Kaliumhexacyanoferrat(III) Lösungen SECTION 1 ...

according to Regulation (EC) No 1907/2006

Safety Data SheetMORPHISTO GmbH

Kaliumhexacyanoferrat(III) Lösungen

Revision date: 13.02.2020 Product code: 11146_collect Page 1 of 7

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier

This MSDS covers the following products in all container sizes:

- REF: 11146.xxxxx – Kaliumhexacyanoferrat(III) 5% (Blutlaugensalz rot)



Further trade names

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

Use as laboratory reagent.

Any non-intended use.

Uses advised against

1.3. Details of the supplier of the safety data sheet

MORPHISTO GmbHCompany name:

Street: Weismüllerstr. 45

Place: D-60314 Frankfurt am Main

Telephone: Telefax:+49 (0) 69 / 400 3019-60 +49 (0) 69 / 400 3019-64

[email protected]:

http://www.morphisto.deInternet:

Poison Information Center Mainz, Germany, Tel: +49(0)6131/192401.4. Emergency telephone

number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008

This mixture is not classified as hazardous in accordance with Regulation (EC) No. 1272/2008.

2.2. Label elements

Hazard components for [email protected]

No risks worthy of mention. Please observe the information on the safety data sheet at all times.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures

aqueous solutionChemical characterization

Further Information

Product does not contain listed SVHC substances > 0,1 % according to Regulation (EC) No. 1907/2006 Article

59 (REACH)

SECTION 4: First aid measures

4.1. Description of first aid measures

In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet

if possible).

General information

Print date: 17.02.2020GB - ENRevision No: 1,0

mailto:[email protected]

http://http://www.morphisto.de





@1501.B015819 In case of allergic symptoms, especially in the breathing area, seek medical advice

immediately.

After inhalation

@0403.B004101 In case of skin irritation, seek medical treatment.

After contact with skin

In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids

apart. Subsequently consult an ophthalmologist.

After contact with eyes

Let water be drunken in little sips (dilution effect). In all cases of doubt, or when symptoms persist, seek medical

advice.

After ingestion

4.2. Most important symptoms and effects, both acute and delayed

No information available.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Carbon dioxide (CO2). Dry extinguishing powder. alcohol resistant foam. Atomized water.

Suitable extinguishing media

High power water jet.

Unsuitable extinguishing media

5.2. Special hazards arising from the substance or mixture

Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2). Nitrogen oxides (NOx). Hydrocyanic

acid (hydrocyanic acid).

In case of fire: Wear self-contained breathing apparatus.

5.3. Advice for firefighters

Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

Additional information

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Wear personal protection equipment. (refer to chapter 8)

Do not allow to enter into surface water or drains.6.2. Environmental precautions

Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).

Treat the recovered material as prescribed in the section on waste disposal .

Clean contaminated objects and areas thoroughly observing environmental regulations.

6.3. Methods and material for containment and cleaning up

See protective measures under point 7 and 8.

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Wear personal protection equipment. (refer to chapter 8)

Advice on safe handling






The product is not: Combustible.

No special fire protection measures are necessary.

Advice on protection against fire and explosion

Avoid contact with skin, eyes and clothes.

General protection and hygiene measures: refer to chapter 8

Further information on handling

7.2. Conditions for safe storage, including any incompatibilities

@1501.B015764

Protect against direct sunlight. Keep away from heat.

Requirements for storage rooms and vessels

Do not store together with: Explosives. Oxidizing solids. Oxidizing liquids. Radioactive substances. Infectious

substances.

Hints on joint storage

Protect against: UV-radiation/sunlight. heat.

Further information on storage conditions

7.3. Specific end use(s)

@0102.B010347

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

To date, no national critical limit values exist.

Additional advice on limit values

8.2. Exposure controls

Use extractor hood (laboratory).

Appropriate engineering controls

Always close containers tightly after the removal of product. Do not eat, drink, smoke or sneeze at the

workplace. Wash hands before breaks and after work. Handle in accordance with good industrial hygiene and

safety practice.

Protective and hygiene measures

Tightly sealed safety glasses. DIN EN 166

Eye/face protection

In case of prolonged or frequently repeated skin contact:

Pull-over gloves of rubber. EN ISO 374

Suitable material:

NBR (Nitrile rubber). (0,11 mm, Breakthrough time >= 480 min):

Before using check leak tightness / impermeability. In the case of wanting to use the gloves again, clean them

before taking off and air them well.

For special purposes, it is recommended to check the resistance to chemicals of the protective gloves

mentioned above together with the supplier of these gloves.

Hand protection

Protective clothing.

Minimum standard for preventive measures while handling with working materials are specified in the TRGS 500

Skin protection






(D).

With correct and proper use, and under normal conditions, breathing protection is not required.

Respiratory protection

No special measures are necessary.

Environmental exposure controls

yellow

liquidPhysical state:

Colour:

9.1. Information on basic physical and chemical properties

SECTION 9: Physical and chemical properties

not determinedOdour:

pH-Value: ~7

Changes in the physical state

~100 °CInitial boiling point and boiling range:

>60 °CFlash point:

none

Explosive properties

not determinedIgnition temperature:

none

Oxidizing properties

Vapour pressure: not determined

Density: not determined

Water solubility: highly soluble.

0% - @1501.B150227Solvent content:

9.2. Other information


SECTION 10: Stability and reactivity

10.1. Reactivity

Stable under normal storage and handling conditions.

10.2. Chemical stability

Stable under normal storage and handling conditions.

Hazardous decomposition products: Hydrocyanic acid (hydrocyanic acid).

10.3. Possibility of hazardous reactions

May release HCN at contact with strong acids when heated.


10.4. Conditions to avoid

Oxidizing agents, strong. Reducing agents, strong. Nitrites. Strong acid. Ammonia. Halogen hydride.

10.5. Incompatible materials

Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2). Nitrogen oxides (NOx). Hydrocyanic

acid (hydrocyanic acid).

10.6. Hazardous decomposition products

SECTION 11: Toxicological information






11.1. Information on toxicological effects

Toxicocinetics, metabolism and distribution


Acute toxicity

Based on available data, the classification criteria are not met.


Irritation and corrosivity

Sensitising effects


Carcinogenic/mutagenic/toxic effects for reproduction


STOT-single exposure



STOT-repeated exposure

Aspiration hazard



Specific effects in experiment on an animal

SECTION 12: Ecological information

12.1. Toxicity

@1718.B017281

12.2. Persistence and degradability

The methods for determining the biological degradability are not applicable to inorganic substances.

12.3. Bioaccumulative potential

No indication of bioaccumulation potential.

@1718.B017281

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

The components in this formulation do not meet the criteria for classification as PBT or vPvB.

@1718.B017281

12.6. Other adverse effects

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal recommendations

Dispose of waste according to applicable legislation. Consult the local waste disposal expert about waste

disposal. Non-contaminated packages may be recycled.

List of Wastes Code - residues/unused products

160509 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded

chemicals; discarded chemicals other than those mentioned in 16 05 06, 16 05 07 or 16 05 08

List of Wastes Code - used product

WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded

chemicals; discarded chemicals other than those mentioned in 16 05 06, 16 05 07 or 16 05 08

160509

List of Wastes Code - contaminated packaging






WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE

CLOTHING NOT OTHERWISE SPECIFIED; absorbents, filter materials, wiping cloths and protective

clothing; absorbents, filter materials, wiping cloths and protective clothing other than those mentioned

in 15 02 02

150203

Handle contaminated packages in the same way as the substance itself.

Contaminated packaging

SECTION 14: Transport information

Land transport (ADR/RID)

Not restricted

Other applicable information (land transport)

Inland waterways transport (ADN)

Not restricted

Other applicable information (inland waterways transport)

Marine transport (IMDG)

Not restricted

Other applicable information (marine transport)

Air transport (ICAO-TI/IATA-DGR)

Not restricted

Other applicable information (air transport)

14.5. Environmental hazards

noENVIRONMENTALLY HAZARDOUS:

14.6. Special precautions for user


14.7. Transport in bulk according to Annex II of Marpol and the IBC Code


SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulatory information

0%, VOC Directive 2004/42/EC: 0 g/l2004/42/EC (VOC):

Additional information

The preparation is not dangerous in the sense of Directive 1999/45/EC.

This mixture is classified as not hazardous according to Regulation (EC) 1272/2008 [CLP].

National regulatory information

2 - clearly water contaminatingWater contaminating class (D):

15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Changes

Rev. 1,00; 13.01.2015; Initial release

Abbreviations and acronyms

ADR: Accord européen sur le transport des marchandises dangereuses par Route ( European Agreement

concerning the






RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer

(Regulations

Concerning the International Transport of Dangerous Goods by Rail )

IMDG: International Maritime Code for Dangerous Goods

IATA: International Air Transport Association

IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)

ICAO: International Civil Aviation Organization

ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)

GHS: Globally Harmonized System of Classification and Labelling of Chemicals

OSHA: Occupational Safety and Health Administration

LC50: Lethal concentration, 50 percent

LD50: Lethal dose, 50 percent

NOAEL: No observed adverse effect level

LOAEL: Lowest observed adverse effect level

NOAEC: No observed adverse effect level

LOAEC: Lowest observed adverse effect concentration

DNEL: Derived No Effect Level

PNEC: predicted no effect concentration

TSCA: Toxic Substances Control Act

IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER

NTP: National Toxicology Program

SARA: Superfund Amendments and Reauthorization Act

GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)

PBT: Persistent bioaccumulative toxic

SVHC: substance of very high concern

The above information describes exclusively the safety requirements of the product and is based on our

present-day knowledge. The information is intended to give you advice about the safe handling of the product

named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be

transferred to other products. In the case of mixing the product with other products or in the case of processing,

the information on this safety data sheet is not necessarily valid for the new made-up material.

Further Information

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety

data sheet.)


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