In order to minimize possible thermal degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack temperature to minimize water vapor condensation before the filter The probe was connected directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two impingers that contained 100 mL of high purity distilled water The train also included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the condensate traps were maintained in an ice bath Ice water was continuously circulated in the condenser and the XAD-2 module to maintain method-required temperature A control console with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected to the final impinger via an umbilical cord to complete the sample train
HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO Dimer Acid Fluoride undergoes hydrolysis instantaneously in water in the sampling train and during the sample recovery step and will be converted to HFPO Dimer Acid such that the amount of HFPO Dimer Acid emissions represents a combination of both HFPO Dimer Acid Fluoride and HFPO Dimer Acid
During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube into the gas stream adjacent to the sampling nozzle The velocity pressure differential was observed immediately after positioning the nozzle at each traverse point and the sampling rate adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each traverse point during all test periods as appropriate Leak checks were performed on the sampling apparatus according to reference method instructions prior to and following each run component change (if required) or during midpoint port changes
522 EPA Method 0010 Sample Recovery
At the conclusion of each test the sampling train was dismantled the openings sealed and the
components transported to the field laboratory trailer for recovery
A consistent procedure was employed for sample recovery
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled
2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments
3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed
4 The volume of liquid collected in the first condensate trap was measured the value
recorded and the contents poured into a polyethylene container
5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed
6 The volume of liquid in the impingers one two and second condensate trap were
measured the values recorded and sample was placed in the same container as Step 4 above then sealed
7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed
8 The silica gel in the final impinger was weighed and the weight gain value recorded
9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter
and distilled water were retained for analysis Each container was labeled to clearly identify its contents The height of the fluid level was
marked on the container of each liquid sample to provide a reference point for a leakage check
during transport All samples were maintained cool
During each test campaign an M-0010 blank train was setup near the test location leak checked
and recovered along with the respective sample train Following sample recovery all samples
were transported to Eurofins TestAmerica (TestAmerica) for sample extraction and analysis
See Figure 5-2 for a schematic of the M-0010 sample recovery process
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Stack gas stream composition (carbon dioxide and oxygen concentrations) was determined utilizing EPA Method 33A and also in combination with Method 0010 procedures discussed in the previous sections
The fixed gases (carbon dioxide and oxygen) sampling train was utilized in accordance with the EPA Reference Method 3 specifications The fixed gases were collected utilizing a diaphragm pump with a flow rotometer and Tedlarreg sample bag
The gas stream composition samples were collected from the exhaust of the control console calibrated orifice at a constant rate of ~05 liters per minute This provided an integrated conditioned (dry) sample The gas passing through the control console orifice was conditioned by the impinger train The sample was integrated with respect to time and location in the stack
Analysis of the Tedlarreg bag samples were performed using EPA Reference Method 3A analytical procedures The conditioned Tedlarreg bag samples were analyzed by calibrated analyzers such as a paramagnetic O2 analyzer and a non-dispersive infrared (NDIR) CO2 analyzer The O2 and CO2 analyzers were configured and calibrated in accordance with the gas analyzer requirements outlined in EPA Reference Method 3A The dry molecular weight of the gas stream was calculated using the measured oxygen and carbon dioxide concentrations The balance of the gas stream was assumed to be nitrogen The dry molecular weight of the gas stream was used to calculate the stack gas volumetric flow rate
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Each test was a minimum of 96 minutes in duration A total of three test runs were performed on
the Polymers Stack
Table 6-1 provides detailed test data and test results for the Polymers Stack
The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all
calculations
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
10222019 1227 PM
16
Sept polymers
TABLE 6-1CHEMOURS - FAYETTEVILLE NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSPOLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245
SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0215 0235 0235Cross sectional nozzle area sqft 0000252 0000301 0000301Barometric pressure in Hg 2972 2981 2981Avg orifice press diff in H2O 075 134 145Avg dry gas meter temp deg F 923 766 808Avg abs dry gas meter temp deg R 552 537 541Total liquid collected by train ml 182 304 333Std vol of H2O vapor coll cuft 09 14 157Dry gas meter calibration factor 10069 10069 10069Sample vol at meter cond dcf 45585 57848 60409Sample vol at std cond dscf (1) 43654 57271 59353Percent of isokinetic sampling 978 951 954
GAS STREAM COMPOSITION DATACO2 by volume dry basis 00 00 00O2 by volume dry basis 209 209 209 N2 by volume dry basis 791 791 791 Molecular wt of dry gas lblb mole 2884 2884 2884H20 vapor in gas stream prop by vol 0019 0024 0026Mole fraction of dry gas 0981 0976 0974Molecular wt of wet gas lblb mole 2863 2857 2856
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O -005 -016 -020Absolute pressure in Hg 2972 2980 2980Avg temperature deg F 82 78 79Avg absolute temperature degR 542 538 539Pitot tube coefficient 084 084 084Total number of traverse points 24 24 24Avg gas stream velocity ftsec 324 364 377Stackduct cross sectional area sqft 491 491 491Avg gas stream volumetric flow wacfmin 9549 10729 11114Avg gas stream volumetric flow dscfmin 9055 10226 10565
(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)
10222019 201 PM
17Sept polymers
TEST DATA Run number 1 2 3 Location Polymers Stack Polymers Stack Polymers Stack Date 092519 092619 092619 Time period 1300-1648 0833-1023 1100-1245
LABORATORY REPORT DATA ugHFPO Dimer Acid 542 633 957
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
21
10222019 1227 PM Sept polymers
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
10222019 1227 PM Sept polymers
CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS
POLYMERS STACK
Test DataRun number 1 2 3Location Polymers Stack Polymers Stack Polymers StackDate 092519 092619 092619Time period 1300-1648 0833-1023 1100-1245Operator MW MW MW
Inputs For CalcsSq rt delta P 056541 063797 066024Delta H 07463 13400 14541Stack temp (degF) 822 780 787Meter temp (degF) 923 766 808Sample volume (act) 45585 57848 60409Barometric press (inHg) 2972 2981 2981Volume H2O imp (ml) 60 100 200Weight change sil gel (g) 122 204 133 CO2 00 00 00 O2 209 209 209 N2 791 791 791Area of stack (sqft) 4910 4910 4910Sample time (min) 96 96 96Static pressure (inH2O) -005 -016 -020Nozzle dia (in) 0215 0235 0235Meter box cal 10069 10069 10069Cp of pitot tube 084 084 084Traverse points 24 24 24
2222
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Diener Acid client Ghertwurs Stack Conditions nneter eox io owo ~5a~aoo2pt~ Assumed Actual Metersox r p Project ID Chemours Moisture ~ Meter Box Del H ~ a~ 131odeSource ID Polymer Impinger Vol (ml) ~ t ~~t~ r Probe ID Length Sample Train (ft3) Samp Lce ID STK SiNca gel (g) ~~~~ P~be Material Bo Leak Check (in Hg) Run NoID 1 CO2 by Vol ~ PitotThermocouple ID ~ Pitot leak check good Test Method ID M0010 02 by Vol Pitot Coefflcfent 8 Pitot Inspection good Date ID 9SEP2019 Temperature (degF) i NoaJe ID Method 3 System good
Pagel of
K Factor 3~
Initial Mid-Point Final
~~~~~~
SourceLocaUon Polyme Stack Meter Temp (F) ~ NoaJe Measurements S ~ j Temp Check fe- eS ~et 0 ~ eS 8 Sample Date ~ Static Press (in HZO) - Avg NonJe Dia (in) v ~ Meter Box Temp Baro Press (in L it Area of Stack (ftZ) Reference Temp Operator ~ ~ Ambient Temp (degF) ~t ~ (7 Sample Time C) PassfFail (+- 2deg) ~ s Fail Fafl
Total Traverse Pts L( Temp Change Response i yes flo ves no
1 ~ r
~~~~ ~~ ~~c~~~~~~r~ of r ~~~~-~~~~~~ ~~rs~c~z ~~~~~~rn~rr~~~~~i~~ - ~i~~~~~i]fTr31~C~ ~~~~~i -bullIl3i~lSi0iL~~
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - H ~ O Diener Acid Page~or client wo
Chemours Stack Conditions Assumed Actual
Metar Box ID Meter sox v K Factor 3 ~ Z 1sa~aoo20~7
Project ID cnemours ^io nnoisture ~ ~yt Meter sox Lei H L Initial Mid-Point Final ModelSource ID Polymer Impinger Vol (ml) ~M ~ Probe ID Length Sample Train (ft) ~ 1
Samp Loc ID STK Silica gel (g) ~~ bull g ~ ~
Probe Material Borg Leak Check Q (in Hg) ~f Run NoID 2
r yt~ CO2 by Vol ~bdquor+ y Pftot Thermocouple ID ~ Pitot leak check good no ~ rq ~p
Test Method ID M0010 02 deg~ by Vol ~ Pitot Coefficient 084 Pitot Inspection good ~o l no J no Date ID 9SEP2019 Temperature (degF) ~~-
~ Noale ID 3 Method 3 System good yes - yeq t np yss ~p
SourceLocation Polymer $tack Meter Temp (F) ~ NoaJe Measurements ZS Z3$~ 1Z S~femp Check re-Test et POSt- BSt et Sample Date L ~ ~ Static Press Qn HZO) ~- Avg NoaJe Dia (In) 23 ~ Meter Box Temp Baro Press (in ) p~ ~ 1 Area of Stack (Hz) Reference Temp Operator iy~~ Ambient Temp (degF) yh ~ ~ Sample Time ~ PassFail (+- pdeg) ~ ass Fail Fell
Total Traverse Pts L ~ Temp Change Response i yes no yes no
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
t y ~
ISOHINETIC FIELD DATA SHEET client Chemours Stack Conditions wo ~saleoo20~~ Assumed Project ID Chemours Moisture ModeSource ID Polymer Impinger Vol (ml) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Test Method ID M0010 02 deg by Vol Date ID 9SEP2019 Temperature (degF) SouroelLocation Polymer $tack Meter Temp (F)
EPA Method 0010 - HF O Dimer Acid Page ~ orb Meter eox io
K Factor 3 I Actual Meter eox r ~ Meter Box Del H L Initial Mid-Point Final Probe ID Length ~ Sample Train (ft3) Probe Material Boro Leak Check Q (in Hg) Pitot Thermocouple ID Pitot leak check good Pitot Coefficient 084 Pitot Inspection good
~ ~r~ ~~ ~~ c~~~r~
~~~~~~~~ is ~_ ~~ NoaJe ID $ Method 3 System good
~i Noale Measurements ~ ~ j j ~ Temp Check ~fe- I se i bet F o f I eS 8 ~y Avg NoaJe Dia (in) ~ Meter Box Temp 7
Area of Stack (ft2) Reference Temp ~~ Sample Time PasslFail (+- pdeg~ Pass Fall Fall
Total Traverse Pts Temp Change Response i no yes no
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
ANALYTICAL REPORTJob Number 140-16785-1
Job Description Polymer Stack - M0010
Contract Number LBIO-67048
ForChemours Company FC LLC The
co AECOMSabre Building Suite 300
4051 Ogletown RoadNewark DE 19713
Attention Michael Aucoin
_____________________________________________
Approved for releaseCourtney M AdkinsProject Manager I1092019 827 AM
Courtney M Adkins Project Manager I5815 Middlebrook Pike Knoxville TN 37921
(865)291-3000 courtneyadkinstestamericainccom
10092019
This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager
This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature
Eurofins TestAmerica Knoxville
5815 Middlebrook Pike Knoxville TN 37921
Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom
10092019Page 1 of 2083030
Table of ContentsCover Title Page 1
Data Summaries 4
Definitions 4
Method Summary 5
Sample Summary 6
Case Narrative 7
QC Association 8
Client Sample Results 10
Default Detection Limits 13
Surrogate Summary 14
QC Sample Results 15
Chronicle 17
Certification Summary 22
Manual Integration Summary 24
Organic Sample Data 26
LCMS 26
8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 32Standards Data 44
8321A_HFPO_Du ICAL Data 448321A_HFPO_Du CCAL Data 67
Raw QC Data 798321A_HFPO_Du Blank Data 798321A_HFPO_Du LCSLCSD Data 91
8321A_HFPO_Du Run Logs 100
10092019Page 2 of 2083131
Table of Contents8321A_HFPO_Du Prep Data 102
Method DV-LC-0012 107Method DV-LC-0012 QC Summary 108Method DV-LC-0012 Sample Data 114Standards Data 151
Method DV-LC-0012 CCAL Data 151Raw QC Data 169
Method DV-LC-0012 Tune Data 169Method DV-LC-0012 Blank Data 174Method DV-LC-0012 LCSLCSD Data 186
Method DV-LC-0012 Run Logs 194Method DV-LC-0012 Prep Data 196
Shipping and Receiving Documents 202
Client Chain of Custody 203
10092019Page 3 of 2083232
DefinitionsGlossaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Qualifiers
LCMSQualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report
curren Listed under the D column to designate that the result is reported on a dry weight basis
Abbreviation
R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoDDOE)
DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
Job Narrative140-16785-1
Sample Receipt
The samples were received on September 27 2019 at 1035 AM in good condition and properly preserved The temperature of the cooler at receipt was 06ordm C
Quality Control and Data Interpretation
Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements
Method 0010Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample
LCMS
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Organic Prep
No analytical or quality issues were noted other than those described in the DefinitionsGlossary page
Comments
Reporting Limits (RLs) and Method Detection Limits (MDLs) for the HFPO-DA used in this report were derived in Denver for reporting soils and water samples Method 0010 sampling train matrix specific RLs and MDLs have not been established for HFPO-DA The soil and water limits are expected to be reasonable approximations of the actual matrix specific limits under these conditions
Breakthrough from the Modified Method 0010 Sampling Train for PFAS compounds will be measured by the percentage ()
concentration of a specific PFAS target analyte determined to be present in the Breakthrough XAD-2 resin module of a test run If the
concentration of a specific PFAS compound is le30 of the sum of the concentrations determined for the other three (3) fractions of the
sampling train then sampling breakthrough is determined not to have occurred Also no breakthrough will be determined to have
occurred if lt 250 microg of a target analyte is collected on all fractions of a sampling train Breakthrough the sampling train implies that
sample loss through the train has occurred and results in a negative bias to the sample results
10092019Page 7 of 2083636
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA
Prep Batch 472296
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air None140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air None140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air None140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air None140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air NoneMB 280-4722961-A Method Blank TotalNA
Air NoneLCS 280-4722962-A Lab Control Sample TotalNA
Prep Batch 472321
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air None140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air None140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air NoneMB 280-47232113-A Method Blank TotalNA
Air NoneMB 280-4723211-A Method Blank TotalNA
Air NoneLCS 280-4723212-A Lab Control Sample TotalNA
Prep Batch 472332
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air None140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air NoneMB 280-47233213-A Method Blank TotalNA
Air NoneMB 280-4723321-A Method Blank TotalNA
Air NoneLCS 280-4723322-A Lab Control Sample TotalNA
Analysis Batch 472874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472296140-16785-2 D-230323042306 R1 M0010 BH TotalNA
Air 8321A 472296140-16785-4 D-2307 R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-6 D-231023112313 R2 M0010 BH TotalNA
Air 8321A 472296140-16785-8 D-2314 R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296140-16785-10 D-231723182320 R3 M0010 BH TotalNA
Air 8321A 472296140-16785-12 D-2321 R3 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA
Air 8321A 472296MB 280-4722961-A Method Blank TotalNA
Air 8321A 472296LCS 280-4722962-A Lab Control Sample TotalNA
Analysis Batch 472875
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472321140-16785-1 D-23012302 R1 M0010 FH TotalNA
Air 8321A 472321140-16785-5 D-23082309 R2 M0010 FH TotalNA
Air 8321A 472321140-16785-9 D-23152316 R3 M0010 FH TotalNA
Air 8321A 472321MB 280-47232113-A Method Blank TotalNA
Air 8321A 472321MB 280-4723211-A Method Blank TotalNA
Air 8321A 472321LCS 280-4723212-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 8 of 2083737
QC Association SummaryJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
LCMS
Analysis Batch 472876
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 472332140-16785-3 D-2305 R1 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-7 D-2312 R2 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332140-16785-11 D-2319 R3 M0010 IMP 12amp3 CONDENSATE TotalNA
Air 8321A 472332MB 280-47233213-A Method Blank TotalNA
Air 8321A 472332MB 280-4723321-A Method Blank TotalNA
Air 8321A 472332LCS 280-4723322-A Lab Control Sample TotalNA
Eurofins TestAmerica Knoxville
10092019Page 9 of 2083838
Client Sample ResultsJob ID 140-16785-1Client Chemours Company FC LLC The
ProjectSite Polymer Stack - M0010
Lab Sample ID 140-16785-1Client Sample ID D-23012302 R1 M0010 FHMatrix AirDate Collected 092519 0000
Date Received 092719 1035Sample Container Air Train
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf
Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf
Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O
Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor
1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg
136 = Specific gravity of mercury
2 Volume of water vapor in the gas sample corrected to standard conditions scf
Vw(std) = (004707 x Vwc) + (004715 x Wwsg)
Vw(std) = ( 004707 x 200 ) + ( 004715 x 133 ) = 157
Where
Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf
Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g
004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml
004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g
4646
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
1092019240 PM Sept polymers
3 Moisture content
Vw(std)bws = -------------------------
Vw(std) + Vm(std)
157bws = ------------------------- = 0026
157 + 59353
Where
bws = Proportion of water vapor by volume in the gasstream dimensionless
4 Mole fraction of dry gas
Md = 1 - bws
Md = 1 - 0026 = 0974
Where
Md = Mole fraction of dry gas dimensionless
5 Dry molecular weight of gas stream lblb-mole
MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )
MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))
MWd = 2884
Where
MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis
O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis
CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide
divided by 100
6 Actual molecular weight of gas stream (wet basis) lblb-mole
MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs = ( 2884 x 0974 ) +( 18 ( 1 - 0974 )) = 2856
Where
MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole
4747
1092019240 PM Sept polymers
7 Average velocity of gas stream at actual conditions ftsec
Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12
Ps x MWs
539Vs = 8549 x 084 x 066024 x ( -------------------- )^12 = 377
2980 x 2856Where
Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460
P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------
136delt p = Velocity head of stack in H2O
8 Average gas stream volumetric flow rate at actual conditions wacfmin
Qs(act) = 60 x Vs x As
Qs(act) = 60 x 377 x 491 = 11114
Where
Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin
As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes
9 Average gas stream dry volumetric flow rate at standard conditions dscfmin
PsQs(std) = 1764 x Md x ----- x Qs(act)
Ts
2980Qs(std) = 1764 x 0974 x -------------------- x 11114
5387
Qs(std) = 10565
Where
Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin
4848
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
1092019240 PM Sept polymers
10 Isokinetic variation calculated from intermediate values percent
17327 x Ts x Vm(std)I = -----------------------------------
Vs x O x Ps x Md x (Dn)2
17327 x 539 x 59353I = -------------------------------------------------- = 954
377 x 96 x 2980 x 0974 x (0235)^2Where
I = Percent of isokinetic samplingO = Total sampling time minutes
Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)
standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI79E15A00E4 Reference Number 160-401424145-1Cylinder Number CC157024 Cylinder Volume 1505 CFLaboratory 124 - Plumsteadville - PA Cylinder Pressure 2015 PSIGPGVP Number A12019 Valve Outlet 590Gas Code CO2O2BALN Certification Date Feb 26 2019
Expiration Date Feb 26 2027
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 061507 K014984 1394 CARBON DIOXIDENITROGEN 057 Jan 30 2024NTRM 16060507 CC401541 23204 OXYGENNITROGEN 02 Dec 24 2021
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
HORIBA VA5011 T5V6VU9P NDIR CO2 NDIR Feb 12 2019SIEMENS OXYMAT 61 S01062 O2 PARAMAGNETIC Feb 18 2019
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC6141 Easton RoadBldg 1Plumsteadville PA 18949Airgascom
Signature on file
Approved for Release Page 1 of 160-401424145-15151
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
CERTIFICATE OF ANALYSISGrade of Product EPA Protocol
Part Number E03NI62E15A0224 Reference Number 82-401288925-1Cylinder Number ALM047628 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Sep 04 2018
Expiration Date Sep 04 2026
Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted
Do Not Use This Cylinder below 100 psig ie 07 megapascals
ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay
CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date
NTRM 13060804 CC415400 2404 CARBON DIOXIDENITROGEN +- 06 May 16 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019
ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration
Horiba VIA 510-CO2-19GYCXEG NDIR Aug 09 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Aug 09 2018
Triad Data Available Upon Request
Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom
Signature on file
Approved for Release Page 1 of 82-401288925-15252
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
P-697 all in oneMOD
Pitot Tube Identification Number
Inspection Date 1518 Individual Conducting Inspection
Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS
Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB
Q1 and Q2 must be lt 10o
B1 or B2 must be lt 5o
Z must be lt 0125 inches
W must be lt 003125 inches
X must be gt 075 inches
Thermocouple meets the Distance Criteria in the adjacent figure
Impact Pressure Opening Plane is above the Nozzle Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample Nozzle and Pitot (X) - inches
Thermocouple meets the Distance Criteria in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from vertical A Tube- degrees (absolute) 0
0
08
Horizontal offset between A and B Tubes (Z) - inches
Vertical offset between A and B Tubes (W) - inches
0007
0018
PASSFAIL
Angle of B1 from vertical B Tube- degrees (absolute)
PASS
PASS
PASS
P-697PM
Angle of Q1 from vertical A Tube- degrees (absolute)
Angle of Q2 from vertical B Tube- degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS Cp is equal to 084
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
DtType S Pitot Tube
3 inch
34 inch
A B
Face Opening Planes
AB
AB
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
5353
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
Long Cal 12 9-10-18
Calibrator MDW Meter Box Number 12 Ambient Temp 72
Date 10-Sep-18 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 14244707
Setting
in H20 (∆H)
ft3
(Vw)ft3
(Vd)oF
(Tw)Outlet oF
(Tdo)Time min
(O) Y ∆H
885853 7500890822 7600
4969 7550892810 7600897795 7700
4985 7650898799 7700908810 780010011 7750
915870 7800925830 7900
9960 7850926870 7900936870 800010000 7950
10069 18812Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter
1 - Channel Temps must agree with +- 5oF or 3oC2 - Acceptable Temperature Difference less than 15
10048
21232
Average Temperature
Reading
Thermocouple Simulator (Accuracy +- 1oF)
Temp Difference 2
()
Temperature Reading from Individual Thermocouple Input 1
Channel Number
19137
Baro Press in Hg ( Pb)
19381
1915810094
10036
2996
9321832
Reference Temperature
Select TemperatureoC oF
30 100 730
20 100 730
15 100 730
17823
10 50 730 10071 18559
10097
Y - Ratio of accuracy of wet test meter to dry gas meter
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice Manometer
Wet Test Meter Dry gas Meter
Gas Volume
Calibration Results
5005 730
Dry Gas Meter
TemperaturesWet Test
Meter
∆H - Pressure differential across orifice
1260
91
1520
131
1070
( ) ( )
( )( ) 2
VwO460tw
460tdPbH03170H
460tw613
HPbVd
)460td(PbVwY
lowast+
lowast
+lowast
∆lowast=∆
+lowast
∆
+lowast
+lowastlowast=
( )( ) ( )( )( )
+
+minus+=
460FTempferenceRe460FTempTest460FTempferenceReDiffTemp o
oo
5454
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
The following WESTON employees participated in this project
Paul Meeter Senior Project Manager
Jeff OrsquoNeill Senior Project Manager
Matt Winkeler Team Member
Steve Rathfon Team Member
Kyle Schweitzer Team Member
57
ADP4FCDtmp
BLANK
ADPCBA6tmp
Calibration
ADPE867tmp
FIELD DATA CALCS
SemiVol Results
ADP1D9Dtmp
FIELD DATA INPUT
ADP7C1Ctmp
SEMIVOLCALC
Flow_Moist_ISO_Calc
ADP64CAtmp
SEMIVOLCALC
ADP52E0tmp
FIELD DATA INPUT
FIELD DATA CALCS
ADP7936tmp
SemiVol Results
Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN
POLYMERS STACKMETER BOX NO 129252019 + 9262019
Run 1 Run 2 Run 3
MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100
CO2 = Percent carbon dioxide by volume dry basis 00 00 00
Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 923 766 808
Tma = Ts + 460
Tma = 9225 + 460
Tma = 55225 53658 54083
Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury
delta H = Avg pressure drop across the orifice meter during sampling in H2O 075 134 145Pb = Barometric Pressure in Hg 2972 2981 2981
Pm = Pb + (delta H 136)
Pm = 2972 + ( 074625 136)
Pm = 2977 2991 2992
Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2
2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 45585 57848 60409
Y = Dry gas meter calibration factor (based on full calibration) 10069 10069 10069Delta H = Dry Gas meter orifice calibration coefficient in H2O 18812 18812 18812
avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 08601 11563 11991O = Total sampling time minutes 96 96 96
Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H
![Laurence W. McKeen, PhD - Pentasil Used in Medical Devices.pdf · of branched polymers include star polymers, comb polymers, brush polymers, dendronized polymers [1], ladders, and](https://static.documents.pub/doc/80x56/5fd30108783da00f76371237/laurence-w-mckeen-phd-pentasil-used-in-medical-devicespdf-of-branched-polymers.jpg)
