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Karthik Vijay [email protected] +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin,...

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Karthik Vijay [email protected] +44 7584 643 677 25 Nov 2015
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Page 1: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Karthik Vijay

[email protected]

+44 7584 643 677

25 Nov 2015

Page 2: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Indium Corporation

© Indium Corporation

Page 3: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Medical PCB Assembly & Solder Paste

Solder paste Requirements

• SAC305 or SnPb alloys• Flux compatibility with

cleaning process• High Electrical Reliability• Low Voiding• Good printing

Page 4: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Cleaning Challenges after Paste Reflow

• High impedance front-end• Flux residues can “short out”

front-end, particularly under humid conditions

Page 5: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

High Electrical ReliabilityStringent SIR Requirements

Spacing = 0.2mmSpacing = 0.5mm

Page 6: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Electrical Reliability for Low-Standoff Component

Dendritic growth

Page 7: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

RCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction

Activator RCOOH in flux

RCOO- + H+

mobile in liquid environment

Solvent dried out

H2O H+ engage in corrosion reaction

Solvent retained

Flux Activator & Solvents during Reflow of Low-Standoff Components

7

Page 8: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Flux Chemistry DesignSIR Electrical Reliability Test

1

2

3

4

5

I

X1 2

34

5 I

X

X X

X

SIR - Standard SIR + Glass Slide

Page 9: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

© Indium Corporation

Voiding

- 225u Square

Apertures (9)

- 7.75mm square

ground plane

P5 Profile

Hot Profile

Check effect of

temperature & time

on voiding

Page 10: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

© Indium Corporation

Voiding

Hot Profile P5 Profile Hot Profile P5 Profile

Paste A Paste I

Paste A (mean void%) Paste I (mean void%)

Hot Profile 22.73% 7.34%

P5 Profile 37.34% 11.58%

Page 11: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Printing – Transfer Efficiency

Slide #11

2-hours 4-hours1-hour

Page 12: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Printing – Response to Pause

Slide #12

Volu

me(%

)

0

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PCB ID

0 Hours 1 Hour 2 Hours 4 Hours 0 Hours 1 Hour 2 Hours 4 Hours 0 Hours 1 Hour 2 Hours 4 Hours 0 Hours 1 Hour 2 Hours 4 Hours 0 Hours 1 Hour 2 Hours 4 Hours 0 Hours 1 Hour 2 Hours 4 Hours RTP

25 mm/s 50 mm/s 100 mm/s 25 mm/s 50 mm/s 100 mm/s Print_Speed

Q230 Indium8.9E (593-6-1) Paste_ID

Std

Dev

0

10

20

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PCB ID

0 Hours 1 Hour 2 Hours 4 Hours 0 Hours 1 Hour 2 Hours 4 Hours 0 Hours 1 Hour 2 Hours 4 Hours 0 Hours 1 Hour 2 Hours 4 Hours 0 Hours 1 Hour 2 Hours 4 Hours 0 Hours 1 Hour 2 Hours 4 Hours RTP

25 mm/s 50 mm/s 100 mm/s 25 mm/s 50 mm/s 100 mm/s Print_Speed

Q230 Indium8.9E (593-6-1) Paste_ID

Paste A Paste I

Minimum DeviationMore Deviation

Area Ratio = 0.58 Apertures = 0.25mm dia

Page 13: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Au Solders in Medical Assembly

Page 14: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Au Solders in Medical Assembly

Page 15: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

High-Strength 80Au/20Sn Solder in Medical Assembly

15 INDIUM CORPORATION CONFIDENTIAL

• Catheters

• Endoscope

• “In Vivo” MEMS &

Sensors

Solder Nitinol &

Stainless Steel

• 80Au/20Sn (Wire,

Washer preform)

• Flux

Page 16: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

High-Strength 80Au/20Sn Solder in Medical Assembly

Very fine wire:

25-250u diameterVery thin preform:

13u thickness

Page 17: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

© Indium Corporation

Au Solders in Implantable Devices

• Pure Gold is inert and often used for biocompatibility reasons

• Precision, high aspect ratio (thin wall/thick), Au washers are required for feed-through apps

• Complex/compound Au “racetrack” designs for sealing batteries and connection boxes

• High purity standards and stringent quality specifications

Page 18: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Complex Au Solder Preforms in Medical Assembly

18 INDIUM CORPORATION CONFIDENTIAL

• Standard aspect ratio = 1.5

(ratio of max thickness to wall)

• Ability to increase the

aspect ratio for wider

process window

Page 19: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

© Indium Corporation

Au & In Solders for Hermetic Sealing

• Hermetic seal often required to protect delicate components from harsh conditions

• Sealing optics in medical devices typically a flux-less process

• AuSn in a flux-less process is ideal for hermetic sealing primarily due to oxide resistance and high reliability characteristics

• Indium and Indium alloys are ideal for cryogenic sealing due to their malleable and ductile properties even at extremely low temperatures

Page 20: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

© Indium Corporation

Integrated Solder Preforms Monitoring & Diagnostic Devices

Page 21: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Flux-Coated Preforms for Cavity Soldering

Current Process

• Paste printed inside

cavity + Preform

(depth 0.15 + 0.1/-0 mm)

• >> 20% voids - rejects

• Reject Rate with solder

paste = 25%

Page 22: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Flux-Coated Preforms for Cavity Soldering

9.27mm x 5.59 mm; 300µ thick

Low Voiding << 5%

Very Good Wetting

Page 23: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

In Solders as TIMs (Thermal Interface

Materials)

Page 24: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Thermal Conductivity

• 100In; k= 87 W/m.K

• Grease/PCM; k= 3-10 W/m.K

Pumpout

• No pumpout with Solder-TIM

• Grease/PCM migrates from the

center; poor thermals

Bakeout

• No bakeout with Solder-TIM

• Grease/PCM becomes powdery

with bakeout ; poor thermals

Thermal Management : Solder-TIMs vs Thermal Grease / Phase Change Materials

Page 25: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Clamping Force

Low

Spot

High

Spot

Base surfaceTIM

Heat-Spring® Compressible Solder-TIM

Heat-Spring®• Compressible Solder-TIM

• Surface altered for lower interface resistance

• Only needs compression force (3-4 bar)

• No heat, No melting, No Metallization, No flux, No Voiding

Page 26: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

26

Effect of Compression on Interface ResistanceGrease vs Flat Solder Foil vs In Heat-Spring®

Page 27: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

27

Time 0 Time 0

88 - 90 86 - 88 84 - 86 82 - 84 80 - 82 78 - 80 76 - 78 74 - 76 72 - 74 70 - 72 68 - 70 66 - 68 64 - 66 62 - 64 60 - 62

1561 Hr. @90C1597 Hr. @90C

88 - 90 86 - 88 84 - 86 82 - 84 80 - 82 78 - 80 76 - 78 74 - 76 72 - 74 70 - 72 68 - 70 66 - 68 64 - 66 62 - 64 60 - 62

3108 Hr. @90C 3056 Hr. @90C

88 - 90 86 - 88 84 - 86 82 - 84 80 - 82 78 - 80 76 - 78 74 - 76 72 - 74 70 - 72 68 - 70 66 - 68 64 - 66 62 - 64 60 - 62

Heat-Spring® Grease Heat-Spring® Grease

Heat-Spring® Grease

Grease vs Heat-Spring®Bake Test @ 90 deg C; T = 0, 1500, 3000 hrs

Grease pumps out of

the interface, leaving

the center dry

Heat-Spring®

conforms to the

interface, leaving the

interface cooler

Page 28: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

28

Grease / PCM

Heat-Spring®

0-50W, 3min ON / 2min OFF, 1000 cycles

Heat-Spring® Resists PumpoutPower Cycling: 0-50W, 3min ON / 2min OFF, 1000 cycles

Page 29: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Grease vs Heat-Spring®Power Cycling: 0-50W, 3min ON / 2min OFF, 1000 cycles

Grease pumps out of

the interface, leaving

the center dry

Heat-Spring®

conforms to the

interface, leaving the

interface cooler

Page 30: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

NanoFoil®

Page 31: Karthik Vijay kvijay@indium.com +44 7584 643 677 KVijay INDIUM.pdfRCOOH encapsulated in solid rosin, incapable of engaging in corrosion reaction Activator RCOOH in flux RCOO-+ H+ mobile

Thank You…


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